JP3226745B2 - Semiconductor cold electron-emitting device and device using the same - Google Patents
Semiconductor cold electron-emitting device and device using the sameInfo
- Publication number
- JP3226745B2 JP3226745B2 JP5009395A JP5009395A JP3226745B2 JP 3226745 B2 JP3226745 B2 JP 3226745B2 JP 5009395 A JP5009395 A JP 5009395A JP 5009395 A JP5009395 A JP 5009395A JP 3226745 B2 JP3226745 B2 JP 3226745B2
- Authority
- JP
- Japan
- Prior art keywords
- semiconductor
- electron
- emitting
- layer
- cold electron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Description
【0001】[0001]
【産業上の利用分野】本発明は、半導体による電子放出
素子に関するものである。さらに詳しくは、本発明は、
加熱を必要としない冷電子放出源として有用なだけでな
く、発光・電子放出機能集積素子としても有用な新規な
半導体素子に関するものである。具体的な利用分野は、
発光形フラットパネルディスプレイ素子(装置)、真空
マイクロエレクトロニクス素子(装置)、極高真空計測
用電子源等である。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a semiconductor electron-emitting device. More specifically, the present invention provides
The present invention relates to a novel semiconductor device that is useful not only as a cold electron emission source that does not require heating but also as a light emitting / electron emitting function integrated device. Specific fields of use are:
Light-emitting flat panel display devices (devices), vacuum microelectronic devices (devices), electron sources for ultra-high vacuum measurement, and the like.
【0002】[0002]
【従来の技術】加熱を必要としない冷電子放出源につい
ては、従来から平面形発光ディスプレイ素子や真空マイ
クロエレクトロニクス素子などの電子放出源として、そ
の開発が望まれており、実際に種々の素子が提案・試作
されてきた。2. Description of the Related Art Development of a cold electron emission source which does not require heating has conventionally been desired as an electron emission source such as a flat light emitting display device or a vacuum microelectronic device. It has been proposed and prototyped.
【0003】その代表的なものとして、金属又は半導体
の電界放出チップアレイ及びシリコンのpn接合又はM
OS(Metal−Oxide−Semiconduc
tor)の構造素子の2つが挙げられる。As typical examples, a metal or semiconductor field emission chip array and a silicon pn junction or M
OS (Metal-Oxide-Semiconductor)
tor).
【0004】[0004]
【発明が解決しようとする課題】しかしながら、前者の
電界放出チップアレイは、製作工程が複雑である。
電子放出特性が真空度に敏感である。安定な動作には
超高真空が必要である。動作電界が高いといった問題
がある。However, the former field emission chip array has a complicated manufacturing process.
The electron emission characteristics are sensitive to the degree of vacuum. Ultrahigh vacuum is required for stable operation. There is a problem that the operating electric field is high.
【0005】また、後者のpn接合およびMOSの構造
素子は、集積回路作製に準じた多くの製作工程と装置
が必要である。素子構造のパラメータ(接合深さ、酸
化膜の厚さ等)の厳密制御の必要性がある等のため、コ
スト低減の点や応用範囲の面で大きな制約と限界があっ
た。[0005] The latter pn junction and MOS structural elements require many manufacturing steps and devices in conformity with integrated circuit fabrication. Because of the necessity of strict control of the parameters of the device structure (such as the junction depth and the thickness of the oxide film), there have been great restrictions and limitations in terms of cost reduction and application range.
【0006】これらの問題を克服することは、冷電子放
出素子を本格的に進展させる上で不可欠である。また、
単なる電子放出機能だけではなく、付加的な機能をも兼
ね備えた冷電子放出素子を志向することも重要な技術課
題であると思われる。[0006] Overcoming these problems is indispensable for developing cold electron-emitting devices in earnest. Also,
It is also considered to be an important technical issue to aim for a cold electron-emitting device having not only an electron emission function but also an additional function.
【0007】このような観点から、研究開発の現状を見
た場合、これまでのところ上記課題に応える提案は、ほ
とんどなされていないのが現状である。[0007] From the above point of view, looking at the current state of research and development, almost no proposals have been made so far to address the above problems.
