JP4243482B2 - リン含有難燃剤およびそれを含有する難燃性熱可塑性組成物 - Google Patents
リン含有難燃剤およびそれを含有する難燃性熱可塑性組成物 Download PDFInfo
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- JP4243482B2 JP4243482B2 JP2002556195A JP2002556195A JP4243482B2 JP 4243482 B2 JP4243482 B2 JP 4243482B2 JP 2002556195 A JP2002556195 A JP 2002556195A JP 2002556195 A JP2002556195 A JP 2002556195A JP 4243482 B2 JP4243482 B2 JP 4243482B2
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- 150000002366 halogen compounds Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- OHMBHFSEKCCCBW-UHFFFAOYSA-N hexane-2,5-diol Chemical compound CC(O)CCC(C)O OHMBHFSEKCCCBW-UHFFFAOYSA-N 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- GBHRVZIGDIUCJB-UHFFFAOYSA-N hydrogenphosphite Chemical class OP([O-])[O-] GBHRVZIGDIUCJB-UHFFFAOYSA-N 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 230000005660 hydrophilic surface Effects 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910001853 inorganic hydroxide Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- AKIDPNOWIHDLBQ-UHFFFAOYSA-N naphthalene-1,4,5,8-tetracarbonyl chloride Chemical compound C1=CC(C(Cl)=O)=C2C(C(=O)Cl)=CC=C(C(Cl)=O)C2=C1C(Cl)=O AKIDPNOWIHDLBQ-UHFFFAOYSA-N 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- XRVCFZPJAHWYTB-UHFFFAOYSA-N prenderol Chemical compound CCC(CC)(CO)CO XRVCFZPJAHWYTB-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000000384 rearing effect Effects 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000008279 sol Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 229910052950 sphalerite Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/12—Esters of phosphoric acids with hydroxyaryl compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- General Health & Medical Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Nanotechnology (AREA)
- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Fireproofing Substances (AREA)
Description
本発明によれば、成分Aにとって好適な芳香族ポリカーボネートおよび/またはポリエステルカーボネートは、文献公知であるかまたは文献から公知の方法で製造され得る(芳香族ポリカーボネートの製造に関しては、例えば、シュネル(Schnell)著、「ケミストリー・アンド・フィジクス・オブ・ポリカーボネーツ(Chemistry and Physics of Polycarbonates)」、インターサイエンス・パブリッシャーズ、1964年および独国特許出願公開第AS1495626号明細書、独国特許発明第A2232877号明細書、同第A2703376号明細書、同第A2714544号明細書、同第A3000610号明細書および同第A3832396号明細書を参照し、芳香族ポリエステルカーボネートの製造に関しては、独国特許発明第A3077934号明細書を参照のこと)。
成分Bは、
B.1 少なくとも1種のビニルモノマー5〜95重量%、30〜90重量%の
B.2 ガラス転移温度10℃未満、好ましくは0℃未満、最も好ましくは−20℃未満の1種以上のグラフトベース95〜5重量%、好ましくは70〜10重量%への
1種以上のグラフトポリマーを包含する。
B.1.1 芳香族ビニル化合物および/または置換核を含有する芳香族ビニル化合物(例えば、スチレン、α-メチルスチレン、p-メチルスチレン、p-クロロスチレン)および/またはメタクリル酸のC1〜C8アルキルエステル(例えば、メチルメタクリレート、エチルメタクリレート)50〜99重量部と、
