JP4505646B2 - Fixed sheet - Google Patents
Fixed sheet Download PDFInfo
- Publication number
- JP4505646B2 JP4505646B2 JP2006041751A JP2006041751A JP4505646B2 JP 4505646 B2 JP4505646 B2 JP 4505646B2 JP 2006041751 A JP2006041751 A JP 2006041751A JP 2006041751 A JP2006041751 A JP 2006041751A JP 4505646 B2 JP4505646 B2 JP 4505646B2
- Authority
- JP
- Japan
- Prior art keywords
- silicone
- layer
- oil
- oily substance
- silicone layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920001296 polysiloxane Polymers 0.000 claims description 73
- 239000000126 substance Substances 0.000 claims description 33
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 21
- 238000000576 coating method Methods 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 14
- 239000004094 surface-active agent Substances 0.000 claims description 13
- 239000011230 binding agent Substances 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 229920006136 organohydrogenpolysiloxane Polymers 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 claims description 3
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 claims description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
- 125000004437 phosphorous atom Chemical group 0.000 claims description 3
- 125000004434 sulfur atom Chemical group 0.000 claims description 3
- -1 aldehyde compounds Chemical class 0.000 description 57
- 239000000853 adhesive Substances 0.000 description 19
- 230000001070 adhesive effect Effects 0.000 description 18
- 235000014113 dietary fatty acids Nutrition 0.000 description 17
- 239000000194 fatty acid Substances 0.000 description 17
- 229930195729 fatty acid Natural products 0.000 description 17
- 239000003921 oil Substances 0.000 description 17
- 235000019198 oils Nutrition 0.000 description 17
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 14
- 239000004014 plasticizer Substances 0.000 description 14
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 13
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 239000011521 glass Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 4
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 4
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 4
- JQCXWCOOWVGKMT-UHFFFAOYSA-N diheptyl phthalate Chemical compound CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- ZWYAVGUHWPLBGT-UHFFFAOYSA-N bis(6-methylheptyl) decanedioate Chemical compound CC(C)CCCCCOC(=O)CCCCCCCCC(=O)OCCCCCC(C)C ZWYAVGUHWPLBGT-UHFFFAOYSA-N 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 229920006267 polyester film Polymers 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 230000003405 preventing effect Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- NVXYNWZJMIFTMV-UHFFFAOYSA-N 10-o-benzyl 1-o-butyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCC1=CC=CC=C1 NVXYNWZJMIFTMV-UHFFFAOYSA-N 0.000 description 2
- LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 description 2
- PZBLUWVMZMXIKZ-UHFFFAOYSA-N 2-o-(2-ethoxy-2-oxoethyl) 1-o-ethyl benzene-1,2-dicarboxylate Chemical compound CCOC(=O)COC(=O)C1=CC=CC=C1C(=O)OCC PZBLUWVMZMXIKZ-UHFFFAOYSA-N 0.000 description 2
- YJERZJLSXBRUDQ-UHFFFAOYSA-N 2-o-(3,4-dihydroxybutyl) 1-o-methyl benzene-1,2-dicarboxylate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OCCC(O)CO YJERZJLSXBRUDQ-UHFFFAOYSA-N 0.000 description 2
- WHHSHXMIKFVAEK-UHFFFAOYSA-N 2-o-benzyl 1-o-octyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 WHHSHXMIKFVAEK-UHFFFAOYSA-N 0.000 description 2
- ALKCLFLTXBBMMP-UHFFFAOYSA-N 3,7-dimethylocta-1,6-dien-3-yl hexanoate Chemical compound CCCCCC(=O)OC(C)(C=C)CCC=C(C)C ALKCLFLTXBBMMP-UHFFFAOYSA-N 0.000 description 2
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- GOJCZVPJCKEBQV-UHFFFAOYSA-N Butyl phthalyl butylglycolate Chemical compound CCCCOC(=O)COC(=O)C1=CC=CC=C1C(=O)OCCCC GOJCZVPJCKEBQV-UHFFFAOYSA-N 0.000 description 2
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 description 2
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 2
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 2
- NEHDRDVHPTWWFG-UHFFFAOYSA-N Dioctyl hexanedioate Chemical compound CCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCC NEHDRDVHPTWWFG-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 2
- 238000012644 addition polymerization Methods 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 2
- WXZOXVVKILCOPG-UHFFFAOYSA-N bis(2-ethylhexyl) benzene-1,3-dicarboxylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC(C(=O)OCC(CC)CCCC)=C1 WXZOXVVKILCOPG-UHFFFAOYSA-N 0.000 description 2
- ZDWGXBPVPXVXMQ-UHFFFAOYSA-N bis(2-ethylhexyl) nonanedioate Chemical compound CCCCC(CC)COC(=O)CCCCCCCC(=O)OCC(CC)CCCC ZDWGXBPVPXVXMQ-UHFFFAOYSA-N 0.000 description 2
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 229940100539 dibutyl adipate Drugs 0.000 description 2
- HCQHIEGYGGJLJU-UHFFFAOYSA-N didecyl hexanedioate Chemical compound CCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCC HCQHIEGYGGJLJU-UHFFFAOYSA-N 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- HHECSPXBQJHZAF-UHFFFAOYSA-N dihexyl hexanedioate Chemical compound CCCCCCOC(=O)CCCCC(=O)OCCCCCC HHECSPXBQJHZAF-UHFFFAOYSA-N 0.000 description 2
- MJOKHGMXPJXFTG-UHFFFAOYSA-N dihexyl nonanedioate Chemical compound CCCCCCOC(=O)CCCCCCCC(=O)OCCCCCC MJOKHGMXPJXFTG-UHFFFAOYSA-N 0.000 description 2
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 2
- 229960001826 dimethylphthalate Drugs 0.000 description 2
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 2
- YCZJVRCZIPDYHH-UHFFFAOYSA-N ditridecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCC YCZJVRCZIPDYHH-UHFFFAOYSA-N 0.000 description 2
- QQVHEQUEHCEAKS-UHFFFAOYSA-N diundecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCC QQVHEQUEHCEAKS-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 229920001477 hydrophilic polymer Polymers 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 229920001515 polyalkylene glycol Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 150000003460 sulfonic acids Chemical class 0.000 description 2
- 239000010689 synthetic lubricating oil Substances 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 description 2
- 239000001069 triethyl citrate Substances 0.000 description 2
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 2
- 235000013769 triethyl citrate Nutrition 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- YOJKKXRJMXIKSR-UHFFFAOYSA-N 1-nitro-2-phenylbenzene Chemical group [O-][N+](=O)C1=CC=CC=C1C1=CC=CC=C1 YOJKKXRJMXIKSR-UHFFFAOYSA-N 0.000 description 1
- ZGHZSTWONPNWHV-UHFFFAOYSA-N 2-(oxiran-2-yl)ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCC1CO1 ZGHZSTWONPNWHV-UHFFFAOYSA-N 0.000 description 1
- HVYJSOSGTDINLW-UHFFFAOYSA-N 2-[dimethyl(octadecyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O HVYJSOSGTDINLW-UHFFFAOYSA-N 0.000 description 1
- NUCFNMOPTGEHQA-UHFFFAOYSA-N 3-bromo-2h-pyrazolo[4,3-c]pyridine Chemical compound C1=NC=C2C(Br)=NNC2=C1 NUCFNMOPTGEHQA-UHFFFAOYSA-N 0.000 description 1
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical class CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 1
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical class CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 description 1
- ULIJUDULYQTGKI-UHFFFAOYSA-N 6-decoxy-6-oxohexanoic acid Chemical compound CCCCCCCCCCOC(=O)CCCCC(O)=O ULIJUDULYQTGKI-UHFFFAOYSA-N 0.000 description 1
- OIUGWVWLEGLAGH-UHFFFAOYSA-N 6-nonoxy-6-oxohexanoic acid Chemical compound CCCCCCCCCOC(=O)CCCCC(O)=O OIUGWVWLEGLAGH-UHFFFAOYSA-N 0.000 description 1
- 241000238366 Cephalopoda Species 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- PYVHTIWHNXTVPF-UHFFFAOYSA-N F.F.F.F.C=C Chemical compound F.F.F.F.C=C PYVHTIWHNXTVPF-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000010654 Melissa officinalis Nutrition 0.000 description 1
- 244000062730 Melissa officinalis Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- CGSLYBDCEGBZCG-UHFFFAOYSA-N Octicizer Chemical compound C=1C=CC=CC=1OP(=O)(OCC(CC)CCCC)OC1=CC=CC=C1 CGSLYBDCEGBZCG-UHFFFAOYSA-N 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 229910020175 SiOH Inorganic materials 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- PZBFGYYEXUXCOF-UHFFFAOYSA-N TCEP Chemical compound OC(=O)CCP(CCC(O)=O)CCC(O)=O PZBFGYYEXUXCOF-UHFFFAOYSA-N 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 description 1
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 description 1
- 235000006732 Torreya nucifera Nutrition 0.000 description 1
- 244000111306 Torreya nucifera Species 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- LNLPZVVOYZTUNG-UHFFFAOYSA-N benzyl(ethenyl)silicon Chemical compound C=C[Si]CC1=CC=CC=C1 LNLPZVVOYZTUNG-UHFFFAOYSA-N 0.000 description 1
- 235000001046 cacaotero Nutrition 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229910052956 cinnabar Inorganic materials 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical compound C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 description 1
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical compound C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 description 1
- 229920005645 diorganopolysiloxane polymer Polymers 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000005338 frosted glass Substances 0.000 description 1
- 239000012208 gear oil Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000000865 liniment Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- WHPISZUUSVIBTD-UHFFFAOYSA-N methyl 2-(dodecylamino)propanoate Chemical compound CCCCCCCCCCCCNC(C)C(=O)OC WHPISZUUSVIBTD-UHFFFAOYSA-N 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- KCXFHTAICRTXLI-UHFFFAOYSA-N propane-1-sulfonic acid Chemical class CCCS(O)(=O)=O KCXFHTAICRTXLI-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000004447 silicone coating Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- HWCHICTXVOMIIF-UHFFFAOYSA-M sodium;3-(dodecylamino)propanoate Chemical compound [Na+].CCCCCCCCCCCCNCCC([O-])=O HWCHICTXVOMIIF-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical compound S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 239000010723 turbine oil Substances 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 229920002554 vinyl polymer Chemical class 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
本発明は、貼り直しが簡単にでき、再剥離時には僅かな剥離力で剥離できる固定シートに関する。 The present invention relates to a fixing sheet that can be easily re-attached and can be peeled off with a slight peeling force during re-peeling.
