JP3080803B2 - Water based nail polish - Google Patents
Water based nail polishInfo
- Publication number
- JP3080803B2 JP3080803B2 JP05019586A JP1958693A JP3080803B2 JP 3080803 B2 JP3080803 B2 JP 3080803B2 JP 05019586 A JP05019586 A JP 05019586A JP 1958693 A JP1958693 A JP 1958693A JP 3080803 B2 JP3080803 B2 JP 3080803B2
- Authority
- JP
- Japan
- Prior art keywords
- pigment
- nail polish
- silicon
- nail
- acrylic resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、顔料分散安定性の優れ
た水系美爪料を提供することを目的としている。BACKGROUND OF THE INVENTION An object of the present invention is to provide a water-based beauty nail preparation having excellent pigment dispersion stability.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】従来よ
り美爪料は酢酸ブチル、酢酸エチル、トルエン等の有機
溶剤を使用したものであり、引火性があると共に塗布時
に溶剤臭を伴うものであった。さらに有機溶剤により爪
の脱脂が生じやすく、爪に対する安全性に問題があっ
た。2. Description of the Prior Art Conventionally, nail polish has used an organic solvent such as butyl acetate, ethyl acetate, and toluene, and is flammable and has a solvent odor during application. there were. Furthermore, degreasing of the nail is easily caused by the organic solvent, and there is a problem in safety for the nail.
【０００３】これに対し、有機溶剤を使用しない美爪料
が種々検討されており、特開昭５４−２８８３６号公
報、特公昭５５−４３４４５号公報、特公昭６１−１０
４３号公報、特公昭６２−６１００２号公報等により、
ポリマーエマルジョンや水性樹脂を配合した美爪料が提
案されている。[0003] On the other hand, various types of nail polish which do not use an organic solvent have been studied, for example, JP-A-54-28836, JP-B-55-43445, and JP-B-61-10.
No. 43, Japanese Patent Publication No. Sho 62-61002, etc.
Nail preparations containing a polymer emulsion or an aqueous resin have been proposed.
【０００４】しかし、これらはいずれも未処理の無機顔
料を使用しており、無機顔料のもつ親水性および水との
比重差により、顔料はいずれも経日で沈降し、使用前に
振とうしても良く混合せず、所望の色調が塗布されない
という欠点があった。また、これらの公報では無機顔料
を分散させるために活性剤やゲル化剤を使用している
が、これだけでは美爪料として塗布むらを生じることな
く塗布できる１０００ｃｐ以下の粘度において、経日で
の顔料沈降を完全に防止することが困難であった。However, all of these use untreated inorganic pigments, and due to the hydrophilicity of the inorganic pigments and the difference in specific gravity with water, all of the pigments settle out over time and are shaken before use. However, they do not mix well, and the desired color tone is not applied. Further, in these publications, an activator or a gelling agent is used to disperse the inorganic pigment. However, with this alone, at a viscosity of 1000 cp or less that can be applied without causing unevenness in application as a nail pill, It was difficult to completely prevent pigment settling.
【０００５】また、特開平４−１０３５１５号公報では
顔料分散安定性を改良するために多価金属元素の含水酸
化物をカチオンポリマーエマルジョンと共に使用してい
るが、カチオンポリマーエマルジョンのｐＨが低いた
め、ｐＨ７〜９のアクリル系エマルジョンと混合して使
用することが困難であった。In Japanese Patent Application Laid-Open No. 4-103515, a hydrated oxide of a polyvalent metal element is used together with a cationic polymer emulsion in order to improve the pigment dispersion stability. However, since the pH of the cationic polymer emulsion is low, It was difficult to mix and use with an acrylic emulsion having a pH of 7 to 9.
【０００６】さらに、特開平４−１０３５１６号公報で
はポリマーエマルジョンと顔料を共に粉砕して顔料を微
粒子化することにより美爪料の外観、光沢を改良する方
法が記載されているが、本発明者が追試した限りでは経
日での顔料沈降を完全に防止することが困難であった。Further, Japanese Patent Application Laid-Open No. 4-103516 discloses a method for improving the appearance and gloss of a nail polisher by pulverizing a polymer emulsion and a pigment together to make the pigment finer. However, it was difficult to completely prevent sedimentation of the pigment over time as long as the additional test was conducted.