【0008】本発明は、以上の事情に鑑みてなされたも
のであり、冷電子放出素子の新しい展開を可能にすると
ともに、半導体応用分野の拡大を図り得る半導体冷電子
放出素子及びこれを用いた装置を提供することを目的と
している。The present invention has been made in view of the above circumstances, and enables a new development of a cold electron emitting device and a semiconductor cold electron emitting device capable of expanding the field of application of a semiconductor. It is intended to provide a device.
【0009】[0009]
【課題を解決するための手段】本発明は、上記目的を達
成するために、 (1)半導体冷電子放出素子において、半導体基板と、
この半導体基板の表面を陽極酸化処理により多孔質化し
た、厚膜の単一層からなる多孔質半導体層と、この多孔
質半導体層上に形成される金属薄膜電極と、前記半導体
基板の裏面に形成されるオーミック電極と、前記金属薄
膜電極に対向して配置され、真空雰囲気でこの金属薄膜
電極からの放出電子を捕獲するコレクタ電極とを具備す
るようにしたものである。According to the present invention, there is provided a semiconductor cold electron emission device comprising: a semiconductor substrate;
The surface of the semiconductor substrate is made porous by anodizing treatment, a porous semiconductor layer composed of a single layer of a thick film , a metal thin film electrode formed on the porous semiconductor layer, and formed on the back surface of the semiconductor substrate. And a collector electrode arranged to face the metal thin-film electrode and capture electrons emitted from the metal thin-film electrode in a vacuum atmosphere.
【0010】(2)上記(1)記載の半導体冷電子放出
素子は、面状又は点状の冷電子放出ダイオードである。( 2 ) The semiconductor cold electron-emitting device according to the above (1) is a planar or point-shaped cold electron-emitting diode.
【0011】(3)上記(2)記載の半導体冷電子放出
素子を、半導体基板面上に多数配列し、それらを電子放
出源として利用する発光形フラットパネルディスプレイ
(素子)装置を得るようにしたものである。( 3 ) A large number of the semiconductor cold electron-emitting devices described in the above ( 2 ) are arranged on the surface of a semiconductor substrate, and a light-emitting flat panel display (device) device using them as an electron-emitting source is obtained. Things.
【0012】[0012]
【作用】本発明は、半導体の陽極酸化処理によって形成
される多孔質半導体(例えば多孔質シリコン)が、量子
サイズ効果の発現により特異な電気的・光学的性質を示
すことに着目してなされたものである。The present invention has been made by paying attention to the fact that a porous semiconductor (for example, porous silicon) formed by anodizing a semiconductor exhibits specific electrical and optical properties due to the development of a quantum size effect. Things.
【0013】本発明の半導体冷電子放出素子は、基本的
には多孔質半導体を高抵抗層として用いた一種のMIS
(Metal−Insulator−Semicond
uctor)ダイオード構造の素子であり、金属薄膜/
多孔質半導体/半導体基板をその構成要素にしている。The semiconductor cold electron emission device of the present invention is basically a kind of MIS using a porous semiconductor as a high resistance layer.
(Metal-Insulator-Semicond
uctor) element having a diode structure and a metal thin film /
The component is a porous semiconductor / semiconductor substrate.
【0014】そこで、半導体基板から注入された電子を
多孔質半導体中の電界で加速し、金属薄膜中をトンネル
効果によって通過させ真空中に放出させるようにしてい
る。Therefore, electrons injected from the semiconductor substrate are accelerated by an electric field in the porous semiconductor, pass through the metal thin film by a tunnel effect, and are emitted into a vacuum.
【0015】本発明により、複雑な工程は不要であ
る。素子構成が単純である。大面積化・多画素化が
容易である。超高真空を必要としない。発光ダイオ
ードとしても機能する等の特徴を持つ冷電子放出素子を
実現することができる。According to the present invention, no complicated steps are required. The element configuration is simple. It is easy to increase the area and increase the number of pixels. Does not require ultra-high vacuum. A cold electron-emitting device having features such as functioning as a light-emitting diode can be realized.
