JP2818831B2 - Eyelash cosmetics - Google Patents
Eyelash cosmeticsInfo
- Publication number
- JP2818831B2 JP2818831B2 JP4169490A JP4169490A JP2818831B2 JP 2818831 B2 JP2818831 B2 JP 2818831B2 JP 4169490 A JP4169490 A JP 4169490A JP 4169490 A JP4169490 A JP 4169490A JP 2818831 B2 JP2818831 B2 JP 2818831B2
- Authority
- JP
- Japan
- Prior art keywords
- eyelashes
- eyelash
- present
- cosmetic
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Description
【発明の詳細な説明】 ［産業上の利用分野］ 請求項１の発明 本発明は、睫に濡れたようなつやと、ハリを与え、使
用時のべたつきが少なく、自然な仕上りが得られ、しか
も塗布後、経時でフレーキング（皮膜が剥離し白片状に
なる）を生じない極めて外観透明性の高い睫用化粧料に
関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The invention of claim 1 provides the present invention with a luster and a firmness that makes the eyelashes wet, less sticky during use, and a natural finish. In addition, the present invention relates to an eyelash cosmetic having extremely high external transparency which does not cause flaking (the film peels off and becomes white flakes) with time after application.
請求項２の発明 本発明は、睫に濡れたようなつやと、ハリを与え、使
用時のべたつきが少なく、自然な仕上りが得られ、しか
も塗布後、経時でフレーキング（皮膜が剥離し白片状に
なる）を生じない、外観色、塗布色ともクリアな色合い
もつ睫用化粧料に関する。Invention of Claim 2 The present invention provides a luster and a firmness that makes the eyelashes wet, reduces stickiness during use, and provides a natural finish. The present invention relates to an eyelash cosmetic that does not cause flakes and has a clear color in both appearance color and application color.
［従来の技術］ 請求項１の発明 近年、水溶性高分子を主体とした透明睫用化粧料が自
然な仕上りが得られる、透明感が目に対し優しいイメー
ジがある等の利用から用いられるようになってきてい
る。透明睫用化粧料には、水溶性カルボキシビニルポリ
マーを塩基性物質で中和した基材が使用感触の面で優れ
ているので主に用いられている。さらに睫につや、ハ
リ、カール効果を与える目的でポリビニルアルコール、
ポリビニルピロリドンとポリ酢酸ビニルの共重合体等が
配合されてきている。[Background Art] In recent years, transparent eyelash cosmetics mainly composed of a water-soluble polymer have been used for the purpose of obtaining a natural finish and having a transparent feeling that is gentle on the eyes. It is becoming. A base material obtained by neutralizing a water-soluble carboxyvinyl polymer with a basic substance is mainly used as a transparent eyelash cosmetic because of its excellent feel in use. Furthermore, for the purpose of giving gloss, firmness, curl effect to eyelashes, polyvinyl alcohol,
Copolymers of polyvinylpyrrolidone and polyvinyl acetate and the like have been blended.
しかしながら、これらの水溶性高分子の配合は塗布
後、経時でフレーキング（皮膜が剥離し白片状になる）
を生ずる、濁りを生じ透明性を損なう、べたつく等の欠
点があるため、その配合する量は限られてしまってい
る。そのために、睫に水々しいつやを与え、十分なハリ
とカール効果を与えるといった透明睫用化粧料として十
分な機能を有するものは未だ得られていない。However, the blending of these water-soluble polymers causes flaking over time after application (the film peels off and becomes white flakes)
, Turbidity, impairing transparency, stickiness, etc., the amount of the compounding is limited. For this reason, there has not yet been obtained a cosmetic having a sufficient function as a transparent eyelash cosmetic which gives the eyelashes freshness and a sufficient elasticity and curl effect.
請求項２の発明 従来からの通常の睫用化粧料には、睫を濃く長くみせ
るためや、睫をカールさせるためや、睫につやを与える
ため等の目的で、合成樹脂エマルジョンが配合されてい
る。一方、近年は消費者の嗜好から様々な色調の睫用化
粧料が研究されており、市場にも広く浸透している。し
かしながら、様々な色調を得るために通常の睫用化粧料
に顔料を配合すると、基剤色のため、濁った色合いにな
り、十分に満足できるものではなかった。The invention of claim 2 The conventional ordinary eyelash cosmetics are blended with a synthetic resin emulsion for the purpose of making the eyelashes look darker and longer, for curling the eyelashes, for glossing the eyelashes, and the like. I have. On the other hand, in recent years, eyelash cosmetics of various colors have been studied according to consumer's tastes, and have widely penetrated the market. However, when a pigment is blended with ordinary eyelash cosmetics in order to obtain various color tones, the base color results in a cloudy hue, which is not satisfactory.
