JP2022508094A - 特定の超分岐コポリマー及び有機uvフィルターを含む化粧品組成物 - Google Patents
特定の超分岐コポリマー及び有機uvフィルターを含む化粧品組成物 Download PDFInfo
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- JP2022508094A JP2022508094A JP2021525598A JP2021525598A JP2022508094A JP 2022508094 A JP2022508094 A JP 2022508094A JP 2021525598 A JP2021525598 A JP 2021525598A JP 2021525598 A JP2021525598 A JP 2021525598A JP 2022508094 A JP2022508094 A JP 2022508094A
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- NUCJYHHDSCEKQN-UHFFFAOYSA-M dimethyl-bis(2-octadecanoyloxyethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC(=O)OCC[N+](C)(C)CCOC(=O)CCCCCCCCCCCCCCCCC NUCJYHHDSCEKQN-UHFFFAOYSA-M 0.000 description 1
- PKPOVTYZGGYDIJ-UHFFFAOYSA-N dioctyl carbonate Chemical compound CCCCCCCCOC(=O)OCCCCCCCC PKPOVTYZGGYDIJ-UHFFFAOYSA-N 0.000 description 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
- 229940030620 distearoylethyl hydroxyethylmonium methosulfate Drugs 0.000 description 1
- HYXKNSUXBZRZIC-UHFFFAOYSA-N dodecyl(dimethyl)azanium;16-methylheptadecanoate Chemical compound CCCCCCCCCCCCN(C)C.CC(C)CCCCCCCCCCCCCCC(O)=O HYXKNSUXBZRZIC-UHFFFAOYSA-N 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- IAJNXBNRYMEYAZ-UHFFFAOYSA-N ethyl 2-cyano-3,3-diphenylprop-2-enoate Chemical compound C=1C=CC=CC=1C(=C(C#N)C(=O)OCC)C1=CC=CC=C1 IAJNXBNRYMEYAZ-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 210000004709 eyebrow Anatomy 0.000 description 1
- 210000000720 eyelash Anatomy 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229940068517 fruit extracts Drugs 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229940095098 glycol oleate Drugs 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 229920006007 hydrogenated polyisobutylene Polymers 0.000 description 1
- 229920000587 hyperbranched polymer Polymers 0.000 description 1
- XALUTBJODRQPLW-UHFFFAOYSA-N icosacyclo[76.4.0.03,76.05,74.07,72.09,70.011,68.013,66.015,64.017,62.019,60.021,58.023,56.025,54.027,52.029,50.031,48.033,46.035,44.037,42]dooctaconta-1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31,33,35,37,39,41,43,45,47,49,51,53,55,57,59,61,63,65,67,69,71,73,75,77,79,81-hentetracontaene Chemical compound C1=CC=CC2=CC3=CC4=CC5=CC6=CC7=CC8=CC9=CC%10=CC%11=CC%12=CC%13=CC%14=CC%15=CC%16=CC%17=CC%18=CC%19=CC%20=CC=CC=C%20C=C%19C=C%18C=C%17C=C%16C=C%15C=C%14C=C%13C=C%12C=C%11C=C%10C=C9C=C8C=C7C=C6C=C5C=C4C=C3C=C21 XALUTBJODRQPLW-UHFFFAOYSA-N 0.000 description 1
- KUVMKLCGXIYSNH-UHFFFAOYSA-N isopentadecane Natural products CCCCCCCCCCCCC(C)C KUVMKLCGXIYSNH-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- CWILBLFCNWVURT-UHFFFAOYSA-N n,n-diethylethanamine;octadecanamide Chemical compound CCN(CC)CC.CCCCCCCCCCCCCCCCCC(N)=O CWILBLFCNWVURT-UHFFFAOYSA-N 0.000 description 1