【0016】[0016]
【実施例】以下、本発明の実施例を図面を参照しながら
説明する。Embodiments of the present invention will be described below with reference to the drawings.
【0017】図1は本発明の実施例を示す半導体冷電子
放出素子の構成を示す図である。FIG. 1 is a diagram showing a configuration of a semiconductor cold electron emission device according to an embodiment of the present invention.
【0018】この図に示すように、裏面にオーミック電
極をとった面方位(111)のn形シリコン基板(n形
シリコンウエハ)(比抵抗が0.0018Ωcm)1表
面に、50wt%HF水溶液とエタノールとの混合液
(混合比は1:1)中で定電流陽極酸化処理(電流密度
は100mA/cm2 、時間は5min)を施し、多孔
質シリコン層(以下、PS層という)2を形成する。陽
極酸化中には500Wのタングステンランプにより試料
面を光照射する。PS層2の厚さは約40μmである。
作製したPS層2の表面にAu薄膜を真空蒸着し(厚さ
15nm、直径6mmの円形)、これを表面側の正電位
VPSにあるAu薄膜電極3として裏面の接地電位にある
オーミック電極4との間でダイオードを形成する。As shown in FIG. 1, an n-type silicon substrate (n-type silicon wafer) (specific resistance: 0.0018 Ωcm) having a plane orientation of (111) with an ohmic electrode on the back surface is coated with a 50 wt% HF aqueous solution. A constant current anodic oxidation treatment (current density: 100 mA / cm 2 , time: 5 min) is performed in a mixed solution with ethanol (mixing ratio: 1: 1) to form a porous silicon layer (hereinafter, referred to as PS layer) 2. I do. During the anodization, the sample surface is irradiated with light by a 500 W tungsten lamp. The thickness of the PS layer 2 is about 40 μm.
An Au thin film is vacuum-deposited (circle having a thickness of 15 nm and a diameter of 6 mm) on the surface of the produced PS layer 2, and is used as an Au thin film electrode 3 having a positive potential V PS on the front surface side and an ohmic electrode 4 having a ground potential on the back surface. And a diode is formed between them.
【0019】ここで、真空チャンバー10を用いて、1
0-7Torrの雰囲気におかれる。Here, using the vacuum chamber 10, 1
Place in an atmosphere of 0 -7 Torr.
【0020】そこで、このダイオードのAu薄膜電極3
に正電圧VPSを印加し、n形シリコン基板1からPS層
2に電子を注入する。その際の電流はIPSである。その
場合、PS層2は高抵抗であるので、印加電界の大部分
はPS層2にかかっているが、PS層2の表面には酸化
層が存在するため、図2のエネルギーバンド図に示すよ
うに、電界強度はPS層2表面ほど強い。Therefore, the Au thin film electrode 3 of this diode
Is applied with a positive voltage V PS to inject electrons from the n-type silicon substrate 1 into the PS layer 2. The current at that time is I PS . In this case, since the PS layer 2 has a high resistance, most of the applied electric field is applied to the PS layer 2, but since an oxide layer exists on the surface of the PS layer 2, the energy band shown in FIG. As described above, the electric field strength is higher on the PS layer 2 surface.
【0021】更に、n形シリコン基板1から注入された
電子は、Au薄膜電極3側に向けてPS層2を走行し、
Au薄膜電極3側に向かう。PS層2表面付近に達した
電子は、そこでの強電界により一部はAu薄膜電極3を
トンネルし、真空チャンバー10の10-7Torrの雰
囲気の真空中に放出される。放出された電子はAu薄膜
電極3に対し数Vの正電圧Vcを印加してあるコレクタ
電極5に集められる。その際の電流はIEMである。Further, electrons injected from the n-type silicon substrate 1 travel through the PS layer 2 toward the Au thin-film electrode 3 side.
It goes to the Au thin film electrode 3 side. Some of the electrons that have reached the vicinity of the surface of the PS layer 2 tunnel through the Au thin-film electrode 3 due to the strong electric field there, and are emitted into the vacuum chamber 10 in a vacuum of 10 −7 Torr. The emitted electrons are collected by the collector electrode 5 to which a positive voltage Vc of several volts is applied to the Au thin film electrode 3. The current at that time is IEM .
