JP2605484Y2 - Base cloth with metallic luster - Google Patents
Base cloth with metallic lusterInfo
- Publication number
- JP2605484Y2 JP2605484Y2 JP1993076174U JP7617493U JP2605484Y2 JP 2605484 Y2 JP2605484 Y2 JP 2605484Y2 JP 1993076174 U JP1993076174 U JP 1993076174U JP 7617493 U JP7617493 U JP 7617493U JP 2605484 Y2 JP2605484 Y2 JP 2605484Y2
- Authority
- JP
- Japan
- Prior art keywords
- metallic luster
- antibacterial
- layer
- deodorizing
- base cloth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Laminated Bodies (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本考案は、脱臭性、抗菌性及び金
属光沢を持った基布に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a base fabric having deodorizing properties, antibacterial properties and metallic luster.
【０００２】[0002]
【従来の技術】従来、金属光沢を有する基布は、風合
い、金属感等を重視したもので基布自体に脱臭性、抗菌
性をもたせるという発想は全く存在しなかった。2. Description of the Related Art Conventionally, a base cloth having a metallic luster emphasizes a feeling of texture, a metallic feeling and the like, and there is no idea that the base cloth itself has a deodorizing property and an antibacterial property.
【０００３】[0003]
【考案が解決しようとする課題】従来の金属光沢を有す
る基布は、脱臭性、抗菌性を得ることは困難であった。
本考案の目的は今までにない脱臭性及び抗菌性を備え、
かつ風合いも優れた金属光沢を有する基布を提供するこ
とにある。It is difficult to obtain a deodorant property and an antibacterial property from a conventional base cloth having a metallic luster.
The purpose of the present invention is to provide unprecedented deodorizing and antibacterial properties,
Another object of the present invention is to provide a base fabric having an excellent metallic luster.
【０００４】[0004]
【課題を解決するための手段】本考案は、基布の片面又
は両面に脱臭・抗菌剤入りの接着層、金属薄膜層、必要
に応じて保護樹脂層、及び離型層を順次設けたことを特
徴とする金属光沢を有する基布である。According to the present invention, an adhesive layer containing a deodorant / antibacterial agent, a metal thin film layer, a protective resin layer and, if necessary, a release layer are sequentially provided on one or both sides of a base fabric. The base cloth has a metallic luster characterized by the following.
【０００５】本考案を図１をもって説明する。本考案の
金属光沢を有する基布は、転写用フィルムとしてプラス
チックフィルム例えば、ポリエステルフィルムの上に
順次離型層、必要に応じて設ける保護層、金属薄膜
層、脱臭・抗菌剤入りの接着層を形成してなるもの
である。この転写用フィルムを基布に転写する。例え
ば、図２に示すように基布の上に順次脱臭・抗菌剤入
りの接着層、金属薄膜層、必要に応じて設ける保護
層、離型層を有する構造のものである。The present invention will be described with reference to FIG. The base fabric having a metallic luster of the present invention is a plastic film as a transfer film, for example, a release layer on a polyester film, a protective layer provided as necessary, a metal thin film layer, an adhesive layer containing a deodorant / antibacterial agent. It is formed. This transfer film is transferred to a base fabric. For example, as shown in FIG. 2, it has a structure in which an adhesive layer containing a deodorant / antibacterial agent, a metal thin film layer, a protective layer provided as needed, and a release layer are sequentially provided on a base cloth.
