JP2021507980A - カプロラクタムモノマーを含む特定のコポリアミド、半結晶性ポリアミド及び補強充填剤を含む、光沢性能を強化したポリアミド組成物 - Google Patents
カプロラクタムモノマーを含む特定のコポリアミド、半結晶性ポリアミド及び補強充填剤を含む、光沢性能を強化したポリアミド組成物 Download PDFInfo
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- JP2021507980A JP2021507980A JP2020554583A JP2020554583A JP2021507980A JP 2021507980 A JP2021507980 A JP 2021507980A JP 2020554583 A JP2020554583 A JP 2020554583A JP 2020554583 A JP2020554583 A JP 2020554583A JP 2021507980 A JP2021507980 A JP 2021507980A
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- polyamide
- mass
- copolyamide
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- acid
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- 239000000203 mixture Substances 0.000 title claims abstract description 97
- 229920006114 semi-crystalline semi-aromatic polyamide Polymers 0.000 title claims abstract description 19
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 239000012763 reinforcing filler Substances 0.000 title claims abstract description 14
- 239000004952 Polyamide Substances 0.000 title claims description 53
- 229920002647 polyamide Polymers 0.000 title claims description 53
- 239000000178 monomer Substances 0.000 title claims description 6
- -1 alicyclic diamine Chemical class 0.000 claims abstract description 19
- 125000003118 aryl group Chemical group 0.000 claims abstract description 16
- 150000001413 amino acids Chemical class 0.000 claims abstract description 10
- 238000002844 melting Methods 0.000 claims abstract description 9
- 230000008018 melting Effects 0.000 claims abstract description 9
- 239000003063 flame retardant Substances 0.000 claims description 17
- 229920006020 amorphous polyamide Polymers 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 239000000654 additive Substances 0.000 claims description 12
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 10
- 238000001746 injection moulding Methods 0.000 claims description 10
- 229920002292 Nylon 6 Polymers 0.000 claims description 9
- 239000003365 glass fiber Substances 0.000 claims description 8
- 229920006131 poly(hexamethylene isophthalamide-co-terephthalamide) Polymers 0.000 claims description 8
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 6
- IGSBHTZEJMPDSZ-UHFFFAOYSA-N 4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine Chemical compound C1CC(N)C(C)CC1CC1CC(C)C(N)CC1 IGSBHTZEJMPDSZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 230000003796 beauty Effects 0.000 claims description 4
- 238000002425 crystallisation Methods 0.000 claims description 4
