JP4672974B2 - Gas generant composition - Google Patents
Gas generant composition Download PDFInfo
- Publication number
- JP4672974B2 JP4672974B2 JP2003361979A JP2003361979A JP4672974B2 JP 4672974 B2 JP4672974 B2 JP 4672974B2 JP 2003361979 A JP2003361979 A JP 2003361979A JP 2003361979 A JP2003361979 A JP 2003361979A JP 4672974 B2 JP4672974 B2 JP 4672974B2
- Authority
- JP
- Japan
- Prior art keywords
- component
- mass
- oxide
- metal
- gas generant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 59
- 239000007789 gas Substances 0.000 claims description 59
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 29
- 239000000347 magnesium hydroxide Substances 0.000 claims description 29
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- -1 carboxy Methyl ethyl cellulose, microcrystalline Chemical compound 0.000 claims description 18
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 17
- NDEMNVPZDAFUKN-UHFFFAOYSA-N guanidine;nitric acid Chemical compound NC(N)=N.O[N+]([O-])=O.O[N+]([O-])=O NDEMNVPZDAFUKN-UHFFFAOYSA-N 0.000 claims description 13
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 12
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 229920002907 Guar gum Polymers 0.000 claims description 9
- 239000000665 guar gum Substances 0.000 claims description 9
- 235000010417 guar gum Nutrition 0.000 claims description 9
- 229960002154 guar gum Drugs 0.000 claims description 9
- 229910044991 metal oxide Inorganic materials 0.000 claims description 9
- 239000007800 oxidant agent Substances 0.000 claims description 9
- 150000004706 metal oxides Chemical class 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 6
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 6
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 6
- 229940105329 carboxymethylcellulose Drugs 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 229920002401 polyacrylamide Polymers 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 5
- 239000000446 fuel Substances 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical group [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000001856 Ethyl cellulose Substances 0.000 claims description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- 229920001249 ethyl cellulose Polymers 0.000 claims description 3
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 3
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 229920000896 Ethulose Polymers 0.000 claims description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 2
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 claims description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 2
- 239000005909 Kieselgur Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 2
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 229920000800 acrylic rubber Polymers 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 238000005576 amination reaction Methods 0.000 claims description 2
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 2
- 239000011609 ammonium molybdate Substances 0.000 claims description 2
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 2
- 229940010552 ammonium molybdate Drugs 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 229910052728 basic metal Inorganic materials 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 229910000416 bismuth oxide Inorganic materials 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 229920002301 cellulose acetate Polymers 0.000 claims description 2
- 229920006217 cellulose acetate butyrate Polymers 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 229910021446 cobalt carbonate Inorganic materials 0.000 claims description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 2
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 claims description 2
- KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 claims description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 229940116318 copper carbonate Drugs 0.000 claims description 2
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 claims description 2
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 2
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 claims description 2
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 2
- 229960001545 hydrotalcite Drugs 0.000 claims description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 2
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- 235000010981 methylcellulose Nutrition 0.000 claims description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 claims description 2
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 2
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 2
- UOURRHZRLGCVDA-UHFFFAOYSA-D pentazinc;dicarbonate;hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]C([O-])=O.[O-]C([O-])=O UOURRHZRLGCVDA-UHFFFAOYSA-D 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims 1
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 229960004643 cupric oxide Drugs 0.000 claims 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 229910052914 metal silicate Inorganic materials 0.000 claims 1
- 229920003087 methylethyl cellulose Polymers 0.000 claims 1
- 239000010445 mica Substances 0.000 claims 1
- 229910052618 mica group Inorganic materials 0.000 claims 1
- 239000008108 microcrystalline cellulose Substances 0.000 claims 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims 1
- 229940016286 microcrystalline cellulose Drugs 0.000 claims 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 30
- 238000002485 combustion reaction Methods 0.000 description 20
- 239000003795 chemical substances by application Substances 0.000 description 15
- 238000009472 formulation Methods 0.000 description 14
- 239000002245 particle Substances 0.000 description 11
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 10
- 229910002091 carbon monoxide Inorganic materials 0.000 description 9
- 231100000331 toxic Toxicity 0.000 description 9
- 230000002588 toxic effect Effects 0.000 description 9
- 229920000877 Melamine resin Polymers 0.000 description 7
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 7
- IDCPFAYURAQKDZ-UHFFFAOYSA-N 1-nitroguanidine Chemical compound NC(=N)N[N+]([O-])=O IDCPFAYURAQKDZ-UHFFFAOYSA-N 0.000 description 6
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 6
- 229910002010 basic metal nitrate Inorganic materials 0.000 description 5
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 5
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 5
- 230000001603 reducing effect Effects 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 description 4
- 150000001540 azides Chemical class 0.000 description 4
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 description 4
- 229910001487 potassium perchlorate Inorganic materials 0.000 description 4
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 3
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 description 3
- YTNLBRCAVHCUPD-UHFFFAOYSA-N 5-(1$l^{2},2,3,4-tetrazol-5-yl)-1$l^{2},2,3,4-tetrazole Chemical compound [N]1N=NN=C1C1=NN=N[N]1 YTNLBRCAVHCUPD-UHFFFAOYSA-N 0.000 description 3
- 239000000567 combustion gas Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 3
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 3
- 239000002341 toxic gas Substances 0.000 description 3
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 2
- ULRPISSMEBPJLN-UHFFFAOYSA-N 2h-tetrazol-5-amine Chemical compound NC1=NN=NN1 ULRPISSMEBPJLN-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 229910001964 alkaline earth metal nitrate Inorganic materials 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- 235000012501 ammonium carbonate Nutrition 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N anhydrous guanidine Natural products NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 2
- 229910003439 heavy metal oxide Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- BAKYASSDAXQKKY-UHFFFAOYSA-N 4-Hydroxy-3-methylbenzaldehyde Chemical compound CC1=CC(C=O)=CC=C1O BAKYASSDAXQKKY-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- YSKUZVBSHIWEFK-UHFFFAOYSA-N ammelide Chemical compound NC1=NC(O)=NC(O)=N1 YSKUZVBSHIWEFK-UHFFFAOYSA-N 0.000 description 1
- MASBWURJQFFLOO-UHFFFAOYSA-N ammeline Chemical compound NC1=NC(N)=NC(O)=N1 MASBWURJQFFLOO-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000002928 artificial marble Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- WFLYOQCSIHENTM-UHFFFAOYSA-N molybdenum(4+) tetranitrate Chemical compound [N+](=O)([O-])[O-].[Mo+4].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-] WFLYOQCSIHENTM-UHFFFAOYSA-N 0.000 description 1
- SFDJOSRHYKHMOK-UHFFFAOYSA-N nitramide Chemical class N[N+]([O-])=O SFDJOSRHYKHMOK-UHFFFAOYSA-N 0.000 description 1
- LFLZOWIFJOBEPN-UHFFFAOYSA-N nitrate, nitrate Chemical compound O[N+]([O-])=O.O[N+]([O-])=O LFLZOWIFJOBEPN-UHFFFAOYSA-N 0.000 description 1
- UAGLZAPCOXRKPH-UHFFFAOYSA-N nitric acid;1,2,3-triaminoguanidine Chemical compound O[N+]([O-])=O.NNC(NN)=NN UAGLZAPCOXRKPH-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- QGWDKKHSDXWPET-UHFFFAOYSA-E pentabismuth;oxygen(2-);nonahydroxide;tetranitrate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[O-2].[Bi+3].[Bi+3].[Bi+3].[Bi+3].[Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O QGWDKKHSDXWPET-UHFFFAOYSA-E 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
Landscapes
- Air Bags (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Description
本発明は、自動車等のエアバック拘束システムに適したガス発生剤組成物、その成型体及びそれらを用いたエアバック用インフレータに関する。 The present invention relates to a gas generant composition suitable for an air bag restraining system of an automobile or the like, a molded body thereof, and an air bag inflator using them.