【０００７】[0007]
【課題を解決するための手段】本発明者はかかる問題を
鑑みて鋭意研究の結果、無機顔料の表面にシリコンを被
覆させたシリコン処理顔料、およびポリオキシエチレン
系ノニオン界面活性剤を配合することによって、アクリ
ル系樹脂エマルジョンを配合した水系美爪料に安定に無
機顔料を配合できることを見出だした。Means for Solving the Problems In view of such problems, the present inventors have made intensive studies and have found that a silicon-treated pigment in which the surface of an inorganic pigment is coated with silicon and a polyoxyethylene-based nonionic surfactant are blended. As a result, it has been found that an inorganic pigment can be stably compounded in a water-based nail polish containing an acrylic resin emulsion.
【０００８】またアクリル系樹脂エマルジョンとして一
般式（Ｉ）で表されるアルコキシシラン不飽和単量体を
共重合させた共重合体エマルジョンを使用すればさらに
顔料の分散安定性が増加することを見出だした。It is also found that the use of a copolymer emulsion obtained by copolymerizing an alkoxysilane unsaturated monomer represented by the general formula (I) as an acrylic resin emulsion further increases the pigment dispersion stability. I started.
【０００９】すなわち本発明は、無機顔料の表面に、少
なくともシリコンを母体顔料に対し０．１〜１０．０重
量％被覆させたシリコン処理顔料１０．０重量％以下、
ポリオキシエチレン系ノニオン界面活性剤０．０１〜１
０．０重量％、アクリル系樹脂エマルジョンを固形分と
して５．０〜４０．０重量％を配合することにより、顔
料分散安定性の優れた水系美爪料を提供するものであ
る。That is, according to the present invention, a silicon-treated pigment in which at least 0.1 to 10.0% by weight of silicon is coated on the surface of an inorganic pigment with respect to a base pigment, 10.0% by weight or less,
Polyoxyethylene nonionic surfactant 0.01-1
By blending 0.0% by weight and 5.0 to 40.0% by weight of an acrylic resin emulsion as a solid content, an aqueous nail polish having excellent pigment dispersion stability is provided.
【００１０】以下、本発明の構成について詳述する。本
発明に使用されるシリコン処理顔料の母体となる無機顔
料は化粧料に配合される無機顔料であれば全て母体とし
て使用することができ、酸化チタン、ベンガラ、黄酸化
鉄、黒酸化鉄、グンジョウ、コンジョウ、酸化クロム、
水酸化クロム、タルク、マイカ、雲母チタン、酸化鉄処
理雲母チタン、コンジョウ処理雲母チタン、カルミン処
理雲母チタン、硫酸バリウム、およびこれらの複合体等
があげられる。Hereinafter, the configuration of the present invention will be described in detail. The inorganic pigment serving as a base of the siliconized pigment used in the present invention can be used as a base as long as it is an inorganic pigment to be blended in cosmetics, and titanium oxide, red iron oxide, yellow iron oxide, black iron oxide, gunjou , Konjo, chromium oxide,
Examples include chromium hydroxide, talc, mica, mica titanium, iron oxide treated mica titanium, konjo treated mica titanium, carmine treated mica titanium, barium sulfate, and composites thereof.
【００１１】これらの母体顔料に被覆するシリコンはメ
チルポリシロキサン、メチルハイドロジェンポリシロキ
サン、メチルフェニルポリシロキサン等の直鎖状ポリオ
ルガノシロキサンやオクタメチルシクロテトラシロキサ
ン、デカメチルシクロペンタシロキサン、ドデカメチル
シクロヘキサシロキサン等の環状ポリオルガノシロキサ
ンあるいはこれらの誘導体等の変性シリコンの類から選
ばれ、被覆方法は焼き付け処理、気相重合法等の公知の
方法で行うものである。もちろん他の油剤を被覆した後
にシリコンをさらに結合させても、他の油剤と共に被覆
処理しても良く、結果として顔料表面にシリコンもしく
はシリコン誘導体が被覆された顔料であれば本発明のシ
リコン処理顔料として全て使用できる。前述したシリコ
ンの被覆量は母体顔料に対し、０．１〜１０．０重量％
である。被覆量が０．１重量％以下では無機顔料の分散
安定性が乏しく、また１０．０重量％以上では美爪料の
粘度が増加し、塗布時にムラを生じるため好ましくな
い。もちろんこれらのシリコンは２種以上を併用しても
良い。Silicon coated on these base pigments may be a linear polyorganosiloxane such as methylpolysiloxane, methylhydrogenpolysiloxane, methylphenylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexene. It is selected from modified silicons such as cyclic polyorganosiloxanes such as sasiloxane or derivatives thereof, and the coating method is performed by a known method such as a baking treatment or a gas phase polymerization method. Of course, silicon may be further bonded after coating with another oil agent, or may be coated with another oil agent. As a result, the silicon-treated pigment of the present invention may be any pigment in which the surface of the pigment is coated with silicon or a silicon derivative. All can be used. The coating amount of silicon described above is 0.1 to 10.0% by weight based on the base pigment.