B.1.2 ビニルシアニド(アクリロニトリルおよびメタクリロニトリルのような不飽和ニトリル)および/または(メタ)アクリル酸のC1〜C8アルキルエステル(例えば、メチルメタクリレート、n-ブチルアクリレート、tert-ブチルアクリレート)および/または不飽和カルボン酸の(無水物およびイミドなどの)誘導体(例えば、無水マレイン酸およびN-フェニル-マレイミド)1〜50重量部と
の混合物である。
成分Cは、1種以上の熱可塑性ビニル(コ)ポリマーC.1および/またはポリアルキレンテレフタレートC.2を包含する。
C.1.1 芳香族ビニル化合物および/または置換核を含む芳香族ビニル化合物(例えば、スチレン、α-メチルスチレン、p-メチルスチレン、p-クロロスチレン)および/または(メタ)アクリル酸の(C1〜C8)アルキルエステル(例えば、メチルメタクリレートまたはエチルメタクリレート)50〜99重量部、好ましくは60〜80重量部と、
C.1.2 ビニルシアニド(不飽和ニトリル)(例えば、アクリロニトリルおよびメタクリロニトリル)および/または(メタ)アクリル酸の(C1〜C8)アルキルエステル(例えば、メチルメタクリレート、n-ブチルアクリレート、tert-ブチルアクリレート)および/または不飽和カルボン酸(例えば、マレイン酸)および/または不飽和カルボン酸の(無水物およびイミドなどの)誘導体(例えば、無水マレイン酸およびN-フェニルマレイミド)1〜50重量部、好ましくは20〜40重量部と
の(コ)ポリマーである。
成分Dは、非常に細かく粉砕された無機粉末を包含する。
本発明の難燃剤は、燃焼時に材料が燃焼滴として滴り落ちる傾向を低減する「滴り落ち防止剤(anti-dripping agents)」と呼ばれるものと組み合わせて使用されてよい。好適な滴り落ち防止剤の例としては、フッ素化ポリオレフィン、シリコーンおよびアラミド繊維を包含する物質の分類からの化合物が挙げられる。これは、本発明の組成物中でも使用され得る。フッ素化ポリオレフィンが、滴り落ち防止剤として好ましく使用される。
本発明の成形用組成物は、内部潤滑剤および離型剤(demoulding agents、例えば、ペンタエリスリトールテトラステアレート)、核形成剤、帯電防止剤、安定化剤、フィラーおよび強化剤(例えば、ガラスまたはカーボン繊維、タルク、珪灰石、マイカ、カオリン、CaCO3およびガラスフレーク)並びに着色剤および顔料などの少なくとも1種の汎用の添加物を含有していてもよい。
列車車両、船舶、航空機、バスおよび他の自動車車両のための内装用構成要素、自動車産業における外装車体パーツ、小型変圧器を含む電気機器のためのハウジング、情報処理および情報伝達用装置のためのハウジング、医療装置のためのハウジングおよびカバー、マッサージ装置およびそのためのハウジング、子供用のおもちゃの乗物、シート状の壁要素、安全装置のためのハウジング、断熱輸送容器、小動物を飼育または運搬するための装置、サニタリーおよび浴室部品のための成形品、排気口のためのカバー格子、庭建物のための成形品、およびガーデン備品のための道具小屋またはハウジング。
実施例1〜4は本発明の難燃剤の製造を表す。
以下の反応によって本発明のリン含有化合物を得た。
HPLC-MS: 純度:99%超の範囲
MS(ES+): 775(24)[MH+],792(100)[M++H2O]
P:元素分析: 7.9%(理論値8.0%)
DIN酸価: 0.25
融点: 89℃
以下の反応によって本発明のリン含有化合物を得た。
HPLC-MS: 純度:100%の範囲
MS(ES+): 733(100)[MH+]
P:元素分析: 8.0%(理論値8.4%)
DIN酸価: 0.76
以下の反応によって本発明のリン含有化合物を得た。
HPLC-MS: 純度:100%の範囲
MS(ES+): 747(100)[MH+]
P:元素分析: 8.0%(理論値8.3%)
DIN酸価: 0.54
以下の反応によって本発明のリン含有化合物を得た。
HPLC-MS: 純度:67%の範囲
MS(ES+): 787(100)[MH+]
P:元素分析: 7.9%(理論値7.9%)
DIN酸価: 0.27
HPLC−実施例1からの物質についてのHPLC測定は、シーティシー・アナリティクス(CTC Analytics)から供給されたHTS PALインジェクター付きAgilent1100クロマトグラフを用いて行った。分離は、InertsilODS-3固定相(長さ:250mm、内径2.1mm、粒径5μm)において、40℃および流速0.2mL/分で行った。液相は、A(水と0.01%蟻酸の混合液)とB(アセトニトリルと0.05%蟻酸の混合液)のグラジエントから構成し、0分ではBを5%、20分でBを100%まで傾斜増加させ、その後、30分においてB100%とした。UV測定はλ=214nmで行った。
実施例2〜4の物質の質量スペクトルは、(+)エレクトロスプレー付きWatersZMD2000分光光度計(spectrophometer)を用いて、m/z範囲110〜1500で測定した。
酸価(mgKOH/g)を以下の式から算出した。
bは、ブランク試験におけるKOHの消費量(mL)であり、
Eは、秤量した量(g)であり、および
5.61は、KOH溶液(mL、c(KOH)=0.1モル/L)をKOH(mg)に転化するための係数である。
熱可塑性ポリカーボネート成形用組成物1〜5(本発明)とV1およびV2(比較)は、実施例1〜4からのオリゴホスフェートおよび公知のオリゴホスフェートを用いて製造した。成形用組成物の組成を表1に示す。
表1中に示す成分(以降に詳細に説明する)を、3リットル内部ニーダーまたはZSK-25装置において240℃でコンパウンド化した。成形品は、Arburg270E射出成形機において240℃で製造した。
相対溶液粘度(溶媒としてのCH2Cl2中、25℃において濃度0.5g/100mLで測定したもの)1.24の、ビスフェノールA系直鎖ポリカーボネート。
