JP2023517422A - トリスアミド化合物およびトリスアミド化合物を含む組成物 - Google Patents
トリスアミド化合物およびトリスアミド化合物を含む組成物 Download PDFInfo
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- JP2023517422A JP2023517422A JP2022535613A JP2022535613A JP2023517422A JP 2023517422 A JP2023517422 A JP 2023517422A JP 2022535613 A JP2022535613 A JP 2022535613A JP 2022535613 A JP2022535613 A JP 2022535613A JP 2023517422 A JP2023517422 A JP 2023517422A
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- benzamide
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- 150000001875 compounds Chemical class 0.000 title claims abstract description 168
- 239000000203 mixture Substances 0.000 title claims abstract description 113
- 229920000642 polymer Polymers 0.000 claims abstract description 101
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 39
- 229920000098 polyolefin Polymers 0.000 claims abstract description 19
- -1 polypropylene Polymers 0.000 claims description 51
- 239000004743 Polypropylene Substances 0.000 claims description 11
- 229920001155 polypropylene Polymers 0.000 claims description 11
- 229920005630 polypropylene random copolymer Polymers 0.000 claims description 9
- 229920005629 polypropylene homopolymer Polymers 0.000 claims description 7
- ULEVUYSYNATVTO-UHFFFAOYSA-N C(C)(C)(C)C1CCC(CC1)NC(C1=CC(=CC(=C1)NC(=O)C1CCC(CC1)C(C)(C)C)NC(=O)C1CCC(CC1)C(C)(C)C)=O Chemical compound C(C)(C)(C)C1CCC(CC1)NC(C1=CC(=CC(=C1)NC(=O)C1CCC(CC1)C(C)(C)C)NC(=O)C1CCC(CC1)C(C)(C)C)=O ULEVUYSYNATVTO-UHFFFAOYSA-N 0.000 claims description 5
- IEDGFUWBKKRBPW-UHFFFAOYSA-N C(C)(C)(C)C1CCC(CC1)NC(C1=CC(=CC(=C1)NC(=O)C1CCC(CC1)C(C)(C)CC)NC(=O)C1CCC(CC1)C(C)(C)CC)=O Chemical compound C(C)(C)(C)C1CCC(CC1)NC(C1=CC(=CC(=C1)NC(=O)C1CCC(CC1)C(C)(C)CC)NC(=O)C1CCC(CC1)C(C)(C)CC)=O IEDGFUWBKKRBPW-UHFFFAOYSA-N 0.000 claims description 5
- XMNRAHIAGOLMSQ-UHFFFAOYSA-N C(C)(C)(CC)C1CCC(CC1)NC(C1=CC(=CC(=C1)NC(=O)C1CCC(CC1)C(C)(C)C)NC(=O)C1CCC(CC1)C(C)(C)C)=O Chemical compound C(C)(C)(CC)C1CCC(CC1)NC(C1=CC(=CC(=C1)NC(=O)C1CCC(CC1)C(C)(C)C)NC(=O)C1CCC(CC1)C(C)(C)C)=O XMNRAHIAGOLMSQ-UHFFFAOYSA-N 0.000 claims description 5
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- JRZAXALORSWYFG-UHFFFAOYSA-N C(C)(C)(C)C1CCC(CC1)NC(C1=CC(=CC(=C1)NC(=O)C1CCC(CC1)C(C)C)NC(=O)C1CCC(CC1)C(C)C)=O Chemical compound C(C)(C)(C)C1CCC(CC1)NC(C1=CC(=CC(=C1)NC(=O)C1CCC(CC1)C(C)C)NC(=O)C1CCC(CC1)C(C)C)=O JRZAXALORSWYFG-UHFFFAOYSA-N 0.000 claims description 4
- RARIEKRLLKAPOA-UHFFFAOYSA-N C(C)(C)(CC)C1CCC(CC1)NC(C1=CC(=CC(=C1)NC(=O)C1CCC(CC1)C(C)(C)CC)NC(=O)C1CCC(CC1)C(C)(C)CC)=O Chemical compound C(C)(C)(CC)C1CCC(CC1)NC(C1=CC(=CC(=C1)NC(=O)C1CCC(CC1)C(C)(C)CC)NC(=O)C1CCC(CC1)C(C)(C)CC)=O RARIEKRLLKAPOA-UHFFFAOYSA-N 0.000 claims description 3
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- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 2
- 238000000605 extraction Methods 0.000 abstract description 18
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- 239000011541 reaction mixture Substances 0.000 description 17
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 16
- 238000003756 stirring Methods 0.000 description 15
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- 239000000047 product Substances 0.000 description 14
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 14
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- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 12
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 12
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- 125000003548 sec-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
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- 239000002244 precipitate Substances 0.000 description 9
- 125000003542 3-methylbutan-2-yl group Chemical group [H]C([H])([H])C([H])(*)C([H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 8
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 8
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 8
- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- NNOHXABAQAGKRZ-UHFFFAOYSA-N 3,5-dinitrobenzoyl chloride Chemical compound [O-][N+](=O)C1=CC(C(Cl)=O)=CC([N+]([O-])=O)=C1 NNOHXABAQAGKRZ-UHFFFAOYSA-N 0.000 description 6
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- 238000004704 ultra performance liquid chromatography Methods 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
- C07C233/64—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings
- C07C233/65—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
- C07C237/28—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton
- C07C237/42—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton having nitrogen atoms of amino groups bound to the carbon skeleton of the acid part, further acylated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
Description
発明の背景
[0002]ポリマー樹脂は、数ある中でも、それらの優れた加工性、機械的特性(とりわけ相対重量基準で)および電気的特性により、様々な分野で広く使用されている。ポリマー自体が有益な特性を有し得るが、さらにポリマーの特性を高めるため、および/または不都合な点を軽減するために添加剤が使用されてもよい。
発明の簡単な概要
[0007]第1の態様において、本発明は、式(I)
発明の詳細な説明
[0009]第1の態様において、本発明は、下記式(I)の化合物を提供し、この化合物は、3,5-ジアミノ安息香酸から形式的に誘導されたトリスアミド誘導体である。式(I)の構造は以下の通りである:
(i)N-(4-イソプロピルシクロヘキシル)-3,5-ビス-[4-イソプロピルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(ii)N-(4-イソプロピルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(iii)N-(4-n-プロピルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(iv)N-(4-n-ブチルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(v)N-(4-tert-ブチルシクロヘキシル)-3,5-ビス-[4-イソプロピルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(vi)N-(4-tert-ブチルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(vii)N-(4-tert-ペンチルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(viii)N-(4-tert-ブチルシクロヘキシル)-3,5-ビス-[4-tert-ペンチルシクロヘキシルカルボニルアミノ]-ベンズアミド;および
(ix)N-(4-tert-ペンチルシクロヘキシル)-3,5-ビス-[4-tert-(ペンチルシクロヘキシルカルボニルアミノ]-ベンズアミド;ならびに
(x)これらの混合物(すなわち、前述の化合物のうちの何れか2つ以上の混合物)からなる群から選択される。
(i)N-(4-イソプロピルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(ii)N-(4-n-プロピルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(iii)N-(4-n-ブチルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(iv)N-(4-tert-ブチルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(v)N-(4-tert-ペンチルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(vi)N-(4-tert-ブチルシクロヘキシル)-3,5-ビス-[4-tert-ペンチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(vii)N-(4-tert-ペンチルシクロヘキシル)-3,5-ビス-[4-tert-ペンチルシクロヘキシルカルボニルアミノ]-ベンズアミド;および
(viii)これらの混合物(すなわち、前述の化合物のうちの何れか2つ以上の混合物)からなる群から選択される。
(i)N-(cis-4-イソプロピルシクロヘキシル)-3,5-ビス-[cis-4-イソプロピルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(ii)N-(cis-4-イソプロピルシクロヘキシル)-3,5-ビス-[cis-4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(iii)N-(cis-4-n-プロピルシクロヘキシル)-3,5-ビス-[cis-4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(iv)N-(cis-4-n-ブチルシクロヘキシル)-3,5-ビス-[cis-4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(v)N-(cis-4-tert-ブチルシクロヘキシル)-3,5-ビス-[cis-4-イソプロピルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(vi)N-(cis-4-tert-ブチルシクロヘキシル)-3,5-ビス-[cis-4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(vii)N-(cis-4-tert-ペンチルシクロヘキシル)-3,5-ビス-[cis-4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(viii)N-(cis-4-tert-ブチルシクロヘキシル)-3,5-ビス-[cis-4-tert-ペンチルシクロヘキシルカルボニルアミノ]-ベンズアミド;および
(ix)N-(cis-4-tert-ペンチルシクロヘキシル)-3,5-ビス-[cis-4-tert-(ペンチルシクロヘキシルカルボニルアミノ]-ベンズアミド);ならびに
(x)これらの混合物(すなわち、前述の化合物のうちの何れか2つ以上の混合物)からなる群から選択される。
(i)N-(cis-4-イソプロピルシクロヘキシル)-3,5-ビス-[cis-4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(ii)N-(cis-4-n-プロピルシクロヘキシル)-3,5-ビス-[cis-4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(iii)N-(cis-4-n-ブチルシクロヘキシル)-3,5-ビス-[cis-4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(iv)N-(cis-4-tert-ブチルシクロヘキシル)-3,5-ビス-[cis-4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(v)N-(cis-4-tert-ペンチルシクロヘキシル)-3,5-ビス-[cis-4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(vi)N-(cis-4-tert-ブチルシクロヘキシル)-3,5-ビス-[cis-4-tert-ペンチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
(vii)N-(cis-4-tert-ペンチルシクロヘキシル)-3,5-ビス-[cis-4-tert-ペンチルシクロヘキシルカルボニルアミノ]-ベンズアミド;および
(viii)これらの混合物(すなわち、前述の化合物のうちの何れか2つ以上の混合物)からなる群から選択される。
次に、式(A)の中間化合物を、既知の方法(たとえば、水素化)を用いて還元して、下記式(B)
次に、式(B)の化合物を所望の4-アルキルシクロヘキサンカルボニルクロリドと反応させて、式(I)の所望の化合物を生成することができる。この最後の工程で、2つの異なる4-アルキルシクロヘキサンカルボニルクロリドの混合物を式(B)の化合物と反応させて、R2およびR3が異なる(または対応するシクロヘキサンジイル部分の1位に結合した非水素置換基に対して異なる空間的関係にある)式(I)の化合物を生成し得る。しかしながら、異なる4-アルキルシクロヘキサンカルボニルクロリドの混合物を使用して生成された反応生成物は、R2とR3とが同じである相当量の式(I)の化合物も含有し得る。したがって、所望の不斉化合物をこれらの他の成分から単離するために、その後の精製が必要となり得る。
次に、式(J)の中間化合物をオキサリルクロリドと反応させて、下記式(K)
次に、式(K)の酸塩化物を所望の4-アルキルシクロヘキシルアミンと反応させて、下記式(L)
次に、式(L)の中間化合物を、既知の方法を使用して水素化して、下記式(M)
最後に、式(M)のアミン化合物を所望の4-アルキルシクロヘキサンカルボニルクロリドと反応させて、式(I)の所望の化合物を生成することができる。
[0029]本例は、本発明によるトリスアミド化合物の調製を示す。
[0034]本例は、本発明によるトリスアミド化合物の調製を示す。
[0039]本例は、本発明によるトリスアミド化合物の調製を記載する。
[0044]本例は、本発明によるポリマー組成物の生成およびそのようなポリマー組成物の特性を示す。
[0048]本例は、本発明のトリスアミド化合物(すなわち、式(I)のトリスアミド化合物)の合成を示す。
[0052]本例は、本発明によるポリマー組成物の生成およびそのようなポリマー組成物の特性を示す。
Claims (19)
- R1、R2、およびR3が、C1~C8アルキル基からなる群から独立して選択される、請求項1に記載の化合物。
- R1、R2、およびR3のうちの少なくとも1つが、分枝アルキル基である、請求項1または請求項2に記載の化合物。
- R1、R2、およびR3のうちの少なくとも2つが、分枝アルキル基である、請求項3に記載の化合物。
- R2およびR3が、分枝アルキル基である、請求項4に記載の化合物。
- R1、R2、およびR3の各々が、分枝アルキル基である、請求項4に記載の化合物。
- 前記化合物が、
N-(4-イソプロピルシクロヘキシル)-3,5-ビス-[4-イソプロピルシクロヘキシルカルボニルアミノ]-ベンズアミド;
N-(4-イソプロピルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
N-(4-n-プロピルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
N-(4-n-ブチルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
N-(4-tert-ブチルシクロヘキシル)-3,5-ビス-[4-イソプロピルシクロヘキシルカルボニルアミノ]-ベンズアミド;
N-(4-tert-ブチルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
N-(4-tert-ペンチルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
N-(4-tert-ブチルシクロヘキシル)-3,5-ビス-[4-tert-ペンチルシクロヘキシルカルボニルアミノ]-ベンズアミド;
N-(4-tert-ペンチルシクロヘキシル)-3,5-ビス-[4-tert-ペンチルシクロヘキシルカルボニルアミノ]-ベンズアミド
およびこれらの混合物からなる群から選択される、請求項1に記載の化合物。 - 前記化合物が、N-(4-tert-ブチルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミドである、請求項6に記載の化合物。
- 前記化合物が、N-(4-tert-ブチルシクロヘキシル)-3,5-ビス-[4-tert-ペンチルシクロヘキシルカルボニルアミノ]-ベンズアミドである、請求項6に記載の化合物。
- 前記化合物が、N-(4-tert-ペンチルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミドである、請求項6に記載の化合物。
- 前記化合物が、N-(4-n-プロピルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミドである、請求項6に記載の化合物。
- 前記化合物が、N-(4-n-ブチルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミドである、請求項6に記載の化合物。
- 前記化合物が、N-(4-イソプロピルシクロヘキシル)-3,5-ビス-[4-tert-ブチルシクロヘキシルカルボニルアミノ]-ベンズアミドである、請求項6に記載の化合物。
- 前記化合物が、N-(4-tert-ブチルシクロヘキシル)-3,5-ビス-[4-イソプロピルシクロヘキシルカルボニルアミノ]-ベンズアミドである、請求項6に記載の化合物。
- (a)請求項1~14の何れか1項に記載の化合物と、
(b)ポリオレフィンポリマーと
を含むポリマー組成物。 - 前記ポリオレフィンポリマーが、ポリプロピレンポリマーである、請求項15に記載のポリマー組成物。
- 前記ポリオレフィンポリマーが、ポリプロピレンホモポリマー、ポリプロピレンランダムコポリマー、およびこれらの混合物からなる群から選択される、請求項16に記載のポリマー組成物。
- 前記ポリオレフィンポリマーが、ポリプロピレンランダムコポリマーである、請求項17に記載のポリマー組成物。
- 式(I)の前記化合物が、前記ポリマー組成物の総重量に対して約0.001重量%以上の量で前記組成物中に存在する、請求項15~18の何れか1項に記載のポリマー組成物。
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