JP3277143B2 - Hair mascara composition - Google Patents
Hair mascara compositionInfo
- Publication number
- JP3277143B2 JP3277143B2 JP21471097A JP21471097A JP3277143B2 JP 3277143 B2 JP3277143 B2 JP 3277143B2 JP 21471097 A JP21471097 A JP 21471097A JP 21471097 A JP21471097 A JP 21471097A JP 3277143 B2 JP3277143 B2 JP 3277143B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- polyoxyethylene
- present
- composition
- stickiness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Description
【0001】[0001]
【発明の属する技術分野】本発明は染毛剤組成物に関
し、更に詳しくは、隠蔽性、耐摩擦性、安定性に優れ、
且つべとつきやごわつきがない感触に優れたヘアーマス
カラ組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair dye composition, and more particularly, to a hair dye composition having excellent concealing properties, rub resistance and stability.
The present invention relates to a hair mascara composition excellent in feeling without stickiness or stiffness.
【0002】[0002]
【従来の技術】近年、若者を中心に髪を脱色した茶髪、
更に髪全体を様々な色で染毛したり、部分的にメッシュ
を入れる等のヘアーカラーリングが流行し、これらヘア
ーカラーリングを実施するにあたり、様々な染毛剤が使
用されている。一般に毛髪を染毛する方法としては、着
色された毛髪の色の持続性の観点から永久染毛剤、半永
久染毛剤及び一時染毛剤に分類され、永久染毛剤、半永
久染毛剤については、色の持続性は高いものの、その染
毛操作は煩雑であり、一度染毛を失敗すると元に戻せな
いという欠点を有している。一方、一時染毛剤は、使用
方法も簡便であり、特にシャンプーで洗うことにより簡
単に洗い落とせることができ、近年その需要も非常に高
まってきている。2. Description of the Related Art In recent years, brown hair whose hair has been bleached mainly by young people,
Furthermore, hair coloring such as coloring the entire hair with various colors or partially meshing the hair has become popular, and various hair dyes have been used in implementing these hair coloring. In general, hair dyeing methods are classified into permanent hair dyes, semi-permanent hair dyes, and temporary hair dyes from the viewpoint of the persistence of the color of colored hair. Although the color persistence is high, the hair dyeing operation is complicated, and has a drawback that once the hair dyeing has failed, it cannot be restored. On the other hand, the temporary hair dye is also easy to use, and can be easily washed off, especially by washing with shampoo, and its demand has been increasing in recent years.
【0003】従来、一時染毛剤は、カーボンブラック、
体質顔料やタール系色素を分散させた溶液状のものを専
用のブラシによって毛髪に塗布するか、又はエアゾール
噴射剤とともにエアゾール缶に充填したスプレー状のも
のを毛髪に塗布し、塗布後に乾燥させることによって色
材を固定させる手法がとられており、その組成物中に
は、固定力を強化するために種々の固着剤が添加されて
いるのが一般的である。[0003] Conventionally, temporary hair dyes are carbon black,
Apply a solution in which the extender or tar pigment is dispersed to the hair with a special brush, or apply a spray filled in an aerosol can together with an aerosol propellant to the hair and dry after application. In general, various fixing agents are added to the composition to enhance the fixing force.
【0004】例えば、特開昭63−218613号公報
及び特開昭63−218614号公報には、アクリル酸
等のアニオン性の重合性不飽和単量体とアクリル酸のア
ルキルエステルとの共重合体よりなるアニオン性樹脂と
顔料を含有した染毛剤組成物が、また、特開昭54−6
7039号公報及び特開昭60−36571号公報に
は、3級アミン含有メタクリレートのモノクロロ酢酸ア
ミン塩とアクリル酸のアルキルエステルとの共重合体よ
りなる両性イオン樹脂と顔料を含有した染毛剤組成物が
開示されている。For example, JP-A-63-218613 and JP-A-63-218614 disclose copolymers of an anionic polymerizable unsaturated monomer such as acrylic acid and an alkyl ester of acrylic acid. A hair dye composition containing an anionic resin and a pigment is disclosed in JP-A-54-6.
No. 7039 and JP-A-60-36571 disclose a hair dye composition containing a zwitterionic resin comprising a copolymer of a monochloroacetic acid amine salt of a tertiary amine-containing methacrylate and an alkyl ester of acrylic acid, and a pigment. Is disclosed.
