JP4669714B2 - Antibacterial treatment method for porous member and antibacterial filter - Google Patents
Antibacterial treatment method for porous member and antibacterial filter Download PDFInfo
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- JP4669714B2 JP4669714B2 JP2005042856A JP2005042856A JP4669714B2 JP 4669714 B2 JP4669714 B2 JP 4669714B2 JP 2005042856 A JP2005042856 A JP 2005042856A JP 2005042856 A JP2005042856 A JP 2005042856A JP 4669714 B2 JP4669714 B2 JP 4669714B2
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- 230000000844 anti-bacterial effect Effects 0.000 title claims description 45
- 238000000034 method Methods 0.000 title claims description 18
- 238000006116 polymerization reaction Methods 0.000 claims description 24
- 238000007740 vapor deposition Methods 0.000 claims description 24
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 14
- -1 polyethylene Polymers 0.000 claims description 14
- 229920001721 polyimide Polymers 0.000 claims description 14
- 239000000919 ceramic Substances 0.000 claims description 12
- 229920003002 synthetic resin Polymers 0.000 claims description 12
- 239000000057 synthetic resin Substances 0.000 claims description 12
- 239000004642 Polyimide Substances 0.000 claims description 11
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 239000004677 Nylon Substances 0.000 claims description 5
- 229920001778 nylon Polymers 0.000 claims description 5
- 239000003242 anti bacterial agent Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 229920003023 plastic Polymers 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- 239000011148 porous material Substances 0.000 description 5
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 2
- 241000588747 Klebsiella pneumoniae Species 0.000 description 2
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 2
- 206010041925 Staphylococcal infections Diseases 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 208000015688 methicillin-resistant staphylococcus aureus infectious disease Diseases 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- HLBLWEWZXPIGSM-UHFFFAOYSA-N 4-Aminophenyl ether Chemical compound C1=CC(N)=CC=C1OC1=CC=C(N)C=C1 HLBLWEWZXPIGSM-UHFFFAOYSA-N 0.000 description 1
- QGMGHALXLXKCBD-UHFFFAOYSA-N 4-amino-n-(2-aminophenyl)benzamide Chemical compound C1=CC(N)=CC=C1C(=O)NC1=CC=CC=C1N QGMGHALXLXKCBD-UHFFFAOYSA-N 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 229920000426 Microplastic Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241000607720 Serratia Species 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
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Description
本発明は、居住空間や移動空間である車両・航空機などで用いられる空気調和機や空気清浄機等で用いられる抗菌性フィルター及び多孔質部材の抗菌処理方法に関するものである。 The present invention relates to an antibacterial filter used in an air conditioner or an air purifier used in a vehicle or aircraft that is a living space or a moving space, and an antibacterial treatment method for a porous member.
衛生管理の面から、身の回りの物に抗菌性を付与する技術が注目されている。最近では、居住空間や車室内の空気調和機、空気清浄機や掃除機等の空気が内部を通過する機器についても、抗菌性が求められつつある。 From the aspect of hygiene management, a technology that gives antibacterial properties to objects around us has been attracting attention. Recently, antibacterial properties are also being demanded for devices through which air passes, such as air conditioners in living spaces and vehicle interiors, air purifiers and vacuum cleaners.
上記列挙した機器は、一般的に内部にフィルターを備え、空気とともに取り込んだ塵埃や菌を少なからず捕獲する構造を有している。捕獲した塵埃は、菌が増殖の温床となるが、フィルターの初期、或いは、定期メンテナンス後初期における抗菌性の度合いに、菌増殖の程度が大きく影響を受ける。
このようなフィルターは、耐久性を考慮して、プラスチックや金属、セラミックス等が材料とされる場合が多い。
The above-listed devices generally include a filter inside, and have a structure for capturing a considerable amount of dust and bacteria taken together with air. The trapped dust becomes a hotbed for growth of bacteria, but the degree of bacterial growth is greatly affected by the degree of antibacterial properties at the initial stage of the filter or at the initial stage after regular maintenance.
