JP6795305B2 - Cleaning agent composition - Google Patents

Cleaning agent composition Download PDF

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JP6795305B2
JP6795305B2 JP2016007197A JP2016007197A JP6795305B2 JP 6795305 B2 JP6795305 B2 JP 6795305B2 JP 2016007197 A JP2016007197 A JP 2016007197A JP 2016007197 A JP2016007197 A JP 2016007197A JP 6795305 B2 JP6795305 B2 JP 6795305B2
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cleaning agent
mass
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fatty acid
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JP2017128625A (en
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健夫 雨宮
健夫 雨宮
恵育 鬼塚
恵育 鬼塚
裕子 藤崎
裕子 藤崎
恵理香 吉田
恵理香 吉田
弘美 遠野
弘美 遠野
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Kracie Home Products Ltd
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Description

本発明は、洗浄剤組成物に関し、詳しくは、泡の立ち始めから泡が細かく、泡持続性の高い洗浄剤組成物に関する。 The present invention relates to a cleaning agent composition, and more particularly to a cleaning agent composition in which bubbles are fine from the beginning of foaming and the foam is highly durable.

洗浄剤組成物には洗浄機能だけでなく、付加価値的機能を備えることが求められてきている。中でも洗顔やボディソープといった皮膚に直接的に触れ使用する形態の洗浄剤組成物は、その使用性が特に求められるものである。 The cleaning agent composition is required to have not only a cleaning function but also an added value function. Above all, the cleansing composition in the form of being used by directly touching the skin such as face wash and body soap is particularly required to be usable.

その観点から、滑り性を向上させるカチオン性ポリマーを複数組み合わせ、マッサージ機能を付与した洗浄剤組成物などが考えられている(例えば、特許文献1参照)。
しかしながら、カチオン性ポリマーは剤として滑り性を向上させるものの、洗浄剤組成物が皮膚に接触する際の泡の状態において、必ずしも泡の弾力や厚みを感じさせるものではなく、泡による付加価値機能を付与するための洗浄剤組成物として適したものではなかった。
From this point of view, a cleaning agent composition obtained by combining a plurality of cationic polymers that improve slipperiness and imparting a massage function is considered (see, for example, Patent Document 1).
However, although the cationic polymer improves the slipperiness as an agent, it does not necessarily make the foam feel the elasticity and thickness in the foam state when the cleaning agent composition comes into contact with the skin, and the value-added function of the foam is added. It was not suitable as a cleaning agent composition for adding.

また、脂肪酸石けんとアミノ酸系界面活性剤および特定のセルロース系ポリマーを組み合わせることで、泡立ちや経時安定性に優れる洗浄料用組成物なども考案されている(例えば、特許文献2参照)。
しかし、脂肪酸石けんにアミノ酸系界面活性剤と特定のセルロース系ポリマーを組み合わせることにより泡立ちや経時安定性は向上するものの、初期に泡立った際の泡質は粗く、泡立ちの初期から泡がクリーミィで心地良く使用できる洗浄剤組成物とはならなかった。
Further, a composition for a cleaning agent having excellent foaming and stability over time has been devised by combining a fatty acid soap, an amino acid-based surfactant and a specific cellulosic-based polymer (see, for example, Patent Document 2).
However, although the combination of fatty acid soap with an amino acid-based surfactant and a specific cellulosic polymer improves foaming and stability over time, the foam quality at the time of initial foaming is coarse, and the foam is creamy and comfortable from the initial stage of foaming. It did not result in a well-used cleaning composition.

このような背景から、泡立てた瞬間から泡が細かく、泡の持続性があるために洗浄行為の間も心地良い泡を感じられる洗浄剤組成物が求められている。 Against this background, there is a demand for a cleaning agent composition in which the foam is fine from the moment of foaming and the foam is persistent, so that a comfortable foam can be felt even during the cleaning operation.

特開2012−158548公報Japanese Unexamined Patent Publication No. 2012-158548 特開2014−218465公報JP-A-2014-218465

上記従来技術を背景とした本発明の目的は、泡の立ち始めから泡が細かく、泡持続性の高い洗浄剤組成物を提供することにある。 An object of the present invention based on the above-mentioned prior art is to provide a cleaning agent composition in which bubbles are fine from the beginning of foaming and the bubbles are highly durable.

本発明者等は、本発明の目的を達成するために鋭意研究した結果、脂肪酸塩とN−アシルグリシン型又はN−アシルメチルアラニン型アミノ酸系界面活性剤、カチオン性ポリマー、ノニオン性ポリマー、無機塩類とを組み合わせることにより、泡の立ち始めから泡が細かく、泡持続性の高い洗浄剤組成物が得られることを見出し、本発明を完成した。 As a result of diligent research to achieve the object of the present invention, the present inventors have conducted diligent studies on fatty acid salts and N-acylglycine-type or N-acylmethylalanine-type amino acid-based surfactants, cationic polymers, nonionic polymers, and inorganic substances. We have found that by combining with salts, a cleaning agent composition in which the foam is fine from the beginning of foaming and has high foam durability can be obtained, and the present invention has been completed.