It is. When the coating amount is 0.1% by weight or less, the dispersion stability of the inorganic pigment is poor, and when the coating amount is 10.0% by weight or more, the viscosity of the nail polish increases, which is not preferable because unevenness occurs during application. Of course, two or more of these silicons may be used in combination.
【００１２】また本発明に使用されるポリオキシエチレ
ン系ノニオン界面活性剤としてはポリオキシエチレンソ
ルビタン脂肪酸エステル、ポリオキシエチレングリセリ
ン脂肪酸エステル、ポリオキシエチレンアルキルエーテ
ル、ポリオキシエチレンアルキルフェニルエーテル、ポ
リオキシエチレンヒマシ油、ポリオキシエチレン硬化ヒ
マシ油等の類から選ばれる。The polyoxyethylene nonionic surfactant used in the present invention includes polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, and polyoxyethylene. It is selected from castor oil, polyoxyethylene hydrogenated castor oil and the like.
【００１３】また本発明に使用されるアクリル系樹脂エ
マルジョンは、少なくともアクリル酸、メタクリル酸あ
るいはそれらのアルキルエステルまたは誘導体の類から
えらばれるモノマーを含む共重合体の水性エマルジョン
であり、共重合させる他のモノマーは特に限定されず、
スチレン、酢酸ビニル等を共重合させても良い。The acrylic resin emulsion used in the present invention is an aqueous emulsion of a copolymer containing at least a monomer selected from the group consisting of acrylic acid, methacrylic acid and their alkyl esters or derivatives. The monomer of is not particularly limited,
Styrene, vinyl acetate and the like may be copolymerized.
【００１４】アクリル酸、メタクリル酸あるいはそれら
のアルキルエステルまたは誘導体の類からえらばれるモ
ノマーとしてはアクリル酸、メタクリル酸、アクリル酸
エチル、メタクリル酸メチル、アクリル酸オクチル、ア
クリロニトリル、アクリルアミド等があげられ、なかで
も一般式（Ｉ）で表されるアルコキシシランを含むアク
リル酸、メタクリル酸の誘導体を共重合させたエマルジ
ョンが顔料分散安定性および化粧持ちの良さの点で好ま
しく、たとえばアクリロキシトリメトキシシラン、メタ
クリロキシトリメトキシシラン、アクリロキシトリエト
キシシラン、メタクリロキシトリエトキシシラン、アク
リロキシトリエトキシメトキシシラン、メタクリロキシ
トリエトキシメトキシシラン、メタクリロキシエチルト
リメトキシシラン、メタクリロキシエチルトリエトキシ
シラン、メタクリロキシプロピルトリメトキシシラン、
メタクリロキシプロピルトリエトキシシラン等があげら
れる。The monomers selected from the group consisting of acrylic acid, methacrylic acid or their alkyl esters or derivatives include acrylic acid, methacrylic acid, ethyl acrylate, methyl methacrylate, octyl acrylate, acrylonitrile, acrylamide and the like. However, an emulsion obtained by copolymerizing a derivative of acrylic acid or methacrylic acid containing an alkoxysilane represented by the general formula (I) is preferable in terms of pigment dispersion stability and cosmetic durability. For example, acryloxytrimethoxysilane and methacrylic acid Roxytrimethoxysilane, acryloxytriethoxysilane, methacryloxytriethoxysilane, acryloxytriethoxymethoxysilane, methacryloxytriethoxymethoxysilane, methacryloxyethyltrimethoxysilane Methacryloxyethyl triethoxysilane, methacryloxypropyl trimethoxysilane,
Methacryloxypropyltriethoxysilane and the like can be mentioned.
【００１５】本発明に使用されるシリコン処理顔料の配
合量は好ましくは０．１〜１０．０重量％以下であり、
美爪料の色調に応じて増減される。１０．０重量％以上
では美爪料の粘度が増加し、塗布時にムラを生じるため
に好ましくない。The amount of the siliconized pigment used in the present invention is preferably 0.1 to 10.0% by weight or less,
It is increased or decreased according to the color tone of the nail polish. If the content is 10.0% by weight or more, the viscosity of the nail enamel increases, which is not preferable because unevenness occurs during application.
【００１６】また本発明に使用されるポリオキシエチレ
ン系ノニオン界面活性剤の配合量は好ましくは０．０１
〜１０．０重量％であり、シリコン処理顔料の配合量に
応じて増減させる。０．０１重量％以下では顔料の分散
安定性が乏しく、また１０．０重量％以上では美爪料の
粘度が増加し、塗布時にムラを生じるだけでなく化粧持
ちも悪くなる傾向にある。The amount of the polyoxyethylene-based nonionic surfactant used in the present invention is preferably 0.01 to 0.01.
１10.0% by weight, which is increased or decreased according to the blending amount of the siliconized pigment. When the content is 0.01% by weight or less, the dispersion stability of the pigment is poor. When the content is 10.0% by weight or more, the viscosity of the nail polishes increases, and not only unevenness occurs at the time of application, but also the long-lasting makeup tends to deteriorate.
【００１７】また本発明に使用されるアクリル系樹脂エ
マルジョンの配合量は好ましくは固形分として５．０〜
４０．０重量％であり、５．０重量％以下では美爪料の
被膜形成効果に乏しく、化粧持ちに優れた美爪料となら
ず、また４０．０重量％以上では美爪料の粘度が増加
し、塗布時にムラを生じる傾向にあるために好ましくな
い。このアクリル系樹脂エマルジョンは２種以上のアク
リル系樹脂エマルジョンを配合してもさしつかえない。The amount of the acrylic resin emulsion used in the present invention is preferably from 5.0 to 5.0 as solids.
When the content is 40.0% by weight or less, the effect of forming a film of the nail enamel is poor when the content is less than 5.0% by weight. Is increased, and unevenness tends to occur during coating, which is not preferable. This acrylic resin emulsion may contain two or more acrylic resin emulsions.
【００１８】本発明の美爪料中には上記必須成分以外に
他の顔料や色素、染料を配合することもできる。タール
系色素はそのまま使用しても比較的安定に分散するが、
もちろん必要に応じてシリコン処理して配合しても良
い。また必要に応じ、ポリオキシエチレン系ノニオン界
面活性剤以外の界面活性剤、可塑剤、粘度調整剤（ゲル
化剤）、防腐剤、香料等を適宜配合することができる。The nail polish of the present invention may contain other pigments, pigments and dyes in addition to the above essential components. Tar pigments are relatively stable even when used as is,
Of course, it may be blended by silicon treatment as needed. If necessary, a surfactant other than the polyoxyethylene-based nonionic surfactant, a plasticizer, a viscosity modifier (gelling agent), a preservative, a fragrance, and the like can be appropriately compounded.
【００１９】[0019]
【実施例】以下、実施例によって本発明の効果を更に詳
しく説明する。表１〜９の組成により、各々の実施例お
よび比較例の美爪料を調整した。ここで表中の数値は全
て重量％である。この美爪料は色素や顔料を界面活性剤
と共にローラーミルにて粉砕練混し、その後アクリル系
樹脂エマルジョンおよびその他の成分と約６０℃にて均
一に混合した後、室温まで冷却して製造した。また、必
要に応じ減圧脱泡をおこない美爪料中に含まれた空気を
除去した。EXAMPLES Hereinafter, the effects of the present invention will be described in more detail with reference to examples. According to the compositions of Tables 1 to 9, the nail polish of each Example and Comparative Example was adjusted. Here, all numerical values in the table are% by weight. This nail polish was manufactured by pulverizing and mixing a pigment and a pigment together with a surfactant in a roller mill, then uniformly mixing with an acrylic resin emulsion and other components at about 60 ° C., and then cooling to room temperature. . In addition, defoaming was performed under reduced pressure as needed to remove air contained in the nail preparation.
【００２０】[0020]
【表１】 [Table 1]
【００２１】[0021]
【表２】 [Table 2]
【００２２】[0022]
【表３】 [Table 3]
【００２３】[0023]
【表４】 [Table 4]
【００２４】[0024]
【表５】 [Table 5]
【００２５】[0025]
【表６】 [Table 6]
【００２６】[0026]
【表７】 [Table 7]
【００２７】[0027]
【表８】 [Table 8]
【００２８】[0028]
【表９】 [Table 9]
【００２９】次いで実施例および比較例の美爪料の顔料
分散安定性試験を実施し、その結果を表１０に記載し
た。顔料分散安定性試験は５℃、３０℃、４５℃の各恒
温槽にて静置状態における経日変化を観察し、４段階
（◎：一ケ月間顔料沈降なし、○：２週間で顔料沈降、
△：１週間で顔料沈降、×：３日以内で顔料沈降）で評
価した。Next, the pigment dispersion stability test of the nail polishes of Examples and Comparative Examples was carried out, and the results are shown in Table 10. The pigment dispersion stability test was carried out by observing the daily change in the stationary state in each of the constant temperature baths at 5 ° C., 30 ° C., and 45 ° C. ,
Δ: pigment sedimentation in 1 week, ×: pigment sedimentation in 3 days or less).