Such a filter is often made of plastic, metal, ceramics or the like in consideration of durability.
プラスチックからフィルターを製造して抗菌性を付与する方法としては、ポリエチレン、ポリスチレン、塩化ビニル、ポリプロピレン等のプラスチックを加熱溶融し、５〜３０％の濃度で抗菌剤を含有したプラスチックペレットであるマスターバッチを添加することにより、抗菌剤を練り込む方法が一般に行われている。尚、この方法の場合、最終製品への抗菌剤の添加量は０．３〜２％程度となる。前記プラスチックには、その種類や加工方法により若干の差があるものの通常は２５０〜３００℃以上の耐熱性が要求され、また、抗菌剤には、この温度において、抗菌剤成分の揮発、分解、含有水分の放出等による抗菌剤の重量変化、抗菌効果の低下や変色等を生じないことが必要とされるため、プラスチックや抗菌剤の材料の選定に制限が生じるという問題があった。 As a method for producing antibacterial properties by producing a filter from plastic, a masterbatch that is a plastic pellet containing an antibacterial agent at a concentration of 5 to 30% by heating and melting a plastic such as polyethylene, polystyrene, vinyl chloride, or polypropylene. In general, a method of kneading an antibacterial agent by adding the above is generally performed. In this method, the amount of antibacterial agent added to the final product is about 0.3 to 2%. The plastics are required to have a heat resistance of 250 to 300 ° C. or more, although there are some differences depending on the type and processing method. In addition, antibacterial agents volatilize, decompose, decompose, There is a problem that the selection of the material of the plastic or the antibacterial agent is limited because it is necessary to prevent the weight change of the antibacterial agent due to the release of the contained moisture, the decrease in the antibacterial effect, and the discoloration.
一方、金属やセラミックスへ抗菌性を付与する方法としては、予め成形した部材表面に貼着剤により抗菌剤を塗布したプラスチックフィルムを貼着する方法が一般に行われている（例えば、特許文献１参照）。
しかしながら、部材の形状が複雑である場合には、部材表面の全面に抗菌性を付与することは困難であるという問題があった（特許文献２参照）。
On the other hand, as a method for imparting antibacterial properties to metals and ceramics, a method of sticking a plastic film in which an antibacterial agent is applied to a previously molded member surface with an adhesive is generally performed (see, for example, Patent Document 1). ).
However, when the shape of the member is complicated, there is a problem that it is difficult to impart antibacterial properties to the entire surface of the member (see Patent Document 2).
本発明は、前記従来技術の問題点を解消し、抗菌性を付与する対象となる部材表面全面に、いわゆる抗菌剤を用いることなく抗菌性を付与することを目的とする。 An object of the present invention is to solve the problems of the prior art and to impart antibacterial properties to the entire surface of a member to be imparted with antibacterial properties without using a so-called antibacterial agent.
本発明者等は前記課題を解決するべく鋭意検討の結果、次の通り解決手段を見いだした。
即ち、本発明の多孔質部材の抗菌処理方法は、請求項１に記載の通り、多孔質部材の表面に蒸着重合法によりナイロン、ポリエチレン、ポリエチレンテレフタレート及びポリイミドの内の何れかの合成樹脂被膜を形成後、抗菌性を得るためにオゾン処理することにより前記多孔質部材に抗菌性を付与することを特徴とする。
また、請求項２に記載の本発明は、請求項１に記載の多孔質部材の抗菌処理方法において、前記多孔質部材がセラミックスであることを特徴とする。
また、本発明の抗菌性フィルターは、請求項３に記載の通り、多孔質部材の表面に蒸着重合法によりナイロン、ポリエチレン、ポリエチレンテレフタレート及びポリイミドの内の何れかの合成樹脂被膜を形成後、抗菌性を得るためにオゾン処理することにより、前記多孔質部材に抗菌性が付与されたことを特徴とする。
また、請求項４に記載の本発明は、請求項３に記載の抗菌性フィルターにおいて、前記部材がセラミックスであることを特徴とする。
As a result of intensive studies to solve the above problems, the present inventors have found a solution means as follows.