従来、基材上にシリコーン層を設け、他方の面に印刷適性処理を施した固定シートが提供されてきた（特許文献１）。このシートの片面に印刷を施し、シリコーン層面を窓ガラス等の表面がフラットな被着体に貼ることにより、ウィンドディスプレイや屋内表示を容易に行うものである。シートを剥がしても糊残りの問題もなく、何回貼っても剥がせるという特徴を有するものであった。（本明細書において、糊とはシリコーン層をさす。） Conventionally, a fixed sheet has been provided in which a silicone layer is provided on a base material and a printability treatment is performed on the other surface (Patent Document 1). Printing is performed on one side of the sheet, and the silicone layer surface is attached to an adherend having a flat surface such as a window glass, thereby easily performing a window display or indoor display. Even if the sheet is peeled off, there is no problem of adhesive residue, and the sheet can be peeled off any number of times. (In this specification, glue refers to a silicone layer.)
しかし、被着体の表面がＯＨ基を持つものであると、時間の経過と共にシリコーン層が被着体と密着し、固定シートを再剥離するときに糊残りが発生する問題があった。特に被着体がガラスの場合、屋外で使用したり、直射日光が直接当る屋内で使用したりすると、数ヶ月経って再剥離すると糊残りが発生した。
基材上にシリコーン層を設け他方の面に印刷を施した固定シートを、屋外や直射日光の当る屋内でのウィンドディスプレイとして貼る場合に、再剥離時、糊残りが発生せず、僅かな剥離力で剥離可能な固定シートとするための固定シートを提供するものである。
When a fixed sheet with a silicone layer on the substrate and printed on the other side is pasted as a wind display outdoors or indoors exposed to direct sunlight, no adhesive residue is generated at the time of re-peeling, and slight peeling A fixing sheet for providing a fixing sheet that can be peeled by force is provided.
第１発明は、基材の上に両末端にのみビニル基を有する直鎖状ポリオルガノシロキサンからなるシリコーンと、両末端及び側鎖にビニル基を有する直鎖状ポリオルガノシロキサンからなるシリコーンと、末端にのみビニル基を有する分岐状ポリオルガノシロキサンからなるシリコーンと、末端及び側鎖にビニル基を有する分岐状ポリオルガノシロキサンからなるシリコーンとから選ばれる少なくとも１種のシリコーンをオルガノハイドロジェンポリシロキサンで架橋させてなるシリコーン層を設けた固定シートにおいて、シリコーン層の上に分子中にＮ、Ｐ、Ｓ原子を少なくとも１種以上有する界面活性剤又は、ジ−ｎ−オクチル錫メルカプタイドを含むオイル状物質層を塗布量０．０１〜１ｇ／ｍ ２ の範囲に設けたことを特徴とする固定シートとする。
第２発明は、前記オイル状物質層は、バインダとオイル状物質からなるものであることを特徴とする第１発明記載の固定シートである。
The first invention comprises a silicone comprising a linear polyorganosiloxane having a vinyl group only at both ends on a substrate, a silicone comprising a linear polyorganosiloxane having a vinyl group at both ends and side chains, At least one silicone selected from a silicone composed of a branched polyorganosiloxane having a vinyl group only at the terminal and a silicone composed of a branched polyorganosiloxane having a vinyl group at the terminal and side chain is an organohydrogenpolysiloxane. A fixed sheet provided with a crosslinked silicone layer , an oily substance containing a surfactant having at least one N, P, or S atom in the molecule or di-n-octyltin mercaptide on the silicone layer A fixed sheet characterized in that the layer is provided in a coating amount range of 0.01 to 1 g / m 2. And
A second invention is the fixing sheet according to the first invention, wherein the oily substance layer is composed of a binder and an oily substance.
本発明の固定シートは、屋外や直射日光の当る屋内でのウィンドディスプレイにおいて、再剥離時、糊残りが発生せず、僅かな剥離力で剥離可能であり、何回でも繰り返し貼付ができる固定シートである。
The fixing sheet of the present invention is a fixing sheet that can be repeatedly applied with any number of times, with no adhesive residue, and with little peeling force, when re-peeling in an outdoor or indoor window display that is exposed to direct sunlight. It is.
（１）基材
各種プラスチックからなるフィルムであれば、特に限定されない。例えばポリオレフィン、ポリエステル等からなるフィルムが例示されるが、これらに限定されるものではない。取り扱い易さ、耐熱性、強度の面より好ましくはポリエステルフィルムを用いるとよい。基材の厚みは、用途に応じて適宜選択すればよいが、通常１２〜２００μｍの範囲のものを用いる。
(1) Base material
The film is not particularly limited as long as it is a film made of various plastics. Examples thereof include films made of polyolefin, polyester, etc., but are not limited thereto. From the viewpoint of ease of handling, heat resistance, and strength, a polyester film is preferably used. The thickness of the base material may be appropriately selected depending on the application, but usually a thickness in the range of 12 to 200 μm is used.
基材フィルムは、シリコーン層が積層される側の表面を活性線で処理したり、また上記表面に接着性を向上させる化合物からなる易接着層を積層したりしたものが好ましくもちいることができる。上記の活性線による処理方法としては、コロナ放電処理、紫外線照射処理、プラズマ処理、火炎処理等が例示される。また、積層により接着性を向上させる易接着層用の化合物としては、ポリエステル系、ポリウレタン系、ポリアクリル系のポリマーまたはこれらの混合物が挙げられる。 As the base film, a film obtained by treating the surface on which the silicone layer is laminated with active rays or laminating an easy-adhesion layer made of a compound that improves adhesiveness on the surface can be preferably used. . Examples of the treatment method using active rays include corona discharge treatment, ultraviolet irradiation treatment, plasma treatment, and flame treatment. In addition, examples of the compound for the easy adhesion layer that improves the adhesion by lamination include polyester-based, polyurethane-based, polyacrylic-based polymers, and mixtures thereof.
（２）シリコーン層
シリコーン層に用いるシリコーンとしては、たとえば、付加重合型のシリコーン重合体を使用することができる。付加重合型シリコーン樹脂は白金触媒により重合するものを挙げることができる。本発明の目的にかなうシリコーン層の性状としては、ゴムのような柔軟性を持っていて被着体の表面の凸凹に対してもシリコーン層の面が凸凹に沿うことがもとめられる。さらに剥離の際には、小さい剥離力で、容易に剥離できることが求められる。
(2) Silicone layer As the silicone used for the silicone layer, for example, an addition polymerization type silicone polymer can be used. Examples of the addition polymerization type silicone resin include those polymerized by a platinum catalyst. As a property of the silicone layer for the purpose of the present invention, it is required that the surface of the silicone layer is along the unevenness even with respect to the unevenness of the surface of the adherend, which is flexible like rubber. Further, when peeling, it is required to be easily peeled with a small peeling force.
