JP3042331B2 - Manufacturing method of ferritic stainless steel sheet - Google Patents

Manufacturing method of ferritic stainless steel sheet

Info

Publication number
JP3042331B2
JP3042331B2 JP6278983A JP27898394A JP3042331B2 JP 3042331 B2 JP3042331 B2 JP 3042331B2 JP 6278983 A JP6278983 A JP 6278983A JP 27898394 A JP27898394 A JP 27898394A JP 3042331 B2 JP3042331 B2 JP 3042331B2
Authority
JP
Japan
Prior art keywords
annealing
temperature
stainless steel
ferritic stainless
steel sheet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP6278983A
Other languages
Japanese (ja)
Other versions
JPH08134550A (en
Inventor
謙一 正村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Priority to JP6278983A priority Critical patent/JP3042331B2/en
Publication of JPH08134550A publication Critical patent/JPH08134550A/en
Application granted granted Critical
Publication of JP3042331B2 publication Critical patent/JP3042331B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Landscapes

  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、フェライト系ステンレ
ス鋼板の製造方法、詳述すれば、高生産性が実現できる
連続焼鈍法により、耐リジング性と表面性状に優れたア
ルミニウム含有フェライト系ステンレス鋼板を製造する
方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of manufacturing a ferritic stainless steel sheet, more specifically, an aluminum-containing ferritic stainless steel sheet having excellent ridging resistance and surface properties by a continuous annealing method capable of realizing high productivity. And a method for producing the same.

【0002】[0002]

【従来の技術】従来から、フェライト系ステンレス鋼板
は、熱間圧延後バッジ炉にて800 〜850 ℃で40時間にも
及ぶ長時間焼鈍を施して製造されている。軟質化と整粒
化のためである。この方法は、焼鈍に要する時間が長
く、また焼鈍炉やコイル置き場の設置場所も広くする必
要があり非能率であった。
2. Description of the Related Art Conventionally, ferritic stainless steel sheets have been manufactured by performing a long-time annealing at 800 to 850 ° C. for as long as 40 hours in a badge furnace after hot rolling. This is for softening and sizing. This method is inefficient because the time required for annealing is long, and the installation place of the annealing furnace and the coil storage space needs to be widened.

【0003】しかし近年、フェライト系ステンレス鋼板
の熱延板を連続焼鈍する方法が提案されている (特開昭
53−40625 号、同53−62724 号、同56−98423 号の各公
報等) 。
In recent years, however, there has been proposed a method of continuously annealing a hot-rolled ferritic stainless steel sheet (Japanese Patent Application Laid-Open No.
Nos. 53-40625, 53-62724 and 56-98423).

【0004】フェライト系ステンレス鋼の熱延鋼板の連
続焼鈍方法としては、焼鈍温度を900 ℃以上にすること
により耐リジング性が改善されるが、900 ℃以上の焼鈍
は変態点以上に相当するため、冷却中にマルテンサイト
が析出して靱性が劣化し、コイル通板中の破断、冷間圧
延中の割れなどが問題となる。その他の問題としては、
炭窒化物の固溶温度以上に加熱することで、冷却中に粒
界に炭窒化物が析出し、その近傍にCr欠乏層が生じ、引
き続き行う酸洗時に粒界腐食を引き起こし、その後の冷
間圧延で倒れ込み、コールドダストと称される微小ヘゲ
疵が発生することが挙げられる。
As a method for continuously annealing a hot-rolled steel sheet of ferritic stainless steel, ridging resistance is improved by setting the annealing temperature to 900 ° C. or higher. However, annealing at 900 ° C. or higher is equivalent to a transformation point or higher. In addition, martensite precipitates during cooling and the toughness deteriorates, which causes problems such as breakage during coil passing and cracking during cold rolling. Other issues include:
By heating to a temperature equal to or higher than the solid solution temperature of carbonitride, carbonitride precipitates at the grain boundaries during cooling, and a Cr-deficient layer is formed in the vicinity thereof, causing intergranular corrosion during subsequent pickling and subsequent cooling. It falls down during cold rolling, and the generation of minute bark flaws called cold dust is mentioned.

【0005】これらの問題を解決する方法として、アル
ミニウムと窒素の重量比Al/Nが2以上になるように鋼組
成を調整し、アルミニウムの量に応じて焼鈍温度を900
℃以上1000℃以下に変更させて焼鈍を行う方法( 特開昭
53−40625 号公報) も提案されている。
As a method for solving these problems, the steel composition is adjusted so that the weight ratio Al / N of aluminum and nitrogen is 2 or more, and the annealing temperature is adjusted to 900 in accordance with the amount of aluminum.
A method of performing annealing by changing the temperature to not less than 1000 ° C.
No. 53-40625) has also been proposed.