自動車における乗員保護装置としてのエアバッグ用ガス発生剤としては、従来からアジ化ナトリウムを用いた組成物が多用されてきた。しかし、アジ化ナトリウムの人体に対する毒性[ＬＤ５０（oral−rat）＝２７ｍｇ／ｋｇ]や取扱い時の危険性が問題視され、それに替わるより安全ないわゆる非アジド系ガス発生剤組成物として、各種の含窒素有機化合物を含むガス発生剤組成物が開発されている。 Conventionally, a composition using sodium azide has been frequently used as a gas generating agent for an air bag as an occupant protection device in an automobile. However, the toxicity of sodium azide to the human body [LD 50 (oral-rat) = 27 mg / kg] and the danger during handling are regarded as problems, and as a safer so-called non-azide gas generant composition, there are various Gas generant compositions containing these nitrogen-containing organic compounds have been developed.
米国特許4,909,549号には、水素を含むテトラゾール、トリアゾール化合物と酸素含有酸化剤との組成物が開示されている。米国特許4,370,181号には、水素を含まないビテトラゾールの金属塩と酸素を含まない酸化剤とからなるガス発生剤組成物が開示されている。米国特許4,369,079号には、水素を含まないビテトラゾールの金属塩とアルカリ金属硝酸塩、アルカリ金属亜硝酸塩、アルカリ土類金属硝酸塩、アルカリ土類金属亜硝酸塩及びこれらの混合物からなるガス発生剤組成物が開示されている。米国特許5,542,999号には、ＧＺＴ，ＴＡＧＮ（トリアミノニトログアニジン），ＮＧ（ニトログアニジン）、ＮＴＯ等の燃料、塩基性硝酸銅、有毒ガスを低減する触媒とクーラント剤からなるガス発生剤が開示されている。特開平10-72273号には、ビテトラゾール金属塩、ビテトラゾールアンモニウム塩、アミノテトラゾールと硝酸アンモニウムからなるガス発生剤が開示されている。 U.S. Pat. No. 4,909,549 discloses a composition of a tetrazole or triazole compound containing hydrogen and an oxygen-containing oxidizing agent. US Pat. No. 4,370,181 discloses a gas generant composition comprising a metal salt of bitetrazole containing no hydrogen and an oxidizing agent containing no oxygen. U.S. Pat.No. 4,369,079 discloses a gas generant composition comprising a hydrogen-free metal salt of bitetrazole and an alkali metal nitrate, an alkali metal nitrite, an alkaline earth metal nitrate, an alkaline earth metal nitrite and a mixture thereof. It is disclosed. US Pat. No. 5,542,999 discloses a gas generating agent comprising a fuel such as GZT, TAGN (triaminonitroguanidine), NG (nitroguanidine), NTO, basic copper nitrate, a catalyst for reducing toxic gases, and a coolant agent. ing. Japanese Patent Application Laid-Open No. 10-72273 discloses a gas generating agent composed of a bitetrazole metal salt, a bitetrazole ammonium salt, aminotetrazole and ammonium nitrate.
しかし、アジド系ガス発生剤は、一般的に燃焼後に窒素しか生成しないが、非アジド系ガス発生剤組成物は、一般的に炭素、窒素、酸素を含むので、燃焼後において、有毒な一酸化炭素及び窒素酸化物を少量生成する欠点がある。また、非アジド系ガス発生剤は、一般的にアジド系ガス発生剤に比べれば、燃焼温度が高く、実際に使われると、大量のクーラントが必要となる。 However, azide-based gas generants generally produce only nitrogen after combustion, whereas non-azide-based gas generant compositions generally contain carbon, nitrogen, and oxygen, so that toxic monoxide after combustion. There is a disadvantage of producing small amounts of carbon and nitrogen oxides. Non-azide gas generants generally have a higher combustion temperature than azide gas generants, and require a large amount of coolant when actually used.
燃焼後における有毒な一酸化炭素及び窒素酸化物の生成量を減らすため、ガス発生剤に金属酸化物、又はDeNOx剤（窒素酸化物低減剤）を添加することが知られている。例えば、ドイツ特許4,401,213号のガス発生剤組成物は、有毒な一酸化炭素及び窒素酸化物の生成量を減らすために、触媒としてのV２O５/MoO３のような重金属酸化物を添加するものである。しかし、重金属酸化物の毒性問題があり、金属酸化物を添加すると、ガス発生剤のガス発生効率が低くなる。 In order to reduce the amount of toxic carbon monoxide and nitrogen oxides produced after combustion, it is known to add metal oxides or DeNOx agents (nitrogen oxide reducing agents) to the gas generating agent. For example, the gas generant composition of German Patent 4,401,213 adds a heavy metal oxide such as V 2 O 5 / MoO 3 as a catalyst to reduce the production of toxic carbon monoxide and nitrogen oxides. Is. However, there is a toxicity problem of heavy metal oxides, and when a metal oxide is added, the gas generation efficiency of the gas generating agent is lowered.