このような性状のシリコーンとして、両末端にのみビニル基を有する直鎖状ポリオルガノシロキサンからなるシリコーンと、両末端及び側鎖にビニル基を有する直鎖状ポリオルガノシロキサンからなるシリコーンと、末端にのみビニル基を有する分岐状ポリオルガノシロキサンからなるシリコーンと、末端及び側鎖にビニル基を有する分岐状ポリオルガノシロキサンからなるシリコーンとから選ばれる少なくとも１種のシリコーンを架橋させてなるものを用いると良い。
As silicone having such properties, a silicone composed of a linear polyorganosiloxane having vinyl groups only at both ends, a silicone composed of a linear polyorganosiloxane having vinyl groups at both ends and side chains, and a terminal. a silicone comprising a branched polyorganosiloxane having vinyl groups only, the end and side chains to crosslink the at least one silicone selected from silicone consisting of branched polyorganosiloxane having a vinyl group is used one made by the good.
これらのシリコーンの１形態としては、両末端にのみビニル基を有する直鎖状ポリオルガノシロキサンとは下記一般式（化１）で表せられる化合物である。 As one form of these silicones, a linear polyorganosiloxane having vinyl groups only at both ends is a compound represented by the following general formula (Formula 1).
（式中Ｒは下記有機基、ｎは整数を表す）
(Wherein R represents the following organic group, and n represents an integer)
（式中Ｒは下記有機基、ｍ、ｎは整数を表す）
このビニル基以外のケイ素原子に結合した有機基（Ｒ）は異種でも同種でもよいが、具体例としてはメチル基、エチル基、プロピル基などのアルキル基、フェニル基、トリル基、などのアリール基、又はこれらの基の炭素原子に結合した水素原子の一部又は全部をハロゲン原子、シアノ基などで置換した同種又は異種の非置換又は置換の脂肪族不飽和基を除く１価炭化水素基で好ましくはその少なくとも５０モル％がメチル基であるものなどが挙げられるが、このジオルガノポリシロキサンは単独でも２種以上の混合物であってもよい。
(Wherein R represents the following organic group, m and n represent an integer)
The organic group (R) bonded to the silicon atom other than the vinyl group may be different or of the same type. Specific examples include alkyl groups such as methyl, ethyl and propyl groups, and aryl groups such as phenyl and tolyl groups. Or a monovalent hydrocarbon group other than the same or different unsubstituted or substituted aliphatic unsaturated group in which part or all of the hydrogen atoms bonded to the carbon atoms of these groups are substituted with a halogen atom, a cyano group, or the like. Preferable examples include those having at least 50 mol% of a methyl group. These diorganopolysiloxanes may be used alone or as a mixture of two or more thereof.
両末端および側鎖にビニル基を有する直鎖状ポリオルガノシロキサンからなるシリコーンは、上記一般式（化１）中のＲの一部がビニル基である化合物である。末端にのみビニル基を有する分岐状ポリオルガノシロキサンからなるシリコーンは上記一般式（化２）で表せられる化合物である。末端及び側鎖にビニル基を有する分岐状ポリオルガノシロキサンからなるシリコーン上記一般式（化２）中のＲの一部がビニル基である化合物である。
A silicone comprising a linear polyorganosiloxane having vinyl groups at both ends and side chains is a compound in which a part of R in the above general formula (Formula 1) is a vinyl group. Silicone consisting branched polyorganosiloxane having vinyl groups only at the terminal is a compound which is expressed by the above general formula (Formula 2). Some of the R of the branched poly consisting polyorganosiloxane silicone the above-mentioned general formula (Formula 2) having a vinyl group at the terminal and side chain is a compound which is a vinyl group.
ここで架橋反応に用いる架橋剤は公知のものでよい。架橋剤の例として、オルガノハイドロジェンポリシロキサンが挙げられる。オルガノハイドロジェンポリシロキサンは１分子中にケイ素原子に結合した水素原子を少なくとも３個有するものであるが、実用上からは分子中に２個の≡ＳｉＨ結合を有するものをその全量の５０重量％までとし、残余を分子中に少なくとも３個の≡ＳｉＨ結合を含むものとすることがよい。 Here, a known crosslinking agent may be used for the crosslinking reaction. Examples of the crosslinking agent include organohydrogenpolysiloxane. Organohydrogenpolysiloxane has at least three hydrogen atoms bonded to silicon atoms in one molecule, but from a practical viewpoint, one having two ≡SiH bonds in the molecule is 50% by weight of the total amount. It is preferable that the remainder contains at least three ≡SiH bonds in the molecule.
架橋反応に用いる白金系触媒は公知のものでよく、これには塩化第一白金酸、塩化第二白金酸などの塩化白金酸、塩化白金酸のアルコール化合物、アルデヒド化合物あるいは塩化白金酸と各種オレフィンとの鎖塩などがあげられる。架橋反応したシリコーン層は、シリコーンゴムのような柔軟性を持ったものとなり、この柔軟性が被着体との密着を容易にさせるものである。 The platinum-based catalyst used for the crosslinking reaction may be a known one, including chloroplatinic acid such as chloroplatinic acid and chloroplatinic acid, alcohol compounds of chloroplatinic acid, aldehyde compounds or chloroplatinic acid and various olefins. And chain salts. The crosslinked silicone layer has flexibility such as silicone rubber, and this flexibility facilitates the close contact with the adherend.
本発明に係るシリコーンの市販品の形状は、無溶剤型、溶剤型、エマルション型があるが、いずれの型も使用できる。中でも、無溶剤型は、溶剤を使用しないため、安全性、衛生性、大気汚染の面で非常に利点がある。又、シリコーン層の塗布厚みは、１．１μｍを超えることが必要であり、場合によっては、数ミリの厚みに設けることから、溶剤型シリコーンや、エマルション型シリコーンでは、塗工時の溶媒の乾燥に多大なエネルギーがかかり、不経済となるので、本発明に使用するシリコーンは、無溶剤型のシリコーンを用いるのがよい。 The shape of the commercially available silicone product according to the present invention includes a solventless type, a solvent type, and an emulsion type, but any type can be used. Above all, the solventless type is very advantageous in terms of safety, hygiene, and air pollution because it does not use a solvent. In addition, the coating thickness of the silicone layer needs to exceed 1.1 μm, and in some cases, it is provided with a thickness of several millimeters. Therefore, in the case of solvent type silicone or emulsion type silicone, the solvent is dried at the time of coating. Therefore, it is preferable to use a solventless silicone as the silicone used in the present invention.
シリコーン層の表面の汚れや異物付着を防いだり、固定シートのハンドリングを向上させるために樹脂フィルム等のセパレータをシリコーン層面に貼り合わせることができる。 A separator such as a resin film can be bonded to the surface of the silicone layer in order to prevent the surface of the silicone layer from being soiled and foreign matter adhered, or to improve the handling of the fixed sheet.
一般にはシリコーン層の厚みは、１．１〜１００μｍの範囲が好ましい。好ましくは、１０〜５０μｍであるとよい。シリコーン層の厚みが、１．１μｍ未満であると、被着体に密着しにくくなり、被着体に対する固定シートの密着面方向の剪断力が１．０Ｎ／ｃｍ２未満となり、長期貼りつけ時には、固定シートが剥がれる可能性が出てくる。シリコーン層の厚みが、１００μｍを超えると、シリコーンの使用量が多くなり、コスト上不経済となる。 In general, the thickness of the silicone layer is preferably in the range of 1.1 to 100 μm. Preferably, it is good in it being 10-50 micrometers. When the thickness of the silicone layer is less than 1.1 μm, it becomes difficult to adhere to the adherend, and the shearing force in the contact surface direction of the fixed sheet with respect to the adherend becomes less than 1.0 N / cm 2 , The fixed sheet may come off. When the thickness of the silicone layer exceeds 100 μm, the amount of silicone used increases, which is uneconomical in terms of cost.
易接着層塗工液、シリコーン層塗工液の塗工方法としては、３本オフセットグラビアコーターや５本ロールコーターに代表される多段ロールコーター、ダイレクトグラビアコーター、バーコーター、エアナイフコーター等が適宜使用される。基材と易接着層とシリコーン層以外の積層の複合手段は、上記の塗工方法に限らずいずれも任意である。すなわち、個別に成形して得られたシートを接着剤や粘着剤または熱接着で貼合わせてもよく、トッピング法、押出しラミネート法等で直接一体化する方法でもよい。 As an easy adhesion layer coating solution and a silicone layer coating solution, a multi-stage roll coater represented by a three-offset gravure coater or a five-roll coater, a direct gravure coater, a bar coater, an air knife coater, etc. are used as appropriate. Is done. The composite means of lamination other than the base material, the easy-adhesion layer, and the silicone layer is not limited to the above-described coating method, and any of them is arbitrary. That is, the sheet | seat obtained by shape | molding separately may be bonded together by an adhesive agent, an adhesive, or heat bonding, and the method of integrating directly by a topping method, an extrusion lamination method, etc. may be sufficient.