- 230000008025 crystallization Effects 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 229920000571 Nylon 11 Polymers 0.000 claims description 2
- 229920000299 Nylon 12 Polymers 0.000 claims description 2
- 229920001007 Nylon 4 Polymers 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 239000002216 antistatic agent Substances 0.000 claims description 2
- 239000011324 bead Substances 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- 239000012760 heat stabilizer Substances 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004611 light stabiliser Substances 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000002667 nucleating agent Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 239000004014 plasticizer Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 claims description 2
- 239000012209 synthetic fiber Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- 239000002023 wood Substances 0.000 claims description 2
- 229920000572 Nylon 6/12 Polymers 0.000 claims 1
- 239000011152 fibreglass Substances 0.000 claims 1
- 238000010586 diagram Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 20
- 238000006068 polycondensation reaction Methods 0.000 description 15
- 229920000877 Melamine resin Polymers 0.000 description 14
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 14
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 9
- 229920000388 Polyphosphate Polymers 0.000 description 8
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 8
- 239000001205 polyphosphate Substances 0.000 description 8
- 235000011176 polyphosphates Nutrition 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 6
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 5
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 5
- 229910052794 bromium Inorganic materials 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 description 4
- QNVNLUSHGRBCLO-UHFFFAOYSA-N 5-hydroxybenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC(O)=CC(C(O)=O)=C1 QNVNLUSHGRBCLO-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 4
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 4
- 229960002255 azelaic acid Drugs 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 3
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- GRKDVZMVHOLESV-UHFFFAOYSA-N (2,3,4,5,6-pentabromophenyl)methyl prop-2-enoate Chemical compound BrC1=C(Br)C(Br)=C(COC(=O)C=C)C(Br)=C1Br GRKDVZMVHOLESV-UHFFFAOYSA-N 0.000 description 2
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 description 2
