JP2021098677A - Detergent composition - Google Patents
Detergent composition Download PDFInfo
- Publication number
- JP2021098677A JP2021098677A JP2019232226A JP2019232226A JP2021098677A JP 2021098677 A JP2021098677 A JP 2021098677A JP 2019232226 A JP2019232226 A JP 2019232226A JP 2019232226 A JP2019232226 A JP 2019232226A JP 2021098677 A JP2021098677 A JP 2021098677A
- Authority
- JP
- Japan
- Prior art keywords
- extract
- skin
- fatty acid
- salt
- detergent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 56
- 239000003599 detergent Substances 0.000 title abstract description 26
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 47
- 239000000194 fatty acid Substances 0.000 claims abstract description 47
- 229930195729 fatty acid Natural products 0.000 claims abstract description 47
- -1 fatty acid salt Chemical class 0.000 claims abstract description 40
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims abstract description 11
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 7
- 229940070765 laurate Drugs 0.000 claims abstract description 6
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims abstract description 5
- 229940105132 myristate Drugs 0.000 claims abstract description 5
- 150000003839 salts Chemical class 0.000 claims description 15
- 239000012459 cleaning agent Substances 0.000 claims description 10
- 239000002280 amphoteric surfactant Substances 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 4
- 239000006260 foam Substances 0.000 abstract description 32
- 238000005406 washing Methods 0.000 abstract description 25
- 229940009098 aspartate Drugs 0.000 abstract description 6
- 206010040880 Skin irritation Diseases 0.000 abstract 1
- 239000002563 ionic surfactant Substances 0.000 abstract 1
- 230000036556 skin irritation Effects 0.000 abstract 1
- 231100000475 skin irritation Toxicity 0.000 abstract 1
- 239000000284 extract Substances 0.000 description 72
- 210000003491 skin Anatomy 0.000 description 44
- 150000004665 fatty acids Chemical class 0.000 description 38
- 238000005187 foaming Methods 0.000 description 26
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 13
- 239000011734 sodium Substances 0.000 description 12
- 238000002156 mixing Methods 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
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- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 8
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 8
- 239000000049 pigment Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000003240 coconut oil Substances 0.000 description 7
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- 125000002252 acyl group Chemical group 0.000 description 6
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- 229910052708 sodium Inorganic materials 0.000 description 6
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
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- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 5
- 230000007794 irritation Effects 0.000 description 5
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- 125000004432 carbon atom Chemical group C* 0.000 description 4
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- 239000000419 plant extract Substances 0.000 description 4
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 4
- 235000019512 sardine Nutrition 0.000 description 4
- 239000002453 shampoo Substances 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 239000008117 stearic acid Substances 0.000 description 4
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- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
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- 230000000052 comparative effect Effects 0.000 description 3
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- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 3
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- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 102000008186 Collagen Human genes 0.000 description 2
- 108010035532 Collagen Proteins 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- FWKQNCXZGNBPFD-UHFFFAOYSA-N Guaiazulene Chemical compound CC(C)C1=CC=C(C)C2=CC=C(C)C2=C1 FWKQNCXZGNBPFD-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000004909 Moisturizer Substances 0.000 description 2
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
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- 229910052783 alkali metal Inorganic materials 0.000 description 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 2
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- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
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Landscapes
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Abstract
Description
本発明は、洗浄剤組成物に関し、詳しくは、泡立ちと泡質(弾力性)が良好で、且つ洗浄後の肌がきしまず、しっとりとした感触を有する洗浄剤組成物に関する。 The present invention relates to a cleansing composition, and more particularly to a cleansing composition having good foaming and foam quality (elasticity), and having a moist feel without squeaking the skin after washing.
近年、自分が敏感肌であると認識する消費者が増加しており、洗浄剤組成物においても洗浄機能だけでなく、皮膚に対する刺激緩和性、保湿力などの付加価値的機能を備えることが求められてきている。また、一方で泡立ちの良さや洗浄力などの、洗浄剤としての基本性能も求められている機能の一つである。 In recent years, the number of consumers who recognize that they have sensitive skin is increasing, and it is required that the detergent composition has not only a cleansing function but also an added value function such as irritation-relieving property and moisturizing power for the skin. Has been done. On the other hand, it is one of the functions that are required to have basic performance as a cleaning agent, such as good foaming and detergency.
その観点から、皮膚に近いpH領域での応用が可能であり、皮膚に対する刺激性の低いアミノ酸系界面活性剤が注目されている中、アミノ酸系界面活性剤、ベタイン系両性界面活性剤、ノニオン性界面活性剤を組み合わせて、低刺激であり、高粘度で調製可能な洗浄剤組成物(例えば特許文献1)や、高級脂肪酸塩、アシルグリシン塩、アシルアスパラギン酸塩、アシルメチルタウリン塩を組み合わせて、洗浄性、バイオフィルム除去性、皮膚低刺激性を有した洗浄剤組成物(例えば特許文献2)、N−アシルグルタミン酸塩、及びN−アシルアスパラギン酸塩を組み合わせることで、皮膚に対して柔和で、きめが細かく、泡の肌への密着性が良い洗浄剤組成物(例えば特許文献3)、アシルアスパラギン酸塩とアシルメチルタウリンMg塩を組み合わせることで、皮膚に対する刺激が緩和で、豊かな泡立ちを有する洗浄剤組成物(例えば特許文献4)などが開発されている。
しかしながら、これらの洗浄剤組成物はアミノ酸系界面活性剤の皮膚に対する緩和性といった特長は活かしているものの、消費者が洗顔やボディソープといった洗浄料を使用する上で不可欠要素である泡立ちと泡質(弾力性)の観点で不十分であった。 However, although these cleansing compositions take advantage of the mildness of amino acid-based surfactants to the skin, foaming and foam quality are essential elements for consumers to use cleansers such as face wash and body soap. It was insufficient in terms of (elasticity).
このような背景から、泡立ちと泡質(弾力性)が良好で、且つ洗浄後の肌がきしまず、しっとりとした感触を有する洗浄剤組成物が求められている。 Against this background, there is a demand for a cleansing composition having good foaming and foam quality (elasticity), which does not make the skin squeaky after washing and has a moist feel.