【0022】図3に放出電子流のVPS依存性を示す。図
3において、10-7Torrの雰囲気で、横軸はV
PS(V)、縦軸は放出電子流(nA/cm2 )を示す。FIG. 3 shows the V PS dependence of the emitted electron current. In FIG. 3, in an atmosphere of 10 −7 Torr, the horizontal axis represents V
PS (V), the vertical axis indicates the emitted electron current (nA / cm 2 ).
【0023】電子放出はVPSが正の領域のみで観測さ
れ、電圧の上昇とともに放出電子流は急激に増大する。
この放出電子流−電圧曲線の理論的な解析結果により、
電子放出がトンネル効果によるものであることが裏付け
られた。Electron emission is observed only in the region where V PS is positive, and the emitted electron current sharply increases as the voltage increases.
According to the theoretical analysis result of this emitted electron current-voltage curve,
It was confirmed that the electron emission was due to the tunnel effect.
【0024】図1のコレクタ電極5に蛍光体を塗布し、
Au薄膜電極3とコレクタ電極5の間に約4kVの電圧
を印加した状態でダイオードから電子放出をさせたとこ
ろ、Au薄膜電極3に対応する円形の均一な蛍光パター
ンが観測された。A phosphor is applied to the collector electrode 5 of FIG.
When electrons were emitted from the diode while a voltage of about 4 kV was applied between the Au thin film electrode 3 and the collector electrode 5, a circular uniform fluorescent pattern corresponding to the Au thin film electrode 3 was observed.
【0025】このことは、PS層2からの電子放出が均
一であることを示すとともに、平面ディスプレイ素子の
電子源としての応用可能性を実証するものである。This shows that the electron emission from the PS layer 2 is uniform and also demonstrates the applicability of the flat display element as an electron source.
【0026】本発明の平面ディスプレイへの応用例を図
4に示す。FIG. 4 shows an application example of the present invention to a flat display.
【0027】この図において、11はオーミック電極、
12はシリコン基板、13は多孔質シリコン層、14は
薄膜電極、15は信号供給源回路、16は蛍光体、17
は電子ビーム加速電圧を供給する電源、18はガラス板
である。In this figure, 11 is an ohmic electrode,
12 is a silicon substrate, 13 is a porous silicon layer, 14 is a thin film electrode, 15 is a signal supply circuit, 16 is a phosphor, 17
Is a power supply for supplying an electron beam acceleration voltage, and 18 is a glass plate.
【0028】この図に示すように、信号供給源回路1
5,15から画像に応じた電気信号がX方向、Y方向か
ら薄膜電極14を通じて供給される。各交点(画素)で
は、供給された電圧に対応して、図1及び図2の原理に
基づいて電子が放出される。放出された電子は加速され
て蛍光体16を発光させ、観測者はそのパターンを画像
として見ることができる。As shown in this figure, the signal supply circuit 1
Electric signals corresponding to the images are supplied from the X-ray direction and the Y-direction through the thin-film electrode from the thin-film electrodes. At each intersection (pixel), electrons are emitted based on the principle of FIGS. 1 and 2 corresponding to the supplied voltage. The emitted electrons are accelerated to cause the phosphor 16 to emit light, and the observer can see the pattern as an image.
【0029】このディスプレイ素子はシリコン基板とガ
ラス基板を基本要素とするもので、薄形、かつ大面積に
構成できることを特徴としている。This display element has a silicon substrate and a glass substrate as basic elements, and is characterized in that it can be made thin and has a large area.
【0030】また、多画素化も容易であり、高解像度も
期待できる。Further, it is easy to increase the number of pixels, and high resolution can be expected.