- ORYGKUIDIMIRNN-UHFFFAOYSA-N 1,2,3,4-tetrabromo-5-(2,3,4,5-tetrabromophenoxy)benzene Chemical compound BrC1=C(Br)C(Br)=CC(OC=2C(=C(Br)C(Br)=C(Br)C=2)Br)=C1Br ORYGKUIDIMIRNN-UHFFFAOYSA-N 0.000 description 2
- XAUQWYHSQICPAZ-UHFFFAOYSA-N 10-amino-decanoic acid Chemical compound NCCCCCCCCCC(O)=O XAUQWYHSQICPAZ-UHFFFAOYSA-N 0.000 description 2
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 2
- PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 description 2
- FTVFPPFZRRKJIH-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CC1(C)CC(N)CC(C)(C)N1 FTVFPPFZRRKJIH-UHFFFAOYSA-N 0.000 description 2
- BDFBPPCACYFGFA-UHFFFAOYSA-N 2,4,6-tris(2,4,6-tribromophenoxy)-1,3,5-triazine Chemical class BrC1=CC(Br)=CC(Br)=C1OC1=NC(OC=2C(=CC(Br)=CC=2Br)Br)=NC(OC=2C(=CC(Br)=CC=2Br)Br)=N1 BDFBPPCACYFGFA-UHFFFAOYSA-N 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 2
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 2
- CARJPEPCULYFFP-UHFFFAOYSA-N 5-Sulfo-1,3-benzenedicarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(S(O)(=O)=O)=C1 CARJPEPCULYFFP-UHFFFAOYSA-N 0.000 description 2
- KBZFDRWPMZESDI-UHFFFAOYSA-N 5-aminobenzene-1,3-dicarboxylic acid Chemical compound NC1=CC(C(O)=O)=CC(C(O)=O)=C1 KBZFDRWPMZESDI-UHFFFAOYSA-N 0.000 description 2
- JJMDCOVWQOJGCB-UHFFFAOYSA-N 5-aminopentanoic acid Chemical compound [NH3+]CCCCC([O-])=O JJMDCOVWQOJGCB-UHFFFAOYSA-N 0.000 description 2
- VWPQCOZMXULHDM-UHFFFAOYSA-N 9-aminononanoic acid Chemical compound NCCCCCCCCC(O)=O VWPQCOZMXULHDM-UHFFFAOYSA-N 0.000 description 2
- 241000219112 Cucumis Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical group [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
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- 125000001931 aliphatic group Chemical group 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 description 2
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- 238000005452 bending Methods 0.000 description 2
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- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- SSJXIUAHEKJCMH-UHFFFAOYSA-N cyclohexane-1,2-diamine Chemical compound NC1CCCCC1N SSJXIUAHEKJCMH-UHFFFAOYSA-N 0.000 description 2
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- UGQQAJOWXNCOPY-UHFFFAOYSA-N dechlorane plus Chemical compound C12CCC3C(C4(Cl)Cl)(Cl)C(Cl)=C(Cl)C4(Cl)C3CCC2C2(Cl)C(Cl)=C(Cl)C1(Cl)C2(Cl)Cl UGQQAJOWXNCOPY-UHFFFAOYSA-N 0.000 description 2
- KTLIMPGQZDZPSB-UHFFFAOYSA-N diethylphosphinic acid Chemical compound CCP(O)(=O)CC KTLIMPGQZDZPSB-UHFFFAOYSA-N 0.000 description 2
- GOJNABIZVJCYFL-UHFFFAOYSA-N dimethylphosphinic acid Chemical compound CP(C)(O)=O GOJNABIZVJCYFL-UHFFFAOYSA-N 0.000 description 2