シリコーン層の表面の汚れや異物付着からの保護や、固定シートのハンドリングを向上させるために樹脂フィルム製またはコート紙等のセパレータをシリコーン層面に貼り合わせる。 In order to protect the surface of the silicone layer from dirt and foreign matter adhesion, and to improve the handling of the fixed sheet, a separator made of resin film or coated paper is bonded to the silicone layer surface.
（４）第１発明は、シリコーン層の表面に分子中にＮ、Ｐ、Ｓ原子を少なくとも１種以上有する界面活性剤又は、ジ−ｎ−オクチル錫メルカプタイドを含むオイル状物質層を設けたものである。オイル状物質層は、少なくともオイル状物質を含有する層をいう。
(4) In the first invention, the surface of the silicone layer is provided with a surfactant having at least one N, P, or S atom in the molecule or an oily substance layer containing di-n-octyltin mercaptoide. It is. The oily substance layer refers to a layer containing at least an oily substance.
シリコーン層の被着体への糊残りは、シリコーン層と被着体界面が長期間にわたり紫外線下にさらされた時に発生する。シリコーン層の形成において、シリコーンの硬化反応に寄与しなかったＳｉＨ基がある程度残存している。環境温度の上昇によって、残存しているＳｉＨ基が徐々に被着体との界面へブリードしてくる。ブリードしたＳｉＨ基に紫外線が照射されると、被着体側の表面のＯＨ基と強固に結合する。このため基材フィルムを剥がす際、シリコーン層は層間破壊し、糊残りを生ずる。シリコーン層の上のオイル状物質層は、この反応を阻害する働きをして糊残りを防止する。 The adhesive residue on the adherend of the silicone layer is generated when the silicone layer and the adherend interface are exposed to ultraviolet rays for a long time. In the formation of the silicone layer, some SiH groups that did not contribute to the silicone curing reaction remain. As the environmental temperature rises, the remaining SiH groups gradually bleed to the interface with the adherend. When the bleed SiH group is irradiated with ultraviolet rays, it is firmly bonded to the OH group on the surface of the adherend. For this reason, when the base film is peeled off, the silicone layer breaks between layers, resulting in adhesive residue. The oily substance layer on the silicone layer functions to inhibit this reaction and prevents adhesive residue.
オイル状物質層は、オイル状物質のみで形成されていても良いし、バインダとオイル状物質からなるものであってもよい。オイル状物質のみによるオイル状物質層であると、オイル状物質の品種によっては、シリコーン層に均一に塗布することが困難な場合がある。そのような場合には、バインダとオイル状物質を溶媒に混合分散したもので塗布することで塗布ムラを解消できる場合がある。 The oily substance layer may be formed of only an oily substance, or may be composed of a binder and an oily substance. When the oily substance layer is composed of only the oily substance, it may be difficult to apply the oily substance uniformly to the silicone layer depending on the type of the oily substance. In such a case, coating unevenness may be eliminated by coating with a binder and oily substance mixed and dispersed in a solvent.
シリコーン層面には、フィルムやコート紙等によるセパレータを貼り合わして表面への汚れ、粉塵の付着防止、キズ防止をする。オイル状物質層が均一に塗布できなくてもセパレータを貼ることにより、界面においてオイル状物質が面方向に移行することで層が均される。均しのために、セパレータを貼って少なくとも１日以上置くのがよい。均しを促進したい場合は、加熱すると良い。加熱温度は、３５〜８０℃の範囲が好ましい。 A separator made of a film or coated paper is attached to the silicone layer surface to prevent contamination, dust adhesion, and scratches on the surface. Even if the oily substance layer cannot be applied uniformly, the layer is leveled by sticking the separator so that the oily substance moves in the surface direction at the interface. For leveling, it is better to put a separator and place it for at least one day. Heating is better if you want to promote leveling. The heating temperature is preferably in the range of 35 to 80 ° C.
オイル状物質層が、オイル状物質のみで形成された層の場合の塗布量は、０．０００１〜０．５ｇ／ｍ２が好ましい。さらに好ましくは、０．００１〜０．１ｇ／ｍ２とする。前記範囲未満であると糊残り防止効果が低くなる。前記範囲を超えるとシリコーン層表面がべたついた感じとなり手の汚れ等が生じる。また、被着体に対する密着性が低下する。 The coating amount when the oil-like substance layer is a layer formed only of the oil-like substance is preferably 0.0001 to 0.5 g / m 2 . More preferably, it is 0.001 to 0.1 g / m 2 . If it is less than the above range, the adhesive residue preventing effect is lowered. If the above range is exceeded, the silicone layer surface will feel sticky and hand stains will occur. Moreover, the adhesiveness with respect to a to-be-adhered body falls.
オイル状物質層が、バインダとオイル状物質で形成される場合のバインダとしては、熱可塑性樹脂を用いる。熱可塑性樹脂としては、例えばポリエステル系樹脂、アクリル系樹脂、ポリアミド樹脂、フェノール樹脂、キシレン樹脂、エチレンー酢酸ビニル共重合体、アルキッド樹脂、ウレタン樹脂、ポリカーボネート樹脂などが挙げられる。これらの１種以上を選択して用いる。これらの樹脂の硬化型樹脂であっても使用できる。バインダと界面活性剤の配合比率は、５：９５〜９５：５の範囲が好ましい。オイル状物質の配合比率が前記範囲未満であると糊残り防止の効果が低下してくる。前記範囲を超えると液体状の界面活性剤の場合にシリコーン層表面がべたついた感じとなり手の汚れ等が生じたり、被着体への密着性が低下する。この場合の、オイル状物質層の塗布量は、０．０１〜1ｇ／ｍ２の範囲が好ましい。前記範囲未満であると糊残り防止効果が低くなる。前記範囲を超えるとシリコーン層表面がべたついた感じとなって手の汚れ等が生じたり、被着体への密着力が低下する。 A thermoplastic resin is used as a binder when the oil-like substance layer is formed of a binder and an oil-like substance. Examples of the thermoplastic resin include polyester resins, acrylic resins, polyamide resins, phenol resins, xylene resins, ethylene-vinyl acetate copolymers, alkyd resins, urethane resins, and polycarbonate resins. One or more of these are selected and used. Even curable resins of these resins can be used. The blending ratio of the binder and the surfactant is preferably in the range of 5:95 to 95: 5. When the blending ratio of the oily substance is less than the above range, the effect of preventing adhesive residue is lowered. When the amount exceeds the above range, the surface of the silicone layer becomes sticky in the case of a liquid surfactant, resulting in hand stains or the like, and poor adhesion to the adherend. In this case, the coating amount of the oily substance layer is preferably in the range of 0.01 to 1 g / m 2 . If it is less than the above range, the adhesive residue preventing effect is lowered. When the above range is exceeded, the surface of the silicone layer becomes sticky, resulting in hand stains and the like, and the adhesion to the adherend is reduced.
被着体の表面にＯＨ基を持ったものとしては、被着体自身が、ＯＨ基を持った樹脂で成型された樹脂成型品であったり、被着体の表面にＯＨ基を持った樹脂で被覆されたもの、または、ガラスが挙げられる。ＯＨ基を持った樹脂としては、ポリエステル系樹脂、アクリル系樹脂、ウレタン系樹脂、シリコーン系樹脂などが挙げられる。 As the one having an OH group on the surface of the adherend, the adherend itself is a resin molded product molded with a resin having an OH group, or a resin having an OH group on the surface of the adherend. Or glass coated with or. Examples of the resin having an OH group include polyester resins, acrylic resins, urethane resins, and silicone resins.
特に被着体がガラスの場合、ガラス表面の存在する多数のＳｉＯＨ基がシリコーン層の残存ＳｉＨ基と強固に結合するので、糊残りが顕著に発生する。基材フィルムを剥がした跡の糊残りは、ガラスが透明であるため非常に目立ち、透明ガラスが曇りガラスのようになってしまう。 In particular, when the adherend is made of glass, a large number of SiOH groups present on the glass surface are strongly bonded to the remaining SiH groups of the silicone layer, so that adhesive residue is remarkably generated. The adhesive residue after the substrate film is peeled off is very conspicuous because the glass is transparent, and the transparent glass becomes like frosted glass.
さらに、オイル状物質の分子中に、付加型シリコーンの硬化反応で触媒毒となり得る原子Ｎ、Ｐ、Ｓ、Ｓnを少なくとも１種以上有するものは、上記の反応に対して触媒毒として働き、糊残り防止に著しい効果が現れる。 Further, those having at least one atom N, P, S, Sn that can become a catalyst poison in the curing reaction of addition-type silicone in the molecule of the oily substance act as a catalyst poison for the above reaction, and paste Significant effect appears in prevention of the rest.
