JP2547373C - - Google Patents
Info
- Publication number
- JP2547373C JP2547373C JP2547373C JP 2547373 C JP2547373 C JP 2547373C JP 2547373 C JP2547373 C JP 2547373C
- Authority
- JP
- Japan
- Prior art keywords
- abrasive
- polishing
- oil
- parts
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005296 abrasive Methods 0.000 claims description 41
- 239000003082 abrasive agent Substances 0.000 claims description 29
- 238000005237 degreasing agent Methods 0.000 claims description 24
- 239000004094 surface-active agent Substances 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 4
- 229910001651 emery Inorganic materials 0.000 claims description 4
- 229910000460 iron oxide Inorganic materials 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- WGLPBDUCMAPZCE-UHFFFAOYSA-N trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims description 2
- 238000005498 polishing Methods 0.000 description 36
- 239000003921 oil Substances 0.000 description 24
- 235000019198 oils Nutrition 0.000 description 24
- 239000000203 mixture Substances 0.000 description 19
- 239000003925 fat Substances 0.000 description 17
- 235000019197 fats Nutrition 0.000 description 17
- -1 sodium alkyl sulfate Chemical class 0.000 description 16
- 238000004140 cleaning Methods 0.000 description 14
- 239000000835 fiber Substances 0.000 description 14
- 238000002156 mixing Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N Stearic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 239000012188 paraffin wax Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- 238000004506 ultrasonic cleaning Methods 0.000 description 4
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-Trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 3
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 239000006061 abrasive grain Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000010951 brass Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- GHNRTXCRBJQVGN-UHFFFAOYSA-N 4-dodecan-6-ylbenzenesulfonic acid Chemical compound CCCCCCC(CCCCC)C1=CC=C(S(O)(=O)=O)C=C1 GHNRTXCRBJQVGN-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N Behenic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N Lauric acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M NaHCO3 Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N Oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N Palmitic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N Resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive Effects 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N edta Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 description 2
- 239000000271 synthetic detergent Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-L 2-sulfobutanedioate Chemical compound OS(=O)(=O)C(C([O-])=O)CC([O-])=O ULUAUXLGCMPNKK-UHFFFAOYSA-L 0.000 description 1