【０００６】各構成要素の材質、特性および厚さ等につ
いて説明する。離型層としては、酢酸セルロース、脂肪
酸エステル、アクリル樹脂、シリコーン、ワックス等適
宜公知の離型剤が用いられる。離型層はベースフィルム
がフラットの場合は、０．０１〜２．０μの厚さであ
り、より好ましくは０．５〜１．０μの厚さで使用され
る。必要に応じて設ける保護層の樹脂としては離型層お
よび金属薄膜層のいずれにも接着性のよい熱硬化性樹
脂、熱可塑性樹脂または紫外線硬化性樹脂がある。これ
らの樹脂は透明性のよいものが使用されるが、染料、顔
料又は艷消し剤を入れて着色してもよい。好ましい樹脂
としてはアクリル樹脂、メラミン樹脂、ウレタン樹脂、
エポキシ樹脂、アルキッド樹脂等がある。一般にその厚
さは、０．２〜５．０μ程度、好ましくは１．０〜３．
０μである。The material, characteristics, thickness and the like of each component will be described. As the release layer, a known release agent such as cellulose acetate, fatty acid ester, acrylic resin, silicone, or wax is used as appropriate. When the base film is flat, the release layer has a thickness of 0.01 to 2.0 μ, more preferably 0.5 to 1.0 μ. As the resin of the protective layer provided as required, there is a thermosetting resin, a thermoplastic resin, or an ultraviolet curable resin having good adhesiveness to both the release layer and the metal thin film layer. Although these resins have good transparency, they may be colored by adding a dye, a pigment or an anti-glazing agent. Preferred resins are acrylic resin, melamine resin, urethane resin,
There are epoxy resin, alkyd resin and the like. Generally, the thickness is about 0.2 to 5.0 μm, preferably 1.0 to 3.0 μm.
0μ.
【０００７】金属薄膜層は、金属光沢を与えるために必
要であり、公知の真空蒸着法、スパッタリング法、イオ
ンプレーティング等の金属（合金も含む）の薄膜形成方
法によって形成される。金属としてはアルミニウム、亜
鉛、錫、金、銀、ニッケル、銅、クロム、チタン、イン
ジウム等を用いることができるが、通常加工性、コス
ト、光沢等からアルミニウムが使用される。厚さは２０
０〜２０００オングストロームが通常である。２００オ
ングストローム未満だと金属光沢が得られ難くなり、２
０００オングストロームを越すと経済的に好ましくなく
実用性に欠ける。特に５００〜１０００オングストロー
ムが好ましい。The metal thin film layer is necessary to give a metallic luster, and is formed by a known metal (including alloy) thin film forming method such as vacuum deposition, sputtering, or ion plating. As the metal, aluminum, zinc, tin, gold, silver, nickel, copper, chromium, titanium, indium and the like can be used, but aluminum is usually used from the viewpoint of workability, cost, gloss and the like. Thickness 20
0-2000 Angstroms is typical. If it is less than 200 angstroms, it is difficult to obtain a metallic luster, and 2
If it exceeds 2,000 angstroms, it is economically undesirable and lacks practicality. Particularly, 500 to 1000 Å is preferable.
【０００８】接着層としては、金属薄膜層及び基布のい
ずれにも接着性のよい樹脂系接着剤が使用される。例え
ば、アクリル系、エステル系、合成ゴムポリウレタン
系、ポリアミド系、エチレン−酢酸ビニル系及びこれら
の共重合体などが一般的に使用できる。接着層には脱臭
剤・抗菌剤が混合される。複合化学脱臭剤として知られ
る公知の脱臭剤及び公知の抗菌剤を適宜使用することが
できる。脱臭機能と抗菌機能を持つ脱臭・抗菌剤も種々
市販されており、これらを用いることが好ましい。その
混合量は脱臭・抗菌作用を示す範囲の適宜の量であり、
例えば接着層中に５〜６０％程度混合される。基布とし
ても適宜公知の基布が使用される。例えばテトロン布、
ナイロン布、綿布、絹布、不織布等があり、その種類、
織り方、等には制限はない。As the adhesive layer, a resin adhesive having good adhesiveness to both the metal thin film layer and the base cloth is used. For example, acrylic type, ester type, synthetic rubber polyurethane type, polyamide type, ethylene-vinyl acetate type, and copolymers thereof can be generally used. A deodorant and an antibacterial agent are mixed in the adhesive layer. Known deodorants and known antibacterial agents known as complex chemical deodorants can be used as appropriate. Various deodorizing and antibacterial agents having a deodorizing function and an antibacterial function are commercially available, and it is preferable to use these. The mixing amount is an appropriate amount in a range showing the deodorizing / antibacterial action,
For example, about 5 to 60% is mixed in the adhesive layer. As the base cloth, a known base cloth is appropriately used. For example, Tetron cloth,
There are nylon cloth, cotton cloth, silk cloth, non-woven cloth, etc.
