JP2021155361A - Fiber-containing cosmetic - Google Patents
Fiber-containing cosmetic Download PDFInfo
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- JP2021155361A JP2021155361A JP2020057304A JP2020057304A JP2021155361A JP 2021155361 A JP2021155361 A JP 2021155361A JP 2020057304 A JP2020057304 A JP 2020057304A JP 2020057304 A JP2020057304 A JP 2020057304A JP 2021155361 A JP2021155361 A JP 2021155361A
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- component
- cosmetic
- fibers
- fiber
- cosmetic according
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Abstract
Description
本発明は、疎水化処理された天然由来繊維を含有する化粧料に関する。 The present invention relates to cosmetics containing naturally derived fibers that have been hydrophobized.
化粧料には疑似毛髪としての効果や光学的な効果、使用感の調整を目的として、繊維が配合されることがある。 Fibers may be added to cosmetics for the purpose of adjusting the effect as pseudo-hair, the optical effect, and the feeling of use.
従来、これらの繊維にはその太さや長さ、機械的強度や撥水性等の物性の調整の容易さからナイロン繊維やポリオレフィン繊維など合成樹脂由来のものが多く使用されてきた。一方で、近年マイクロプラスチックによる海洋を中心とする環境への悪影響が懸念されており、化粧料に配合される繊維成分においても対応が必要となってきている。 Conventionally, many of these fibers derived from synthetic resins such as nylon fibers and polyolefin fibers have been used because of the ease of adjusting physical properties such as thickness and length, mechanical strength and water repellency. On the other hand, in recent years, there are concerns about the adverse effects of microplastics on the environment, especially in the ocean, and it is becoming necessary to take measures for the fiber components contained in cosmetics.
環境に配慮した繊維としては、例えばポリ乳酸等の生分解性を有する合成樹脂繊維をマスカラに配合する技術(例えば特許文献1)や、シルク繊維を用いるマスカラ技術(例えば特許文献2)や、固形樹脂繊維として、ウール繊維、レーヨン繊維、セルロース系繊維等を用いる整髪化粧料技術(例えば特許文献3)等が提案されている。 Examples of environment-friendly fibers include a technique for blending biodegradable synthetic resin fibers such as polylactic acid into mascara (for example, Patent Document 1), a mascara technique using silk fibers (for example, Patent Document 2), and solids. As the resin fiber, a hairdressing cosmetic technique (for example, Patent Document 3) using wool fiber, rayon fiber, cellulose fiber and the like has been proposed.
また、織物や服飾用途において、セルロース繊維の撥水加工技術として、イソシアネートとフッ素系樹脂を用いてセルロースにフッ素樹脂を架橋結合させる技術(例えば特許文献4)や、カルボキシル基又はスルホン基を有する化合物とイソシアネート系化合物及び非フッ素系撥水剤を用いる技術(例えば特許文献5)等が提案されている。 Further, in textiles and clothing applications, as a water-repellent processing technique for cellulose fibers, a technique for cross-linking a fluororesin to cellulose using isocyanate and a fluororesin (for example, Patent Document 4), and a compound having a carboxyl group or a sulfone group. And techniques using isocyanate compounds and non-fluoropolymer water repellents (for example, Patent Document 5) have been proposed.
しかしながら、例えば特許文献1に記載のポリ乳酸等の生分解性を有する合成樹脂繊維は、微生物を多量に含む堆肥中では生分解性が十分に高いものの、現在課題となっている海洋中での生分解性は十分とは言い切れない課題があった。また、特許文献2や3のような天然由来の繊維は、主な構造構成成分が糖類やアミノ酸等であるため、合成樹脂と比較して肌やケラチン繊維に対して親和性が高いものの、撥水性に劣っているものが多く、その結果、化粧料中での分散状態や仕上がり後の化粧持続性の点で課題があった。
また、例えば特許文献4や5のようなイソシアネート系化合物と撥水剤を用いる技術では、耐久性が強く撥水効果の高い繊維は得られるものの、撥水剤そのものがポリマー、またはポリマー化しやすく、生分解性を有さないため、環境への悪影響を与える恐れがあった。
However, for example, the biodegradable synthetic resin fiber such as polylactic acid described in Patent Document 1 has sufficiently high biodegradability in compost containing a large amount of microorganisms, but is currently a problem in the ocean. There was a problem that biodegradability was not sufficient. In addition, naturally-derived fibers such as Patent Documents 2 and 3 have higher affinity for skin and keratin fibers than synthetic resins because their main structural constituents are sugars and amino acids, but they are repellent. Many of them are inferior in water-based properties, and as a result, there are problems in terms of the dispersed state in cosmetics and the durability of makeup after finishing.
Further, in the technique using an isocyanate compound and a water repellent as in Patent Documents 4 and 5, for example, although fibers having high durability and high water repellent effect can be obtained, the water repellent itself is easily polymerized or polymerized. Since it is not biodegradable, it may have an adverse effect on the environment.
そこで、本発明は、マイクロプラスチックを含まない天然系の繊維を用いて、従来の合成樹脂繊維を用いたものと遜色のない化粧料を提供することを主な目的とする。 Therefore, it is a main object of the present invention to provide cosmetics that are comparable to those using conventional synthetic resin fibers by using natural fibers that do not contain microplastics.
本発明者は、鋭意検討の結果、特定の疎水性表面処理を施したセルロ−ス繊維やシルク繊維等の天然系繊維を配合することで、皮膚または毛髪に対し繊維の均一な付着性があり、化粧持続性に優れる化粧料が得られることを見出し、本発明を完成させた。 As a result of diligent studies, the present inventor has obtained uniform adhesion of fibers to the skin or hair by blending natural fibers such as cellulosic fibers and silk fibers that have been subjected to a specific hydrophobic surface treatment. The present invention has been completed by finding that a cosmetic having excellent long-lasting makeup can be obtained.
すなわち、本発明は
〔1〕 次の成分(A);
(A)(a1)疎水化処理剤 で表面処理された(a2)非プラスチック繊維を含有する化粧料。
〔2〕
前記成分(A)の平均長さが0.1mm〜4mmであり、平均太さが10μm〜50μmである前記〔1〕に記載の化粧料。
〔3〕
前記成分(a1)疎水化処理剤として、アルキルアルコキシシラン、脂肪酸及びその塩、金属石鹸、アシル化アミノ酸及びその塩、レシチンから選ばれる1種又は2種以上を含む前記〔1〕又は〔2〕に記載の化粧料。
〔4〕
前記成分(a2)非プラスチック繊維として、セルロース、レーヨン、アセテート、麻、コットン等の植物性繊維、シルク、ウール、蜘蛛糸等の動物性繊維から選ばれる1種又は2種以上を含む前記〔1〕〜〔3〕の何れか1つに記載の化粧料。
〔5〕
さらに成分(B)着色顔料として、酸化鉄、カーボンブラック、酸化チタン、黒酸化チタン、(チタン/酸化チタン)焼結物、グンジョウ、コンジョウ、マンガンバイオレット、カルミン、タール色素から選ばれる1種または2種以上を含有する〔1〕〜〔4〕の何れか1つに記載の化粧料。
〔6〕
前記成分(A)として、前記成分(B)着色顔料を表面吸着させた成分(a2)が成分(a1)で疎水化表面処理されたもの、および前記成分(a1)疎水化処理剤で表面処理された(B)着色顔料が(a2)に表面吸着されたものから選ばれる1種または2種以上を含有する前記〔1〕〜〔5〕の何れか1つに記載の化粧料。
〔7〕
化粧料がケラチン繊維用化粧料である前記〔1〕〜〔6〕の何れか1つに記載の化粧料。
〔8〕
さらに成分(C)植物系樹脂として、ロジン酸及びその誘導体、カルナウバロウエキス、およびキャンデリラロウエキスから選ばれる1種または2種以上を含む前記〔1〕〜〔7〕の何れか1つに記載の化粧料。
〔9〕
実質的に合成樹脂を含まない前記〔1〕〜〔8〕の何れか1つに記載の化粧料。
That is, the present invention [1] has the following component (A);
(A) A cosmetic containing (a2) non-plastic fibers surface-treated with a (a1) hydrophobizing agent.