- 229920000180 Alkyd Polymers 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 240000000218 Cannabis sativa Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 240000008528 Hevea brasiliensis Species 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229940039717 Lanolin Drugs 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N Oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- IYJYQHRNMMNLRH-UHFFFAOYSA-N Sodium aluminate Chemical compound [Na+].O=[Al-]=O IYJYQHRNMMNLRH-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- CZMRCDWAGMRECN-GDQSFJPYSA-N Sucrose Natural products O([C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](CO)O1)[C@@]1(CO)[C@H](O)[C@@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-GDQSFJPYSA-N 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 210000002268 Wool Anatomy 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 125000004432 carbon atoms Chemical group C* 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- XGZRAKBCYZIBKP-UHFFFAOYSA-L disodium;dihydroxide Chemical compound [OH-].[OH-].[Na+].[Na+] XGZRAKBCYZIBKP-UHFFFAOYSA-L 0.000 description 1
- 229950008690 docosanoic acid Drugs 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000002349 favourable Effects 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000007849 furan resin Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 235000012765 hemp Nutrition 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 235000012766 marijuana Nutrition 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 239000005445 natural product Substances 0.000 description 1
- 229930014626 natural products Natural products 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 235000021118 plant-derived protein Nutrition 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000011528 polyamide (building material) Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000012256 powdered iron Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000001187 sodium carbonate Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 210000001519 tissues Anatomy 0.000 description 1
- 229960002415 trichloroethylene Drugs 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N triclene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Description
【発明の詳細な説明】
【０００１】
【産業上の利用分野】
本発明は界面活性剤および脱脂剤を含む油脂性バフ研磨材に関する。より詳し
くは本発明は、研磨後の洗浄を迅速かつ容易に行い得る油脂性バフ研磨材に関す
る。
【０００２】
【従来の技術】
メッキや塗装の下地研磨、ステンレス表面研磨、スケール除去、バリ取り、面
取り、研掃作業、梨地仕上げ、目付等は研磨材による機械的研磨により一般に行
われている。
機械的研磨には、ａ）バレル研磨、ｂ）バフ研磨に代表される回転工具による
研磨、ｃ）粉体を噴射する乾式噴射、ｄ）水と混合した研磨材を噴射する湿式研
磨、ｅ）アブレッシブベルト研磨、ｆ）水や油等の高圧媒体による研磨、ｇ）研
磨材を含む粘性流体の加圧による研磨等がある。
鉄、ステンレス、銅、真鍮、亜鉛やアルミニウム等からなる各種金属物品のメ
ッキ等の表面加工前にはバフ研磨が一般的に行われている。バフ研磨の研磨材と
しては微粉末状の研磨性材料を油脂に混ぜ、固形化し、棒状とした油性バフ研磨
材が多用され、これは該棒状研磨材をバフに押しつけることにより発生する摩擦
熱で油脂が溶解し、バフ面に研磨材が塗布され、研磨可能な状態となるものであ
る。また、目的によっては、水溶性接着剤に研磨性材料を加えて練り合わせて成
形した非油性バフ研磨材が用いられることもある。
しかしながら、これら従来の研磨材では、研磨処理後、研磨物品に付着残留す
る研磨材を除去するために、加温したトリクロロエチレン（トリクレン）、トリ
クロロエタンまたはエチレンクロライド、または塩酸中での超音波洗浄が必要で
あり、そのためのドラフト等の処理設備が必要であるばかりでなく、上記塩素系
の洗浄溶液はいずれも危険なものであり取扱いの際、注意が必要で、しかも作業
環境を悪化させるものであった。中でも、トリクレンのように地方自治体によっ
ては使用が禁止されている洗浄液もある。
また、複雑な形状の物品、凹凸の激しい物品、細かい孔を多数有する物品等の
場合、それらの入り組んだ部分や孔に入り込んだ研磨材は上記のような洗浄液中
での長時間の超音波洗浄によっても、容易には取り除くことができず、最終的に
は手作業により行わなければならず、作業効率は著しく低いものだった。
【０００３】
【発明が解決しようとする課題】
以上のような状況であるので、塩素系の溶液を用いる研磨処理後の物品の洗浄
に代わる系が当業界では強く要望されていた。そこで、本発明は上記問題点を解