相対溶液粘度(溶媒としてのCH2Cl2中、25℃において濃度0.5g/100mLで測定したもの)1.25の、ビスフェノールA系直鎖ポリカーボネート。
スチレンとアクリロニトリルの比73:27のコポリマー40重量部と、粒状架橋ポリブタジエンゴム(平均粒径d50=0.3μm)60重量部とから成り、エマルション重合によって製造されたグラフトポリマー。
スチレンとアクリロニトリルの比73:27のコポリマー84重量部と、架橋ポリブタジエンゴム16重量部とから成り、塊重合によって製造されたグラフトポリマー。
スチレンとアクリロニトリルの比72:28であり、限界粘度(ジメチルホルムアミド中、20℃で測定したもの)0.55dL/gのスチレン/アクリロニトリルコポリマー。
実施例1からのTMC-ビスフェノールジホスフェート。
実施例3からのメチルシクロヘキシル-ビスフェノールジホスフェート。
実施例2からのシクロヘキシル-ビスフェノールジホスフェート。
タルク:平均粒径1.2μmのNaintsch(登録商標)A3(ナインッシュ・ミネラルヴェルケ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング(Naintsch Mineralweke GmbH)、グラーツ、オーストリア国)。
平均粒径約50nmのPural(登録商標)200、ナノスケール水酸化アルミニウム[AlO(OH)](コンデア(Condea)、ハンブルグ、独国から供給されたもの)。
前記成分BのSANグラフトポリマーの水中エマルションと、テトラフルオロエチレンポリマーの水中エマルションとを含む凝集混合物としてのテトラフルオロエチレンポリマー。前記混合物中のグラフトポリマーBとテトラフルオロエチレンポリマーEとの重量比は、90重量%対10重量%であった。テトラフルオロエチレンポリマーエマルションは、固形分60重量%であり、平均粒径0.05〜0.5μmであった。SANグラフトポリマーエマルションは、固形分34重量%および平均ラテックス粒径d500.3μmであった。
テトラフルオロエチレンポリマー(テフロン(登録商標)30N)のエマルションを、SANグラフトポリマーBのエマルションと混合し、ポリマー固形分に対して1.8重量%のフェノール性酸化防止剤で安定化させた。この混合物を、85〜95℃においてMgSO4(エプソム塩)の水溶液と酢酸を用い、pH4〜5で凝集させ、濾過して、電解質が事実上無くなるまで洗浄した。その後、遠心分離によって水を全て遊離した後、100℃で乾燥させて粉末を形成した。
Blendex(登録商標)449:PTFE 50重量%およびSANコポリマー 50重量%を含有する、ジェネラル・エレクトリック・プラスティクス(General Electric Plastics)から供給されたPTFE製剤。
亜リン酸塩(phosphite)安定化剤。
離型剤(demoulding agent)としてのペンタエリスリトールテトラステアレート(PETS)。
熱変形耐性VicatBおよびHDT/Aはそれぞれ、DIN53460(ISO306)およびISO75に従って、寸法80mm×10mm×4mmのバーについて求めた。
ノッチ付きバー衝撃値akは、ISO180/1Aに従って求めた。
試料の火炎特性は、UL94Vに従って、厚さ1.6mmおよび3.2mmのバーについて測定した。
物質試料を、寸法127mm×12.7mm×1.6(3.2)mmのバーに成形した。このバーを、試験片の底部がワッディング(wadding)材料のストリップの305mm上に位置するように、垂直に固定した。各テストバーはそれぞれ、10秒間の2回連続の点火操作によって点火し、点火後毎に燃焼特性を観察した後、試料を評価した。高さ10mm(3.8インチ)の青色の炎のブンゼンバーナーを用いて試料を点火した。バーナーに供給されるガスは、熱量値3.73×104kJ/m3の天然ガスであった(1000BTU/立方フィート)。
Claims (10)
- 少なくとも1種の熱可塑性樹脂と、請求項1に記載のオリゴホスフェートとを含有する熱可塑性組成物。
- 熱可塑性樹脂が、ポリカーボネート、ポリエステルカーボネート、ポリフェニレンオキサイド、ポリエステル、ポリアミド、ポリエステルアミド、ビニル(コ)ポリマーおよびアクリル/ブタジエン/スチレン(ABS)コポリマーから選択される請求項2記載の熱可塑性組成物。
- ポリカーボネートを含有し、かつ少なくとも1種のビニルモノマー5〜95重量%の、ガラス転移温度が約10℃以下の少なくとも1種のグラフトベース95〜5重量%へのグラフトポリマーを該組成物の重量に対して50重量%まで含有する請求項2または3記載の熱可塑性組成物。
- グラフトポリマーが、ジエン系、EP(D)M系、アクリレート系またはシリコーンゴム系ポリマーである請求項4記載の熱可塑性組成物。
- エマルション重合もしくは塊重合されたABSまたはそれらの混合物をグラフトポリマーとして含有する請求項4または5記載の熱可塑性組成物。
- フッ素化ポリオレフィンを含有する請求項2〜6のいずれかに記載の熱可塑性組成物。
- ナノスケールの無機材料またはタルクを含有する請求項2〜7のいずれかに記載の熱可塑性組成物。
- 請求項2〜8のいずれかに記載の熱可塑性組成物を含有する成形用組成物。
- シーチング、部分品(section)、列車、船舶、航空機または道路車両(road vehicle)のための内装用部品、自動車のための車体パーツ、小型変圧器を含む電気機器のためのハウジング、情報処理および情報伝達用装置のためのハウジング、医療装置のためのハウジングまたはカバー、子供用のおもちゃの乗物、シート状の壁要素、安全装置のためのハウジング、断熱輸送容器、小動物を飼育または供給するための装置、サニタリーおよび浴室部品のための成形品、排気口のためのカバー格子、スラブ、パイプ、内装用および外部使用のための電気設備コンジェット、庭建物のための成形品、およびガーデン備品のための道具小屋またはハウジングの形態の請求項9記載の成形用組成物。