【0005】[0005]
【発明が解決しようとする課題】しかしながら、これら
樹脂を固着剤として使用した染毛剤組成物は、固定力に
おいては十分な機能を有しているものの、服や布で擦ら
れた場合、顔料が移行して服を汚すという耐摩擦性、及
び樹脂同士が固着して毛髪のべとつきやごわつきによる
違和感を与えて感触を悪化させるという使用感について
問題点を有していた。また、ごわつき等の感触を良好に
しようとした場合、固着剤の配合量を下げることにより
解決されるが、組成物の粘性が低くなり、顔料が沈降
し、ムラ染めの原因となる等の問題点を有していた。However, the hair dye composition using these resins as a fixing agent has a sufficient function in fixing power, but when rubbed with clothes or cloths, it does However, there is a problem about friction resistance that causes migration and soiling of clothes, and a feeling of use in which resins adhere to each other to give a sense of incongruity due to stickiness or stiffness of the hair and deteriorate the feel. In addition, when an attempt is made to improve the feeling of stiffness or the like, the problem is solved by reducing the amount of the fixing agent. However, the viscosity of the composition becomes low, the pigment precipitates, and problems such as uneven dyeing are caused. Had a point.
【0006】現在市販されている一時染毛剤をみると、
着色剤としてカーボンブラック又はタール系色素を用い
たものがヘアーマスカラ剤として見受けられるが、これ
らは耐摩擦性に欠け、一度衣服につくと洗濯しても落ち
ないという問題点を有している。また、剤形としてスプ
レー状のものも見受けられるが、これらは部分的に染毛
することは極めて困難であり、且つ、ごわつきにより使
用感が劣っている。従って、隠蔽性や耐摩擦性に優れ、
べとつきやごわつきがなく、色ムラなく染毛でき、且つ
簡便に使用できるヘアーマスカラ組成物が強く望まれて
いる。[0006] Looking at temporary hair dyes currently on the market,
Hair colorants using carbon black or tar pigment as a coloring agent are found as hair mascara agents, but they have a problem in that they lack rub resistance and do not fall off even after washing once on clothes. Spray-like dosage forms are also found, but it is extremely difficult to partially dye the hair, and the feeling of use is inferior due to stiffness. Therefore, excellent concealing properties and friction resistance,
There is a strong demand for a hair mascara composition that is free of stickiness and stiffness, can dye hair without unevenness of color, and can be used easily.
【0007】[0007]
【課題を解決するための手段】係る現状において、本発
明者等は、鋭意研究を重ねた結果、特定の顔料とゲル化
剤(但し、キサンタンガムを除く。)及びフィルム形成
ポリマーとを特定比率で配合した一時染毛剤が上記課題
を解決することを見出し、さらにHLB値が12〜18
である非イオン性界面活性剤を併用することによりその
効果が増強されることを見出し、本発明を完成した。す
なわち上記課題は、本発明に係る、パール光沢を有する
顔料2〜40重量%、ゲル化剤(但し、キサンタンガム
を除く。)0.1〜5重量%、及びフィルム形成性ポリ
マー0.2〜5重量%を含有することを特徴とするヘア
ーマスカラ組成物、HLB値が12〜18である非イオ
ン性界面活性剤をさらに含有することを特徴とする同ヘ
アーマスカラ組成物によって解決される。Under the present circumstances, the present inventors have conducted intensive studies, and as a result, have determined that a specific pigment, a gelling agent (excluding xanthan gum) and a film-forming polymer at a specific ratio. It has been found that the blended temporary hair dye solves the above problems, and the HLB value is 12 to 18
The present inventors have found that the effect is enhanced by using a nonionic surfactant in combination, and completed the present invention. That is, the object is to provide a pigment having a pearl luster of 2 to 40% by weight according to the present invention, a gelling agent (however, xanthan gum).
except for. ) 0.1 to 5 wt%, and film-forming polymer 0.2-5 hair mascara composition characterized in that it contains% by weight, a nonionic surfactant having an HLB value is 12 to 18 further It is solved by the same hair mascara composition characterized by containing.