- 210000000282 nail Anatomy 0.000 description 1
- 125000005487 naphthalate group Chemical group 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- WUVYPLAYXXCICD-UHFFFAOYSA-N octanoyloxycarbonyl octanoate Chemical compound CCCCCCCC(=O)OC(=O)OC(=O)CCCCCCC WUVYPLAYXXCICD-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- 230000008845 photoaging Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003902 salicylic acid esters Chemical class 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 229940079776 sodium cocoyl isethionate Drugs 0.000 description 1
- 229940045898 sodium stearoyl glutamate Drugs 0.000 description 1
- 235000010956 sodium stearoyl-2-lactylate Nutrition 0.000 description 1
- KDHFCTLPQJQDQI-BDQAORGHSA-M sodium;(4s)-4-amino-5-octadecanoyloxy-5-oxopentanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC([O-])=O KDHFCTLPQJQDQI-BDQAORGHSA-M 0.000 description 1
- KNYAZNABVSEZDS-UHFFFAOYSA-M sodium;2-octadecanoyloxypropanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)OC(C)C([O-])=O KNYAZNABVSEZDS-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 229940057981 stearalkonium chloride Drugs 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/88—Polyamides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
- A61K2800/522—Antioxidants; Radical scavengers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/544—Dendrimers, Hyperbranched polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/591—Mixtures of compounds not provided for by any of the codes A61K2800/592 - A61K2800/596
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Polyamides (AREA)
Abstract
Description
本発明は、化粧品分野、特にサンケアの分野に関する。
化粧品分野において、化粧品組成物、すなわち配合物の詳細は、手触り、感触及び視覚の態様に非常に影響されやすい。
したがって、表面が接触する時の表面から表面への化粧品組成物のそのような移動を減少させることが非常に望ましい。
第1の態様において、本発明は、
モノマー
(i)ドデセニルコハク酸無水物
(ii)ジイソプロパノールアミン
(iii)式
の末端基を有するビスジメチルアミノプロピルアミン
の、1200~4000g/molの分子量Mnを有する超分岐コポリマーと、
少なくとも1つの液体有機UVフィルター及び/又は少なくとも1つの固体有機UVフィルターと
を含む化粧品組成物に関する。
a1)モノマー(i)及びモノマー(ii)及びモノマー(iii)を重合させて、次式
の末端ジメチルアミノ基を有するポリエステルアミドを得ること
a2)2-クロロアセテート、特に2-クロロ酢酸ナトリウムによるステップa1)のポリエステルアミドのジメチルアミノ基の四級化。
(i)ドデセニルコハク酸無水物
(ii)ジイソプロパノールアミン
(iii)式
の末端基を有するビスジメチルアミノプロピルアミン
の、1200~4000g/molの分子量Mnを有する超分岐コポリマーの量は、
典型的に、化粧品組成物の全重量に基づき、0.1~3重量%である。
ビスエチルヘキシルオキシフェノールメトキシフェニルトリアジン、ブチルメトキシジベンゾイルメタン、メチレンビスベンゾトリアゾリルテトラメチルブチルフェノール及びジエチルアミノヒドロキシベンゾイルヘキシルベンゾエートからなる群から選択される少なくとも1つの固体有機UV(A)フィルター、
及び
エチルヘキシルメトキシシンナメート、オクトクリレン、ホモサレート、エチルヘキシルサリチラート及びベンゾフェノン-3、ドロメトリゾールトリシロキサンからなる群から選択される少なくとも1つの液体有機UV(B)フィルター
の組合せが特に好ましい。
(i)ドデセニルコハク酸無水物
(ii)ジイソプロパノールアミン
(iii)式
の末端基を有するビスジメチルアミノプロピルアミン
の、1200~4000g/molの分子量Mnを有する特定の超分岐コポリマーが使用される場合、化粧品組成物は、接触表面への材料移動の強い減少を有することが見出された。
(i)ドデセニルコハク酸無水物
(ii)ジイソプロパノールアミン
(iii)式
の末端基を有するビスジメチルアミノプロピルアミン
