JP2008273942A - Elastic gel-like oily cosmetic - Google Patents
Elastic gel-like oily cosmetic Download PDFInfo
- Publication number
- JP2008273942A JP2008273942A JP2008074621A JP2008074621A JP2008273942A JP 2008273942 A JP2008273942 A JP 2008273942A JP 2008074621 A JP2008074621 A JP 2008074621A JP 2008074621 A JP2008074621 A JP 2008074621A JP 2008273942 A JP2008273942 A JP 2008273942A
- Authority
- JP
- Japan
- Prior art keywords
- elastic gel
- stability
- component
- oily
- cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、弾性ゲル状油性化粧料に関するものであり、更に詳しくは、部分架橋型オルガノポリシロキサン重合物を2〜10質量%、低粘度シリコーン油、粉体を10〜40質量%、イヌリン脂肪酸エステルを配合し、弾力感があり、伸び広がりがよく、化粧膜の均一性に優れ、静置安定性が良好であり、実使用安定性に優れた弾性ゲル状油性化粧料に関するものである。 The present invention relates to an elastic gel oily cosmetic, and more specifically, 2 to 10% by mass of a partially crosslinked organopolysiloxane polymer, low-viscosity silicone oil, 10 to 40% by mass of powder, inulin fatty acid. The present invention relates to an elastic gel-like oily cosmetic that contains an ester, has a feeling of elasticity, spreads well, is excellent in the uniformity of a cosmetic film, has good stability at rest, and has excellent stability in actual use.
化粧料には油性化粧料、水性化粧料、粉体化粧料、油中水型化粧料、水中油型化粧料等様々な剤形や形状が開発され使用感や使用性の向上が検討されている(例えば特許文献1)。
最近では、粉体化粧料と油性化粧料の中間の領域、例えばファニキュラー領域と呼ばれる領域や、その中でも、粉体化粧料の特徴である、優れた携帯性や、軽い延び広がり、べたつきのないさらさらとした感触と、油性化粧料の特徴とする高いエモリエント効果や高い肌への付着性を併せ持ち、両者の優位な点をもつ化粧料の開発がなされてきた(例えば特許文献2、3参照)。さらに、粉体化粧料と油性化粧料の中間の領域においては、従来の粉体化粧料や油性化粧料では得られない、独特の弾力性をもつユニークな使用感の、弾性ゲル状の化粧料の検討がなされてきた(特許文献4、5、6参照)。
Various formulations and shapes have been developed for cosmetics, such as oily cosmetics, water-based cosmetics, powder cosmetics, water-in-oil cosmetics, and oil-in-water cosmetics, and improvements in usability and usability are being studied. (For example, Patent Document 1).
Recently, an intermediate region between powder cosmetics and oily cosmetics, for example, a region called a funicular region, and among them, excellent portability, light extension and spread, which are the characteristics of powder cosmetics, are not sticky The development of cosmetics that have both a smooth feel, a high emollient effect characteristic of oil-based cosmetics, and high adhesion to the skin, and having the advantages of both (see, for example, Patent Documents 2 and 3). . Furthermore, in the region between powder cosmetics and oily cosmetics, elastic gel-like cosmetics with a unique feeling of use and unique elasticity that cannot be obtained with conventional powder cosmetics and oily cosmetics. Has been studied (see Patent Documents 4, 5, and 6).
しかしながら、架橋型オルガノポリシロキサンと固形油と粉体を用いる技術やファニキュラー領域と呼ばれる領域における、弾力性のある感触を有する弾性ゲル状油性化粧料は、処方領域が非常に狭く、化粧料一個の量単位が大きくなったり、適用部位が広くなったりすると、ユニークな弾力をもつ使用感が得られなくなったり、静置安定性が悪くなったりする場合があった。また繰り返し使用することで、発汗、分離、排液やよれなどが生じてくることがあり実使用時の安定性が悪くなる場合があった。
また、架橋型ポリシロキサンと多量のシリコーン油を配合した化粧料では安定性は良好でも、伸び広がりで満足いくものではなかった。油性化粧料において、特許文献1のようにイヌリン脂肪酸エステルと部分架橋型ポリシロキサン重合物を組み合わせてシリコーン油以外の油剤との相溶性の向上や、使用感を向上させた技術はあるが、弾性ゲル状という特殊な領域で検討されたものではなく、粉と油の分離に対しては何の示唆もない。また、特許文献6のように、シリコーン弾性粉体と油剤を組み合わせて弾性化粧料を得る技術はあるが、ゲル構造により弾力性を得る架橋型オルガノポリシロキサン重合物と粉体とイヌリン脂肪酸エステルを組み合わせた弾性状の化粧料は報告されていない。
このため弾性ゲル状油性化粧料の長所である弾力感を感じ、伸び広がりがよく、化粧膜の均一性に優れ、静置安定性に優れ、さらに実使用時の安定性に優れた化粧料の開発が望まれていた。
However, elastic gel-like oily cosmetics with a resilient feel in a region using a cross-linked organopolysiloxane, solid oil and powder, and a region called the funicular region, have a very narrow prescription area, and one cosmetic When the unit of the amount is increased or the application site is widened, there is a case where a feeling of use with a unique elasticity cannot be obtained or the stationary stability is deteriorated. Also, repeated use may cause sweating, separation, drainage, or kinking, which may deteriorate the stability during actual use.
In addition, cosmetics containing a cross-linked polysiloxane and a large amount of silicone oil are not satisfactory in terms of spreading even though the stability is good. In oily cosmetics, there is a technique for improving compatibility with oil agents other than silicone oil by combining an inulin fatty acid ester and a partially cross-linked polysiloxane polymer as in Patent Document 1, and improving the feeling of use. It has not been studied in the special area of gel, and there is no suggestion for the separation of powder and oil. Further, as in Patent Document 6, there is a technique for obtaining an elastic cosmetic by combining silicone elastic powder and an oil agent. However, a cross-linked organopolysiloxane polymer that obtains elasticity by a gel structure, powder, and inulin fatty acid ester No combined elastic cosmetic has been reported.
For this reason, it feels the elasticity that is an advantage of elastic gel oily cosmetics, has good spread, excellent uniformity of the cosmetic film, excellent standing stability, and excellent stability in actual use. Development was desired.
そこで本発明者らは鋭意検討の結果、部分架橋型オルガノポリシロキサンと低粘度シリコーン油と粉体とイヌリン脂肪酸エステルとを特定量で配合する弾性ゲル状油性化粧料が、上記課題を解決することを見出し、本発明を完成した。 Thus, as a result of intensive studies, the present inventors have found that an elastic gel-like oily cosmetic comprising a partially-crosslinked organopolysiloxane, a low-viscosity silicone oil, a powder, and an inulin fatty acid ester in a specific amount solves the above problems. The present invention has been completed.
すなわち、本発明は次の成分;
(a)部分架橋型オルガノポリシロキサン重合物 2〜10質量%
(b)低粘度シリコーン油
(c)粉体 10〜40質量%
(d)イヌリン脂肪酸エステル
を配合したことを特徴とする弾性ゲル状油性化粧料を提供するものである。
That is, the present invention includes the following components:
(A) 2-10% by mass of partially crosslinked organopolysiloxane polymer
(B) Low-viscosity silicone oil (c) Powder 10-40% by mass
(D) To provide an elastic gel oily cosmetic characterized by containing an inulin fatty acid ester.
前記成分(a)及び(b)の配合比の範囲が質量比で(a):(b)=1:4〜1:30である事を特徴とする弾性ゲル状油性化粧料を提供するものである。 Provided is an elastic gel-like oily cosmetic characterized in that the mixing ratio of the components (a) and (b) is (a) :( b) = 1: 4 to 1:30 in mass ratio It is.