That is, according to the antibacterial treatment method for a porous member of the present invention, the synthetic resin coating of any one of nylon, polyethylene, polyethylene terephthalate and polyimide is formed on the surface of the porous member by vapor deposition polymerization as described in claim 1. After formation, the porous member is imparted with antibacterial properties by ozone treatment to obtain antibacterial properties.
The present invention according to
In addition, the antibacterial filter of the present invention is the antibacterial filter after forming a synthetic resin film of nylon, polyethylene, polyethylene terephthalate and polyimide on the surface of the porous member by vapor deposition polymerization method as described in claim 3. Antibacterial properties are imparted to the porous member by performing ozone treatment in order to obtain properties.
According to a fourth aspect of the present invention, in the antibacterial filter according to the third aspect, the member is a ceramic.
本発明の方法によれば、蒸着重合法により合成樹脂被膜を形成して抗菌性を付与するため、多孔質部材を構成する材料について制限されることなく、しかも、短時間で多孔質部材の孔表面に均一に抗菌性を付与することができる。また、多孔質部材として、セラミックスを選定した場合には、セラミックス粒子の欠落を防止することができる。
また、本発明のフィルターによれば、多孔質部材の孔表面に均一に抗菌性が付与されているため、抗菌性がフィルターの一部のみが低下するということがない。
According to the method of the present invention, since a synthetic resin film is formed by vapor deposition polymerization to impart antibacterial properties, the material constituting the porous member is not limited, and the pores of the porous member can be formed in a short time. Antibacterial properties can be imparted uniformly to the surface. Further, when ceramics is selected as the porous member, it is possible to prevent the ceramic particles from being lost.
Moreover, according to the filter of the present invention, since the antibacterial property is uniformly imparted to the pore surface of the porous member, the antibacterial property does not decrease only a part of the filter.
本発明の抗菌処理方法は、まず、多孔質部材の表面に蒸着重合法により合成樹脂被膜を形成する。
前記多孔質部材としては、窒化アルミニウム、窒化硅素などのセラミックスや、ガラス、カーボン、金属、プラスチック等を使用することができ、この中でもセラミックスを使用することが好ましい。
また、前記多孔質部材の最小気孔径は３μｍ以上とすることが好ましい。形成されたポリイミド被膜の膜厚が１μｍの場合でも気体流路が確保されるからである。また、前記多孔質部材の最大気孔径は４ｍｍとすることが好ましい。
また、前記多孔質部材の気孔径は、多孔質部材に形成された流路の構造が、多孔質部材の表面側から裏面側に直線的に貫通するような構造の場合には、５μｍ〜１００μｍとすることが好ましく、多孔質部材の内部において三次元網目構造の場合には、１００μｍ〜２．５ｍｍとすることが好ましい。
また、前記多孔質部材の気孔率は、１０％〜９０％の範囲内で選択することができるが、機械的強度の観点からすると３０％〜８０％の範囲内で選択することが好ましい。
前記合成樹脂被膜は、ナイロン、ポリエチレン、ポリエチレンテレフタレート、ポリイミド等を使用することができる。
前記ポリイミド被膜の蒸着重合法については、原料モノマー、蒸着条件など、従来のポリイミドの蒸着重合と特に変わるところはなく、原料モノマーとして、例えば、無水ピロメリト酸（ＰＭＤＡ）と、４，４'−オキシジアニリン（ＯＤＡ）の組み合わせ、或いは、ＰＭＤＡと３，５’−ジアミノ安息香酸（ＤＢＡ）の組み合わせ等特に限定されるものではない。
前記合成樹脂被膜の厚みは、１μｍ以上とすることが好ましい。１μｍ未満であると、抗菌性能が不足するからである。
In the antibacterial treatment method of the present invention, a synthetic resin film is first formed on the surface of a porous member by vapor deposition polymerization.
As the porous member, ceramics such as aluminum nitride and silicon nitride, glass, carbon, metal, plastic, and the like can be used, and among these, ceramic is preferable.
The minimum pore diameter of the porous member is preferably 3 μm or more. This is because even when the film thickness of the formed polyimide coating is 1 μm, a gas flow path is secured. The maximum pore diameter of the porous member is preferably 4 mm.
The pore diameter of the porous member is 5 μm to 100 μm in the case where the flow path structure formed in the porous member linearly penetrates from the front surface side to the back surface side of the porous member. In the case of a three-dimensional network structure inside the porous member, the thickness is preferably 100 μm to 2.5 mm.
The porosity of the porous member can be selected within a range of 10% to 90%, but is preferably selected within a range of 30% to 80% from the viewpoint of mechanical strength.
For the synthetic resin film, nylon, polyethylene, polyethylene terephthalate, polyimide, or the like can be used.
The polyimide film vapor deposition polymerization method is not particularly different from conventional polyimide vapor deposition polymerization in terms of raw material monomers and vapor deposition conditions. Examples of raw material monomers include pyromellitic anhydride (PMDA) and 4,4′-oxy. There is no particular limitation such as a combination of dianiline (ODA) or a combination of PMDA and 3,5′-diaminobenzoic acid (DBA).
The thickness of the synthetic resin film is preferably 1 μm or more. It is because antibacterial performance is insufficient when it is less than 1 μm.
上記の多孔質部材の表面に形成された合成樹脂被膜は、次にオゾン処理され、抗菌性が得られることになる。
前記オゾン処理に関しては、前記合成樹脂被膜をオゾン雰囲気と接触させることができれば特に温度や時間等の条件については制限はなく、一例として、合成樹脂被膜が形成された多孔質部材を２００〜２５０℃の範囲で加熱して、オゾンに１０分程度接触させるようにすればよい。
The synthetic resin film formed on the surface of the porous member is then treated with ozone to obtain antibacterial properties.
With respect to the ozone treatment, there are no particular restrictions on conditions such as temperature and time as long as the synthetic resin film can be brought into contact with an ozone atmosphere. As an example, the porous member on which the synthetic resin film is formed is 200 to 250 ° C. It is sufficient to heat within a range of 10 to contact with ozone for about 10 minutes.
上記方法により、処理された多孔質部材は、空気調和機や空気清浄機等の機器の通風路に配置することにより、抗菌性を有するフィルターとして機能することになる。 The porous member treated by the above method functions as a filter having antibacterial properties by being disposed in a ventilation path of a device such as an air conditioner or an air purifier.
（実施例１）
次に、本発明の実施例について図面を参照して説明する。
図１は、蒸着重合対象物に対して、ポリイミド被膜を形成するための蒸着重合装置の略断面図である。
蒸着重合装置１には、図示しないガス導入バルブを介してモノマーガスを導入する一対の第１ガス導入口２及び第２ガス導入口３と、図示しない油拡散ポンプに連通する排気バルブを介して排気作動を行うための真空排気口４とが設けられている。また、蒸着重合装置１の内部には、蒸着重合対象物として直方体形状の多孔質部材（セラミックス）５が配置されている。この多孔質部材５は、蒸着重合装置１の天井部１ａから必要な張力に充分耐えうる索条６により懸吊される等して、いずれの面も遮蔽されることなく装置１内に露出されるようになっている。また、蒸着重合装置１は、内部の温度を制御できる温度制御手段７が設置されており、蒸着重合反応に必要な熱を供給できるように構成されている。そして、蒸着重合対象物たる多孔質部材５の表面は、上記した温度制御手段７により加熱された装置１の内壁から輻射熱で全体が均等に加熱される。