【0006】Cを0.010 %以下とし、Alの含有量に応じ
て850 ℃以上950 ℃以下の温度で焼鈍を施すことで結晶
粒界への炭化物の析出を抑え、ゴールドダスト発生を防
止する方法 (特開昭53−62724 号公報) も提案されてい
る。
A method of suppressing the precipitation of carbides at the crystal grain boundaries by annealing at a temperature of 850 ° C. to 950 ° C. depending on the Al content by setting C to 0.010% or less, and preventing gold dust generation ( JP-A-53-62724) has also been proposed.

【0007】一方、冷却速度に着目し、850 ℃以上1100
℃以下に加熱後、700 ℃以上900 ℃以下の温度範囲まで
1〜15℃/秒の平均冷却速度で冷却し、Cr炭窒化物の析
出を抑える方法 (特開昭56−98423 号公報) も提案され
ている。
On the other hand, focusing on the cooling rate,
A method of suppressing the precipitation of Cr carbonitride by heating to a temperature range of 700 ° C. to 900 ° C. at an average cooling rate of 1 to 15 ° C./sec after heating to a temperature of 700 ° C. to 900 ° C. (JP-A-56-98423). Proposed.

【0008】[0008]

【発明が解決しようとする課題】しかしながら、これら
の従来技術は、フェライト系ステンレス鋼板の耐リジン
グ性の改善とCr炭窒化物析出に伴うゴールドダストの抑
制を考えた場合、まだ十分とは言えない。
However, these prior arts are not yet satisfactory when considering improvement of ridging resistance of ferritic stainless steel sheet and suppression of gold dust accompanying Cr carbonitride precipitation. .

【0009】すなわち、アルミニウムと窒素の重量比Al
/Nが2以上になるように含有し、アルミニウムの量に応
じ焼鈍温度を900 ℃以上1000℃以下で焼鈍を行う特開昭
53−40625 号公報開示の方法では、焼鈍温度を1000℃以
下と規定しているため耐リジング性のさらなる向上がな
されない。
That is, the weight ratio of aluminum to nitrogen, Al
/ N is 2 or more, and annealing is performed at an annealing temperature of 900 ° C or more and 1000 ° C or less according to the amount of aluminum.
In the method disclosed in JP-A-53-40625, since the annealing temperature is specified to be 1000 ° C. or less, the ridging resistance is not further improved.

【0010】また、Cを0.010 %以下とし、Alの含有量
に応じて850 ℃以上950 ℃以下に焼鈍する特開昭53−62
724 号公報開示の方法では、C量を0.010 %以下にする
ためコストが高くなり実用的でなく、また強度が十分確
保できない恐れがある。
Japanese Patent Application Laid-Open (JP-A) No. 53-62 discloses a method in which C is set to 0.010% or less and annealing is performed at 850 ° C. to 950 ° C. depending on the Al content.
In the method disclosed in Japanese Patent Publication No. 724, since the amount of C is set to 0.010% or less, the cost is increased, which is not practical, and the strength may not be sufficiently secured.

【0011】そして、850 ℃以上1100℃以下に加熱後、
700 ℃以上900 ℃以下の温度範囲まで1〜15℃/秒の平
均冷却速度で冷却する特開昭56−98423 号公報に開示す
る方法では、実際のラインを通板する際、平均冷却速度
を1〜15℃/秒の徐冷にするには無理であり実用的でな
い。
Then, after heating to 850 ° C. or higher and 1100 ° C. or lower,
In the method disclosed in JP-A-56-98423, in which cooling is performed at an average cooling rate of 1 to 15 ° C./sec to a temperature range of 700 ° C. or more and 900 ° C. or less, the average cooling rate when passing through an actual line is It is impossible to perform slow cooling at 1 to 15 ° C./sec, which is not practical.

【0012】ここに、本発明の目的は、耐リジング性の
改善とゴールドダストを抑制したAl含有フェライト系ス
テンレス鋼板の経済的な製造方法を提供することであ
る。
Here, an object of the present invention is to provide an economical method for producing an Al-containing ferritic stainless steel sheet with improved ridging resistance and suppressed gold dust.