There are no restrictions on weaving, etc.
【０００９】[0009]
【実施例】厚さ１６μの２軸延伸ポリエチレンテレフタ
レートフィルムに離型層（酢酸セルロース樹脂厚さ０．
５μ）、保護層（メラミンニトロセルロース／油性染料
からなる厚さ１．５μ）の順に塗布し、次いで真空蒸着
により厚さ５００オングストロームのアルミニウム薄膜
を形成した。この上に接着層（ポリウレタン／コロネー
ト系接着剤に脱臭・抗菌剤ダイムシューＯ−３００（大
日精化工業株式会社）を４０％混入、厚さ１０μを塗布
する。このようにして得られた転写フィルムのコート面
をナイロントリコット（３０デニール）を合わせて、転
写機にてプレスロール（温度９０℃、圧力１００ｋｇ／
ｃｍ２，スピード１０ｍ／ｍｉｎ）でフィルム面より加
熱圧着し転写加工することで、ナイロントリコット片面
に脱臭・抗菌剤入り接着層、金属薄膜層、保護層、離型
層が転写される。１５時間程度の常温エージング後、プ
レス機にて表層のポリエステルフィルムを剥ぎ取りなが
ら常温プレス（２００ｋｇ／ｃｍ２）して布目に転写膜
を入れることで、密着性、金属光沢が安定し、風合いの
よい金属光沢を有しかつ脱臭抗菌性に優れている基布が
得られる。EXAMPLE A release layer (cellulose acetate resin having a thickness of 0.1 μm) was formed on a biaxially oriented polyethylene terephthalate film having a thickness of 16 μm.
5 μm) and a protective layer (1.5 μm in thickness composed of melamine nitrocellulose / oil-based dye) were applied in that order, and then a 500 Å-thick aluminum thin film was formed by vacuum evaporation. An adhesive layer (polyurethane / coronate adhesive, deodorant / antibacterial agent Dime shoe O-300 (Dainichi Seika Kogyo Co., Ltd.) mixed at 40% and applied with a thickness of 10 μm. Transfer film thus obtained Nylon tricot (30 denier) was applied to the coated surface of the above, and pressed by a transfer machine at a press roll (temperature 90 ° C., pressure 100 kg /
(cm 2 , speed 10 m / min) from the film surface by heat-compression bonding and transfer processing, thereby transferring the deodorizing / antibacterial agent-containing adhesive layer, metal thin film layer, protective layer, and release layer to one side of the nylon tricot. After room-temperature aging for about 15 hours, the transfer film is placed on the cloth by room-temperature pressing (200 kg / cm 2 ) while peeling off the surface polyester film with a press machine, whereby the adhesion, the metallic luster are stabilized, and the texture is improved. A base fabric having good metallic luster and excellent deodorizing and antibacterial properties is obtained.
【００１０】上記の基布について抗菌性試験及び脱臭性
能試験を行った。抗菌性試験とその結果を下記する。 供試菌株：（Ａ）グラム陰性菌：大腸菌（Ｅ．ｃｏｌｉ
ＩＡＭ １２６８） （Ｂ）グラム陰性菌：枯草菌（Ｂ．ｓｕｂｔｉｌｌｓ
ＩＡＭ １０６９） 試験方法： 前培養 ：前培養用ニュートリエントブロス液体培地、
３７℃、１６ｈｒ振とう培養。 抗菌試験：前培養は、ニュートリエントブロス液体培地
を用いて、前培養した菌液を１／２００に稀釈した後、
Ｌ字管に５ｍｌ、サンプル（１０×１０ｍｍ、２５枚）
を入れ、３７℃、２４ｈｒ振とう培養した。培養液は、
稀釈平板法により生菌数を測定し、生菌数の少ない試料
を抗菌力のあるものと判定した。 試験結果：表１に記載する。An antibacterial test and a deodorizing performance test were conducted on the above-mentioned base fabric. The antibacterial test and the results are described below. Test strain: (A) Gram-negative bacteria: E. coli
(IAM 1268) (B) Gram-negative bacteria: B. subtills
IAM 1069) Test method: Pre-culture: Nutrient broth liquid medium for pre-culture,
Shaking culture at 37 ° C for 16 hours. Antibacterial test: Pre-culture was performed by diluting the pre-cultured bacterial solution to 1/200 using a nutrient broth liquid medium.