ＷＯ98／04507号には、硫酸アンモニウム、炭酸アンモニウム、尿素等のDeNOx剤とガス発生剤とを併用して、燃焼ガス中の窒素酸化物の生成量を低減することが開示されている。しかし、硫酸アンモニウムを使うと、有毒な硫黄酸化物を生成し、炭酸アンモニウム、尿素は、熱安定性に問題があり、更にこれらのDeNOx剤を添加すると、ガス発生剤の酸化剤を消耗し、有毒な一酸化炭素の生成量が増える。
従って、本発明の課題は、ガス発生剤の燃焼ガス中の有毒な一酸化炭素及び窒素酸化物の生成量が少なく、燃焼温度が低いガス発生剤組成物、その成型体及びそれらを用いたエアバック用インフレータを提供することにある。 Accordingly, an object of the present invention is to provide a gas generant composition having a low generation temperature of toxic carbon monoxide and nitrogen oxide in the combustion gas of the gas generant and a low combustion temperature, a molded body thereof, and an air using the same. The object is to provide a back inflator.
本発明者は、ガス発生剤組成物の組成として特定の組み合わせのものを選択することにより、燃焼温度を低下でき、その結果、燃焼ガス中の有毒な一酸化炭素、アンモニウム及び窒素酸化物の生成量を低減できることを見出し、本発明を完成した。 The inventor can reduce the combustion temperature by selecting a specific combination of gas generant compositions, resulting in the generation of toxic carbon monoxide, ammonium and nitrogen oxides in the combustion gas. The present invention has been completed by finding that the amount can be reduced.
本発明は、課題の解決手段として、
下記（ａ）成分、（ｂ）成分及び（ｃ）成分含有し、必要に応じて更に（ｄ）成分、（ｅ）成分及び（ｆ）成分から選ばれる１、２又は３を含有するガス発生剤組成物を提供する。
As a means for solving the problems, the present invention
Gas generation containing the following (a) component, (b) component and (c) component, and further containing 1, 2 or 3 as required from (d) component, (e) component and (f) component An agent composition is provided.
（ａ）燃料としての有機化合物
（ｂ）含酸素酸化剤
（ｃ）水酸化マグネシウム、又は水酸化マグネシウム及び水酸化アルミニウムの混合物
（ｄ）バインダ
（ｅ）金属酸化物、金属炭酸化物から選ばれる添加剤
（ｆ）比表面積が１００〜５００ｍ２／ｇである二酸化ケイ素
更に本発明は、他の課題の解決手段として、上記のガス発生剤組成物を成形して得られるガス発生剤組成物成型体と、上記のガス発生剤組成物又は前記のガス発生剤成型体を用いるエアバッグ用インフレータを提供する。
(A) Organic compound as fuel (b) Oxygenated oxidizer (c) Magnesium hydroxide or a mixture of magnesium hydroxide and aluminum hydroxide (d) Binder (e) Addition selected from metal oxide and metal carbonate Agent (f) Silicon dioxide having a specific surface area of 100 to 500 m 2 / g Further, the present invention provides a gas generant composition molded body obtained by molding the gas generant composition as a means for solving other problems. And an inflator for an airbag using the gas generant composition or the gas generant molded body.
本発明のガス発生剤組成物及びその成型体は、燃焼温度が低く、燃焼時に一酸化炭素や窒素酸化物の生成量が少ない。 The gas generant composition of the present invention and the molded body thereof have a low combustion temperature, and the amount of carbon monoxide and nitrogen oxides produced during combustion is small.
本発明で用いる（ａ）成分の燃料としての有機化合物としては、テトラゾール類化合物、グアニジン類化合物、トリアジン類化合物、ニトロアミン類化合物から選ばれる少なくとも１種が挙げられる。 Examples of the organic compound as the component (a) fuel used in the present invention include at least one selected from tetrazole compounds, guanidine compounds, triazine compounds, and nitroamine compounds.
テトラゾール類化合物は、５−アミノテトラゾール、ビテトラゾールアンモニウム塩等が好ましい。グアニジン類化合物は、グアニジン硝酸塩（硝酸グアニジン）、アミノグアニジン硝酸塩、ニトログアニジン、トリアミノグアニジン硝酸塩等が好ましい。トリアジン化合物は、メラミン、シアヌル酸、アンメリン、アンメリド、アンメランド等が好ましい。ニトロアミン類化合物は、シクロ−1,3,5-トリメチレン-2,4,6-トリニトラミンが好ましい。 The tetrazole compounds are preferably 5-aminotetrazole, bitetrazole ammonium salt and the like. The guanidine compound is preferably guanidine nitrate (guanidine nitrate), aminoguanidine nitrate, nitroguanidine, triaminoguanidine nitrate or the like. The triazine compound is preferably melamine, cyanuric acid, ammelin, ammelide, ammeland and the like. The nitroamine compound is preferably cyclo-1,3,5-trimethylene-2,4,6-trinitramine.
本発明で用いる（ｂ）成分の含酸素酸化剤は、（ｂ−１）塩基性金属硝酸塩、硝酸塩、硝酸アンモニウム、及び（ｂ−２）過塩素酸塩及び塩素酸塩から選ばれる少なくとも１種を含有することが好ましい。 The oxygen-containing oxidizer of component (b) used in the present invention is at least one selected from (b-1) basic metal nitrate, nitrate, ammonium nitrate, and (b-2) perchlorate and chlorate. It is preferable to contain.
（ｂ−１）成分の塩基性金属硝酸塩としては、塩基性硝酸銅、塩基性硝酸コバルト、塩基性硝酸亜鉛、塩基性硝酸マンガン、塩基性硝酸鉄、塩基性硝酸モリブデン、塩基性硝酸ビスマス及び塩基性硝酸セリウムから選ばれる少なくとも１種が挙げられる。 As the basic metal nitrate of component (b-1), basic copper nitrate, basic cobalt nitrate, basic zinc nitrate, basic manganese nitrate, basic iron nitrate, basic molybdenum nitrate, basic bismuth nitrate and base And at least one selected from basic cerium nitrate.
