JP3651643B2 - Mascara composition - Google Patents
Mascara composition Download PDFInfo
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- JP3651643B2 JP3651643B2 JP25777097A JP25777097A JP3651643B2 JP 3651643 B2 JP3651643 B2 JP 3651643B2 JP 25777097 A JP25777097 A JP 25777097A JP 25777097 A JP25777097 A JP 25777097A JP 3651643 B2 JP3651643 B2 JP 3651643B2
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- Prior art keywords
- polyethylene glycol
- red
- mascara
- powder
- mascara composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Description
【0001】
【発明の属する技術分野】
本発明は、高重合度ポリエチレングリコールを含有して成る、睫を濃く長く見せる効果に優れるマスカラ組成物に関する。
【0002】
【従来の技術】
マスカラは、睫を長く美しく見せるために用いられているメイクアップ化粧料の一種である。マスカラは目的に応じて、睫をカールする力の強いカールタイプ,睫を長く見せる効果の高いロングラッシュタイプ,睫のボリュームを向上させるボリュームタイプなどに分類される。睫の長さ,太さ,粗密の度合い,上を向いて生えているか下を向いて生えているか等の条件が人によりかなり異なるため、目的に応じてこれらのタイプのマスカラが別々に市販されている。これらのタイプの中でも、ボリュームタイプ及びロングラッシュタイプのマスカラは、睫の生え方が粗で短い人が多い日本人に一般的に好まれて使用されている。
【0003】
このようなボリュームタイプのマスカラでは、ボリュームを付与するためには一般的に、ワックスや脂肪酸,脂肪酸塩が用いられる。例えば、特開平6−9431号公報ではワックス粒子の水性分散物と少なくとも1種の水溶性皮膜形成性ポリマーと顔料とを含有して成るメーキャップ組成物が、特開平5−194148号公報では炭化水素ワックスと水溶性ポリマーを含有する睫及び(又は)眉のメイクアップ及び手入れのための組成物及びその製造方法がそれぞれ開示されている。
【0004】
また、睫を長く見せるためには、ナイロン等の短い繊維がしばしば用いられる。しかしながらナイロンなどの短い繊維をマスカラ組成物に配合した場合、繊維が睫からとれて目の中に入りやすく、特にコンタクトレンズ使用時には、目やレンズに傷が付くなどの問題点があった。
【0005】
さらに、睫のボリュームを向上させ、かつ長く見せるタイプのマスカラ組成物は得られていない。
【0006】
【発明が解決しようとする課題】
そこで本発明においては、睫にボリュームを付与し、かつ長く見せる効果に優れたマスカラ組成物を得ることを目的とした。
【0007】
【課題を解決するための手段】
本発明者等は上記課題を解決するため鋭意研究の結果、高重合度ポリエチレングリコールをマスカラ組成物に含有させることにより、睫にボリュームを付与し、かつ長く見せる効果に優れるマスカラ組成物を得ることができることを見いだし、本発明を完成した。
【0008】
【発明の実施の形態】
本発明で用いられる高重合度ポリエチレングリコールは、増粘効果を有する水溶性高分子であり、増粘剤,顔料分散剤として用いられている。かかる高重合度ポリエチレングリコールの化粧料への応用としては、ヒアルロン酸塩と併用した安定性,保湿性に優れた化粧料(特開昭63−156838号公報),糖アルキルと併用したシャンプー組成物(特開平5−43434号公報),高重合度ポリエチレングリコールを泡特性改善剤として含有する整髪料組成物(特開平6−9344号公報),架橋型アクリル酸ポリマーと併用した水性ゲル組成物(ヨーロッパ特許94−400760),ベタインと併用した毛髪化粧料(特開平7−69840号公報),アミン若しくはアミド型界面活性剤と併用した洗浄料(特開平8−157349号公報),界面活性剤,カチオンポリマーと併用したコンディショニングシャンプー組成物(特開平9−175952号公報)等が開示されている。しかしながら、高重合度ポリエチレングリコールが睫にボリュームを付与し、かつ長く見せる効果を有することは知られていなかった。
【0009】
本発明で用いられる高重合度ポリエチレングリコールは、分子量950以上のポリエチレングリコールであり、ボリューム感の点から分子量10000以上のポリエチレングリコールが好ましく用いられる。かかる高重合度ポリエチレングリコールとしては、市販のPolyox WSR N−10,N−30(分子量1万〜500万:以上Union Carbide社製),PEG−1000〜PEG−20000(分子量950〜25000:以上三洋化成工業社製)等を使用することができる。高重合度ポリエチレングリコールはマスカラ組成物に、0.01〜5重量%配合することができる。