[2]
The cosmetic according to the above [1], wherein the component (A) has an average length of 0.1 mm to 4 mm and an average thickness of 10 μm to 50 μm.
[3]
[1] or [2], which comprises one or more selected from alkylalkoxysilane, fatty acid and salt thereof, metal soap, acylated amino acid and salt thereof, and lecithin as the hydrophobizing agent for component (a1). Cosmetics listed in.
[4]
As the component (a2) non-plastic fiber, one or more selected from vegetable fibers such as cellulose, rayon, acetate, hemp and cotton, and animal fibers such as silk, wool and spider silk are included in the above [1]. ] To the cosmetic according to any one of [3].
[5]
Further, as the component (B) coloring pigment, one or 2 selected from iron oxide, carbon black, titanium oxide, black titanium oxide, (titanium / titanium oxide) sintered body, gunjo, konjo, manganese violet, carmine, and tar pigment. The cosmetic according to any one of [1] to [4] containing seeds or more.
[6]
As the component (A), the component (a2) on which the color pigment (B) is surface-adsorbed is surface-treated with the component (a1), and the component (a1) is surface-treated with the hydrophobic treatment agent. The cosmetic according to any one of the above [1] to [5], which contains one or more selected from those in which the colored pigment (B) is surface-adhered to (a2).
[7]
The cosmetic according to any one of the above [1] to [6], wherein the cosmetic is a cosmetic for keratin fibers.
[8]
Further, according to any one of the above [1] to [7], the component (C) plant-based resin contains one or more selected from rosin acid and its derivatives, carnauba wax extract, and candelilla wax extract. Cosmetics.
[9]
The cosmetic according to any one of the above [1] to [8], which does not substantially contain a synthetic resin.
本技術によれば、環境負荷のあるマイクロプラスチックを用いることなく、繊維が皮膚またはケラチン繊維に均一に付着し、その特性を十分に発揮できる上、化粧持続性にも優れる化粧料を提供することができる。
ここに記載された効果は、必ずしも限定されるものではなく、本明細書中に記載されたいずれかの効果であってもよい。
According to this technology, it is possible to provide a cosmetic that allows the fibers to adhere uniformly to the skin or keratin fibers without using microplastics that have an environmental load, can fully exhibit their characteristics, and has excellent makeup durability. Can be done.
The effects described herein are not necessarily limited, and may be any of the effects described herein.
次に、本技術の好ましい実施形態について詳細に説明する。ただし、本技術は以下の好ましい実施形態に限定されず、本技術の範囲内で自由に変更することができるものである。尚、本明細書において百分率は特に断りのない限り質量による表示である。なお、本明細書においては、〜を用いて数値範囲を表す際は、その範囲は両端の数値を含むものとする。また、平均長さ、平均幅、平均粒子径は、走査型電子顕微鏡(日本電子製、JSM−7800prime)、または光学顕微鏡を用いて観察し、画像解析装置(ルーゼックスAP、ニレコ社製)による測定により求めた値(メジアン径D50)を示すものである。 Next, preferred embodiments of the present technology will be described in detail. However, the present technology is not limited to the following preferred embodiments, and can be freely changed within the scope of the present technology. In this specification, the percentage is expressed by mass unless otherwise specified. In addition, in this specification, when the numerical value range is expressed by using ~, the range includes the numerical values at both ends. The average length, average width, and average particle size are observed with a scanning electron microscope (JSM-7800 prime manufactured by JEOL Ltd.) or an optical microscope, and measured with an image analyzer (Luzex AP, manufactured by Nireco). It shows the value (median diameter D50) obtained by the above.
<本技術の疎水化処理非プラスチック繊維>
本技術の(A)疎水化処理非プラスチック繊維は(a1)疎水化処理剤を用いて(a2)非プラスチック繊維を処理したものである。
<Hydrophobicized non-plastic fiber of this technology>
The (A) hydrophobized non-plastic fiber of the present technology is obtained by treating (a2) the non-plastic fiber with (a1) a hydrophobizing agent.
成分(a2)非プラスチック繊維は化学合成によるポリマーを含まない繊維であり、素材として具体的には麻、コットン、イグサ等の繊維、パルプ等から精製して得られるセルロース繊維、セルロース再生繊維であるレーヨン、セルロースをアセチル化して得られる半合成のアセテート繊維等の植物性繊維や、シルク、ウール、カシミヤ、モヘア、キャメル、蜘蛛糸等の動物が産生する動物性繊維が挙げられる。その中でも、肌及びケラチン繊維への均一な付着性、(a1)による疎水化処理のしやすさ、経済性の観点からセルロース、レーヨン、アセテート、麻、コットン、シルク、ウール、蜘蛛糸が好ましい。これらの繊維は、内部に別の物質を練りこんで繊維状にしても良く、天然由来の成分により染められていても良く、複合化の有無は特に限定しない。 Component (a2) Non-plastic fiber is a fiber that does not contain a polymer produced by chemical synthesis, and specifically, as a material, it is a fiber such as hemp, cotton, origusa, a cellulose fiber obtained by purifying from pulp or the like, or a cellulose regenerated fiber. Examples thereof include vegetable fibers such as semi-synthetic acetate fibers obtained by acetylating rayon and cellulose, and animal fibers produced by animals such as silk, wool, cashmere, mohair, camel and spider silk. Among them, cellulose, rayon, acetate, linen, cotton, silk, wool and spider silk are preferable from the viewpoints of uniform adhesion to the skin and keratin fibers, ease of hydrophobization treatment by (a1), and economy. These fibers may be formed into fibers by kneading another substance inside, or may be dyed with naturally derived components, and the presence or absence of compounding is not particularly limited.
本発明の(a2)非プラスチック繊維の平均長さと平均太さは、温度25℃、湿度50%の環境下において無作為に選択した50本の繊維を、光学顕微鏡、または電子顕微鏡で観察した平均値で得られる。繊維の平均長さは、繊維の長径の平均粒子径を計測したものであり、0.1mm〜5mmが好ましく、0.1mm〜4mmがより好ましく、0.5mm〜3mmが更に好ましい。また繊維の平均太さは、繊維の形状に寄らず、繊維の最短径を計測したものではなく、長径を軸としたときの最大幅である回転直径の平均値を示すものである。5μm〜80μmが好ましく、10μm〜50μmがより好ましい。繊維の平均長さ、平均太さがこの範囲であれば、繊維の均一な付着性、化粧持続性の点で特に良好なものが得られる。 The average length and average thickness of the (a2) non-plastic fibers of the present invention are the average of 50 randomly selected fibers observed with an optical microscope or an electron microscope in an environment of a temperature of 25 ° C. and a humidity of 50%. Obtained by value. The average length of the fiber is a measurement of the average particle size of the major axis of the fiber, and is preferably 0.1 mm to 5 mm, more preferably 0.1 mm to 4 mm, still more preferably 0.5 mm to 3 mm. Further, the average thickness of the fiber does not depend on the shape of the fiber and does not measure the shortest diameter of the fiber, but indicates the average value of the rotation diameter which is the maximum width when the major axis is the axis. It is preferably 5 μm to 80 μm, more preferably 10 μm to 50 μm. When the average length and the average thickness of the fibers are within this range, particularly good ones can be obtained in terms of uniform adhesion of the fibers and long-lasting makeup.