【0013】[0013]

【課題を解決するための手段】そこで、本発明者は、か
かる目的達成のために種々検討を重ねた結果、従来のア
ルミニウム添加フェライト系ステンレス鋼板のAl含有量
を上げ、かつC含有量を下げることにより変態点を上
げ、1000℃以上の高温焼鈍を可能にすることにより、耐
リジング性に優れかつ、ゴールドダストの発生を抑えた
実用的なAl含有フェライト系ステンレス鋼板が製造でき
ることを見い出し、本発明を完成した。
The inventor of the present invention has conducted various studies to achieve the object, and as a result, has increased the Al content and reduced the C content of the conventional aluminum-added ferritic stainless steel sheet. By raising the transformation point and enabling high-temperature annealing at 1000 ° C or higher, we found that a practical Al-containing ferritic stainless steel sheet with excellent ridging resistance and suppressed generation of gold dust could be manufactured. Completed the invention.

【0014】また、同時に熱間圧延時のスラブ加熱を低
温化することでAlN を析出させ、さらなる耐リジング性
の向上を可能とさせた。
At the same time, by lowering the slab heating during the hot rolling, AlN is precipitated to further improve the ridging resistance.

【0015】よって、本発明の要旨とするところは、重
量%で、C:0.02〜0.05%、Si:1.0 %以下、Mn:1.5
%以下、N:0.01〜0.03%、Cr:15〜18%、Al:0.10〜
0.30%、残部Feおよび不可避的不純物より成る鋼組成を
有するスラブを1100〜1200℃に加熱して熱間圧延を行
い、得られた熱延板を、焼鈍温度1000〜1100℃、冷却速
度15℃/秒以上で急冷する連続焼鈍を行い、その後、冷
間圧延、再結晶焼鈍を行うことを特徴とする、耐リジン
グ性に優れ、表面性状が良好なアルミニウム含有フェラ
イト系ステンレス鋼板の製造方法である。
Therefore, the gist of the present invention is as follows: C: 0.02 to 0.05%, Si: 1.0% or less, Mn: 1.5% by weight.
%, N: 0.01 to 0.03%, Cr: 15 to 18%, Al: 0.10 to
A slab having a steel composition consisting of 0.30%, the balance of Fe and unavoidable impurities is heated to 1100 to 1200 ° C and hot rolled, and the obtained hot rolled sheet is subjected to an annealing temperature of 1000 to 1100 ° C and a cooling rate of 15 ° C. This is a method for producing an aluminum-containing ferritic stainless steel sheet having excellent ridging resistance and excellent surface properties, characterized by performing continuous annealing of quenching at a rate of / sec or more, followed by cold rolling and recrystallization annealing. .

【0016】[0016]

【作用】本発明は下記(1) 〜(4) を満たすことにより、
高生産性の連続焼鈍法にて耐リジング性と表面性状に優
れたアルミニウム含有フェライト系ステンレス鋼板を製
造する方法である。
[Action] The present invention satisfies the following (1) to (4),
This is a method of manufacturing an aluminum-containing ferritic stainless steel sheet having excellent ridging resistance and surface properties by a high productivity continuous annealing method.

【0017】(1) 鋼板の化学成分を高Al、低C化するこ
とで変態点を上げ高温焼鈍を可能にする。 (2) 1000〜1100℃での焼鈍を行い、AlN 析出効果により
耐リジング性を向上させる。 (3) 低C化と15℃/秒以上の急冷という冷却条件によ
り、Cr炭窒化物の析出を抑えゴールドダストを発生させ
ない。 (4) 熱間圧延時のスラブ加熱温度を1100〜1200℃と低く
し、AlN 析出効果により耐リジング性をさらに向上させ
る。
(1) The transformation point is raised by making the chemical composition of the steel sheet high in Al and low in C to enable high temperature annealing. (2) Anneal at 1000 to 1100 ° C to improve ridging resistance by AlN precipitation effect. (3) Precipitation of Cr carbonitride is suppressed and no gold dust is generated by the cooling conditions of low C and rapid cooling at 15 ° C / sec or more. (4) The slab heating temperature during hot rolling is reduced to 1100 to 1200 ° C, and the ridging resistance is further improved by the AlN precipitation effect.