【0010】
本発明においては、睫にボリューム感を付与する効果を顕著にするために、色材を配合することができる。かかる色材としては化粧料に一般に用いられる色材であれば良く、例えば、タルク,カオリン,雲母,セリサイト,合成雲母,バーミキュライト,炭酸マグネシウム,炭酸カルシウム,ケイ酸アルミニウム,ケイ酸バリウム,ケイ酸カルシウム,ケイ酸マグネシウム,ケイ酸ストロンチウム,無水ケイ酸,ゼオライト,硫酸バリウム,焼石膏,リン酸カルシウム,フッ素アパタイト,ヒドロキシアパタイト,セラミックパウダー,窒化ホウ素等の無機粉体、ミリスチン酸亜鉛,パルミチン酸カルシウム,ステアリン酸マグネシウム,ステアリン酸アルミニウム等の金属セッケン、ナイロン末,ポリエチレン末,ポリメタクリル酸メチル末,ポリスチレン末,スチレンアクリル酸共重合体末,セルロース末等の有機粉体、二酸化チタン,酸化亜鉛等の無機白色顔料、ベンガラ,チタン酸鉄,γ−酸化鉄,黄酸化鉄,黄土,黒酸化鉄,カーボンブラック,低次酸化チタン,マンゴバイオレット,コバルトバイオレット,酸化クロム,水酸化クロム,チタン酸コバルト,グンジョウ,コンジョウ等の無機着色顔料、酸化チタン被覆マイカ,酸化鉄被覆マイカ,酸化チタン・酸化鉄被覆マイカ,酸化チタン被覆オキシ塩化ビスマス,着色酸化チタン被覆マイカ,オキシ塩化ビスマス,魚鱗箔等のパール顔料、アルミニウム末,銅末等の金属粉末顔料、赤色201号,赤色202号,赤色204号,赤色205号,赤色220号,赤色226号,赤色228号,赤色405号,橙色203号,橙色204号,黄色205号,黄色401号,青色404号等の有機色素、赤色3号,赤色104号,赤色106号,赤色227号,赤色230号,赤色401号,赤色505号,橙色205号,黄色4号,黄色5号,黄色202号,黄色203号,緑色3号,青色1号等の有機色素及びこれらのジルコニウム,バリウム,又はアルミニウムレーキ顔料、クロロフィル,β−カロチン,シコニン,カーサミン等の天然色素、染料などが挙げられる。
【0011】
さらに、マスカラ皮膜に張りを付加する観点から皮膜形成能を有する高分子化合物、皮膜形成剤を配合することができる。皮膜形成剤を配合する場合その配合量は、マスカラ組成物全量に対して0.001〜80重量%、更に好ましくは5.0〜80.0重量%である。かかる皮膜形成剤としては、ポリビニルアルコール,ポリビニルピロリドン,メトキシエチレン無水マレイン酸共重合体,両性(メタ)アクリル酸エステル共重合体,カチオン化セルロース,ポリ塩化ジメチルメチレンピペリジニウム,ヒドロキシエチルセルロース,ヒドロキシプロピルセルロース等の水溶性高分子、ポリ(メタ)アクリル酸エステル共重合体,ポリスチレンラテックス,ポリ酢酸ビニル,ポリ塩化ビニル等の水系エマルション等が例示される。
【0012】
さらに、本発明のマスカラ組成物には、その他目的に応じて本発明の効果を損なわない量的,質的範囲内で、マスカラ組成物に一般的に用いられる固型,半固型,液状の油分、薬剤、乳化剤、増粘剤、紫外線吸収剤、粘土鉱物、香料、防腐剤、アルコール、多価アルコール、水溶性高分子、酸化防止剤、保湿剤などを配合することができる。
【0013】
【実施例】
さらに本発明の特徴について、実施例により詳細に説明する。
【0014】
製法:(1)〜(5)を混合し75℃に加熱して溶解,均一化する。(6)の顔料を添加し、コロイドミルを通して均一に分散させる。さらに(7)の成分を混合,溶解して75℃に加熱し、加熱溶解均一化した(8)〜(11)の成分を添加して乳化後、冷却する。
【0015】
法:(1)〜(5)を混合し75℃に加熱して溶解,均一化する。(6)の顔料を添加し、コロイドミルを通して均一に分散させる。さらに(7)の成分を混合,溶解し80℃に加熱し、加熱溶解均一化した(8)〜(10)の成分を添加して乳化後、冷却し、(11)の成分を添加する。
【0016】
製法:(1)〜(5)を混合し75℃に加熱して溶解,均一化する。(6)の顔料を添加しコロイドミルを通して均一に分散させた後、(7)の成分を添加する。
【0017】
上記実施例1〜3を用いて、ボリュームの付与、及び睫を長く見せる効果について官能評価を行った。同時に高重合度ポリエチレングリコールをポリエチレングリコール(平均分子量500)に代替した比較例1〜3を調製し、比較例を標準とした比較評価を行った。評価は女性10名を一群として行い、結果は各評価をつけたパネラーの数で表1に示した。
【0018】
【表1】
【0019】
表1に示したように、マスカラ組成物に高重合度ポリエチレングリコールを配合することにより、睫にボリューム感を付与し、更に長く見せる効果を有することが示された。なお、本発明の使用者において、目の痛みや眼粘膜の刺激を訴えたパネラーは認められなかった。
【0020】
【発明の効果】
以上詳述したように、本発明のマスカラ組成物は、高重合度ポリエチレングリコールを配合することにより、睫にボリュームを付与し、更に睫を長く見せる効果を有する。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a mascara composition containing a high polymerization degree polyethylene glycol and having an excellent effect of making wrinkles appear dark and long.
[0002]
[Prior art]
Mascara is a type of makeup cosmetic that is used to make a long and beautiful look. Mascara is classified according to the purpose, such as a curl type with strong curling power, a long lash type with a long effect of showing the heel, and a volume type that improves the volume of the heel. These types of mascara are marketed separately depending on the purpose because the conditions such as the length, thickness, degree of density of the cocoon, and whether it grows upward or downward, vary considerably from person to person. ing. Among these types, the volume type and long lash type mascara are generally preferred and used by Japanese people who have a rough and short habit.
[0003]
In such a volume type mascara, wax, a fatty acid, or a fatty acid salt is generally used to give a volume. For example, JP-A-6-9431 discloses a makeup composition containing an aqueous dispersion of wax particles, at least one water-soluble film-forming polymer, and a pigment. JP-A-5-194148 discloses a hydrocarbon. A composition for the makeup and care of eyebrows and / or eyebrows containing a wax and a water-soluble polymer and a method for its manufacture are disclosed, respectively.
[0004]
Also, short fibers such as nylon are often used to make the wrinkles look longer. However, when short fibers such as nylon are blended in the mascara composition, the fibers are easily removed from the eyelids and enter the eye. When using contact lenses, there is a problem that the eyes and the lens are damaged.
[0005]
Furthermore, a mascara composition of the type that improves the volume of the cocoon and shows it for a long time has not been obtained.
[0006]
[Problems to be solved by the invention]
Therefore, an object of the present invention is to obtain a mascara composition excellent in the effect of imparting a volume to the cocoon and making it look long.
[0007]
[Means for Solving the Problems]
As a result of intensive studies to solve the above-mentioned problems, the present inventors have obtained a mascara composition excellent in the effect of imparting a volume to the cocoon and making it look long by adding a high polymerization degree polyethylene glycol to the mascara composition. The present invention has been completed.