成分(a1)疎水化処理剤は、非プラスチック繊維の表面特性を改質するものであり、一般にプラスチック繊維に比べて非プラスチック繊維は親水性が高く、化粧料中に配合された際の分散性や化粧膜の持続性に課題があるため、その他成分に混合しやすい状態にするために予め処理するものである。疎水化処理剤は、繊維の表面に化学的結合または静電的あるいは物理的吸着し、表面を疎水化するものであり、具体的には、例えば、メチルハイドロジェンポリシロキサン、末端アルコシシジメチルポリシロキサン、アクリルシリコーン、フッ素化シリコーン等のオルガノシロキサン、アルキルアルコキシシラン、パーフルオロアルキルアルコキシシラン等のシランカップリング剤、トリイソステアリン酸イソプロピルチタン等のチタネートカップリング剤、ミリスチン酸、ステアリン酸カリウム等の脂肪酸及びその塩、ラウリン酸亜鉛、ミリスチン酸マクネシウム、ステアリン酸アルミニウム等の金属石鹸、ステアロイルグルタミン酸ナトリウムまたは2ナトリウム、パルミトイルグルタミン酸マグネシウム、ステアロイルアスパラギン酸ナトリウム、N−ラウロイル−L−リジン等のアシルアミノ酸塩、例えば大豆、卵黄、ひまわり等から得られるレシチン等が挙げられる。その中でも、処理剤自身がマイクロプラスチックに該当しないこと、繊維への処理のしやすさ、化粧持続性の観点から、アルキルアルコキシシラン、脂肪酸及びその塩、金属石鹸、アシル化アミノ酸及びその塩、レシチンが好ましい。 Ingredient (a1) The hydrophobizing agent modifies the surface properties of non-plastic fibers. Generally, non-plastic fibers have higher hydrophilicity than plastic fibers, and dispersibility when blended in cosmetics. And because there is a problem in the durability of the cosmetic film, it is treated in advance to make it easy to mix with other ingredients. The hydrophobizing agent chemically bonds or electrostatically or physically adsorbs to the surface of the fiber to make the surface hydrophobic, and specifically, for example, methylhydrogenpolysiloxane, terminal alkossididimethylpoly. Organosiloxanes such as siloxane, acrylic silicones and fluorinated silicones, silane coupling agents such as alkylalkoxysilanes and perfluoroalkylalkoxysilanes, titanate coupling agents such as isopropyltitanium triisostearate, fatty acids such as myristic acid and potassium stearate. And salts thereof, metal soaps such as zinc laurate, macnesium myristate, aluminum stearate, and acyl amino acid salts such as sodium stearoyl glutamate or disodium, magnesium palmitoyl glutamate, sodium stearoyl aspartate, N-lauroyl-L-lysine, for example. Examples thereof include lecithin obtained from soybean, egg yolk, sunflower and the like. Among them, alkylalkoxysilanes, fatty acids and salts thereof, metal soaps, acylated amino acids and salts thereof, and lecithin from the viewpoints that the treatment agent itself does not correspond to microplastics, ease of treatment into fibers, and long-lasting makeup. Is preferable.
成分(a1)の成分(a2)への処理方法については、通常公知の処理方法を用いることができるが、具体的には、前記処理剤を水、アセトン、イソプロパノール、イソドデカン等の揮発性溶媒に溶解又は分散し、その中に繊維の一種または二種以上を加え、撹拌後、溶媒を留去して繊維上に処理剤を吸着させ、場合によっては更に焼き付け処理をする方法や、前記処理剤が金属石鹸やアシル化アミノ酸塩の場合は、脂肪酸又はアシル化アミノ酸の水溶液に繊維を加えて分散した後、塩化亜鉛等の金属塩を加えて処理剤の金属石鹸又はアシル化アミノ酸塩を繊維に析出・吸着させる方法等が挙げられる。尚、本発明に用いられる成分(a2)非プラスチック繊維は合成繊維に比べ耐熱性が弱い傾向にあるため、処理時の温度は120℃を超えないことが好ましく、110℃以下であることがより好ましい。成分(a1)に用いられる疎水化処理剤による繊維の処理量は、処理剤の種類によっても異なるが、概ね繊維の0.1〜20%が好ましく、0.5〜10%が特に好ましい。 As a method for treating the component (a1) to the component (a2), a generally known treatment method can be used. Specifically, the treatment agent is used in a volatile solvent such as water, acetone, isopropanol, or isododecane. A method of dissolving or dispersing, adding one or more kinds of fibers to the mixture, stirring, distilling off the solvent to adsorb the treatment agent on the fibers, and in some cases further baking treatment, or the above-mentioned treatment agent. In the case of metal soap or acylated amino acid salt, the fiber is added to an aqueous solution of fatty acid or acylated amino acid and dispersed, and then a metal salt such as zinc chloride is added to add the metal soap or acylated amino acid salt of the treatment agent to the fiber. Examples thereof include a method of precipitating and adsorbing. Since the component (a2) non-plastic fiber used in the present invention tends to have weaker heat resistance than the synthetic fiber, the temperature at the time of treatment preferably does not exceed 120 ° C, and more preferably 110 ° C or less. preferable. The amount of the fiber treated by the hydrophobizing treatment agent used for the component (a1) varies depending on the type of the treatment agent, but is generally preferably 0.1 to 20% of the fiber, and particularly preferably 0.5 to 10%.
本発明における成分(A)疎水化処理非プラスチック繊維の含有量は、下限としては、好ましくは0.1%以上、より好ましくは1%以上、さらに好ましくは3%以上、上限として好ましくは20%以下、より好ましくは15%以下、さらに好ましくは7%以下である。含有量がこの範囲であれば、繊維による化粧効果、化粧持続性の点で特に良好なものが得られる。 The content of the component (A) hydrophobized non-plastic fiber in the present invention is preferably 0.1% or more, more preferably 1% or more, further preferably 3% or more, and preferably 20% as the upper limit. Below, it is more preferably 15% or less, still more preferably 7% or less. When the content is within this range, a particularly good one can be obtained in terms of cosmetic effect and cosmetic durability due to the fiber.
本発明の成分(B)は、酸化鉄、カーボンブラック、酸化チタン、黒酸化チタン、(チタン/酸化チタン)焼結物、グンジョウ、コンジョウ、マンガンバイオレット、カルミン、タール色素等の着色顔料から選ばれるものを含有することができる。成分(B)は化粧料に色を付ける効果を付与するものであれば、特に形状・粒径は限定せず、1種または2種以上組み合わせて配合してもよい。また、成分(A)は、成分(a2)の繊維に、成分(B)を予め表面に付着させるか繊維内部に分散させたものを(a1)により疎水化処理しても良く、予め(a1)で疎水化処理した成分(B)を成分(a2)に被覆吸着処理させても良い。なお、これらの処理を行う場合に、成分(B)の化粧料中の分散性を向上させ、特に発色と化粧持ちに優れる化粧料が得られる場合がある。本発明における、成分(B)の含有量は、下限として0%以上、好ましくは1%以上、より好ましくは3%以上であり、上限として、好ましくは20%以下、より好ましくは15%以下、更に好ましくは10%以下である。 The component (B) of the present invention is selected from colored pigments such as iron oxide, carbon black, titanium oxide, black titanium oxide, (titanium / titanium oxide) sintered products, gunjo, konjo, manganese violet, carmine, and tar pigments. Can contain things. The shape and particle size of the component (B) are not particularly limited as long as they give the effect of coloring the cosmetics, and one type or a combination of two or more types may be blended. Further, the component (A) may be prepared by adsorbing the component (B) on the surface of the fiber of the component (a2) in advance or dispersing the component (B) inside the fiber and hydrophobizing the fiber by (a1). ) May be coated and adsorbed on the component (a2). In addition, when these treatments are performed, the dispersibility of the component (B) in the makeup may be improved, and a cosmetic having particularly excellent color development and makeup retention may be obtained. The content of the component (B) in the present invention is 0% or more, preferably 1% or more, more preferably 3% or more as the lower limit, and preferably 20% or less, more preferably 15% or less as the upper limit. More preferably, it is 10% or less.