塩基性金属硝酸塩は、燃焼速度を高めるため、平均粒径は３０μｍ以下が好ましく、１０μｍ以下がより好ましい。なお、平均粒径は、レーザー散乱光による粒度分布法により測定したものである。測定サンプルは、塩基性金属硝酸塩を水に分散させた後、超音波を３分間照射したものを用い、粒子数の５０％累積値（Ｄ５０）を求めて、２回の測定による平均値を平均粒径とする。 The basic metal nitrate has an average particle size of preferably 30 μm or less and more preferably 10 μm or less in order to increase the burning rate. The average particle size is measured by a particle size distribution method using laser scattered light. The measurement sample was obtained by dispersing a basic metal nitrate in water and then irradiating with ultrasonic waves for 3 minutes, obtaining a 50% cumulative value (D 50 ) of the number of particles, and calculating the average value of two measurements. Average particle diameter.
（ｂ−１）成分の硝酸塩としては、硝酸カリウム、硝酸ナトリウム等のアルカリ類金属硝酸塩と硝酸ストロンチウム等のアルカリ土類金属硝酸塩等が挙げられる。 Examples of the nitrate of component (b-1) include alkaline metal nitrates such as potassium nitrate and sodium nitrate, and alkaline earth metal nitrates such as strontium nitrate.
（ｂ−２）成分の過塩素酸塩及び塩素酸塩は、酸化作用と共に、燃焼促進作用もする成分である。酸化作用は、燃焼中に酸素を発生することで燃焼を効率良く進行させると共に、アンモニア、一酸化炭素等の有毒ガスの生成量を減少させる作用を意味する。一方、燃焼促進作用は、ガス発生剤組成物の着火性を向上させる作用、又は燃焼速度を向上させる作用を意味する。 The (b-2) component perchlorate and chlorate are components that also have a combustion promoting action as well as an oxidizing action. Oxidation means the action of efficiently producing combustion by generating oxygen during combustion and reducing the amount of toxic gases such as ammonia and carbon monoxide. On the other hand, the combustion promoting action means an action for improving the ignitability of the gas generant composition or an action for improving the combustion rate.
過塩素酸塩及び塩素酸塩としては、過塩素酸アンモニウム、過塩素酸カリウム、過塩素酸ナトリウム、塩素酸カリウム、塩素酸ナトリウムから選ばれる少なくとも１種が挙げられる。 Examples of the perchlorate and chlorate include at least one selected from ammonium perchlorate, potassium perchlorate, sodium perchlorate, potassium chlorate, and sodium chlorate.
本発明で用いる（ｃ）成分は水酸化マグネシウム、又は水酸化マグネシウム及び水酸化アルミニウムの混合物であり、水酸化マグネシウムを単独で用いることが好ましい。水酸化マグネシウム及び水酸化アルミニウムの混合物であるとき、水酸化マグネシウムの含有量は５０質量％以上である。 The component (c) used in the present invention is magnesium hydroxide or a mixture of magnesium hydroxide and aluminum hydroxide, and it is preferable to use magnesium hydroxide alone. When it is a mixture of magnesium hydroxide and aluminum hydroxide, the content of magnesium hydroxide is 50% by mass or more.
水酸化マグネシウムと水酸化アルミニウムは、低毒性が要求される難燃剤、人工大理石の原料、洗剤用のほか、樹脂やゴムの添加剤としても使用されているもので、毒性が低く、分解開始温度が高いという特徴がある。更に熱分解するときに大きく吸熱し、酸化マグネシウム又は酸化アルミニウムと水を生成する。このため、水酸化マグネシウム又は水酸化アルミニウムを含有させることにより、ガス発生剤組成物の燃焼温度が低くなり、燃焼後における、有毒な窒素酸化物と一酸化炭素の生成量を少なくするように作用する。このような有毒ガスの低減作用は、特に酸化剤として（ｂ−２）成分を使用したときに顕著となる。 Magnesium hydroxide and aluminum hydroxide are used as flame retardants that require low toxicity, raw materials for artificial marble, detergents, and as additives for resins and rubbers. Is characterized by high. Furthermore, when it thermally decomposes, it absorbs a large amount of heat and produces magnesium oxide or aluminum oxide and water. For this reason, the inclusion of magnesium hydroxide or aluminum hydroxide lowers the combustion temperature of the gas generant composition and acts to reduce the production of toxic nitrogen oxides and carbon monoxide after combustion. To do. Such a toxic gas reducing action is particularly noticeable when the component (b-2) is used as an oxidizing agent.
水酸化マグネシウム又は水酸化アルミニウムは、その平均粒径を調整することにより、（ａ）〜（ｃ）成分等を混合するときの全体の分散性を向上できるので、混合作業が容易となるほか、得られたガス発生剤組成物の着火性も向上される。 Magnesium hydroxide or aluminum hydroxide can improve the overall dispersibility when mixing the components (a) to (c) by adjusting the average particle size, so that the mixing operation becomes easy. The ignitability of the obtained gas generant composition is also improved.
水酸化マグネシウム又は水酸化アルミニウムの平均粒径は、好ましくは０．１〜７０μｍ、より好ましくは０．５〜５０μｍ、更に好ましくは２〜３０μｍである。平均粒径の測定方法は、塩基性金属硝酸塩の平均粒径の測定方法と同じである。 The average particle diameter of magnesium hydroxide or aluminum hydroxide is preferably 0.1 to 70 μm, more preferably 0.5 to 50 μm, and still more preferably 2 to 30 μm. The method for measuring the average particle size is the same as the method for measuring the average particle size of the basic metal nitrate.
本発明で用いる（ｄ）成分のバインダは、必要に応じて（ａ）〜（ｃ）成分、又は（ａ）〜（ｃ）成分と（ｅ）成分及び／又は（ｆ）成分と共に用いられる成分であり、ガス発生剤組成物の成形性を高め、ガス発生剤成型体の強度を高める成分である。ガス発生剤成型体の成型強度が強くない場合は、実際に燃焼する時に成型体が崩れて暴走的に燃焼して、燃焼をコントロールできない恐れがある。 The binder of the component (d) used in the present invention is a component used together with the components (a) to (c) or the components (a) to (c) and the components (e) and / or (f) as necessary. It is a component that improves the moldability of the gas generant composition and increases the strength of the gas generant molded product. If the molding strength of the gas generant molded body is not strong, the molded body may collapse when it is actually burned, causing runaway combustion, and control of combustion may not be possible.