このように構成された蒸着重合装置１を用い、その内部に多孔質部材５を配置した状態で、最初に真空排気口４に連なる図示しない排気バルブにより真空排気を作動させて装置１の内部圧力を１０-2Ｐａに減圧し、この圧力状態を保ちながら温度制御手段７により、その内部を２００℃に加熱してこの状態を保持する。そして、予め温度制御手段９により、２０８℃に加熱した容器８内の気体状態のピロメリト酸二無水物（ＰＭＤＡ）を第１ガス導入口２から、また、予め温度制御手段１１により１９０℃に加熱した容器１０内の気体状態の４，４'−ジアミノジフェニルエーテル（ＯＤＡ）を第２ガス導入口３から同時に導入して、この状態で、多孔質部材５の表面で蒸着重合反応を３０分に亘って進行させ、多孔質部材５の表面全体に６μｍの膜厚のポリイミド膜を被覆した。
次に、蒸着重合装置１の温度を上げることにより該ポリイミド膜被覆多孔質部材５を、３００℃まで上昇させて１時間保持した後、温度制御を停止し、真空排気した。自然冷却によりポリイミド膜被覆多孔質部材５の温度が２００〜２５０℃に下がったところで、バルブ１２を介して酸素を流量２０Ｌ／ｍｉｎでオゾン発生器を通して蒸着重合装置１に流入させた。前記酸素は、酸素流入により蒸着重合装置１が大気圧になったところで、図示しないが真空排気系のリークバルブを開放して流出する酸素及びオゾンを、オゾン分解器を介して大気に放出している。この状態で１０分間経過後、オゾンを除去し該ポリイミド膜被覆多孔質部材５を取り出し、大気中に１週間放置した。
Example 1
Next, embodiments of the present invention will be described with reference to the drawings.
FIG. 1 is a schematic cross-sectional view of a vapor deposition polymerization apparatus for forming a polyimide film on a vapor deposition polymerization object.
The vapor deposition polymerization apparatus 1 includes a pair of
Using the vapor deposition polymerization apparatus 1 configured as described above, with the porous member 5 disposed therein, first, the vacuum exhaust is operated by an exhaust valve (not shown) connected to the vacuum exhaust port 4 to thereby operate the internal pressure of the apparatus 1. The pressure is reduced to 10 −2 Pa, and while maintaining this pressure state, the temperature control means 7 heats the inside to 200 ° C. and maintains this state. Then, pyromellitic dianhydride (PMDA) in a gaseous state in the container 8 heated to 208 ° C. by the temperature control means 9 in advance is heated from the
Next, after raising the temperature of the vapor deposition polymerization apparatus 1, the polyimide film-covered porous member 5 was raised to 300 ° C. and held for 1 hour, and then temperature control was stopped and evacuated. When the temperature of the polyimide film-coated porous member 5 was lowered to 200 to 250 ° C. by natural cooling, oxygen was allowed to flow into the vapor deposition polymerization apparatus 1 through the
次に、上記ポリイミド膜被覆多孔質部材５の抗菌性を確かめるために、上記処理が施されていない多孔質部材（セラミックス）を比較例１として、ＪＩＳ Ｚ ２８０１に従った試験方法で抗菌性の試験を行った。 Next, in order to confirm the antibacterial property of the polyimide film-covered porous member 5, a porous member (ceramics) that has not been subjected to the above treatment is set as Comparative Example 1, and the antibacterial property is tested by a test method according to JIS Z 2801. A test was conducted.
（実施例２）
上記実施例１と同様に蒸着重合法により、ポリエチレンテレフタレート被覆被膜が形成された多孔質部材を、加熱炉内で１００℃に加熱し、酸素を流量２０Ｌ／ｍｉｎでオゾン発生器を通し、この状態を２０分間保持し、オゾンを除去し、ポリエチレンテレフタレート被覆被膜が形成された多孔質部材を取り出し、大気中に１週間放置した。
そして、実施例１及び比較例１同様に、ＪＩＳ Ｚ ２８０１に従った試験方法で抗菌性の試験を行った。
上記試験の結果を下記表１に示す。
(Example 2)
The porous member on which the polyethylene terephthalate coating film was formed by vapor deposition polymerization as in Example 1 was heated to 100 ° C. in a heating furnace, and oxygen was passed through an ozone generator at a flow rate of 20 L / min. Was kept for 20 minutes to remove ozone, and the porous member on which the polyethylene terephthalate coating film was formed was taken out and left in the atmosphere for one week.