本発明には成分(C)として天然樹脂を配合することができる。成分(C)の天然樹脂は動植物から抽出される固体〜高粘度液体の不揮発性成分であり、成分(A)疎水化処理非プラスチック繊維の化粧料中での分散性及び肌やケラチン繊維への付着力を向上する目的で使用される。成分(A)の分散が良い油溶性かつ肌やケラチンへの付着に優れる親水部位を同時に有していることが好ましく、具体的にはロジン酸、ロジン酸とペンタエリスリット、ジペンタエリスリット、グリセリン、エチレングリコール、プロピレングリコール、ジエチレングリコール、ネオペンチルグリコール、トリメチロールプロパン、ヘキサントリオール等の多価アルコールとのエステル等のロジン酸誘導体、カルナウバロウの樹脂分を濃縮したカルナウバロウエキス、キャンデリラロウの樹脂分を濃縮したキャンデリラロウエキス等が挙げられる。 In the present invention, a natural resin can be blended as the component (C). The natural resin of component (C) is a solid to high-viscosity liquid non-volatile component extracted from animals and plants, and component (A) dispersibility of hydrophobized non-plastic fibers in cosmetics and on skin and keratin fibers. Used for the purpose of improving adhesion. It is preferable that the component (A) has a hydrophilic site that is oil-soluble and has excellent adhesion to the skin and keratin at the same time. Rosin acid derivatives such as esters with polyhydric alcohols such as glycerin, ethylene glycol, propylene glycol, diethylene glycol, neopentyl glycol, trimethylolpropane, and hexanetriol, carnauba wax extract with concentrated carnauba wax resin, and candelilla wax resin. Examples thereof include candelilla wax extract obtained by concentrating rosin.
本発明における成分(C)の天然樹脂の含有量は、下限として、好ましくは0.1%以上、より好ましくは0.5%以上、さらに好ましくは3%以上であり、上限として、好ましくは30%以下、より好ましくは20%以下、さらに好ましくは10%以下である。含有量がこの範囲であれば、化粧料中での繊維の分散状態、繊維の均一な付着、化粧持続性の点で特に良好なものが得られる。 The content of the natural resin of the component (C) in the present invention is preferably 0.1% or more, more preferably 0.5% or more, still more preferably 3% or more as the lower limit, and preferably 30 or more as the upper limit. % Or less, more preferably 20% or less, still more preferably 10% or less. When the content is in this range, particularly good ones can be obtained in terms of the dispersed state of the fibers in the cosmetic, the uniform adhesion of the fibers, and the durability of the makeup.
本発明はマイクロプラスチックを用いないという観点から、本発明の化粧料中で、繊維以外の成分においても合成樹脂を使用しないことが好ましい。合成樹脂とは、天然由来の加工物は含まず、モノマーを出発とする有機合成により得られる皮膜を形成する高分子であり、25℃において水への溶解度が0.1g/100ml以下であり、水中で固体の形状を有するものと本発明では定義する。 From the viewpoint of not using microplastics in the present invention, it is preferable not to use synthetic resins in the cosmetics of the present invention even in components other than fibers. The synthetic resin is a polymer that does not contain naturally-derived processed products and forms a film obtained by organic synthesis starting from a monomer, and has a solubility in water of 0.1 g / 100 ml or less at 25 ° C. It is defined in the present invention as having a solid shape in water.
本発明の化粧料は、上記必須成分を含有する化粧料であれば、剤型は特に限定されないが、本発明の効果が特に発揮されやすい剤型は、連続相が油相である油性型、または油中水型、粉末、粉末固型が好ましい。また、本発明の化粧料の形態は、液状、ペースト状であると、肌への塗布性等の使用性、化粧膜の均一性等の観点より好ましい。 The dosage form of the cosmetic of the present invention is not particularly limited as long as it is a cosmetic containing the above essential ingredients, but the dosage form in which the effect of the present invention is particularly likely to be exhibited is an oily type in which the continuous phase is an oil phase. Alternatively, a water-in-oil type, a powder, or a solid powder type is preferable. Further, when the form of the cosmetic of the present invention is liquid or paste, it is preferable from the viewpoint of usability such as applicability to the skin and uniformity of the cosmetic film.
本発明の化粧料には、上記成分の他、本発明の効果を損なわない範囲で、必要に応じて、油剤、粉体、界面活性剤及び、ベンゾフェノン系,PABA系,ケイ皮酸系,サリチル酸系,4−tert−ブチル−4’−メトキシジベンゾイルメタン,オキシベンゾン等の紫外線吸収剤、多価アルコール,タンパク質,ムコ多糖,コラーゲン,エラスチン等の保湿剤、α−トコフェロール,アスコルビン酸等の酸化防止剤、ビタミン類、消炎剤,生薬等の美容成分、パラオキシ安息香酸エステル,フェノキシエタノール,1,3−ブチレングリコール等の防腐剤、メチルセルロース,ヒドロキシメチルセルロース,キサンタンガム,カラギーナン,グアーガム,寒天,ペクチン等の水系増粘剤、水、香料等を適宜配合することができる。 In addition to the above-mentioned components, the cosmetic of the present invention includes oils, powders, surfactants, benzophenone-based, PABA-based, silicic acid-based, and salicylic acid, if necessary, as long as the effects of the present invention are not impaired. System, UV absorbers such as 4-tert-butyl-4'-methoxydibenzoylmethane and oxybenzone, moisturizers such as polyhydric alcohols, proteins, mucopolysaccharides, collagen and elastins, and antioxidants such as α-tocopherol and ascorbic acid. Beauty ingredients such as agents, vitamins, anti-inflammatory agents, crude drugs, preservatives such as paraoxybenzoic acid ester, phenoxyethanol, 1,3-butylene glycol, water-based increase such as methylcellulose, hydroxymethylcellulose, xanthan gum, carrageenan, guar gum, agar, pectin, etc. A viscous agent, water, a fragrance and the like can be appropriately blended.
本発明の化粧料において、油剤を配合することにより、エモリエント感を付与したり、硬さや塗布時の感触を調整することができる。ここで用いられる油剤としては、成分(C)の天然樹脂以外のものであり、通常化粧料に用いられる油剤であれば特に限定されず、動物油、植物油、合成油等の起源及び、固形油、半固形油、液体油、揮発性油等の性状を問わず、炭化水素類、油脂類、ロウ類、硬化油類、エステル油類、脂肪酸類、高級アルコール類、シリコーン油類、フッ素系油類、ラノリン誘導体類等の油剤が挙げられ、これらを一種又は二種以上用いることができる。本発明の化粧料における、これら油剤の配合量は、概ね10〜80%である。 In the cosmetic of the present invention, by blending an oil agent, it is possible to impart an emollient feeling and adjust the hardness and the feel at the time of application. The oil agent used here is other than the natural resin of the component (C), and is not particularly limited as long as it is an oil agent usually used for cosmetics, and the origin of animal oil, vegetable oil, synthetic oil, etc., and solid oil, Regardless of the properties of semi-solid oils, liquid oils, volatile oils, etc., hydrocarbons, oils and fats, waxes, hydrogenated oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine-based oils , Oil agents such as lanolin derivatives, and one or more of these can be used. The blending amount of these oils in the cosmetic of the present invention is approximately 10 to 80%.
本発明の化粧料において、粉体を配合することにより、着色効果、紫外線遮断効果、メーキャップ効果等を付与でき、更に感触を調整することができる。ここで用いられる粉体としては、通常化粧用粉体として用いられている粉体であれば、球状、板状、針状等の形状、煙霧状、微粒子、顔料級等の粒子径、多孔質、無孔質等の粒子構造等により特に限定されず、無機粉体類、光輝性粉体類、有機粉体類、色素粉体類、金属粉体類、複合粉体類等が挙げられる。尚、これら粉体は、フッ素系化合物、シリコーン系化合物、金属石鹸、レシチン、水素添加レシチン、コラーゲン、炭化水素、高級脂肪酸、高級アルコール、エステル、ワックス、ロウ、界面活性剤等の一種又は二種以上を用いて表面処理を施してあっても良い。本発明の化粧料における、これら粉体の配合量は、粉体の配合目的等により異なるが、概ね0.1〜60%である。 In the cosmetic of the present invention, by blending powder, a coloring effect, an ultraviolet blocking effect, a make-up effect and the like can be imparted, and the feel can be further adjusted. As the powder used here, if it is a powder usually used as a cosmetic powder, it has a spherical shape, a plate shape, a needle shape, etc., a smoke atom shape, fine particles, a pigment grade, etc. , Inorganic powders, glittering powders, organic powders, pigment powders, metal powders, composite powders and the like are not particularly limited depending on the particle structure such as non-porous material. These powders are one or two kinds of fluorine-based compounds, silicone-based compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants and the like. Surface treatment may be performed using the above. The blending amount of these powders in the cosmetic of the present invention varies depending on the blending purpose of the powder and the like, but is approximately 0.1 to 60%.