本発明は上記課題を鑑みてなされたものであり、その目的は、泡立ちと泡質(弾力性)が良好で、且つ洗浄後の肌がきしまず、しっとりとした感触を有する洗浄剤組成物を提供することにある。 The present invention has been made in view of the above problems, and an object of the present invention is to provide a cleansing composition having good foaming and foam quality (elasticity), which does not make the skin squeaky after washing and has a moist feel. To provide.
本発明者等は、本発明の目的を達成するために鋭意研究した結果、所定の脂肪酸塩とN−アシルアスパラギン塩とN−アシルメチルタウリン塩を組み合わせることにより、泡立ちと泡質(弾力性)が良好で、且つ洗浄後の肌がきしまず、しっとりとした感触を有する洗浄剤組成物が得られることを見出し、本発明を完成した。 As a result of diligent research to achieve the object of the present invention, the present inventors have obtained foaming and foam quality (elasticity) by combining a predetermined fatty acid salt, N-acylasparagin salt and N-acylmethyltaurine salt. The present invention has been completed by finding that a cleaning agent composition can be obtained that has good results, does not cause the skin to become squeaky after washing, and has a moist feel.
第一の発明は、
(A)ミリスチン酸塩を含みラウリン酸塩を含まない脂肪酸塩
(B)N−アシルアスパラギン酸塩
(C)N−アシルメチルタウリン塩
を含有することを特徴とする洗浄剤組成物である。
The first invention is
A cleaning composition comprising (A) a fatty acid salt containing myristate and not containing laurate (B) N-acylaspartate (C) N-acylmethyltaurine salt.
第二の発明は、更に(D)両性界面活性剤を含有する、第一の発明に記載の洗浄剤組成物である。 The second invention is the detergent composition according to the first invention, which further contains (D) an amphoteric surfactant.
第三の発明は、更に(E)アルキルポリグルコシドを含有する、第一又は第二の発明に記載の洗浄剤組成物である。 The third invention is the detergent composition according to the first or second invention, which further contains (E) an alkyl polyglucoside.
第四の発明は、前記成分(A)が、ミリスチン酸塩を3〜12質量%含有する、第一乃至第三の発明のいずれかに記載の洗浄剤組成物である。 The fourth invention is the detergent composition according to any one of the first to third inventions, wherein the component (A) contains 3 to 12% by mass of myristic acid salt.
本発明によれば、泡立ちと泡質(弾力性)が良好で、且つ洗浄後の肌がきしまず、しっとりとした感触を有する洗浄剤組成物を提供することができる。 According to the present invention, it is possible to provide a cleansing composition having good foaming and foam quality (elasticity), which does not make the skin squeaky after washing and has a moist feel.
以下、本発明の洗浄剤組成物について詳細に説明する。 Hereinafter, the detergent composition of the present invention will be described in detail.
<成分(A) ミリスチン酸塩を含みラウリン酸塩を含まない脂肪酸塩>
本発明の洗浄剤組成物で用いられる成分(A)はミリスチン酸塩を含みラウリン酸塩を含まない脂肪酸塩である。成分(A)を配合することにより、泡立ちと泡質(弾力性)を向上させることができる。脂肪酸塩を構成する脂肪酸は、泡立ちと泡質(弾力性)の観点から、炭素数14の飽和脂肪酸を含有することが好ましい。また皮膚に対する刺激の観点から、炭素数12以下の脂肪酸塩を含有しないことが好ましい。例えばミリスチン酸、パルミチン酸、ステアリン酸などの単一の脂肪酸や、ヤシ油脂肪酸、牛脂脂肪酸、ヒマシ油脂肪酸、オリーブ油脂肪酸、パーム油脂肪酸などから誘導される脂肪酸、又はそれらの混合物が挙げられる。脂肪酸塩を構成する塩としては、例えばナトリウム塩、カリウム塩等のアルカリ金属塩、低級アルカノールアミン塩などが挙げられるが、好ましくは、ナトリウム塩、カリウム塩であり、安定性の観点からは特にカリウム塩が好ましい。
<Component (A) Fatty acid salt containing myristic acid salt and not laurate salt>
The component (A) used in the detergent composition of the present invention is a fatty acid salt containing myristate and not laurate. By blending the component (A), foaming and foam quality (elasticity) can be improved. The fatty acid constituting the fatty acid salt preferably contains a saturated fatty acid having 14 carbon atoms from the viewpoint of foaming and foam quality (elasticity). Further, from the viewpoint of irritation to the skin, it is preferable not to contain a fatty acid salt having 12 or less carbon atoms. Examples thereof include single fatty acids such as myristic acid, palmitic acid and stearic acid, fatty acids derived from coconut oil fatty acids, beef fat fatty acids, castor oil fatty acids, olive oil fatty acids, palm oil fatty acids and the like, or mixtures thereof. Examples of the salt constituting the fatty acid salt include alkali metal salts such as sodium salt and potassium salt, lower alkanolamine salt and the like, but sodium salt and potassium salt are preferable, and potassium is particularly preferable from the viewpoint of stability. Salt is preferred.
また、皮膚への刺激緩和の観点から、本発明における脂肪酸塩は、ラウリン酸以外の脂肪酸の塩である。ラウリン酸塩は角層内に入り込み、細胞間脂質を乱すことから皮膚への刺激が高く好ましくない。ラウリン酸は、洗浄力、泡立ち(起泡性)、泡持続性に優れる成分であることが知られているが、本発明ではラウリン酸塩を含まなくても、ラウリン酸以外の脂肪酸の塩と所定の他の必須成分と組み合わせることにより、皮膚への刺激を緩和しながら、泡立ちと泡質(弾力性)が良好である点において優れている。 Further, from the viewpoint of alleviating irritation to the skin, the fatty acid salt in the present invention is a salt of a fatty acid other than lauric acid. Laurate enters the stratum corneum and disturbs intercellular lipids, which is highly irritating to the skin and is not preferable. Lauric acid is known to be a component having excellent detergency, foaming (foaming property), and foam persistence, but in the present invention, even if it does not contain lauric acid, it can be used as a salt of a fatty acid other than lauric acid. When combined with certain other essential ingredients, it is excellent in that it has good foaming and foam quality (elasticity) while alleviating irritation to the skin.
