JP2932700B2 - Blade material and manufacturing method - Google Patents
Blade material and manufacturing methodInfo
- Publication number
- JP2932700B2 JP2932700B2 JP74091A JP74091A JP2932700B2 JP 2932700 B2 JP2932700 B2 JP 2932700B2 JP 74091 A JP74091 A JP 74091A JP 74091 A JP74091 A JP 74091A JP 2932700 B2 JP2932700 B2 JP 2932700B2
- Authority
- JP
- Japan
- Prior art keywords
- blade
- layer
- intermetallic compound
- base material
- foil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Description
【０００１】[0001]
【産業上の利用分野】本発明は、２枚の刃が摺動的に接
触して剪断を行なう、またはネットと刃とが摺動的に接
触して剪断を行なうタイプの利器または工具に使用する
刃物材と、その製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is used for a tool or a tool of the type in which two blades slidably contact with each other for shearing, or a net and a blade slidably contact each other for shearing. And a method of manufacturing the same.
【０００２】[0002]
【従来の技術】電気カミソリのように、固定ネットとそ
れに接して回転または往復動する刃とでネットがとらえ
たヒゲを剪断するタイプの刃物は、相互の繰り返し摺動
に耐えるよう、耐摩耗性が高くなければならない。 同
様なことは、各種の電動カッタ−にも要求される。 こ
のため、刃物材としては、耐食性の要求にこたえること
も兼ねて、高炭素ステンレス鋼（代表的にはＳＵＳ４４
０Ｂ）などが用いられている。2. Description of the Related Art A blade, such as an electric razor, that shears a beard captured by a fixed net and a blade that rotates or reciprocates in contact with the fixed net, has abrasion resistance so as to withstand mutual repetitive sliding. Must be high. The same is required for various electric cutters. For this reason, as a blade material, high carbon stainless steel (typically SUS44) is used to meet the demand for corrosion resistance.
0B) is used.
【０００３】しかし既存の材料は満足できるものとはい
えず、切れ味を長期にわたって維持する刃物材の出現が
待たれていた。[0003] However, existing materials are not satisfactory, and the appearance of blade materials that maintain the sharpness over a long period of time has been awaited.
【０００４】[0004]
【発明が解決しようとする課題】本発明の目的は、この
ような要望にこたえて、耐食性と耐摩耗性が高く、かつ
それらが長期間持続して切れ味が保たれる刃物材と、そ
の製造方法を提供することにある。SUMMARY OF THE INVENTION The object of the present invention is to meet such demands and to provide a blade material which has high corrosion resistance and abrasion resistance and which maintains its sharpness for a long period of time. It is to provide a method.
【０００５】[0005]
【課題を解決するための手段】本発明の刃物材のひとつ
の態様は、２枚の刃が摺動的に接触して剪断を行なう刃
物材において、図３および図６に示すように、それらの
刃の接触面上に、刃物基材（１）中の金属元素とＡｌと
の金属間化合物の層（４）を介してＡｌ2Ｏ3の層（５）
を有する刃物材である。One aspect of the blade material of the present invention is a blade material in which two blades slidably contact with each other to perform shearing, as shown in FIGS. A layer of Al 2 O 3 (5) on a contact surface of the blade through a layer (4) of an intermetallic compound of a metal element and Al in the blade substrate (1)
It is a blade material having.
【０００６】本発明の刃物材のいまひとつの態様は、ネ
ットと刃とが摺動的に接触してネットがとらえた被切断
物の剪断を行なう刃物材において、少なくとも刃の接触
面上に、上記と同様に、刃物基材（１）中の金属元素と
Ａｌとの金属間化合物の層（４）を介してＡｌ2Ｏ3の層
（５）を有する刃物材である。Another aspect of the blade material according to the present invention is a blade material in which a net and a blade are slidably contacted to shear a workpiece caught by the net. Similarly to the above, a blade material having a layer (5) of Al 2 O 3 via a layer (4) of an intermetallic compound of a metal element and Al in the blade substrate (1).
