JP2739911B2 - Lubricants for high temperature metal processing such as metal casting and molten metal pouring - Google Patents
Lubricants for high temperature metal processing such as metal casting and molten metal pouringInfo
- Publication number
- JP2739911B2 JP2739911B2 JP1258241A JP25824189A JP2739911B2 JP 2739911 B2 JP2739911 B2 JP 2739911B2 JP 1258241 A JP1258241 A JP 1258241A JP 25824189 A JP25824189 A JP 25824189A JP 2739911 B2 JP2739911 B2 JP 2739911B2
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- JP
- Japan
- Prior art keywords
- oil
- metal
- casting
- pouring
- mold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Continuous Casting (AREA)
- Lubricants (AREA)
Description
【発明の詳細な説明】 産業上の利用分野： 本発明は、酸化防止機能を備えた金属の鋳造、溶融金
属の注湯等の高温金属処理用潤滑剤に関する。Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a lubricant for high-temperature metal treatment such as casting of a metal having anti-oxidation function and pouring of molten metal.
発明が解決しようとする課題： 従来の金属の精密鋳造法、ダイカスト法、熱間鋳造
法、鋳物軽合金鋳造法、押出し法、造塊法、連続鋳造法
において、潤滑物質として各種パウダー黒鉛、植物油、
鉱物油、シリコーン油等が単独又は、混合物として使用
されているが、高温金属表面の酸化を完全に避けること
ができない。金属表面の酸化が起ると、金属表面に肌、
疵等が生ずる。従来においてこのような金属表面の酸化
を防止するためにアルゴン窒素等の不活性ガスを高温金
属表面に吹きつけることを行なつて来た。しかし不活性
ガスを吹きつけたのでは溶融金属自体が冷却される欠点
があり、又不活性ガスそのものが高価であるという欠点
があつた。Problems to be Solved by the Invention: In conventional precision casting method, die casting method, hot casting method, casting light alloy casting method, extrusion method, ingot casting method, continuous casting method of various metals, various powder graphites, vegetable oils as lubricating substances. ,
Mineral oil, silicone oil and the like are used alone or as a mixture, but oxidation of the hot metal surface cannot be completely avoided. When oxidation of the metal surface occurs, skin,
Scratches and the like occur. Conventionally, in order to prevent such oxidation of the metal surface, an inert gas such as argon nitrogen has been blown onto the high-temperature metal surface. However, blowing the inert gas has a disadvantage that the molten metal itself is cooled, and that the inert gas itself is expensive.
課題を解決するための手段： 本発明は従来潤滑剤として使用されていた菜種油、大
豆油等の植物油及び流動パラフイン油、ミネラル油等の
鉱物油からなる群から選ばれた少なくとも１種の油にテ
トラフルオルエチレン樹脂（以下PTFEという）又はPTFE
と窒化ホウ素（以下NBという）を総重量に対して１〜20
重量％添加することによつて得られた潤滑剤は潤滑機能
と共に金属の酸化防止機能を備えていることを発見し、
本発明に至つた。このPTFEとNBは油中においてコロイド
状に分散されている。ステアリン酸のナトリウム、カリ
ウム又はリチウム塩等が完全のための潤滑助剤として使
用しても良い。Means for Solving the Problems: The present invention relates to at least one oil selected from the group consisting of vegetable oils such as rapeseed oil and soybean oil and mineral oils such as liquid paraffin oil and mineral oil which have been conventionally used as lubricants. Tetrafluoroethylene resin (hereinafter referred to as PTFE) or PTFE
And boron nitride (hereinafter referred to as NB) in an amount of 1 to 20 with respect to the total weight.
It was discovered that the lubricant obtained by adding wt% has a function of preventing metal oxidation as well as a function of lubrication.
The present invention has been reached. The PTFE and NB are colloidally dispersed in the oil. Sodium, potassium or lithium salts of stearic acid may be used as a lubricating aid for completeness.