【0018】次に、本発明における化学成分および製造
条件の選定理由を詳述する。 C:Cはフェライト系ステンレス鋼板においてはCr炭化
物を生成し粒界腐食の原因となるため基本的には好まし
くない。しかし過度のCの低減は、製鋼時の脱炭のコス
トアップが問題となる。また強度の低下も懸念される。
ここではC量を適度に下げることにより、変態点を上げ
連続焼鈍化を容易にする範囲としてC量は0.02〜0.05%
とした。好ましくは、0.03〜0.04%である。
Next, the reasons for selecting the chemical components and the production conditions in the present invention will be described in detail. C: C is basically not preferable because ferrite stainless steel sheets generate Cr carbides and cause intergranular corrosion. However, an excessive reduction in C poses a problem of increasing the cost of decarburization during steelmaking. Also, there is a concern that the strength may decrease.
Here, the C amount is 0.02 to 0.05% as a range in which the transformation point is increased by appropriately lowering the C amount to facilitate continuous annealing.
And Preferably, it is 0.03 to 0.04%.

【0019】Si:Siは脱酸のため不可避な元素であり、
通常のフェライト系ステンレス鋼に含有量されている程
度の1.0 %以下とした。好ましくは、0.5 %以下であ
る。
Si: Si is an inevitable element for deoxidation,
The content was set to 1.0% or less, which is the level contained in ordinary ferritic stainless steel. Preferably, it is 0.5% or less.

【0020】Mn:Mnは熱間加工性を良好にし、強度を確
保するため1.5 %以下含有させる。好ましくは、1.0 %
以下である。
Mn: Mn is contained in an amount of 1.5% or less to improve hot workability and secure strength. Preferably, 1.0%
It is as follows.

【0021】N:NはCと同様にフェライト系ステンレ
ス鋼板においては、Cr窒化物を生成し粒界腐食の原因と
なるため基本的には好ましくないが、本鋼種のようなAl
添加鋼では、AlN の析出による耐リジング性の向上が見
込まれるためN量は0.01〜0.03%とした。
N: Like N, N is basically not preferable in ferritic stainless steel sheets because it forms Cr nitrides and causes intergranular corrosion.
In the added steel, the amount of N was set to 0.01 to 0.03% because improvement in ridging resistance due to precipitation of AlN is expected.

【0022】Cr:Crはステンレス鋼において、耐食性お
よび耐酸化性のため必要不可欠な成分である。安価な一
般的商用フェライト系ステンレス鋼を対象としているた
め15〜18%とした。
Cr: Cr is an essential component in stainless steel for corrosion resistance and oxidation resistance. Since it is intended for inexpensive general commercial ferritic stainless steel, it is set at 15 to 18%.

【0023】Al:Alを添加することにより、スラブ加熱
時および高温連続焼鈍時にAlN が析出し、集合組織が壊
れることから耐リジング性が向上する。また、変態点を
上昇させる効果があり連続焼鈍化を容易にする。Al量を
増やす (特に0.14%以上添加) とゴールドダストの発生
原因である粒界腐食感受性が減少する効果もある。しか
し、Alを過剰に添加すると、酸洗工程でスケール除去が
困難になることから0.10〜0.30%とした。好ましくは、
0.14〜0.20%である。
Al: By adding Al, AlN precipitates during slab heating and continuous high-temperature annealing and breaks the texture, thereby improving ridging resistance. In addition, it has the effect of raising the transformation point and facilitates continuous annealing. Increasing the Al content (especially 0.14% or more) also has the effect of reducing intergranular corrosion susceptibility, which is the cause of gold dust generation. However, if Al is added excessively, it becomes difficult to remove scale in the pickling process, so the content was set to 0.10 to 0.30%. Preferably,
0.14 to 0.20%.

【0024】熱間圧延条件:スラブ加熱温度を1300℃か
ら1000℃へと低温にするに従い、熱間圧延後の組織は展
伸粒から等軸細粒化した組織へと変化していく。高温ス
ラブ材ではγ+αの2相域圧延となる。γ相の部分は圧
延により展伸し、熱間圧延後の冷却でマルテンサイトと
なり、その後の連続焼鈍でα+炭化物に分解するが、依
然として展伸粒は残りリジング性を悪化させる。
Hot rolling conditions: As the slab heating temperature is lowered from 1300 ° C. to 1000 ° C., the structure after hot rolling changes from wrought grain to equiaxed grain. In the case of a high-temperature slab material, two-phase rolling of γ + α is performed. The portion of the γ phase is expanded by rolling, becomes martensite by cooling after hot rolling, and is decomposed into α + carbides by continuous annealing, but the expanded particles remain and deteriorate ridging properties.