【００３０】[0030]
【表１０】 [Table 10]
【００３１】また、実施例および比較例の美爪料の実用
特性試験を実施し、その結果を表１１〜１２に記載し
た。実用特性試験は、２０名の女性パネラーに美爪料を
爪に塗布し、その使用品質（塗り易さ、色むら、乾燥速
度、光沢、仕上がり、化粧持ち）を５段階評価（５：良
い、４：やや良い、３：ふつう、２：やや悪い、１：悪
い）で集計し、その平均値を４段階（◎：４以上、○：
３〜４、△：２〜３、×：２以下）で評価した。Further, practical property tests of the nail prep of Examples and Comparative Examples were conducted, and the results are shown in Tables 11 to 12. In the practical characteristics test, a nail polish was applied to the nails of 20 female panelists, and the quality of use (ease of application, uneven color, drying speed, gloss, finish, makeup durability) was evaluated on a five-point scale (5: good, 4: Slightly good, 3: Normal, 2: Slightly bad, 1: Poor, and averaged in 4 steps (A: 4 or more, O:
3-4, Δ: 2-3, ×: 2 or less).
【００３２】[0032]
【表１１】 [Table 11]
【００３３】[0033]
【表１２】 [Table 12]
【００３４】表１０より、実施例はいずれも比較例に比
べて顔料分散安定性に優れていることが明らかである。From Table 10, it is evident that all of the examples are more excellent in pigment dispersion stability than the comparative examples.
【００３５】また表１１〜１２より、実施例はいずれも
比較例に比べて実用特性においても同等もしくはそれ以
上の評価を有していることが明らかである。From Tables 11 to 12, it is clear that all of the examples have equal or better evaluations in practical characteristics than the comparative examples.
【００３６】[0036]
【発明の効果】本発明の水系美爪料は、顔料分散安定性
に優れた効果を有するものである。The water-based nail polishes of the present invention have excellent pigment dispersion stability.
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Claims (2)
に対し０．１〜１０．０重量％被覆させたシリコン処理
顔料、ポリオキシエチレン系ノニオン界面活性剤、アク
リル系樹脂エマルジョンを含有することを特徴とする水
系美爪料1. An inorganic pigment containing, on the surface thereof, a silicon-treated pigment in which silicon is coated in an amount of 0.1 to 10.0% by weight based on a base pigment, a polyoxyethylene nonionic surfactant, and an acrylic resin emulsion. Water-based nail polish characterized by
とも下記一般式（Ｉ）で表されるアルコキシシラン不飽
和単量体の一種以上を共重合してなる共重合体エマルジ
ョンである請求項１記載の水系美爪料。 【化１】 2. The aqueous system according to claim 1, wherein the acrylic resin emulsion is a copolymer emulsion obtained by copolymerizing at least one kind of an alkoxysilane unsaturated monomer represented by the following general formula (I). Beauty nails. Embedded image
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05019586A JP3080803B2 (en) | 1993-01-11 | 1993-01-11 | Water based nail polish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05019586A JP3080803B2 (en) | 1993-01-11 | 1993-01-11 | Water based nail polish |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06211630A JPH06211630A (en) | 1994-08-02 |
| JP3080803B2 true JP3080803B2 (en) | 2000-08-28 |
Family
ID=12003365
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP05019586A Expired - Lifetime JP3080803B2 (en) | 1993-01-11 | 1993-01-11 | Water based nail polish |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3080803B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3554174B2 (en) * | 1998-01-26 | 2004-08-18 | ポーラ化成工業株式会社 | Powder-resin complex containing cosmetics |
| EP1288258B1 (en) * | 2001-03-02 | 2009-12-23 | Shiseido Co., Ltd. | Aqueous polymer emulsions and cosmetics with the use of the same |
| JP5886020B2 (en) * | 2011-12-14 | 2016-03-16 | 三菱鉛筆株式会社 | Aqueous beauty nail composition |
-
1993
- 1993-01-11 JP JP05019586A patent/JP3080803B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06211630A (en) | 1994-08-02 |
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