【0008】[0008]
【発明の実施の形態】以下発明の実施の形態を詳説す
る。本発明に使用するパール光沢を有する顔料は、以下
のものが挙げられる。 1.雲母チタン。 2.カルミン、コンジョウ、群青、黒酸化鉄、ベンガ
ラ、黄酸化鉄、酸化クロム、水酸化クロム等の無機顔料
より選ばれる一種又は二種以上の有色顔料で被覆された
雲母チタン。 3.アゾ顔料、酸性染料、フタロシアニン顔料、スレン
顔料、キナクリドン顔料、ジオキサジン顔料、イソイン
ドリノン顔料等の有機顔料又は有機染料から選ばれる一
種又は二種以上で被覆された雲母チタン。Embodiments of the present invention will be described below in detail. The pigment having a pearl luster used in the present invention includes the following. 1. Mica titanium. 2. Mica titanium coated with one or more colored pigments selected from inorganic pigments such as carmine, konjo, ultramarine, black iron oxide, red iron oxide, yellow iron oxide, chromium oxide, and chromium hydroxide. 3. Mica titanium coated with one or more organic pigments or organic dyes such as azo pigments, acid dyes, phthalocyanine pigments, sullen pigments, quinacridone pigments, dioxazine pigments and isoindolinone pigments.
【0009】これらのパール光沢を有する顔料のうち好
ましいものとしては、雲母チタン、カルミン,コンジョ
ウ,群青,黒酸化鉄,ベンガラ,黄酸化鉄,酸化クロ
ム,水酸化クロムからなる群より選ばれる一種又は二種
以上の有色顔料で被覆された雲母チタン、赤色404
号,赤色226号,赤色202号,赤色206号,黄色
401号,青色404号等の、遷移金属によるレーキを
なされていないアゾ染料から選ばれる一種又は二種以上
で被覆された雲母チタンである。Among these pigments having a pearly luster, preferred are those selected from the group consisting of titanium mica, carmine, konjo, ultramarine, black iron oxide, red iron oxide, yellow iron oxide, chromium oxide, and chromium hydroxide. Titanium mica coated with two or more colored pigments, red 404
No. 2, red 226, red 202, red 206, yellow 401, blue 404, etc., and mica titanium coated with one or two or more azo dyes not laked by a transition metal. .
【0010】これらのパール光沢を有する顔料は、一種
又は二種以上を混合して用いることができ、その配合量
は特に限定されるものではないが、本発明のヘアーマス
カラ組成物全量に対して2〜40重量%である。2重量
%未満では、目的とする隠蔽力が得られなく、また40
重量%を超えると使用上のびや付きが悪く均一に着色し
ない。These pigments having a pearl luster can be used alone or as a mixture of two or more kinds. The amount of the pigments is not particularly limited, but is based on the total amount of the hair mascara composition of the present invention. 2 to 40% by weight. If it is less than 2% by weight, the desired hiding power cannot be obtained and
If the content is more than 10% by weight, unevenness in use and poor coloring are not obtained.
【0011】本発明に使用するゲル化剤は、カルボキシ
ビニルポリマー,アルキルアクリル酸−アクリル酸共重
合体,ポリアクリル酸アミド,シェラック等が挙げられ
る。カルボキシビニルポリマーとしては、カーボポール
(B.F.グッドリッチケミカル社製),ハイビスワコ
ー(和光純薬製)、アルキルアクリル酸−アクリル酸共
重合体としては、PEMULEN(B.F.グッドリッ
チケミカル社製)、ポリアクリル酸アミドとしては、セ
ピゲル(セピック社製)の商品名等で市販されている。
これらのゲル化剤は、一種又は二種以上を混合して用い
ることができ、ゲル化剤の配合量は本発明に係る組成物
全量に対して0.1〜5重量%である。0.1重量%未
満では、顔料の沈殿等が発生し安定性上問題があり、5
重量%を超えると粘度が高く、使用上のびや付きが悪
い。The gelling agent used in the present invention includes carboxyvinyl polymer, alkylacrylic acid-acrylic acid copolymer, polyacrylamide, shellac and the like. Carbopol (manufactured by BF Goodrich Chemical Co., Ltd.) and Hibiswako (manufactured by Wako Pure Chemical Industries) as carboxyvinyl polymers, and PEMULEN (BF Goodrich Chemical Co., Ltd.) as alkylacrylic acid-acrylic acid copolymer. And polyacrylamide are commercially available under the trade name of Sepigel (Sepic).
These gelling agents can be used alone or in combination of two or more, and the compounding amount of the gelling agent is 0.1 to 5% by weight based on the total amount of the composition according to the present invention. If the amount is less than 0.1% by weight, precipitation of the pigment or the like occurs, and there is a problem in stability.
Exceeding the weight percent results in high viscosity and poor adhesion during use.