- GWZCCUDJHOGOSO-UHFFFAOYSA-N diphenic acid Chemical compound OC(=O)C1=CC=CC=C1C1=CC=CC=C1C(O)=O GWZCCUDJHOGOSO-UHFFFAOYSA-N 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 description 2
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
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- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- HRRDCWDFRIJIQZ-UHFFFAOYSA-N naphthalene-1,8-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(C(=O)O)=CC=CC2=C1 HRRDCWDFRIJIQZ-UHFFFAOYSA-N 0.000 description 2
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- BNJOQKFENDDGSC-UHFFFAOYSA-N octadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCC(O)=O BNJOQKFENDDGSC-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 2
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 description 2
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
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- 239000001294 propane Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- LWBHHRRTOZQPDM-UHFFFAOYSA-N undecanedioic acid Chemical compound OC(=O)CCCCCCCCCC(O)=O LWBHHRRTOZQPDM-UHFFFAOYSA-N 0.000 description 2
- 150000003751 zinc Chemical class 0.000 description 2
- YMIUHIAWWDYGGU-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2,3,5,6-tetrabromo-4-(2,3,4,5,6-pentabromophenoxy)phenoxy]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC(C(=C1Br)Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br YMIUHIAWWDYGGU-UHFFFAOYSA-N 0.000 description 1
- FYADHXFMURLYQI-UHFFFAOYSA-N 1,2,4-triazine Chemical compound C1=CN=NC=N1 FYADHXFMURLYQI-UHFFFAOYSA-N 0.000 description 1
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 1
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 1
- VECYFPCPMVHUEN-UHFFFAOYSA-N 2,2-dimethylheptane-1,7-diamine Chemical compound NCC(C)(C)CCCCCN VECYFPCPMVHUEN-UHFFFAOYSA-N 0.000 description 1
- QPIDRHUVWIFOBW-UHFFFAOYSA-N 2,2-dimethylhexane-1,6-diamine Chemical compound NCC(C)(C)CCCCN QPIDRHUVWIFOBW-UHFFFAOYSA-N 0.000 description 1
- CRTFIUQMLDPORS-UHFFFAOYSA-N 2,2-dimethyloctane-1,8-diamine Chemical compound NCC(C)(C)CCCCCCN CRTFIUQMLDPORS-UHFFFAOYSA-N 0.000 description 1
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- 230000008447 perception Effects 0.000 description 1
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- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
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- 239000001384 succinic acid Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000011885 synergistic combination Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