【0031】なお、本発明の冷電子源による平面ディス
プレイの構成は、図4に限定されるものではなく、種々
の変形が可能である。例えば、シリコン基板側から一様
に放出させた電子流を画像に応じて強度変調するメッシ
ュ状グリッド電極をシリコン基板とガラス基板との中間
に配置する方法、図4の各画素にスイッチング用の能動
素子(トランジスタまたはダイオード)を配置する方法
などが考えられる。The configuration of the flat display using the cold electron source of the present invention is not limited to that shown in FIG. 4, and various modifications are possible. For example, a method in which a mesh grid electrode for intensity-modulating the electron flow uniformly emitted from the silicon substrate side in accordance with an image is arranged between the silicon substrate and the glass substrate, and each pixel in FIG. A method of arranging elements (transistors or diodes) can be considered.
【0032】また、本願の発明者によって、既に特開平
4−356977号公報によって提案されているよう
に、本発明のダイオードは、電子放出と同時に可視光を
放出する発光ダイオードとしても動作させることができ
る。As already proposed by the inventor of the present application in Japanese Patent Application Laid-Open No. 4-356977, the diode of the present invention can be operated as a light emitting diode that emits visible light simultaneously with electron emission. it can.
【0033】更に、上記実施例ではシリコンを基板とし
たものであるが、本発明はシリコンに限られたものでは
なく、陽極酸化を適用できる半導体は全て利用すること
ができる。Further, in the above embodiment, silicon is used as a substrate, but the present invention is not limited to silicon, and any semiconductor to which anodic oxidation can be applied can be used.
【0034】すなわち、ゲルマニウム(Ge)、炭化シ
リコン(SiC)、ヒ化ガリウム(GaAs)、リン化
インジウム(InP)、セレン化カドミウム(CdS
e)など、IV族、III −V族、II−VI族などの単体及び
化合物半導体の多くが、これに該当する。That is, germanium (Ge), silicon carbide (SiC), gallium arsenide (GaAs), indium phosphide (InP), cadmium selenide (CdS)
e) and the like, and many elemental and compound semiconductors of the IV group, the III-V group, the II-VI group and the like fall under this category.
【0035】以上述べたように、本発明は独自の半導体
構成要素によって新規の半導体冷電子放出素子及びそれ
を用いた装置を開発したもので、その応用範囲及び適用
範囲は極めて広い。As described above, the present invention has developed a novel semiconductor cold electron-emitting device and an apparatus using the same using unique semiconductor components, and its application range and application range are extremely wide.
【0036】なお、本発明は上記実施例に限定されるも
のではなく、本発明の趣旨に基づいて種々の変形が可能
であり、これらを本発明の範囲から排除するものではな
い。It should be noted that the present invention is not limited to the above-described embodiment, and various modifications are possible based on the spirit of the present invention, and these are not excluded from the scope of the present invention.
【0037】[0037]
【発明の効果】以上、詳細に説明したように、本発明に
よれば、以下のような効果を奏することができる。As described above, according to the present invention, the following effects can be obtained.
【0038】(A)請求項1記載の発明によれば、複雑
な工程は不要であり、素子構成が単純な、半導体冷電子
放出素子を得ることができる。(A) According to the first aspect of the present invention, it is possible to obtain a semiconductor cold electron emission device having a simple device configuration without complicated steps.
【0039】また、大面積化・多画素化が容易であり、
超高真空を必要としない。Further, it is easy to increase the area and increase the number of pixels.
Does not require ultra-high vacuum.
【0040】より具体的には、多孔質シリコン層を電
子が走行する際の散乱損失が小さいことから、ホットエ
レクトロンがより効率的に生成される。More specifically, since the scattering loss when electrons travel through the porous silicon layer is small, hot electrons are generated more efficiently.
【0041】その結果、電子放出効率が高く、放出さ
れる電子のエネルギーも高い。As a result, the electron emission efficiency is high and the energy of the emitted electrons is high.
【0042】多孔質シリコン層を厚くできるため、素
子の形成および大面積化が容易であり、素子の動作信頼
性も高い。Since the thickness of the porous silicon layer can be increased, it is easy to form the device and increase the area, and the operation reliability of the device is high.
【0043】(B)請求項2記載の発明によれば、上記
(A)の効果を有する面状又は点状の冷電子放出ダイオ
ードを得ることができる。(B) According to the second aspect of the present invention, it is possible to obtain a planar or point-shaped cold electron emitting diode having the effect (A).