オイル状物質とは、常温で液体あるいはペースト状のオイルであり、植物油、油脂、鉱物油、合成潤滑油、界面活性剤、可塑剤、高級アルコール、高級脂肪酸、高級脂肪酸エステル等を挙げることができる。これらのものより、界面活性剤等を用いる。
Oily substances are oils that are liquid or paste at room temperature, and include vegetable oils, fats and oils, mineral oils, synthetic lubricating oils, surfactants, plasticizers, higher alcohols, higher fatty acids, higher fatty acid esters, and the like. . A surfactant or the like is used from these.
植物油としてはアマニ油、カヤ油、サフラー油、大豆油、シナギリ油、ゴマ油、トウモロコシ油、ナタネ油、ヌカ油、綿実油、オリーブ油、サザンカ油、つばき油、ヒマシ油、落花生油、バーム油、椰油等が挙げられる。油脂としては、牛脂、豚油、羊油、カカオ油等、鉱物油としてはマシン油、絶縁油、タービン油、モーター油、ギヤ油、切削油、流動パラフィン等を挙げることができる。合成潤滑油としては、化学大辞典（共立出版社）に記載の要件を満たすものを任意に使用することができ、例えばオレフィン重合油、ジエステル油、ポリアルキレングリコール油、ジエステル油、ポリアルキレングリコール油、シリコーン油等を挙げることができる。 Vegetable oils include linseed oil, kaya oil, safflower oil, soybean oil, cinnabar oil, sesame oil, corn oil, rapeseed oil, squid oil, cottonseed oil, olive oil, sasanqua oil, camellia oil, castor oil, peanut oil, balm oil, coconut oil Etc. Examples of the fats and oils include beef tallow, pork oil, sheep oil, cacao oil and the like, and examples of the mineral oil include machine oil, insulating oil, turbine oil, motor oil, gear oil, cutting oil, and liquid paraffin. As the synthetic lubricating oil, those satisfying the requirements described in the Chemical Dictionary (Kyoritsu Publishing Co., Ltd.) can be arbitrarily used. For example, olefin polymer oil, diester oil, polyalkylene glycol oil, diester oil, polyalkylene glycol oil And silicone oil.
界面活性剤としては、アニオン性、カチオン性、非イオン性、両性等の性質に関らず、従来公知のいかなるものも用いることができる。 As the surfactant, any conventionally known surfactant can be used regardless of properties such as anionic, cationic, nonionic and amphoteric.
アニオン性界面活性剤としては、脂肪酸塩類、アビエチン酸塩類、ヒドロキシアルカンスルホン酸塩類、アルカンスルホン酸塩類、ジアルキルスルホ琥珀酸塩類、直鎖アルキルベンゼンスルホン酸塩類、アルキルナフタレンスルホン酸塩類、アルキルフェノキシポリオキシエチレンプロピルスルホン酸塩類、ポリオキシエチレンアルキルスルホフェニルエーテル塩類、Ｎ−メチル−Ｎ−オレイルタウリンナトリウム塩類、Ｎ−アルキルスルホ琥珀酸モノアミド二ナトリウム塩類、石油スルホン錯塩類、硫酸化ひまし油、硫酸化牛脂油、脂肪酸アルキルエステルの硫酸エステル塩類、ポリオキシエチレンアルキルエーテル硫酸エステル塩類、脂肪酸モノグリセリド硫酸エステル塩類、ポリオキシエチレンアルキルフェニルエーテル硫酸エステル塩類、ポリオキシエチレンスチリルフェニルエーテル硫酸エステル塩類、アルキル燐酸エステル塩類、ポリオキシエチレンアルキルエーテル燐酸エステル塩類、ポリオキシエチレンアルキルフェニルエーテル燐酸エステル塩類、スチレンと無水マレイン酸共重合物の部分鹸化物類、ナフタレンスルホン酸塩ホルマリン縮合物類などが挙げられる。 Anionic surfactants include fatty acid salts, abietic acid salts, hydroxyalkane sulfonic acid salts, alkane sulfonic acid salts, dialkyl sulfosuccinic acid salts, linear alkylbenzene sulfonic acid salts, alkylnaphthalene sulfonic acid salts, alkylphenoxypolyoxyethylene. Propyl sulfonates, polyoxyethylene alkyl sulfophenyl ether salts, N-methyl-N-oleyl taurine sodium salts, N-alkyl sulfosuccinic acid monoamide disodium salts, petroleum sulfone complex salts, sulfated castor oil, sulfated beef oil, Fatty acid alkyl ester sulfates, polyoxyethylene alkyl ether sulfates, fatty acid monoglyceride sulfates, polyoxyethylene alkylphenyl ether sulfates Polyoxyethylene styryl phenyl ether sulfate ester salts, alkyl phosphate ester salts, polyoxyethylene alkyl ether phosphate ester salts, polyoxyethylene alkyl phenyl ether phosphate ester salts, partially saponified styrene and maleic anhydride copolymers, And naphthalene sulfonate formalin condensates.
カチオン性界面活性剤の具体例としては、アルキルアミン塩類、第４級アンモニウム塩類、ポリオキシエチレンアルキルアミン塩類、ポリエチレンポリアミン誘導体などが挙げられる。 Specific examples of the cationic surfactant include alkylamine salts, quaternary ammonium salts, polyoxyethylene alkylamine salts, polyethylene polyamine derivatives and the like.
非イオン性界面活性剤の具体例としては、ポリオキシエチレンアルキルエーテル類、ポリオキシエチレンアルキルフェニルエーテル類、ポリオキシエチレンポリスチリルフェニルエーテル類、ポリオキシエチレンポリオキシプロピレンアルキルエーテル類、グリセリン脂肪酸部分エステル化物類、ソルビタン脂肪酸部分エステル化物類、ペンタエリスリトール脂肪酸部分エステル化物類、プロピレングリコールモノ脂肪酸エステル類、ショ糖脂肪酸部分エステル化物類、ポリオキシエチレンソルビタン脂肪酸部分エステル化物類、ポリオキシエチレンソルビトール脂肪酸部分エステル化物類、ポリエチレングリコール脂肪酸エステル類、ポリグリセリン脂肪酸部分エステル化物類、ポリオキシエチレン化ひまし油類、ポリオキシエチレングリセリン脂肪酸部分エステル化物類、脂肪酸ジエタノールアミド類、Ｎ、Ｎ−ビス−２−ヒドロキシアルキルアミン類、ポリオキシエチレンアルキルアミン類、トリエタノールアミン脂肪酸エステル類、トリアルキルアミンオキシド類、ポリオキシエチレン−ポリオキシプロピレンブロックポリマーなどが挙げられる。その他シリコーン系界面活性剤、フッ素系界面活性剤も使用することができる。 Specific examples of nonionic surfactants include polyoxyethylene alkyl ethers, polyoxyethylene alkyl phenyl ethers, polyoxyethylene polystyryl phenyl ethers, polyoxyethylene polyoxypropylene alkyl ethers, glycerin fatty acid partial esters , Sorbitan fatty acid partial esterified product, pentaerythritol fatty acid partial esterified product, propylene glycol monofatty acid ester, sucrose fatty acid partial esterified product, polyoxyethylene sorbitan fatty acid partial esterified product, polyoxyethylene sorbitol fatty acid partial ester Products, polyethylene glycol fatty acid esters, polyglycerol fatty acid partial esterified products, polyoxyethylenated castor oil, polyoxyethylene glycol Phosphorus fatty acid partial esterified products, fatty acid diethanolamides, N, N-bis-2-hydroxyalkylamines, polyoxyethylene alkylamines, triethanolamine fatty acid esters, trialkylamine oxides, polyoxyethylene-poly Examples thereof include oxypropylene block polymers. In addition, silicone surfactants and fluorine surfactants can also be used.