NBは耐熱、高温潤滑性、高温、溶鋼表面との潤滑、離
型性に勝れている、PTFEは耐熱、潤滑、離型性に勝れ高
温、溶鋼表面と接触して瓦斯化して生成する四弗化炭素
（CF4）の強力なイオン還元反応によつてスカムの発生
を防止、凝固シエル形成時に起る一次表面酸化防止する
と共にモールド、フード内を非酸化性雰囲気を保つて高
温、溶湯界面鋳片の表面酸化を積極的に防止する。即ち
この冶金的メカニズムを上記潤滑ベイスオイルに復合さ
せることにより通常のオイラー機構によつてモールド、
キヤスターに潤滑給油を連続的に供給することにより高
温活性潤滑剤が達成され高品位の精密鋳片がマスプロダ
クトが出来る。その効果は顕著で他の追随を許さない。
尚一般的熱分解は吸熱反応で（窒素シール）あるのに対
し本高温活性潤滑剤は（PTFE）発熱反応（11,000cal/
g）で保温効果がありストリームのスタグネイト（淀
み）及びに不連続等の温度低下について起る鋳造障害を
カバーすることが出来る。安全性について本高温活性潤
滑剤はPTFEコンテンドが最大10wt％以下で油の油煙（オ
イルミスト）に微量のHFは吸着拡散される為自然換気で
充分である。NB is superior in heat resistance, high temperature lubrication, high temperature, lubrication with molten steel surface, excellent in releasability, PTFE is superior in heat resistance, lubrication, high releasability, high temperature, is produced by gasification in contact with molten steel surface Prevents the generation of scum due to the strong ion reduction reaction of carbon tetrafluoride (CF 4 ), prevents the primary surface oxidation that occurs during the formation of solidified shells, and maintains the non-oxidizing atmosphere in the mold and hood, so that high temperature and molten metal Actively prevents surface oxidation of interface slabs. That is, by combining this metallurgical mechanism with the lubricating base oil, a mold is formed by a normal Euler mechanism,
By continuously supplying lubricating lubricating oil to the caster, a high-temperature active lubricant is achieved, and high-quality precision cast slabs can be mass-produced. The effect is remarkable and unrivaled.
The general thermal decomposition is an endothermic reaction (nitrogen sealing), whereas the high-temperature active lubricant (PTFE) has an exothermic reaction (11,000cal /
g) has a heat retaining effect, and can cover casting obstacles caused by temperature drop such as stagnate of the stream and discontinuity. Safety As for this high temperature active lubricant, natural ventilation is sufficient because the PTFE content is less than 10wt% at maximum and a small amount of HF is adsorbed and diffused into oil fume (oil mist).
本発明の潤滑剤は、鉄、鉄合金、ステンレス鋼、アル
ミニウム、アルミニウム合金、銅等の鋳造等のあらゆる
高温金属加工用潤滑剤として使用できる。特に鉄の鋳造
等においてはPTFEのみでは潤滑作用を果さない場合があ
る。この場合NBを添加する。NBを添加した潤滑油を使用
すると、金属の離型性が良くなるので、あらゆる金属の
鋳造等の加工に潤滑剤の成分の１種としてNBを使用でき
る。The lubricant of the present invention can be used as a lubricant for high-temperature metal working such as casting of iron, iron alloy, stainless steel, aluminum, aluminum alloy, copper and the like. Particularly, in iron casting and the like, lubrication may not be achieved by PTFE alone. In this case, NB is added. The use of a lubricating oil to which NB is added improves the releasability of the metal, so that NB can be used as one of the components of the lubricant in processing such as casting of any metal.