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- FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
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- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/14—Chemical modification with acids, their salts or anhydrides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- B29K2509/00—Use of inorganic materials not provided for in groups B29K2503/00 - B29K2507/00, as filler
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Abstract
Description
本発明は、ポリアミド組成物であって、a)カプロラクタムモノマー又はこれに対応するアミノ酸、少なくとも1種の芳香族二酸コモノマー及び少なくとも1種の脂環式ジアミンコモノマーを含む少なくとも1種のコポリアミド;b)少なくとも1種の半結晶性ポリアミド;及びc)少なくとも1種の補強充填剤、任意で、d)少なくとも1種の非晶質ポリアミドを含み、a)少なくとも1種のコポリアミドの結晶化温度(Tc)が150℃以下であり、かつ、融解温度(Tm)とTcとの差が50℃以上である、ポリアミド組成物に関する。また、本発明は、そのようなポリアミド組成物を製造する方法に関する。
以下で、本発明に適切な技術的脈略を持たせ、本発明の利点がより完全に理解されるように、先行技術について議論を行う。しかし、本明細書を通して行う先行技術のいかなる議論も、かかる先行技術が、広く知られている、又は当該分野における共通の一般的知識の一部を形成するとの明示的又は黙示的な承認とみなされるべきではないことを理解されたい。
したがって、本発明の目的は、満足のいく機械的特性を維持しながら、優れた光沢性能及び良好な表面外観を発揮するポリアミド組成物を提供することである。
式(II):−NH−R2−NH−CO−R3−CO−
式中、
−R1は、現れるごとに互いに同一であるか又は異なり、1〜17個の炭素原子を有する二価の炭化水素基であり;
−R2は、現れるごとに互いに同一であるか又は異なり、1〜18個の炭素原子を有する二価の炭化水素基であり;
−R3は、現れるごとに互いに同一であるか又は異なり、1〜16個の炭素原子を有する二価の炭化水素基である。
(i)−NH−(CH2)5−CO−、すなわち、特に、ε−カプロラクタムの重縮合反応によって得ることができる繰り返し単位、
(ii)−NH−(CH2)8−CO−、すなわち、特に、9−アミノノナン酸の重縮合反応によって得ることができる繰り返し単位、
(iii)−NH−(CH2)9−CO−、すなわち、特に、10−アミノデカン酸の重縮合反応により得ることができる繰り返し単位、
(iv)−NH−(CH2)10−CO−、すなわち、特に、11−アミノウンデカン酸の重縮合反応により得ることができる繰り返し単位、
(v)−NH−(CH2)11−CO−、すなわち、特に、ラウロラクタムの重縮合反応により得ることができる繰り返し単位、
(vi)−NH−(CH2)6−NH−CO−(CH2)4−CO−、すなわち、特に、ヘキサメチレンジアミンとアジピン酸との重縮合反応により得ることができる繰り返し単位。
(vii)−NH−(CH2)6−NH−CO−(CH2)8−CO−、すなわち、特に、ヘキサメチレンジアミンとセバシン酸との重縮合反応により得ることができる繰り返し単位、
(viii)−NH−(CH2)6−NH−CO−(CH2)10−CO−、すなわち、特に、ヘキサメチレンジアミンとドデカン酸との重縮合反応により得ることができる繰り返し単位、
(ix)−NH−(CH2)10−NH−CO−(CH2)10−CO−、すなわち、特に、デカメチレンジアミンとドデカン酸との重縮合反応により得ることができる繰り返し単位、
(x)−NH−(CH2)6−NH−CO−(CH2)7−CO−、すなわち、特に、ヘキサメチレンジアミンとアゼライン酸(別名、ノナン二酸として知られている)との重縮合反応により得ることができる繰り返し単位、
(xi)−NH−(CH2)12−NH−CO−(CH2)10−CO−、すなわち、特に、ドデカメチレンジアミンとドデカン酸との重縮合反応により得ることができる繰り返し単位、
(xii)−NH−(CH2)10−NH−CO−(CH2)8−CO−、すなわち、特に、デカメチレンジアミンとデカン酸との重縮合反応により得ることができる繰り返し単位、
(xiii)−NH−(CH2)4−NH−CO−(CH2)4−CO−、すなわち、特に、1,4−ブタンジアミンとアジピン酸との重縮合反応により得ることができる繰り返し単位、及び
(xvi)−NH−(CH2)4−NH−CO−(CH2)8−CO−、すなわち、特に、1,4−ブタンジアミンとセバシン酸との重縮合反応により得ることができる繰り返し単位
を挙げることができる。
テレフタル酸とイソホロンジアミンの混合物をコモノマーとして含むコポリアミド6、及び
イソフタル酸とイソホロンジアミンの混合物をコモノマーとして含むコポリアミド6を挙げることができるが、これらに限定されるものではない。
− ホスフィンオキシド、例えば、トリフェニルホスフィンオキシド、トリス(3−ヒドロキシプロピル)ホスフィンオキシド、及びトリス(3−ヒドロキシ−2−メチルプロピル)ホスフィンオキシド;