【０００７】金属間化合物の層およびＡｌ2Ｏ3の層は、
刃物基材の表面のうち、少なくとも摺動的に接触する面
にあればよいが、他の面にも存在すれば、全体として耐
食性が向上して好ましい。The layer of the intermetallic compound and the layer of Al 2 O 3
Of the surfaces of the blade base material, at least the surface that slidably contacts the surface is sufficient, but the presence of the other surface is preferable because the corrosion resistance is improved as a whole.
【０００８】刃物基材としては、刃物に要求される諸性
質すなわち靭性、剛性などをそなえている任意の合金が
使用できるが、好適なものを挙げれば、前記した高硬度
非磁性ステンレス鋼のほか、Ｆｅ−Ｍｎ合金およびＢｅ
−Ｃｕ合金である。 これらの合金の基材金属の表面
に、Ｎｉ層を設けたものであってもよい。 この場合、
金属間化合物としてはＮｉＡｌおよびＮｉ3Ａｌの少な
くとも一方、多くの場合は両方が生成する。[0008] As the blade substrate, any alloy having various properties required for the blade, ie, toughness, rigidity, etc., can be used. , Fe-Mn alloy and Be
-Cu alloy. A Ni layer may be provided on the surface of a base metal of these alloys. in this case,
As the intermetallic compound, at least one of NiAl and Ni 3 Al, and in most cases, both are formed.
【０００９】上記のような刃物材を製造する本発明の方
法は、基本的には図１および図２に示すように、刃物基
材（１）の表面（図示した例では両方の面）にＡｌ箔
（２Ａ）を重ね圧延によりクラッドし、得られたクラッ
ド材に対して真空焼鈍および酸化性雰囲気下での加熱を
行なって、刃物基材中の金属とＡｌ層との間に金属間化
合物を形成させるとともに、表面にＡｌ2Ｏ3層（５）を
形成させ、図３にみるような製品を得ることからなる。[0009] The method of the present invention for producing a blade material as described above basically applies to the surface (both surfaces in the illustrated example) of the blade substrate (1) as shown in FIGS. The aluminum foil (2A) is clad by lap rolling, and the obtained clad material is subjected to vacuum annealing and heating in an oxidizing atmosphere to form an intermetallic compound between the metal in the blade base material and the Al layer. And an Al 2 O 3 layer (5) on the surface to obtain a product as shown in FIG.
【００１０】本発明の刃物材の製造方法の別の態様は、
図４および図５に示すように、刃物基材（１）の表面に
Ｎｉ箔（３Ａ）およびＡｌ箔（２Ａ）をこの順でクラッ
ドし、得られたクラッド材に対し真空焼鈍および酸化性
雰囲気下での加熱を行なって、Ｎｉ層とＡｌ層との間で
ＮｉＡｌおよび（または）Ｎｉ3Ａｌを形成させるとと
もに、表面にＡｌ2Ｏ3層（５）を形成させることからな
る。[0010] Another aspect of the method for producing a blade material of the present invention is as follows.
As shown in FIGS. 4 and 5, a Ni foil (3A) and an Al foil (2A) are clad on the surface of the blade base material (1) in this order, and the obtained clad material is subjected to vacuum annealing and an oxidizing atmosphere. The lower heating is performed to form NiAl and / or Ni 3 Al between the Ni layer and the Al layer, and to form the Al 2 O 3 layer (5) on the surface.
【００１１】真空焼鈍は、４００〜６５０℃×１〜２０
０分間、代表的には６００℃×２分間行なう。The vacuum annealing is performed at 400 to 650 ° C. × 1 to 20
This is performed for 0 minutes, typically at 600 ° C. for 2 minutes.
【００１２】酸化性雰囲気下での加熱は、大気中、６０
０〜１２００℃×１〜１０００分間、代表的には９００
℃×２分間の条件で行なうのが適当である。Heating in an oxidizing atmosphere is carried out in air at 60
0 to 1200 ° C for 1 to 1000 minutes, typically 900
It is appropriate to carry out under the condition of ° C. × 2 minutes.