【0044】(C)請求項3記載の発明によれば、上記
(B)の半導体冷電子放出素子を、半導体基板面上に多
数配列し、それらを電子放出源として利用する発光形フ
ラットパネルディスプレイ装置を得ることができる。(C) According to the third aspect of the present invention, a large number of the cold semiconductor electron-emitting devices of the above (B) are arranged on the surface of a semiconductor substrate, and these are used as an electron emission source. A device can be obtained.
【図1】本発明の実施例を示す半導体冷電子放出素子の
構成を示す図である。FIG. 1 is a diagram showing a configuration of a semiconductor cold electron emission device according to an embodiment of the present invention.
【図2】本発明の実施例を示す半導体冷電子放出素子の
エネルギーバンド図である。FIG. 2 is an energy band diagram of the semiconductor cold electron emission device according to the embodiment of the present invention.
【図3】本発明の実施例を示す半導体冷電子放出素子の
放出電子流のVPS依存性を示す図である。FIG. 3 is a diagram showing the VPS dependence of the emitted electron current of the semiconductor cold electron emitting device according to the embodiment of the present invention.
【図4】本発明の実施例を示す平面ディスプレイ素子の
構成を示す図である。FIG. 4 is a diagram showing a configuration of a flat display element showing an embodiment of the present invention.
1 n形シリコン基板(n形シリコンウエハ) 2,13 多孔質シリコン層(PS層) 3 Au薄膜電極 4,11 オーミック電極 5 コレクタ電極 10 真空チャンバー 12 シリコン基板 14 薄膜電極 15 信号供給源回路 16 蛍光体 17 電子ビーム加速電圧を供給する電源 18 ガラス板 Reference Signs List 1 n-type silicon substrate (n-type silicon wafer) 2, 13 porous silicon layer (PS layer) 3 Au thin-film electrode 4, 11 ohmic electrode 5 collector electrode 10 vacuum chamber 12 silicon substrate 14 thin-film electrode 15 signal supply circuit 16 fluorescence Body 17 Power supply for supplying electron beam acceleration voltage 18 Glass plate
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平5−342995(JP,A) 特開 平6−177020(JP,A) 特開 平4−356977(JP,A) 特開 平6−13653(JP,A) 特開 平6−268260(JP,A) Journal of Vacuum Science & Technol ogy B Vol.12,No.2, p.662 Applied Physics L etters Vol66,No.4, p.422 (58)調査した分野(Int.Cl.7,DB名) H01J 31/12 H01L 33/00 ────────────────────────────────────────────────── ─── Continuation of the front page (56) References JP-A-5-342995 (JP, A) JP-A-6-177020 (JP, A) JP-A-4-356977 (JP, A) JP-A-6-356977 13653 (JP, A) JP-A-6-268260 (JP, A) Journal of Vacuum Science & Technolology B Vol. 12, No. 2, p. 662 Applied Physics Letters Vol 66, No. 4, p. 422 (58) Fields surveyed (Int. Cl. 7 , DB name) H01J 31/12 H01L 33/00
Claims (3)
化した、厚膜の単一層からなる多孔質半導体層と、 (c)該多孔質半導体層上に形成される金属薄膜電極
と、 (d)前記半導体基板の裏面に形成されるオーミック電
極と、 (e)前記金属薄膜電極に対向して配置され、真空雰囲
気で該金属薄膜電極からの放出電子を捕獲するコレクタ
電極とを具備することを特徴とする半導体冷電子放出素
子。(A) a semiconductor substrate; (b) a thick single-layer porous semiconductor layer obtained by making the surface of the semiconductor substrate porous by anodizing treatment; and (c) the porous semiconductor layer. A metal thin film electrode formed on the layer; (d) an ohmic electrode formed on the back surface of the semiconductor substrate; and (e) a metal thin film electrode disposed opposite to the metal thin film electrode, and And a collector electrode for capturing the emitted electrons.