本発明の洗浄剤組成物で用いられる成分(A)を具体的に例示すれば、ミリスチン酸ナトリウム、パルミチン酸ナトリウム、ステアリン酸ナトリウム、イソステアリン酸ナトリウム、オレイン酸ナトリウム、ミリスチン酸カリウム、パルミチン酸カリウム、ステアリン酸カリウム、イソステアリン酸カリウム、オレイン酸カリウム、ミリスチン酸トリエタノ―ルアミン、パルミチン酸トリエタノ―ルアミン、ステアリン酸トリエタノ―ルアミン、イソステアリン酸トリエタノ―ルアミン、オレイン酸トリエタノ―ルアミン、牛脂脂肪酸ナトリウム、ヒマシ油脂肪酸ナトリウム、オリーブ油脂肪酸ナトリウム、パーム油脂肪酸ナトリウム、牛脂脂肪酸カリウム、ヒマシ油脂肪酸カリウム、オリーブ油脂肪酸カリウム、パーム油脂肪酸カリウム、牛脂脂肪酸トリエタノ―ルアミン、ヒマシ油脂肪酸トリエタノ―ルアミン、オリーブ油脂肪酸トリエタノ―ルアミン、パーム油脂肪酸トリエタノ―ルアミン等が挙げられる。本発明の洗浄剤組成物には、これら高級脂肪酸塩を1種単独又は2種以上を組み合わせて用いることができる。 Specific examples of the component (A) used in the cleaning agent composition of the present invention include sodium myristate, sodium palmitate, sodium stearate, sodium isostearate, sodium oleate, potassium myristate, potassium palmitate, and the like. Potassium stearate, potassium isostearate, potassium oleate, trietanolamine myristate, trietanolamine palmitate, trietanolamine stearate, trietanolamine isostearate, trietanolamine oleate, sodium beef fatty acid, sodium castor oil fatty acid , Olive Oil Fatty Acid Sodium, Palm Oil Fatty Acid Sodium, Beef Fatty Acid Potassium, Himashima Fatty Acid Potassium, Olive Oil Fatty Acid Potassium, Palm Oil Fatty Acid Potassium, Beef Fatty Acid Trietanolamine, Himashima Fatty Acid Trietanolamine, Olive Oil Fatty Acid Trietanolamine, Palm Oil Fatty Acid Examples thereof include trietanolamine. In the detergent composition of the present invention, these higher fatty acid salts can be used alone or in combination of two or more.
本発明の洗浄剤組成物において、成分(A)の配合量は、好ましくは3〜15質量%であり、より好ましくは5〜10質量%である。3質量%以上では、良好な泡量、泡質(弾力性)が得られ、15質量%以下では、洗浄後の肌きしみが強くなく、しっとりとした感触が得られる。なお、2種以上を組み合わせて用いる場合には、それらを合計したものである。 In the detergent composition of the present invention, the blending amount of the component (A) is preferably 3 to 15% by mass, more preferably 5 to 10% by mass. When it is 3% by mass or more, a good foam amount and foam quality (elasticity) can be obtained, and when it is 15% by mass or less, the skin squeaky after washing is not strong and a moist feel can be obtained. When two or more types are used in combination, they are the total.
また、本発明の成分(A)は、洗浄剤組成物全質量に対してミリスチン酸塩を3〜12質量%含有することが好ましい。ミリスチン酸塩を上記含有量で含有することにより泡膜への吸着が早く強固な泡膜を作りやすいことから、泡立ちと泡質が良好になるため好ましい。また、以下に詳述する成分(B)及び(C)と組合せることにより、相乗的に泡立ちと泡質が良くなることからも好ましい。 Further, the component (A) of the present invention preferably contains 3 to 12% by mass of myristic acid salt with respect to the total mass of the detergent composition. By containing myristic acid salt in the above content, it is preferable because it is adsorbed to the foam film quickly and it is easy to form a strong foam film, and thus foaming and foam quality are improved. It is also preferable to combine with the components (B) and (C) described in detail below because the foaming and foam quality are synergistically improved.
<成分(B) N−アシルアスパラギン酸塩>
本発明の洗浄剤組成物で用いられる成分(B)はN−アシルアスパラギン酸塩である。成分(B)を配合することにより、洗浄後の肌のきしみを抑え、しっとりとした肌感触を付与することができる。かかるアシル基は炭素原子数8〜22の脂肪酸残基が好ましく、例えばラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、オレイン酸などの単一のアシル基や、ヤシ油脂肪酸、牛脂脂肪酸、ヒマシ油脂肪酸、オリーブ油脂肪酸、パーム油脂肪酸などから誘導されるアシル基、又はそれらの混合物が挙げられる。アミノ酸系界面活性剤の塩としては、例えばナトリウム塩、カリウム塩等のアルカリ金属塩、低級アルカノールアミン塩などが挙げられるが、好ましくは、ナトリウム塩、カリウム塩である。
<Component (B) N-acylaspartate>
The component (B) used in the detergent composition of the present invention is N-acylaspartate. By blending the component (B), it is possible to suppress squeaky skin after washing and impart a moist skin feel. Such acyl groups are preferably fatty acid residues having 8 to 22 carbon atoms, such as a single acyl group such as lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, and oleic acid, coconut oil fatty acid, and beef fatty acid. , Acyl groups derived from castor oil fatty acid, olive oil fatty acid, palm oil fatty acid and the like, or a mixture thereof. Examples of the salt of the amino acid-based surfactant include alkali metal salts such as sodium salt and potassium salt, lower alkanolamine salts and the like, and sodium salt and potassium salt are preferable.