バインダとしては、カルボキシメチルセルロース、カルボキシメチルセルロースナトリウム塩、カルボキシメチルセルロースカリウム塩、カルボキシメチルセルロースアンモニウム塩、酢酸セルロース、セルロースアセテートブチレート、メチルセルロース、エチルセルロース、ヒドロキシエチルセルロース、エチルヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、カルボキシメチルエチルセルロース、微結晶性セルロース、ポリアクリルアミド、ポリアクリルアミドのアミノ化物、ポリアクリルヒドラジド、アクリルアミド・アクリル酸金属塩共重合体、ポリアクリルアミド・ポリアクリル酸エステル化合物の共重合体、ポリビニルアルコール、アクリルゴム、グアガム、デンプン、シリコーンから選ばれる少なくとも１種が挙げられる。 Examples of the binder include carboxymethyl cellulose, carboxymethyl cellulose sodium salt, carboxymethyl cellulose potassium salt, carboxymethyl cellulose ammonium salt, cellulose acetate, cellulose acetate butyrate, methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, ethyl hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl ethyl cellulose, fine Crystalline cellulose, polyacrylamide, polyacrylamide amination, polyacryl hydrazide, acrylamide / metal acrylate copolymer, polyacrylamide / polyacrylate copolymer, polyvinyl alcohol, acrylic rubber, guar gum, starch, At least one selected from silicone And the like.
本発明で用いる（ｅ）成分の金属酸化物、金属炭酸化物から選ばれる添加剤は、必要に応じて（ａ）〜（ｃ）成分、又は（ａ）〜（ｃ）成分と（ｄ）成分及び／又は（ｆ）成分と共に用いられる成分であり、水酸化アルミニウムの作用を補助する目的で、即ち、ガス発生剤の燃焼温度を下げ、燃焼速度を調整し、燃焼後の有毒な窒素酸化物と一酸化炭素の生成量を低減させる目的で加えるものである。 The additive selected from the metal oxide and metal carbonate of the component (e) used in the present invention is the components (a) to (c), or the components (a) to (c) and the component (d) as necessary. And / or a component used together with the component (f) for the purpose of assisting the action of aluminum hydroxide, that is, reducing the combustion temperature of the gas generating agent, adjusting the combustion rate, and toxic nitrogen oxides after combustion. And for the purpose of reducing the amount of carbon monoxide produced.
添加剤としては、酸化銅、酸化鉄、酸化亜鉛、酸化コバルト、酸化マンガン、酸化モリブデン、酸化ニッケル、酸化ビスマス、シリカ、アルミナ等の金属酸化物；炭酸コバルト、炭酸カルシウム、塩基性炭酸亜鉛、塩基性炭酸銅等の金属炭酸塩又は塩基性金属炭酸塩；酸性白土、カオリン、タルク、ベントナイト、ケイソウ土、ヒドロタルサイト等の金属酸化物又は水酸化物の複合化合物；ケイ酸ナトリウム、マイカモリブデン酸塩、モリブデン酸コバルト、モリブデン酸アンモニウム等の金属酸塩、二硫化モリブデン、ステアリン酸カルシウム、窒化ケイ素、炭化ケイ素から選ばれる少なくとも１種が挙げられる。 Additives include metal oxides such as copper oxide, iron oxide, zinc oxide, cobalt oxide, manganese oxide, molybdenum oxide, nickel oxide, bismuth oxide, silica, and alumina; cobalt carbonate, calcium carbonate, basic zinc carbonate, base Metal carbonates such as basic copper carbonate or basic metal carbonates; complex compounds of metal oxides or hydroxides such as acid clay, kaolin, talc, bentonite, diatomaceous earth, hydrotalcite; sodium silicate, mycamolybdic acid Examples thereof include at least one selected from salts, metal acid salts such as cobalt molybdate and ammonium molybdate, molybdenum disulfide, calcium stearate, silicon nitride, and silicon carbide.
本発明で用いる（ｆ）成分の二酸化ケイ素は、必要に応じて（ａ）〜（ｃ）成分、又は（ａ）〜（ｃ）成分と（ｄ）成分及び／又は（ｅ）成分と共に用いられる成分であり、（ａ）成分の着火性を改良する目的で配合される成分である。（ａ）成分の着火性の改良効果は、特に（ａ）成分としてグアニジン類化合物を用いたときに高くなる。 The silicon dioxide of the component (f) used in the present invention is used together with the components (a) to (c), or the components (a) to (c) and the component (d) and / or the component (e) as necessary. It is a component that is blended for the purpose of improving the ignitability of the component (a). The effect of improving the ignitability of the component (a) is particularly high when a guanidine compound is used as the component (a).
（ｆ）成分の二酸化ケイ素は、比表面積が好ましくは１００〜５００ｍ２／ｇ、より好ましくは１５０〜３００ｍ２／ｇである。比表面積はＢＥＴ法により測定されるものである。 Component (f) of the silicon dioxide has a specific surface area of preferably 100 to 500 m 2 / g, more preferably 150 to 300 m 2 / g. The specific surface area is measured by the BET method.
本発明のガス発生剤組成物に含まれる各成分の含有割合及び配合例は、下記のとおりである。 The contents of each component contained in the gas generant composition of the present invention and the formulation examples are as follows.
（１）（ａ）〜（ｃ）成分の組成物
（ａ）成分の有機化合物の含有量は、好ましくは１０〜６０質量％、より好ましくは１５〜６０質量％、更に好ましくは１０〜５５質量％；
（ｂ−１）成分の酸化剤の含有量は、好ましくは１０〜８５質量％、より好ましくは２０〜７０質量％、更に好ましくは３０〜６０質量％；
（ｂ−２）成分の酸化剤の含有量は、好ましくは０．５〜２０質量％、より好ましくは１〜１０質量％、更に好ましくは１〜５質量％；
（ｃ）成分の水酸化マグネシウム（又は水酸化マグネシウムと水酸化アルミニウムの混合物）の含有量は、０．１〜２０質量％、好ましくは３〜１５質量％、より好ましくは４〜１０質量％。
(1) Composition of components (a) to (c) The content of the organic compound (a) is preferably 10 to 60% by mass, more preferably 15 to 60% by mass, and still more preferably 10 to 55% by mass. %;
(B-1) Content of the oxidizing agent of a component becomes like this. Preferably it is 10-85 mass%, More preferably, it is 20-70 mass%, More preferably, it is 30-60 mass%;
(B-2) Content of the oxidizing agent of a component becomes like this. Preferably it is 0.5-20 mass%, More preferably, it is 1-10 mass%, More preferably, it is 1-5 mass%;
The content of component (c) magnesium hydroxide (or a mixture of magnesium hydroxide and aluminum hydroxide) is 0.1 to 20% by mass, preferably 3 to 15% by mass, more preferably 4 to 10% by mass.
（配合例１）
（ａ）硝酸グアニジン ３０〜６０質量％
（ｂ）塩基性硝酸銅 ３０〜６０質量％
（ｃ）水酸化マグネシウム ３〜１０質量％
（配合例２）
（ａ）ニトログアニジン ２５〜６０質量％
（ｂ）塩基性硝酸銅 ３０〜６０質量％
（ｃ）水酸化マグネシウム ３〜１５質量％。
(Formulation example 1)
(A) Guanidine nitrate 30-60% by mass
(B) Basic copper nitrate 30-60 mass%
(C) Magnesium hydroxide 3 to 10% by mass
(Formulation example 2)
(A) Nitroguanidine 25-60% by mass
(B) Basic copper nitrate 30-60 mass%
(C) Magnesium hydroxide 3-15% by mass.
（配合例３）
（ａ）硝酸グアニジン又はメラミン １５〜５０質量％
（ｂ−１）塩基性硝酸銅 ３０〜７０質量％
（ｂ−２）過塩素酸ナトリウム、過塩素酸カリウム及び過塩素酸アンモニウムから選ばれる少なくとも１種の過塩素酸塩 ０．５〜５質量％
（ｃ）水酸化マグネシウム ０．５〜１０質量％。
(Formulation example 3)
(A) Guanidine nitrate or melamine 15-50% by mass
(B-1) Basic copper nitrate 30-70 mass%
(B-2) At least one perchlorate selected from sodium perchlorate, potassium perchlorate and ammonium perchlorate 0.5 to 5% by mass
(C) Magnesium hydroxide 0.5-10 mass%.
（配合例４）
（ａ）硝酸グアニジン又はメラミン １５〜５０質量％
（ｂ−１）塩基性硝酸銅 ３０〜７０質量％
（ｂ−２）塩素酸ナトリウム又は塩素酸カリウム ０．５〜５質量％
（ｃ）水酸化マグネシウム ０．５〜１０質量％。
(Formulation example 4)
(A) Guanidine nitrate or melamine 15-50% by mass
(B-1) Basic copper nitrate 30-70 mass%
(B-2) Sodium chlorate or potassium chlorate 0.5-5 mass%
(C) Magnesium hydroxide 0.5-10 mass%.
（３）（ａ）〜（ｃ）成分に対して、（ｄ）成分、（ｅ）成分及び（ｆ）成分から選ばれる１、２又は３を含む組成物
（ｄ）成分の含有量は、好ましくは２０質量％以下、より好ましくは０．５〜１０質量％、更に好ましくは１〜７質量％；
（ｅ）成分の含有量は、好ましくは２０質量％以下、より好ましくは１〜１５質量％、更に好ましくは３〜１０質量％。
(3) A composition comprising 1, 2 or 3 selected from the component (d), the component (e) and the component (f) with respect to the components (a) to (c). Preferably it is 20 mass% or less, More preferably, it is 0.5-10 mass%, More preferably, it is 1-7 mass%;
(E) Content of a component becomes like this. Preferably it is 20 mass% or less, More preferably, it is 1-15 mass%, More preferably, it is 3-10 mass%.
（配合例５）
（ａ）ニトログアニジン ２０〜５０質量％
（ｂ）硝酸ストロンチウム ３０〜６０質量％
（ｃ）水酸化マグネシウム ０．５〜１５質量％
（ｄ）カルボキシメチルセルロースナトリウム塩又はグアガム ０．５〜１０質量％。
(Formulation example 5)
(A) Nitroguanidine 20-50 mass%
(B) Strontium nitrate 30-60% by mass
(C) Magnesium hydroxide 0.5-15% by mass
(D) Carboxymethylcellulose sodium salt or guar gum 0.5 to 10% by mass.
（配合例６）
（ａ）ニトログアニジン ３０〜５０質量％
（ｂ）塩基性硝酸銅 ３０〜６０質量％
（ｃ）水酸化マグネシウム ０．５〜１０質量％
（ｄ）グアガム ０．５〜１０質量％。
(Formulation example 6)
(A) Nitroguanidine 30-50% by mass
(B) Basic copper nitrate 30-60 mass%
(C) Magnesium hydroxide 0.5-10 mass%
(D) Guam gum 0.5-10 mass%.
（配合例７）
（ａ）メラミン １５〜４０質量％
（ｂ）塩基性硝酸銅 ３０〜７０質量％
（ｃ）水酸化マグネシウム ０．５〜１５質量％
（ｄ）カルボキシメチルセルロースナトリウム塩又はグアガム ０．５〜１０質量％。
(Formulation example 7)
(A) Melamine 15-40% by mass
(B) Basic copper nitrate 30-70 mass%
(C) Magnesium hydroxide 0.5-15% by mass
(D) Carboxymethylcellulose sodium salt or guar gum 0.5 to 10% by mass.
（配合例８）
（ａ）硝酸グアニジン ３０〜５０質量％
（ｂ）塩基性硝酸銅 ３０〜６０質量％
（ｃ）水酸化マグネシウム ０．５〜１５質量％
（ｄ）カルボキシメチルセルロースナトリウム塩又はグアガム ０．５〜１０質量％。
(Formulation example 8)
(A) Guanidine nitrate 30-50% by mass
(B) Basic copper nitrate 30-60 mass%
(C) Magnesium hydroxide 0.5-15% by mass
(D) Carboxymethylcellulose sodium salt or guar gum 0.5 to 10% by mass.
（配合例９）
（ａ）硝酸グアニジン、ニトログアニジン、メラミンから選択される２成分、又は３成分の混合燃料 １５〜５０質量％
（ｂ）塩基性硝酸銅 ３０〜６０質量％
（ｃ）水酸化マグネシウム ０．５〜１５質量％
（ｄ）カルボキシメチルセルロースナトリウム塩又はグアガム ０．５〜１０質量％。
(Formulation example 9)
(A) Two-component or three-component mixed fuel selected from guanidine nitrate, nitroguanidine, and melamine 15 to 50% by mass
(B) Basic copper nitrate 30-60 mass%
(C) Magnesium hydroxide 0.5-15% by mass
(D) Carboxymethylcellulose sodium salt or guar gum 0.5 to 10% by mass.
（配合例10）
（ａ）硝酸グアニジン又はメラミン １５〜５０質量％
（ｂ−１）塩基性硝酸銅 ３０〜６０質量％
（ｂ−２）過塩素酸ナトリウム、過塩素酸カリウム及び過塩素酸アンモニウムから選ばれる少なくとも１種の過塩素酸塩 ０．５〜５質量％
（ｃ）水酸化マグネシウム ０．５〜１５質量％
（ｄ）カルボキシメチルセルロースナトリウム塩又はグアガム ０．５〜１０質量％。
(Formulation example 10)
(A) Guanidine nitrate or melamine 15-50% by mass
(B-1) Basic copper nitrate 30-60 mass%
(B-2) At least one perchlorate selected from sodium perchlorate, potassium perchlorate and ammonium perchlorate 0.5 to 5% by mass
(C) Magnesium hydroxide 0.5-15% by mass
(D) Carboxymethylcellulose sodium salt or guar gum 0.5 to 10% by mass.
（配合例11）
（ａ）硝酸グアニジン又はメラミン １５〜５０質量％
（ｂ−１）塩基性硝酸銅 ３０〜６０質量％
（ｂ−２）塩素酸ナトリウム又は過塩素酸カリウム ０．５〜５質量％
（ｃ）水酸化マグネシウム ０．５〜１５質量％
（ｄ）カルボキシメチルセルロースナトリウム塩又はグアガム ０．５〜１０質量％。
(Formulation example 11)
(A) Guanidine nitrate or melamine 15-50% by mass
(B-1) Basic copper nitrate 30-60 mass%
(B-2) Sodium chlorate or potassium perchlorate 0.5-5 mass%
(C) Magnesium hydroxide 0.5-15% by mass
(D) Carboxymethylcellulose sodium salt or guar gum 0.5 to 10% by mass.
（配合例12）
（ａ）硝酸グアニジン ３０〜５０質量％
（ｂ）塩基性硝酸銅 ３０〜６０質量％
（ｃ）水酸化マグネシウム ０．５〜１５質量％
（ｆ）二酸化ケイ素 ０．１〜５質量％
（配合例13）
（ａ）硝酸グアニジン ３０〜５０質量％
（ｂ）塩基性硝酸銅 ３０〜６０質量％
（ｃ）水酸化マグネシウム ０．５〜１５質量％
（ｄ）カルボキシメチルセルロースナトリウム塩又はグアガム ０．５〜１０質量％
（ｆ）二酸化ケイ素 ０．１〜５質量％
本発明のガス発生剤組成物は、所望の形状に成型することができ、単孔円柱状、多孔円柱状又はペレット状の成型体にすることができる。
(Formulation example 12)
(A) Guanidine nitrate 30-50% by mass
(B) Basic copper nitrate 30-60 mass%
(C) Magnesium hydroxide 0.5-15% by mass
(F) Silicon dioxide 0.1-5 mass%
(Formulation example 13)
(A) Guanidine nitrate 30-50% by mass
(B) Basic copper nitrate 30-60 mass%
(C) Magnesium hydroxide 0.5-15% by mass
(D) Carboxymethylcellulose sodium salt or guar gum 0.5 to 10% by mass
(F) Silicon dioxide 0.1-5 mass%
The gas generant composition of the present invention can be molded into a desired shape, and can be formed into a single-hole cylindrical, porous cylindrical, or pellet-shaped molded body.
これらの成型体は、ガス発生剤組成物に水又は有機溶媒を添加混合し、押出成型する方法（単孔円柱状、多孔円柱状の成型体）又は打錠機等を用いて圧縮成型する方法（ペレット状の成型体）により製造することができる。単孔円柱状、多孔円柱状のものは、孔が長さ方向に貫通しているもの、孔が貫通せずに窪みを形成しているもののいずれでもよい。 These molded products are prepared by adding water or an organic solvent to the gas generating composition, mixing and extruding (single-hole cylindrical or porous cylindrical molded body) or compression molding using a tableting machine or the like. It can be manufactured by (pellet-shaped molded body). The single-hole columnar shape and the porous columnar shape may be either those in which the hole penetrates in the length direction or those in which the hole does not penetrate and forms a recess.
本発明のガス発生剤組成物又はそれから得られる成型体は、例えば、各種乗り物の運転席のエアバック用インフレータ、助手席のエアバック用インフレータ、サイドエアバック用インフレータ、インフレータブルカーテン用インフレータ、ニーボルスター用インフレータ、インフレータブルシートベルト用インフレータ、チューブラーシステム用インフレータ、プリテンショナー用ガス発生器に適用できる。 Examples of the gas generant composition of the present invention or a molded product obtained therefrom include, for example, an inflator for an air bag in a driver seat of various vehicles, an inflator for an air bag in a passenger seat, an inflator for a side air bag, an inflator for an inflatable curtain, and a knee bolster It can be applied to inflators for inflatable seat belts, inflators for inflatable seat belts, inflators for tubular systems, and gas generators for pretensioners.
また本発明のガス発生剤組成物又はそれから得られる成型体を使用するインフレータは、ガスの供給が、ガス発生剤からだけのパイロタイプと、アルゴン等の圧縮ガスとガス発生剤の両方であるハイブリッドタイプのいずれでもよい。 The inflator using the gas generant composition of the present invention or a molded product obtained therefrom is a hybrid in which the gas supply is a pyrotype only from the gas generant, and a compressed gas such as argon and the gas generant. Any type.
更に本発明のガス発生剤組成物又はそれから得られる成型体は、***やスクイブのエネルギーをガス発生剤に伝えるためのエンハンサ剤（又はブースター）等と呼ばれる着火剤として用いることもできる。 Furthermore, the gas generant composition of the present invention or a molded product obtained therefrom can be used as an igniting agent called an enhancer (or booster) for transmitting the energy of the detonator or squib to the gas generant.
以下に、実施例に基づいて本発明をより詳細に説明するが、本発明はこれらの実施例によって限定されるものではない。 Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited to these examples.
実施例１、比較例１
表１に示す各成分の合計５０００ｇと水７３７ｇを混合機に仕込んで混合した。この混合物を押出機で押し出し、裁断、乾燥を経て、外径4.25ｍｍ、内径1.10ｍｍ、長さ4.08ｍｍの単孔薬形状のガス発生剤組成物を得た。このガス発生剤組成物40.3ｇを、内径57ｍｍ、高さ32ｍｍのチャンバーに入れて密閉し、試験用のインフレータを作った。
Example 1 and Comparative Example 1
A total of 5000 g of each component shown in Table 1 and 737 g of water were charged into a mixer and mixed. This mixture was extruded with an extruder, cut, and dried to obtain a gas generating composition in the form of a single-hole medicine having an outer diameter of 4.25 mm, an inner diameter of 1.10 mm, and a length of 4.08 mm. 40.3 g of this gas generant composition was placed in a chamber having an inner diameter of 57 mm and a height of 32 mm and sealed to prepare a test inflator.