は、面状又は点状の冷電子放出ダイオードである半導体
冷電子放出素子。2. The semiconductor cold electron-emitting device according to claim 1, wherein the semiconductor cold electron-emitting device is a planar or point-shaped cold electron-emitting diode.
を、半導体基板面上に多数配列し、それらを電子放出源
として利用する発光形フラットパネルディスプレイ装
置。3. A light-emitting flat panel display device in which a large number of the semiconductor cold electron-emitting devices according to claim 2 are arranged on a semiconductor substrate surface, and these are used as electron-emitting sources.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5009395A JP3226745B2 (en) | 1995-03-09 | 1995-03-09 | Semiconductor cold electron-emitting device and device using the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5009395A JP3226745B2 (en) | 1995-03-09 | 1995-03-09 | Semiconductor cold electron-emitting device and device using the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH08250766A JPH08250766A (en) | 1996-09-27 |
JP3226745B2 true JP3226745B2 (en) | 2001-11-05 |
Family
ID=12849448
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5009395A Expired - Fee Related JP3226745B2 (en) | 1995-03-09 | 1995-03-09 | Semiconductor cold electron-emitting device and device using the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3226745B2 (en) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3281533B2 (en) * | 1996-03-26 | 2002-05-13 | パイオニア株式会社 | Cold electron emission display device and semiconductor cold electron emission element |
TW391022B (en) | 1997-10-29 | 2000-05-21 | Mitsubishi Rayon Co | Field emission electron source, method of producing the same, and use of the same |
KR100338140B1 (en) * | 1998-09-25 | 2002-05-24 | 이마이 기요스케 | Electric field emission type electron source |
TW436837B (en) | 1998-11-16 | 2001-05-28 | Matsushita Electric Works Ltd | Field emission-type electron source and manufacturing method thereof and display using the electron source |
JP2000294122A (en) | 1999-04-08 | 2000-10-20 | Nec Corp | Manufacture of field emission cold cathode and flat- panel display |
TW472273B (en) | 1999-04-23 | 2002-01-11 | Matsushita Electric Works Ltd | Field emission-type electron source and manufacturing method thereof |
US6765342B1 (en) * | 1999-10-18 | 2004-07-20 | Matsushita Electric Work, Ltd. | Field emission-type electron source and manufacturing method thereof |
TW497278B (en) * | 2000-03-24 | 2002-08-01 | Japan Science & Tech Corp | Method for generating trajectory electron, trajectory electron solid state semiconductor element |
TWI286773B (en) | 2000-10-26 | 2007-09-11 | Matsushita Electric Works Ltd | Field emission type electron source |
US6844664B2 (en) | 2001-04-24 | 2005-01-18 | Matsushita Electric Works, Ltd. | Field emission electron source and production method thereof |
JP3705803B2 (en) | 2002-07-01 | 2005-10-12 | 松下電器産業株式会社 | Phosphor light emitting element, method for manufacturing the same, and image drawing apparatus |
JP2004265603A (en) | 2003-01-14 | 2004-09-24 | Sharp Corp | Electron emission system, cleaning unit for and cleaning method of electron emission device |
JP4216112B2 (en) | 2003-04-21 | 2009-01-28 | シャープ株式会社 | Electron emitting device and image forming apparatus using the same |
EP1667188A4 (en) * | 2003-09-16 | 2008-09-10 | Sumitomo Electric Industries | Diamond electron emitter and electron beam source using same |
JP4122043B1 (en) | 2007-04-25 | 2008-07-23 | 株式会社クレステック | Surface emission type electron source and drawing apparatus |
JP4303308B2 (en) | 2007-11-20 | 2009-07-29 | シャープ株式会社 | Electron-emitting device, electron-emitting device, self-luminous device, image display device, air blower, cooling device, charging device, image forming device, electron beam curing device, and method for manufacturing electron-emitting device |
US8299700B2 (en) | 2009-02-05 | 2012-10-30 | Sharp Kabushiki Kaisha | Electron emitting element having an electron acceleration layer, electron emitting device, light emitting device, image display device, cooling device, and charging device |
CN101814405B (en) | 2009-02-24 | 2012-04-25 | 夏普株式会社 | Electron emitting element, method for producing electron emitting element and each device using the same |