− ホスホン酸若しくはその塩又はホスフィン酸若しくはその塩、例えば、ホスフィン酸の亜鉛塩、マグネシウム塩、カルシウム塩、アルミニウム塩又はマンガン塩、特に、ジエチルホスフィン酸のアルミニウム塩又はジメチルホスフィン酸の亜鉛塩;
− 環状二リン酸エステルなどの環状ホスホナート、例えば、Antiblaze 1045;
− トリフェニルホスファート、アンモニウムポリホスファート、メラミンポリホスファート及びナトリウムポリホスファートなどのホスファート;
− 赤リン、例えば、安定化された又はコーティングされた形態であるか、粉末であるか、又はマスターバッチの形態であるかを問わない;
*有機窒素化合物タイプの難燃剤、例えば、トリアジン、シアヌル酸及び/又はイソシアヌル酸、メラミン又はその誘導体、例えば、メラミンシアヌラート、メラミンオキサラート、フタラート、ボラート、スルファート、ホスファート、ポリホスファート及び/又はピロホスファート、メラミン縮合生成物、例えばメレム(melem)、メラム(melam)及びメロン(melon)など、トリ(ヒドロキシエチル)イソシアヌラート、ベンゾグアナミン、グアニジン、アラントイン及びグリコールウリル;
*ハロゲン化誘導体を含有する難燃剤、例えば:
− 臭素誘導体、例えば、PBDPO(ポリブロモジフェニルオキシド)、BrPS(ポリブロモスチレン及び臭素化ポリスチレン)、ポリ(ペンタブロモベンジルアクリレート)、臭素化インダン、テトラデカブロモジフェノキシベンゼン(Saytex 120)、1,2−ビス(ペンタブロモフェニル)エタンすなわちSaytex 8010(Albemarle社製)、テトラブロモビスフェノールA及び臭素化エポキシオリゴマー。特に、臭素化誘導体の中で、(Chemtura社製)PDBS−80などのポリジブロモスチレン、(Albemarle社製)Saytex HP 3010又は(Dead Sea Bromine Group社製)FR−803Pなどの臭素化ポリスチレン、デカブロモジフェニルエーテル(DBPE)すなわち(Dead Sea Bromine Group社製)FR−1210、オクタブロモジフェニルエーテル(OBPE)、2,4,6−トリス(2,4,6−トリブロモフェノキシ)−1,3,5−トリアジンすなわち(Dead Sea Bromine Group社製)FR−245、ポリ(ペンタブロモベンジルアクリレート)すなわち(Dead Sea Bromine Group社製)FR−1025、及び(Dead Sea Bromine Group社製)F−2300及びF2400などのテトラブロモビスフェノールAのエポキシ末端オリゴマー又はポリマーなどが挙げられる;
− 塩素化化合物、例えばDechlorane Plus(登録商標)(OxyChem社販売、CAS 13560−89−9参照)などの塩素化脂環式化合物
これらの化合物は、単独で又は組み合わせて、時には、相乗的方法で使用することができる。特に、ホスフィンオキシド、ホスホン酸若しくはその塩又はホスフィン酸若しくはその塩及び環状ホスホナートなどの、リン含有化合物と、メラム、メレム、メラミンホスファート、メラミンポリホスファート、メラミンピロホスファート又はアンモニウムポリホスファートなどの、窒素含有誘導体との相乗的組合せが好ましい。
[R1R2P(=O)−O]Z −MZ+
の化合物F1を含む本発明に係る組成物が特に好ましい。
上記式中、
− R1及びR2は、同一であるか又は異なって、1〜6個の炭素原子、好ましくは1〜3個の炭素原子を含む直鎖状又は分枝状のアルキル鎖、及び/又はアリール基を表す;
− Mは、カルシウムイオン、マグネシウムイオン、アルミニウムイオン及び/又は亜鉛イオン、好ましくはマグネシウムイオン及び/又はアルミニウムイオンを表す;
− Zは2又は3、好ましくは3を表す。
本発明の実施例1〜12(以下、Ex1〜12):
− Ex1〜6:ポリアミド6、ポリアミド6,6又はコポリアミド6,6/6T、PSB231、添加剤及び50.0質量%のガラス繊維の混合物
− Ex7〜12:Ex1〜6と同様であるが、難燃剤20.0質量%及びガラス繊維30.0質量%を含む。
− CE1〜4:ポリアミド6、ポリアミド6,6又はコポリアミド6,6/6T、添加剤、及び50.0質量%のガラス繊維の混合物
− CE5〜8:CE1〜4と同様であるが、難燃剤20.0質量%及びガラス繊維30.0質量%を含む。
− PSB231:テレフタル酸とイソホロンジアミンの混合物(Solvay社製)をコモノマーとして含むコポリアミド6
− ポリアミド6:TOFLON(登録商標)1011 BRT(Hyosung社から入手可能);
− ポリアミド6,6:STABAMID(登録商標)26AE1 K PA66(Solvay Polyamide & Intermediates社から入手可能);
− コポリアミド6,6/6T:STABAMID(登録商標)26UE1(Solvay Polyamide & Intermediates社から入手可能):
− コポリアミド6/6,6:NOVAMID(登録商標)2430A(DSMから入手可能);
− PA3426:非晶質コポリアミド6T/6I(DuPont de Nemour社からSelar PA3426として入手可能);
− ガラス繊維:289H(日本電気ガラス株式会社から入手可能);
− 難燃剤:EXOLIT(登録商標)OP1400(Clariant社から入手可能);
− 添加剤:着色剤、酸化防止剤など
調製した組成物を下記の表1〜3に詳述する。割合は、組成物中の質量パーセントで示す。