［発明が解決しようとする課題］ 請求項１の発明 本発明者らは、上記事情に鑑み、睫に濡れたようなツ
ヤと十分なるハリとカール効果を与え、また使用時べた
つきが少なく、自然な仕上りを与え、しかも睫に塗布後
の経時においてもフレーキングを起こさない透明性に優
れる睫用化粧料について鋭意研究を重ねた結果、水溶性
カルボキシビニルポリマーと、塩基性物質とからなる基
剤に特定の物質を配合することにより、これらの問題点
を全て解決できることを見出し、本発明を完成するに至
った。[Problems to be Solved by the Invention] In view of the above circumstances, the inventors of the present invention have given a luster as if wet to the eyelashes, and have a sufficient firmness and curling effect, and have a low stickiness during use and a natural As a result of intensive research on cosmetics for eyelashes that give a good finish and that do not cause flaking even after application to the eyelashes and evolve over time, a base consisting of a water-soluble carboxyvinyl polymer and a basic substance It has been found that all these problems can be solved by adding a specific substance to the present invention, and the present invention has been completed.
請求項２の発明 本発明者らは、上記事情に鑑み、顔料のもつ色合い、
質感をそのまま引き出し、外観色、塗布色ともクリアな
発色を有し、さらに睫に濡れたようなツヤと十分なるハ
リとカール効果を与え、また使用時べたつきが少なく、
自然な仕上りを与え、しかも睫に塗布後の経時において
もフレーキングを起こさない睫用化粧料について鋭意研
究を重ねた結果、水溶性カルボキシビニルポリマーと、
塩基性物質と、顔料とからなる基剤に特定の物質を配合
することにより、これらの問題点を全て解決できること
を見出し、本発明を完成するに至った。Inventors of Claim 2 In view of the above circumstances, the present inventors have considered the color of the pigment,
It brings out the texture as it is, has a clear coloration in both the appearance color and the application color, and gives a sufficient gloss and curl effect with a gloss that gets wet on the eyelashes, and also has less sticky when used,
As a result of intensive research on eyelash cosmetics that give a natural finish and do not cause flaking even after application to the eyelashes, water-soluble carboxyvinyl polymer,
It has been found that all of these problems can be solved by blending a specific substance with a base composed of a basic substance and a pigment, and the present invention has been completed.
［課題を解決するための手段］ 請求項１の発明 すなわち、本発明は、水溶性カルボキシビニルポリマ
ーと、塩基性物質と、デキストリンとを含有することを
特徴とする睫用化粧料である。Means for Solving the Problems Invention of Claim 1 That is, the present invention is an eyelash cosmetic comprising a water-soluble carboxyvinyl polymer, a basic substance, and dextrin.
請求項２の発明 すなわち、本発明は、水溶性カルボキシビニルポリマ
ーと、塩基性物質と、デキストリンと、顔料とを含有す
ることを特徴とする睫用化粧料である。That is, the present invention is an eyelash cosmetic comprising a water-soluble carboxyvinyl polymer, a basic substance, dextrin, and a pigment.
以下、本発明の構成について詳述する。 Hereinafter, the configuration of the present invention will be described in detail.
本発明の請求項１又は２で用いられる水溶性カルボキ
シビニルポリマーは、特に限定されるものではなく、上
市されているものでは、カーボポール940、カーボポー
ル941、カーボポール934（いずれもB.F.Goodrich Chemi
cal社製）やハイビスワコー104、ハイビスワコー105
（いずれも和光純薬工業社製）等が挙げられる。配合量
は、使用感触や目的とする粘度等によって適宜決められ
るが、一般的に化粧料全量中0.05〜５重量％である。The water-soluble carboxyvinyl polymer used in claim 1 or 2 of the present invention is not particularly limited, and those marketed include Carbopol 940, Carbopol 941, and Carbopol 934 (all BF Goodrich Chemi
cal), Hibiswako 104, Hibiswako 105
(All manufactured by Wako Pure Chemical Industries, Ltd.). The compounding amount is appropriately determined depending on the feeling of use and the desired viscosity, but is generally 0.05 to 5% by weight based on the total amount of the cosmetic.
