JP4508654B2 - 高シリカシャバサイト、その合成及びオキシジェネート類のオレフィン類への変換におけるその使用 - Google Patents
高シリカシャバサイト、その合成及びオキシジェネート類のオレフィン類への変換におけるその使用 Download PDFInfo
- Publication number
- JP4508654B2 JP4508654B2 JP2003576342A JP2003576342A JP4508654B2 JP 4508654 B2 JP4508654 B2 JP 4508654B2 JP 2003576342 A JP2003576342 A JP 2003576342A JP 2003576342 A JP2003576342 A JP 2003576342A JP 4508654 B2 JP4508654 B2 JP 4508654B2
- Authority
- JP
- Japan
- Prior art keywords
- shabasite
- catalyst
- sub
- crystalline material
- conversion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Description
(式中、Xは、アルミニウム、硼素、鉄、インジウム及び/又はガリウムのような3価元素であり、Yは、珪素、錫、チタン及び/又はゲルマニウムのような4価元素であり、nは100より大きく、典型的には200より大きく、例えば300乃至4,000であり、400乃至1,200のような範囲である)
のモル関係を含む組成を有する多孔質結晶質物質にある。
(式中、Xは、アルミニウム、硼素、鉄、インジウム及び/又はガリウムのような3価元素であり、Yは、珪素、錫、チタン及び/又はゲルマニウムのような4価元素であり、nは100より大きい)のモル関係を含む組成を有する多孔質結晶質物質を含有する触媒と接触させる段階を含む、オレフィンを生成する方法にある。
(式中、Xは、アルミニウム、硼素、鉄、インジウム及び/又はガリウムのような3価元素であり、Yは、珪素、錫、チタン及び/又はゲルマニウムのような4価元素であり、nは100より大きく、典型的には200より大きく、例えば300乃至4,000であり、400乃至1,200のような範囲である)
のモル関係を含む組成を有する
X2O3:(n)YO2:(m)R:(x)F:zH2O、
(式中、X、Y及びnは先のパラグラフで定義した通りであり、mは15乃至350の範囲であり、30乃至50のような範囲であり、zは0乃至10の範囲であり、xは7乃至175の範囲であり、15乃至25のような範囲である)
のモル関係を含む組成を有する。
風袋を計ったプラスチックビーカー中で、37.5gの0.823MのROH(RはN,N,N−トリアルキル−1−アダマンタアンモニウム)溶液と0.094gのAl(NO3)
3・9H2Oの混合物を13.0gのTEOS(テトラエチルオルトシリケート)とともに、生成されたゲルの重量が12.7gに低減されるまで3日間攪拌することにより、アルミノ珪酸塩反応混合物を調製した。次にそのゲルを乳鉢と乳棒で粉末に擦り潰し、125ml容のテフロンで裏打ちされたオートクレーブに入れた。次に、1.6gの49%のHF水溶液を入れて攪拌した。得られた混合物は、下記のモル組成:
0.6HF:0.5ROH:0.002Al2O3:SiO2:3.7H2O
を有した。
Claims (3)
- ジャバサイトの骨組種を有し、X2O3:(n)YO2、
(式中、Xは3価元素であり、Yは4価元素であり、nは100より大きい)のモル関係を含む組成を有する多孔質結晶質物質。 - (a) 水、3価元素Xの酸化物、4価元素Yの酸化物、弗化物イオン及び指示剤(R)、の供給原を含有し、多孔質結晶質物質を生成することができる混合物を調製する工程であり、Rが、N−アルキル−3−キヌクリジノール、N,N,N−トリアルキル−1−アダマンタアンモニウムカチオン類及びN,N,N−トリアルキル−エキソアミノノルボルナンから成る群から選ばれる工程、
(b) 前記物質の結晶が生成されるまで100乃至225℃の温度を含む十分な条件下で前記混合物を維持する工程及び
(c) 工程(b)から前記結晶物質を回収する工程、
を含む、請求項1 に記載の多孔質結晶質物質を合成する方法。 - オキシジェネート変換条件下で、有機オキシジェネート化合物を請求項1 に記載の多孔質結晶質物質を含有する触媒と接触させる工程を含む、オレフィンを生成させる方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36445002P | 2002-03-15 | 2002-03-15 | |
PCT/US2003/005082 WO2003078324A1 (en) | 2002-03-15 | 2003-02-20 | High silica chabazite, its synthesis and its use in the conversion of oxygenates to olefins |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2005520763A JP2005520763A (ja) | 2005-07-14 |
JP2005520763A5 JP2005520763A5 (ja) | 2006-04-06 |
JP4508654B2 true JP4508654B2 (ja) | 2010-07-21 |
Family
ID=28041917
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003576342A Expired - Fee Related JP4508654B2 (ja) | 2002-03-15 | 2003-02-20 | 高シリカシャバサイト、その合成及びオキシジェネート類のオレフィン類への変換におけるその使用 |
Country Status (13)
Country | Link |
---|---|
US (2) | US7148172B2 (ja) |
EP (1) | EP1485323B1 (ja) |
JP (1) | JP4508654B2 (ja) |
CN (1) | CN100418881C (ja) |
AT (1) | ATE350338T1 (ja) |
AU (1) | AU2003222228A1 (ja) |
DE (1) | DE60310898T2 (ja) |
EA (1) | EA007658B1 (ja) |
ES (1) | ES2279105T3 (ja) |
MY (1) | MY131154A (ja) |
TW (1) | TWI315718B (ja) |
WO (1) | WO2003078324A1 (ja) |
ZA (1) | ZA200407139B (ja) |
Families Citing this family (59)
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EP1701913B1 (en) * | 2003-12-23 | 2017-01-25 | ExxonMobil Chemical Patents Inc. | Chabazite-type molecular sieve and its synthesis method |
US7094389B2 (en) * | 2003-12-23 | 2006-08-22 | Exxonmobil Chemical Patents Inc. | Chabazite-containing molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins |
CN1902132B (zh) * | 2003-12-30 | 2010-10-27 | 埃克森美孚研究工程公司 | 高固体含量材料处理 |
AU2005309942B2 (en) * | 2004-11-29 | 2010-11-25 | Chevron U.S.A. Inc. | High-silica molecular sieve CHA |
US20060115398A1 (en) * | 2004-11-29 | 2006-06-01 | Chevron U.S.A. Inc. | Synthesis of amines using high-silica molecular sieve CHA |