本発明の化粧料において、乳化剤、分散剤、湿潤剤等の目的で、界面活性剤を配合することができる。ここで用いられる界面活性剤としては、通常化粧料に用いられている界面活性剤であれば、何れでも良く、非イオン性界面活性剤、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤等が挙げられ、これらを一種又は二種以上を用いることができる。尚、本発明の化粧料における、界面活性剤の配合量は、界面活性剤の配合目的により異なるが、概ね0.01〜15%である。 In the cosmetic of the present invention, a surfactant can be blended for the purpose of an emulsifier, a dispersant, a wetting agent and the like. The surfactant used here may be any surfactant that is usually used in cosmetics, and is a nonionic surfactant, an anionic surfactant, a cationic surfactant, or an amphoteric interface. Activators and the like can be mentioned, and one or more of these can be used. The blending amount of the surfactant in the cosmetic of the present invention varies depending on the blending purpose of the surfactant, but is approximately 0.01 to 15%.
前記化粧料として、具体的には、例えば、乳液、クリーム、化粧水、美容液、パック、オールインワンジェル、日焼け止め、洗浄料などの基礎化粧料、メイク下地、BBクリーム、ファンデーション、白粉、頬紅、口紅、アイブロウ、マスカラ、アイライナー、ネイルエナメル等のメイクアップ化粧料、養毛料、疑似増毛剤、ヘアトニック、シャンプー、リンス、ヘアワックス等の頭髪用化粧料、分散液、軟膏、液剤、エアゾール、貼付剤、パップ剤、リニメント剤等のいずれの形態であってもよい。これらの中でも、本技術の繊維の効果が顕著に発揮される点から、アイブロウ、マスカラ、ネイルエナメル、頭髪化粧料等のケラチン繊維に使用される化粧料であることが好ましい。 Specific examples of the cosmetics include basic cosmetics such as milky lotion, cream, lotion, beauty liquid, pack, all-in-one gel, sunscreen, and cleaning agent, makeup base, BB cream, foundation, white powder, and cheek red. Makeup cosmetics such as lipstick, eyebrow, mascara, eyeliner, nail enamel, hair restorer, pseudo hair thickener, hair tonic, shampoo, rinse, hair wax and other hair cosmetics, dispersion, ointment, liquid, aerosol, It may be in any form such as a patch, a poultice, and a liniment. Among these, cosmetics used for keratin fibers such as eyebrow, mascara, nail enamel, and hair cosmetics are preferable because the effects of the fibers of the present technology are remarkably exhibited.
次に、実施例を挙げて本発明を更に説明するが、本発明はこれら実施例に限定されるものではない。 Next, the present invention will be further described with reference to examples, but the present invention is not limited to these examples.
[成分(A)の疎水化処理非プラスチック繊維の製造実施例1]
PC純度90%のレシチン5部をイソプロパノール100部に溶解させ、そこに平均長さ3mm、平均太さ40μmのパルプ由来セルロース繊維(a2−1)95部を分散させた。
撹拌しながら80℃に加熱してイソプロパノールを減圧乾燥し、粉砕後、レシチン5%処理セルロースを得た。
[Production Example 1 of Hydrophobicized Non-Plastic Fiber of Component (A)]
Five parts of lecithin having a PC purity of 90% were dissolved in 100 parts of isopropanol, and 95 parts of pulp-derived cellulose fibers (a2-1) having an average length of 3 mm and an average thickness of 40 μm were dispersed therein.
The isopropanol was dried under reduced pressure by heating to 80 ° C. with stirring, and after pulverization, lecithin 5% treated cellulose was obtained.
[成分(A)の疎水化処理非プラスチック繊維の製造実施例2]
精製水120部にラウリン酸ナトリウム3部を70℃で加熱溶解させ、室温冷却後、そこに平均長さ1mm、平均太さ25μmの絹紡糸(a2−2)97部を分散させた。そこに10%塩化亜鉛水溶液10部を加え、10分撹拌しラウリン酸亜鉛を絹紡糸表面に析出させた。精製水による洗浄と濾過を2度行った後に50℃で減圧乾燥させ、粉砕後、ラウリン酸亜鉛3%処理シルクを得た。
[Production Example 2 of Hydrophobicized Non-Plastic Fiber of Component (A)]
Three parts of sodium laurate was heated and dissolved in 120 parts of purified water at 70 ° C., cooled to room temperature, and then 97 parts of silk spinning (a2-2) having an average length of 1 mm and an average thickness of 25 μm were dispersed therein. 10 parts of a 10% zinc chloride aqueous solution was added thereto, and the mixture was stirred for 10 minutes to precipitate zinc laurate on the silk spinning surface. After washing with purified water and filtering twice, the silk was dried under reduced pressure at 50 ° C. and pulverized to obtain silk treated with 3% zinc laurate.
[成分(A)の疎水化処理非プラスチック繊維の製造実施例3]
オクチルトリエトキシシラン2部をイソプロパノール60部に溶解させ、そこに平均長さ2mm、平均太さ40μmのレーヨン繊維(a2−3)98部を分散させた。撹拌しながら70℃に加熱してイソプロパノールを減圧乾燥し、オクチルトリエトキシシラン2%処理レーヨンを得た。
[Production Example 3 of Hydrophobicized Non-Plastic Fiber of Component (A)]
Two parts of octyltriethoxysilane were dissolved in 60 parts of isopropanol, and 98 parts of rayon fiber (a2-3) having an average length of 2 mm and an average thickness of 40 μm were dispersed therein. The isopropanol was dried under reduced pressure by heating to 70 ° C. with stirring to obtain rayon treated with octyltriethoxysilane 2%.
[成分(A)の疎水化処理非プラスチック繊維の製造実施例4]
平均長さ2mm、平均太さ22μmのメリノー種ウール繊維(a2−4)97部にパルミトイルグルタミン酸Mg、パルミトイルサルコシンNa、パルミトイルプロリン、パルミチン酸の混合物(SEPIFEEL ONE、SEPPIC社製)3部を添加し、パウダーミキサーを用いて60℃において5分間混合した。室温冷却後粉砕し、アシル化アミノ酸3%処理ウールを得た。
[Production Example 4 of Hydrophobicized Non-Plastic Fiber of Component (A)]
3 parts of a mixture of palmitoyl glutamate Mg, palmitoyl sarcosine Na, palmitoyl proline, and palmitic acid (SEPFIEL ONE, manufactured by SEPPIC) was added to 97 parts of merino wool fiber (a2-4) having an average length of 2 mm and an average thickness of 22 μm. , Was mixed at 60 ° C. for 5 minutes using a powder mixer. After cooling to room temperature, the wool was pulverized to obtain wool treated with 3% acylated amino acids.
下記表1に示す処方の油性マスカラを調製し、ロングラッシュ効果、化粧膜の均一性、化粧持続性及び耐水性を下記の方法により評価した。その結果を表1に示す。 The oil-based mascaras of the formulations shown in Table 1 below were prepared, and the long rush effect, the uniformity of the cosmetic film, the makeup durability and the water resistance were evaluated by the following methods. The results are shown in Table 1.
※2:レオパールKL2(千葉製粉社製)
※3:カルナバワックスをイソプロパノールで抽出、蒸留して得られ、軟化点が70℃、ヨウ素価が40である樹脂組成物
※4:AEROSIL 300(日本アエロジル社製)
※5:BENTONE 38V BC(エレメンティス社製)
※6:TAROX IRON OXIDE ABL−412HP(チタン工業社製)
※7:タルクJA−46R(浅田製粉社製)
* 2: Leopal KL2 (manufactured by Chiba Flour Milling Co., Ltd.)