Then, as in Example 1 and Comparative Example 1, antibacterial properties were tested by a test method according to JIS Z 2801.
The results of the above test are shown in Table 1 below.
表１から、実施例１及び２の処理がされた多孔質部材は、黄色ブドウ球菌、大腸菌、肺炎かん菌、緑膿菌、Ｏ−１５７、枯草菌、セラチア及びＭＲＳＡのいずれに対しても、抗菌性に優れることがわかった。これらの菌の中でも、黄色ブドウ球菌、大腸菌、肺炎かん菌、緑膿菌、Ｏ−１５７及びＭＲＳＡに対しては、抗菌活性値が４以上であり、これらの菌に対する抗菌性がより優れていることがわかった。 From Table 1, the porous member treated in Examples 1 and 2 is S. aureus, Escherichia coli, Klebsiella pneumoniae, Pseudomonas aeruginosa, O-157, Bacillus subtilis, Serratia and MRSA. It was found to be excellent in antibacterial properties. Among these bacteria, the antibacterial activity value is 4 or more against S. aureus, Escherichia coli, Klebsiella pneumoniae, Pseudomonas aeruginosa, O-157 and MRSA, and the antibacterial properties against these bacteria are more excellent. I understood it.
本発明の抗菌処理方法は、居住空間や自動車に使用される合成樹脂部材等に広く利用することができ、また、本発明の抗菌性フィルターは、空気調和機、空気清浄機や掃除機等の空気が内部を通過する機器に広く利用することができる。 The antibacterial treatment method of the present invention can be widely used for synthetic resin members used in living spaces and automobiles, and the antibacterial filter of the present invention is used in air conditioners, air purifiers, vacuum cleaners, etc. It can be widely used for devices through which air passes.
１ 蒸着重合装置
２，３ ガス導入口
４ 真空排気口
５ 多孔質部材
６ 索条
７ 温度制御手段
８ 容器
９ 温度制御手段
１０ 容器
１１ 温度制御手段
DESCRIPTION OF SYMBOLS 1
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0827303A (en) * | 1994-07-19 | 1996-01-30 | Idemitsu Kosan Co Ltd | Porous material and production thereof |
| JP2002292768A (en) * | 2001-03-29 | 2002-10-09 | Kurashiki Seni Kako Kk | Honeycomb structure |
| JP2004115777A (en) * | 2002-09-06 | 2004-04-15 | Ulvac Japan Ltd | Antibacterial polymer and its production method, antibacterial polymer coating film and its making method, and article having the coating film on its surface |
| JP2004350935A (en) * | 2003-05-29 | 2004-12-16 | Jigyo Sozo Kenkyusho:Kk | Filter |
| JP2005213310A (en) * | 2004-01-28 | 2005-08-11 | Ulvac Japan Ltd | Method for hydrophilizing surface of polyimide membrane |
| JP2007528451A (en) * | 2004-02-02 | 2007-10-11 | ナノシス・インク． | Porous substrates, articles, systems and compositions containing nanofibers and methods for their use and production |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0827303A (en) * | 1994-07-19 | 1996-01-30 | Idemitsu Kosan Co Ltd | Porous material and production thereof |
| JP2002292768A (en) * | 2001-03-29 | 2002-10-09 | Kurashiki Seni Kako Kk | Honeycomb structure |
| JP2004115777A (en) * | 2002-09-06 | 2004-04-15 | Ulvac Japan Ltd | Antibacterial polymer and its production method, antibacterial polymer coating film and its making method, and article having the coating film on its surface |
| JP2004350935A (en) * | 2003-05-29 | 2004-12-16 | Jigyo Sozo Kenkyusho:Kk | Filter |
| JP2005213310A (en) * | 2004-01-28 | 2005-08-11 | Ulvac Japan Ltd | Method for hydrophilizing surface of polyimide membrane |
| JP2007528451A (en) * | 2004-02-02 | 2007-10-11 | ナノシス・インク． | Porous substrates, articles, systems and compositions containing nanofibers and methods for their use and production |
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