【0025】しかし、1200℃以下の低温加熱を行うと、
圧延時にγ相の析出は認められず、またAlN が析出した
ままの組織のため、その後の連続焼鈍で等軸で微細な再
結晶組織となる。1100℃未満の低温加熱は実操業上不可
能なため、スラブ加熱温度は1100〜1200℃とする。その
他の熱間圧延条件は本発明にあって特に制限はされず、
仕上温度、圧下量などは例えば従来のそれと同様に行え
ばよい。
However, when heating at a low temperature of 1200 ° C. or less,
No precipitation of the γ phase is observed during rolling, and the structure is the one in which AlN has been precipitated, so that the subsequent continuous annealing results in an equiaxed and fine recrystallized structure. Since low-temperature heating below 1100 ° C is not practically possible, the slab heating temperature should be 1100-1200 ° C. Other hot rolling conditions are not particularly limited in the present invention,
The finishing temperature, the reduction amount, etc. may be performed in the same manner as in the conventional case.

【0026】熱延板の連続焼鈍条件:本発明が対象とす
る鋼種は、従来のアルミニウム含有フェライト系ステン
レス鋼に対し、高Al、低C化したことにより変態点が上
がり、1000℃以上の高温焼鈍が可能となった。また、Al
N の析出温度が上昇したことにより、1000℃以上の高温
焼鈍でも耐リジング性を向上させることができる。ま
た、従来材に比べ靱性が向上したため、熱延板の連続焼
鈍ラインでの通板も問題ない。なお、焼鈍温度が1100℃
超になると変態点を超えるため、連続焼鈍の温度は1000
〜1100℃とした。
Continuous annealing condition of hot-rolled sheet: The steel type targeted by the present invention has a higher transformation point due to high Al and low C compared to the conventional aluminum-containing ferritic stainless steel, and has a high transformation temperature of 1000 ° C. or higher. Annealing became possible. Also, Al
Due to the increase in the precipitation temperature of N 2, ridging resistance can be improved even at a high temperature annealing of 1000 ° C. or more. Further, since the toughness is improved as compared with the conventional material, there is no problem in passing the hot-rolled sheet through the continuous annealing line. The annealing temperature is 1100 ℃
Since the temperature exceeds the transformation point when exceeding, the temperature of continuous annealing is 1000
~ 1100 ° C.

【0027】このような焼鈍温度への加熱に引き続いて
15℃/ 秒以上の冷却速度で急冷を行うが、これはCrの炭
窒化物の粒界への析出を阻止するためであり、これによ
りゴールドダストの発生が効果的に防止できる。冷却速
度15℃/ 秒とは、ほぼ空冷による冷却に相当し、そのほ
か水冷による冷却のように冷却速度を上昇させることも
可能であるが、経済上の観点から通常はその上限は50℃
/ 秒である。連続焼鈍に続いては、慣用手段にしたがっ
て冷間圧延および再結晶焼鈍処理を行う。本発明におい
て特にそれらの条件に制限はない。
Following the heating to the annealing temperature,
The quenching is performed at a cooling rate of 15 ° C./second or more, in order to prevent the precipitation of Cr at the grain boundaries of carbonitrides, thereby effectively preventing the generation of gold dust. The cooling rate of 15 ° C / sec is almost equivalent to cooling by air cooling.In addition, it is possible to increase the cooling rate like cooling by water cooling, but from an economic viewpoint, the upper limit is usually 50 ° C.
/ Second. Following the continuous annealing, cold rolling and recrystallization annealing are performed according to conventional means. In the present invention, those conditions are not particularly limited.

【0028】[0028]

【実施例】次に、実施例によって本発明の作用効果をさ
らに具体的に説明する。表1に示す成分組成の鋼片を溶
製し、表2に示す試験条件で熱間圧延(3.0mm)、および
中間焼鈍を行った。
Next, the operation and effect of the present invention will be described more specifically with reference to examples. A slab having the composition shown in Table 1 was melted and subjected to hot rolling (3.0 mm) and intermediate annealing under the test conditions shown in Table 2.

【0029】その後、圧下率0.5 〜1%の調質圧延を行
った後、酸洗を行い冷間圧延(1.0mm) を施し、900 ℃、
2分の仕上焼鈍、酸洗を行い、得られた供試材について
以下の調査を行った。
Then, after temper rolling at a rolling reduction of 0.5 to 1%, pickling and cold rolling (1.0 mm) were carried out at 900 ° C.
The sample was subjected to finish annealing and pickling for 2 minutes, and the following test was performed on the obtained test material.