【００１３】[0013]
【作用】真空焼鈍により、圧延過程で生じた加工硬化が
消滅し、基材とＡｌ箔の間、また基材とＮｉ箔を重ねた
場合はＮｉ箔とＡｌ箔との間で、相互に拡散が進む。続
く酸化性雰囲気下での加熱により、拡散はさらに進行す
る。 その結果、基材中のＡｌと金属間化合物を形成す
る金属元素、たとえば基材がステンレス鋼の場合はＦｅ
およびＮｉが、Ａｌと、Ｆｅ3Ａｌ，ＮｉＡｌ，Ｎｉ3Ａ
ｌなどの化合物をつくる。 基材とＡｌ箔との間にＮｉ
箔をはさんだ場合には、金属間化合物としてＮｉＡｌお
よびＮｉ3Ａｌが生成することはいうまでもない。The work hardening generated in the rolling process disappears due to the vacuum annealing, and is diffused between the base material and the Al foil or between the Ni foil and the Al foil when the base material and the Ni foil are stacked. Advances. Diffusion further proceeds by the subsequent heating in an oxidizing atmosphere. As a result, a metal element that forms an intermetallic compound with Al in the base material, such as Fe when the base material is stainless steel
And Ni are Al and Fe 3 Al, NiAl, Ni 3 A
Make compounds such as l. Ni between substrate and Al foil
Needless to say, when the foil is sandwiched, NiAl and Ni 3 Al are generated as intermetallic compounds.
【００１４】酸化性雰囲気下での加熱により、表面のＡ
ｌ層は酸化されてＡｌ2Ｏ3となり、主としてウィスカー
の形で成長する。By heating in an oxidizing atmosphere, the surface A
The 1 layer is oxidized to Al 2 O 3 and grows mainly in the form of whiskers.
【００１５】上記したような金属間化合物は一般に耐食
性にすぐれているので、表面を被覆するＡｌ2Ｏ3層にピ
ンホールやミクロなクラックが生じても、腐食を下の基
材に及ぼすことなく、そこで食い止める。Since the above-mentioned intermetallic compound generally has excellent corrosion resistance, even if pinholes or microcracks occur in the Al 2 O 3 layer covering the surface, corrosion does not affect the underlying substrate. And stop it there.
【００１６】表面のＡｌ2Ｏ3はセラミックの層であっ
て、よく知られているとおり耐摩耗性が高く、刃物の切
れ味の維持に効果的である。Al 2 O 3 on the surface is a ceramic layer, and as is well known, has high abrasion resistance and is effective in maintaining the sharpness of the blade.
【００１７】[0017]
【実施例】［実施例１］高硬度非磁性ステンレス鋼「Ｄ
ＳＮ６」（大同特殊鋼の鋼種記号、合金組成は、０．０
９Ｃ−０．３Ｓｉ−１．５Ｍｎ−１２．０Ｎｉ−１８．
０Ｃｒ−Ｆｅ）の、厚さ０．４mmのシートを用意した。
その両面に厚さ１５μｍのＡｌ箔を重ねてクラッド圧
延して、厚さ０．３８mmの積層材とした。[Example 1] High hardness non-magnetic stainless steel "D"
SN6 "(Steel type symbol of Daido special steel, alloy composition is 0.0
9C-0.3Si-1.5Mn-12.0Ni-18.
0Cr-Fe), a sheet having a thickness of 0.4 mm was prepared.
A 15 μm-thick Al foil was overlaid on each side and clad rolled to obtain a laminated material having a thickness of 0.38 mm.
【００１８】積層材を冷間圧延して厚さ０．１mmのシー
トにしてから、真空中で６００℃×２０分間の焼鈍、続
いて大気中で１０００℃×１時間の加熱を行なった。
これにより、図３に示す層構成の刃物材を得た。The laminated material was cold-rolled into a sheet having a thickness of 0.1 mm, and then annealed at 600 ° C. for 20 minutes in vacuum, and then heated at 1000 ° C. for 1 hour in air.