の、1200~4000g/molの分子量Mnを有する超分岐コポリマーの使用である。
以下の実験によって本発明をさらに例示する。これらの実施例は実例となり、いずれかの様式に本発明の範囲を制限するように意図されない。
欧州特許第2794729B1号明細書の実施例3に従って、237.59gのN,N-ビス(N’N’-ジメチルアミノプロピル)アミン及び112.6gのジイソプロパノールアミン及び426.89gのドデセニルコハク酸無水物を使用して、モノマードデセニルコハク酸無水物及びジイソプロパノールアミン及びビスジメチルアミノプロピルアミンの超分岐コポリマーHBC1を調製した。加熱及び減圧後、0.3meq/g未満の残留カルボン酸含有量(滴定分析)、AV=9.8mg KOH/g及び2.99meq/gのアミン含有量(滴定分析)、並びに分子量Mn=2240が得られた。1H-NMR分析によってクロロ酢酸塩の完全な変換が示されるまで、この生成物を水中でクロロ酢酸ナトリウムと反応させ、80℃で撹拌し、次式
の末端基を有し、2.3kDaの分子量Mnを有する超分岐コポリマーHBC1を得た。
材料移動は、以下に概説されるスポンジ試験によって決定した。
-スポンジクロス(Weita AGからのWeitawip Claire:セルロース/綿繊維混合物、200g/m2、厚さ5mm)を76mm×26mmに切断する。
-スポンジ試料の風袋を測定する。
-それぞれの試料(=化粧品組成物)350mgを適用して、76mm×26mmのスポンジ表面上に均一に分布させる。
-試料が適用されたスポンジの重量を測定する。
-顕微鏡スライド(ガラスプレート76mm×26mm×1mm)の風袋を測定する。
-特定の圧力を試料に適用するために500gのバランス重量(高さ:6.3cm、接触領域の直径:3.7cm)がその上に10秒間配置されたスポンジ上に顕微鏡スライド(ガラスプレート)を配置する。
-慎重に顕微鏡スライドを垂直に取り除く。
-取り除かれた顕微鏡スライドの重量を測定し、したがって、ガラスプレートに移動した試料の量を測定する。
-それぞれの試料の平均値を得るために、それぞれの組成物に対して10回試験を繰り返す。
表1による油相の成分(重量部)を組み合わせて、85℃まで加熱した。表1による水相の成分(重量部)を組み合わせ、そしてキサンタンガムが完全に溶解するまで撹拌し、次いで80℃まで加熱した。2つの相を組み合わせて、10’000rpmで1分間、均質化させた。穏やかな撹拌下、エマルジョンを35℃まで冷却する。実施例において超分岐コポリマーが使用される場合、この時点でそれぞれの超分岐ポリマー(重量部)を撹拌下のエマルジョンに添加する。エマルジョンが室温に到達するまで、撹拌を続けた。それぞれの組成物が70グラムの全重量を有するように、使用される組成物の成分の量(100重量%まで合計する)が選択される。
Claims (17)
- 前記モノマー(i)対モノマー(ii)のモル比が、5:1~0.5:1、特に4:1~1:1、好ましくは3:1~3:2であることを特徴とする、請求項1~2のいずれか一項に記載の化粧品組成物。
- 前記モノマー(i)対モノマー(iii)のモル比が、5:1~0.5:1、特に3:1~1:1、好ましくは2.5:1~1.1:1であることを特徴とする、請求項1~3のいずれか一項に記載の化粧品組成物。
- 前記超分岐コポリマーが、1400~3000g/mol、好ましくは2100~2300g/molの数平均分子量Mnを有することを特徴とする、請求項1~4のいずれか一項に記載の化粧品組成物。
- 前記超分岐コポリマーがポリクオタニウム-110であることを特徴とする、請求項1~5のいずれか一項に記載の化粧品組成物。
- 固体有機UVフィルター、特に固体有機UV(A)フィルターの量が、0.1~約6重量%の範囲、好ましくは0.5~5重量%、最も好ましくは1~4重量%の範囲で選択されることを特徴とする、請求項1~6のいずれか一項に記載の化粧品組成物。
- 固体有機UVフィルター、特に固体有機UV(B)フィルターの量が、0.1~約6重量%の範囲、好ましくは0.5~5重量%、最も好ましくは1~4重量%の範囲で選択されることを特徴とする、請求項1~7のいずれか一項に記載の化粧品組成物。
- 液体有機UVフィルター、特に液体有機UV(B)フィルターの量が、0.1~約10重量%の範囲、好ましくは0.5~8重量%、最も好ましくは1~6重量%の範囲で選択されることを特徴とする、請求項1~8のいずれか一項に記載の化粧品組成物。
- 前記組成物が、少なくとも1つが固体又は液体有機UV(A)フィルターであり、少なくとも1つが固体又は液体有機UV(B)フィルターである、少なくとも2つのUVフィルターを含むことを特徴とする、請求項1~9のいずれか一項に記載の化粧品組成物。
- 前記組成物が、少なくとも1つが固体又は液体有機UV(A)フィルターであり、少なくとも1つが固体又は液体有機UV(B)フィルターである、少なくとも2つの有機UVフィルターを含み、
特に、
少なくとも1つの固体有機UV(A)フィルターと少なくとも1つの液体有機UV(B)フィルターとの組合せを含み、
より特に、
ビスエチルヘキシルオキシフェノールメトキシフェニルトリアジン、ブチルメトキシジベンゾイルメタン、メチレンビスベンゾトリアゾリルテトラメチルブチルフェノール及びジエチルアミノヒドロキシベンゾイルヘキシルベンゾエートからなる群から選択される少なくとも1つの固体有機UV(A)フィルター、
及び
エチルヘキシルメトキシシンナメート、オクトクリレン、ホモサレート、エチルヘキシルサリチラート及びベンゾフェノン-3、ドロメトリゾールトリシロキサンからなる群から選択される少なくとも1つの液体有機UV(B)フィルター
の組合せを含むことを特徴とする、請求項10に記載の化粧品組成物。 - 前記化粧品組成物が、スキンケア組成物、好ましくはサンケア組成物であることを特徴とする、請求項1~11のいずれか一項に記載の化粧品組成物。
- 前記組成物が、スルフェートを含まない化粧品組成物であることを特徴とする、請求項1~12のいずれか一項に記載の化粧品組成物。
- 前記組成物が、カチオン乳化剤を含まないことを特徴とする、請求項1~13のいずれか一項に記載の化粧品組成物。