【0030】(1) 機械的特性調査 供試材のT部、M部、B部からL方向にJIS 13B 号試験
片を採取し引張試験を行った上で、最良値をサンプル特
性とした。
(1) Investigation of Mechanical Properties A JIS No. 13B test piece was sampled from the T part, M part, and B part of the test material in the L direction, and a tensile test was performed.

【0031】(2) 耐リジング性の調査 供試材のT部、M部、B部からT方向にJIS 5号試験片
を採取し、リジング測定試験を行った上で最良値をサン
プル特性とした。
(2) Investigation of ridging resistance A JIS No. 5 test piece was sampled in the T direction from the T, M, and B parts of the test material, and a ridging measurement test was performed. did.

【0032】耐リジング性の評価は、表面粗さを測定
し、最大粗さをリジング高さとした。ただし、その評価
基準は、A' 、B、B' はそれぞれリジングの高さが1
2、18、24μm である。
For evaluation of ridging resistance, the surface roughness was measured, and the maximum roughness was defined as the ridging height. However, the evaluation criterion is that A ', B and B' each have a ridging height of 1
2, 18, and 24 μm.

【0033】(3) ゴールドダスト特性調査 目視により判定し、3段階で評価した。 ○:明らかに正常 △:若干のゴールドダストあり ×:ゴールドダストあり 結果を表3に示す。表3に示すとおり、本発明材の機械
的特性は良好であり、耐リジング性、ゴールドダスト特
性も従来材に比べ向上した。
(3) Investigation of Gold Dust Characteristics Judgment was made visually and evaluated in three steps. :: Clearly normal Δ: Some gold dust X: Gold dust present The results are shown in Table 3. As shown in Table 3, the mechanical properties of the material of the present invention were good, and the ridging resistance and the gold dust property were also improved as compared with the conventional material.

【0034】次に、鋼組成(0.03C−0.3Si −0.12Mn−0.
1Ni −16.2Cr−0.12Al−0.0121N)のアルミニウム含有フ
ェライト系ステンレス鋼について加熱温度と保持時間を
変えて、そのときのAlN 析出状態を調べた。結果は図1
に示す通りである。
Next, the steel composition (0.03C-0.3Si-0.12Mn-0.
1Ni-16.2Cr-0.12Al-0.0121N) aluminum-containing ferritic stainless steel was examined by changing the heating temperature and the holding time, and the AlN precipitation state at that time. The result is shown in FIG.
As shown in FIG.

【0035】実線は従来法、破線は本発明法によるAlN
析出領域を示す。
The solid line is the conventional method, and the dashed line is the AlN
Shows the precipitation area.

【0036】従来法では鋼中C量が高く、変態点が低い
のでAlN の析出範囲は1000℃以下であり、AlN 析出のた
めには1000℃以下で長時間の連続焼鈍が必要であり、そ
のため耐リジング性が劣化していた。
In the conventional method, the C content in steel is high and the transformation point is low, so that the precipitation range of AlN is 1000 ° C. or less. For AlN precipitation, continuous annealing at 1000 ° C. or less for a long time is necessary. The ridging resistance was deteriorated.

【0037】本発明法では、C量を下げたため変態点が
上昇し、図1に示すように、従来材に比べAlN 析出範囲
が高温側に移行する。したがって、本発明法では、1000
℃以上1100℃までの高温短時間連続焼鈍で、AlN を析出
させることが可能となるため、耐リジング性の向上が可
能となる。同様に、熱延板焼鈍温度と衝撃値(Kg-m/mm2)
との関係を調べ、その結果を図2にグラフで示す。
In the method of the present invention, the transformation point rises because the C content is reduced, and as shown in FIG. 1, the AlN precipitation range shifts to the higher temperature side as compared with the conventional material. Therefore, in the method of the present invention, 1000
Since AlN can be precipitated by continuous annealing at a high temperature of 1100 ° C. or more and a high temperature of 1100 ° C., ridging resistance can be improved. Similarly, hot rolled sheet annealing temperature and impact value (Kg-m / mm 2 )
Was examined, and the results are shown in a graph in FIG.