US20060115399A1 (en) * | 2004-11-29 | 2006-06-01 | Chevron U.S.A. Inc. | Treatment of engine exhaust using high-silica molecular sieve CHA |
US7282082B2 (en) * | 2004-11-29 | 2007-10-16 | Chevron Usa, Inc. | Gas separation using high-silica molecular sieve CHA |
US20060116540A1 (en) * | 2004-11-29 | 2006-06-01 | Chevron U.S.A. Inc. | Conversion of oxygenates to light olefins using high-silica molecular sieve CHA |
US20060115403A1 (en) * | 2004-11-29 | 2006-06-01 | Chevron U.S.A. Inc. | Reduction of oxides of nitrogen in a gas stream using high-silics molecular sieve CHA |
US7402297B2 (en) * | 2004-11-29 | 2008-07-22 | Chevron U.S.A. Inc. | High-silica molecular sieve CHA |
US7226575B2 (en) * | 2004-11-30 | 2007-06-05 | Chevron U.S.A. Inc. | Boron-containing molecular sieve CHA |
US7749471B2 (en) * | 2004-11-30 | 2010-07-06 | Chevron U.S.A. Inc. | Reduction of oxides of nitrogen in a gas stream using boron-containing molecular sieve CHA |
US7462744B1 (en) * | 2004-11-30 | 2008-12-09 | Chevron U.S.A. Inc. | Synthesis of amines using boron-containing molecular sieve CHA |
US20060115400A1 (en) * | 2004-11-30 | 2006-06-01 | Chevron U.S.A. Inc. | Treatment of engine exhaust using boron-containing molecular sieve CHA |
EP1838420B1 (en) * | 2004-11-30 | 2021-02-17 | Chevron U.S.A., Inc. | Boron-containing molecular sieve cha |
US7754187B2 (en) * | 2005-10-31 | 2010-07-13 | Exxonmobil Chemical Patents Inc. | Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins |
WO2007053239A1 (en) * | 2005-10-31 | 2007-05-10 | Exxonmobil Chemical Patents Inc. | Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins |
WO2007114195A1 (ja) * | 2006-03-30 | 2007-10-11 | Mitsubishi Chemical Corporation | プロピレンの製造方法 |
JP5135839B2 (ja) * | 2006-03-30 | 2013-02-06 | 三菱化学株式会社 | プロピレンの製造方法 |
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-
2003
- 2003-02-20 DE DE60310898T patent/DE60310898T2/de not_active Expired - Lifetime
- 2003-02-20 JP JP2003576342A patent/JP4508654B2/ja not_active Expired - Fee Related
- 2003-02-20 US US10/370,923 patent/US7148172B2/en not_active Expired - Lifetime
- 2003-02-20 EP EP03717907A patent/EP1485323B1/en not_active Expired - Lifetime
- 2003-02-20 EA EA200401139A patent/EA007658B1/ru not_active IP Right Cessation
- 2003-02-20 WO PCT/US2003/005082 patent/WO2003078324A1/en active IP Right Grant
- 2003-02-20 AT AT03717907T patent/ATE350338T1/de not_active IP Right Cessation
- 2003-02-20 CN CNB038089467A patent/CN100418881C/zh not_active Expired - Fee Related
- 2003-02-20 AU AU2003222228A patent/AU2003222228A1/en not_active Abandoned
- 2003-02-20 ES ES03717907T patent/ES2279105T3/es not_active Expired - Lifetime
- 2003-02-26 TW TW092104088A patent/TWI315718B/zh not_active IP Right Cessation
- 2003-03-03 MY MYPI20030745A patent/MY131154A/en unknown
-
2004
- 2004-09-07 ZA ZA200407139A patent/ZA200407139B/en unknown
-
2006
- 2006-10-31 US US11/590,230 patent/US7435863B2/en not_active Expired - Lifetime
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AU2003222228A1 (en) | 2003-09-29 |
US7435863B2 (en) | 2008-10-14 |
US20030176751A1 (en) | 2003-09-18 |
EP1485323A1 (en) | 2004-12-15 |
US7148172B2 (en) | 2006-12-12 |
JP2005520763A (ja) | 2005-07-14 |
ATE350338T1 (de) | 2007-01-15 |
CN100418881C (zh) | 2008-09-17 |
ZA200407139B (ja) | 2006-06-28 |
US20070043251A1 (en) | 2007-02-22 |
EA007658B1 (ru) | 2006-12-29 |
TWI315718B (en) | 2009-10-11 |
DE60310898D1 (de) | 2007-02-15 |
DE60310898T2 (de) | 2007-10-11 |
WO2003078324A1 (en) | 2003-09-25 |
ES2279105T3 (es) | 2007-08-16 |
MY131154A (en) | 2007-07-31 |
EP1485323B1 (en) | 2007-01-03 |
TW200304427A (en) | 2003-10-01 |
EA200401139A1 (ru) | 2005-04-28 |
CN1646427A (zh) | 2005-07-27 |
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