本発明の洗浄剤組成物で用いられる成分(B)N−アシルアスパラギン酸塩を具体的に例示すれば、ラウロイルアスパラギン酸Na、ミリストイルアスパラギン酸Na、オレイルアスパラギン酸Na等が挙げられる。本発明の洗浄剤組成物には、これらN−アシルアスパラギン酸Naを1種単独又は2種以上を組み合わせて用いることができる。 Specific examples of the component (B) N-acylaspartate used in the cleaning agent composition of the present invention include Na lauroyl aspartate, Na myristyl aspartate, and Na oleyl aspartate. In the detergent composition of the present invention, these Na N-acylaspartate can be used alone or in combination of two or more.
本発明の洗浄剤組成物において、成分(B)N−アシルアスパラギン酸塩の配合量は、好ましくは0.5〜7質量%であり、より好ましくは1.5〜4質量%である。0.5質量%以上では洗浄後の肌がしっとりとした感触になり7%以下では泡質がきめ細かくなるため好ましい。なお、2種以上を組み合わせて用いる場合には、それらを合計したものである。 In the detergent composition of the present invention, the blending amount of the component (B) N-acylaspartate is preferably 0.5 to 7% by mass, more preferably 1.5 to 4% by mass. When it is 0.5% by mass or more, the skin feels moist after washing, and when it is 7% or less, the foam quality becomes fine, which is preferable. When two or more types are used in combination, they are the total.
<成分(C) N−アシルメチルタウリン塩>
本発明の洗浄剤組成物で用いられる成分(C)はN−アシルメチルタウリン塩である。成分(C)を配合することにより、より泡質がきめ細かくなる。かかるアシル基は炭素原子数8〜22の脂肪酸残基が好ましく、例えばラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、オレイン酸などの単一のアシル基や、ヤシ油脂肪酸、牛脂脂肪酸、ヒマシ油脂肪酸、オリーブ油脂肪酸、パーム油脂肪酸などから誘導されるアシル基、又はそれらの混合物が挙げられる。
<Component (C) N-acylmethyl taurine salt>
The component (C) used in the detergent composition of the present invention is an N-acylmethyl taurine salt. By blending the component (C), the foam quality becomes finer. Such acyl groups are preferably fatty acid residues having 8 to 22 carbon atoms, such as a single acyl group such as lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, and oleic acid, coconut oil fatty acid, and beef fatty acid. , Acyl groups derived from castor oil fatty acid, olive oil fatty acid, palm oil fatty acid and the like, or a mixture thereof.
本発明の洗浄剤組成物で用いられる成分(C)N−アシルメチルタウリン塩を具体的に例示すれば、ラウロイルメチルタウリンNa、ミリストイルメチルタウリンNa、ラウロイルメチルタウリンMg等が挙げられる。本発明の洗浄剤組成物には、これらN−アシルメチルタウリン塩を1種単独又は2種以上を組み合わせて用いることができる。 Specific examples of the component (C) N-acylmethyl taurine salt used in the detergent composition of the present invention include lauroyl methyl taurine Na, myristyl methyl taurine Na, and lauroyl methyl taurine Mg. In the detergent composition of the present invention, these N-acylmethyl taurine salts can be used alone or in combination of two or more.
本発明の洗浄剤組成物において、成分(C)N−アシルメチルタウリン塩の配合量は、好ましくは0.5〜7質量%であり、より好ましくは1.5〜4質量%である。0.5質量
%以上では、泡がきめ細かくなり7%以下では経時安定性が良好である。なお、2種以上を組み合わせて用いる場合には、それらを合計したものである。
In the detergent composition of the present invention, the blending amount of the component (C) N-acylmethyl taurine salt is preferably 0.5 to 7% by mass, more preferably 1.5 to 4% by mass. At 0.5% by mass or more, the bubbles become finer, and at 7% or less, the stability over time is good. When two or more types are used in combination, they are the total.
<成分(D) 両性界面活性剤>
本発明の洗浄剤組成物で用いられる成分(D)は、両性界面活性剤である。成分(D)を配合することにより、洗浄後の肌のきしみ感をより軽減することができる。両性界面活性剤としては、特に限定されるものではないが、例えばラウリン酸アミドプロピルベタイン、ヤシ油脂肪酸アミドプロピルベタイン、ラウリルジメチルアミノ酢酸ベタイン、2−アルキル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、ラウリルアミノジ酢酸ナトリウム、β−アミノプロピオン酸ナトリウム、N−ラウロイル−N’−カルボキシメチル−N’−ヒドロキシエチルエチレンジアミンナトリウム等が挙げられ、適宜1種又は2種以上選択して用いればよい。
<Component (D) amphoteric surfactant>
The component (D) used in the detergent composition of the present invention is an amphoteric surfactant. By blending the component (D), the squeaky feeling of the skin after washing can be further reduced. The amphoteric surfactant is not particularly limited, and is, for example, lauric acid amide propyl betaine, coconut oil fatty acid amide propyl betaine, lauryldimethylaminoacetic acid betaine, 2-alkyl-N-carboxymethyl-N-hydroxyethyl imidazole. Examples thereof include linium betaine, sodium laurylaminodiacetate, sodium β-aminopropionate, N-lauroyl-N'-carboxymethyl-N'-hydroxyethylethylenediamine sodium, and one or more of them are appropriately selected and used. Just do it.
本発明の洗浄剤組成物において、成分(D)両性界面活性剤の配合量は、好ましくは2〜10質量%であり、より好ましくは3〜7質量%である。2%以上では洗浄後の肌にきしみを感じず、10%以下では、洗浄後の肌にべたつきを感じることなくしっとりとした感触となるため好ましい。なお、2種以上を組み合わせて用いる場合には、それらを合計したものである。 In the detergent composition of the present invention, the blending amount of the component (D) amphoteric surfactant is preferably 2 to 10% by mass, more preferably 3 to 7% by mass. When it is 2% or more, the skin after washing does not feel squeaky, and when it is 10% or less, the skin after washing does not feel sticky and feels moist, which is preferable. When two or more types are used in combination, they are the total.
