JP4328803B2 - 燃料電池の内部におけるゼーベック効果の利用による電気のコージェネレーション - Google Patents
燃料電池の内部におけるゼーベック効果の利用による電気のコージェネレーション Download PDFInfo
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- JP4328803B2 JP4328803B2 JP2006516292A JP2006516292A JP4328803B2 JP 4328803 B2 JP4328803 B2 JP 4328803B2 JP 2006516292 A JP2006516292 A JP 2006516292A JP 2006516292 A JP2006516292 A JP 2006516292A JP 4328803 B2 JP4328803 B2 JP 4328803B2
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- Prior art keywords
- fuel cell
- basic
- conductor
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- internal conduit
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- Expired - Fee Related
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- 239000000446 fuel Substances 0.000 title claims abstract description 48
- 230000005678 Seebeck effect Effects 0.000 title claims description 3
- 230000005611 electricity Effects 0.000 title description 3
- 239000004020 conductor Substances 0.000 claims abstract description 41
- 238000002485 combustion reaction Methods 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 31
- 239000004065 semiconductor Substances 0.000 claims description 17
- 239000002826 coolant Substances 0.000 claims description 16
- 238000001816 cooling Methods 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910000927 Ge alloy Inorganic materials 0.000 claims description 6
- 229910000676 Si alloy Inorganic materials 0.000 claims description 6
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 3
- 238000011084 recovery Methods 0.000 claims 1
- 239000012809 cooling fluid Substances 0.000 abstract 1
- 239000012528 membrane Substances 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000002775 capsule Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04067—Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
- H10N10/80—Constructional details
- H10N10/85—Thermoelectric active materials
- H10N10/851—Thermoelectric active materials comprising inorganic compositions
- H10N10/855—Thermoelectric active materials comprising inorganic compositions comprising compounds containing boron, carbon, oxygen or nitrogen
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
- H10N10/10—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects
- H10N10/13—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects characterised by the heat-exchanging means at the junction
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1007—Fuel cells with solid electrolytes with both reactants being gaseous or vaporised
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Fuel Cell (AREA)
- Hybrid Cells (AREA)
- Secondary Cells (AREA)
Description
Claims (9)
- 熱源を構成し、対向して配置された、燃焼による発熱反応のための、少なくとも2つの基本セル(2)(3)と、冷源を構成する冷却液(12)の循環のために、上記基本セルの間に形成された内部導管(11)とを含んでなる燃料電池において、
それぞれが、P型の半導体材料、N型の半導体材料からなる2つの伝導体材料(14)(15)の素子の対を有する、複数の熱電モジュール(13)を有し、各上記対の各素子の第1端部は上記熱源または上記冷源と熱的に接触し、上記対の各素子の第2端部は、上記第1端部が接触しない方の上記冷源または上記熱源と熱的に接触し、隣接する熱電モジュールは電気的に接続され、