組成例１ 基 油 菜種油 90wt％ 添加剤 PTFEパウダー 4 〃 添加剤 NB パウダー 2 〃 ステアリン酸リチウム 1 〃 有機アマイド 3wt％（分散剤） 組成例２ 基 油 菜種油 83wt％ 添加剤 PTFEパウダー 8 〃 添加剤 NB パウダー 3 〃 ステアリン酸リチウム 1 〃 有機アマイド 5 〃 組成例３ 基 油 流動パラフイン 90wt％ 添加剤 PTFEパウダー 4 〃 添加剤 NB パウダー 2 〃 ステアリン酸リチウム 1 〃 有機アマイド 3wt％ 組成例４ 基 油 流動パラフイン 83wt％ 添加剤 PTFEパウダー 8 〃 添加剤 NB パウダー 3 〃 ステアリン酸リチウム 1 〃 有機アマイド 5 〃 組成例５ 基 油 菜種油 43wt％ 基 油 流動パラフイン 43 〃 添加剤 PTFEパウダー 6 〃 添加剤 NB パウダー 3 〃 ステアリン酸リチウム 1 〃 有機アマイド 4 〃 組成例６ 基 油 菜種油 92wt％ 添加剤 PTFEパウダー 4 〃 ステアリン酸リチウム 1 〃 有機アマイド 3 〃 組成例７ 基 油 流動パラフイン 88wt％ 添加剤 PTFEパウダー 8 〃 ステアリン酸リチウム 1 〃 有機アマイド 3 〃 組成例８ 基 油 菜種油 45wt％ 基 油 流動パラフイン 45 〃 添加剤 PTFEパウダー 6 〃 ステアリン酸リチウム 1 〃 有機アマイド 3 〃 実施例１ 連続鋳造法により銅板張り角モールド上部四方より従
来は、精製菜種油、植物系、鉱物系、単体、複合で潤滑
供給リング内供給して鋼片スラブ表面が潤滑離型、酸化
複合によつて肌荒れ皮下ブローホール、あばた特にコー
ナーの酸化露出によりブルムやスラブの端部しわ起因な
つていた、鋼片全面酸化によつて歩留まり悪く又モール
ド銅板張りについて潤滑、離型良くないため寿命回転率
が悪くなつている。本発明は寄り良い潤滑、離型、無酸
化剤、組成例１、２、６、８従来と同一条件により潤滑
供給リング内に供給して出て来た鋼片スラブ表面観察結
果肌荒れがなく滑らかで無酸化状態であつた。特に問題
でやすい、コーナー部分は滑らかで金属光沢を保つてい
た。特に例２全面的良好であつた。歩留まりについては
全体同一であり約３％向上した。Composition Example 1 Base oil Rapeseed oil 90 wt% Additive PTFE powder 4 添加 Additive NB powder 2 リ チ ウ ム Lithium stearate 1 〃 Organic amide 3 wt% (dispersant) Composition example 2 Base oil Rapeseed oil 83 wt% Additive PTFE powder 8 添加 Additive NB Powder 3 リ チ ウ ム Lithium stearate 1 〃 Organic amide 5 〃 Composition example 3 Base oil Liquid paraffin 90 wt% Additive PTFE powder 4 〃 Additive NB powder 2 リ チ ウ ム Lithium stearate 1 〃 Organic amide 3 wt% Composition example 4 Base oil Liquid paraffin 83 wt % Additive PTFE powder 8 〃 Additive NB powder 3 リ チ ウ ム Lithium stearate 1 〃 Organic amide 5 〃 Composition example 5 Base oil Rapeseed oil 43 wt% Base oil Liquid paraffin 43 添加 Additive PTFE powder 6 〃 Additive NB powder 3 〃 Stearic acid Lithium 1 〃 Organic amide 4 組成 Composition example 6 Base oil Rapeseed oil 92wt% Additive PTFE powder 4 〃 Stearic acid Titanium 1 〃 Organic amide 3 〃 Composition example 7 Base oil Liquid paraffin 88 wt% additive PTFE powder 8 リ チ ウ ム Lithium stearate 1 〃 Organic amide 3 〃 Composition example 8 Base oil Rapeseed oil 45 wt% Base oil Liquid paraffin 45 〃 Additive PTFE powder 6リ チ ウ ム Lithium stearate 1 〃 Organic amide 3 実 施 Example 1 Steel slab slabs supplied by lubricating rapeseed oil, vegetable, mineral, simple, composite, and lubricating supply ring from the upper four sides of the square mold with continuous casting by continuous casting method The surface is lubricated. The surface is roughened due to oxidized composite.The surface is blown by subcutaneous blowholes. In addition, the life rotation rate is deteriorated because the mold release is not good. The present invention provides better lubrication, mold release, non-oxidizing agent, composition examples 1, 2, 6, and 8 under the same conditions as in the prior art. In a non-oxidized state. Particularly troublesome, the corners were smooth and had a metallic luster. In particular, Example 2 was entirely good. The yield was the same overall and improved about 3%.