<成分(E) アルキルポリグルコシド>
本発明の洗浄剤組成物で使用される成分(E)はアルキルポリグルコシドである。成分(E)を配合することにより、洗浄後の肌にしっとりとした感触をより付与することができる。具体的に例示すれば、デシルグルコシド、ラウリルグルコシド、ミリスチルグルコシド、ココイルグルコシド等が挙げられる。これらアルキルポリグルコシドは市販品を使用することができ、具体的に例示すれば、マイドール10、マイドール12(いずれも花王社製)、プランタケア2000UP、プランタケア1200UP、プランタケア818UP、プランタケア800UP等のプランタケアシリーズ(いずれもBASF社製)等が挙げられる。本発明の洗浄剤組成物には、これらアルキルポリグルコシドを1種単独又は2種以上を組み合わせて用いることができる。
<Component (E) Alkyl polyglucoside>
The component (E) used in the detergent composition of the present invention is an alkyl polyglucoside. By blending the component (E), it is possible to give the skin a moisturized feel after washing. Specific examples include decyl glucoside, lauryl glucoside, myristyl glucoside, and cocoyl glucoside. Commercially available products can be used for these alkyl polyglucosides. Specifically, Mydor 10, Mydor 12 (all manufactured by Kao Corporation), Plantacare 2000UP, Plantacare 1200UP, Plantacare 818UP, Plantacare Planter care series such as 800UP (both manufactured by BASF) and the like can be mentioned. In the detergent composition of the present invention, these alkyl polyglucosides can be used alone or in combination of two or more.
本発明の洗浄剤組成物において、成分(E)アルキルポリグルコシドの配合量は、1〜7%が好ましい。1%以上では、洗浄後の肌のしっとりとした感触が得られ、7%以下ではアルキルポリグルコシド特有のべたつき感が残らず、感触上好ましい。 In the detergent composition of the present invention, the blending amount of the component (E) alkylpolyglucoside is preferably 1 to 7%. When it is 1% or more, a moist feeling of the skin after washing is obtained, and when it is 7% or less, the sticky feeling peculiar to alkylpolyglucoside does not remain, which is preferable in terms of feel.
<その他の成分>
本発明の洗浄剤組成物は、上述した成分の他に、本発明の目的を損なわない範囲で他の成分、例えば、アニオン界面活性剤(上記成分(C)を除く)、ノニオン界面活性剤、粉体(顔料、色素、樹脂等)、生理活性成分、酸化防止剤、金属イオン封鎖剤、防腐剤、紫外線吸収剤、香料、保湿剤、塩類、溶媒、パール化剤、中和剤、昆虫忌避剤、酵素等の成分を適宜配合することができる。
<Other ingredients>
In addition to the above-mentioned components, the detergent composition of the present invention includes other components, for example, anionic surfactants (excluding the above-mentioned component (C)), nonionic surfactants, as long as the object of the present invention is not impaired. Powders (pigments, pigments, resins, etc.), physiologically active ingredients, antioxidants, sequestrants, preservatives, UV absorbers, fragrances, moisturizers, salts, solvents, pearling agents, neutralizers, insect repellents Ingredients such as agents and enzymes can be appropriately blended.
上記アニオン界面活性剤としては、特に限定されるものではなく、例えばラウリル硫酸トリエタノールアミン、ラウリル硫酸アンモニウム、ラウリルエーテル硫酸ナトリウム、ポリオキシエチレンラウリルエーテル硫酸ナトリウム、ポリオキシエチレンヤシ油脂肪酸アミドエーテル硫酸カリウム、ラウリルリン酸ナトリウム、ポリオキシエチレンラウリルエーテル酢酸ナトリウム等が挙げられ、適宜1種又は2種以上選択して用いればよい。 The anionic surfactant is not particularly limited, and for example, triethanolamine lauryl sulfate, ammonium lauryl sulfate, sodium lauryl ether sulfate, sodium polyoxyethylene lauryl ether sulfate, polyoxyethylene coconut oil fatty acid amide ether potassium sulfate, and the like. Examples thereof include sodium lauryl phosphate and sodium polyoxyethylene lauryl ether acetate, and one or two or more thereof may be appropriately selected and used.
上記ノニオン界面活性剤としては、特に限定されるものではないが、例えばポリオキシエチレンセチルエーテル、モノステアリン酸ソルビタン、トリイソステアリン酸ポリオキシエチレンソルビタン、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンモノイソス
テアレート、ポリオキシエチレンジオレイン酸グリセリル、ヤシ油脂肪酸ジエタノールアミド、ヤシ油脂肪酸モノエタノールアミド、ヤシ油脂肪酸N−メチルエタノールアミド、ポリオキシエチレンポリオキシプロピレングリコール、モノラウリン酸ポリエチレングリコール等が挙げられ、適宜1種又は2種以上選択して用いればよい。
The nonionic surfactant is not particularly limited, but for example, polyoxyethylene cetyl ether, sorbitan monostearate, polyoxyethylene sorbitan triisostearate, polyoxyethylene hydrogenated castor oil, polyoxyethylene monoisosteer. Rate, glyceryl polyoxyethylene dioleate, coconut oil fatty acid diethanolamide, coconut oil fatty acid monoethanolamide, coconut oil fatty acid N-methylethanolamide, polyoxyethylene polyoxypropylene glycol, polyethylene glycol monolaurate, etc. One type or two or more types may be selected and used.