Thus, a blade material having a layer configuration shown in FIG. 3 was obtained.
【００１９】得られた刃物材に対して、下記の試験を行
なった。 １） 耐摩耗性：大越式摩耗試験機による摩耗試験、相
手材はＷＣ ２） 高温耐食性：６００℃×３０分間の加熱−５％食
塩水中に浸漬×５分間−乾燥のサイクルから成る試験 比較のため、ＳＵＳ４４０Ｂ鋼の厚さ０．１mmのシート
を、同様に試験した。The following test was performed on the obtained blade material. 1) Abrasion resistance: Abrasion test by Ogoshi abrasion tester, WC is the counterpart material 2) High temperature corrosion resistance: Test consisting of heating at 600 ° C for 30 minutes-immersion in 5% saline solution x 5 minutes-drying cycle Therefore, a sheet of SUS440B steel having a thickness of 0.1 mm was similarly tested.
【００２０】結果を、あわせて図７および図８に示す。The results are shown in FIG. 7 and FIG.
【００２１】［実施例２］実施例１で用いたものと同じ
ＤＳＮ６のシートの両面に、厚さが１００μｍのＮｉ箔
をはさんで、やはり厚さ１５μｍのＡｌ箔を重ね、クラ
ッド圧延および冷間圧延を行なって厚さ０．１mmのシー
トとした。Example 2 A 15 μm thick Al foil was also placed on both sides of the same DSN6 sheet used in Example 1 with a 100 μm thick Ni foil interposed therebetween, and clad rolling and cooling were performed. Cold rolling was performed to obtain a sheet having a thickness of 0.1 mm.
【００２２】実施例１と同じ条件で真空焼鈍および大気
中の加熱を行なって、図６に示す層構成の刃物材を得
た。Vacuum annealing and heating in the air were performed under the same conditions as in Example 1 to obtain a blade material having a layer structure shown in FIG.
【００２３】実施例１の刃物材と同様、この材料も、基
材のＤＳＮ６が加熱処理によって時効硬化しているの
で、図示した耐摩耗性および耐食性とともに、電気カミ
ソリの材料として好適であった。Like the blade material of Example 1, this material was also suitable as an electric razor material, as well as the abrasion resistance and corrosion resistance shown, since the DSN 6 of the base material was age-hardened by heat treatment.
【００２４】[0024]
【発明の効果】本発明により、表面がセラミックスのＡ
ｌ2Ｏ3で被覆されて耐摩耗性の向上した刃物材が実現す
る。 この刃物材は、Ａｌ2Ｏ3層の下に存在する金属間
化合物の層により、耐食性が高められている。 従っ
て、この材料で製作した刃物は、長期にわたってよい切
れ味を維持することができる。According to the present invention, the surface of ceramics is
A blade material coated with l 2 O 3 and having improved wear resistance is realized. This blade material is enhanced in corrosion resistance by an intermetallic compound layer present under the Al 2 O 3 layer. Therefore, a blade made of this material can maintain good sharpness over a long period of time.
【００２５】[0025]
【図１】 本発明の刃物材の基本的な製造工程を説明す
るための材料の断面図であって、基材とＡｌ箔を重ねた
段階を示す。FIG. 1 is a cross-sectional view of a material for explaining a basic manufacturing process of a blade material according to the present invention, showing a stage in which a base material and an Al foil are stacked.
【図２】 本発明の刃物材の基本的な製造工程を説明す
るための材料の断面図であって、クラッド圧延した段階
を示す。FIG. 2 is a cross-sectional view of a material for explaining a basic manufacturing process of the blade material of the present invention, and shows a stage after clad rolling.
【図３】 図１および図２の工程によって得た、本発明
の刃物材の基本的な層構成を示す図。FIG. 3 is a diagram showing a basic layer configuration of the blade material of the present invention obtained by the steps of FIGS. 1 and 2;
【図４】 本発明の刃物材の別の製造工程を説明するた
めの材料の断面図であって、図１に対応して、基材とＡ
ｌ箔を、Ｎｉ箔を介して重ねた段階を示す。FIG. 4 is a cross-sectional view of a material for explaining another manufacturing process of the blade material of the present invention, and corresponds to FIG.