本発明の請求項１又は２で用いられる塩基性物質は特
に限定されるものではなく、例えば、水酸化ナトリウ
ム、水酸化カリウム等の水酸化物、Ｌ−アルギニン、Ｌ
−リジン等の塩基性アミノ酸や、トリエタノールアミ
ン、２−アミノ−２−メチルプロパノール等のアミン
類、アンモニア等が挙げられる。塩基性物質の配合量
は、カルボキシビニルポリマーの種類、配合量、目的と
する粘度によって決定すればよく特に限定されないが、
通常0.05〜3.0重量％程度である。The basic substance used in claim 1 or 2 of the present invention is not particularly limited, and examples thereof include hydroxides such as sodium hydroxide and potassium hydroxide, L-arginine, and L-arginine.
Basic amino acids such as lysine; amines such as triethanolamine and 2-amino-2-methylpropanol; and ammonia. The amount of the basic substance is not particularly limited as long as it is determined according to the type of the carboxyvinyl polymer, the amount of the carboxyvinyl polymer, and the intended viscosity.
Usually, it is about 0.05 to 3.0% by weight.
本発明の請求項１又は２で用いられるデキストリン
は、でんぷんを分解してマルトースに至る中間段階生成
物の総称で、でんぷんを酵素、酸、熱などで処理して得
られ、（C6H10O5）ｎ・xH2Oで表されるものであり、水
に溶解するものであれば特に限定されるものでなく、上
市されているものではアミコール（日澱化学社製）やパ
インデックス、Ａソルブルスターチ、アラビックス、パ
インフロー、グリスター（いずれも松谷化学社製）やソ
ルブルスターチ＃16（ニチリン化学社製）やサンデック
ス（三和澱粉社製）等が挙げられる。配合量は化粧料全
量中0.5〜30重量％が好ましく、さらに好ましくは１〜2
5重量％である。0.5重量％未満では、睫につや、ハリを
与えるといった化粧効果が十分でなく、30重量％を越え
るとべたつき使用感触が悪くなる。The dextrin used in claim 1 or 2 of the present invention is a general term for an intermediate stage product that degrades starch to maltose, and is obtained by treating starch with an enzyme, an acid, heat, or the like, and (C 6 H 10 O 5 ) It is represented by nxH 2 O, and is not particularly limited as long as it is soluble in water. Among those on the market, amicol (manufactured by Nisseki Chemical Co., Ltd.), Paindex, A Soluble Starch, Arabix, Pine Flow, Glister (all manufactured by Matsutani Chemical Co., Ltd.), Soluble Starch # 16 (manufactured by Nichirin Chemical Co., Ltd.) and Sandex (manufactured by Sanwa Starch Co., Ltd.). The compounding amount is preferably 0.5 to 30% by weight based on the total amount of the cosmetic, more preferably 1 to 2%.
5% by weight. If it is less than 0.5% by weight, the cosmetic effect such as giving gloss and firmness to the eyelashes is not sufficient, and if it exceeds 30% by weight, the sticky feel becomes poor.
本発明の請求項２に用いられる顔料としては、例えば
タルク、カオリン、炭酸カルシウム、亜鉛華、二酸化チ
タン、赤酸化鉄、黄酸化鉄、黒酸化鉄、群青、チタンコ
ーティッドマイカ、マイカ／酸化鉄／酸化チタン、オキ
シ塩化ビスマス、ベンガラ、粘結顔料、グンジョウピン
ク、水酸化クロム、雲母チタン、酸化クロム、酸化アル
ミニウムコバルト、紺青、黒酸化鉄、カーボンブラッ
ク、無水ケイ酸、ケイ酸マグネシウム、ベントナイト、
マイカ、セリサイト、酸化ジルコニウム、硫酸バリウ
ム、酸化マグネシウム、酸化亜鉛、酸化チタン、軽質炭
酸カルシウム、重質炭酸カルシウム、軽質炭酸マグネシ
ウム、重質炭酸マグネシウム、カラミン、ナイロンパウ
ダー、ポリエチレン末、セルロースパウダー、アクリル
系樹脂、フタロシアニンブルー、ヘリンドンピンク、ハ
ンサエロー、タートラジンAlレーキ、リソールルビンBC
A等が挙げられる。配合量は化粧料全量中0.05重量％〜2
0重量％が好ましい。Examples of the pigment used in the second aspect of the present invention include talc, kaolin, calcium carbonate, zinc white, titanium dioxide, red iron oxide, yellow iron oxide, black iron oxide, ultramarine blue, titanium coated mica, and mica / iron oxide. / Titanium oxide, bismuth oxychloride, red iron oxide, binder pigment, Gunjo pink, chromium hydroxide, mica titanium, chromium oxide, aluminum cobalt oxide, navy blue, black iron oxide, carbon black, silicic anhydride, magnesium silicate, bentonite ,
Mica, sericite, zirconium oxide, barium sulfate, magnesium oxide, zinc oxide, titanium oxide, light calcium carbonate, heavy calcium carbonate, light magnesium carbonate, heavy magnesium carbonate, calamine, nylon powder, polyethylene powder, cellulose powder, acrylic Resin, phthalocyanine blue, herringdon pink, Hansa Yellow, Tartrazine Al Lake, Lisor Rubin BC
A and the like. The compounding amount is 0.05% by weight to 2% of the total amount of the cosmetic.
0% by weight is preferred.
本発明の請求項１又は２の睫用化粧料には、経時での
保存安定性や紫外線照射を受けた時の安定性を良好に保
ち、品質を維持させるためにヘキサメタリン酸ソーダ、
エデト酸ソーダ、グルコン酸ソーダ等の金属イオン封鎖
剤を配合することが好ましい。また必要に応じて、エタ
ノールやイソプロパノール等の低級アルコール、1,3−
ブチレングリコール、ジプロピレングリコール、グリセ
リンやソルビトール等の多価アルコール、界面活性剤、
他の水溶性高分子、海藻抽出物やケラチン誘導体等の毛
髪保護剤、コンドロイチン硫酸ソーダやヒアルロン酸ソ
ーダ等の保湿剤、薬剤、色素、防腐剤、香料、酸化防止
剤、紫外線吸収剤等を配合することもできる。当然のこ
とながら、これらの成分は本発明の効果を損なわない質
的、量的範囲内でなければならない。The eyelash cosmetic according to claim 1 or 2 of the present invention has good storage stability over time and stability when exposed to ultraviolet irradiation, and sodium hexametaphosphate to maintain quality.
It is preferable to add a sequestering agent such as sodium edetate and sodium gluconate. If necessary, lower alcohols such as ethanol and isopropanol, 1,3-
Butylene glycol, dipropylene glycol, polyhydric alcohols such as glycerin and sorbitol, surfactants,
Contains other water-soluble polymers, hair protection agents such as seaweed extract and keratin derivatives, humectants such as chondroitin sulfate sodium and sodium hyaluronate, drugs, pigments, preservatives, fragrances, antioxidants, ultraviolet absorbers, etc. You can also. Naturally, these components must be within qualitative and quantitative ranges that do not impair the effects of the present invention.
［実施例］ 次に実施例をあげて本発明をさらに詳細に説明する。
本発明はこれにより限定されるものではない。配合量は
重量％である。実施例に先立ち、効果試験方法及び評価
方法について述べる。[Examples] Next, the present invention will be described in more detail with reference to examples.
The present invention is not limited by this. The compounding amount is% by weight. Prior to the examples, an effect test method and an evaluation method will be described.
使用性（さっぱりさ、つや、はり） テスターが実際に睫用化粧料を塗布して、使用時のさ
っぱりさ、使用後のつや及びはりについて官能評価し
た。Usability (freshness, gloss, beam) The tester actually applied the cosmetic for eyelashes, and carried out a sensory evaluation on the refreshment at the time of use, the gloss after use, and the beam.
◎：非常に良好 ○：良好 △：やや不良 ×：不良 化粧もち（発粉の有無） テスターが実際に睫用化粧料を塗布して、経時での発
粉の有無を評価した。：: Very good ○: Good △: Slightly poor ×: Poor Makeup stickiness (presence or absence of powdering) The tester actually applied eyelash cosmetics and evaluated the presence or absence of powdering over time.
透明性（Ｌ値） 日立カラーアナライザー607を用いて測定した。厚さ1
cmのガラスセルに試料を取り、380〜780nmの光を透過さ
せ、後に置いた標準白色板のＬ値を測定することで透明
性を評価した。Transparency (L value) It was measured using Hitachi Color Analyzer 607. Thickness 1
A sample was taken in a glass cell of cm, light of 380 to 780 nm was transmitted, and the transparency was evaluated by measuring the L value of a standard white plate placed behind.
Ｌ値90以上：全く透明 Ｌ値80〜89:やや不透明 Ｌ値70〜79:かなり不透明 Ｌ値69以下：ほとんど不透明 実施例１〜３、比較例１〜５ 表−１に示す処方により睫用化粧料を製造し、それぞ
れについて評価した。L value 90 or more: Totally transparent L value 80-89: Slightly opaque L value 70-79: Pretty opaque L value 69 or less: Almost opaque Example 1-3, Comparative examples 1-5 For eyelashes according to the formulation shown in Table-1 Cosmetics were manufactured and evaluated for each.
（製法） （６）に（１）（３）（４）（５）（７）を溶解し、
この中に別に（８）に（９）を溶解したものと（２）と
加えて均一に撹拌し、睫用化粧料を得た。(Production method) Dissolve (1), (3), (4), (5) and (7) in (6),
Into this, (9) was dissolved in (8) and (2) were added, and the mixture was stirred uniformly to obtain eyelash cosmetics.
表−１から明らかなように実施例１〜３は、睫につや
とはりを与え、さっぱりとした使用感触で化粧もちの良
い透明睫用化粧料であることが確認された。 As is clear from Table 1, Examples 1 to 3 gave gloss to the eyelashes, and were confirmed to be clear eyelash cosmetics with a refreshing feel of use and good makeup.
実施例４ 表−２に示す処方により睫用化粧料を製造し、評価し
た。Example 4 Eyelash cosmetics were manufactured according to the formulations shown in Table 2 and evaluated.
（製法） （６）に（１）（３）〜（５）（７）〜（12）を溶
解、分散し、この中に別に（12）に（13）を溶解したも
のと（２）と加えて均一に撹拌し、睫用化粧料を得た。(Manufacturing method) (1) (3) to (5) (7) to (12) were dissolved and dispersed in (6), and (13) was separately dissolved in (12) and (2). In addition, the mixture was stirred uniformly to obtain eyelash cosmetics.
表−２から明らかなように実施例４は、睫につやとは
りを与え、さっぱりとした使用感触で化粧もちに優れた
睫用化粧料であることが確認された。また、実施例４の
睫用化粧料は、外観色、塗布色ともクリアな色合いをも
つものであった。 As is evident from Table 2, Example 4 gave a gloss to the eyelashes, and was confirmed to be a cosmetic material for eyelashes having a refreshing feel of use and excellent makeup. Further, the eyelash cosmetic of Example 4 had a clear color in both the appearance color and the application color.
［発明の効果］ 本発明の請求項１の睫用化粧料は、睫に濡れたような
つやと、ハリを与え、使用時のべたつきが少なく、自然
な仕上りが得られ、しかも塗布後、経時でフレーキング
（皮膜が剥離し白片状になる）を生じない極めて外観透
明性の高いものであり、請求項２記載の睫用化粧料は、
睫に濡れたようなつやと、ハリを与え、使用時のべたつ
きが少なく、自然な仕上りが得られ、しかも塗布後、経
時でフレーキング（皮膜が剥離し白片状になる）を生じ
ない、外観色、塗布色ともクリアな色合いもつものであ
る。[Effects of the Invention] The eyelash cosmetic according to claim 1 of the present invention gives a luster and a firmness to the eyelashes, gives less stickiness during use, and provides a natural finish, and after application, it is time-lapsed. The eyelash cosmetic according to claim 2, which has extremely high appearance and transparency without causing flaking (the film peels off and forms white flakes).
Gives the eyelashes a wet shine, firmness, less stickiness during use, a natural finish, and no flaking (the film peels off and becomes white flakes) over time after application. Both the appearance color and the application color have clear hues.
Claims (2)
性物質と、デキストリンとを含有することを特徴とする
睫用化粧料。1. An eyelash cosmetic comprising a water-soluble carboxyvinyl polymer, a basic substance, and dextrin.
性物質と、デキストリンと、顔料とを含有することを特
徴とする睫用化粧料。2. An eyelash cosmetic comprising a water-soluble carboxyvinyl polymer, a basic substance, dextrin, and a pigment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4169490A JP2818831B2 (en) | 1990-02-22 | 1990-02-22 | Eyelash cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4169490A JP2818831B2 (en) | 1990-02-22 | 1990-02-22 | Eyelash cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03246214A JPH03246214A (en) | 1991-11-01 |
| JP2818831B2 true JP2818831B2 (en) | 1998-10-30 |
Family
ID=12615534
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4169490A Expired - Lifetime JP2818831B2 (en) | 1990-02-22 | 1990-02-22 | Eyelash cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2818831B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0733635A (en) * | 1993-07-21 | 1995-02-03 | Kao Corp | Skin external preparation |
| US6045783A (en) * | 1998-05-22 | 2000-04-04 | Coty B.V. | Cosmetic formulation with a swelling effect |
| KR100530839B1 (en) * | 1998-12-30 | 2006-03-23 | 주식회사 엘지생활건강 | Mascara cosmetic composition |
| JP5755910B2 (en) * | 2011-03-10 | 2015-07-29 | 日本メナード化粧品株式会社 | Eyelash cosmetic |
-
1990
- 1990-02-22 JP JP4169490A patent/JP2818831B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH03246214A (en) | 1991-11-01 |
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