また、上記粉体としては、例えば赤色201号、黄色4号、青色1号、黒色401号等の色素、黄色4号Alレーキ、黄色203号Baレーキ等のレーキ色素、ナイロンパウダー、シルクパウダー、シリコーンパウダー、セルロースパウダー、シリコーンエラストマー球状粉体、ポリエチレン末等の高分子、黄酸化鉄、赤色酸化鉄、酸化クロム、カーボンブラック、群青、紺青等の有色顔料、酸化亜鉛、酸化チタン等の白色顔料、タルク、マイカ、セリサイト、カオリン等の体質顔料、雲母チタン等のパール顔料、硫酸バリウム、炭酸カルシウム、炭酸マグネシウム、珪酸マグネシウム等の金属塩、シリカ、アルミナ等の無機粉体、ベントナイト、スメクタイト、窒化ホウ素等が挙げられる。これらの粉体の形状(球状、棒状、針状、板状、不定形状、燐片状、紡錘状など)に特に制限はない。 Examples of the powder include pigments such as Red No. 201, Yellow No. 4, Blue No. 1, Black No. 401, rake pigments such as Yellow No. 4 Al Lake and Yellow No. 203 Ba Lake, nylon powder, and silk powder. Silicone powder, cellulose powder, silicone elastomer spherical powder, polymers such as polyethylene powder, colored pigments such as yellow iron oxide, red iron oxide, chromium oxide, carbon black, ultramarine blue, dark blue, and white pigments such as zinc oxide and titanium oxide. , Tarku, mica, sericite, kaolin and other extender pigments, mica titanium and other pearl pigments, barium sulfate, calcium carbonate, magnesium carbonate, magnesium silicate and other metal salts, silica, alumina and other inorganic powders, bentonite, smectite, Examples include boron nitride. The shape of these powders (spherical, rod-shaped, needle-shaped, plate-shaped, indefinite-shaped, fluff-shaped, spindle-shaped, etc.) is not particularly limited.
上記生理活性成分としては、皮膚に塗布した場合に皮膚に何らかの生理活性を与える物質が挙げられる。例えば、抗炎症剤、老化防止剤、紫外線防御剤、ひきしめ剤、抗酸化剤、保湿剤、血行促進剤、抗菌剤、殺菌剤、乾燥剤、冷感剤、温感剤、ビタミン類、アミノ酸、創傷治癒促進剤、刺激緩和剤、鎮痛剤、細胞賦活剤、酵素成分等が挙げられる。上記生理活性成分は、天然系の植物抽出成分、海藻抽出成分、生薬成分や、化合物等が挙げられるが、これらの中でも、特に天然系の植物抽出成分、海藻抽出成分、生薬成分が安全性の点で好ましい。 Examples of the bioactive component include substances that give some bioactivity to the skin when applied to the skin. For example, anti-inflammatory agents, anti-aging agents, UV protection agents, tightening agents, antioxidants, moisturizers, blood circulation promoters, antibacterial agents, bactericides, desiccants, cooling agents, warming agents, vitamins, amino acids, Wound healing promoters, irritation relievers, analgesics, cell activators, enzyme components and the like can be mentioned. Examples of the bioactive component include natural plant extract components, seaweed extract components, crude drug components, compounds, etc. Among these, natural plant extract components, seaweed extract components, and crude drug components are particularly safe. It is preferable in terms of points.
上記天然系の植物抽出成分、海藻抽出成分、生薬成分の例としては、例えばアシタバエキス、アマチャエキス、アルテアエキス、アロエエキス、アンズエキス、イチョウエキス、ウイキョウエキス、ウーロン茶エキス、エイジツエキス、オウゴンエキス、オウバクエキス、オトギリソウエキス、オランダカラシエキス、オレンジエキス、海水乾燥物、海藻エキス、加水分解コムギ末、加水分解シルク、カモミラエキス、カロットエキス、カワラヨモギエキス、甘草エキス、カキョクエキス、キウイエキス、キューカンバーエキス、クチナシエキス、クマザサエキス、クララエキス、クルミエキス、グレープフルーツエキス、クロレラエキス、クワエキス、紅茶エキス、酵母エキス、コラーゲン、サルビアエキス、サボンソウエキス、サンザシエキス、ジオウエキス、シコンエキス、シソエキス、シナノキエキス、シャクヤクエキス、シラカバエキス、スギナエキス、セイヨウキズタエキス、セイヨウサンザシエキス、セイヨウニワトコエキス、セイヨウノコギリソウエキス、セイヨウハッカエキス、セージエキス、センキュウエキス、センブリエキス、ダイズエキス、タイソウエキス、タイムエキス、茶エキス、チョウジエキス、チンピエキス、トウキエキス、トウニンエキス、ドクダミエキス、トマトエキス、納豆エキス、ニンジンエキス、ニンニクエキス、ノバラエキス、蜂蜜、ハマメリスエキス、ヒキオコシエキス、ビサボロール、ビワエキス、ブクリョウエキス、プロポリス、ヘチマエキス、ペパーミントエキス、ボダイジュエキス、ホップエキス、マドンナリリー花エキス、マロニエエキス、ムクロジエキス、メリッサエキス、モモエキス、ユキノシタエキス、ユズエキス、ヨモギエキス、ラベンダーエキス、レモンエキス、レンゲソウエキス、ローズマリーエキス、ローヤルゼリーエキス等を挙げることができる。 Examples of the above-mentioned natural plant extract component, seaweed extract component, and crude drug component include, for example, Ashitaba extract, Amacha extract, Artea extract, Aloe extract, Anzu extract, Ginkgo extract, Wikyo extract, Woolong tea extract, Agetsu extract, Ogon extract, Oubaku extract, Otogirisou extract, Dutch mustard extract, orange extract, dried seawater, seaweed extract, hydrolyzed wheat powder, hydrolyzed silk, chamomile extract, carrot extract, kawarayomogi extract, licorice extract, kakyoku extract, kiwi extract, cucumber extract, Kuchinashi extract, Kumazasa extract, Clara extract, Walnut extract, Grapefruit extract, Chlorella extract, Kwa extract, Tea extract, Yeast extract, Collagen, Salvia extract, Sabonsou extract, Sanzashi extract, Jio extract, Shikon extract, Shiso extract, Shinanoki extract, Shakuyaku extract, White birch extract, sugina extract, sardine extract, sardine extract, sardine extract, sardine extract, sage extract, sage extract, senkyu extract, senburi extract, soybean extract, taiso extract, thyme extract, tea extract, chowji extract, chimpi extract , Touki extract, Tounin extract, Dokudami extract, Tomato extract, Natto extract, Carrot extract, Garlic extract, Novara extract, Honey, Hamamelis extract, Hikiokoshi extract, Bisaborol, Biwa extract, Bukuryo extract, Propolis, Hechima extract, Peppermint extract, Bodaiju extract, Hop Examples thereof include extracts, madonna lily flower extracts, marronnier extracts, mukuroji extracts, melissa extracts, peach extracts, yukinoshita extracts, yuzu extracts, yomogi extracts, lavender extracts, lemon extracts, astragalus extracts, rosemary extracts, royal jelly extracts and the like.