前記成分(d)のイヌリン脂肪酸エステルの配合量が0.5〜10質量%(以下単に「%」で示す)である事を特徴とする弾性ゲル状油性化粧料を提供するものである。 The present invention provides an elastic gel oily cosmetic characterized in that the blending amount of the inulin fatty acid ester of the component (d) is 0.5 to 10% by mass (hereinafter simply referred to as “%”).
前記成分(d)のイヌリン脂肪酸エステルが、炭素数8〜32の直鎖または分枝鎖の飽和または不飽和脂肪酸とイヌリンとのエステル化合物で且つ、イヌリンの平均分子量が300〜10,000の範囲であることを特徴とする弾性ゲル状油性化粧料を提供するものである。 The inulin fatty acid ester of the component (d) is an ester compound of a linear or branched saturated or unsaturated fatty acid having 8 to 32 carbon atoms and inulin, and the average molecular weight of inulin is in the range of 300 to 10,000. The present invention provides an elastic gel oily cosmetic characterized by the above.
前記成分(b)の低粘度シリコーン油が、粘度が1〜100mm2/sであることを特徴とする弾性ゲル状油性化粧料を提供するものである。 The low-viscosity silicone oil as the component (b) has an viscosity of 1 to 100 mm 2 / s and provides an elastic gel oily cosmetic.
本発明の弾性ゲル状油性化粧料は、弾力感があり、伸び広がりがよく、化粧膜の均一性に優れ、静置安定性に優れ、実使用安定性に優れるものである。 The elastic gel-like oily cosmetic of the present invention has a feeling of elasticity, spreads well, is excellent in the uniformity of the cosmetic film, is excellent in stationary stability, and is excellent in actual use stability.
以下本発明を詳細に説明する。
本発明の弾性ゲル状油性化粧料とは、例えば、化粧料の表面を指で軽く押して弾力性を感じる化粧料であって、軽く押して変形したものが、放したときに戻るものである。
例えば、物性値で表すのであれば、本発明の弾性ゲル状油性化粧料の弾性とは、TA Instruments社製の「AR2000 Advanced Rheometer」を用いて、「Oscillation procedure」測定において、応力が1Pa、温度が25℃の時、周波数0.01Hzのひずみにおけるtanδ値が0.05〜10の範囲であり、かつ応力が1Pa、温度が25℃の時、周波数0.01Hzのひずみにおけるtanδ値(以下tanδ1)と、周波数0.1Hzのひずみにおけるtanδ値(tanδ2)の比(tanδ1/tanδ2)が1.5〜5であり、かつレオテック社製の「FUDOHレオメーター」を用いた測定において、室温下で、10mmφのアダプターを2cm/min.のスピードで試料中に上方から1mm進入させたときの応力のピーク値(単位g)が10〜200gで表されるものである。
この測定におけるtanδ値はtanδ=G’‘/G’であり、G’‘は粘性項であり、G’は弾性項である。
The present invention will be described in detail below.
The elastic gel-like oily cosmetic of the present invention is, for example, a cosmetic that feels elasticity by lightly pressing the surface of the cosmetic with a finger, and the one that has been lightly pressed and deformed returns when released.
For example, in terms of physical properties, the elasticity of the elastic gel-like oily cosmetic composition of the present invention means that the stress is 1 Pa, temperature in the “Oscillation procedure” measurement using “AR2000 Advanced Rheometer” manufactured by TA Instruments. When the temperature is 25 ° C., the tan δ value at a strain of 0.01 Hz is in a range of 0.05 to 10, and when the stress is 1 Pa and the temperature is 25 ° C., the tan δ value at a strain of 0.01 Hz (hereinafter referred to as tan δ1). ) And a tan δ value (tan δ 2) ratio (tan δ 1 / tan δ 2) at a strain of a frequency of 0.1 Hz is 1.5 to 5, and in a measurement using a “FUDOH rheometer” manufactured by Rheotech, at room temperature 10 mmφ adapter at 2 cm / min. The peak value (unit: g) of stress when the sample is entered 1 mm from above at a speed of 10 to 200 g is represented by 10 to 200 g.
The tan δ value in this measurement is tan δ = G ″ / G ′ , G ″ is a viscous term, and G ′ is an elastic term.
本発明に用いられる成分(a)の部分架橋型オルガノポリシロキサン重合物とは、ベンゼンに不溶であるが、自重と同重量以上のベンゼンを含みうる三次元架橋構造を有するオルガノポリシロキサン重合物であり、特公平8−6035号公報等に記載されているものが例示される。部分架橋型オルガノポリシロキサン重合物は、オルガノポリシロキサンを架橋結合させて得られる重合物であり、一部に三次元架橋構造を有し、R2SiO単位及びRSiO1.5単位よりなり、R3SiO0.5単位及び/又はSiO2単位を含んでいても良い。但し、各構成単位のRは水素原子、メチル基、エチル基、プロピル基等のアルキル基、フェニル基、トリル基等などのアリール基、およびビニル基等の脂肪族不飽和基などが例示され、同種又は異なった種類であっても良い。
市販品としては、部分架橋型オルガノポリシロキサン重合物と低粘度シリコーン油と混合して用いるものが一般的で、このような混合物としては、例えば、KSG−15(部分架橋型メチルポリシロキサン5部とデカメチルシクロペンタシロキサン95部)、KSG−16(部分架橋型メチルポリシロキサン25部とメチルポリシロキサン75部)、KSG−17(部分架橋型メチルポリシロキサン5部とオクタメチルシクロテトラシロキサン95部)、KSG−18(部分架橋型メチルポリシロキサン15部とメチルフェニルポリシロキサン85部)等が挙げられる。
The partially crosslinked organopolysiloxane polymer of component (a) used in the present invention is an organopolysiloxane polymer having a three-dimensional crosslinked structure that is insoluble in benzene but can contain benzene in the same weight or more. Yes, those described in Japanese Patent Publication No. 8-6035 are exemplified. The partially cross-linked organopolysiloxane polymer is a polymer obtained by cross-linking organopolysiloxane, partially having a three-dimensional cross-linking structure, consisting of R 2 SiO units and RSiO 1.5 units, and R 3 SiO 0.5 units and / or SiO 2 units may be included. However, R of each structural unit is exemplified by an alkyl group such as a hydrogen atom, a methyl group, an ethyl group, and a propyl group, an aryl group such as a phenyl group and a tolyl group, and an aliphatic unsaturated group such as a vinyl group. The same kind or different kind may be sufficient.
As a commercial item, what is used by mixing a partially crosslinked organopolysiloxane polymer and a low-viscosity silicone oil is generally used. As such a mixture, for example, KSG-15 (partially crosslinked methylpolysiloxane 5 parts) And decamethylcyclopentasiloxane 95 parts), KSG-16 (partially crosslinked methylpolysiloxane 25 parts and methylpolysiloxane 75 parts), KSG-17 (partially crosslinked methylpolysiloxane 5 parts and octamethylcyclotetrasiloxane 95 parts) ), KSG-18 (15 parts of partially crosslinked methylpolysiloxane and 85 parts of methylphenylpolysiloxane) and the like.