[0008]
DETAILED DESCRIPTION OF THE INVENTION
The high-polymerization polyethylene glycol used in the present invention is a water-soluble polymer having a thickening effect, and is used as a thickener and a pigment dispersant. Such high-polymerization polyethylene glycol is applied to cosmetics as cosmetics having excellent stability and moisture retention in combination with hyaluronate (Japanese Patent Laid-Open No. 63-156838), and shampoo compositions in combination with sugar alkyls. (Japanese Patent Laid-Open No. 5-43434), a hair styling composition containing a high polymerization degree polyethylene glycol as a foam property improving agent (Japanese Patent Laid-Open No. 6-9344), and an aqueous gel composition used in combination with a cross-linked acrylic acid polymer ( European Patent No. 94-400730), hair cosmetics used in combination with betaine (JP-A-7-69840), detergents used in combination with amine or amide type surfactants (JP-A-8-157349), surfactants, A conditioning shampoo composition used in combination with a cationic polymer (JP-A-9-175952) is disclosed. . However, it has not been known that polyethylene glycol having a high degree of polymerization has an effect of imparting a volume to the cocoon and making it look long.
[0009]
The high polymerization degree polyethylene glycol used in the present invention is a polyethylene glycol having a molecular weight of 950 or more, and a polyethylene glycol having a molecular weight of 10,000 or more is preferably used from the viewpoint of volume feeling. As such a high polymerization degree polyethylene glycol, commercially available Polyox WSR N-10, N-30 (molecular weight 10,000 to 5,000,000: or more manufactured by Union Carbide), PEG-1000 to PEG-20000 (molecular weight 950 to 25000: more than Sanyo) Kasei Kogyo Co., Ltd.) can be used. The high polymerization degree polyethylene glycol can be blended in the mascara composition by 0.01 to 5% by weight.
[0010]
In the present invention, a coloring material can be blended in order to make the effect of imparting a volume feeling to the wrinkles. Such a color material may be any color material generally used in cosmetics, for example, talc, kaolin, mica, sericite, synthetic mica, vermiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, silicic acid. Calcium, magnesium silicate, strontium silicate, silicic anhydride, zeolite, barium sulfate, calcined gypsum, calcium phosphate, fluorapatite, hydroxyapatite, ceramic powder, inorganic powder such as boron nitride, zinc myristate, calcium palmitate, stearin Metal powder such as magnesium oxide, aluminum stearate, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene acrylic acid copolymer powder, cellulose powder, organic powder, titanium dioxide, oxide oxide Inorganic white pigments such as Bengala, iron titanate, γ-iron oxide, yellow iron oxide, ocher, black iron oxide, carbon black, low order titanium oxide, mango violet, cobalt violet, chromium oxide, chromium hydroxide, titanic acid Inorganic color pigments such as cobalt, gunjo, and salmon, titanium oxide coated mica, iron oxide coated mica, titanium oxide / iron oxide coated mica, titanium oxide coated bismuth oxychloride, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil, etc. Pearl powder, metal powder pigment such as aluminum powder, copper powder, red 201, red 202, red 204, red 205, red 220, red 226, red 228, red 405, orange 203, Organic dyes such as orange 204, yellow 205, yellow 401, blue 404, red 3, red 104, Organics such as red 106, red 227, red 230, red 401, red 505, orange 205, yellow 4, yellow 5, yellow 202, yellow 203, green 3 and blue 1 Examples thereof include pigments and natural pigments such as zirconium, barium, or aluminum lake pigments, chlorophyll, β-carotene, shikonin, and Casamin, and dyes.
[0011]
Furthermore, from the viewpoint of adding tension to the mascara film, a polymer compound having a film forming ability and a film forming agent can be blended. When the film forming agent is blended, the blending amount is 0.001 to 80% by weight, more preferably 5.0 to 80.0% by weight, based on the total amount of the mascara composition. Such film forming agents include polyvinyl alcohol, polyvinyl pyrrolidone, methoxyethylene maleic anhydride copolymer, amphoteric (meth) acrylic acid ester copolymer, cationized cellulose, polydimethylmethylene piperidinium chloride, hydroxyethyl cellulose, hydroxypropyl Examples thereof include water-soluble polymers such as cellulose, poly (meth) acrylic acid ester copolymers, aqueous emulsions such as polystyrene latex, polyvinyl acetate, and polyvinyl chloride.
[0012]
Furthermore, the mascara composition of the present invention has a solid, semi-solid, and liquid form generally used for mascara compositions within a quantitative and qualitative range that does not impair the effects of the present invention according to other purposes. Oils, drugs, emulsifiers, thickeners, ultraviolet absorbers, clay minerals, fragrances, preservatives, alcohols, polyhydric alcohols, water-soluble polymers, antioxidants, humectants and the like can be blended.
[0013]
【Example】
Further, the features of the present invention will be described in detail with reference to examples.
[0014]
Production method: (1) to (5) are mixed and heated to 75 ° C. to dissolve and homogenize. The pigment of (6) is added and dispersed uniformly through a colloid mill. Further, the component (7) is mixed and dissolved, heated to 75 ° C., the components (8) to (11), which have been uniformly heated and dissolved, are added and emulsified, and then cooled.
[0015]
Method: (1) to (5) are mixed and heated to 75 ° C. to dissolve and homogenize. The pigment of (6) is added and dispersed uniformly through a colloid mill. Further, the component (7) is mixed, dissolved, heated to 80 ° C., the components (8) to (10), which are heated and homogenized, are added and emulsified, cooled, and the component (11) is added.
[0016]
Production method: (1) to (5) are mixed and heated to 75 ° C. to dissolve and homogenize. After the pigment (6) is added and dispersed uniformly through a colloid mill, the component (7) is added.
[0017]
Using Examples 1 to 3 above, sensory evaluation was performed on the effect of imparting volume and making wrinkles look longer. At the same time, Comparative Examples 1 to 3 were prepared by replacing polyethylene glycol (average molecular weight of 500) with a high polymerization degree polyethylene glycol, and comparative evaluation was performed using the comparative example as a standard. The evaluation was performed with 10 women as a group, and the results are shown in Table 1 in terms of the number of panelists with each evaluation.
[0018]
[Table 1]
[0019]
As shown in Table 1, it was shown that by adding a high polymerization degree polyethylene glycol to the mascara composition, the buds were given a volume feeling and had an effect of making it look longer. In the users of the present invention, no panelists complaining of eye pain or irritation of the eye mucosa were found.
[0020]
【The invention's effect】
As described in detail above, the mascara composition of the present invention has the effect of imparting a volume to the wrinkles and further lengthening the wrinkles by blending the high polymerization degree polyethylene glycol.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25777097A JP3651643B2 (en) | 1997-09-05 | 1997-09-05 | Mascara composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25777097A JP3651643B2 (en) | 1997-09-05 | 1997-09-05 | Mascara composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH1179940A JPH1179940A (en) | 1999-03-23 |
JP3651643B2 true JP3651643B2 (en) | 2005-05-25 |
Family
ID=17310867
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP25777097A Expired - Fee Related JP3651643B2 (en) | 1997-09-05 | 1997-09-05 | Mascara composition |
Country Status (1)
Country | Link |
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JP (1) | JP3651643B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018181230A1 (en) | 2017-03-30 | 2018-10-04 | L'oreal | Composition for keratin fibers |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5095974B2 (en) * | 2006-10-02 | 2012-12-12 | 株式会社コーセー | Oil-in-water cosmetic for cosmetics |
FR3019739B1 (en) * | 2014-04-11 | 2017-08-04 | Oreal | COSMETIC COMPOSITION FOR COATING KERATIN FIBERS. |
JP6571356B2 (en) * | 2015-03-16 | 2019-09-04 | アサヌマ コーポレーション株式会社 | Cosmetic for salmon |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5754111A (en) * | 1980-09-19 | 1982-03-31 | Kao Corp | Hair-setting composition |
FR2491933B1 (en) * | 1980-10-10 | 1985-07-12 | Oreal | NOVEL POLYETHYLENE GLYCOLS DERIVATIVES, THEIR USE AND COSMETIC AND PHARMACEUTICAL COMPOSITIONS CONTAINING THEM |
JPS59116207A (en) * | 1982-12-22 | 1984-07-05 | Pola Chem Ind Inc | Makeup cosmetic |
FR2659011B1 (en) * | 1990-03-01 | 1994-09-30 | Oreal | WATER RESISTANT COMPOSITION FOR COATING EYELASHES, AND PREPARATION METHOD THEREOF. |
JPH05262617A (en) * | 1992-03-23 | 1993-10-12 | Shiseido Co Ltd | Make-up cosmetic |
-
1997
- 1997-09-05 JP JP25777097A patent/JP3651643B2/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018181230A1 (en) | 2017-03-30 | 2018-10-04 | L'oreal | Composition for keratin fibers |
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Publication number | Publication date |
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JPH1179940A (en) | 1999-03-23 |
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