JP4777448B2 (en) | 2009-05-19 | 2011-09-21 | シャープ株式会社 | Electron emitting device, electron emitting device, self-luminous device, image display device, blower device, cooling device, charging device, image forming device, and electron beam curing device |
JP4732533B2 (en) | 2009-05-19 | 2011-07-27 | シャープ株式会社 | Electron-emitting device and manufacturing method thereof, and electron-emitting device, charging device, image forming device, electron beam curing device, self-luminous device, image display device, blower, and cooling device |
JP4932873B2 (en) | 2009-05-19 | 2012-05-16 | シャープ株式会社 | Self-light-emitting element, self-light-emitting device, image display device, self-light-emitting element driving method, and method of manufacturing self-light-emitting element |
JP4732534B2 (en) | 2009-05-19 | 2011-07-27 | シャープ株式会社 | Electron emitting element, electron emitting device, charging device, image forming device, electron beam curing device, self-luminous device, image display device, blower, cooling device |
CN101930884B (en) | 2009-06-25 | 2012-04-18 | 夏普株式会社 | Electron emitting element and method for producing electron emitting element, electron emitting device, self luminescence device and image display device |
JP4880740B2 (en) | 2009-12-01 | 2012-02-22 | シャープ株式会社 | Electron-emitting device and manufacturing method thereof, and electron-emitting device, charging device, image forming device, electron beam curing device, self-luminous device, image display device, blower, and cooling device |
-
1995
- 1995-03-09 JP JP5009395A patent/JP3226745B2/en not_active Expired - Fee Related
Non-Patent Citations (2)
Title |
---|
Applied Physics Letters Vol66,No.4,p.422 |
Journal of Vacuum Science & Technology B Vol.12,No.2,p.662 |
Also Published As
Publication number | Publication date |
---|---|
JPH08250766A (en) | 1996-09-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP3226745B2 (en) | Semiconductor cold electron-emitting device and device using the same | |
US6629869B1 (en) | Method of making flat panel displays having diamond thin film cathode | |
US3814968A (en) | Solid state radiation sensitive field electron emitter and methods of fabrication thereof | |
NL8400297A (en) | Semiconductor device for generating an electron beam. | |
US4801994A (en) | Semiconductor electron-current generating device having improved cathode efficiency | |
US20050018467A1 (en) | Electron emission device | |
US7399987B1 (en) | Planar electron emitter (PEE) | |
US4506284A (en) | Electron sources and equipment having electron sources | |
JP2003529183A (en) | Photocathode for electron source supported by diamond | |
CA1253260A (en) | Semiconductor device for generating an electron beam | |
JP3187302B2 (en) | Electron emission cathode, electron emission element, flat display, and thermoelectric cooling device using the same, and method of manufacturing electron emission cathode | |
US6340425B2 (en) | Method of manufacturing cold cathode device having porous emitter | |
US4620132A (en) | Electron beam scannable LED display device | |
US6340859B1 (en) | Cold cathode electron emission device for activating electron emission using external electric field | |
US6278229B1 (en) | Field emission displays having a light-blocking layer in the extraction grid | |
JP2001068011A (en) | n-TYPE DIAMOND ELECTRON EMISSIVE ELEMENT AND ELECTRONIC DEVICE | |
JP2002015658A (en) | Electric field emission type cold cathode device and its manufacturing method, as well as vacuum microdevice | |
JP3117773B2 (en) | Silicon-integrated integrated light emitting device and method of manufacturing the same | |
JP3154065B2 (en) | Electron emitting device, and electron emitting device, display device, and electron beam drawing device using the same | |
JP3465890B2 (en) | Electron emitting element and flat display using the same | |
Hoeberechts | Novel silicon avalanche diode as a direct modulated cathode with integrated planar electron-optics | |
JPH1167067A (en) | Thin film cold cathode | |
JP2000306497A (en) | Field emission element | |
JPH0496281A (en) | Semiconductor light emitting device | |
JPH07226148A (en) | Semiconductor electron emitting element |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20010821 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |