JP3608227B2 - Membrane separator - Google Patents
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- JP3608227B2 JP3608227B2 JP20609594A JP20609594A JP3608227B2 JP 3608227 B2 JP3608227 B2 JP 3608227B2 JP 20609594 A JP20609594 A JP 20609594A JP 20609594 A JP20609594 A JP 20609594A JP 3608227 B2 JP3608227 B2 JP 3608227B2
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Description
【0001】
【産業上の利用分野】
この発明は、膜によって内部が原水室と透過室とに仕切られた膜モジュールを有し、原水室に原水を給水し、原水室から膜を透過して透過室に流入した透過水を貯槽に貯え、貯槽から必要個所に配水する膜分離装置に関する。
【0002】
【従来の技術】
近年、膜分離技術の発達により各種の分野で膜濾過が使用されるようになった。例えば河川水、工業用水、上水を、RO膜分離するための前処理の凝集、沈殿、濾過に代ってUF膜や、MF膜で膜濾過を行い、前処理プロセスを簡素化したり、河川水等の水を浄水場で浄化して一般家庭に配水する場合、浄化を膜濾過で行うのに使用されるようになった。このような膜濾過を行う膜分離装置として、本特許出願人は特願平5−213063号で膜によって内部が原水室と透過室とに仕切られた膜モジュールと、加圧ポンプを有し、原水室に原水を給水する原水給水手段と、原水室から膜を透過して透過室に流入した原水中の透過水を貯槽に取出す採水手段と、貯槽から透過水を必要個所に配水する配水手段と、逆洗ポンプを有し、前記貯槽の透過水を膜モジュールの透過室に注入する逆洗手段と、循環ポンプを有し、透過室の透過水を透過室から抜出して再び透過室に戻す循環手段と、該循環手段に洗浄薬液を注入する薬注手段とを有する装置を提案した。
【0003】
【発明が解決しようとする課題】
このような膜分離装置で膜濾過運転を行うと、膜の原水室側の膜面に原水に含まれている濁質やコロイドがケーク層を形成すると共に、フミン酸やフルボン酸などの有機性物質(TOC成分)が膜面に析出し、ゲル状物質となって強固に膜に付着し、次第に膜の濾過抵抗が増大する。従って、通常は膜分離装置を二系列設置し、その一系列をメインとして運転し、それの原水室側膜面に形成されたケーク層や、ゲル状物質を除去する洗浄を行う際に他の一系列を運転するようにしているため、設備費が嵩むと共に、設置面積も増大する。
【0004】
【課題を解決するための手段】
上記問題点を解消するために請求項1に記載の発明は、膜によって内部が原水室と透過室とに仕切られた膜モジュールと、加圧ポンプを有し、原水室に原水を給水する原水給水手段と、原水室から膜を透過して透過室に流入した原水中の透過水を貯槽に取出す採水手段と、貯槽から透過水を必要個所に配水する配水手段と、逆洗ポンプを有し、前記貯槽の透過水を洗浄水として膜モジュールの透過室に注入する逆洗手段とを有する膜分離装置において、循環ポンプを有し、前記逆洗手段により洗浄水として透過室に注入された透過水を透過室から抜出して再び透過室に戻す循環手段と、薬注ポンプを有し、該循環手段に洗浄薬液を注入する薬注手段を設け、前記貯槽の容量を、膜モジュールの洗浄に使用する透過水の使用水量と、その洗浄時間内に透過水を必要個所に配水しなければならない透過水の必要配水量との合計、又はそれ以上にし、且つ貯槽にはレベルスイッチを設け、このレベルスイッチは、貯槽内の透過水の水量が、膜モジュールの洗浄に使用する透過水の使用水量と、その洗浄時間内に透過水を配水しなければならない透過水の必要給水量との合計、又はそれ以上になるとこれを検出し、前記加圧ポンプ、逆洗ポンプ、循環ポンプ、薬注ポンプに指令し、原水の給水を停止し、膜の洗浄を開始させる膜分離装置であって、薬注手段により洗浄薬液が注入された循環手段の透過水の洗浄薬液の濃度が所定になったら循環ポンプ、薬注ポンプを停め、逆洗手段の逆洗ポンプを作動させる制御手段を備えたことを特徴とする。
【0005】
【実施例】
図示の実施例は、前述の先行提案と同じで、河川1から河川水を取水ポンプ2で着水槽3に揚水し、着水槽から河川水を原水槽4を経て加圧ポンプP1 で膜モジュール10に供給し、浄化を行う。膜モジュール10は膜11によって内部が原水室12と、透過室13とに仕切られ、加圧ポンプP1 により河川水(原水)は給水管14で原水室12に供給される。原水室に供給された原水のうち膜11を透過した透過水は透過室13に流入し、こゝから採水管15で貯槽16に導き、浄水場の場合は貯槽16から一般家庭に配水管17で配水する。尚、図示の膜分離装置はクロスフロー型であるため、原水室に供給された原水中、膜を透過しなかった濃縮水は原水室の出口管18、給水循環管19により再び給水管14に戻され、給水循環ポンプP2 で原水室に供給されて循環する。
【0006】
膜モジュールの膜11の、原水室側膜面に形成される前述のケーク層や、付着するゲル状物質を洗浄して除去するため、原水室の出口管18には洗浄廃水の排出管20を接続し、給水循環管19には弁V1 、排出管20には弁V2 を設け、原水室から出口管18に出るのが濃縮水の場合はV1 を開、V2 を閉にし、洗浄廃水の場合はV1 を閉、V2 は開にする。又、貯槽に貯えた透過水を洗浄水として透過室13に加圧注入し、膜濾過のときとは逆に洗浄水を膜に透過させるため、貯槽と採水管15の途中との間に逆洗ポンプP3 を有する供給管21を接続する。更に、採水管15の途中と透過室13との間に循環ポンプP4 を有する循環管22を接続し、透過室の透過水(洗浄水)を透過室から抜出して再び透過室に戻し、循環できるようにする。そして、この循環管22には薬液槽23の例えば次亜塩素酸ソーダを注入するための薬注ポンプP5 を有する薬注管24を接続する。採水管15には、供給管21、及び循環管22の接続位置よりも下流に弁V3 を設け、洗浄の際には閉にして洗浄水が貯槽16に流入するのを防止する。又、循環管22の透過室13に接続する端部には弁V4 を設ける。
【0007】
洗浄を行うには、弁V1 ,V3 を閉、弁V2 を開、弁V4 を閉に保ち、ポンプP1 ,P2 を停め、先ず逆洗ポンプP3 を運転し、貯槽内の透過水を洗浄水にして供給管21、採水管15から透過室13に圧入する。弁V3 ,V4 が閉、循環ポンプP4 は停止しているので透過室に圧入された洗浄水は膜11を膜濾過の際とは逆方向に透過し、原水室の膜面に形成されたケーク層を剥離しながら原水室に流入し、剥れたケーク層を伴って排出管20から排出する。尚、少なくともポンプP2 の吐出側にチャッキ弁(図示せず)を設け、原水槽4側への逆流を防止する。このケーク層の剥離を約1分行ったら、逆洗ポンプP3 の運転を停め、弁V4 を開にし、循環ポンプP4 、薬注ポンプP5 を運転する。これによって透過室を満たして残っている洗浄水は循環管22、採水管15を通って透過室に循環し、この循環する洗浄水に薬液槽23の次亜塩素酸ソーダが添加される。循環する洗浄水中の次亜塩素酸ソーダの濃度が所定になったら、循環ポンプ、薬注ポンプを停め、弁V4 を閉にし、逆洗ポンプP3 を運転して貯槽内の透過水を透過室に圧入し、透過室中の次亜塩素酸ソーダを含む洗浄水を膜11に膜濾過の際とは逆方向に透過させ、膜面に強固に付着したゲル状物質に次亜塩素酸ソーダを接触させてゲル状物質を膜面から除去し、排出管20から排出する。こうして次亜塩素酸ソーダを含む洗浄水がすべて膜を透過して原水室から排出管20に排出され、原水室及び透過室が透過水で満ちたら逆洗ポンプの運転を停め、弁V2 を閉、弁V1 ,V3 を開にし、加圧ポンプP1 、給水循環ポンプP2 を運転し、膜濾過を再開する。ゲル状物質を除去する薬液洗浄の所要時間は約30分から1時間である。
【0008】
従来は、膜11の原水室側膜面にケーク層、ゲル状物質が付着し、原水が膜を透過する透過流速が低下する都度、上記洗浄を行い、その洗浄を行っている間は予備の膜分離装置で膜濾過を行って貯槽に透過水を補給し、一般家庭などへの配水に支障が生じるのを防いでいたのである。
【0009】
本発明は貯槽16の容量を、前述したケーク層の剥離、ゲル状物質の除去のために洗浄水として使用する透過水の使用水量と、その洗浄時間内に透過水を一般家庭などに配水しなければならない必要配水量との合計、又はそれ以上にする。この場合、必要配水量は、洗浄の所要時間が1時間であるときは、1時間よりも多い例えば2時間分の配水量にすることが好ましい。そして、貯槽16にはレベルスイッチ25を設け、貯水槽内の透過水の水量が上記洗浄に使用する透過水の使用水量と、洗浄時間内の必要配水量との合計、又はそれ以上になるとレベルスイッチ25は水位でそれを検出して制御器26に出力し、制御器26は前述のポンプP1 ,P2 ,P3 ,P4 ,P5 、及び弁V1 ,V2 ,V3 ,V4 をシーケンス制御し、原水の給水を停めて膜濾過を停止し、ケーク層の剥離、ゲル状物質の除去の洗浄を自動的に行わせ、洗浄が終ると膜濾過を再開させるのである。
【0010】
膜濾過の停止、ケーク層の剥離、ゲル状物質の除去、膜濾過の再開のためのポンプや弁の制御の態様は前述した通りである。
【0012】
【発明の効果】
この発明によれば、貯槽内の透過水の水量が、洗浄に使用する透過水の使用水量と、洗浄時間内の必要配水量の合計、又はそれ以上になり、洗浄を行っても一般家庭などへの配水に支障が無くなったら洗浄を行うので、膜分離装置は一系列設置するだけで済み、二系列設置する場合に較べて設備費は大幅に低減すると共に、設置面積も少なくて済む。更に、貯槽内の透過水の水量が、洗浄に使用する透過水の使用水量と、洗浄時間内の必要配水量の合計、又はそれ以上になると洗浄が開始する。これによって膜濾過の開始から洗浄の開始までの膜濾過運転時間は、膜の原水側膜面にケーク層が形成され、且つゲル状物質が付着して膜の透過流速が低下したら洗浄を開始する従来の場合に較べて可成り短くなる。従って、膜の原水側膜面に形成されるケーク層や、付着するゲル状物質が少ないうちに洗浄を行うので洗浄に使用する透過水の使用量、及び薬液の使用量は節減できると共に、洗浄の所要時間も短縮し、それでいて充分な洗浄効果をあげることができる。
【図面の簡単な説明】
【図1】本発明の膜分離装置の一実施例の系統図である。
【符号の説明】
1 河川
2 取水ポンプ
3 着水槽
4 原水槽
10 膜モジュール
11 膜
12 原水室
13 透過室
14 給水管
15 採水管
16 貯槽
17 配水管
18 出口管
19 給水循環管
20 洗浄廃水の排出管
21 逆洗水の供給管
22 循環管
23 薬液槽
24 薬注管
25 レベルスイッチ
26 制御器
P1 加圧ポンプ
P2 給水循環ポンプ
P3 逆洗ポンプ
P4 循環ポンプ
P5 薬注ポンプ
V1 弁
V2 弁
V3 弁
V4 弁[0001]
[Industrial application fields]
This invention has a membrane module whose interior is divided into a raw water chamber and a permeation chamber by a membrane, feeds raw water into the raw water chamber, and permeate that has permeated the membrane from the raw water chamber and flowed into the permeation chamber into the storage tank. The present invention relates to a membrane separation device that stores and distributes water from a storage tank to necessary places.
[0002]
[Prior art]
In recent years, membrane filtration has been used in various fields due to the development of membrane separation technology. For example, instead of agglomeration, precipitation, and filtration of pretreatment for separating RO water from river water, industrial water, and clean water, membrane filtration is performed with a UF membrane or MF membrane to simplify the pretreatment process, When water such as water is purified at a water purification plant and distributed to ordinary households, it has come to be used for purification by membrane filtration. As a membrane separation apparatus for performing such membrane filtration, the present applicant has a membrane module whose interior is divided into a raw water chamber and a permeation chamber by a membrane in Japanese Patent Application No. 5-213063, and a pressure pump. Raw water supply means for supplying raw water to the raw water room, water sampling means for extracting the permeated water in the raw water that has passed through the membrane from the raw water room and flowed into the permeation chamber, and water distribution that distributes the permeated water from the storage tank to the necessary locations And a backwashing means having a backwash pump and injecting the permeated water of the storage tank into the permeation chamber of the membrane module, and having a circulation pump, extracting the permeated water of the permeation chamber from the permeation chamber and returning to the permeation chamber again. An apparatus having a circulation means for returning and a medicine injection means for injecting a cleaning chemical into the circulation means has been proposed.
[0003]
[Problems to be solved by the invention]
When membrane filtration operation is performed with such a membrane separator, turbidity and colloids contained in the raw water form a cake layer on the membrane surface on the raw water chamber side of the membrane, and organic substances such as humic acid and fulvic acid are used. The substance (TOC component) precipitates on the membrane surface and becomes a gel-like substance and adheres firmly to the membrane, gradually increasing the filtration resistance of the membrane. Therefore, normally, two series of membrane separation devices are installed, and the one series is operated as the main, and the cake layer formed on the raw water chamber side membrane surface and other washings when removing the gel-like substance are performed. Since one line is operated, the equipment cost increases and the installation area also increases.
[0004]
[Means for Solving the Problems]
In order to solve the above-mentioned problems, the invention according to claim 1 is a raw water having a membrane module that is partitioned into a raw water chamber and a permeation chamber by a membrane and a pressure pump, and supplying the raw water to the raw water chamber. There are water supply means, water collection means for extracting the permeated water in the raw water that has passed through the membrane from the raw water chamber and flowed into the permeation chamber, a water distribution means for distributing the permeated water from the storage tank to the required location, and a backwash pump. And a backwashing means for injecting the permeated water of the storage tank into the permeation chamber of the membrane module as washing water, and having a circulation pump and being injected into the permeation chamber as washing water by the backwashing means A circulation means for extracting permeate water from the permeation chamber and returning it to the permeation chamber and a chemical injection pump for injecting a cleaning chemical into the circulation means are provided, and the capacity of the storage tank is used for cleaning the membrane module. The amount of permeated water used and when cleaning it The permeated water must be distributed to the required locations within the sum of the permeated water required, or more, and a level switch is provided in the storage tank. The permeated water used for cleaning the membrane module and the required amount of permeated water to which permeated water must be distributed within the cleaning time are detected or detected when the sum is exceeded. This is a membrane separation device that commands the pressure pump, backwash pump, circulation pump, and chemical injection pump, stops the supply of raw water, and starts cleaning the membrane. A control means for stopping the circulation pump and the chemical injection pump and operating the backwash pump of the backwash means when the concentration of the cleaning chemical solution for permeated water reaches a predetermined value is provided.
[0005]
【Example】
The embodiment shown in the figure is the same as the above-mentioned prior proposal. River water is taken from the river 1 to the landing tank 3 by the
[0006]
In order to clean and remove the above-mentioned cake layer formed on the membrane surface of the
[0007]
In order to perform cleaning, the valves V 1 and V 3 are closed, the valve V 2 is opened, the valve V 4 is kept closed, the pumps P 1 and P 2 are stopped, the backwash pump P 3 is first operated, The permeated water is made into wash water and pressed into the
[0008]
Conventionally, when the cake layer or gel-like substance adheres to the membrane surface of the
[0009]
The present invention distributes the capacity of the
[0010]
The mode of controlling the pump and valve for stopping the membrane filtration, peeling the cake layer, removing the gel-like substance, and restarting the membrane filtration is as described above.
[0012]
【The invention's effect】
According to this invention, the amount of permeated water in the storage tank becomes the sum of the amount of permeated water used for cleaning and the required amount of water distribution within the cleaning time, or more, and even if cleaning is performed, ordinary households, etc. Cleaning is performed when there is no problem in water distribution to the water supply, so it is only necessary to install the membrane separation apparatus in one line, and the equipment cost can be greatly reduced and the installation area can be reduced as compared with the case of installing in two lines. Furthermore, when the amount of permeated water in the storage tank becomes the sum of the amount of permeated water used for cleaning and the required amount of water distribution within the cleaning time, or more, the cleaning starts. As a result, the membrane filtration operation time from the start of membrane filtration to the start of washing starts washing when a cake layer is formed on the membrane surface of the raw water side of the membrane, and the permeation flow rate of the membrane decreases due to adhesion of gel substances. Compared to the conventional case, it is considerably shorter. Therefore, the cake layer formed on the membrane surface of the raw water side of the membrane, and the amount of permeated water used for washing and the amount of chemical used can be reduced because washing is performed while the amount of attached gel-like substance is small. The time required for this is also shortened, and still a sufficient cleaning effect can be obtained.
[Brief description of the drawings]
FIG. 1 is a system diagram of an embodiment of a membrane separation apparatus of the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1
Claims (1)
薬注手段により洗浄薬液が注入された循環手段の透過水の洗浄薬液の濃度が所定になったら循環ポンプ、薬注ポンプを停め、逆洗手段の逆洗ポンプを作動させる制御手段を備えたことを特徴とする膜分離装置。The membrane module was internally partitioned into a raw water chamber and a permeation chamber by a membrane, a pressure pump, raw water supply means for supplying raw water to the raw water chamber, and the raw water chamber permeated the membrane and flowed into the permeation chamber Water collection means for extracting permeated water from the raw water into the storage tank, water distribution means for distributing permeated water from the storage tank to the necessary locations, and a backwash pump, and using the permeated water in the storage tank as washing water in the permeation chamber of the membrane module In the membrane separation apparatus having a backwashing means for injecting, a circulation means having a circulation pump, and extracting the permeated water injected into the permeation chamber as wash water by the backwashing means and returning it to the permeation chamber again; A chemical injection pump is provided, and a chemical injection means for injecting a cleaning chemical into the circulation means is provided, and the capacity of the storage tank is determined based on the amount of permeated water used for cleaning the membrane module and the permeated water within the cleaning time. Permeation that has to be distributed to the necessary places And the storage tank is provided with a level switch, and the level switch is configured so that the amount of permeated water in the storage tank is equal to the amount of permeated water used for cleaning the membrane module, When the sum of the permeated water required to distribute the permeated water within the washing time or more than this is detected, this is detected and commanded to the pressurization pump, backwash pump, circulation pump and chemical injection pump. A membrane separation device that stops the supply of raw water and starts washing the membrane,
When the concentration of the cleaning chemical solution of the permeated water of the circulating means into which the cleaning chemical solution was injected by the chemical injection means becomes predetermined, the circulation pump and the chemical injection pump are stopped and the control means for operating the back washing pump of the back washing means is provided. A membrane separator characterized by the above.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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JP20609594A JP3608227B2 (en) | 1994-08-09 | 1994-08-09 | Membrane separator |
Applications Claiming Priority (1)
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JP20609594A JP3608227B2 (en) | 1994-08-09 | 1994-08-09 | Membrane separator |
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JPH0852330A JPH0852330A (en) | 1996-02-27 |
JP3608227B2 true JP3608227B2 (en) | 2005-01-05 |
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JP20609594A Expired - Fee Related JP3608227B2 (en) | 1994-08-09 | 1994-08-09 | Membrane separator |
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JP4709095B2 (en) * | 2006-08-04 | 2011-06-22 | 水道機工株式会社 | Operation method of slurry solid-liquid separation membrane filtration device and slurry solid-liquid separation membrane filtration device |
CN102688694B (en) * | 2012-06-01 | 2014-07-23 | 河南方周瓷业有限公司 | On-line back washing process system of porous ceramic film |
CN107198970A (en) * | 2017-07-24 | 2017-09-26 | 金科水务工程(北京)有限公司 | A kind of full waterpower is made up a prescription Membrane cleaning system |
CN108744987B (en) * | 2018-06-20 | 2023-09-01 | 华北电力大学 | Water supplementing microstructure and system for gas membrane separation |
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