1 shows a stage in which 1 foil is stacked via a Ni foil.
【図５】 本発明の刃物材の別の製造工程を説明するた
めの、材料の断面図であって、図２に対応して、クラッ
ド圧延した段階を示す。FIG. 5 is a cross-sectional view of the material for explaining another manufacturing process of the blade material of the present invention, and shows a stage of clad rolling corresponding to FIG.
【図６】 図４および図５の工程によって得た、本発明
の刃物材の層構成を示す図。FIG. 6 is a diagram showing a layer configuration of the blade material of the present invention obtained by the steps of FIGS. 4 and 5;
【図７】 本発明の実施例における、耐摩耗性のデータ
を示すグラフ。FIG. 7 is a graph showing wear resistance data in Examples of the present invention.
【図８】 本発明の実施例における、耐食性のデータを
示すグラフ。FIG. 8 is a graph showing corrosion resistance data in an example of the present invention.
１ 基材 ２Ａ，２Ｂ Ａｌ ３Ａ，３Ｂ Ｎｉ ４ Ｆｉ3Ａｌ，Ｎｉ3Ａｌ，ＮｉＡｌ ５ Ａｌ2Ｏ３ 1 Base material 2A, 2B Al 3A, 3B Ni 4 Fi 3 Al, Ni 3 Al, NiAl 5 Al 2 O 3
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.6，ＤＢ名) B26D 1/14 B26B 19/00 ──────────────────────────────────────────────────続 き Continued on front page (58) Field surveyed (Int. Cl. 6 , DB name) B26D 1/14 B26B 19/00
Claims (9)
挟んだ被切断物の剪断を行なう刃物材において、それら
の刃の接触面上に、刃物基材中の金属元素とＡｌとの金
属間化合物の層を介してＡｌ2Ｏ3の層を有することを特
徴とする刃物材。1. A blade material in which two blades slidably contact with each other to shear an object sandwiched between the blades, and a metal in a blade substrate is provided on a contact surface of the blades. A blade material having a layer of Al 2 O 3 via a layer of an intermetallic compound of an element and Al.
鋼、Ｆｅ−Ｍｎ合金およびＢｅ−Ｃｕ合金からえらんだ
基材金属のいずれかから成るものである請求項１の刃物
材。2. The blade material according to claim 1, wherein the blade substrate is made of any one of a base metal selected from a high-hardness non-magnetic stainless steel, an Fe—Mn alloy, and a Be—Cu alloy.
にＮｉ層を設けたものであり、金属間化合物がＮｉＡｌ
および（または）Ｎｉ3Ａｌである請求項１の刃物材。3. The cutting tool base material according to claim 2, wherein a Ni layer is provided on the surface of the base metal, and the intermetallic compound is NiAl.
And / or Ni 3 Al.
がとらえた被切断物の剪断を行なう刃物において、少な
くとも刃の接触面上に、刃物基材中の金属元素とＡｌと
の金属間化合物の層を介してＡｌ2Ｏ3の層を有すること
を特徴とする刃物材。4. A cutting tool in which a net and a blade are slidably contacted to shear a workpiece caught by the net, wherein at least on a contact surface of the blade, a metal element in the cutting tool base material and Al A blade material having an Al 2 O 3 layer via an intermetallic compound layer.
鋼、Ｆｅ−Ｍｎ合金およびＢｅ−Ｃｕ合金からえらんだ
基材金属のいずれかから成るものである請求項４の刃物
材。5. The blade material according to claim 4, wherein the blade substrate is made of any one of a base metal selected from a high-hardness non-magnetic stainless steel, an Fe—Mn alloy, and a Be—Cu alloy.
にＮｉ層を設けたものであり、金属間化合物がＮｉＡｌ
および（または）Ｎｉ3Ａｌである請求項４の刃物材。6. The knife base material according to claim 2, wherein a Ni layer is provided on the surface of the base metal, and the intermetallic compound is NiAl.
And / or Ni 3 Al.
得られたクラッド材に対し真空焼鈍および酸化性雰囲気
下での加熱を行なって、刃物基材中の金属元素とＡｌ層
との間に金属間化合物を形成させるとともに、表面にＡ
ｌ2Ｏ3層を形成させることからなる刃物材の製造方法。7. An aluminum foil is clad on a surface of a blade base material,
The obtained clad material is subjected to vacuum annealing and heating in an oxidizing atmosphere to form an intermetallic compound between the metal element in the blade base material and the Al layer, and to form A on the surface.
A method for producing a blade material comprising forming an l 2 O 3 layer.
この順でクラッドし、得られたクラッド材に対し真空焼
鈍および酸化性雰囲気下での加熱を行なって、Ｎｉ層と
Ａｌ層との間でＮｉＡｌおよび（または）Ｎｉ3Ａｌを
形成させるとともに、表面にＡｌ2Ｏ3層を形成させるこ
とからなる刃物材の製造方法。8. A Ni foil and an Al foil are clad on the surface of the blade base material in this order, and the obtained clad material is subjected to vacuum annealing and heating in an oxidizing atmosphere to form a Ni layer and an Al layer. A method of manufacturing a blade material comprising forming NiAl and / or Ni 3 Al between the layers and forming an Al 2 O 3 layer on the surface.
０分間、酸化性雰囲気下での加熱を大気中６００〜１０
００℃×５〜２０時間の条件で実施する請求項７または
８の製造方法。9. Vacuum annealing at 400 to 650 ° C. × 1 to 20
Heating in an oxidizing atmosphere for 0 minute is performed in air at 600 to 10
The method according to claim 7, wherein the method is carried out under the conditions of 00 ° C. × 5 to 20 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP74091A JP2932700B2 (en) | 1991-01-08 | 1991-01-08 | Blade material and manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP74091A JP2932700B2 (en) | 1991-01-08 | 1991-01-08 | Blade material and manufacturing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04250995A JPH04250995A (en) | 1992-09-07 |
| JP2932700B2 true JP2932700B2 (en) | 1999-08-09 |
Family
ID=11482114
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP74091A Expired - Fee Related JP2932700B2 (en) | 1991-01-08 | 1991-01-08 | Blade material and manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2932700B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150056467A1 (en) * | 2012-04-02 | 2015-02-26 | Office National D'etudes Et De Recherches Aérospatiales | Method for Producing a Nickel Aluminide Coating on a Metal Substrate, and Part having One Such Coating |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69610576T2 (en) * | 1995-05-19 | 2001-05-31 | Matsushita Electric Works Ltd | Electric shaver cutting unit |
| DE69602226T2 (en) * | 1995-05-19 | 1999-08-19 | Matsushita Electric Works Ltd | Iron alloy with Fe-Al diffusion layer and process for its production |
| DE10159949C1 (en) * | 2001-12-06 | 2003-05-22 | Wieland Werke Ag | Use of a copper-aluminum alloy as bearing material in the manufacture of wear resistant sliding bearings used in the car industry |
| CN103210112B (en) * | 2010-11-17 | 2015-10-21 | 新日铁住金高新材料株式会社 | Metal foil for base material |
| JP5816617B2 (en) | 2010-11-17 | 2015-11-18 | 新日鉄住金マテリアルズ株式会社 | Metal foil for substrate and manufacturing method thereof |
-
1991
- 1991-01-08 JP JP74091A patent/JP2932700B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150056467A1 (en) * | 2012-04-02 | 2015-02-26 | Office National D'etudes Et De Recherches Aérospatiales | Method for Producing a Nickel Aluminide Coating on a Metal Substrate, and Part having One Such Coating |
| US10549378B2 (en) * | 2012-04-02 | 2020-02-04 | Office National D'etudes Et De Recherches Aérospatiales | Method for producing a nickel aluminide coating on a metal substrate, and part having one such coating |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04250995A (en) | 1992-09-07 |
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