また、本発明における成分(a)の部分架橋型オルガノポリシロキサン重合物は、長鎖アルキル基を含有する部分架橋型オルガノポリシロキサン重合物も含み、部分的に架橋結合を有する三次元構造を呈するシリコーン系エラストマーに長鎖アルキル基を有する化合物であれば特に制限されず、上記長鎖アルキル基としては炭素数8〜30個の直鎖状のアルキル基を好適に例示することができる。
かかる成分(a)は、例えば、SiO2単位、HSiO1.5単位、RSiO1.5単位、RHSiO単位、R2SiO単位、R3SiO0.5単位及びR2HSiO0.5単位(ここで、Rは脂肪族不飽和基を除く置換もしくは非置換の炭素数1〜30の一価炭化水素基である)からなる群から選択された少なくとも1種の構造単位で構成され、ケイ素原子に結合した水素原子を平均で1.5個以上分子中に含有するオルガノハイドロジェンポリシロキサンと、SiO2単位、(CH2=CH)SiO1.5単位、RSiO1.5単位、R(CH2=CH)SiO単位、R2SiO単位、R3SiO0.5単位、R2(CH2=CH)SiO0.5単位、(ここでRは脂肪族不飽和基を除く置換もしくは非置換の炭素数1〜30の一価炭化水素基である)からなる群から選択された構造単位で構成されると共に、分子中にケイ素原子に結合したビニル基を平均で1.5個以上含有するビニル基含有オルガノポリシロキサン及び/又はCmH2m−1(CH2)xCmH2m−1で表される不飽和炭化水素(但し、mは2〜6、xは1以上の整数である。)との付加重合によって得ることができる。
但し、前記構造単位であるオルガノハイドロジェンポリシロキサンとビニル基含有オルガノポリシロキサンのRは、脂肪酸不飽和基を除く置換もしくは非置換の炭素数1〜30の一価炭化水素基を表すが、そのRの一部は脂肪酸不飽和基を除く置換もしくは非置換の炭素数8〜30の一価炭化水素基である。この炭素数8〜30の一価炭化水素基は、構造単位中5〜50モル%であることが好ましく、特に10〜40モル%であると静値安定性及び実使用安定性が良好になり好ましい。
Further, the partially crosslinked organopolysiloxane polymer of component (a) in the present invention also includes a partially crosslinked organopolysiloxane polymer containing a long-chain alkyl group, and exhibits a three-dimensional structure partially having a crosslinking bond. If it is a compound which has a long-chain alkyl group in a silicone type elastomer, it will not restrict | limit in particular, As a long-chain alkyl group, a C8-C30 linear alkyl group can be illustrated suitably.
Such component (a) is, for example, SiO 2 unit, HSiO 1.5 unit, RSiO 1.5 unit, RHSiO unit, R 2 SiO unit, R 3 SiO 0.5 unit and R 2 HSiO 0.5 unit (here R is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 30 carbon atoms excluding an aliphatic unsaturated group), and is composed of at least one structural unit selected from the group consisting of Organohydrogenpolysiloxane containing 1.5 or more bonded hydrogen atoms in the molecule on average, SiO 2 unit, (CH 2 ═CH) SiO 1.5 unit, RSiO 1.5 unit, R (CH 2 = CH) SiO unit, R 2 SiO unit, R 3 SiO 0.5 unit, R 2 (CH 2 ═CH) SiO 0.5 unit, where R is a substituted or unsubstituted group excluding an aliphatic unsaturated group Carbon number 1 to 30 monovalent hydrocarbon groups) and a vinyl group containing 1.5 or more vinyl groups bonded to silicon atoms on average in the molecule. organopolysiloxane and / or C m H 2m-1 (CH 2) x C m H 2m-1 represented by an unsaturated hydrocarbon (where, m is 2 to 6, x is an integer of 1 or more.) Can be obtained by addition polymerization.
However, R of the organohydrogenpolysiloxane and vinyl group-containing organopolysiloxane as the structural unit represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 30 carbon atoms excluding a fatty acid unsaturated group. A part of R is a substituted or unsubstituted monovalent hydrocarbon group having 8 to 30 carbon atoms excluding a fatty acid unsaturated group. The monovalent hydrocarbon group having 8 to 30 carbon atoms is preferably 5 to 50 mol% in the structural unit, and particularly when it is 10 to 40 mol%, the static stability and the actual use stability are improved. preferable.
このような長鎖アルキル基を含有する部分架橋型オルガノポリシロキサン重合物としては、例えばINCI名(International Nomenclature Cosmetic Ingredient labeling names)で(ビニルジメチコン/ラウリルジメチコン)クロスポリマーが挙げられる。市販品としては、長鎖アルキル基を含有する部分架橋型オルガノポリシロキサン重合物に炭化水素油又はエステル油を配合したシリコーンゲルを挙げることができる。例えば、KSG−41は、ミネラルオイル65〜75%を含み、KSG−42は、イソドデカン70〜80%を含み、KSG−43は、トリオクタノイン(トリ−2−エチルヘキサン酸グリセリル)65〜75%を含み、KSG−44は、スクワラン65〜75%を含んでいるもの(いずれも信越化学工業社製)等を具体的に挙げられ、これらを1種または2種以上用いることができる。 Examples of the partially crosslinked organopolysiloxane polymer containing such a long-chain alkyl group include (vinyl dimethicone / lauryl dimethicone) crosspolymer under the INCI name (International Nomenclature Cosmetic Labeling Names). As a commercial item, the silicone gel which mix | blended hydrocarbon oil or ester oil with the partially crosslinked type organopolysiloxane polymer containing a long-chain alkyl group can be mentioned. For example, KSG-41 contains 65-75% mineral oil, KSG-42 contains 70-80% isododecane, and KSG-43 contains 65-75 trioctanoin (glyceryl tri-2-ethylhexanoate). KSG-44 specifically includes those containing 65 to 75% squalane (all manufactured by Shin-Etsu Chemical Co., Ltd.) and the like, and one or more of them can be used.
成分(a)の部分架橋型オルガノポリシロキサン重合物の配合量は、本発明の弾性ゲル状油性化粧料中に2〜10%であり、好ましくは3〜8%の範囲である。成分(a)の配合量が2%未満であると弾力感や静置安定性や実使用安定性で満足するものが得られず、また、10%を超えると伸び広がりや化粧膜の均一性の点で好ましくない。
長鎖アルキル基を含有する部分架橋型オルガノポリシロキサン重合物と長鎖アルキル基を含有しない部分架橋型オルガノポリシロキサン重合物を併用することによって、伸び広がりがより向上するため好ましい。
The amount of the partially crosslinked organopolysiloxane polymer of component (a) is 2 to 10%, preferably 3 to 8% in the elastic gel oily cosmetic of the present invention. If the blending amount of the component (a) is less than 2%, a satisfactory feeling of elasticity, standing stability and actual use stability cannot be obtained, and if it exceeds 10%, the spread and uniformity of the cosmetic film are not obtained. This is not preferable.
It is preferable to use a partially cross-linked organopolysiloxane polymer containing a long-chain alkyl group and a partially cross-linked organopolysiloxane polymer not containing a long-chain alkyl group in order to further improve the spread.
本発明に用いられる成分(b)の低粘度シリコ−ン油は、ジメチルポリシロキサン、メチルフェニルポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、メチルトリメチコン等が挙げられ、これらを1種又は2種以上用いることができる。尚、本発明において、成分(b)として、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン等の環状シリコーン、25℃での粘度が1〜100mm2/sの直鎖シリコ−ン等の揮発性シリコーン油を選択することにより、弾力感があり、伸び広がりがより良好な弾性ゲル状油性化粧料を得ることができる。このような成分(b)は、市販品として、シリコンKF−96(6cs)、(10cs)、(20cs)、(30cs)、(50cs)、(100cs)、シリコンKF−995、KF−994(以上信越化学工業社製)、シリコンDC−345、シリコンSH−245(以上東レ・ダウコ−ニング社製)等を挙げられ、これらを1種又は2種以上用いることができる。成分(b)の配合量としては、20〜75%の範囲であることが好ましく、さらに好ましくは25〜70%である。配合量がこの範囲であると弾力感や伸び広がりが向上するため好ましい。 Examples of the low viscosity silicone oil of component (b) used in the present invention include dimethylpolysiloxane, methylphenylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, methyltrimethicone, etc. Two or more species can be used. In the present invention, as component (b), cyclic silicone such as octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane, and volatile such as linear silicone having a viscosity at 25 ° C. of 1 to 100 mm 2 / s. By selecting silicone oil, it is possible to obtain an elastic gel-like oily cosmetic material that has a feeling of elasticity and has a better spread. Such components (b) are commercially available products such as silicon KF-96 (6 cs), (10 cs), (20 cs), (30 cs), (50 cs), (100 cs), silicon KF-995, KF-994 ( As mentioned above, manufactured by Shin-Etsu Chemical Co., Ltd.), silicon DC-345, silicon SH-245 (above manufactured by Toray Dow Corning Co., Ltd.) and the like can be mentioned, and one or more of these can be used. As a compounding quantity of a component (b), it is preferable that it is the range of 20 to 75%, More preferably, it is 25 to 70%. If the blending amount is within this range, it is preferable because the feeling of elasticity and the spread of elongation are improved.