シリコーン系界面活性剤としてはジメチルシリコン、アミノシラン、アクリルシラン、ビニルベンジルシラン、ビニルベンジシルアミノシラン、グリシドシラン、メルカプトシラン、ジメチルシラン、ポリジメチルシロキサン、ポリアルコキシシロキサン、ハイドロジエン変性シロキサン、ビニル変性シロキサン、ヒドロキシ変性シロキサン、アミノ変性シロキサン、カルボキシル変性シロキサン、ハロゲン化変性シロキサン、エポキシ変性シロキサン、メタクリロキシ変性シロキサン、メルカプト変性シロキサン、フッ素変性シロキサン、アルキル基変性シロキサン、フェニル変性シロキサン、アルキレンオキシド変性シロキサン等が挙げられる。フッ素系界面活性剤としては、４フッ化エチレン、パーフルオロアルキルアンモニウム塩、パーフルオロアルキルスルホン酸アミド、パーフルオロアルキルスルホン酸ナトリウム、パーフルオロアルキルカリウム塩、パーフルオロアルキルカルボン酸塩、パーフルオロアルキルスルホン酸塩、パーフルオロアルキルエチレンオキシド付加物、パーフルオロアルキルトリメチルアンモニウム塩、パーフルオロアルキルアミノスルホン酸塩、パーフルオロアルキル燐酸エステル、パーフルオロアルキル化合物、パーフルオロアルキルベタイン、パーフルオロアルキルハロゲン化合物等が挙げられる。
両性界面活性剤としては、ラウリルアミノプロピオン酸メチル、ラウリルアミノプロピオン酸ナトリウム、アルキルジメチルベタイン、ラウリルジメチルベタイン、ステアリルジメチルベタイン、ラウリルジヒドロキシエチルベタイン等が挙げられる。
Silicone surfactants include dimethyl silicon, amino silane, acrylic silane, vinyl benzyl silane, vinyl benzyl silyl amino silane, glycid silane, mercapto silane, dimethyl silane, polydimethyl siloxane, polyalkoxy siloxane, hydrodiene modified siloxane, vinyl modified siloxane, hydroxy Examples include modified siloxane, amino-modified siloxane, carboxyl-modified siloxane, halogenated-modified siloxane, epoxy-modified siloxane, methacryloxy-modified siloxane, mercapto-modified siloxane, fluorine-modified siloxane, alkyl group-modified siloxane, phenyl-modified siloxane, and alkylene oxide-modified siloxane. Fluorosurfactants include ethylene tetrafluoride, perfluoroalkyl ammonium salt, perfluoroalkyl sulfonic acid amide, sodium perfluoroalkyl sulfonate, perfluoroalkyl potassium salt, perfluoroalkyl carboxylate, perfluoroalkyl sulfone. Acid salts, perfluoroalkyl ethylene oxide adducts, perfluoroalkyl trimethyl ammonium salts, perfluoroalkyl aminosulfonates, perfluoroalkyl phosphates, perfluoroalkyl compounds, perfluoroalkyl betaines, perfluoroalkyl halogen compounds, and the like. .
Examples of the amphoteric surfactant include methyl laurylaminopropionate, sodium laurylaminopropionate, alkyldimethylbetaine, lauryldimethylbetaine, stearyldimethylbetaine, lauryldihydroxyethylbetaine and the like.
可塑剤としては、ジメチルフタレート（ＤＭＰ）、ジエチルフタレート（ＤＥＰ）、ジブチルフタレート（ＤＢＰ）、ジヘプチルフタレート（ＤＨＰ）、ジオクチルフタレート（ＤｎＯＰ）、ジオクチルデシルフタレート（ＤＯＤＰ）、ジイソデシルフタレート（ＤＩＤＰ）、ジウンデシルフタレート（ＤＵＰ）、ジトリデシルフタレート（ＤＴＤＰ）、ジ2-エチルヘキシルフタレート（ＤＯＰ）、ジ2-エチルヘキシルイソフタレート（ＤＯＩＰ）、ジ2-エチルヘキシルテレフタレート（ＤＯＴＰ）、ブチルベンジルフタレート（ＢＢＰ）、トリス（β−クロロエチル）フタレート（ＴＣＥＰ）オクチルベンジルフタレート（ＯＢＰ）などのフタル酸系可塑剤、トリクレジルホスフェート（ＴＣＰ）、クレジルジフェニルホスフェート（ＣＤＰ）、2-エチルヘキシルジフェニルホスフェート（ＯＤＰ）、トリブチルホスフェート（ＴＢＰ）、トリ2-エチルヘキシルホスフェート（ＴＯＰ）、トリフェニルホスフェート（ＴＰＰ）などのリン酸系可塑剤、オレイン酸ブチルなどの脂肪族一塩基酸エステル、ジブチルアジペート（ＤＢＡ）、ジｎ−ヘキシルアジペート（ＤＨＡ）、ジ2-エチルヘキシルアジペート（ＤＯＡ）、ジイソ2-エチルヘキシルアジペート（ＤＩＯＡ）、ジｎ−オクチルアジペート（ＤｎＯＡ）、ジデシルアジペート（ＤＤＡ）、ジイソデシルアジペート（ＤＩＤＡ）、ｎ−オクチル・ｎ−デシルアジペート（ＮＯＤＡ）、ｎ−ヘプチル・ｎ−ノニルアジペート（ＮＨＮＡ）などのアジピン酸系可塑剤、ジブチルセバケート（ＤＢＳ）、ジオクチルセバケート（ＤＯＳ）、ジイソオクチルセバケート（ＤＩＯＳ）、ブチルベンジルセバケート（ＢＢＳ）などのセバシン酸系可塑剤、ジ2-エチルヘキシルアゼレート（ＤＯＺ）、ジヘキシルアゼレート（ＤＨＺ）、ジイソオクチルアゼレート（ＤＩＯＺ）などのアゼライン酸系可塑剤、トリエチルシトレート（ＴＥＣ）、アセチル・トリエチルシトレート（ＡＴＥＣ）、トリブチルシトレート（ＴＢＣ）、アセチル・トリブチルシトレート（ＡＴＢＣ）、アセチル・トリオクチルシトレート（ＡＴＯＣ）などのクエン酸系可塑剤、メチルフタリル・エチルグリコレート（ＭＰＥＧ）、エチルフタリル・エチルグリコレート（ＥＰＥＧ）、ブチルフタリル・ブチルグリコレート（ＢＰＢＧ）などのグリコール酸系可塑剤、トリオクチル・トリメリテート（ＴＯＴＭ）、トリｎ−オクチル・ｎ−デシルトリメリテート（ＮＯＤＴＭ）などのトリメリット酸系可塑剤、メチルアセチル・リシノレート（ＭＡＲ）、ブチルアセチル・リシノレート（ＢＡＲ）などのリシノール酸系可塑剤、ポリプロピレンアジペート（ＰＰＡ）、ポリプロピレンセバケート（ＰＰＳ）などのポリエステル系可塑剤、エポキシ化大豆油（ＥＳＢＯ）、エポキシ化アマニ油（ＥＸＬＯ）、エポキシブチルステアレート、エポキシオクチルステアレート（ＯＥＸＴ）などのエポキシ系可塑剤、塩素化パラフィン、塩素化ビフェニル、塩素化脂肪酸ポリエステルなどの塩素化系可塑剤、2-ニトロビフェニルなどを挙げることができる。 Examples of the plasticizer include dimethyl phthalate (DMP), diethyl phthalate (DEP), dibutyl phthalate (DBP), diheptyl phthalate (DHP), dioctyl phthalate (DnOP), dioctyl decyl phthalate (DODP), diisodecyl phthalate (DIDP), diun Decyl phthalate (DUP), ditridecyl phthalate (DTDP), di-2-ethylhexyl phthalate (DOP), di-2-ethylhexyl isophthalate (DOIP), di-2-ethylhexyl terephthalate (DOTP), butyl benzyl phthalate (BBP), tris ( Phthalic acid plasticizers such as β-chloroethyl) phthalate (TCEP) octylbenzyl phthalate (OBP), tricresyl phosphate (TCP), cresyl diphenyl phosphate (CDP) , Phosphate plasticizers such as 2-ethylhexyldiphenyl phosphate (ODP), tributyl phosphate (TBP), tri-2-ethylhexyl phosphate (TOP), triphenyl phosphate (TPP), and aliphatic monobasic esters such as butyl oleate Dibutyl adipate (DBA), di-n-hexyl adipate (DHA), di-2-ethylhexyl adipate (DOA), diiso-2-ethylhexyl adipate (DIOA), di-n-octyl adipate (DnOA), didecyl adipate (DDA), Adipic acid plasticizers such as diisodecyl adipate (DIDA), n-octyl / n-decyl adipate (NODA), n-heptyl / n-nonyl adipate (NHNA), dibutyl sebacate (DBS), dioctyl sebacate (DOS) Sebacic acid plasticizers such as diisooctyl sebacate (DIOS) and butylbenzyl sebacate (BBS), di-2-ethylhexyl azelate (DOZ), dihexyl azelate (DHZ), diisooctyl azelate (DIOS), etc. Such as azelaic acid plasticizer, triethyl citrate (TEC), acetyl triethyl citrate (ATEC), tributyl citrate (TBC), acetyl tributyl citrate (ATBC), acetyl trioctyl citrate (ATOC), etc. Citric acid plasticizers, glycolic acid plasticizers such as methylphthalyl ethyl glycolate (MPEG), ethylphthalyl ethyl glycolate (EPEG), butylphthalyl butyl glycolate (BPBG), trioctyl trimellitate (TOTM), Trimellitic acid plasticizers such as tri-n-octyl / n-decyl trimellitate (NODTM), ricinoleic acid plasticizers such as methylacetyl ricinolate (MAR) and butylacetyl ricinolate (BAR), polypropylene adipate (PPA) ), Polyester plasticizers such as polypropylene sebacate (PPS), epoxy plasticizers such as epoxidized soybean oil (ESBO), epoxidized linseed oil (EXLO), epoxybutyl stearate, epoxyoctyl stearate (OEXT), Examples include chlorinated plasticizers such as chlorinated paraffin, chlorinated biphenyl, and chlorinated fatty acid polyester, and 2-nitrobiphenyl.