5 ml sample in L-shaped tube (10 × 10 mm, 25 sheets)
And cultured with shaking at 37 ° C. for 24 hours. The culture solution is
The number of viable cells was measured by the dilution plate method, and a sample having a small number of viable cells was determined to have antibacterial activity. Test results: described in Table 1.
【００１１】[0011]
【表１】 [Table 1]
【００１２】上記の試験結果より、本考案品の抗菌性
は、コントロール（脱臭・抗菌剤なし）と比較して、大
腸菌、枯草菌について、菌の増殖を抑制していると判定
される。From the above test results, it can be determined that the antibacterial property of the product of the present invention suppresses the growth of Escherichia coli and Bacillus subtilis as compared with the control (without deodorant and antibacterial agent).
【００１３】脱臭性能測定試験とその結果を下記する。 試験方法： （Ａ）アンモニア ３００ｍｌ容三角フラスコに、２８％アンモニア水溶液
を１０μｌを入れ、完全にガス化させ、サンプル５０×
２００ｍｍ、１枚投入、２５℃に保存し、所定の時間経
過後、北川式ガス検知器を用いて、フラスコ内のアンモ
ニア残存濃度を測定した。 （Ｂ）トリメチルアミン ３００ｍｌ容三角フラスコに、０．５％トリメチルアミ
ン水溶液を４μｌを入れ、完全にガス化させ、サンプル
５０×２００ｍｍ、１枚投入、２５℃に保存し、所定の
時間経過後、北川式ガス検知器を用いて、フラスコ内の
トリメチルアミン残存濃度を測定した。 （Ｃ）硫化水素 ３００ｍｌ容三角フラスコに、８００ｐｐｍ硫化ナトリ
ウム水溶液を１ｍｌおよび１規定硫酸０．１ｍｌを入
れ、硫化水素を生成させ、サンプル５０×２００ｍｍ、
１枚投入、２５℃に保存し、所定の時間経過後、北川式
ガス検知器を用いて、フラスコ内の硫化水素残存濃度を
測定した。試験結果：表２に記載する。The deodorizing performance measurement test and the results are described below. Test Method: (A) Ammonia A 300 ml Erlenmeyer flask was charged with 10 μl of a 28% aqueous ammonia solution, and completely gasified.
One 200 mm sheet was charged and stored at 25 ° C., and after a predetermined time had elapsed, the residual ammonia concentration in the flask was measured using a Kitagawa gas detector. (B) Trimethylamine In a 300 ml Erlenmeyer flask having a capacity of 300 ml, 4 μl of a 0.5% aqueous solution of trimethylamine was put, completely gasified, a sample of 50 × 200 mm, one sheet was placed, and stored at 25 ° C. The residual concentration of trimethylamine in the flask was measured using a gas detector. (C) Hydrogen sulfide In a 300 ml Erlenmeyer flask, 1 ml of an 800 ppm aqueous solution of sodium sulfide and 0.1 ml of 1 N sulfuric acid were added to generate hydrogen sulfide.
One sheet was charged, stored at 25 ° C., and after a predetermined time, the residual hydrogen sulfide concentration in the flask was measured using a Kitagawa gas detector. Test results: described in Table 2.