成分(b)の配合量は、配合比が前記成分(a)、成分(b)の比で(a):(b)=1:4〜1:30の範囲であり、好ましくは(a):(b)=1:6〜1:20の範囲である。この範囲であると弾力感や伸び広がりの点で優れたものが得られる。 The blending amount of component (b) is such that the blending ratio is the ratio of component (a) and component (b) in the range of (a) :( b) = 1: 4 to 1:30, preferably (a) : (B) = 1: 6 to 1:20. If it is within this range, an excellent product can be obtained in terms of elasticity and spread.
本発明に用いられる成分(c)の粉体は、化粧料一般に使用される粉体であれば、球状、板状、針状等の形状、煙霧状、微粒子、顔料級等の粒子径、多孔質、無孔質等の粒子構造等により特に限定されず、無機粉体類、光輝性粉体類、有機粉体類、色素粉体類、複合粉体類等が挙げられる。具体的には、酸化チタン、黒酸化チタン、コンジョウ、群青、ベンガラ、黄酸化鉄、黒酸化鉄、酸化亜鉛、酸化アルミニウム、二酸化珪素、酸化マグネシウム、酸化ジルコニウム、炭酸マグネシウム、炭酸カルシウム、酸化クロム、水酸化クロム、カーボンブラック、ケイ酸アルミニウム、ケイ酸マグネシウム、ケイ酸アルミニウムマグネシウム、雲母、合成雲母、セリサイト、タルク、カオリン、炭化珪素、硫酸バリウム、ベントナイト、スメクタイト、窒化硼素等の無機粉体類、オキシ塩化ビスマス、雲母チタン、酸化鉄コーティング雲母、酸化鉄雲母チタン、有機顔料処理雲母チタン、酸化チタン処理ガラス末、アルミニウムパウダー等の光輝性粉体類、ナイロンパウダー、ポリメチルメタクリレート、ポリエチレンパウダー、ポリスチレンパウダー、オルガノポリシロキサンエラストマーパウダー、ポリメチルシルセスキオキサンパウダー、ポリウレタンパウダー、ウールパウダー、シルクパウダー、結晶セルロース、N−アシルリジン等の有機粉体類、有機タール系顔料、有機色素のレーキ顔料等の色素粉体類、微粒子酸化チタン被覆雲母チタン、微粒子酸化亜鉛被覆雲母チタン、硫酸バリウム被覆雲母チタン、酸化チタン含有二酸化珪素、酸化亜鉛含有二酸化珪素等の複合粉体等が挙げられ、これらを1種又は2種以上用いることができる。 As long as the powder of component (c) used in the present invention is a powder generally used in cosmetics, it has a spherical shape, a plate shape, a needle-like shape, a haze-like shape, a fine particle, a pigment grade particle size, a porous There are no particular limitations depending on the particle structure such as quality and non-porous, and inorganic powders, glitter powders, organic powders, pigment powders, composite powders and the like can be mentioned. Specifically, titanium oxide, black titanium oxide, conger, ultramarine, bengara, yellow iron oxide, black iron oxide, zinc oxide, aluminum oxide, silicon dioxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, chromium oxide, Inorganic powders such as chromium hydroxide, carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, sericite, talc, kaolin, silicon carbide, barium sulfate, bentonite, smectite, boron nitride , Bismuth oxychloride, titanium mica, iron oxide coated mica, iron oxide mica titanium, organic pigment-treated mica titanium, titanium oxide-treated glass powder, aluminum powder and other glittering powders, nylon powder, polymethyl methacrylate, polyethylene powder, Police Organic powders such as ren powder, organopolysiloxane elastomer powder, polymethylsilsesquioxane powder, polyurethane powder, wool powder, silk powder, crystalline cellulose, N-acyl lysine, organic tar pigment, organic pigment lake pigment, etc. Pigment powders, fine particle titanium oxide-coated mica titanium, fine particle zinc oxide-coated mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, and the like. Two or more species can be used.
本発明に用いられる成分(c)の粉体の配合量は、本発明の弾性ゲル状油性化粧料中に10〜40%であり、好ましくは20〜35%の範囲である。成分(c)の配合量が10%未満であると弾力感が得られず、化粧膜の均一性の点で好ましくなく、40%を越えると伸び広がりの点で好ましくない。 The compounding quantity of the powder of the component (c) used for this invention is 10 to 40% in the elastic gel oily cosmetics of this invention, Preferably it is the range of 20 to 35%. If the blending amount of the component (c) is less than 10%, a feeling of elasticity cannot be obtained, which is not preferable from the viewpoint of the uniformity of the decorative film, and if it exceeds 40%, it is not preferable from the viewpoint of elongation spread.
本発明に用いられる成分(d)のイヌリン脂肪酸エステルとしては、炭素数8〜32の直鎖または分岐鎖の飽和または不飽和脂肪酸とイヌリンとのエステル化合物で、イヌリンの平均分子量は300〜10,000の範囲が好ましく、これらを1種または2種以上を用いることができる。具体的には、特開平3−197409号公報や特開2002−193732号公報に記載されているものが挙げられ、市販品としては、レオパールISK(千葉製粉社製)等が挙げられる。これらのイヌリン脂肪酸エステルは、液状環状シリコーン油をゲル化させ、静値安定性を向上するととも実使用安定性を向上させる効果がある。 The inulin fatty acid ester of component (d) used in the present invention is an ester compound of a linear or branched saturated or unsaturated fatty acid having 8 to 32 carbon atoms and inulin, and the average molecular weight of inulin is 300 to 10, The range of 000 is preferable, and one or more of these can be used. Specific examples include those described in JP-A-3-197409 and JP-A-2002-193732, and examples of commercially available products include Leo Pearl ISK (manufactured by Chiba Flour Mills). These inulin fatty acid esters have the effect of gelling a liquid cyclic silicone oil to improve the static stability and the actual use stability.
本発明に用いられる成分(d)のイヌリン脂肪酸エステルの配合量は、本発明の弾性ゲル状油性化粧料中に0.5〜10%が好ましく、さらに好ましくは1〜8%である。成分(d)の配合量が0.5%未満であると実使用安定性が満足いくものでなく10%を越えると伸び広がりの点で満足いくものが得られない。 0.5-10% is preferable in the elastic gel oily cosmetics of this invention, and, as for the compounding quantity of the inulin fatty acid ester of the component (d) used for this invention, More preferably, it is 1-8%. When the blending amount of component (d) is less than 0.5%, the actual use stability is not satisfactory, and when it exceeds 10%, a satisfactory one cannot be obtained in terms of elongation spread.