決するためになされたものであり、バフ研磨に使用され、研磨後の洗浄をトリク
レン等を用いずに迅速かつ容易に行い得る研磨材の提供を課題とする。
【０００４】
【課題を解決するための手段】
すなわち、本発明の油脂性バフ研磨材は、ケイ石、焼成アルミナ、溶融アルミ
ナ、酸化鉄、酸化クロムおよびエメリーからなる群から選択される少なくとも１
種と油脂分とからなる研磨性材料１００重量部に対して界面活性剤および脱脂剤
を０．１ないし１０重量部含むことを特徴とする。
本発明はまた、研磨性材料１００重量部に対して繊維性成分０．１ないし５０
０重量部をさらに含む上記油脂性バフ研磨材に関する。
【０００５】
本発明において使用される研磨性材料とは、油脂分と、研削作用を有する硬質
物質および加工面の仕上げや艶出し等の琢磨作用を有する硬質物質であり、一般
に研削材、琢磨材と呼ばれる砥粒分とからなるものを意味する。ここで砥粒分は
ケイ石（ケイ酸コロイド，ＳｉＯ2）、焼成アルミナ（Ａｌ2Ｏ3）、溶融アルミ
ナ（Ａｌ2Ｏ3）、酸化鉄（Ｆｅ2Ｏ3）、酸化クロム（Ｃｒ2Ｏ3）およびエメリー
（コランダム，砂石）の少なくとも１種である。この砥粒分の種類や粒径・粒度
等は被研磨物や使用されるバフ等に応じて適宜選択されるものである。また、上
記砥粒分は１種のみ、または２種以上を組み合わせて用いることができる。
【０００６】
一方、研磨性材料の油脂分は、油脂、油剤およびパラフィン等である。
使用され得る油脂は、天然の動植物界に広く存在する主として脂肪酸とトリグ
リセリンとのモノ−ないしトリ−エステルであり、天然物だけでなく、合成のも
のであってよく、植物油例えば大豆油、ヤシ油、アマニ油、綿実油、ナタネ油、
キリ油、ヒマシ油、松脂またはトール油等、動物油例えば牛脂、ラノリン、鯨油
等を例示できる。
また、油剤は上記油脂を加工して得られるものであり、例えば油脂に水素添加
した硬化油、油脂の加水分解により得られる脂肪酸およびグリセリン、およびそ
の他の多価アルコール等である。脂肪酸の代表例には、例えばラウリル酸、ミリ
スチル酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘニン酸等がある。
さらに、パラフィンとして炭素数１０ないし４０程度の直鎖または分岐鎖飽和
炭化水素、例えばパラフィンワックス等を例示できる。
【０００７】
本発明において使用される界面活性剤は、特に制限されず、陰イオン活性剤、
陽イオン活性剤、非イオン活性剤および両性イオン活性剤のいずれであっても、
それらの混合物であってもよい。それぞれの典型例として、陰イオン活性剤には
、セッケン、アルキル硫酸エステルナトリウム、オレフィン硫酸エステルナトリ
ウム、アルキルベンゼンスルホン酸ナトリウム、アルキルナフタリンスルホン酸
ナトリウム、オレイン酸アミドスルホン酸ナトリウム、ジアルキルスルホコハク
酸ナトリウム等があり、陽イオン活性剤にはハロゲン化トリメチルアミノエチル
アルキルアミド、アルキルピリジニウム硫酸塩、ハロゲン化アルキルトリメチル
アンモニウム等があり、非イオン活性剤にはポリオキシエチレンアルキルエーテ
ル、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレンアルキルフェニル
エーテル、多価アルコール脂肪酸エステル、ポリオキシエチレン多価アルコール
脂肪酸エステル、ショ糖脂肪酸エステル等があり、そして両性イオン活性剤には
アルキルトリメチルアミノ酢酸、アルキルジエチレントリアミノ酢酸等がある。
本発明においては、上記の中でアルキル硫酸エステル塩、アルキルベンゼンス
ルホン酸塩、脂肪酸アミドスルホン酸塩、ポリオキシエチレンアルキルまたはア
ルキルフェニルエーテル等を主成分とし、それに炭酸塩、アルミナケイ酸塩、酵
素等が配合された家庭用または工業用の合成洗剤が入手しやすさおよびコストの
点から好適である。
【０００８】
また、本発明において使用される脱脂剤は、金属表面の脱脂のために通常用い
られているものであり、例えば炭酸ナトリウム、水酸化ナトリウム、リン酸ナト
リウム、トリポリリン酸ナトリウム、ケイ酸ナトリウム、アルミン酸ナトリウム
、ホウ砂、炭酸水素ナトリウム、キレート剤〔例えばエチレンジアミン四酢酸（
ＥＤＴＡ），オキシカルボン酸等〕等を挙げることができる。本発明における脱
脂剤として１種のみで使用されてもよいが、好ましくは適当な比率で配合された
混合物で用いられる。また、上記脱脂剤は、被研磨物の材質よっては、腐食を引
き起こすものもあるので、脱脂剤と被研磨物との組合せを適宜選択する必要があ
る。
この脱脂剤として、金属表面の脱脂用に市販されている浸漬脱脂剤および電解
脱脂剤が好適に使用されるが、その際にも、被研磨物品の材質に適した脱脂剤を
用いることが好ましいことはいうまでもない。市販の脱脂剤としては、例えばキ
ザイ株式会社製のマックスクリーン（商品名）やテイオンクリーナー（商品名）
のシリーズおよび上村工業株式会社製のアサヒクリーナー（商品名）やＵ−クリ
ーナー（商品名）のシリーズを挙げることができる。
本発明において、研磨性材料に界面活性剤および脱脂剤を添加したことにより
、被研磨物品の研磨後の洗浄を、従来のトリクレン等の塩素系溶剤を用いずに、
加温した水を用いて、十分かつ確実に行うことができる。また、この洗浄を行う
温水に界面活性剤および脱脂剤を添加することにより、研磨後の物品の洗浄をよ
り効果的に行うことができる。
【０００９】
次に、本発明において使用されてもよい繊維性成分は、天然繊維および化学繊
維を意味し、前者の例として植物繊維（木材繊維、綿繊維、麻繊維等）、動物繊
維（羊毛、絹等）および鉱物繊維（アスベスト等）があり、後者の例として無機
繊維（ガラス繊維等）、再生繊維（レーヨン等）、半合成繊維（アセテート等）
、合成繊維（ナイロン等）がある。また、繊維性成分として、紙（例えば新聞紙
、包装紙、薄葉紙、雑種紙等）を煮詰めることにより生成する植物繊維のような
、既製の繊維製品から再生された繊維を用いることもでき、上記のような紙から
の植物繊維は入手しやすさやコストの点で好ましいものである。
この繊維性成分の種類や太さ・長さ等は研磨性材料との組合せで適宜選択され
る。繊維性成分もまた、１種または２種以上を組み合わせて用い得る。
なお、繊維性成分を配合することにより、研磨性材料としてエメリーの配合量
を増やすことができ、より切れの良い研磨材とすることができる。また、ペース
ト状研磨材とした場合に空気と接触しても固まりにくいという利点もある。
【００１０】
上記研磨材の各成分の配合量は、上記したように研磨性材料１００重量部に対
して界面活性剤および脱脂剤が０．１ないし１０重量部であり、そして所望によ
り添加してもよい繊維性成分が０．１ないし５００重量部である。界面活性剤お
よび脱脂剤の配合量が０．１重量部未満であると、研磨後の物品の洗浄の際、該
物品に付着した、または物品の細部に入り込んだ細かい研磨材残渣の洗浄作用が
得られず、また１０重量部を越えても該洗浄作用は平衡状態に達するだけでなく
、研磨性材料の研磨力を低下させ好ましくない。繊維性成分の配合量が０．１重