上記内部導管(11)が2枚の板(18)によって構成され、上記伝導体材料(14)(15)の端部の一方で、上記熱電モジュール(13)を構成する素子の対が、接続導体(16)を介して、上記基本セル(2)(3)または上記板(18)と熱的に接続され、上記伝導体材料(14)(15)の端部の他方で、隣接する上記熱電モジュール(13)の素子同士が、接続導体(17)を介して、上記基本セル(2)(3)または上記板(18)と熱的に接続されていることを特徴とする、燃料電池。 - 上記基本セル(2)(3)内を酸素(8)および水素(10)が流れ、上記酸素(8)、上記水素(10)および上記冷却液(12)が流れる方向が同じであることを特徴とする、請求項1に記載の燃料電池。
- 上記N型の半導体は、リンをドーピングされたシリコンとゲルマニウムの合金であり、上記P型の半導体は、ホウ素をドーピングされたシリコンとゲルマニウムの合金であることを特徴とする、請求項1または2に記載の燃料電池。
- 上記伝導体材料の端部を接続する上記接続導体(16)(17)は、モリブデンの電極から構成されることを特徴とする、請求項1、2または3に記載の燃料電池。
- 第1の上記基本セル(2)と上記内部導管(11)との間に配置された一連の上記熱電モジュールのうちの最後に電気的に接続された熱電モジュールは、第2の上記基本セル(3)と上記内部導管(11)との間に配置された一連の上記熱電モジュールのうちの最初に電気的に接続された熱電モジュールと、電気的に直列に接続されることを特徴とする、請求項1〜4のいずれか1つに記載の燃料電池。
- 上記板(18)の内面にフィン(19)が設けられたことを特徴とする、請求項1〜5のいずれか1つに記載の燃料電池。
- 熱源を構成し、対向して配置された、燃焼による発熱反応のための、少なくとも2つの基本セル(2)(3)と、冷源を構成する冷却液(12)の循環のために、上記基本セルの間に形成された内部導管(11)とを含んでなる燃料電池から発生する熱エネルギの一部分の回収方法において、
それぞれが、P型の半導体材料、N型の半導体材料からなる2つの伝導体材料(14)(15)の素子の対を有する、複数の熱電モジュール(13)を設け、各上記対の各素子の第1端部を上記熱源または上記冷源と熱的に接触させ、上記対の各素子の第2端部を、上記第1端部が接触しない方の上記冷源または上記熱源と熱的に接触させ、隣接する熱電モジュールを電気的に接続し、
上記内部導管(11)を2枚の板(18)によって構成し、上記伝導体材料(14)(15)の端部の一方で、上記熱電モジュール(13)を構成する素子の対が、接続導体(16)を介して、上記基本セル(2)(3)または上記板(18)と熱的に接続し、上記伝導体材料(14)(15)の端部の他方で、隣接する上記熱電モジュール(13)の素子同士が、接続導体(17)を介して、上記基本セル(2)(3)または上記板(18)と熱的に接続し、ゼーベック効果によって発生される電気エネルギを回収することを特徴とする、燃料電池から発生する熱エネルギの回収方法。 - 上記基本セル(2)(3)内を流れる酸素(8)および水素(10)ならびに上記冷却液(12)が流れる方向を同じにすることを特徴とする、請求項7に記載の燃料電池から発生する熱エネルギの回収方法。
- 上記燃料電池の冷却は、2相冷却であることを特徴とする、請求項7または8に記載の燃料電池から発生する熱エネルギの回収方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0307187A FR2856198B1 (fr) | 2003-06-16 | 2003-06-16 | Cogeneration d'electricite par utilisation de l'effet seebeck a l'interieur d'une pile a combustible |
PCT/FR2004/001480 WO2005004263A2 (fr) | 2003-06-16 | 2004-06-14 | Cogeneration d’electricite par utilisation de l’effet seebeck a l’interieur d’une pile a combustible |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006527905A JP2006527905A (ja) | 2006-12-07 |
JP4328803B2 true JP4328803B2 (ja) | 2009-09-09 |
Family
ID=33484446
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006516292A Expired - Fee Related JP4328803B2 (ja) | 2003-06-16 | 2004-06-14 | 燃料電池の内部におけるゼーベック効果の利用による電気のコージェネレーション |
Country Status (8)
Country | Link |
---|---|
US (1) | US20060216559A1 (ja) |
EP (1) | EP1668726B1 (ja) |
JP (1) | JP4328803B2 (ja) |
AT (1) | ATE484855T1 (ja) |
CA (1) | CA2529224C (ja) |
DE (1) | DE602004029593D1 (ja) |
FR (1) | FR2856198B1 (ja) |
WO (1) | WO2005004263A2 (ja) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007200710A (ja) * | 2006-01-26 | 2007-08-09 | Nippon Oil Corp | 固体酸化物形燃料電池スタック |
JP5128777B2 (ja) * | 2006-02-27 | 2013-01-23 | 株式会社アツミテック | 発電装置 |
GB0608345D0 (en) | 2006-04-27 | 2006-06-07 | Univ Warwick | Implant |
KR100645594B1 (ko) * | 2006-07-12 | 2006-11-15 | 한국에너지기술연구원 | 연료전지 성능 평가용 셀 또는 스택 및 연료전지 성능 평가방법 |
JPWO2008020502A1 (ja) * | 2006-08-18 | 2010-01-07 | 株式会社アツミテック | 車両の駆動装置 |
JP2008140611A (ja) * | 2006-11-30 | 2008-06-19 | Suzuki Motor Corp | 車両用燃料電池システムの温度制御装置 |
JP5106944B2 (ja) | 2007-08-06 | 2012-12-26 | 株式会社アツミテック | 発電装置 |