【0012】これらのゲル化剤は、中和剤とともに用い
られることが通常であり、例えば、ジイソプロパノール
アミン,トリエタノールアミン等のアルカノールアミン
類、アンモニア、水酸化カリウム、水酸化ナトリウム、
塩基性アミノ酸類(リジン,アルギニン等)、塩基性ポ
リペプチド等が挙げらる。中和剤の配合量は、使用した
ゲル化剤の種類によって適宜変更されるものであるが、
通常、ゲル化剤重量に対して0.2〜5倍の比率で配合
される。These gelling agents are usually used together with a neutralizing agent, for example, alkanolamines such as diisopropanolamine and triethanolamine, ammonia, potassium hydroxide, sodium hydroxide,
Basic amino acids (lysine, arginine, etc.), basic polypeptides and the like can be mentioned. The amount of the neutralizing agent is appropriately changed depending on the type of the gelling agent used,
Usually, it is blended at a ratio of 0.2 to 5 times the weight of the gelling agent.
【0013】本発明に使用するフィルム形成性ポリマー
としては、ノニオン性高分子化合物と両性高分子化合物
が特に好ましいものとして挙げられる。ノニオン性高分
子化合物としては、例えば、ポリビニルピロリドン(ル
ビスコールK、BASF社製)、ビニルピロリドンと酢
酸ビニルとの共重合体(ルビスコールVA、BASF社
製)、及びビニルピロリドンとジメチルアミノエチルメ
タクリレートとの共重合体(コポリマー937、ISP
社製)が挙げられる。両性高分子化合物としては、ジア
ルキルアミノエチルメタクリレート重合体のモノクロル
酢酸両性化物(ユカフォーマー、三菱化学社製)が挙げ
られる。As the film-forming polymer used in the present invention, nonionic polymer compounds and amphoteric polymer compounds are particularly preferred. Examples of the nonionic polymer compound include polyvinylpyrrolidone (Rubiscol K, manufactured by BASF), a copolymer of vinylpyrrolidone and vinyl acetate (Rubiscol VA, manufactured by BASF), and vinylpyrrolidone and dimethylaminoethyl methacrylate. (Copolymer 937, ISP
Company). Examples of the amphoteric polymer compound include a monoalkylacetic acid amphoteric product of a dialkylaminoethyl methacrylate polymer (Yuka Former, manufactured by Mitsubishi Chemical Corporation).
【0014】ノニオン高分子化合物は、ゲル化剤の粘度
を損なわない点で両性高分子化合物よりも好ましい。The nonionic polymer compound is preferable to the amphoteric polymer compound in that the nonionic polymer compound does not impair the viscosity of the gelling agent.
【0015】これらのフィルム形成性ポリマーの配合量
は、本発明に係る組成物全量に対して0.2〜5重量%
である。0.2重量%未満では充分な効果が得られな
く、5重量%を超えて配合するとごわつき等が発生して
毛髪の感触が低下する。The amount of the film-forming polymer is from 0.2 to 5% by weight based on the total amount of the composition according to the present invention.
It is. If the content is less than 0.2% by weight, sufficient effects cannot be obtained. If the content is more than 5% by weight, stiffness or the like is generated and the feel of hair is reduced.
【0016】本発明のヘアーマスカラ組成物には、更に
非イオン性界面活性剤を配合すると更に安定性を向上
し、ごわつきを減少させることができる。非イオン性界
面活性剤は、HLB値が12〜18の範囲にあるもので
あり、この範囲を外れると顔料の分散性及び毛髪への均
一な染着性が劣る。本発明に用いられるHLB値が12
〜18である非イオン界面活性剤としては、例えば、ポ
リオキシエチレンセチルエーテル(12〜30E.
O.),ポリオキシエチレンオレイルエーテル(15〜
50E.O.),ポリオキシエチレンステアリルエーテ
ル(15〜50E.O.),ポリオキシエチレンノニル
フェニルエーテル(10〜40E.O.),ポリオキシ
エチレンオクチルフェニルエーテル(10〜30E.
O.),ポリオキシエチレンラウリルエーテル(10〜
30E.O.)、ポリオキシエチレンイソステアリルエ
ーテル(15〜35E.O.),ポリオキシエチレンペ
ンタデシルエーテル(20〜40E.O.),ポリオキ
シエチレンベヘニルエーテル(18〜40E.O.),
ポリオキシエチレンコレステリルエーテル(20〜40
E.O.)等のポリオキシエチレンアルキルエーテル、
ポリオキシエチレン(15〜50E.O.)モノステア
レート,ポリオキシエチレン(30〜100E.O.)
ジステアレート,ポリオキシエチレン(12〜30E.
O.)モノイソステアレート等の脂肪酸ポリエチレング
リコール、ポリオキシエチレン(15〜50E.O.)
グリセリルモノシソステアレート,ポリオキシエチレン
(40〜80E.O.)グリセリルトリイソステアレー
ト等の脂肪酸ポリオキシエチレングリセリル、ポリオキ
シエチレン(15〜40E.O.)ソルビタンものラウ
レート等のポリオキシエチレンソルビタン脂肪酸エステ
ル、ポリオキシエチレンソルビットテトラオレエート
(20〜40E.O.),ポリオキシエチレンソルビッ
トテトラステアレート(20〜60E.O.)等のポリ
オキシエチレンソルビット脂肪酸エステル、ポリオキシ
エチレン硬化ヒマシ油(40〜100E.O.)等のポ
リオキシエチレン硬化ヒマシ油、ポリオキシエチレンラ
ノリン(15〜35E.O.),ポリオキシエチレンラ
ノリンアルコール(15〜40E.O.)等のポリオキ
シエチレンラノリン誘導体等が挙げられる。好ましい非
イオン性界面活性剤としては、顔料の分散性の点で、ポ
リオキシエチレンソルビタンモノステアレート(20
E.O.),ポリオキシエチレン硬化ヒマシ油(60
E.O.)等が挙げられる。When the hair mascara composition of the present invention further contains a nonionic surfactant, stability can be further improved and stiffness can be reduced. The nonionic surfactant has an HLB value in the range of 12 to 18. When the HLB value is out of this range, the dispersibility of the pigment and the uniform dyeing property on the hair are inferior. The HLB value used in the present invention is 12
Examples of the nonionic surfactant of No. 18 include polyoxyethylene cetyl ether (12 to 30E.
O. ), Polyoxyethylene oleyl ether (15-
50E. O. ), Polyoxyethylene stearyl ether (15 to 50 EO), polyoxyethylene nonyl phenyl ether (10 to 40 EO), polyoxyethylene octyl phenyl ether (10 to 30 EO).
O. ), Polyoxyethylene lauryl ether (10-
30E. O. ), Polyoxyethylene isostearyl ether (15 to 35 EO), polyoxyethylene pentadecyl ether (20 to 40 EO), polyoxyethylene behenyl ether (18 to 40 EO),
Polyoxyethylene cholesteryl ether (20-40
E. FIG. O. ) And other polyoxyethylene alkyl ethers,
Polyoxyethylene (15 to 50 EO) monostearate, polyoxyethylene (30 to 100 EO)
Distearate, polyoxyethylene (12-30E.
O. ) Fatty acid polyethylene glycol such as monoisostearate, polyoxyethylene (15 to 50 EO)
Fatty acid polyoxyethylene glyceryl such as glyceryl monosisostearate, polyoxyethylene (40-80 EO) glyceryl triisostearate, polyoxyethylene sorbitan such as polyoxyethylene (15-40 EO) sorbitan laurate Fatty acid esters, polyoxyethylene sorbite tetraoleate (20 to 40 EO), polyoxyethylene sorbite fatty acid esters such as polyoxyethylene sorbite tetrastearate (20 to 60 EO), polyoxyethylene hydrogenated castor oil ( Polyoxyethylene hydrogenated castor oil such as 40 to 100 EO, polyoxyethylene lanolin such as polyoxyethylene lanolin (15 to 35 EO) and polyoxyethylene lanolin alcohol (15 to 40 EO) Conductor, and the like. Preferred nonionic surfactants include polyoxyethylene sorbitan monostearate (20) in view of the dispersibility of the pigment.
E. FIG. O. ), Polyoxyethylene hydrogenated castor oil (60
E. FIG. O. ) And the like.
【0017】これらの非イオン性界面活性剤は、一種又
は二種以上を混合して用いることができ、その配合量
は、本発明に係る組成物全量に対して0.1〜5重量%
が好ましい。0.1重量%未満では、顔料の分散性が悪
く顔料が不均一となる場合があり、また5重量%を超え
るとべたつきを生じたり、耐摩擦性が低下したりして好
ましくない場合がある。These nonionic surfactants can be used singly or as a mixture of two or more. The compounding amount is 0.1 to 5% by weight based on the total amount of the composition according to the present invention.
Is preferred. If it is less than 0.1% by weight, the dispersibility of the pigment may be poor and the pigment may be non-uniform. If it exceeds 5% by weight, stickiness may occur or friction resistance may decrease, which is not preferable. .
【0018】本発明の組成物中には、例えば上記成分の
他に、本発明の効果を損なわない範囲で、乳化安定化の
為の乳化剤、色調安定化の為の色剤を添加することがで
きる。乳化剤としてはアニオン性,両性,カチオン性の
いずれの界面活性剤をも使用することができる。色剤と
しては、種々のタール系色素を使用することができる。In the composition of the present invention, besides the above components, for example, an emulsifier for stabilizing the emulsification and a colorant for stabilizing the color tone may be added within a range not to impair the effects of the present invention. it can. As the emulsifier, any of anionic, amphoteric and cationic surfactants can be used. Various tar dyes can be used as the coloring agent.
【0019】また、商品価値を高める為に、香料、又は
色素を添加しても良い。更に、組成物の経日的変質を防
止するために防腐剤、金属イオン封鎖剤、pH調製剤、
紫外線吸収剤、酸化防止剤、グリセリン,プロピレング
リコール等の湿潤剤を添加することもできる。In order to increase the commercial value, a fragrance or a pigment may be added. Further, a preservative, a sequestering agent, a pH adjusting agent,
Ultraviolet absorbers, antioxidants, humectants such as glycerin and propylene glycol can also be added.
【0020】以下に本発明を実施例をもって詳細に説明
するが、本発明はこれらにより限定されるものではな
い。実施例に先立って各実施例で採用した試験法を説明
する。Hereinafter, the present invention will be described in detail with reference to Examples, but the present invention is not limited thereto. Prior to the examples, test methods adopted in each example will be described.
【0021】(1)隠蔽力(試験法) 染色に使用するヘアーマスカラ組成物の試料をガラス板
に0.2mmの厚さで均一な皮膜を作製し、一昼夜乾燥
した後、色彩色差計を用いて、皮膜の明度(La)を測
定した。次に、長さ10cm、重さ1gの毛束の明度
(Lb)を測定した後に、ヘアーマスカラ組成物の試料
0.5gを均等に塗布し、25℃、RH60%の条件下
で1時間放置して乾燥させた。乾燥後、色彩色差計を用
いて、染色した毛髪の明度(Lc)を測定した。次に以
下の式に従って、染色による隠蔽力を求めた。この場
合、値が高いほど隠蔽力が高いことを示す。 式 : 隠蔽力=(Lc−La)×100/(Lb−L
a) 尚、評価基準は、以下の通りである。 ◎:極めて良好 隠蔽力90%以上 ○:良好 隠蔽力80%以上、90%未満 △:やや悪い 隠蔽力50%以上、80%未満 ×:悪い 隠蔽力50%未満(1) Hiding power (test method) A sample of the hair mascara composition to be used for dyeing was formed into a uniform film of 0.2 mm thickness on a glass plate, dried all day and night, and then used with a colorimeter. The lightness (La) of the film was measured. Next, after measuring the lightness (Lb) of a hair bundle having a length of 10 cm and a weight of 1 g, a 0.5 g sample of the hair mascara composition was evenly applied and left at 25 ° C. and RH 60% for 1 hour. And dried. After drying, the lightness (Lc) of the dyed hair was measured using a colorimeter. Next, the hiding power by dyeing was determined according to the following equation. In this case, the higher the value, the higher the hiding power. Formula: Hiding power = (Lc−La) × 100 / (Lb−L)
a) The evaluation criteria are as follows. :: extremely good hiding power 90% or more ○: good hiding power 80% or more, less than 90% Δ: somewhat poor hiding power 50% or more, less than 80% ×: poor hiding power less than 50%
【0022】(2)耐摩擦性(試験法) 長さ10cm、重さ1gの毛束にヘアーマスカラ組成物
の試料0.5gを均等に塗布し、25℃、RH60%の
条件下で1時間放置して乾燥させた。次にこの染色毛髪
に木綿の布を擦り付け、布に付着した顔料の量を目視に
より判断した。尚、評価基準は、以下のとおりである。 ◎:極めて良好 全く転着ない ○:良好 殆ど転着なし △:やや悪い やや転着する ×:悪い 転着量が大きい(2) Friction Resistance (Test Method) A 0.5 g sample of the hair-mascara composition was evenly applied to a hair bundle having a length of 10 cm and a weight of 1 g, and subjected to 1 hour at 25 ° C. and RH 60%. Leave to dry. Next, a cotton cloth was rubbed against the dyed hair, and the amount of pigment adhering to the cloth was visually determined. The evaluation criteria are as follows. ◎: Very good, no transfer ○: Good, almost no transfer △: Slightly poor Slightly transferable ×: Bad Large transfer amount
【0023】(3)安定性(試験法) ヘアーマスカラ組成物の安定性に関しては、50℃の恒
温糟にて静置し、2ヶ月経過した後に、その性状につい
て検査した。尚、評価基準は、以下のとおりである。 ○:良好 分離、変色及び粘度低下がない ×:悪い 分離、変色及び粘度低下の発生あり(3) Stability (Test Method) Regarding the stability of the hair mascara composition, the composition was allowed to stand in a constant temperature bath at 50 ° C., and after 2 months had passed, the properties were examined. The evaluation criteria are as follows. :: good No separation, no discoloration and no decrease in viscosity ×: poor separation, discoloration and a decrease in viscosity occurred
【0024】(4)官能試験(べたつき及びごわつきの
評価) 20名の被験者によってヘアーマスカラ組成物の試料を
使用し、部分的に染毛を実施した。その後被験者本人
が、べたつき及びごわつきについて官能評価した。尚、
評価基準は、以下の通りである。 ◎:極めて良好 べたつきがない又はごわつかないと答えた被験者の数が17人 以上 ○:良好 べたつきがない又はごわつかないと答えた被験者の数が12人 以上、17人未満 △:やや悪い べたつきがない又はごわつかないと答えた被験者の数が8人以 上、12人未満 ×:悪い べたつきがない又はごわつかないと答えた被験者の数が8人未 満(4) Sensory test (evaluation of stickiness and stiffness) A sample of the hair-mascara composition was used by 20 subjects to partially dye hair. Thereafter, the subject himself made a sensory evaluation of stickiness and stiffness. still,
The evaluation criteria are as follows. ◎: Very good The number of subjects who answered no stickiness or no stickiness was 17 or more ○: The number of subjects who answered no sticky or no stickiness was 12 or more and less than 17 △: Somewhat bad sticky Or, the number of subjects who answered that they were not confused was 8 or more and less than 12 ×: Bad The number of subjects who answered no stickiness or was not confused was less than 8
【0025】[0025]
実施例1〜4、比較例1〜4 下記表1に示す組成のヘアーマスカラ組成物を常法によ
り調製し、マスカラ容器に充填し、マスカラブラシを用
いて試料を毛髪に塗布し、隠蔽力、耐摩擦性、安定性及
び官能試験(べたつき及びごわつきの評価)について評
価を行った。Examples 1 to 4, Comparative Examples 1 to 4 A hair mascara composition having the composition shown in Table 1 below was prepared by a conventional method, filled in a mascara container, and a sample was applied to the hair using a mascara brush. The rub resistance, stability and sensory test (evaluation of stickiness and stiffness) were evaluated.
【0026】[0026]
【表1】 [Table 1]
【0027】表1より明らかなように本発明のヘアーマ
スカラ組成物(実施例1〜4)はいずれも優れた性能を
有していた。一方、必須成分のいずれかを欠いた比較例
では、隠蔽力、耐摩擦性、安定性及び官能試験(べたつ
き及びごわつきの評価)において劣っている項目があり
本発明の目的を達成できなかった。As is clear from Table 1, the hair mascara compositions (Examples 1 to 4) of the present invention all had excellent performance. On the other hand, in Comparative Examples lacking any of the essential components, there were inferior items in hiding power, friction resistance, stability and sensory tests (evaluation of stickiness and stiffness), and the object of the present invention could not be achieved.
【0028】実施例5〜8、比較例5〜8 下記表2に示す組成のヘアーマスカラ組成物を常法によ
り調製し、隠蔽力、耐摩擦性、安定性及び官能試験(べ
たつき及びごわつきの評価)について評価を行った。Examples 5 to 8 and Comparative Examples 5 to 8 Hair mascara compositions having the compositions shown in Table 2 below were prepared by conventional methods, and were evaluated for hiding power, rub resistance, stability and sensory tests (evaluation of stickiness and stiffness). ) Was evaluated.
【0029】[0029]
【表2】 [Table 2]
【0030】表2より明らかなように本発明のヘアーマ
スカラ組成物(実施例5〜8)は、いずれも優れた性能
を有していた。一方、必須成分のいずれかを欠いた、又
は配合量範囲を逸脱した比較例では、隠蔽力、耐摩擦
性、安定性及び官能試験(べたつき及びごわつきの評
価)において劣っている項目があり本発明の目的を達成
できなかった。As is clear from Table 2, the hair mascara compositions of the present invention (Examples 5 to 8) all had excellent performance. On the other hand, in Comparative Examples which lack any of the essential components or deviate from the compounding amount range, there are some items which are inferior in hiding power, abrasion resistance, stability and sensory test (evaluation of stickiness and stiffness). Was unable to achieve its goal.
【0031】実施例9〜14、比較例9〜10 下記表3に示す組成のヘアーマスカラ組成物を常法によ
り調製し、隠蔽力、耐摩擦性、安定性及び官能試験(べ
たつき及びごわつきの評価)について評価を行った。Examples 9 to 14 and Comparative Examples 9 to 10 Hair mascara compositions having the compositions shown in Table 3 below were prepared by conventional methods, and were evaluated for hiding power, rub resistance, stability and sensory tests (evaluation of stickiness and stiffness). ) Was evaluated.
【0032】[0032]
【表3】 [Table 3]
【0033】表3より明らかなように本発明のヘアーマ
スカラ組成物(実施例9〜14)はいずれも優れた性能
を有していた。一方、必須成分のいずれかを欠いた、又
は配合量範囲を逸脱した比較例では、隠蔽力、耐摩擦
性、安定性及び官能試験(べたつき及びごわつきの評
価)において劣っている項目があり本発明の目的を達成
できなかった。As is clear from Table 3, the hair mascara compositions of the present invention (Examples 9 to 14) all had excellent performance. On the other hand, in Comparative Examples which lack any of the essential components or deviate from the compounding amount range, there are some items which are inferior in hiding power, abrasion resistance, stability and sensory test (evaluation of stickiness and stiffness). Was unable to achieve its goal.
【0034】[0034]
【発明の効果】以上記載のごとく、本発明が、隠蔽性、
耐摩擦性、安定性に優れ、且つべとつきやごわつきがな
い感触に優れたヘアーマスカラ組成物を提供できること
は明らかである。As described above, the present invention provides a concealing property,
It is clear that a hair mascara composition having excellent rub resistance and stability and excellent feeling without stickiness or stiffness can be provided.
Claims (2)
ゲル化剤(但し、キサンタンガムを除く。)0.1〜5
重量%、及びフィルム形成性ポリマー0.2〜5重量%
を含有することを特徴とするヘアーマスカラ組成物。1. A pigment having a pearl luster of 2 to 40% by weight,
Gelling agent (excluding xanthan gum) 0.1 to 5
Wt%, and 0.2-5 wt% of a film-forming polymer
A hair mascara composition comprising:
面活性剤を含有する請求項1記載のヘアーマスカラ組成
物。2. The hair mascara composition according to claim 1, which contains a nonionic surfactant having an HLB value of 12 to 18.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP21471097A JP3277143B2 (en) | 1997-08-08 | 1997-08-08 | Hair mascara composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP21471097A JP3277143B2 (en) | 1997-08-08 | 1997-08-08 | Hair mascara composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH1149651A JPH1149651A (en) | 1999-02-23 |
JP3277143B2 true JP3277143B2 (en) | 2002-04-22 |
Family
ID=16660339
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP21471097A Expired - Lifetime JP3277143B2 (en) | 1997-08-08 | 1997-08-08 | Hair mascara composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3277143B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7702095B2 (en) | 2003-01-30 | 2010-04-20 | Mosaid Technologies Incorporated | Method and system for providing DC power on local telephone lines |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4895669B2 (en) * | 2006-04-28 | 2012-03-14 | 株式会社マンダム | Temporary hair dyeing composition |
JP4714076B2 (en) * | 2006-05-16 | 2011-06-29 | ホーユー株式会社 | Hair coating composition |
KR101427570B1 (en) * | 2007-11-30 | 2014-08-08 | (주)아모레퍼시픽 | Conditioner composition for dying hair |
-
1997
- 1997-08-08 JP JP21471097A patent/JP3277143B2/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7702095B2 (en) | 2003-01-30 | 2010-04-20 | Mosaid Technologies Incorporated | Method and system for providing DC power on local telephone lines |
US8107618B2 (en) | 2003-01-30 | 2012-01-31 | Mosaid Technologies Incorporated | Method and system for providing DC power on local telephone lines |
US8787562B2 (en) | 2003-01-30 | 2014-07-22 | Conversant Intellectual Property Management Inc. | Method and system for providing DC power on local telephone lines |
Also Published As
Publication number | Publication date |
---|---|
JPH1149651A (en) | 1999-02-23 |
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