この試験用のインフレータを用い、２８００Ｌタンクの排ガス試験を実施した。２８００Ｌタンク試験は、試験用のインフレータを内容積２８００Ｌの鉄製のタンクにセットし、インフレータを点火してから、３分、１５分、３０分経過した時点におけるタンク内のＮＯ、ＮＯ２、ＣＯ、ＮＨ３濃度を検知管により測定し、３分、１５分、３０分経過時のガス濃度の平均値を各ガスの濃度とした。結果を表１に示す。 Using this test inflator, an exhaust gas test of a 2800 L tank was conducted. In the 2800L tank test, the test inflator was set in an iron tank having an internal volume of 2800L, and after the inflator was ignited, NO, NO 2 , CO, The NH 3 concentration was measured with a detector tube, and the average value of the gas concentration at the lapse of 3 minutes, 15 minutes, and 30 minutes was taken as the concentration of each gas. The results are shown in Table 1.
ＧＮは硝酸グアニジン、ＢＣＮは塩基性硝酸銅、ＣＭＣＮａはカルボキメチルセルロースナトリウム塩である。塩基性硝酸銅の平均粒径は４．７μｍ、水酸化マグネシウムの平均粒径は４．１μｍである。
GN is guanidine nitrate, BCN is basic copper nitrate, and CMCNa is carboxymethylcellulose sodium salt. The average particle diameter of basic copper nitrate is 4.7 μm, and the average particle diameter of magnesium hydroxide is 4.1 μm.
Claims (6)
（ａ）燃料としての硝酸グアニジン
（ｂ）含酸素酸化剤としての塩基性硝酸銅
（ｃ）水酸化マグネシウム、又は水酸化マグネシウム及び水酸化アルミニウムの混合物
（ｄ）バインダ
（ｅ）金属酸化物、金属炭酸化物から選ばれる添加剤
（ｆ）比表面積が１００〜５００ｍ2／ｇである二酸化ケイ素 Following component (a), (b) component and (c) contains the component, further in component (d), the gas generating composition containing one, two or three selected from the component (e) and (f) component .
(A) Guanidine nitrate as fuel (b) Basic copper nitrate as oxygen-containing oxidant (c) Magnesium hydroxide or a mixture of magnesium hydroxide and aluminum hydroxide (d) Binder (e) Metal oxide, metal Additives selected from carbonates (f) Silicon dioxide having a specific surface area of 100 to 500 m 2 / g
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| US7833365B2 (en) | 2006-01-26 | 2010-11-16 | Daicel Chemical Industries, Ltd. | Rare earth compound containing gas generating composition |
| US7887650B2 (en) | 2006-03-02 | 2011-02-15 | Daicel Chemical Industries, Ltd. | Gas generating composition |
| JP5277428B2 (en) * | 2006-05-02 | 2013-08-28 | 日本化薬株式会社 | Gas actuator composition for gas actuator for operating safety parts and gas generator for gas actuator using the same |
| EP2070870A1 (en) * | 2007-12-14 | 2009-06-17 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO | Formulation for generating nitrogen gas |
| FR2949778B1 (en) * | 2009-09-10 | 2013-05-10 | Snpe Materiaux Energetiques | PYROTECHNIC COMPOUNDS GENERATORS OF GAS |
| FR2975097B1 (en) * | 2011-05-09 | 2015-11-20 | Sme | PYROTECHNIC COMPOUNDS GENERATORS OF GAS |
| JP2016525992A (en) * | 2013-04-25 | 2016-09-01 | フィッシャーヴェルケ ゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー コマンディートゲゼルシャフトｆｉｓｃｈｅｒｗｅｒｋｅ ＧｍｂＨ ＆ Ｃｏ． ＫＧ | Electrically ignitable caseless propellant, its manufacturing method and use |
| JP6562659B2 (en) * | 2015-03-04 | 2019-08-21 | 日本化薬株式会社 | Gas generant composition |
| CN116323521A (en) * | 2020-10-01 | 2023-06-23 | 株式会社大赛璐 | Gas generating agent composition |
| KR20230115291A (en) * | 2020-10-01 | 2023-08-02 | 주식회사 다이셀 | gas generant composition |
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|---|---|---|---|---|
| JPH04265292A (en) * | 1990-10-25 | 1992-09-21 | Automot Syst Lab Inc | Azide-free gas generating composition |
| JPH05117070A (en) * | 1991-04-15 | 1993-05-14 | Automot Syst Lab Inc | Gas forming composition |
| JPH09124389A (en) * | 1995-10-30 | 1997-05-13 | Nippon Oil & Fats Co Ltd | Gas generating agent composition |
| JP2002047379A (en) * | 2000-08-03 | 2002-02-12 | Nippon Zeon Co Ltd | Compounding material for rubber, rubber composition, and crosslinked rubber |
| JP2003529515A (en) * | 1999-09-16 | 2003-10-07 | オートモーティブ システムズ ラボラトリー インコーポレーテッド | Gas generating agent containing silicone fuel |
| JP2005145718A (en) * | 2002-10-31 | 2005-06-09 | Daicel Chem Ind Ltd | Gas generating agent composition |
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Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04265292A (en) * | 1990-10-25 | 1992-09-21 | Automot Syst Lab Inc | Azide-free gas generating composition |
| JPH05117070A (en) * | 1991-04-15 | 1993-05-14 | Automot Syst Lab Inc | Gas forming composition |
| JPH09124389A (en) * | 1995-10-30 | 1997-05-13 | Nippon Oil & Fats Co Ltd | Gas generating agent composition |
| JP2003529515A (en) * | 1999-09-16 | 2003-10-07 | オートモーティブ システムズ ラボラトリー インコーポレーテッド | Gas generating agent containing silicone fuel |
| JP2002047379A (en) * | 2000-08-03 | 2002-02-12 | Nippon Zeon Co Ltd | Compounding material for rubber, rubber composition, and crosslinked rubber |
| JP2005145718A (en) * | 2002-10-31 | 2005-06-09 | Daicel Chem Ind Ltd | Gas generating agent composition |
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