また、上記天然系の植物抽出成分、海藻抽出成分、生薬成分以外の成分としては、例えばデオキシリボ核酸、コラーゲン、エラスチン、キチン、キトサン、加水分解卵殻膜などの生体高分子、アミノ酸、乳酸ナトリウム、尿素、ピロリドンカルボン酸ナトリウム、ベタイン、ホエイなどの保湿成分、スフィンゴ脂質、セラミド、コレステロール、コレステロール誘導体、リン脂質などの油性成分、ε−アミノカプロン酸、グリチルリチン酸、β−グリチルレチン酸、塩化リゾチーム、グアイアズレン、ヒドロコルチゾン等の抗炎症剤、
ビタミン類(A、B2、B6、C、D、E)、パントテン酸カルシウム、ビオチン、ニコチン酸アミド、ビタミンCエステル等のビタミン類、アラントイン、ジイソプロピルアミンジクロロアセテート、4−アミノメチルシクロヘキサンカルボン酸等の活性成分、トコフェロール、カロチノイド、フラボノイド、タンニン、リグナン、サポニン等の抗酸化剤、α−ヒドロキシ酸、β−ヒドロキシ酸などの細胞賦活剤、γ−オリザノール、ビタミンE誘導体などの血行促進剤、イソプロピルメチルフェノール、トリクロサン、ヒノキチオール、塩化ベンザルコニウム等の殺菌剤、l−メントール、ハッカ油等の冷感剤、レチノール、レチノール誘導体等の創傷治癒剤等が挙げられる。
In addition, examples of components other than the above-mentioned natural plant extract component, seaweed extract component, and biopharmaceutical component include biopolymers such as deoxyribonucleic acid, collagen, elastin, chitin, chitosan, and hydrolyzed eggshell membrane, amino acids, sodium lactate, and urea. , Moisturizing ingredients such as sodium pyrrolidone carboxylate, betaine, whey, oily ingredients such as sphingolipid, ceramide, cholesterol, cholesterol derivative, phospholipid, ε-aminocaproic acid, glycyrrhizinic acid, β-glycyrrhetinic acid, lysozyme chloride, guaiazulene, hydrocortisone Anti-inflammatory agents, etc.
Vitamins (A, B2, B6, C, D, E), vitamins such as calcium pantothenate, biotin, nicotinic acid amide, vitamin C ester, allantin, diisopropylamine dichloroacetate, 4-aminomethylcyclohexanecarboxylic acid, etc. Active ingredients, tocopherols, carotinoids, flavonoids, tannins, lignans, saponins and other antioxidants, α-hydroxy acids, β-hydroxy acids and other cell activators, γ-orizanol, vitamin E derivatives and other blood circulation promoters, isopropylmethyl Examples thereof include bactericides such as phenol, triclosan, hinokithiol and benzalkonium chloride, cold sensitizers such as l-menthol and peppermint oil, and wound healing agents such as retinol and retinol derivatives.
本発明の洗浄剤組成物は、洗顔、クレンジング、ボディシャンプー、ハンドソープ、シェービング料、マッサージ料等の皮膚用洗浄剤として好適に使用できる。またそれぞれ、粘性液体、クリーム状等の形態として用いることができ、特に洗顔フォーム、液状ボディシャンプーとして好適に用いられる。 The cleansing composition of the present invention can be suitably used as a cleansing agent for the skin such as face wash, cleansing, body shampoo, hand soap, shaving agent, and massage agent. In addition, they can be used in the form of viscous liquid, cream, etc., respectively, and are particularly preferably used as face wash foam and liquid body shampoo.
次に本発明について実施例をもって詳細に説明するが、本発明はこれにより限定されるものではない。実施例に先立ち、各実施例で採用した試験法、評価法を説明する。 Next, the present invention will be described in detail with reference to Examples, but the present invention is not limited thereto. Prior to the examples, the test method and the evaluation method adopted in each example will be described.
a)泡立ち、泡質(弾力性)、洗浄後の肌のしっとりとした感触についての試験法
10名の専門パネルにより、実施例及び比較例のボディシャンプーを使用し、使用時の泡立ち、泡質(弾力性)、洗浄後の肌のきしみのなさ、洗浄後の肌のしっとりとした感触の各項目について官能評価した。尚、評価基準は以下の通りである。
[使用時の泡立ち]
◎:極めて良好 泡立ちが良いと答えた被験者の数が8人以上
○:良好 泡立ちが良いと答えた被験者の数が6人以上、8人未満
△:やや悪い 泡立ちが良いと答えた被験者の数が4人以上、6人未満
×:悪い 泡立ちが良いと答えた被験者の数が4人未満
[使用時の泡質(弾力性)]
◎:極めて良好 泡質(弾力性)が良いと答えた被験者の数が8人以上
○:良好 泡質(弾力性)が良いと答えた被験者の数が6人以上、8人未満
△:やや悪い 泡質(弾力性)が良いと答えた被験者の数が4人以上、6人未満
×:悪い 泡質(弾力性)が良いと答えた被験者の数が4人未満
[洗浄後の肌のきしみのなさ]
◎:極めて良好 肌のきしみがないと答えた被験者の数が8人以上
○:良好 肌のきしみがないと答えた被験者の数が6人以上、8人未満
△:やや悪い 肌のきしみがないと答えた被験者の数が4人以上、6人未満
×:悪い 肌のきしみがないと答えた被験者の数が4人未満
[洗浄後の肌のしっとりとした感触]
◎:極めて良好 しっとりとした感触があると答えた被験者の数が8人以上
○:良好 しっとりとした感触があると答えた被験者の数が6人以上、8人未満
△:やや悪い しっとりとした感触があると答えた被験者の数が4人以上、6人未満
×:悪い しっとりとした感触があると答えた被験者の数が4人未満
a) Foaming, foaming quality (elasticity), test method for moisturized skin after washing Using the body shampoos of Examples and Comparative Examples by a panel of 10 people, foaming and foaming quality during use Sensory evaluation was performed on each item of (elasticity), no squeaky skin after washing, and moist feeling of the skin after washing. The evaluation criteria are as follows.