量部未満であると、繊維の前記効力が発揮されず、また、５００重量部を越える
と、固形ないし練状の研磨材の形状を保持できず、しかも研磨性材料の研磨力を
低下させ好ましくない。
【００１１】
さらに、本発明における研磨材によっては、上記研磨性材料とその他の各成分
とを結合するために、結合剤をさらに配合する必要がある場合もある。これは、
接着剤と総称される、膠、糊、ラバーセメント等の中から、使用される研磨性材
料とその他の各成分の種類に応じて適宜選択され得る。例を挙げると、天然物系
としてデンプン、デキストリン、植物ガム、動植物タンパク質、アスファルト、
セラック、天然ゴム、ケイ酸ナトリウム等があり、合成品系として熱可塑性樹脂
のセルロース系、アルキド、アクリルエステル、ポリアミド、ポリスチレン、合
成ゴム、ポリビニルアルコール等、熱硬化性樹脂の尿素樹脂、メラミン樹脂、フ
ェノール樹脂、レゾルシノール樹脂、フラン樹脂、エポキシ樹脂、不飽和ポリエ
ステル等がある。
【００１２】
本発明の研磨材は、適当量の上記各成分を、順次または同時に混合し、使用さ
れた各成分の性質および意図する研磨材に応じた処理を施して製造される。その
場合、必要に応じて、その他の成分を添加して加工性等を改善することもできる
。例えば、油脂性の棒状バフ研磨材は、研磨性材料の砥粒分の微粉末に、ステア
リン酸、硬化油、牛脂、松脂、パラフィン等の油脂分と界面活性剤および／また
は脱脂剤、所望により繊維性成分を配合して固形化することにより製造される。
【００１３】
本発明の研磨材により研磨し得る物品は、研磨が必要なあらゆるものであり、
金属からなるものでも、プラスチックからなるものであってよい。具体的には、
鉄鋼、非鉄金属、各種合金等の金属または繊維で強化されていてもよいビニル樹
脂、フェノール樹脂、尿素樹脂、メラミン樹脂等のプラスチックからなるものが
例示できる。
【００１４】
【実施例】
次に本発明を実施例に基づいて説明するが、本発明はこれらに限定されるもの
ではない。
参考例１
ステアリン酸、硬化油、牛脂、松脂およびパラフィンを適量ずつ配合し、油脂
混合物とする。微粉末状のケイ酸コロイド（ケイ石，ＳｉＯ2）７００ｇに家庭
用合成洗剤１０ｇと上記油脂混合物を少量配合し、十分に混合後、常温にて砥石
型の棒状に固め、バフ研磨材とする。
参考例２
焼成アルミナと溶融アルミナの微粉末状の混合物（Ａｌ2Ｏ3）７００ｇに市販
の脱脂剤（商品名マックスクリーンＢＧＦ−２１０，キザイ株式会社製）１０ｇ
と上記油脂混合物を少量配合し、十分に混合後、常温にて砥石型の棒状に固め、
バフ研磨材とする。
実施例１
微粉末状の酸化鉄（Ｆｅ2Ｏ3）７００ｇに家庭用合成洗剤１０ｇおよび市販の
脱脂剤（商品名マックスクリーンＢＧ−２０，キザイ株式会社製）１０ｇと上記
油脂混合物を少量配合し、十分に混合後、常温にて砥石型の棒状に固め、バフ研
磨材とする。
実施例２
微粉末状の酸化クロム（Ｃｒ2Ｏ3）７００ｇにドデシル硫酸ナトリウム１０ｇ
および市販の脱脂剤（商品名アサヒクリーナーＮｏ．２００，上村工業株式会社
製）１０ｇと上記油脂混合物を少量配合し、十分に混合後、常温にて砥石型の棒
状に固め、バフ研磨材とする。
実施例３
細かく裁断した紙５ｇおよび膠１５０ｇに水１００ｍｌを加え、これらを煮つ
め（この段階で紙はほぐれ植物繊維の状態となる）、これに微粉末状のケイ酸コ
ロイド（ケイ石，ＳｉＯ2）３５０ｇ、砂石（商品名トリエメリーエキストラ♯
２２０，宇治電化学工業株式会社製）３５０ｇ、ポリオキシエチレンアルキルエ
ーテル１０ｇおよびリン酸ナトリウム、ケイ酸ナトリウム、炭酸ナトリウム、水
酸化ナトリウムとキレート剤の混合物１０ｇと上記油脂混合物を少量配合し、十
分に混合後、さらに蒸発により水を除去し、常温にて砥石型の棒状に固め、バフ
研磨材とする。
比較例１ないし５
参考例１および２ならびに実施例１ないし３のそれぞれにおいて使用されてい
る界面活性剤（洗剤）および／または脱脂剤を配合せずに、それぞれのバフ研磨
材を製造した。
試験例１
参考例１および２ならびに実施例１ないし３および比較例１ないし５において
製造したバフ研磨材を用いて真鍮、ステンレスまたは亜鉛からなる３種の腕時計
側板、多数の細溝を設けた真鍮板、および多数の小孔を穿設したアルミニウム製
円盤をバフ研磨し、その後、７５℃の温水中で超音波洗浄を行った。いずれの被
研磨物品の場合も研磨の状態は良好で、中でも実施例２および比較例４によるも
のはつやが特によく出、また、実施例３および比較例５によるものは特に切れが
良かった。しかし、比較例１ないし５の研磨材による研磨洗浄後の物品には、１
０分間の洗浄後でも研磨材残渣が多量に残り、特に細溝や小孔に詰まった残渣は
全く除去されていなかった。これに対し、実施例１ないし３の研磨材による研磨
後の物品は１分間の洗浄で研磨材残渣が完全に除去されていた。
なお、比較例１ないし５の研磨材による研磨後の物品の研磨材残渣の除去には
、従来のように、超音波洗浄機中の５０ないし８０℃に加熱したトリクレン、ト
リクロロエタンまたはエチレンクロライド中での最低３分間の処理、または手作
業による除去が必要だった。
【００１５】
試験例２
実施例１ないし３で製造した研磨材によりその他の金属部品、プラスチック部
品、ガラス部品、セラミック部品の研磨を行ったところ、いずれも好ましい研磨
結果が得られ、７５℃の温水中での超音波洗浄により、１分間以内に確実に洗浄
され、さらに該温水に洗剤および脱脂剤を添加した場合、より短時間で洗浄され
た。
【００１６】
【発明の効果】
以上詳細に説明したように、本発明の油脂性バフ研磨材は、研磨性材料に特定
の配合比で界面活性剤および脱脂剤を配合したことにより、従来のバフ研磨材で
は必要だった研磨処理後の物品のトリクレン、トリクロロエタンまたはエチレン
クロライド、または塩酸中での浸漬洗浄が不要となり、温水中での浸漬洗浄のみ
で完全に清浄にすることができる。また、界面活性剤および脱脂剤の配合による
研磨材への切れやつや出し効果に対する悪影響はなく、繊維性成分をさらに配合
することにより、切れをより向上させることができる。従って、本発明の油脂性
バフ研磨材は優れた研磨作用を有するとともに、トリクレン等による洗浄および
それに伴う特殊な排気設備を不要とし、作業環境を悪化させることもない。この
ように、本発明の研磨材によれば、簡単な研磨・洗浄設備での処理が可能となる
。
さらに、本発明の上記研磨材は、金属物品やプラスチック物品等のバフ研磨用
として用いられ、適当な研磨性材料を選択することにより、研削用、仕上げ用お
よび光沢用の各種研磨材とすることができ、広範囲に利用可能である。Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an oily buffing abrasive containing a surfactant and a degreasing agent. More specifically, the present invention relates to an oily and buffed abrasive capable of performing washing after polishing quickly and easily. 2. Description of the Related Art Underground polishing of plating and painting, surface polishing of stainless steel, scale removal, deburring, chamfering, polishing, satin finish, and basis weight are generally performed by mechanical polishing with an abrasive. Mechanical polishing includes a) barrel polishing, b) polishing with a rotating tool typified by buffing, c) dry jetting of powder, d) wet polishing of jetting an abrasive mixed with water, e). Abrasive belt polishing, f) polishing with a high-pressure medium such as water or oil, g) polishing by pressing a viscous fluid containing an abrasive, and the like. Buffing is generally performed before surface processing such as plating of various metal articles made of iron, stainless steel, copper, brass, zinc, aluminum, and the like. As a polishing material for buffing, a powdery abrasive material is mixed with oil and fat, solidified, and a rod-shaped oily buffing polishing material is frequently used. This is frictional heat generated by pressing the bar-shaped polishing material against a buff. The fats and oils are dissolved, the abrasive is applied to the buff surface, and the buff can be polished. Further, depending on the purpose, a non-oil-based buffing abrasive formed by adding an abrasive material to a water-soluble adhesive and kneading the mixture may be used. However, these conventional abrasives require ultrasonic cleaning in heated trichloroethylene (trichlene), trichloroethane or ethylene chloride, or hydrochloric acid in order to remove the abrasive remaining on the abrasive article after the polishing treatment. Not only do they require processing equipment such as a fume hood, but also the chlorine-based cleaning solutions described above are all dangerous and must be handled with care and degrade the working environment. Was. Among them, there are cleaning liquids, such as Tricrene, whose use is prohibited by local governments. In addition, in the case of articles with complicated shapes, articles with severe irregularities, articles having many fine holes, etc., the intricate portions and the abrasives entering the holes are subjected to long-term ultrasonic cleaning in the above-described cleaning liquid. However, it could not be easily removed, and ultimately had to be performed manually, resulting in extremely low work efficiency. [0003] Under the circumstances described above, there has been a strong demand in the art for a system that replaces the cleaning of articles after polishing using a chlorine-based solution. Then, this invention is made in order to solve the said problem, and it is used for buff polishing, and makes it a subject to provide the polishing material which can be quickly and easily performed after polishing without using trichlorene etc. . [0004] That is, the oily and buffed abrasive of the present invention comprises at least one selected from the group consisting of silica stone, calcined alumina, fused alumina, iron oxide, chromium oxide and emery.
It is characterized by containing 0.1 to 10 parts by weight of a surfactant and a degreasing agent based on 100 parts by weight of the abrasive material composed of seeds and fats and oils. The present invention also provides a fibrous component of 0.1 to 50 parts by weight per 100 parts by weight of the abrasive material.
The oil-based buffing abrasive further comprises 0 parts by weight. The abrasive material used in the present invention is an oil or fat, a hard substance having a grinding action, and a hard substance having a polishing action such as finishing or polishing a processed surface. Means what is called abrasive grains. Here, the abrasive is silica (colloidal silicate, SiO 2 ), calcined alumina (Al 2 O 3 ), fused alumina (Al 2 O 3 ), iron oxide (Fe 2 O 3 ), and chromium oxide (Cr 2 O). 3 ) and at least one of emery (corundum, sandstone). The type, particle size, particle size, and the like of the abrasive particles are appropriately selected according to the object to be polished, the buff used, and the like. Further, the abrasive grains can be used alone or in combination of two or more. On the other hand, the fats and oils of the abrasive material are fats and oils, oils, paraffin and the like. The fats and oils which can be used are mainly mono- or tri-esters of fatty acids and triglycerin which are widely present in the natural animal and plant kingdoms, and may be not only natural products but also synthetic ones, and vegetable oils such as soybean oil, coconut Oil, linseed oil, cottonseed oil, rapeseed oil,
Animal oils such as tallow oil, castor oil, pine resin, tall oil and the like, such as beef tallow, lanolin, and whale oil, can be exemplified. The oil agent is obtained by processing the above fats and oils, for example, hardened oil obtained by hydrogenating fats and oils, fatty acids and glycerin obtained by hydrolysis of fats and oils, and other polyhydric alcohols. Representative examples of fatty acids include, for example, lauric acid, myristyl acid, palmitic acid, stearic acid, oleic acid, behenic acid, and the like. Further, as the paraffin, a linear or branched saturated hydrocarbon having about 10 to 40 carbon atoms, for example, paraffin wax can be exemplified. The surfactant used in the present invention is not particularly limited, and an anionic surfactant,
Regardless of the cationic surfactant, nonionic surfactant and zwitterionic surfactant,
A mixture thereof may be used. As typical examples of each, anionic surfactants include soap, sodium alkyl sulfate, sodium olefin sulfate, sodium alkyl benzene sulfonate, sodium alkyl naphthalene sulfonate, sodium oleamide amide sulfonate, sodium dialkyl sulfosuccinate, and the like. , Cationic surfactants include trimethylaminoethyl alkylamide halides, alkylpyridinium sulfates, alkyltrimethylammonium halides, and the like. Nonionic surfactants include polyoxyethylene alkyl ethers, polyoxyethylene fatty acid esters, and polyoxyethylene. There are alkyl phenyl ether, polyhydric alcohol fatty acid ester, polyoxyethylene polyhydric alcohol fatty acid ester, sucrose fatty acid ester, etc. The zwitterionic active agent is an alkyl trimethyl amino acid, and alkyl diethylenetriaminopentaacetic acid Te. In the present invention, among the above, an alkyl sulfate salt, an alkylbenzene sulfonate, a fatty acid amide sulfonate, a polyoxyethylene alkyl or an alkylphenyl ether or the like as a main component, and a carbonate, an alumina silicate, an enzyme, etc. Are preferred from the viewpoint of availability and cost. [0008] The degreasing agent used in the present invention is one that is usually used for degreasing a metal surface, such as sodium carbonate, sodium hydroxide, sodium phosphate, sodium tripolyphosphate, and sodium silicate. , Sodium aluminate, borax, sodium bicarbonate, chelating agents [eg, ethylenediaminetetraacetic acid (
EDTA), oxycarboxylic acid, etc.]. Although only one type may be used as the degreasing agent in the present invention, it is preferably used in a mixture blended in an appropriate ratio. In addition, the above degreasing agent may cause corrosion depending on the material of the object to be polished. Therefore, it is necessary to appropriately select a combination of the degreasing agent and the object to be polished. As this degreasing agent, immersion degreasing agents and electrolytic degreasing agents that are commercially available for degreasing metal surfaces are preferably used, and in that case, it is preferable to use a degreasing agent suitable for the material of the article to be polished. Needless to say. Commercially available degreasing agents include, for example, Mac Screen (trade name) and Tion Cleaner (trade name) manufactured by Kizai Co., Ltd.
And U-Cleaner (trade name) and U-Cleaner (trade name) series manufactured by Uemura Kogyo Co., Ltd. In the present invention, by adding a surfactant and a degreasing agent to the abrasive material, cleaning after polishing the article to be polished is performed using heated water without using a conventional chlorinated solvent such as trichlene. Can be performed sufficiently and reliably. In addition, by adding a surfactant and a degreasing agent to the warm water for performing the washing, the article after polishing can be more effectively washed. Next, fibrous components that may be used in the present invention mean natural fibers and chemical fibers, and examples of the former include plant fibers (wood fibers, cotton fibers, hemp fibers, etc.) and animal fibers (wool). , Silk, etc.) and mineral fibers (asbestos, etc.). Examples of the latter are inorganic fibers (glass fibers, etc.), recycled fibers (rayon, etc.), semi-synthetic fibers (acetate, etc.).
, Synthetic fibers (nylon, etc.). Further, as the fibrous component, a fiber regenerated from a ready-made fiber product such as a plant fiber produced by boiling down paper (eg, newsprint, wrapping paper, tissue paper, hybrid paper, etc.) can be used. Such plant fibers from paper are preferred in terms of availability and cost. The type, thickness and length of the fibrous component are appropriately selected in combination with the abrasive material. The fibrous component can also be used alone or in combination of two or more. In addition, by blending the fibrous component, the blending amount of emery as the abrasive material can be increased, and a more sharp abrasive can be obtained. In addition, there is also an advantage that the paste-like abrasive is hard to be hardened even when it comes into contact with air. The amount of each component of the abrasive is 0.1 to 10 parts by weight of a surfactant and a degreasing agent with respect to 100 parts by weight of the abrasive material as described above. The preferred fibrous component is 0.1 to 500 parts by weight. When the compounding amount of the surfactant and the degreasing agent is less than 0.1 part by weight, the cleaning action of fine abrasive residues adhered to the article or introduced into the details of the article at the time of cleaning the article after polishing may be reduced. If it is not obtained, and if it exceeds 10 parts by weight, the cleaning action not only reaches an equilibrium state, but also undesirably lowers the polishing power of the abrasive material. If the compounding amount of the fibrous component is less than 0.1 part by weight, the above-mentioned effect of the fiber is not exhibited, and if it exceeds 500 parts by weight, the shape of the solid or kneaded abrasive cannot be maintained, and It is not preferable because the polishing power of the abrasive material is reduced. Further, depending on the abrasive used in the present invention, it may be necessary to further add a binder in order to bond the above-mentioned abrasive material and other components. this is,
It can be appropriately selected from glue, glue, rubber cement, and the like, which are collectively referred to as an adhesive, depending on the type of the abrasive material used and other components. Examples include starch, dextrin, plant gum, plant and animal proteins, asphalt,
There are shellac, natural rubber, sodium silicate, etc., and synthetic products such as cellulose resin of thermoplastic resin, alkyd, acrylic ester, polyamide, polystyrene, synthetic rubber, polyvinyl alcohol, etc., urea resin of thermosetting resin, melamine resin, phenol Resin, resorcinol resin, furan resin, epoxy resin, unsaturated polyester and the like. The abrasive of the present invention is produced by mixing an appropriate amount of each of the above components sequentially or simultaneously and subjecting them to a treatment according to the properties of each component used and the intended abrasive. In this case, if necessary, other components can be added to improve the workability and the like. For example, an oily rod-shaped buffing abrasive is obtained by adding a fat and oil such as stearic acid, hardened oil, tallow, rosin, paraffin, and a surfactant and / or a degreasing agent to fine powder of abrasive grains of an abrasive material, if desired. It is manufactured by blending fibrous components and solidifying. Articles that can be polished with the abrasive of the present invention are all those that require polishing,
It may be made of metal or plastic. In particular,
Examples thereof include plastics such as a vinyl resin, a phenol resin, a urea resin, and a melamine resin which may be reinforced with a metal such as a steel, a non-ferrous metal, and various alloys, or a fiber. EXAMPLES Next, the present invention will be described based on examples, but the present invention is not limited to these. Reference Example 1 Stearic acid, hardened oil, beef tallow, rosin, and paraffin are mixed in appropriate amounts to prepare a fat mixture. A small amount of 10 g of a synthetic detergent for home use and a small amount of the above oil and fat mixture are mixed with 700 g of a fine powdered colloidal silicate (silica, SiO 2 ), and after sufficient mixing, the mixture is solidified into a whetstone-shaped rod at room temperature to obtain a buff abrasive. . Reference Example 2 A commercially available degreasing agent (trade name: MacScreen BGF-210, manufactured by Kizai Co., Ltd.) was added to 700 g of a fine powder mixture (Al 2 O 3 ) of calcined alumina and fused alumina.
And a small amount of the above fat and oil mixture, and after mixing well, solidified into a whetstone-shaped rod at room temperature,
Use buffing abrasive. Example 1 A small amount of 10 g of a synthetic detergent for home use, 10 g of a commercially available degreasing agent (trade name: MacScreen BG-20, manufactured by Kizai Co., Ltd.) and 700 g of fine powdered iron oxide (Fe 2 O 3 ) and a small amount of the above oil and fat mixture were mixed. After sufficient mixing, the mixture is solidified into a whetstone-shaped rod at room temperature to obtain a buff abrasive. Example 2 10 g of sodium dodecyl sulfate was added to 700 g of chromium oxide (Cr 2 O 3 ) in the form of fine powder.