各成分を、重量フィーダを使用して二軸スクリュー押出機に供給した。このとき、必要に応じて、各成分を部分的に事前混合した。押出機内での加熱は、配合物中の最も高い温度で溶融するポリアミド成分の融点よりも高い温度か又は少なくとも等しい温度で行い、溶融ポリアミド樹脂コンパウンドを生成した。例えば、Ex1の組成物は、ポリアミド樹脂のペレットと添加剤を均一にプレミックスし、これを重量ホッパーからCoperion社製ZSK26二軸押出機に供給し、一方、押出機のサイドフィード領域4からガラス繊維を溶融ポリマーに供給して得た。押出温度は、ノズルからポリアミド66樹脂のホッパーまで280−280−280−280−280−280−280−280−280−270−260℃で、スループット及びスクリュー速度はそれぞれ、25kg/hr及び300RPMであった。次に、押出物を室温で水中冷却し、ペレット状に細断した。
溶融ポリアミドマトリックスを同様に製造した。当該ポリアミド、難燃剤、及び添加剤を一緒に混合してEx1で使用したのと同じ押出機のホッパーに入れ、一方、各サイドフィーダを用いて押出機のサイドフィード領域を介してガラス繊維を供給して、Ex7〜12の組成物を得た。押出条件は、Ex1の場合と同じとした。押出物は、同様に室温で水中冷却し、ペレットに細断した。
Claims (15)
- a)カプロラクタムモノマー又はこれに対応するアミノ酸、少なくとも1種の芳香族二酸コモノマー及び少なくとも1種の脂環式ジアミンコモノマーを含む少なくとも1種のコポリアミド;
b)少なくとも1種の半結晶性ポリアミド;
c)少なくとも1種の補強充填剤;及び
d)少なくとも1種の非晶質ポリアミド
を含み、
a)少なくとも1種のコポリアミドの結晶化温度(Tc)が150℃以下であり、かつ、融解温度(Tm)とTcとの差が50℃以上であることを特徴とするポリアミド組成物。 - さらにe)少なくとも1種の難燃剤を含む、請求項1に記載のポリアミド組成物。
- a)少なくとも1種のコポリアミドが、モノマー及びコモノマーの総モル数に基づいて、少なくとも75モル%のカプロラクタムモノマー又はこれに対応するアミノ酸を含む、請求項1又は2に記載のポリアミド組成物。
- b)少なくとも1種の半結晶性ポリアミドが、ポリアミド6、ポリアミド6,6、ポリアミド6,10、ポリアミド4,6、ポリアミド11、ポリアミド12、ポリアミド6,12、コポリアミド6,6/6T、コポリアミド6,10/6T、コポリアミド6,12/6T、コポリアミド12/6T、コポリアミド6/6T、及びそれらの任意の組合せからなる群から選択される、請求項1〜3のいずれか一項に記載のポリアミド組成物。
- c)少なくとも1種の補強充填剤が、ガラス繊維、ガラスビーズ、炭酸カルシウム、ケイ酸塩、タルク、カオリン、珪灰石、雲母、木粉、及びその他の天然物の粉末及び繊維、及び合成繊維からなる群から選択され、好ましくはガラス繊維である、請求項1〜4のいずれか一項に記載のポリアミド組成物。
- d)非晶質ポリアミドが、ポリアミド6I/6T、ポリアミド6I/10T、ビス−4−(アミノ−3−メチル−シクロヘキシル)−メタン(3,3’−ジメチル−4,4’−ジアミノジシクロヘキシルメタン)(MACM)、及びそれらの混合物及びコポリアミドからなる群から選択され、好ましくはポリアミド6I/6Tである、請求項1〜5のいずれか一項に記載のポリアミド組成物。
- さらに、着色剤、潤滑剤、光安定剤、熱安定剤、可塑剤、造核剤、界面活性剤、酸化防止剤、帯電防止剤、顔料、及びそれらの任意の組合せからなる群から選択される、f)少なくとも1種の添加剤を含む、請求項1〜6のいずれか一項に記載のポリアミド組成物。
- a)少なくとも1種のコポリアミドを、組成物の総質量に対して、2.0〜30.0質量%、好ましくは3.0〜20.0質量%、より好ましくは5.0〜15.0質量%の量で含む、請求項1〜7のいずれか一項に記載のポリアミド組成物。
- b)少なくとも1種の半結晶性ポリアミドを、組成物の総質量に対して、18.0〜83.0質量%、好ましくは40.0〜77.0質量%、より好ましくは50.0〜70.0質量%の量で含む、請求項1〜8のいずれか一項に記載のポリアミド組成物。
- c)少なくとも1種の補強充填剤を、組成物の総質量に対して、15.0〜70.0質量%、好ましくは20.0〜50.0質量%、より好ましくは25.0〜35.0質量%の量で含む、請求項1〜9のいずれか一項に記載のポリアミド組成物。
- d)少なくとも1種の非晶質ポリアミドを、組成物の総質量に対して、3.0〜20.0質量%、好ましくは3.0〜12.0質量%、より好ましくは4.0〜10.0質量%の量で含む、請求項1〜10のいずれか一項に記載のポリアミド組成物。
- a)少なくとも1種のコポリアミド、b)少なくとも1種の半結晶性ポリアミド、及びc)少なくとも1種の補強充填剤を溶融混合する工程を含むことを特徴とする請求項1〜11のいずれか一項に記載のポリアミド組成物を製造する方法。
- 請求項1〜11のいずれか一項に記載の組成物を射出成形又は押出成形することによって製造した成形部品。
- 自動車用途、産業機械及び電気製品・器具の、好ましくは、自動車サイドミラーベースプレート、審美的部品、携帯電話フレーム、エンジンビューティーカバー、ノートブックフレーム、回路ブレーカーケース、磁気スイッチ、接触器、電気及び電子デバイス用コネクターのハウジング又はハウジング部品を製造するための請求項13に記載の成形部品の使用。
- 請求項13に記載の成形部品を含むハウジング又はハウジング部品。
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WO (1) | WO2019122141A1 (ja) |
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JPH0255763A (ja) * | 1988-08-22 | 1990-02-26 | Unitika Ltd | ガラス繊維強化樹脂組成物 |
JP2014122321A (ja) * | 2012-12-21 | 2014-07-03 | Ems-Patent Ag | 耐汚染性物品およびその使用 |