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DE10100591A DE10100591A1 (de) | 2001-01-09 | 2001-01-09 | Phosphorhaltiges Flammschutzmittel und Flammwidrige thermoplastische Formmassen |
PCT/EP2001/015350 WO2002055526A1 (de) | 2001-01-09 | 2001-12-28 | Phosphorhaltiges flammschutzmittel und flammwidrige thermoplastische formmassen |
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JP2004527474A JP2004527474A (ja) | 2004-09-09 |
JP2004527474A5 JP2004527474A5 (ja) | 2005-12-22 |
JP4243482B2 true JP4243482B2 (ja) | 2009-03-25 |
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EP (1) | EP1351965B1 (ja) |
JP (1) | JP4243482B2 (ja) |
KR (1) | KR100801836B1 (ja) |
CN (1) | CN1252077C (ja) |
AT (1) | ATE347559T1 (ja) |
BR (1) | BR0116727B1 (ja) |
CA (1) | CA2433727C (ja) |
DE (2) | DE10100591A1 (ja) |
ES (1) | ES2278815T3 (ja) |
MX (1) | MXPA03006125A (ja) |
RU (1) | RU2003124747A (ja) |
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US20100152348A1 (en) * | 2006-04-06 | 2010-06-17 | David Abecassis | Nanocompatibilized novel polymer blends |
US20080227899A1 (en) * | 2006-05-11 | 2008-09-18 | David Abecassis | Novel method for polymer RDP-clay nanocomposites and mechanisms for polymer/polymer blending |
US20080023679A1 (en) * | 2006-05-11 | 2008-01-31 | David Abecassis | Novel flame retardant nanoclay |
US20080317987A1 (en) * | 2006-07-21 | 2008-12-25 | David Abecassis | Nanocomposite materials for ethanol, methanol and hydrocarbon transportation use and storage |
US20080064798A1 (en) * | 2006-07-21 | 2008-03-13 | David Abecassis | Novel method for nanoclay particle dispersion |
US9127154B2 (en) * | 2006-10-13 | 2015-09-08 | Bayer Materialscience Llc | Impact resistant, flame retardant thermoplastic molding composition |
US8642700B2 (en) * | 2006-11-03 | 2014-02-04 | Bayer Materialscience Llc | Thermoplastic composition having low gloss and low temperature impact performance |
KR100773734B1 (ko) * | 2006-12-29 | 2007-11-09 | 제일모직주식회사 | 난연성이 우수한 열가소성 폴리에스테르 수지 조성물 |
EP2103000B1 (en) * | 2007-01-09 | 2018-08-22 | Nokia Technologies Oy | Power for uplink acknowledgment transmission |
WO2008115414A2 (en) * | 2007-03-15 | 2008-09-25 | Glen Burnie Technologies, L.L.C. | A novel method for producing an organoclay additive for use in polypropylene |
US20100029986A1 (en) * | 2007-10-19 | 2010-02-04 | David Abecassis | Novel amine functionalized carbon nanotube |
TWI385206B (zh) * | 2009-10-28 | 2013-02-11 | Taiwan Textile Res Inst | 無融滴阻燃母粒、用以製備該阻燃母粒的組成物與方法以及包含該阻燃母粒的阻燃物 |
TWI385205B (zh) * | 2009-10-28 | 2013-02-11 | Taiwan Textile Res Inst | 無鹵低磷阻燃母粒、用以製備該阻燃母粒的組成物與方法以及包含該阻燃母粒的阻燃物 |