本発明は弾性ゲル状油性化粧料であるため、前記必須成分以外の油性成分を配合することができる。油性成分としては、動物油、植物油、合成油等の起源及び、固形油、半固形油、液体油等の性状を問わず、例えば固形油としては、炭化水素類、ロウ類、油脂類、脂肪酸類、高級アルコール類、エステル類、硬化油類、シリコーン油類、フッ素系油類等が使用できる。具体的には、例えばパラフィンワックス、セレシンワックス、マイクロクリスタリンワックス、エチレンプロピレンコポリマー、フィッシュトロップスワックス、カカオ脂、パーム油、牛脂、モンタンワックス、ビーズワックス、カルナウバワックス、キャンデリラワックス、モクロウ、ゲイロウ、ミツロウ、ステアリン酸、ラウリン酸、ミリスチン酸、ベヘニン酸、ロジン酸、12−ヒドロキシステアリン酸、セチルアルコール、ステアリルアルコール、ベヘニルアルコール、ジステアリン酸プロピレングリコール、トリベヘン酸グリセリル、コレステロール脂肪酸エステル、N−ラウロイル−L−グルタミン酸ジ(コレステリル・ベヘニル・オクチルドデシル)、ステアリル変性オルガノポリシロキサン等が挙げられる。また、半固形油及び液状油としては、例えば炭化水素類、油脂類、エステル油類、脂肪酸類、高級アルコール類、ラノリン誘導体類、油性ゲル化剤類、シリコーン油類、類等が挙げられる。具体的には、流動パラフィン、スクワラン、ワセリン等の炭化水素類、ミンク油、マカデミアンナッツ油等の油脂類、オリーブ油、ヒマシ油、ホホバ油、トリ2―エチルヘキサン酸グリセリル、イソノナン酸イソトリデシル、2−エチルヘキサン酸セチル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸オクチルドデシル、トリオクタン酸グリセリル、ジイソステアリン酸ポリグリセリル、トリイソステアリン酸グリセリル、トリイソステアリン酸ジグリセリル、トリイソステアリン酸ポリグリセリル、リンゴ酸ジイソステアリル、ジオクタン酸ネオペンチルグリコール等のエステル類、オレイン酸、イソステアリン酸等の脂肪酸類、オレイルアルコール等の高級アルコール類、部分架橋型ポリエーテル変性メチルポリシロキサン、オレイル変性メチルポリシロキサン、ポリビニルピロリドン変性メチルポリシロキサン等のシリコーン油類、酢酸ラノリン、ラノリン脂肪酸イソプロピル、ラノリンアルコール等のラノリン誘導体類、イソステアリン酸アルミニウム、ステアリン酸カルシウム等の油性ゲル化剤類等が挙げられ、これらの1種又は2種以上用いることができる。 Since the present invention is an elastic gel oily cosmetic, oily components other than the essential components can be blended. The oily component may be of any origin, such as animal oil, vegetable oil, synthetic oil, and solid oil, semi-solid oil, liquid oil, etc., for example, solid oil includes hydrocarbons, waxes, fats and oils, fatty acids Higher alcohols, esters, hydrogenated oils, silicone oils, fluorine oils, and the like can be used. Specifically, for example, paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, fish trops wax, cacao butter, palm oil, beef tallow, montan wax, bees wax, carnauba wax, candelilla wax, molasses, gayrow , Beeswax, stearic acid, lauric acid, myristic acid, behenic acid, rosin acid, 12-hydroxystearic acid, cetyl alcohol, stearyl alcohol, behenyl alcohol, propylene glycol distearate, glyceryl tribehenate, cholesterol fatty acid ester, N-lauroyl-L -Dimethyl glutamate (cholesteryl, behenyl, octyldodecyl), stearyl-modified organopolysiloxane and the like. Examples of semi-solid oil and liquid oil include hydrocarbons, fats and oils, ester oils, fatty acids, higher alcohols, lanolin derivatives, oily gelling agents, silicone oils, and the like. Specifically, hydrocarbons such as liquid paraffin, squalane and petrolatum, oils and fats such as mink oil and macadamian nut oil, olive oil, castor oil, jojoba oil, glyceryl tri-2-ethylhexanoate, isotridecyl isononanoate, 2 -Cetyl ethylhexanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, polyglyceryl diisostearate, glyceryl triisostearate, diglyceryl triisostearate, polyglyceryl triisostearate, diisostearyl malate, dioctane Esters such as neopentyl glycol acid, fatty acids such as oleic acid and isostearic acid, higher alcohols such as oleyl alcohol, and partially crosslinked polyether-modified methyl polymers Silicone oils such as siloxane, oleyl-modified methylpolysiloxane, polyvinylpyrrolidone-modified methylpolysiloxane, lanolin derivatives such as lanolin acetate, lanolin fatty acid isopropyl, lanolin alcohol, and oily gelling agents such as aluminum isostearate and calcium stearate 1 type, or 2 or more types can be used.
本発明の弾性ゲル状油性化粧料には、本発明の効果を損なわない程度で、必要に応じて、前記必須成分以外の各種成分、例えば、界面活性剤、水性成分、水溶性高分子、紫外線吸収剤、保湿剤、褪色防止剤、酸化防止剤、消泡剤、美容成分、防腐剤、香料などを各種の効果を付与するために適宜配合することができる。 The elastic gel-like oily cosmetic of the present invention has various components other than the essential components, for example, a surfactant, an aqueous component, a water-soluble polymer, an ultraviolet ray, and the like, as long as the effects of the present invention are not impaired. Absorbers, humectants, anti-fading agents, antioxidants, antifoaming agents, cosmetic ingredients, preservatives, fragrances and the like can be appropriately blended in order to impart various effects.
粉体の分散性向上を目的とする界面活性剤としては、化粧料一般に用いられている界面活性剤であればよく、ノニオン性界面活性剤、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤等が挙げられる。
ノニオン界面活性剤としては、例えば、グリセリン脂肪酸エステル及びそのアルキレングリコール付加物、ポリグリセリン脂肪酸エステル及びそのアルキレングリコール付加物、プロピレングリコール脂肪酸エステル及びそのアルキレングリコール付加物、ソルビタン脂肪酸エステル及びそのアルキレングリコール付加物、ソルビトールの脂肪酸エステル及びそのアルキレングリコール付加物、ポリアルキレングリコール脂肪酸エステル、蔗糖脂肪酸エステル、ポリオキシアルキレンアルキルエーテル、グリセリンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレン硬化ヒマシ油、ラノリンのアルキレングリコール付加物、ポリオキシアルキレン変性シリコーン等が挙げられる。
アニオン界面活性剤としては、例えば、ステアリン酸、ラウリン酸のような脂肪酸及びそれらの無機及び有機塩、アルキルベンゼン硫酸塩、アルキルスルホン酸塩、α−オレフィンスルホン酸塩、ジアルキルスルホコハク酸塩、α−スルホン化脂肪酸塩、アシルメチルタウリン塩、N−メチル−N−アルキルタウリン塩、ポリオキシエチレンアルキルエーテル硫酸塩、ポリオキシエチレンアルキルフェニルエーテル硫酸塩、アルキル燐酸塩、ポリオキシエチレンアルキルエーテル燐酸塩、ポリオキシエチレンアルキルフェニルエーテル燐酸塩、N−アシルアミノ酸塩、N−アシル−N−アルキルアミノ酸塩、ο−アルキル置換リンゴ酸塩、アルキルスルホコハク酸塩等が挙げられる。
カチオン界面活性剤としては、例えば、アルキルアミン塩、ポリアミン及びアルカノルアミン脂肪酸誘導体、アルキル四級アンモニウム塩、環式四級アンモニウム塩等が挙げられる。
両性界面活性剤としては、アミノ酸タイプやベタインタイプのカルボン酸型、硫酸エステル型、スルホン酸型、リン酸エステル型のものがあり、人体に対して安全とされるものが使用できる。例えば、大豆リン脂質が挙げられる。
As the surfactant for improving the dispersibility of the powder, any surfactant generally used in cosmetics may be used. Nonionic surfactant, anionic surfactant, cationic surfactant, amphoteric Surfactant etc. are mentioned.
Nonionic surfactants include, for example, glycerin fatty acid esters and alkylene glycol adducts thereof, polyglycerin fatty acid esters and alkylene glycol adducts thereof, propylene glycol fatty acid esters and alkylene glycol adducts thereof, sorbitan fatty acid esters and alkylene glycol adducts thereof. , Fatty acid ester of sorbitol and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, alkylene glycol of lanolin Examples include adducts, polyoxyalkylene-modified silicones, and the like.