実用例２ アルミ、アルミ合金ダイカスト法金型に自動注湯従来
の潤滑、離型剤として油溶性、黒鉛、水溶性黒鉛、油溶
性シリコン油、水溶性シリコン油、ベース油に鉱物油に
黒鉛を添加したものであり金型に連続的スプレー塗布し
いるため型内に残留炭素物が不着蓄積により精度も悪く
なりよつて早めに金型脱脂洗浄アルミ表面酸化されその
上面に残留分不着により脱脂洗浄酸化皮膜表面処理を起
なければならない手数かり且つ作業環境については黒鉛
粉残留炭素粉に黒鉛が飛び環境が悪くなる。酸化防止に
ならないため歩留まり悪い。本発明は寄り良い潤滑、離
型、無酸化剤組成例３、４、７従来と同一条件により金
型に自動スプレー塗布し自動注湯、冷却後のアルミ、金
型表面の状態観察した結果いずれの場合においても金属
表面は肌荒れがなく滑らかでアルミ金属光沢で無酸化で
あり残留物の不着もなくそのため洗浄が省略出来そのた
めに連続使用可能となる無酸化であるため歩留まり向上
きよする。作業環境については黒粉が出ないため良い環
境改善に寄与する。Practical example 2 Automatic pouring into aluminum and aluminum alloy die-casting molds Conventional lubrication, oil-soluble, graphite, water-soluble graphite, oil-soluble silicon oil, water-soluble silicon oil, water-soluble silicon oil as base oil, mineral oil as base oil, graphite Since it is added and the spray is continuously applied to the mold, the residual carbon material adheres and accumulates in the mold, causing the accuracy to deteriorate. As a result, the aluminum surface of the mold is degreased and washed quickly. As for the trouble and work environment in which the oxide film surface treatment must be performed, graphite scatters on the graphite powder residual carbon powder, and the environment deteriorates. Yield is poor because it does not prevent oxidation. The present invention provides better lubrication, mold release, and non-oxidant composition examples 3, 4 and 7. Automatic spray application to the mold under the same conditions as in the past, automatic pouring, cooling after cooling, and observation of the state of the mold surface. Even in the case of (1), the metal surface is smooth without any roughening, is aluminum metal luster and is non-oxidizing, and there is no non-adherence of the residue. Therefore, the cleaning can be omitted and the non-oxidizing method can be used continuously, thereby improving the yield. The work environment contributes to good environmental improvement because no black powder is produced.
実用例３ 金型鋳造法に従来は金型、潤滑、離型剤として油溶性
黒鉛、シリコーン油使用されていましたが黒鉛の場合悪
くなる作業環境、残留炭素分が金型内表面不着鋳造物表
面不着するため定期的に金型表面洗浄を行なわなければ
ならない、鋳造物面の酸化、残留物のその後塗装するも
のもあり洗浄必要とする、同様にシリコーン油について
も同じである。本発明は組成例３、４、７、８を金型に
自動スプレー塗布し自動注湯、冷却後の鋳造物金型内表
面の酸化、残留物について状態観察した結果実施例３、
４、７、８いずれの場合においても表面肌は酸化なく滑
らかで金属光沢をしていた。残留物については４、７は
肉眼ではわからなかつた。組成物８については少量の残
留物が見られたが自働には差し支えない程度あつた。潤
滑、離型は良好で無酸化によつて歩留まり向上する。残
留物の不着がないため鋳造金型の洗浄工程が省略出来又
全面無手入となりコスト低減に寄与する。Practical example 3 Conventionally, oil-soluble graphite and silicone oil were used as molds, lubrication, and mold release agents in the mold casting method. The surface of the mold must be periodically cleaned to prevent surface adhesion. Oxidation of the casting surface and subsequent coating of the residue may require cleaning. The same applies to silicone oil. According to the present invention, composition examples 3, 4, 7, and 8 were automatically applied by spraying to a mold, automatically poured, and the state of oxidation of the inner surface of the casting mold after cooling and the residue were observed.
In all cases of 4, 7, and 8, the surface skin was smooth without oxidation and had a metallic luster. For residues, 4 and 7 were not noticeable to the naked eye. In composition 8, a small amount of residue was observed, but the degree was small enough to be sufficient for autonomy. Lubrication and mold release are good, and the yield is improved by non-oxidation. Since there is no residue adhesion, the step of cleaning the casting mold can be omitted, and the entire surface is free of maintenance, which contributes to cost reduction.
実用例４ スエデン製横型ニヤネツトシエイプ法（引抜法）従来
は銅、銅合金、黄銅自動注湯ら丸型黒鉛モールド内界面
に潤滑、離型剤を使用していないためモールド引抜かれ
た場合にモールド界面磨耗激しく、銅表面酸化している
ため表面切削加工していた、本発明は潤滑、離型、酸化
防止として組成例１、２、６を上、下２ケ所からスプレ
ー注入して引抜て出て来たものを銅表面の状態観察した
結果、銅メタル状の滑らかで金属光沢を保つていた。酸
化しないため歩留まりがいちぢるしく向上した。黒鉛モ
ールドは高価なもので磨耗減により寿命回転率が良くな
りコント低減に寄与する。Practical example 4 Swedish horizontal shear shaping method (pulling method) Conventionally, copper, copper alloy, brass automatic pouring, etc., when lubrication and mold release agent are not used at the interface inside the round graphite mold, when the mold is pulled out The surface of the mold was abraded due to severe mold interface wear and the copper surface was oxidized. The present invention sprays composition examples 1, 2, and 6 from upper and lower two places for lubrication, mold release, and oxidation prevention. As a result of observing the state of the copper surface, it was found that the copper metal was smooth and had a metallic luster. Yield has improved significantly since it is not oxidized. Graphite molds are expensive and contribute to a reduction in control because the life rotation rate is improved due to reduced wear.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ Ｃ１０Ｍ 147:02 125:26） Ｃ１０Ｎ 30:10 40:20 40:36 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification code FI C10M 147: 02 125: 26) C10N 30:10 40:20 40:36
Claims (2)
イン油、ミネラル油等の鉱物油からなる群から選ばれた
少なくとも１種類の油および総重量に基づいてテトラフ
ルオルエチレン樹脂１〜20重量％を含み、テトラフルオ
ルエチレン樹脂が油中にコロイド状で分散している、酸
化防止機能を備えた金属の鋳造、溶融金属の注湯等の高
温金属処理用潤滑剤。(1) at least one oil selected from the group consisting of vegetable oils such as rapeseed oil and soybean oil and mineral oils such as liquid paraffin oil and mineral oil; % In which a tetrafluoroethylene resin is dispersed in oil in a colloidal form, and which is used for high-temperature metal treatment such as casting of a metal having antioxidant function and pouring of molten metal.
イン油、ミネラル油等の鉱物油からなる群から選ばれた
少なくとも１種類の油、テトラフルオルエチレン樹脂お
よび窒化ホウ素を含み、テトラフルオルエチレン樹脂と
窒化ホウ素の合計重量は総重量に基づいて１〜20重量％
であり、テトラフルオルエチレン樹脂および窒化ホウ素
が油中にコロイド状で分散している、酸化防止機能を備
えた金属の鋳造、溶融金属の注湯等の高温金属処理用潤
滑剤。2. An oil containing at least one oil selected from the group consisting of vegetable oils such as rapeseed oil and soybean oil and mineral oils such as liquid paraffin oil and mineral oil, tetrafluoroethylene resin and boron nitride, The total weight of ethylene resin and boron nitride is 1 to 20% by weight based on the total weight
A lubricant for high-temperature metal treatment, such as casting of a metal having an antioxidant function and pouring of molten metal, in which a tetrafluoroethylene resin and boron nitride are dispersed in oil in a colloidal state.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1258241A JP2739911B2 (en) | 1989-10-03 | 1989-10-03 | Lubricants for high temperature metal processing such as metal casting and molten metal pouring |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1258241A JP2739911B2 (en) | 1989-10-03 | 1989-10-03 | Lubricants for high temperature metal processing such as metal casting and molten metal pouring |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03121197A JPH03121197A (en) | 1991-05-23 |
| JP2739911B2 true JP2739911B2 (en) | 1998-04-15 |
Family
ID=17317490
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1258241A Expired - Fee Related JP2739911B2 (en) | 1989-10-03 | 1989-10-03 | Lubricants for high temperature metal processing such as metal casting and molten metal pouring |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2739911B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012108994A2 (en) * | 2011-02-07 | 2012-08-16 | Sergachev Technologies Llc | Metal treatment composition and method of treating rubbing surfaces |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20080014789A (en) * | 2005-04-26 | 2008-02-14 | 리뉴어블 루브리컨츠 인코포레이션 | High temperature biobased lubricant compositions comprising boron nitride |
| WO2006116502A1 (en) * | 2005-04-26 | 2006-11-02 | Renewable Lubricants, Inc. | High temperature biobased lubricant compositions comprising boron nitride |
| JP7161539B2 (en) * | 2018-01-29 | 2022-10-26 | パーデュー・リサーチ・ファウンデーション | Lubricant composition for die casting, method of using the composition, and products manufactured using the composition |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4127491A (en) * | 1976-07-23 | 1978-11-28 | Michael Ebert | Hybrid lubricant including halocarbon oil |
| JPS5334808A (en) * | 1976-09-14 | 1978-03-31 | Showa Seisakushiyo Kk | Method of increasing lubrication in oil |
| JPS63291994A (en) * | 1987-05-23 | 1988-11-29 | Kawabata Seisakusho:Kk | Lubrication oil |
-
1989
- 1989-10-03 JP JP1258241A patent/JP2739911B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012108994A2 (en) * | 2011-02-07 | 2012-08-16 | Sergachev Technologies Llc | Metal treatment composition and method of treating rubbing surfaces |
| WO2012108994A3 (en) * | 2011-02-07 | 2012-10-11 | Sergachev Technologies Llc | Metal treatment composition and method of treating rubbing surfaces |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH03121197A (en) | 1991-05-23 |
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