【0038】一般的に、焼鈍温度が鋼の変態点を越える
とAlN 析出量が少なくなるため、衝撃特性は急激に低下
することが判っている。実線で示す従来法では、鋼中C
量が高く、変態点が低くなるので、衝撃特性を良好に保
つためには1000℃以下の低温で長時間焼鈍せざるを得
ず、そのため、1000℃を越える高温で連続焼鈍すると、
AlN 析出量不足に起因する衝撃値低下がみられ、連続焼
鈍中に板破断を起こし操業一時停止 (1〜2時間) 等の
トラブルが散発する問題があった。
In general, it has been found that when the annealing temperature exceeds the transformation point of steel, the amount of AlN precipitated decreases, so that the impact characteristics sharply decrease. In the conventional method shown by the solid line, C
Since the amount is high and the transformation point is low, in order to maintain good impact characteristics, it is necessary to perform annealing at a low temperature of 1000 ° C. or less for a long time, so if continuous annealing at a high temperature exceeding 1000 ° C.,
The impact value was reduced due to the insufficient amount of AlN precipitation, and there was a problem that the plate was broken during continuous annealing and troubles such as a temporary stoppage of the operation (1-2 hours) were sporadic.

【0039】しかし、本発明法では、鋼中C量を下げた
ので、変態点温度が上昇し、AlN 析出も高温側 (1100℃
以上) へ移行する。したがって、本発明では1000℃以上
1100℃までの高温連続焼鈍を行っても、AlN が十分析出
するため、図2に示すように1000〜1100℃の高温連続焼
鈍を行っても、衝撃値は低下せず、連続焼鈍中の板破断
等のトラブルも発生しない。
However, in the method of the present invention, since the amount of C in the steel was reduced, the transformation point temperature was increased, and the precipitation of AlN was also on the high temperature side (1100 ° C.).
To). Therefore, in the present invention, 1000 ° C or more
Even when high-temperature continuous annealing up to 1100 ° C is performed, AlN is sufficiently precipitated. Therefore, even if high-temperature continuous annealing at 1000 to 1100 ° C is performed as shown in FIG. No troubles such as plate breakage occur.

【0040】[0040]

【表1】 [Table 1]

【0041】[0041]

【表2】 [Table 2]

【0042】[0042]

【表3】 [Table 3]

【0043】[0043]

【発明の効果】本発明法により、従来のアルミニウム含
有フェライトステンレス鋼に対し、高Al、低C化したこ
とにより、変態点が上昇し、1000℃以上の高温焼鈍が可
能となった。またAlN の析出温度が上昇したことによ
り、1000℃以上の高温焼鈍でも耐リジング性が向上し
た。従来材に比べ靱性が向上したため、ライン通板時の
板破断の問題もない実用的な連続焼鈍が実現できた。
According to the method of the present invention, the transformation point is raised and the high temperature annealing at 1000 ° C. or more is made possible by increasing the Al and the C content as compared with the conventional aluminum-containing ferritic stainless steel. In addition, the rise in the precipitation temperature of AlN improved the ridging resistance even at a high temperature annealing of 1000 ° C or higher. Since the toughness was improved as compared with the conventional material, practical continuous annealing without the problem of plate breakage during line passing was realized.

【図面の簡単な説明】[Brief description of the drawings]

【図1】AlN の析出状態を温度および保持時間に対して
示すグラフである。
FIG. 1 is a graph showing the precipitation state of AlN with respect to temperature and holding time.

【図2】熱延板の焼鈍温度と衝撃値との関係を示すグラ
フである。
FIG. 2 is a graph showing a relationship between an annealing temperature of a hot-rolled sheet and an impact value.

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 重量%で、 C:0.02〜0.05%、 Si:1.0 %以下、 Mn:1.5
%以下、 N:0.01〜0.03%、 Cr:15〜18%、 Al:0.10
〜0.30%、 残部Feおよび不可避的不純物よりなる鋼組成を有するス
ラブを1100〜1200℃に加熱して熱間圧延を行い、得られ
た熱延板を、焼鈍温度1000〜1100℃、冷却速度15℃/秒
以上で急冷する連続焼鈍を行い、その後、冷間圧延およ
び再結晶焼鈍を行うことを特徴とする、耐リジング性に
優れ、表面性状が良好なアルミニウム含有フェライト系
ステンレス鋼板の製造方法。
C .: 0.02 to 0.05%, Si: 1.0% or less, Mn: 1.5% by weight
%: N: 0.01 to 0.03%, Cr: 15 to 18%, Al: 0.10
A slab having a steel composition consisting of 0.30.30%, the balance of Fe and unavoidable impurities is heated to 1100 to 1200 ° C. to perform hot rolling, and the obtained hot rolled sheet is subjected to an annealing temperature of 1000 to 1100 ° C. and a cooling rate of 15%. A method for producing an aluminum-containing ferritic stainless steel sheet having excellent ridging resistance and excellent surface properties, comprising performing continuous annealing by rapidly cooling at a rate of at least ° C / sec, and then performing cold rolling and recrystallization annealing.
JP6278983A 1994-11-14 1994-11-14 Manufacturing method of ferritic stainless steel sheet Expired - Lifetime JP3042331B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6278983A JP3042331B2 (en) 1994-11-14 1994-11-14 Manufacturing method of ferritic stainless steel sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6278983A JP3042331B2 (en) 1994-11-14 1994-11-14 Manufacturing method of ferritic stainless steel sheet