JP2015120908A (ja) * | 2013-12-20 | 2015-07-02 | エーエムエス−パテント アクチェンゲゼルシャフト | プラスチック成形材料及びその使用 |
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DE3200428A1 (de) | 1982-01-09 | 1983-07-14 | Bayer Ag, 5090 Leverkusen | Polyamidformmassen |
JP2000186200A (ja) * | 1998-07-07 | 2000-07-04 | Unitika Ltd | ポリアミド樹脂組成物及びその製造法 |
DE4227428A1 (de) * | 1992-08-19 | 1994-02-24 | Bayer Ag | Hochschlagzäh-modifiziertes, verstärktes Polyamid 66 |
DE4430932A1 (de) | 1994-08-31 | 1996-03-07 | Hoechst Ag | Flammgeschützte Polyesterformmasse |
US6015510A (en) | 1996-08-29 | 2000-01-18 | E. I. Du Pont De Nemours And Company | Polymer flame retardant |
TW491843B (en) | 1997-03-04 | 2002-06-21 | Nissan Chemical Ind Ltd | 1,3,5-triazine derivative salts of polyacids comprising phosphorus, sulfur, and oxygen and process for producing the same |
US6025419A (en) | 1997-04-07 | 2000-02-15 | E. I. Du Pont De Nemours And Company | Flame retardant resin compositions |
DE19933901A1 (de) | 1999-07-22 | 2001-02-01 | Clariant Gmbh | Flammschutzmittel-Kombination |
EP2460858B1 (de) * | 2010-12-02 | 2014-01-22 | EMS-Patent AG | Polyamidformmassen auf Basis von Mischungen aus transparenten Copolyamiden und aliphatischen Homopolyamiden zur Herstellung von transparenten Formteilen |
JP6710637B2 (ja) * | 2013-11-13 | 2020-06-17 | パフォーマンス・ポリアミデス,エスアエス | ポリアミド組成物 |
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2018
- 2018-12-20 US US16/955,536 patent/US11401417B2/en active Active
- 2018-12-20 WO PCT/EP2018/086220 patent/WO2019122141A1/en unknown
- 2018-12-20 JP JP2020554583A patent/JP2021507980A/ja active Pending
- 2018-12-20 KR KR1020207021290A patent/KR20200094224A/ko active IP Right Grant
- 2018-12-20 EP EP18827084.7A patent/EP3728404A1/en not_active Withdrawn
- 2018-12-20 CN CN201880082540.5A patent/CN111630083B/zh active Active
Patent Citations (3)
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JPH0255763A (ja) * | 1988-08-22 | 1990-02-26 | Unitika Ltd | ガラス繊維強化樹脂組成物 |
JP2014122321A (ja) * | 2012-12-21 | 2014-07-03 | Ems-Patent Ag | 耐汚染性物品およびその使用 |
JP2015120908A (ja) * | 2013-12-20 | 2015-07-02 | エーエムエス−パテント アクチェンゲゼルシャフト | プラスチック成形材料及びその使用 |
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EP3728404A1 (en) | 2020-10-28 |
US20210079217A1 (en) | 2021-03-18 |
CN111630083A (zh) | 2020-09-04 |
BR112020011539A2 (pt) | 2020-11-17 |
US11401417B2 (en) | 2022-08-02 |
WO2019122141A1 (en) | 2019-06-27 |
KR20200094224A (ko) | 2020-08-06 |
CN111630083B (zh) | 2023-09-01 |
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