- 前記接触表面がガラス表面であることを特徴とする、請求項15に記載の使用。
- 前記接触表面が、携帯電話、コンピュータデバイス又はタブレットのディスプレーであることを特徴とする、請求項15又は16に記載の使用。
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PCT/EP2019/082490 WO2020109263A1 (en) | 2018-11-26 | 2019-11-26 | Cosmetic composition comprising specific hyperbranched copolymers and organic uv filters |
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AU (1) | AU2019388178A1 (ja) |
BR (1) | BR112021009886A2 (ja) |
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JP2015529674A (ja) * | 2012-09-17 | 2015-10-08 | ディーエスエム アイピー アセッツ ビー.ブイ. | ヘアケアポリマー |
WO2017174214A1 (en) * | 2016-04-07 | 2017-10-12 | The Boots Company Plc | Polymer-containing composition and method thereof |
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US5192534A (en) * | 1988-12-30 | 1993-03-09 | L'oreal | Composition for inducing and stimulating hair growth and/or retarding its loss, based on pyrimidine derivatives and sunscreens |
JP5403361B2 (ja) * | 2006-06-16 | 2014-01-29 | ディーエスエム アイピー アセッツ ビー.ブイ. | 超分岐縮合ポリマーに基づく組成物および新規超分岐縮合ポリマー |
WO2013092800A1 (en) | 2011-12-20 | 2013-06-27 | Dsm Ip Assets B.V. | Hyperbranched polymers |
EP2883533B1 (en) * | 2013-12-13 | 2018-08-22 | Kao Germany GmbH | Hair conditioner composition |
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- 2019-11-26 CN CN201980076840.7A patent/CN113164373A/zh active Pending
- 2019-11-26 WO PCT/EP2019/082490 patent/WO2020109263A1/en unknown
- 2019-11-26 EP EP19805994.1A patent/EP3886803B1/en active Active
- 2019-11-26 BR BR112021009886-0A patent/BR112021009886A2/pt not_active Application Discontinuation
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- 2019-11-26 JP JP2021525598A patent/JP7436109B2/ja active Active
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WO2006013200A1 (en) * | 2004-08-02 | 2006-02-09 | L'oreal | Cosmetic care and/or makeup composition comprising at least one polyesteramide polymer |
JP2011524883A (ja) * | 2008-06-19 | 2011-09-08 | ディーエスエム アイピー アセッツ ビー.ブイ. | シャンプー製剤 |
JP2015529737A (ja) * | 2012-09-17 | 2015-10-08 | ディーエスエム アイピー アセッツ ビー.ブイ. | ヘアケアポリマー |
JP2015529674A (ja) * | 2012-09-17 | 2015-10-08 | ディーエスエム アイピー アセッツ ビー.ブイ. | ヘアケアポリマー |
WO2017174214A1 (en) * | 2016-04-07 | 2017-10-12 | The Boots Company Plc | Polymer-containing composition and method thereof |
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EP3886803A1 (en) | 2021-10-06 |
EP3886803B1 (en) | 2023-08-09 |
ES2962131T3 (es) | 2024-03-15 |
AU2019388178A1 (en) | 2021-05-27 |
CN113164373A (zh) | 2021-07-23 |
JP7436109B2 (ja) | 2024-02-21 |
US20220023190A1 (en) | 2022-01-27 |
BR112021009886A2 (pt) | 2021-08-17 |
WO2020109263A1 (en) | 2020-06-04 |
KR20210096148A (ko) | 2021-08-04 |
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