Examples of the anionic surfactant include fatty acids such as stearic acid and lauric acid and their inorganic and organic salts, alkylbenzene sulfates, alkyl sulfonates, α-olefin sulfonates, dialkyl sulfosuccinates, α-sulfones. Fatty acid salt, acylmethyl taurine salt, N-methyl-N-alkyl taurine salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxy Examples thereof include ethylene alkylphenyl ether phosphate, N-acyl amino acid salt, N-acyl-N-alkyl amino acid salt, o-alkyl substituted malate, alkyl sulfosuccinate and the like.
Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, and cyclic quaternary ammonium salts.
Examples of amphoteric surfactants include amino acid type and betaine type carboxylic acid types, sulfate ester types, sulfonic acid types, and phosphate ester types, and those that are safe for the human body can be used. An example is soybean phospholipid.
モイスチャー効果やみずみずしい感触を付与する目的で用いる水性成分としては、水及び水に可溶な成分であれば何れでもよく、例えば、プロピレングリコール、1,3−ブチレングリコール、ジプロピレングリコール、ポリエチレングリコール等のグリコール類、グリセリン、ジグリセリン、ポリグリセリン等のグリセロール類、アロエベラ、ウイッチヘーゼル、ハマメリス、キュウリ、レモン、ラベンダー、ローズ等の植物抽出液等が挙げられる。但し、本発明は油性化粧料のため、得られる効果を損なわないためには、水性成分の配合量は10%以下であることが好ましい。
感触の改善を目的で用いる水溶性高分子としては、グアーガム、コンドロイチン硫酸ナトリウム、ヒアルロン酸、アラビアガム、アルギン酸ナトリウム、カラギーナン、ムコ多糖、コラーゲン、エラスチン、ケラチン等の天然系のもの、メチルセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース等の半合成系のもの、カルボキシビニルポリマー、ポリビニルアルコール、ポリビニルピロリドン、ポリアクリル酸ナトリウム等の合成系のものを挙げることができる。
紫外線吸収剤としては、例えばベンゾフェノン系、PABA系、ケイ皮酸系、サリチル酸系、4−tert−ブチル−4’−メトキシジベンゾイルメタン、オキシベンゾン等が挙げられる。酸化防止剤としては、例えばα−トコフェロール、アスコルビン酸等、美容成分としては、例えばビタミン類、タンパク質、消炎剤、生薬等、防腐剤としては、例えばパラオキシ安息香酸エステル、フェノキシエタノール等が挙げられる。
As an aqueous component used for the purpose of imparting a moisture effect and a fresh feeling, any component that is soluble in water and water may be used. For example, propylene glycol, 1,3-butylene glycol, dipropylene glycol, polyethylene glycol, etc. Glycerols, glycerols such as glycerin, diglycerin and polyglycerin, plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose. However, since the present invention is an oily cosmetic, the blending amount of the aqueous component is preferably 10% or less so as not to impair the effects obtained.
Examples of water-soluble polymers used for the purpose of improving the touch include guar gum, sodium chondroitin sulfate, hyaluronic acid, gum arabic, sodium alginate, carrageenan, mucopolysaccharide, collagen, elastin, keratin, etc., methyl cellulose, hydroxyethyl cellulose And semi-synthetic materials such as carboxymethyl cellulose, and synthetic materials such as carboxyvinyl polymer, polyvinyl alcohol, polyvinyl pyrrolidone, and sodium polyacrylate.
Examples of the ultraviolet absorber include benzophenone, PABA, cinnamic acid, salicylic acid, 4-tert-butyl-4′-methoxydibenzoylmethane, oxybenzone, and the like. Examples of antioxidants include α-tocopherol and ascorbic acid. Examples of cosmetic ingredients include vitamins, proteins, anti-inflammatory agents and herbal medicines. Examples of antiseptics include paraoxybenzoic acid esters and phenoxyethanol.
本発明の弾性ゲル状油性化粧料は、ファンデーション、頬紅、口紅、アイシャドウ、アイブロウ、コンシーラー等のメーキャップ化粧料、日焼け止め化粧料等のスキンケア化粧料等が挙げられるが、本発明の効果が顕著に発揮される化粧料は、メーキャップ化粧料である。 Examples of the elastic gel oily cosmetic of the present invention include makeup cosmetics such as foundation, blusher, lipstick, eye shadow, eyebrow and concealer, and skin care cosmetics such as sunscreen cosmetics, etc., but the effect of the present invention is remarkable. The cosmetics exhibited in the makeup are makeup cosmetics.
本発明の弾性ゲル状油性化粧料は、通常公知の方法、例えば、成分(a)、(b)及び成分(c)を加熱混合し、更に成分(d)を必要に応じてその他成分を均一に分散させることにより製造することができる。 The elastic gel oily cosmetics of the present invention are usually known methods, for example, the components (a), (b) and the component (c) are heated and mixed, and the component (d) is mixed with other components as necessary. It can be manufactured by dispersing in the slag.
次に以下に実施例をあげて本発明をさらに説明するが、本発明はこれら実施例に限定されるものではない。 EXAMPLES Next, the present invention will be further described with reference to the following examples, but the present invention is not limited to these examples.
実施例1〜7及び比較例1〜6:弾性ゲル状ファンデーション
表1に示す組成の弾性ゲル状ファンデーションを以下に示す製造方法により調製し、「弾力感」、「伸び広がり」、「化粧膜の均一性」、「静置安定性」、「実使用安定性」について以下に示す評価方法及び判断基準により評価し、結果を併せて表1に示した。
また、各試料について弾性を表す値を、前記測定方法に従って測定した結果を表2に示した。尚、本発明では、それぞれの範囲を弾性がるものと定義した。tanδ1(0.05〜10の範囲)、tanδ1/tanδ2(1.5〜5の範囲)、応力のピーク値(進入硬度)(10〜200の範囲)
Examples 1 to 7 and Comparative Examples 1 to 6: Elastic Gel Foundations An elastic gel foundation having the composition shown in Table 1 was prepared by the manufacturing method shown below, and “elasticity”, “elongation”, “decorative film” The “uniformity”, “stationary stability”, and “actual use stability” were evaluated by the following evaluation methods and criteria, and the results are shown in Table 1.
In addition, Table 2 shows the results of measuring the value representing elasticity for each sample according to the measurement method. In the present invention, each range is defined as elastic. tan δ1 (in the range of 0.05 to 10), tan δ1 / tan δ2 (in the range of 1.5 to 5), peak value of stress (ingress hardness) (in the range of 10 to 200)
注1:シリコン KSG−16(信越化学工業社製)
注2:シリコンKF−96(10CS)(信越化学工業社製)
注3:レオパールISK(千葉製粉社製)
注4:シリコンKF−995(信越化学工業社製)
注5:シリコン KSG−15(信越化学工業社製)
注6:サイロスフェアC−1504(富士シリシア化学社製)
Note 1: Silicon KSG-16 (manufactured by Shin-Etsu Chemical Co., Ltd.)
Note 2: Silicon KF-96 (10CS) (Shin-Etsu Chemical Co., Ltd.)
Note 3: Leopard ISK (Chiba Flour Mills)
Note 4: Silicon KF-995 (manufactured by Shin-Etsu Chemical Co., Ltd.)
Note 5: Silicon KSG-15 (manufactured by Shin-Etsu Chemical Co., Ltd.)
Note 6: Cyrossphere C-1504 (manufactured by Fuji Silysia Chemical Ltd.)
(製造方法)
A:成分1〜7を均一に分散する。
B:成分8〜12を90℃まで加熱して溶解し、混合する。
C:成分13〜17及びA、Bを混合する。
D:Cを90℃まで加温し弾性ゲル状油性ファンデーションを得た。
(Production method)
A: Components 1 to 7 are uniformly dispersed.
B: Components 8 to 12 are heated to 90 ° C to dissolve and mixed.
C: Components 13 to 17 and A and B are mixed.
D: C was heated to 90 ° C. to obtain an elastic gel oily foundation.