* 3: A resin composition obtained by extracting and distilling carnauba wax with isopropanol and having a softening point of 70 ° C. and an iodine value of 40. * 4: AEROSIL 300 (manufactured by Aerosil Japan)
* 5: BENTONE 38V BC (manufactured by Elementis)
* 6: TAROX IRON OXIDE ABL-412HP (manufactured by Titan Kogyo)
* 7: Talc JA-46R (manufactured by Asada Flour Milling Co., Ltd.)
(製造方法)
A.成分(1)〜(8)を100℃に加熱し、均一に混合する。
B.室温冷却後、成分(9)〜(22)を成分Aに加え、均一に分散する。
C.Bを容器に充填して製品とする。
(Production method)
A. Ingredients (1) to (8) are heated to 100 ° C. and mixed uniformly.
B. After cooling to room temperature, the components (9) to (22) are added to the component A and uniformly dispersed.
C. B is filled in a container to obtain a product.
(評価方法)
下記評価項目について各々下記方法により評価を行った。
(評価項目)
a.ロングラッシュ効果:睫が長くなる化粧効果が得られるかどうか
b.化粧膜の均一性:マスカラ液及び繊維が塊状に付着せず一定の厚みを持っているかどうか
c.化粧持続性:時間が経っても化粧効果が持続しているかどうか
評価項目a、bについて、各試料を用いて専門パネル20名による使用テストを行い、パネル各人が下記絶対評価基準にて7段階に評価し評点を付け、各試料のパネル全員の評点合計から、その平均値を算出し、下記判定基準により判定した。評価項目cについては使用後パネルに通常生活をしてもらい、8時間後に評価を行った。
<絶対評価基準>
(評点):(評価)
6 :非常に良い
5 :良い
4 :やや良い
3 :普通
2 :やや悪い
1 :悪い
0 :非常に悪い
<判定基準>
(判定):(評点の平均点)
◎ :5点を超える :非常に良好
○ :3.5点を超える5点以下:良好
△ :2点を超える3.5点以下:やや不良
× :2点以下 :不良
(Evaluation method)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
a. Long rush effect: Whether a cosmetic effect that lengthens the eyelashes can be obtained b. Uniformity of cosmetic film: Whether the mascara liquid and fibers do not adhere in a lump and have a certain thickness
c. Makeup Persistence: Whether the cosmetic effect persists over time For evaluation items a and b, each sample was used by 20 specialized panels, and each panel conducted a usage test based on the following absolute evaluation criteria. The grades were evaluated and graded, and the average value was calculated from the total score of all the panels of each sample, and the judgment was made according to the following criteria. For evaluation item c, the panel was asked to live a normal life after use, and evaluation was performed 8 hours later.
<Absolute evaluation criteria>
(Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad <Judgment criteria>
(Judgment): (Average score)
◎: Exceeding 5 points: Very good ○: Exceeding 3.5 points and 5 points or less: Good △: Exceeding 2 points and 3.5 points or less: Slightly defective ×: 2 points or less: Defect
d.耐水性の評価方法
ガラス板状にアプリケーターを用いて、各マスカラを400μmの厚さとなるように塗工した後、室温で4時間乾燥させてマスカラ塗膜を作成する。作成したマスカラ塗膜の表面に水0.8gを滴下し、5分経過後不織布にて水滴をふき取り、塗膜の状態及び不織布への付着状態を目視で観察する。
(評価基準)
◎:塗膜に変化はなく、不織布に水以外の付着物はない。
○:塗膜に変化はないが、不織布に僅かに繊維又はマスカラ液の付着が見られる。
△:塗膜の表面に僅かに擦れ跡等の変化があり、不織布に繊維又はマスカラ液の付着が見られる。
×:塗膜の表面に明らかに擦れ跡があり、不織布に繊維及びマスカラ液の付着が見られる。
d. Evaluation method of water resistance Using an applicator on a glass plate, each mascara is coated to a thickness of 400 μm, and then dried at room temperature for 4 hours to prepare a mascara coating film. 0.8 g of water is dropped on the surface of the prepared mascara coating film, and after 5 minutes, the water droplets are wiped off with a non-woven fabric, and the state of the coating film and the state of adhesion to the non-woven fabric are visually observed.
(Evaluation criteria)
⊚: There is no change in the coating film, and there is no deposit other than water on the non-woven fabric.
◯: There is no change in the coating film, but slight adhesion of fibers or mascara liquid is observed on the non-woven fabric.
Δ: There is a slight change in the surface of the coating film such as rubbing marks, and adhesion of fibers or mascara liquid is observed on the non-woven fabric.
X: There are obvious rubbing marks on the surface of the coating film, and fibers and mascara liquid adhere to the non-woven fabric.
表1の結果から明らかな如く、本発明の実施例1〜7の油性マスカラは、比較例1〜4に比べ、ロングラッシュ効果、化粧膜の均一性、化粧持続性、耐水性の全てにおいて優れたものであった。
これに対して、未処理の繊維を含有した比較例1〜4では、繊維の分散性が悪いため均一に睫毛に付着せず、ロングラッシュ効果や化粧膜の均一性が低かった。また、化粧持続性や耐水性の点でも満足のいくものが得られなかった。
As is clear from the results in Table 1, the oil-based mascaras of Examples 1 to 7 of the present invention are superior to Comparative Examples 1 to 4 in all of the long rush effect, the uniformity of the makeup film, the makeup durability, and the water resistance. It was a gift.
On the other hand, in Comparative Examples 1 to 4 containing untreated fibers, the fibers did not adhere uniformly to the eyelashes due to poor dispersibility, and the long rush effect and the uniformity of the decorative film were low. In addition, no satisfactory result was obtained in terms of makeup durability and water resistance.
実施例8:水中油型アイブロウマスカラ
(成分) (%)
(1)ジメチルポリシロキサン※8 3
(2)ステアリン酸 1
(3)パルミチン酸 1
(4)重質流動イソパラフィン※9 0.1
(5)フィッシャートロプシュワックス 3
(6)エイコセンビニルピロリドン共重合体※10 3
(7)コレステロール 2
(8)トリメチルシロキシケイ酸※11 2
(9)キャンデリラロウ樹脂※12 0.5
(10)精製水 残量
(11)カルボキシメチルセルロース 1
(12)アクリル酸アルキル・酢酸ビニル共重合体エマルジョン※13 10
(13)トリエタノールアミン 1.2
(14)オクチルトリエトキシシラン処理酸化チタン被覆ガラス末 1
(15)EDTA−2Na 0.5
(16)トレハロース 0.5
(17)ポリビニルアルコール 1
(18)ラウロイルリジン3%処理カーボンブラック10%被覆シルク(a2−1)
5
(19)球状セルロース※14 1
(20)煙霧状無水ケイ酸※15 5
※8:BELSIL DM 1PLUS(旭化成ワッカーシリコーン社製)
※9:パールリーム18(日油社製)
※10:ANTARON V−220(ISP社製)
※11:SR−1000(モメンティブ・パフォーマンス・マテリアルズ・ジャパン社製)※12:キャンデリラ樹脂E−1(日本ナチュラルプロダクツ社製)
※13:ビニゾール2140L(固形分45%)(大同化成工業社製)
※14:CELLULOBEADS D−10(大東化成工業社製)
※15:AEROSIL 380S(日本アエロジル社製)
Example 8: Oil-in-water eyebrow mascara (ingredient) (%)
(1) Dimethylpolysiloxane * 8 3
(2) Stearic acid 1
(3) Palmitic acid 1
(4) Heavy liquid isoparaffin * 9 0.1
(5) Fischer-Tropsch wax 3
(6) Eikosen vinylpyrrolidone copolymer * 10 3
(7) Cholesterol 2
(8) Trimethylsiloxysilicic acid * 112
(9) Candelilla low resin * 12 0.5
(10) Remaining amount of purified water (11) Carboxymethyl cellulose 1
(12) Alkyl acrylate / vinyl acetate copolymer emulsion * 13 10
(13) Triethanolamine 1.2
(14) Octiltriethoxysilane-treated titanium oxide-coated glass powder 1
(15) EDTA-2Na 0.5
(16) Trehalose 0.5
(17) Polyvinyl alcohol 1
(18) Lauroyl lysine 3% treated carbon black 10% coated silk (a2-1)
5
(19) Spherical cellulose * 14 1
(20) Haze-like silicic anhydride * 15 5
* 8: BEALSIL DM 1PLUS (manufactured by Asahi Kasei Wacker Silicone)
* 9: Pearl Dream 18 (manufactured by NOF CORPORATION)
* 10: ANTARON V-220 (manufactured by ISP)
* 11: SR-1000 (manufactured by Momentive Performance Materials Japan) * 12: Candelilla Resin E-1 (manufactured by Japan Natural Products)
* 13: Vinizol 2140L (solid content 45%) (manufactured by Daido Kasei Kogyo Co., Ltd.)
* 14: CELLULOBEADS D-10 (manufactured by Daito Kasei Kogyo Co., Ltd.)
* 15: AEROSIL 380S (manufactured by Aerosil Japan)
(製造方法)
A.成分(1)〜(9)を100℃まで加熱し、均一に混合する。
B.成分(10)〜(20)を均一に混合し80℃に加熱する。
C.BにAを加え乳化する。
D.Cを室温まで冷却し、容器に充填し製品とする。
(Production method)
A. Ingredients (1) to (9) are heated to 100 ° C. and mixed uniformly.
B. Ingredients (10) to (20) are uniformly mixed and heated to 80 ° C.
C. Add A to B and emulsify.
D. C is cooled to room temperature and filled in a container to prepare a product.
本発明の水中油型アイブロウマスカラは、眉毛の自然な増毛感、化粧膜の均一性、化粧持続性、耐水性の全てにおいて優れたものであった。 The oil-in-water eyebrow mascara of the present invention was excellent in all of the natural feeling of thickening of eyebrows, the uniformity of makeup film, the durability of makeup, and the water resistance.
実施例9:油中水型ヘアマスカラ:
(成分) (%)
(1)イソステアリン酸デキストリン※16 3
(2)ロジン酸ペンタエリスリトール※17 10
(3)イソステアリン酸フィトステリル 1
(4)ポリビニルピロリドン 0.1
(5)軽質流動イソパラフィン※18 残量
(6)デキストリン脂肪酸エステル※19 2
(7)煙霧状無水ケイ酸※20 8
(8)有機変性ベントナイト※5 2
(9)ステロイルグルタミン酸2Na3%処理チタン・酸化チタン焼結物※21
5
(10)ウール繊維(a2−4) 5
(11)1,3−ブチレングリコール 8
(12)精製水 3
(13)香料 0.1
※16:ユニフィルマHVY(千葉製粉社製)
※17:エステルガムHP(荒川化学工業社製)
※18:IPソルベント1620MU(出光興産社製)
※19:レオパールTL2(千葉製粉社製)
※20:AEROSIL R974(日本アエロジル社製)
※21:TILACK D(赤穂化成社製)
Example 9: Water-in-oil hair mascara:
(Ingredient) (%)
(1) Dextrin isostearate * 16 3
(2) Pentaerythritol rosinate * 17 10
(3) Phytosteryl isostearate 1
(4) Polyvinylpyrrolidone 0.1
(5) Light liquid isoparaffin * 18 Remaining amount (6) Dextrin fatty acid ester * 192
(7) Haze-like silicic anhydride * 2008
(8) Organically modified bentonite * 5 2
(9) Titanium / titanium oxide sintered product treated with 2Na of steroylglutamic acid 3% * 21
5
(10) Wool fiber (a2-4) 5
(11) 1,3-butylene glycol 8
(12) Purified water 3
(13) Fragrance 0.1
* 16: Unifilma HVY (manufactured by Chiba Flour Milling Co., Ltd.)
* 17: Ester gum HP (manufactured by Arakawa Chemical Industry Co., Ltd.)
* 18: IP solvent 1620MU (manufactured by Idemitsu Kosan Co., Ltd.)
* 19: Leopal TL2 (manufactured by Chiba Flour Milling Co., Ltd.)
* 20: AEROSIL R974 (manufactured by Aerosil Japan)
* 21: TILK AD (manufactured by Ako Kasei Co., Ltd.)
(製造方法)
A.成分(1)〜(8)を100℃に加熱溶解し、常温になるまで冷却する。その後、
成分(9)と(10)を予め混合吸着させてから、加えて分散する。
B.Aに成分(11)〜(13)を加えて乳化する。
C.Bを容器に充填して製品とする。
(Production method)
A. Ingredients (1) to (8) are heated and dissolved at 100 ° C. and cooled to room temperature. afterwards,
The components (9) and (10) are mixed and adsorbed in advance, and then added and dispersed.
B. Ingredients (11) to (13) are added to A to emulsify.
C. B is filled in a container to obtain a product.
本発明の油中水型ヘアマスカラは、頭髪のボリュームアップ効果、化粧膜の均一性、化粧持続性、耐水性の全てにおいて優れたものであった。 The water-in-oil type hair mascara of the present invention was excellent in all of the effect of increasing the volume of hair, the uniformity of the makeup film, the durability of makeup, and the water resistance.
実施例10:油性マスカラトップコート
(成分) (%)
(1)メチルトリメチコン※22 10
(2)イソドデカン 残量
(3)パルミチン酸デキストリン※19 5
(4)エチレン・プロピレンコポリマー 1
(5)ポリイソブチレン※23 0.1
(6)メチルフェニルポリシロキサン 0.5
(7)煙霧状無水ケイ酸※24 10
(8)球状炭酸カルシウム 5
(9)クオタニウム−18ヘクトライト 2
(10)エタノール 0.5
(11)ジプロピレングリコール 1
(12)カーボンブラック 0.05
(13)黒酸化鉄被覆合成金雲母※25 1
(14)イソステアリン酸処理2%処理レーヨン(a2−3) 1
(15)アモジメチコン処理無水ケイ酸※26 5
※22:シリコーンTMF−1.5(信越化学工業社製)
※23:オパノールB−100(BASF社製)
※24:AEROSIL R972(日本アエロジル社製)
※25:NK−BLACK(日本光研工業社製)
※26:処理量5%、粒子径15μm
Example 10: Oil-based mascara top coat (ingredient) (%)
(1) Methyltrimethicone * 22 10
(2) Remaining amount of isododecane (3) Dextrin palmitate * 195
(4) Ethylene-propylene copolymer 1
(5) Polyisobutylene * 23 0.1
(6) Methylphenylpolysiloxane 0.5
(7) Haze-like silicic anhydride * 24 10
(8) Spherical calcium carbonate 5
(9) Quotanium-18 hectorite 2
(10) Ethanol 0.5
(11) Dipropylene glycol 1
(12) Carbon black 0.05
(13) Black iron oxide-coated synthetic phlogopite * 25 1
(14) Isostearic acid treatment 2% treatment rayon (a2-3) 1
(15) Amodimethicone-treated silicic anhydride * 265
* 22: Silicone TMF-1.5 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 23: Opanol B-100 (manufactured by BASF)
* 24: AEROSIL R972 (manufactured by Aerosil Japan)
* 25: NK-BLACK (manufactured by Nippon Koken Kogyo Co., Ltd.)
* 26: Processing amount 5%, particle size 15 μm
(製造方法)
A.成分(1)〜(6)を95℃で加熱溶解する。
B.Aに成分(7)〜(15)を加え、均一に混合する。
C.Bを容器に充填して製品とする。
(Production method)
A. Ingredients (1) to (6) are heated and dissolved at 95 ° C.
B. Ingredients (7) to (15) are added to A and mixed uniformly.
C. B is filled in a container to obtain a product.
本発明の油性マスカラトップコートは、ロングラッシュ効果、化粧膜の均一性、化粧持続性、耐水性の全てにおいて優れたものであった。 The oil-based mascara top coat of the present invention was excellent in all of the long rush effect, the uniformity of the makeup film, the makeup durability, and the water resistance.
実施例11:パウダーファンデーション
(成分) (%)
(1)タルク 残量
(2)ラウリン酸亜鉛処理(6%)マイカ 20
(3)レシチン処理板状セルロース※27 10
(4)シリカ※28 5
(5)オキシ塩化ビスマス 2
(6)窒化ホウ素 5
(7)板状硫酸バリウム※29 7
(8)トリイソステアリン酸イソプロピルチタン(10%)処理微粒子酸化チタン
5
(9)オクチルトリエトキシシラン(2%)処理ベンガラ 0.4
(10)オクチルトリエトキシシラン(2%)処理黄酸化鉄 1.2
(11)オクチルトリエトキシシラン(2%)処理黒酸化鉄 0.2
(12)ステアロイルアスパラギン酸(3%)処理亜麻繊維※30 3
(13)クロルフェネシン 0.3
(14)メトキシケイ皮酸オクチル 4
(15)ステアリン酸オクチルドデシル 5
(16)セスキイソステアリン酸ソルビタン 1
※27:処理量1%、平均粒径20μm、アスペクト比20
※28:シリカマイクロビードP−1505(日記触媒化成社製)
※29:板状硫酸バリウムHL(堺化学工業製)
※30:平均太さ15μm、平均長さ0.5mm
Example 11: Powder foundation (ingredient) (%)
(1) Talc remaining amount (2) Zinc laurate treatment (6%) Mica 20
(3) Lecithin-treated plate-shaped cellulose * 27 10
(4) Silica * 285
(5) Bismuth oxychloride 2
(6) Boron nitride 5
(7) Plate-shaped barium sulfate * 297
(8) Titanium isopropyl triisostearate (10%) treated fine particle titanium oxide
5
(9) Octiltriethoxysilane (2%) treated Bengala 0.4
(10) Octiltriethoxysilane (2%) treated iron oxide 1.2
(11) Octiltriethoxysilane (2%) treated black iron oxide 0.2
(12) Stearoyl aspartic acid (3%) treated flax fiber * 30 3
(13) Chlorphenesin 0.3
(14) Octyl methoxycinnamate 4
(15) Octyldodecyl stearate 5
(16) Sorbitan sesquiisostearate 1
* 27: Processing amount 1%, average particle size 20 μm, aspect ratio 20
* 28: Silica Microbead P-1505 (manufactured by Diary Catalytic Chemicals Co., Ltd.)
* 29: Plate-shaped barium sulfate HL (manufactured by Sakai Chemical Industry Co., Ltd.)
* 30: Average thickness 15 μm, average length 0.5 mm
(製造方法)
A.成分(1)〜(13)を均一に混合する。
B.Aに成分(14)〜(16)を加え、均一に混合する。
C.Bを粉砕処理し、金皿にプレス成型して製品とする。
(Production method)
A. Ingredients (1) to (13) are uniformly mixed.
B. Ingredients (14) to (16) are added to A and mixed uniformly.
C. B is crushed and press-molded into a gold plate to obtain a product.
本発明のパウダーファンデーションは、自然な産毛感、化粧膜の均一性、化粧持続性、耐水性の全てにおいて優れたものであった。 The powder foundation of the present invention was excellent in all of natural hair growth feeling, makeup film uniformity, makeup durability, and water resistance.
実施例12:ネイルエナメル
(成分) (%)
(1)(酢酸/酪酸)セルロース 8
(2)ニトロセルロース(30%)シンナー溶液 25
(3)酢酸エチル 15
(4)酢酸ブチル 残量
(5)ヘプタン 2
(6)イソプロピルアルコール 5
(7)クエン酸アセチルトリブチル 4
(8)安息香酸スクロース 1
(9)ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル 0.1
(10)ステアラルコニウムヘクトライト 2.5
(11)パーフルオロオクチルトリエトキシシラン(5%)処理黄酸化鉄 1.1
(12)赤226号 0.8
(13)パーフルオロオクチルトリエトキシシラン(5%)酸化チタン被覆ホウケイ酸
3
(14)パーフルオロオクチルトリエトキシシラン処理(5%)絹紡糸(a2−2)
1.5
Example 12: Nail enamel (ingredient) (%)
(1) (Acetic acid / butyric acid) Cellulose 8
(2) Nitrocellulose (30%) thinner solution 25
(3) Ethyl acetate 15
(4) Butyl acetate remaining amount (5) Heptane 2
(6) Isopropyl alcohol 5
(7) Acetyl tributyl citrate 4
(8) Sucrose benzoate 1
(9) Diethylaminohydroxybenzoyl hexyl benzoate 0.1
(10) Stearalconium hectorite 2.5
(11) Perfluorooctyltriethoxysilane (5%) treated iron oxide 1.1
(12) Red No. 226 0.8
(13) Perfluorooctyltriethoxysilane (5%) Titanium oxide-coated borosilicate
3
(14) Perfluorooctyltriethoxysilane treatment (5%) Silk spinning (a2-2)
1.5
(製造方法)
A.成分(1)〜(9)を均一に混合する。
B.Aに成分(10)〜(14)を加え、均一に混合する。
C.Bを容器に充填して製品とする。
(Production method)
A. Ingredients (1) to (9) are uniformly mixed.
B. Ingredients (10) to (14) are added to A and mixed uniformly.
C. B is filled in a container to obtain a product.
本発明のネイルエナメルは、爪の補強効果、化粧膜の均一性、化粧持続性、耐水性の全てにおいて優れたものであった。 The nail enamel of the present invention was excellent in all of the nail reinforcing effect, the uniformity of the makeup film, the makeup durability, and the water resistance.
Claims (9)
(A)(a1)疎水化処理剤 で処理された (a2)非プラスチック繊維
を含有する化粧料。 The following component (A);
(A) (a1) Cosmetics containing non-plastic fibers treated with a hydrophobizing agent (a2).
The cosmetic according to any one of claims 1 to 8, wherein the cosmetic does not substantially contain a synthetic resin.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2022260147A1 (en) * | 2021-06-10 | 2022-12-15 | Spiber株式会社 | Additive for cosmetic composition |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003146829A (en) * | 2001-11-12 | 2003-05-21 | Asahi Kasei Corp | Modified powder and cosmetic |
JP2012211128A (en) * | 2011-03-22 | 2012-11-01 | Kose Corp | Cosmetic for keratin fiber |
JP2014028785A (en) * | 2012-07-05 | 2014-02-13 | Kose Corp | Powder cosmetic |
US20140134217A1 (en) * | 2012-11-09 | 2014-05-15 | Johnson & Johnson Consumer Companies, Inc. | Leave-on compositions containing cellulose materials |
JP2015071587A (en) * | 2013-09-04 | 2015-04-16 | 株式会社コーセー | Powder cosmetic |
JP2016041673A (en) * | 2014-08-13 | 2016-03-31 | 大東化成工業株式会社 | Eyelash cosmetic |
-
2020
- 2020-03-27 JP JP2020057304A patent/JP2021155361A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003146829A (en) * | 2001-11-12 | 2003-05-21 | Asahi Kasei Corp | Modified powder and cosmetic |
JP2012211128A (en) * | 2011-03-22 | 2012-11-01 | Kose Corp | Cosmetic for keratin fiber |
JP2014028785A (en) * | 2012-07-05 | 2014-02-13 | Kose Corp | Powder cosmetic |
US20140134217A1 (en) * | 2012-11-09 | 2014-05-15 | Johnson & Johnson Consumer Companies, Inc. | Leave-on compositions containing cellulose materials |
JP2015071587A (en) * | 2013-09-04 | 2015-04-16 | 株式会社コーセー | Powder cosmetic |
JP2016041673A (en) * | 2014-08-13 | 2016-03-31 | 大東化成工業株式会社 | Eyelash cosmetic |
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Publication number | Priority date | Publication date | Assignee | Title |
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WO2022260147A1 (en) * | 2021-06-10 | 2022-12-15 | Spiber株式会社 | Additive for cosmetic composition |
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