基材も受けられたシリコーン層の反対面には、印刷適正を上げる処理をすることにより装飾用固定シートとして用いることができる。印刷適正は、基材の表面を改質して印刷インキやトナーの付着性を向上することによって与えられる。また、基材の表面に親水性ポリマー層または多孔質の微粒子を配合した親水性ポリマー層を形成することにより、インクジェット用インクの受容性が高められる。得られた固定シートは、印刷またはコピーの内容により、ポスターその他の広告媒体としてウインドーガラスへの表示、建物の壁や掲示板に、また会議資料や連絡、通達の手段としてホワイトボードや壁、掲示板に貼着して利用することができる。 The opposite surface of the silicone layer that has also received the substrate can be used as a decorative fixing sheet by subjecting it to a process for increasing printing suitability. Printability is given by modifying the surface of the substrate to improve the adhesion of printing ink and toner. Further, by forming a hydrophilic polymer layer or a hydrophilic polymer layer in which porous fine particles are blended on the surface of the substrate, the acceptability of the inkjet ink is enhanced. The obtained fixed sheet is printed or copied, displayed on a window glass as a poster or other advertising medium, on the wall or bulletin board of a building, or on a white board, wall or bulletin board as a means of meeting materials, communication or notification. Can be used by sticking to.
本発明を下記の実施例によって、さらに具体的に説明する。
１．易接着層の形成
基材として片面に印刷適性処理を施した厚さ５０μｍのポリエステルフィルムの他の面に、下記の配合にて調合した塗液を、デスパーにて撹拌後、塗工、乾燥させ、厚み０.３μｍの易接着層を形成した。
ポリエステル樹脂（東洋紡績製バイロン200、Ｔｇ６７℃）１２重量部、 トルエン８８重量部
The present invention will be described more specifically with reference to the following examples.
1. On the other side of the 50 μm thick polyester film with printability treatment on one side as the base material for the easy-adhesion layer, the coating solution prepared with the following composition was stirred with a desper and then coated and dried. An easy adhesion layer having a thickness of 0.3 μm was formed.
12 parts by weight of polyester resin (Toyobo's Byron 200, Tg 67 ° C), 88 parts by weight of toluene
２．シリコーン層の形成
易接着層の上に、下記のシリコーン塗液を塗布し、１５０℃の乾燥炉にて１００秒加熱して、厚み２５μｍのシリコーン層を形成して、固定シートを得た。
両末端のみビニル基を有する直鎖状ポリオルガノシリコーン １００重量部
(無溶剤型)(商品名「Ｘ-６２−１３４７」信越化学工業(株)製)
白金触媒 (商品名「ＣＡＴ−ＰＬ−５６」信越化学工業(株)製) ２重量部
2. Formation of a silicone layer The following silicone coating solution was applied on the easy-adhesion layer and heated for 100 seconds in a drying oven at 150 ° C. to form a silicone layer having a thickness of 25 μm to obtain a fixed sheet.
100 parts by weight of linear polyorganosilicone having vinyl groups only at both ends
(Solventless type) (trade name "X-62-1347" manufactured by Shin-Etsu Chemical Co., Ltd.)
Platinum catalyst (trade name “CAT-PL-56” manufactured by Shin-Etsu Chemical Co., Ltd.) 2 parts by weight
３．オイル状物質層の形成
シリコーン層の上に、オイル状物質として表１の界面活性剤をトルエン中に希釈して、含有量が１重量％の塗工液を用意する。塗工液を塗布乾燥し、塗布量が０．０５ｇ／ｍ２になるようにオイル状物質層を形成した。
3. Formation of oily substance layer
On the silicone layer, the surfactant in Table 1 as an oily substance is diluted in toluene to prepare a coating solution having a content of 1% by weight. The coating liquid was applied and dried, and an oily substance layer was formed so that the coating amount was 0.05 g / m 2 .
４．セパレータの貼り合わせ
固定シートのシリコーン層面にセパレータとして厚さ５０μｍのポリエステルフィルムを貼り合わせて６０℃の温度で７２時間処理して、オイル状物質層を均して実施例１〜７の固定シートを作成した。
4). A polyester film having a thickness of 50 μm is bonded to the silicone layer surface of the separator fixing sheet as a separator and treated at a temperature of 60 ° C. for 72 hours, and the oily substance layer is leveled to obtain the fixing sheets of Examples 1 to 7. Created.
５．糊残り評価
被着体として、厚み１．３ｍｍ、５０×７５ｍｍのサイズのソーダ石灰ガラスを用いた。被着体に表１の実施例１〜６、参考例７、比較例１の固定シートをガラスのサイズにカットして貼り付けた。貼り付けたものを、スガ試験製紫外線フェードメーターで５０時間、紫外線を照射した。その後固定シートをガラスより剥がして糊残りを調べた。糊残りの結果は、表１の通りである。実施例のいずれのサンプルも糊残りは見られなかった。また、紫外線照射後の実施例の各サンプルは、貼ったり剥がしたりの作業は紫外線照射前と同じように容易に剥がれ固着できるものであった。
5). As the adhesive residue evaluation adherend, soda-lime glass having a thickness of 1.3 mm and a size of 50 × 75 mm was used. The fixing sheets of Examples 1 to 6, Reference Example 7 and Comparative Example 1 in Table 1 were cut into a glass size and attached to the adherend. The pasted material was irradiated with ultraviolet rays for 50 hours with an ultraviolet fade meter manufactured by Suga Test. Thereafter, the fixed sheet was peeled off from the glass and the adhesive residue was examined. The results of the adhesive residue are as shown in Table 1. No adhesive residue was found in any of the examples. Moreover, each sample of the Example after ultraviolet irradiation was able to be easily peeled off and fixed in the same manner as before ultraviolet irradiation in the operation of pasting and peeling.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006041751A JP4505646B2 (en) | 2006-02-20 | 2006-02-20 | Fixed sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006041751A JP4505646B2 (en) | 2006-02-20 | 2006-02-20 | Fixed sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007216589A JP2007216589A (en) | 2007-08-30 |
| JP4505646B2 true JP4505646B2 (en) | 2010-07-21 |
Family
ID=38494363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006041751A Active JP4505646B2 (en) | 2006-02-20 | 2006-02-20 | Fixed sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4505646B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6252490B2 (en) * | 2012-12-28 | 2017-12-27 | 旭硝子株式会社 | GLASS LAMINATE, PROCESS FOR PRODUCING THE SAME, AND SUPPORT SUBSTRATE WITH SILICONE RESIN LAYER |
Citations (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5411119A (en) * | 1977-06-28 | 1979-01-27 | Asahi Glass Co Ltd | Method of making laminated glass |
| JPS5538841A (en) * | 1978-09-12 | 1980-03-18 | Hitachi Chem Co Ltd | Surface protective film |
| JPS58101177A (en) * | 1981-12-14 | 1983-06-16 | Modern Plast Kogyo Kk | Method for improving moisture-resistant adhesivity of pressure-sensitive adhesive sheet for laminating on window pane |
| JPH06171212A (en) * | 1992-12-03 | 1994-06-21 | Mitsubishi Paper Mills Ltd | Pressure sensitive recording sheet |
| JPH06271821A (en) * | 1993-03-23 | 1994-09-27 | Lintec Corp | Removable type tacky protecting tape |
| JPH0858229A (en) * | 1994-08-23 | 1996-03-05 | Mitsubishi Paper Mills Ltd | Lamination type pressure-sensitive recording sheet and production thereof |
| JPH08245377A (en) * | 1995-03-15 | 1996-09-24 | Yamanouchi Pharmaceut Co Ltd | Pharmaceutical preparation for percutaneous absorption |
| JPH1067971A (en) * | 1996-08-28 | 1998-03-10 | Canon Inc | Dicing tape |
| JPH1129753A (en) * | 1997-07-09 | 1999-02-02 | Oji Paper Co Ltd | Pressure-sensitive adhesive sheet |
| JPH11256115A (en) * | 1998-03-13 | 1999-09-21 | Teijin Ltd | Surface-protective film |
| JP2000026817A (en) * | 1998-07-14 | 2000-01-25 | Teijin Ltd | Surface-protective film |
| JP2000044921A (en) * | 1998-08-04 | 2000-02-15 | Dow Corning Toray Silicone Co Ltd | Suspension-type silicone adhesive, preparation thereof and preparation of adhesive substrate |
| JP2001247695A (en) * | 2000-03-06 | 2001-09-11 | Toshihiko Sato | Method of manufacturing sanitary product packaging material |
| JP2001354939A (en) * | 2000-06-14 | 2001-12-25 | Shin Etsu Chem Co Ltd | Silicone pressure-sensitive adhesive composition |
| JP2003096429A (en) * | 2001-09-25 | 2003-04-03 | Shin Etsu Chem Co Ltd | Silicone adhesive composition and adhesive tape |
| JP2003320631A (en) * | 2002-05-08 | 2003-11-11 | Fujimori Kogyo Co Ltd | Surface protective film and laminate using the same |
| JP2004059800A (en) * | 2002-07-30 | 2004-02-26 | Fujicopian Co Ltd | Fixed sheet for decoration |
| JP2004190013A (en) * | 2002-11-28 | 2004-07-08 | Shin Etsu Chem Co Ltd | Silicone pressure-sensitive adhesive composition and pressure-sensitive adhesive tape |
| JP2004338123A (en) * | 2003-05-13 | 2004-12-02 | Fujicopian Co Ltd | Fixing sheet for inkjet recording |