(評価項目):(a)「弾力感」、(b)「伸び広がり」、(c)「化粧膜の均一性」、(d)「静置安定性」、(e)「実使用安定性」 (Evaluation items): (a) “Elasticity”, (b) “Elongation spread”, (c) “Uniformity of cosmetic film”, (d) “Standing stability”, (e) “Actual use stability” "
(評価方法):(a)〜(c)化粧料専門パネル20名に前記実施例及び比較例の弾性ゲル状ファンデーションを使用してもらい、「弾力感」、「伸び広がり」、「化粧膜の均一性」について、各自が以下の基準に従って7段階評価し、更に、全パネルの評点の平均点を以下の判定基準に従って判定した。
(絶対評価)
(評点):(評価)
6:非常に良い
5:良い
4:やや良い
3:普通
2:やや悪い
1:悪い
0:非常に悪い
(判定基準)
(評点平均値) :(判定)
5点を超える :非常に良好:◎
3.5点を超えて5点以下 :良好 :○
2点を超えて3.5点以下 :やや不良 :△
2点以下 :不良 :×
(Evaluation method): (a) to (c) 20 panelists specializing in cosmetics use the elastic gel-like foundations of the above-mentioned examples and comparative examples. Each of the “uniformity” was evaluated according to the following criteria in seven stages, and the average score of all panels was determined according to the following criteria.
(Absolute evaluation)
(Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad (judgment criteria)
(Average score): (Judgment)
More than 5 points: Very good: ◎
Over 3.5 points and 5 points or less: Good: ○
Over 2 points and 3.5 points or less: Somewhat bad: △
2 points or less: Defect: ×
(評価方法):(d)前記実施例及び比較例の弾性ゲル状ファンデーションを50℃のインキュベーターに2ヶ月間放置し、室温に戻した時の外観状態を観察し、室温で2ヶ月間保存したものと比べ、「静置安定性」として以下に示す基準により判定した。
判定基準:
外観の状態変化 :判定
全く変化無し :◎
発汗、分離、排液による僅かな変化(問題無し):○
発汗、分離、排液による変化 :△
発汗、分離、排液による激しい変化 :×
(Evaluation method): (d) The elastic gel-like foundations of the above examples and comparative examples were left in an incubator at 50 ° C. for 2 months, and the appearance when returned to room temperature was observed and stored at room temperature for 2 months. Compared to the above, the “static stability” was determined according to the following criteria.
Judgment criteria:
Appearance state change: Judgment no change: ◎
Slight changes due to sweating, separation, and drainage (no problem): ○
Changes due to sweating, separation, and drainage: △
Severe changes due to sweating, separation, or drainage: ×
(評価方法):(e)前記実施例及び比較例の弾性ゲル状ファンデーションを一日10回マットでこすり、これをバックに入れて持ち歩くことを2週間連続で行ったあとの外観状態を観察し、静置で2週間保存したものと比べ、「実使用安定性」として以下に示す基準により判定した。
判定基準:
外観の状態変化 :判定
全く変化無し :◎
発汗、分離、排液、よれによる僅かな変化(問題無し):○
発汗、分離、排液、よれによる変化 :△
発汗、分離、排液、よれによる激しい変化 :×
(Evaluation method): (e) The elastic gel-like foundations of the above-mentioned examples and comparative examples were rubbed with a mat 10 times a day, and the appearance after observation was carried out for 2 weeks in a row. In comparison with the samples stored for 2 weeks, the “actual use stability” was determined according to the following criteria.
Judgment criteria:
Appearance state change: Judgment no change: ◎
Slight changes due to sweating, separation, drainage, and twisting (no problem): ○
Changes due to sweating, separation, drainage, and twisting: △
Severe changes due to sweating, separation, drainage, and twisting: ×
表1の結果から明らかなように、本発明の実施品である実施例1〜7の弾性ゲル状ファンデーションは、「弾力感」があり、「伸び広がり」、「化粧膜の均一性」、「静置安定性」、「実使用安定性」の全ての項目に優れた弾性ゲル状油性化粧料であった。実施例1は、実施例4に比べ弾力感があり、静置安定性や実使用安定性も良好であった為、全ての項目でとても良い評価が得られた。
一方、成分(a)を配合していない比較例1では、弾力感がなく、静置安定性(液体油が分離する)において実施例より劣っていた。また、成分(c)を配合していない比較例4では、発色はもとより、カバー力がなく、弾力感が得られず、実施例より劣っていた。また、成分(d)を配合していない比較例6では、実使用安定性(容器中に化粧料がよれる)において実施例より劣っていた。
As is clear from the results of Table 1, the elastic gel foundations of Examples 1 to 7 which are the products of the present invention have “elasticity”, “elongation spread”, “uniformity of the cosmetic film”, “ It was an elastic gel-like oily cosmetic excellent in all items of “Stability of standing” and “Stability of actual use”. Since Example 1 had a feeling of elasticity compared to Example 4 and was also stable in stability and actual use, very good evaluation was obtained for all items.
On the other hand, in Comparative Example 1 in which the component (a) was not blended, there was no elasticity and it was inferior to the examples in the stationary stability (liquid oil separated). Further, in Comparative Example 4 in which the component (c) was not blended, not only the coloring but also the covering power was not obtained and the elasticity was not obtained, which was inferior to the examples. Moreover, in the comparative example 6 which does not mix | blend a component (d), it was inferior to the Example in actual use stability (cosmetics depend on in a container).
表2の結果から明らかなように、本発明の実施品である実施例1〜7の弾性ゲル状ファンデーションは、「弾力」を表す値が全て範囲に入っており、官能検査の「弾力感」と一致するものであった。一方、比較例1、2、4はtanδ1/tanδ2の値が、それぞれ1.2、1.4、1.0となり、周波数を変えた時においても応力が変わらない弾力項が低いものであるが、評価項目の弾力感も得られないものとなった。また、比較例3はtanδ1が12と、非常に弾力項が非常に高くなるものは、評価項目の伸び広がりを得られないものであった。さらに、比較例の5は進入硬度が210となり、非常に固い為、弾力感、伸び広がり、化粧膜の均一性を得られないものであった。 As is clear from the results in Table 2, the elastic gel foundations of Examples 1 to 7, which are the products of the present invention, all have values representing “elasticity” within the range, and “elasticity” of the sensory test. Was consistent with. On the other hand, in Comparative Examples 1, 2, and 4, the values of tan δ1 / tan δ2 are 1.2, 1.4, and 1.0, respectively, and the elasticity term that does not change the stress even when the frequency is changed is low. Also, the elasticity of the evaluation items could not be obtained. In Comparative Example 3, when tan δ1 was 12, and the elasticity term was extremely high, it was not possible to obtain the expansion of the evaluation items. Further, Comparative Example 5 had an entry hardness of 210, which was very hard, so that it was not possible to obtain a feeling of elasticity, spread and uniformity of the decorative film.
実施例8:弾性ゲル状頬紅
(成分) (%)
1.酸化チタン 1
2.酸化亜鉛 1
3.球状ナイロンパウダー(平均粒子5μm) 5
4.合成マイカ(注6) 5
5.ベンガラ 0.8
6.黄酸化鉄 0.5
7.黒酸化鉄 0.1
8.雲母チタン(注7) 2
9.ジメチルポリシロキサン(注2) 20
10.部分架橋型ポリシロキサン混合物(注1) 15
11.キャンデリラロウ 1
12.イヌリン脂肪酸エステル(注3) 1
13.シクロペンタシロキサン(注4) 残量
14.部分架橋型ポリシロキサン混合物(注5) 25
15.パラオキシ安息香酸メチル 0.2
16.香料 0.1
Example 8: Elastic gel blusher (component) (%)
1. Titanium oxide 1
2. Zinc oxide 1
3. Spherical nylon powder (average particle size 5μm) 5
4). Synthetic mica (Note 6) 5
5. Bengala 0.8
6). Yellow iron oxide 0.5
7). Black iron oxide 0.1
8). Mica titanium (Note 7) 2
9. Dimethylpolysiloxane (Note 2) 20
10. Partially cross-linked polysiloxane mixture (Note 1) 15
11. Candelilla Row 1
12 Inulin fatty acid ester (Note 3) 1
13. Cyclopentasiloxane (Note 4) Residual amount 14. Partially cross-linked polysiloxane mixture (Note 5) 25
15. Methyl paraoxybenzoate 0.2
16. Fragrance 0.1
注6:PDM−10L(トピー工業社製)
注7:FLAMENCO SUPER PEARL(メルク社製)
Note 6: PDM-10L (Topy Industries, Ltd.)
Note 7: FLAMENCO SUPER PEARL (Merck)
(製造方法)
A:成分1〜9を均一に分散する。
B:成分10〜12を90℃まで加熱して溶解し、混合する。
C:成分13〜16及びA、Bを混合する。
D:Cを90℃まで加温し弾性ゲル状油性頬紅を得た。
(Production method)
A: Components 1 to 9 are uniformly dispersed.
B: Components 10 to 12 are heated to 90 ° C. to dissolve and mixed.
C: Components 13 to 16 and A and B are mixed.
D: C was heated to 90 ° C. to obtain an elastic gel oily blusher.
以上のようにして得られた実施例8の弾性ゲル状頬紅は、「弾力感」、「伸び広がり」、「化粧膜の均一性」、「静置安定性」、「実使用安定性」の全ての項目に優れた弾性ゲル状油性化粧料であった。また物性値は、tanδ1=0.4、tanδ1/tanδ2=3、応力のピーク値(進入硬度)=35であり、弾力性のあるものであった。 The elastic gel blusher of Example 8 obtained as described above has “elasticity”, “elongation spread”, “uniformity of cosmetic film”, “static stability”, and “actual use stability”. It was an elastic gel oily cosmetic excellent in all items. The physical property values were tan δ1 = 0.4, tan δ1 / tan δ2 = 3, and the peak value of stress (approach hardness) = 35, which was elastic.
実施例9:弾性ゲル状コントロールカラー
(成分) (%)
1.シリコーン処理酸化チタン 20
2.酸化亜鉛 2
3.シリコーン処理タルク 8
4.マイカ 4
5.ベンガラ 0.4
6.黄酸化鉄 3
7.黒酸化鉄 0.3
8.PEG−9ポリジメチルシロキシエチルジメチコン 1
9.ジメチルポリシロキサン 15
10.部分架橋型ポリシロキサン混合物(注1) 15
11.キャンデリラロウ(注8) 1
12.シクロペンタシロキサン 残量
13.部分架橋型ポリシロキサン混合物(注5) 20
14.ナイロン末(注9) 1
15.イヌリン脂肪酸エステル 2
16.パラオキシ安息香酸メチル 0.2
17.香料 0.2
Example 9: Elastic gel-like control color (component) (%)
1. Silicone-treated titanium oxide 20
2. Zinc oxide 2
3. Silicone-treated talc 8
4). Mica 4
5. Bengala 0.4
6). Yellow iron oxide 3
7). Black iron oxide 0.3
8). PEG-9 polydimethylsiloxyethyl dimethicone 1
9. Dimethylpolysiloxane 15
10. Partially cross-linked polysiloxane mixture (Note 1) 15
11. Candelilla wax (Note 8) 1
12 Cyclopentasiloxane remaining amount 13. Partially cross-linked polysiloxane mixture (Note 5) 20
14 Nylon powder (Note 9) 1
15. Inulin fatty acid ester 2
16. Methyl paraoxybenzoate 0.2
17. Fragrance 0.2
注8:精製キャンデリラワックスMD−21(日本ナチュラルプロダクツ社製)
注9:東レ ナイロン粉末 SP−500(東レ社製)
Note 8: Refined candelilla wax MD-21 (manufactured by Nippon Natural Products)
Note 9: Toray nylon powder SP-500 (Toray Industries, Inc.)
(製造方法)
A:成分1〜7を均一に分散する。
B:成分8〜11を90℃まで加熱して溶解し、混合する。
C:成分12〜17及びA、Bを混合する。
D:Cを90℃まで加温し弾性ゲル状油性コントロールカラーを得た。
(Production method)
A: Components 1 to 7 are uniformly dispersed.
B: Components 8 to 11 are heated to 90 ° C to dissolve and mixed.
C: Components 12 to 17 and A and B are mixed.
D: C was heated to 90 ° C. to obtain an elastic gel oil control color.
以上のようにして得られた実施例8の弾性ゲル状頬紅は、「弾力感」、「伸び広がり」、「化粧膜の均一性」、「静置安定性」、「実使用安定性」の全ての項目に優れた弾性ゲル状油性化粧料であった。また物性値は、tanδ1=0.24、tanδ1/tanδ2=2.5、応力のピーク値(進入硬度)=130であり、弾力性のあるものであった。 The elastic gel blusher of Example 8 obtained as described above has “elasticity”, “elongation spread”, “uniformity of cosmetic film”, “static stability”, and “actual use stability”. It was an elastic gel oily cosmetic excellent in all items. The physical property values were tan δ1 = 0.24, tan δ1 / tan δ2 = 2.5, and the peak value of stress (approach hardness) = 130, which was elastic.
Claims (5)
(a)部分架橋型オルガノポリシロキサン重合物 2〜10質量%
(b)低粘度シリコーン油
(c)粉体 10〜40質量%
(d)イヌリン脂肪酸エステル
を配合したことを特徴とする弾性ゲル状油性化粧料。 The following components (a) to (d);
(A) 2-10% by mass of partially crosslinked organopolysiloxane polymer
(B) Low-viscosity silicone oil (c) Powder 10-40% by mass
(D) An elastic gel oily cosmetic comprising an inulin fatty acid ester.
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JP2010163370A (en) * | 2009-01-13 | 2010-07-29 | Kao Corp | Oily cosmetic for amending unevenness |
JP2012184206A (en) * | 2011-03-08 | 2012-09-27 | Kose Corp | Oily solid cosmetic |
JP2019104710A (en) * | 2017-12-13 | 2019-06-27 | 東色ピグメント株式会社 | Oily cosmetic |
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JPH03197409A (en) * | 1989-12-27 | 1991-08-28 | Kobayashi Kose Co Ltd | Fructo-oligosaccharide fatty acid ester derivative and cosmetic containing the same |
JP2004244333A (en) * | 2003-02-12 | 2004-09-02 | Noevir Co Ltd | Oily cosmetic |
JP2005104894A (en) * | 2003-09-30 | 2005-04-21 | Haba Laboratories Inc | Oily cosmetic |
JP2005200369A (en) * | 2004-01-16 | 2005-07-28 | Nippon Menaade Keshohin Kk | Cosmetic |
JP2005314369A (en) * | 2004-03-29 | 2005-11-10 | Tokiwa Corp | Solid oily cosmetic |
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JPH03197409A (en) * | 1989-12-27 | 1991-08-28 | Kobayashi Kose Co Ltd | Fructo-oligosaccharide fatty acid ester derivative and cosmetic containing the same |
JP2004244333A (en) * | 2003-02-12 | 2004-09-02 | Noevir Co Ltd | Oily cosmetic |
JP2005104894A (en) * | 2003-09-30 | 2005-04-21 | Haba Laboratories Inc | Oily cosmetic |
JP2005200369A (en) * | 2004-01-16 | 2005-07-28 | Nippon Menaade Keshohin Kk | Cosmetic |
JP2005314369A (en) * | 2004-03-29 | 2005-11-10 | Tokiwa Corp | Solid oily cosmetic |
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JP2010163370A (en) * | 2009-01-13 | 2010-07-29 | Kao Corp | Oily cosmetic for amending unevenness |
JP2012184206A (en) * | 2011-03-08 | 2012-09-27 | Kose Corp | Oily solid cosmetic |
JP2019104710A (en) * | 2017-12-13 | 2019-06-27 | 東色ピグメント株式会社 | Oily cosmetic |
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