【００１４】[0014]
【表２】 [Table 2]
【００１５】上記の試験結果より、本考案品の脱臭性は
コントロール（脱臭・抗菌剤なし）と比較して、アンモ
ニア、トリメチルアミン、硫化水素の脱臭性に優れてい
ると判定される。From the above test results, it is determined that the product of the present invention has superior deodorizing properties for ammonia, trimethylamine and hydrogen sulfide as compared with the control (without deodorizing and antibacterial agent).
【００１６】[0016]
【考案の効果】本考案は、基布の片面又は両面に脱臭・
抗菌剤入り接着層、金属薄膜層、必要に応じ保護樹脂
層、離型層を転写した基布であって良好な金属光沢、風
合いと脱臭・抗菌性を有した基布を得ることができた。
表１及び表２に示した通り今までになかった脱臭・抗菌
効果を得られた。本考案によって得られた金属光沢およ
び脱臭・抗菌効果のある基布は衣類、人形ドレス、小物
入れ、バック、カーテン等に有効に使用される。[Effect of the invention] The present invention is based on deodorizing one or both sides of the base fabric.
An adhesive layer containing an antimicrobial agent, a metal thin film layer, a protective resin layer, and a base cloth to which a release layer was transferred as required, and a base cloth having good metallic luster, texture, deodorization and antibacterial properties could be obtained. .
As shown in Tables 1 and 2, unprecedented deodorizing and antibacterial effects were obtained. The base fabric having the metallic luster and deodorizing / antibacterial effect obtained by the present invention can be effectively used for clothes, doll dresses, accessory cases, bags, curtains and the like.
【図１】本考案の実施例を示す脱臭・抗菌性を有する金
属光沢を持った基布転写用フィルムの一部拡大断面図で
ある。FIG. 1 is a partially enlarged cross-sectional view of a base fabric transfer film having a metallic luster having deodorizing and antibacterial properties, showing an embodiment of the present invention.
【図２】本考案の脱臭性、抗菌性を有する金属光沢を持
った基布の一部拡大断面図がある。FIG. 2 is a partially enlarged cross-sectional view of a base fabric having a metallic luster having deodorizing and antibacterial properties according to the present invention.
【符号の説明】 ベースフィルム 離型層 保護（着色）層 金属薄膜層 脱臭抗菌剤入り接着層 基布[Explanation of symbols] Base film Release layer Protective (colored) layer Metal thin film layer Adhesive layer containing deodorant antibacterial agent Base fabric
フロントページの続き (58)調査した分野(Int.Cl.7，ＤＢ名) B32B 15/14 B32B 15/08 B32B 27/18 D06M 11/83 Continuation of the front page (58) Field surveyed (Int. Cl. 7 , DB name) B32B 15/14 B32B 15/08 B32B 27/18 D06M 11/83
Claims (1)
応じて保護層、及び離型層を順次設け、接着層に脱臭剤
及び抗菌剤を混合したことを特徴とする金属光沢を有す
る基布。1. A metallic luster characterized in that an adhesive layer, a metal deposition layer, a protective layer, and a release layer are provided sequentially on a base cloth, and a deodorant and an antibacterial agent are mixed in the adhesive layer. Base fabric having
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1993076174U JP2605484Y2 (en) | 1993-12-22 | 1993-12-22 | Base cloth with metallic luster |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1993076174U JP2605484Y2 (en) | 1993-12-22 | 1993-12-22 | Base cloth with metallic luster |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0737634U JPH0737634U (en) | 1995-07-11 |
| JP2605484Y2 true JP2605484Y2 (en) | 2000-07-17 |
Family
ID=13597740
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1993076174U Expired - Fee Related JP2605484Y2 (en) | 1993-12-22 | 1993-12-22 | Base cloth with metallic luster |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2605484Y2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5285993B2 (en) * | 2008-08-05 | 2013-09-11 | 東洋紡スペシャルティズトレーディング株式会社 | Woven knitted fabric for winter clothing |
| US10160184B2 (en) * | 2013-06-03 | 2018-12-25 | Xefco Pty Ltd | Insulated radiant barriers in apparel |
-
1993
- 1993-12-22 JP JP1993076174U patent/JP2605484Y2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0737634U (en) | 1995-07-11 |
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