| JP2005142401A (en) * | 2003-11-07 | 2005-06-02 | Tomoegawa Paper Co Ltd | Semiconductor device, its manufacturing method, and adhesive sheet for manufacturing same |
| JP2005238651A (en) * | 2004-02-26 | 2005-09-08 | Nitto Denko Corp | Antistatic adhesion type optical film and image display |
| JP2005534904A (en) * | 2002-07-30 | 2005-11-17 | イクスパル フィジィオン ベスローテン フェンノートシャップ | Analysis system and method for analyzing and controlling glass manufacturing processes |
| JP2006016555A (en) * | 2004-07-02 | 2006-01-19 | Dow Corning Toray Co Ltd | Silicone-based pressure-sensitive adhesive and adhesive tape |
| JP2006509062A (en) * | 2002-12-04 | 2006-03-16 | テサ・アクチエンゲゼルシヤフト | Antistatic pressure sensitive adhesive strip |
| JP2006514977A (en) * | 2003-04-14 | 2006-05-18 | エルテーエス ローマン テラピー−ジステーメ アーゲー | Therapeutic patch having a polysiloxane matrix containing capsaicin |
-
2006
- 2006-02-20 JP JP2006041751A patent/JP4505646B2/en active Active
Patent Citations (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5411119A (en) * | 1977-06-28 | 1979-01-27 | Asahi Glass Co Ltd | Method of making laminated glass |
| JPS5538841A (en) * | 1978-09-12 | 1980-03-18 | Hitachi Chem Co Ltd | Surface protective film |
| JPS58101177A (en) * | 1981-12-14 | 1983-06-16 | Modern Plast Kogyo Kk | Method for improving moisture-resistant adhesivity of pressure-sensitive adhesive sheet for laminating on window pane |
| JPH06171212A (en) * | 1992-12-03 | 1994-06-21 | Mitsubishi Paper Mills Ltd | Pressure sensitive recording sheet |
| JPH06271821A (en) * | 1993-03-23 | 1994-09-27 | Lintec Corp | Removable type tacky protecting tape |
| JPH0858229A (en) * | 1994-08-23 | 1996-03-05 | Mitsubishi Paper Mills Ltd | Lamination type pressure-sensitive recording sheet and production thereof |
| JPH08245377A (en) * | 1995-03-15 | 1996-09-24 | Yamanouchi Pharmaceut Co Ltd | Pharmaceutical preparation for percutaneous absorption |
| JPH1067971A (en) * | 1996-08-28 | 1998-03-10 | Canon Inc | Dicing tape |
| JPH1129753A (en) * | 1997-07-09 | 1999-02-02 | Oji Paper Co Ltd | Pressure-sensitive adhesive sheet |
| JPH11256115A (en) * | 1998-03-13 | 1999-09-21 | Teijin Ltd | Surface-protective film |
| JP2000026817A (en) * | 1998-07-14 | 2000-01-25 | Teijin Ltd | Surface-protective film |
| JP2000044921A (en) * | 1998-08-04 | 2000-02-15 | Dow Corning Toray Silicone Co Ltd | Suspension-type silicone adhesive, preparation thereof and preparation of adhesive substrate |
| JP2001247695A (en) * | 2000-03-06 | 2001-09-11 | Toshihiko Sato | Method of manufacturing sanitary product packaging material |
| JP2001354939A (en) * | 2000-06-14 | 2001-12-25 | Shin Etsu Chem Co Ltd | Silicone pressure-sensitive adhesive composition |
| JP2003096429A (en) * | 2001-09-25 | 2003-04-03 | Shin Etsu Chem Co Ltd | Silicone adhesive composition and adhesive tape |
| JP2003320631A (en) * | 2002-05-08 | 2003-11-11 | Fujimori Kogyo Co Ltd | Surface protective film and laminate using the same |
| JP2004059800A (en) * | 2002-07-30 | 2004-02-26 | Fujicopian Co Ltd | Fixed sheet for decoration |
| JP2005534904A (en) * | 2002-07-30 | 2005-11-17 | イクスパル フィジィオン ベスローテン フェンノートシャップ | Analysis system and method for analyzing and controlling glass manufacturing processes |
| JP2004190013A (en) * | 2002-11-28 | 2004-07-08 | Shin Etsu Chem Co Ltd | Silicone pressure-sensitive adhesive composition and pressure-sensitive adhesive tape |
| JP2006509062A (en) * | 2002-12-04 | 2006-03-16 | テサ・アクチエンゲゼルシヤフト | Antistatic pressure sensitive adhesive strip |
| JP2006514977A (en) * | 2003-04-14 | 2006-05-18 | エルテーエス ローマン テラピー−ジステーメ アーゲー | Therapeutic patch having a polysiloxane matrix containing capsaicin |
| JP2004338123A (en) * | 2003-05-13 | 2004-12-02 | Fujicopian Co Ltd | Fixing sheet for inkjet recording |
| JP2005142401A (en) * | 2003-11-07 | 2005-06-02 | Tomoegawa Paper Co Ltd | Semiconductor device, its manufacturing method, and adhesive sheet for manufacturing same |
| JP2005238651A (en) * | 2004-02-26 | 2005-09-08 | Nitto Denko Corp | Antistatic adhesion type optical film and image display |
| JP2006016555A (en) * | 2004-07-02 | 2006-01-19 | Dow Corning Toray Co Ltd | Silicone-based pressure-sensitive adhesive and adhesive tape |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007216589A (en) | 2007-08-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP7174696B2 (en) | Pressure-sensitive adhesive layer-forming organopolysiloxane composition and use thereof | |
| US11987731B2 (en) | Organopolysiloxane composition for forming pressure sensitive adhesive layer, and use of same | |
| CN104946194A (en) | Silicone adhesive composition, method for making the same and adhesive film | |
| CA1298566C (en) | Radiation grafting of organopolysiloxanes | |
| JP5049144B2 (en) | Image display device manufacturing method, and image display device manufactured using the manufacturing method | |
| JP7469232B2 (en) | Silicone pressure sensitive adhesive composition and its uses | |
| KR102532824B1 (en) | Pressure-sensitive adhesive layer-forming organopolysiloxane composition and use thereof | |
| TW201139590A (en) | Re-adherable silicone-based adhesive composition, sheet-shaped base material having re-adherable adhesive layer obtained by curing said composition, and use of said base material as protective film or affixing sheet | |
| KR20070004584A (en) | A composition having improved adherence with addition-curable material, and composite article incorporating the composition | |
| FI110189B (en) | Silicone emulsion composition for surface release treatment | |
| TWI383030B (en) | Silicone-free adhesive composition without aromatic solvent and adhesive tape, sheet or label | |
| US20170355878A9 (en) | Silicone release coating composition and low release force emulsion silicone release coating for films and papers having cured release coating | |
| JP7121726B2 (en) | Cure-reactive organopolysiloxane composition, pressure-sensitive adhesive composition using same, and use thereof | |
| JP7237854B2 (en) | Solvent-type curable organopolysiloxane composition, release sheet and method for producing the same | |
| KR102525733B1 (en) | Pressure-sensitive adhesive layer-forming organopolysiloxane composition and use thereof | |
| JP2005506437A (en) | For example, a liquid silicone formulation for forming a water repellent and peelable crosslinked elastomeric coating on a solid support formed from paper | |
| CN101932638B (en) | Silicone-self-adhesives, method for the production thereof, complexes using same and uses | |
| JP4505646B2 (en) | Fixed sheet | |
| JP4505644B2 (en) | Fixed sheet | |
| KR102639595B1 (en) | Laminated films, release films and laminates | |
| KR101358511B1 (en) | Adhesive functional film | |
| JP4505645B2 (en) | Affixing the fixed sheet | |
| JP2007217617A (en) | Separator for firmly-attached sheet | |
| CA1226387A (en) | Bonding surfaces with permanent-bond adhesive | |
| JP4505642B2 (en) | Attaching sheet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20090108 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100114 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100308 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20100330 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20100408 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130514 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 Ref document number: 4505646 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130514 Year of fee payment: 3 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140514 Year of fee payment: 4 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |