JP2022512293A - 改善された付着のための毛髪コンディショニング組成物 - Google Patents
改善された付着のための毛髪コンディショニング組成物 Download PDFInfo
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- 150000003512 tertiary amines Chemical group 0.000 description 1
- YMBCJWGVCUEGHA-UHFFFAOYSA-M tetraethylammonium chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC YMBCJWGVCUEGHA-UHFFFAOYSA-M 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- AQZSPJRLCJSOED-UHFFFAOYSA-M trimethyl(octyl)azanium;chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(C)C AQZSPJRLCJSOED-UHFFFAOYSA-M 0.000 description 1
- 229940035936 ubiquinone Drugs 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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- A61K8/00—Cosmetics or similar toiletry preparations
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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Abstract
Description
(i)0.01~10重量%の直鎖状カチオン性コンディショニング界面活性剤と、
(ii)0.1~10重量%の直鎖状脂肪質と、
(iii)微粒子状有益剤と、
(iv)0.01~5重量%の、100%活性分枝状カチオン性補助界面活性剤であって、構造1:
・R1およびR2は直鎖状アルキル鎖であり、飽和または不飽和であり、炭素-炭素鎖の長さがC4~C20、好ましくはC6~C18、より好ましくはC8~C12、最も好ましくはC6~C10であり、
・nは0~10の範囲を有し、好ましくは0および1から選択され、
・mは1~6の範囲を有し、好ましくは1および2から選択され、
・R3はC1~C4、好ましくはC1~C2の炭素-炭素鎖の長さを有するアルキル鎖であり、
・R4はプロトンまたはC1~C4、好ましくはC1~C2の炭素-炭素鎖の長さを有するアルキル鎖であり、かつ
・Xは有機また無機アニオンである)、
から選択される分枝状カチオン性補助界面活性剤と、を含有する組成物であって、
分枝状カチオン性補助界面活性剤(iv)と直鎖状カチオン性界面活性剤(i)とのモル比が、1:20~1:1、好ましくは1:10~1:1、最も好ましくは1:5~1:2の範囲である、組成物が提供される。
コンディショナー組成物は、美容的に許容でき、毛髪への局所適用に適した直鎖状カチオン性コンディショニング界面活性剤を含有するものである。
N+(R1)(R2)(R3)(R4)、式中、R1、R2、R3およびR4は、独立して(C1~C30)アルキルまたはベンジルである、構造を有する。
(i)一般式(II):
R1CONH(CH2)mN(R2)R3(II)
に相当するアミドアミンであって、式中、R1は10つ以上の炭素原子を有するヒドロカルビル鎖であり、R2およびR3は独立して、炭素原子1~10つから選択されるヒドロカルビル鎖であり、mは1~約10の整数であるアミドアミン、および
(ii)酸、がある。
式中、R1は約11~約24つの炭素原子を有するヒドロカルビル残基であり、
R2およびR3は、それぞれ独立して1~約4つの炭素原子を有するヒドロカルビル残基、好ましくはアルキル基であり、mは1~約4の整数である化合物に相当するようなものである。
本発明の組成物は、0.1~10重量%の直鎖状脂肪質を含有する。
本発明の組成物は、微粒子状有益剤を含有する。微粒子状有益剤は、好ましくは、コンディショニング活性剤、頭皮活性剤、カプセル化芳香剤、乳化芳香剤およびこれらの混合物から選択される。より好ましくは、微粒子状有益剤は、コンディショニング活性剤、カプセル化芳香剤およびこれらの混合物から選択される。最も好ましくは、微粒子状有益剤は、シリコーンエマルジョンおよびカプセル化芳香剤から選択される。
本発明の組成物は、シリコーンコンディショニング剤の乳化液滴を含有し得る。
本発明の組成物は、分枝状カチオン性補助界面活性剤を含有する。
分枝状カチオン性補助界面活性剤は、構造1
・R1およびR2は直鎖状アルキル鎖であり、飽和または不飽和であり、炭素-炭素鎖の長さがC4~C20、好ましくはC6~C18、より好ましくはC8~C12、最も好ましくはC6~C10であり、
・nは0~10の範囲を有し、
・mは1~6の範囲を有し、
・R3はC1~C4、好ましくはC1~C2の炭素-炭素鎖の長さを有するアルキル鎖であり、
・R4はプロトンまたはC1~C4、好ましくはC1~C2の炭素-炭素鎖の長さを有するアルキル鎖であり、かつ
・Xは有機または無機アニオンである、構造から選択され、