BR112012014682A2 (pt) * | 2009-12-16 | 2016-04-05 | Basf Se | uso de um composto de fósforo, processo para fornecer retardância de chama a um material, composição polímerica, processo para a preparação de um polímero de estireno expansível, processo para a produção uma espuma de polímero de estireno extrusado, uso de uma composição polimérica livre de halogênio, e, composto de fósforo |
DE102010035103A1 (de) * | 2010-08-23 | 2012-02-23 | Catena Additives Gmbh & Co. Kg | Flammschutzmittelzusammensetzungen enthaltend Triazin-interkalierte Metall-Phosphate |
KR20130046974A (ko) * | 2011-10-28 | 2013-05-08 | 엘지이노텍 주식회사 | 광학 부재, 이를 포함하는 표시장치 및 이의 제조방법 |
CN105601996B (zh) * | 2016-02-04 | 2018-03-06 | 中国科学院宁波材料技术与工程研究所 | 一种化合物及应用了其的高分子材料 |
CN111788281A (zh) * | 2018-02-16 | 2020-10-16 | 大八化学工业株式会社 | 包含芳香族磷酸酯的阻燃剂和包含该阻燃剂的热塑性树脂组合物 |
WO2020031495A1 (ja) * | 2018-08-06 | 2020-02-13 | 大八化学工業株式会社 | 芳香族リン酸エステルを含む熱硬化性樹脂用難燃剤、それを含む熱硬化性樹脂組成物、その硬化物およびその用途 |
JP2020111668A (ja) * | 2019-01-11 | 2020-07-27 | 三菱エンジニアリングプラスチックス株式会社 | 難燃性ポリカーボネート樹脂組成物および成形品 |
JP7172905B2 (ja) * | 2019-07-30 | 2022-11-16 | 味の素株式会社 | エポキシ樹脂組成物、エポキシ樹脂組成物の硬化物、樹脂シート、プリント配線板及び半導体装置 |
KR20240017851A (ko) * | 2021-06-08 | 2024-02-08 | 파나소닉 아이피 매니지먼트 가부시키가이샤 | 수지 조성물, 프리프레그, 수지 부가 필름, 수지 부가 금속박, 금속 클래드 적층판, 및 배선판 |
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-
2001
- 2001-01-09 DE DE10100591A patent/DE10100591A1/de not_active Withdrawn
- 2001-12-28 KR KR1020037009111A patent/KR100801836B1/ko not_active IP Right Cessation
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- 2001-12-28 RU RU2003124747/04A patent/RU2003124747A/ru not_active Application Discontinuation
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Also Published As
Publication number | Publication date |
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CA2433727C (en) | 2010-08-24 |
US20020137821A1 (en) | 2002-09-26 |
WO2002055526A1 (de) | 2002-07-18 |
CN1252077C (zh) | 2006-04-19 |
US7019056B2 (en) | 2006-03-28 |
CA2433727A1 (en) | 2002-07-18 |
EP1351965A1 (de) | 2003-10-15 |
CN1486324A (zh) | 2004-03-31 |
EP1351965B1 (de) | 2006-12-06 |
DE10100591A1 (de) | 2002-07-11 |
JP2004527474A (ja) | 2004-09-09 |
ES2278815T3 (es) | 2007-08-16 |
ATE347559T1 (de) | 2006-12-15 |
KR100801836B1 (ko) | 2008-02-11 |
DE50111603D1 (de) | 2007-01-18 |
TW575619B (en) | 2004-02-11 |
KR20030077565A (ko) | 2003-10-01 |
BR0116727A (pt) | 2003-12-23 |
BR0116727B1 (pt) | 2012-09-18 |
MXPA03006125A (es) | 2004-05-04 |
RU2003124747A (ru) | 2005-01-10 |
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