US8924056B2 (en) * | 2009-10-07 | 2014-12-30 | Ford Global Technologies, Llc | System and method for balancing a storage battery for an automotive vehicle |
US8822096B2 (en) | 2010-12-09 | 2014-09-02 | Blackberry Limited | Fuel cell electrical power source for a portable electronic device with thermoelectric module |
SK50222011A3 (sk) | 2011-04-21 | 2014-07-02 | PROGRESSIVE SOLUTIONS & UPGRADES s.r.o. | Kombinovaný magnetohydrodynamický a elektrochemický spôsob výroby, najmä elektrickej energie a zariadenie |
JP5977117B2 (ja) * | 2012-08-28 | 2016-08-24 | 住友理工株式会社 | 車両用防音カバー |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1539333B1 (de) * | 1967-04-01 | 1970-06-04 | Siemens Ag | Thermoelektrische Anordnung und Verfahren zu ihrer Herstellung |
US3964930A (en) * | 1975-07-21 | 1976-06-22 | United Technologies Corporation | Fuel cell cooling system |
JPH10163538A (ja) * | 1996-12-04 | 1998-06-19 | Ngk Insulators Ltd | 熱交換器用熱電変換装置 |
DE19825872C1 (de) * | 1998-06-10 | 1999-10-07 | Forschungszentrum Juelich Gmbh | Brennstoffzelle mit thermoelektrischen Elementen |
US6096964A (en) * | 1998-11-13 | 2000-08-01 | Hi-Z Technology, Inc. | Quantum well thermoelectric material on thin flexible substrate |
JP2002141077A (ja) * | 2000-11-06 | 2002-05-17 | Sony Corp | 固体高分子電解質型燃料電池及び燃料電池スタック |
JP2002238272A (ja) * | 2001-02-06 | 2002-08-23 | Tokyo Gas Co Ltd | 高温排熱利用発電装置 |
JP2003086223A (ja) * | 2001-09-10 | 2003-03-20 | Nippon Steel Corp | 固体電解質型燃料電池と熱電発電装置とのコンバインドシステム |
US7625647B2 (en) * | 2002-12-09 | 2009-12-01 | Gm Global Technology Operations, Inc. | Fuel cell system with integrated thermal-to-electric generating devices |
-
2003
- 2003-06-16 FR FR0307187A patent/FR2856198B1/fr not_active Expired - Fee Related
-
2004
- 2004-06-14 US US10/560,822 patent/US20060216559A1/en not_active Abandoned
- 2004-06-14 AT AT04767343T patent/ATE484855T1/de not_active IP Right Cessation
- 2004-06-14 JP JP2006516292A patent/JP4328803B2/ja not_active Expired - Fee Related
- 2004-06-14 CA CA2529224A patent/CA2529224C/en not_active Expired - Fee Related
- 2004-06-14 EP EP04767343A patent/EP1668726B1/fr not_active Expired - Lifetime
- 2004-06-14 DE DE602004029593T patent/DE602004029593D1/de not_active Expired - Lifetime
- 2004-06-14 WO PCT/FR2004/001480 patent/WO2005004263A2/fr active Application Filing
Also Published As
Publication number | Publication date |
---|---|
EP1668726A2 (fr) | 2006-06-14 |
FR2856198B1 (fr) | 2005-12-16 |
EP1668726B1 (fr) | 2010-10-13 |
WO2005004263A2 (fr) | 2005-01-13 |
DE602004029593D1 (de) | 2010-11-25 |
JP2006527905A (ja) | 2006-12-07 |
CA2529224C (en) | 2013-05-14 |
WO2005004263A3 (fr) | 2006-04-27 |
CA2529224A1 (en) | 2005-01-13 |
FR2856198A1 (fr) | 2004-12-17 |
ATE484855T1 (de) | 2010-10-15 |
US20060216559A1 (en) | 2006-09-28 |
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R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
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LAPS | Cancellation because of no payment of annual fees |