Also, 10 g of a commercially available degreasing agent (trade name: Asahi Cleaner No. 200, manufactured by Uemura Kogyo Co., Ltd.) and a small amount of the above oil / fat mixture are blended, sufficiently mixed, and then solidified into a whetstone bar at room temperature to obtain a buff abrasive. . Example 3 100 g of water was added to 5 g of finely cut paper and 150 g of glue, and the mixture was boiled (at this stage, the paper became a state of vegetable fibers), and this was mixed with fine powdered silicate colloid (silica, SiO 2). ) 350 g, sandstone (trade name: Triemery Extra II)
220, manufactured by Ujiden Kagaku Kogyo Co., Ltd.) 350 g, 10 g of polyoxyethylene alkyl ether, 10 g of a mixture of sodium phosphate, sodium silicate, sodium carbonate, sodium hydroxide and a chelating agent and a small amount of the above oil / fat mixture, and sufficiently mixed After mixing, water is further removed by evaporation, and the mixture is solidified into a whetstone-shaped rod at room temperature to obtain a buff abrasive. Comparative Examples 1 to 5 Buffing abrasives were produced without blending the surfactant (detergent) and / or degreasing agent used in Reference Examples 1 and 2 and Examples 1 to 3, respectively. Test Example 1 Three wristwatch side plates made of brass, stainless steel or zinc using the buff abrasives produced in Reference Examples 1 and 2 and Examples 1 to 3 and Comparative Examples 1 to 5, and brass provided with a large number of narrow grooves The plate and an aluminum disk having a number of small holes were buffed and then subjected to ultrasonic cleaning in 75 ° C. hot water. In any of the articles to be polished, the polished state was good. Among them, those of Example 2 and Comparative Example 4 were particularly glossy, and those of Example 3 and Comparative Example 5 were particularly sharp. However, the articles after polishing and cleaning with the abrasives of Comparative Examples 1 to 5 include 1
Even after washing for 0 minutes, a large amount of abrasive residue remained, and especially no residue clogged in narrow grooves or small holes was removed at all. On the other hand, the articles polished by the abrasives of Examples 1 to 3 were completely removed from the abrasive residues by washing for 1 minute. In addition, the removal of the abrasive residue of the article after polishing with the abrasive of Comparative Examples 1 to 5 was carried out in a conventional manner in trichlorene, trichloroethane or ethylene chloride heated to 50 to 80 ° C. in an ultrasonic cleaner. Requires a minimum of 3 minutes of treatment or manual removal. Test Example 2 When polishing other metal parts, plastic parts, glass parts, and ceramic parts with the abrasives produced in Examples 1 to 3, favorable polishing results were obtained, and hot water at 75 ° C. was obtained. The ultrasonic cleaning in the inside surely performed the cleaning within one minute, and when a detergent and a degreasing agent were added to the warm water, the cleaning was performed in a shorter time. As described in detail above, the oily and buffed abrasive of the present invention is obtained by mixing a surfactant and a degreasing agent in a specific mixing ratio with an abrasive material, thereby obtaining a conventional buffed abrasive. Abrasives do not need to be immersed and washed in trichlene, trichloroethane or ethylene chloride, or hydrochloric acid after polishing, which is necessary with abrasives, and can be completely cleaned only by immersion and washing in warm water. In addition, the mixing of the surfactant and the degreasing agent has no adverse effect on the cutting or polishing effect on the abrasive, and the cutting can be further improved by further mixing the fibrous component. Therefore, the oily and buffed abrasive of the present invention has an excellent polishing effect, and does not require cleaning with trichlene or the like and a special exhaust facility associated therewith, and does not deteriorate the working environment. As described above, according to the abrasive of the present invention, it is possible to perform processing with a simple polishing / cleaning facility. Further, the abrasive of the present invention is used for buffing metal articles and plastic articles, etc., and by selecting an appropriate abrasive material, it can be used as various abrasives for grinding, finishing and gloss. And is widely available.
Claims (1)
よびエメリーからなる群から選択される少なくとも１種と油脂分とからなる研磨
性材料１００重量部に対して界面活性剤および脱脂剤を０．１ないし１０重量部
含むことを特徴とする油脂性バフ研磨材。 【請求項２】 研磨性材料１００重量部に対して繊維性成分０．１ないし５０
０重量部をさらに含む請求項１記載の油脂性バフ研磨材。Claims: 1. An abrasive material comprising at least one selected from the group consisting of silica stone, calcined alumina, fused alumina, iron oxide, chromium oxide, and emery and an oil and fat, in an amount of 100 parts by weight. An oily and buffed abrasive comprising 0.1 to 10 parts by weight of a surfactant and a degreasing agent. 2. A fibrous component of 0.1 to 50 per 100 parts by weight of the abrasive material.
The oily and buffed abrasive according to claim 1, further comprising 0 parts by weight.
Family
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