[Bubbling during use]
⊚: Very good Number of subjects who answered that foaming was good 8 or more ○: Good Number of subjects who answered good foaming was 6 or more and less than 8 △: Number of subjects who answered that foaming was good 4 or more, less than 6 ×: Poor The number of subjects who answered that foaming was good was less than 4 [Foam quality (elasticity) when used]
⊚: Very good The number of subjects who answered that the foam quality (elasticity) was good was 8 or more ○: Good The number of subjects who answered that the foam quality (elasticity) was good was 6 or more and less than 8 △: Slightly The number of subjects who answered that the foam quality (elasticity) was good was 4 or more and less than 6 ×: The number of subjects who answered that the foam quality (elasticity) was good was less than 4 [Skin after washing] No squeak]
◎: Very good Number of subjects who answered that there was no skin squeak was 8 or more ○: Good The number of subjects who answered that there was no skin squeak was 6 or more and less than 8 △: Slightly bad There was no skin squeak The number of subjects who answered that there were 4 or more and less than 6 ×: The number of subjects who answered that there was no bad skin squeak was less than 4 [moist feeling of the skin after washing]
⊚: Very good The number of subjects who answered that they had a moist feeling was 8 or more ○: Good The number of subjects who answered that they had a moist feeling was 6 or more and less than 8 △: Somewhat bad Moist The number of subjects who answered that they had a feeling was 4 or more and less than 6 ×: The number of subjects who answered that they had a bad moist feeling was less than 4
実施例1〜10、比較例1〜7
表1に示す組成のボディウォッシュを調整し、これらを使用した時の泡立ちと泡質(弾力性)、洗浄後の肌のきしみのなさ、洗浄後の肌のしっとりとした感触について調べた。結果を併せて表1に示す。
Examples 1-10, Comparative Examples 1-7
The body wash having the composition shown in Table 1 was adjusted, and the foaming and foam quality (elasticity) when these were used, the lack of squeaky skin after washing, and the moist feeling of the skin after washing were investigated. The results are also shown in Table 1.
表1より明らかなように、本発明の成分を用いた実施例1〜10のボディシャンプー組成物は比較例1〜7の組成物に比べていずれも優れた性能を見出した。 As is clear from Table 1, the body shampoo compositions of Examples 1 to 10 using the ingredients of the present invention were found to have excellent performance as compared with the compositions of Comparative Examples 1 to 7.
以下、本発明の洗顔料組成物のその他の処方例を挙げる。なお、この処方例の洗顔料組成物についても、泡立ち、泡質(弾力性)、洗浄後の肌のきしみのなさ、洗浄後の肌のしっとりとした感触について調べた。 Hereinafter, other formulation examples of the facial cleanser composition of the present invention will be given. The facial cleanser composition of this formulation was also examined for foaming, foam quality (elasticity), no squeaky skin after washing, and a moist feeling of the skin after washing.
処方例 洗顔フォーム
(1)ミリスチン酸K 12.0
(2)パルミチン酸K 2.0
(3)ステアリン酸K 1.0
(4)ミリストイルアスパラギン酸Na 10. 0
(5)ココイルメチルタウリンMg 10.0
(6)ラウリルグルコシド 2.5
(7)コカミドプロピルベタイン 3.0
(8)ココアンホ酢酸Na 2.0
(9)塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体 0.5
(10)ヒドロキシプロピルメチルセルロース 0.5
(11)ラウロイルグルタミン酸ジ(フィトステリル/オクチルドデシル) 0.5
(12)セラミド2 0.1
(13)セラミド5 0.1
(14)グリコシルトレハロース 1.5
(15)エデト酸二ナトリウム 0.2
(16)フェノキシエタノール 0.5
(17)DPG 2.0
(18)グリセリン 5.0
(19)香料 0.2
(20)精製水 残余
Prescription example Facial cleansing foam (1) Myristic acid K 12.0
(2) Palmitic acid K 2.0
(3) Stearic acid K 1.0
(4) Na myristoylation aspartate 10.0
(5) Cocoyl methyl taurine Mg 10.0
(6) Lauryl glucoside 2.5
(7) Cocamidopropyl Betaine 3.0
(8) Sodium cocoamphoacetate 2.0
(9) Dimethyldialylammonium chloride / acrylamide copolymer 0.5
(10) Hydroxypropyl Methyl Cellulose 0.5
(11) Di (phytosteryl / octyldodecyl) lauroyl glutamate 0.5
(12) Ceramide 2 0.1
(13) Ceramide 5 0.1
(14) Glycosyl trehalose 1.5
(15) Disodium edetate 0.2
(16) Phenoxyethanol 0.5
(17) DPG 2.0
(18) Glycerin 5.0
(19) Fragrance 0.2
(20) Purified water residue
常法により上記組成の洗顔フォームを調製し、泡立ち、泡質(弾力性)、洗浄後の肌のきしみのなさ、洗浄後の肌のしっとりとした感触を評価したところ、実施例と同様に、いずれの特性も優れており良好な結果を得た。 A facial cleansing foam having the above composition was prepared by a conventional method, and the foaming, foam quality (elasticity), the absence of squeaky skin after washing, and the moist feel of the skin after washing were evaluated. Both characteristics were excellent and good results were obtained.
Claims (4)
(B)N−アシルアスパラギン酸塩
(C)N−アシルメチルタウリン塩
を含有することを特徴とする洗浄剤組成物。 A cleaning composition comprising (A) a fatty acid salt containing myristate and not containing laurate (B) N-acylaspartate (C) N-acylmethyltaurine salt.
The cleaning agent composition according to any one of claims 1 to 3, wherein the component (A) contains myristic acid salt in an amount of 3 to 12% by mass based on the total mass of the cleaning agent composition.
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