Publications (2)

Publication Number Publication Date
JPH08134550A JPH08134550A (en) 1996-05-28
JP3042331B2 true JP3042331B2 (en) 2000-05-15

Family

ID=17604795

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6278983A Expired - Lifetime JP3042331B2 (en) 1994-11-14 1994-11-14 Manufacturing method of ferritic stainless steel sheet

Country Status (1)

Country Link
JP (1) JP3042331B2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100598576B1 (en) * 1999-09-01 2006-07-13 주식회사 포스코 Method for producing ferritic stainless steel sheets having excellent press formability and ridging properity
KR100467719B1 (en) * 2000-12-08 2005-01-24 주식회사 포스코 Method of producing ferritic stainless steel sheets having softning, anti-ridging property and excellent spinning formability
JP5768641B2 (en) * 2010-10-08 2015-08-26 Jfeスチール株式会社 Ferritic stainless steel having excellent corrosion resistance and electrical conductivity, method for producing the same, polymer electrolyte fuel cell separator, and polymer electrolyte fuel cell
CN112646958A (en) * 2020-11-30 2021-04-13 中国科学院金属研究所 Heat treatment process of low-alloy high-strength high-weather-resistance structural steel for highway guardrail

Also Published As

Publication number Publication date
JPH08134550A (en) 1996-05-28

Similar Documents

Publication Publication Date Title
US8048239B2 (en) Ferritic stainless steel sheet superior in shapeability and method of production of the same
JP5862051B2 (en) High-strength cold-rolled steel sheet excellent in workability and manufacturing method thereof
JP4225976B2 (en) Cr-containing heat-resistant steel sheet having excellent workability and method for producing the same
JP6795122B1 (en) High-strength galvanized steel sheet and its manufacturing method
JPWO2020203158A1 (en) Steel plate
EP3705592A1 (en) High-strength cold-rolled steel sheet, high-strength plated steel sheet, and production methods therefor
KR20220073804A (en) Ferritic stainless steel sheet, manufacturing method thereof, and ferritic stainless steel member
JPWO2020148948A1 (en) High-strength galvanized steel sheet and its manufacturing method
WO2022080497A1 (en) Steel sheet and method for manufacturing same
US20060225820A1 (en) Ferritic stainless steel sheet excellent in formability and method for production thereof
JP3468048B2 (en) Manufacturing method of high carbon cold rolled steel sheet with excellent formability
JP4205893B2 (en) High-strength hot-rolled steel sheet excellent in press formability and punching workability and manufacturing method thereof
US11718887B2 (en) Ferrite-based stainless steel having excellent impact toughness, and method for producing same
JP3042331B2 (en) Manufacturing method of ferritic stainless steel sheet
WO2009066868A1 (en) Low chrome ferritic stainless steel with high corrosion resistance and stretchability and method of manufacturing the same
JP3804408B2 (en) Method for producing heat-resistant and corrosion-resistant steel sheet containing Cr with excellent formability
JP6947327B2 (en) High-strength steel sheets, high-strength members and their manufacturing methods
KR102463485B1 (en) Ferritic stainless steel sheet, manufacturing method thereof, and ferritic stainless steel member
JP4205892B2 (en) High-strength hot-rolled steel sheet excellent in press formability and punching workability and manufacturing method thereof
JP2001089814A (en) Method of manufacturing ferritic stainless steel sheet excellent in ductility, workability and ridging resistance
JP3911075B2 (en) Manufacturing method of steel sheet for ultra deep drawing with excellent bake hardenability
KR102568217B1 (en) Ultra-high strength steel sheet having excellent hole-expandability and method of manufacturing the same
TWI711706B (en) Automobile steel material with high yield strength and method of manufacturing the same
JP4606820B2 (en) Method for producing soft Nb-added ferritic stainless steel sheet
JP3925063B2 (en) Cold-rolled steel sheet excellent in press formability and strain age hardening characteristics and method for producing the same

Legal Events

Date Code Title Description
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20000208