分枝状カチオン性補助界面活性剤(iv)と直鎖状カチオン性界面活性剤(i)とのモル比が、1:20~1:1、好ましくは1:10~1:1、最も好ましくは1:5~1:2の範囲である。
本発明の組成物は、良好な粘度特性および降伏応力特性を提供する。
i)0.4~8重量%の、8~22つの炭素原子を有する脂肪族アルコールと、
ii)0.1~2重量%のカチオン性界面活性剤と、を含有し、
組成物は、組成物で処理される毛髪に対して、1~250g、好ましくは2~100g、より好ましくは2~50g、さらにより好ましくは5~40g、最も好ましくは5~25gの引っ張り質量を与える。
本発明による組成物は、ヘアコンディショニング組成物に一般的に使用される、多数の成分のいずれかを含有してもよい。
1.界面活性剤および脂肪質(分枝状材料を含有)を好適な容器に添加し、80℃まで加熱する。
2.溶融ブレンドを、45~70℃の温度で、開示された組成物に従って好適な量の水に添加する。
3.混合物を、不透明および濃厚になるまで混合する。
4.続いて、加熱を止め、40℃未満に冷却し、残りの材料とともに残りの水を添加する。
5.最後に、配合物を、Silversonミキサーにて、5000rpmで5分間、高せん断力で混合する。
組成物Aおよび組成物1を用いた毛髪のトリートメント
使用した毛髪は、ダークブラウンの、ヨーロッパ人の毛髪を、重量5gおよび長さ6インチのヘアピースにしたものであった。
Claims (12)
- (i)0.01~10重量%の直鎖状カチオン性コンディショニング界面活性剤と、
(ii)0.1~10重量%の直鎖状脂肪質と、
(iii)微粒子状有益剤と、
(iv)0.01~5重量%の、100%活性分枝状カチオン性補助界面活性剤であって、構造1:
・R1およびR2は直鎖状アルキル鎖であり、飽和または不飽和であり、炭素-炭素鎖の長さがC4~C20、好ましくはC6~C18、より好ましくはC8~C12、最も好ましくはC6~C10であり、
・nは0~10の範囲を有し、好ましくは0および1から選択され、
・mは1~6の範囲を有し、好ましくは1および2から選択され、
・R3はC1~C4、好ましくはC1~C2の炭素-炭素鎖の長さを有するアルキル鎖であり、
・R4はプロトンまたはC1~C4、好ましくはC1~C2の炭素-炭素鎖の長さを有するアルキル鎖であり、かつ
・Xは有機また無機アニオンである)
から選択される分枝状カチオン性補助界面活性剤と、
を含有する組成物であって、
分枝状カチオン性補助界面活性剤(iv)と直鎖状カチオン性界面活性剤(i)とのモル比が、1:20~1:1、好ましくは1:10~1:1、最も好ましくは1:5~1:2の範囲である、組成物。 - 前記直鎖状カチオン性コンディショニング界面活性剤が、
式1:N+(R1)(R2)(R3)(R4)
(式中、R1、R2、R3およびR4は、独立してC1~C30アルキルまたはベンジルである)を有する、請求項1に記載の組成物。 - 前記直鎖状カチオン性コンディショニング界面活性剤が、ベヘニルトリメチルアンモニウムクロリド、ベヘントリモニウムメトサルフェート、セチルトリメチルアンモニウムクロリドおよびこれらの混合物から選択される、請求項2に記載の組成物。
- 一般式(II):
R1CONH(CH2)mN(R2)R3(II)
(式中、R1は10以上の炭素原子を有するヒドロカルビル鎖であり、
R2およびR3は、独立して、炭素原子1~10つのヒドロカルビル鎖から選択され、
mは1~10の整数である)に相当するアミドアミンと、酸とを含有する、請求項1から3のいずれかに記載の組成物。 - 前記分枝状カチオン性補助界面活性剤が、0.1重量%~1重量%、最も好ましくは0.1重量%~0.5重量%の量で存在する、請求項1から4のいずれかに記載の組成物。
- 分枝状カチオン性補助界面活性剤(iv)と直鎖状カチオン性界面活性剤(i)との前記モル比が、1:10~1:1、好ましくは1:5~1:2の範囲である、請求項1から5のいずれかに記載の組成物。
- 前記微粒子状有益剤が、コンディショニング活性剤、頭皮活性剤、カプセル化芳香剤、乳化芳香剤およびその混合物から選択される、請求項1から6のいずれかに記載の組成物。
- 前記微粒子状有益剤が、シリコーンである、請求項7に記載の組成物。
- 前記シリコーンが、全組成物の0.1重量%~10重量%、より好ましくは0.1重量%~5重量%、最も好ましくは0.25重量%~3重量%の量で存在する、請求項8に記載の組成物。
- 25℃および1Hzで、30~200パスカル(Pa)、最も好ましくは40~150Paのピーク値の範囲の降伏応力を有する、請求項1から9のいずれかに記載の組成物。
- X-が、ハロゲン化物、メタンスルホナート基およびエタンスルホナート基から選択されるアニオンである、請求項1から10のいずれかに記載の組成物。
- 構造1による分枝状カチオン性補助界面活性剤なしの同一の組成物と比較して、毛髪への微粒子状有益剤の付着を増大させる方法であって、
請求項1~11のいずれかに記載の組成物を毛髪に適用する工程と、
前記毛髪を水ですすぐ工程
とを含む、方法。
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JP2015522638A (ja) * | 2012-07-27 | 2015-08-06 | ユニリーバー・ナームローゼ・ベンノートシヤープ | 組成物 |
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