第一の発明は、下記成分(A)および成分(B)を含有することを特徴とし、洗浄剤組成物総量に対して成分(B)が0.05質量%〜1.0質量%含有することを特徴とする洗浄剤組成物。
(A)脂肪酸塩
(B)N−アシルグリシン型又はN−アシルメチルアラニン型アミノ酸系界面活性剤
The first invention is characterized by containing the following component (A) and component (B), and the component (B) is contained in an amount of 0.05% by mass to 1.0% by mass with respect to the total amount of the cleaning agent composition. A cleaning agent composition characterized by that.
(A) Fatty acid salt (B) N-acylglycine type or N-acylmethylalanine type amino acid-based surfactant

第二の発明は、更に(C)カチオン性ポリマーを含有することを特徴とする請求項1に記載の洗浄剤組成物。 The cleaning composition according to claim 1, wherein the second invention further contains (C) a cationic polymer.

第三の発明は、更に(D)ノニオン性ポリマーを含有することを特徴とする請求項1または請求項2に記載の洗浄剤組成物。 The cleaning composition according to claim 1 or 2, wherein the third invention further contains (D) a nonionic polymer.

第四の発明は、(B)がN−アシルメチルアラニン型アミノ酸系界面活性剤であることを特徴とする請求項1〜3に記載の洗浄剤組成物。 The cleaning composition according to claim 1, wherein (B) is an N-acylmethylalanine-type amino acid-based surfactant.

本発明によれば、泡の立ち始めから泡が細かく、泡持続性の高い洗浄剤組成物を提供することができる。 According to the present invention, it is possible to provide a cleaning agent composition in which the foam is fine from the beginning of foaming and the foam is highly durable.

以下、本発明の洗浄剤組成物について詳細に説明する。 Hereinafter, the cleaning agent composition of the present invention will be described in detail.

本発明の洗浄剤組成物で用いられる成分(A)は脂肪酸塩である。脂肪酸塩を構成する脂肪酸としては、好ましくは炭素数8〜22の飽和の脂肪酸である。例えばラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸などの単一の脂肪酸や、ヤシ油脂肪酸、牛脂脂肪酸、ヒマシ油脂肪酸、オリーブ油脂肪酸、パーム油脂肪酸などから誘導される脂肪酸、又はそれらの混合物が挙げられる。脂肪酸塩を構成する塩としては、例えばナトリウム塩、カリウム塩等のアルカリ金属塩、低級アルカノールアミン塩などが挙げられるが、好ましくは、ナトリウム塩、カリウム塩である。 The component (A) used in the cleaning composition of the present invention is a fatty acid salt. The fatty acid constituting the fatty acid salt is preferably a saturated fatty acid having 8 to 22 carbon atoms. Examples include single fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, fatty acids derived from coconut oil fatty acids, beef fat fatty acids, castor oil fatty acids, olive oil fatty acids, palm oil fatty acids, etc., or mixtures thereof. Be done. Examples of the salt constituting the fatty acid salt include alkali metal salts such as sodium salt and potassium salt, lower alkanolamine salts, and the like, but sodium salt and potassium salt are preferable.

本発明の洗浄剤組成物で用いられる成分(A)脂肪酸塩を具体的に例示すれば、ラウリン酸ナトリウム、ミリスチン酸ナトリウム、パルミチン酸ナトリウム、ステアリン酸ナトリウム、イソステアリン酸ナトリウム、オレイン酸ナトリウム、ラウリン酸カリウム、ミリスチン酸カリウム、パルミチン酸カリウム、ステアリン酸カリウム、イソステアリン酸カリウム、オレイン酸カリウム、ラウリン酸トリエタノ―ルアミン、ミリスチン酸トリエタノ―ルアミン、パルミチン酸トリエタノ―ルアミン、ステアリン酸トリエタノ―ルアミン、イソステアリン酸トリエタノ―ルアミン、オレイン酸トリエタノ―ルアミン、ヤシ油脂肪酸ナトリウム、牛脂脂肪酸ナトリウム、ヒマシ油脂肪酸ナトリウム、オリーブ油脂肪酸ナトリウム、パーム油脂肪酸ナトリウム、パーム核油脂肪酸ナトリウム、ヤシ油脂肪酸カリウム、牛脂脂肪酸カリウム、ヒマシ油脂肪酸カリウム、オリーブ油脂肪酸カリウム、パーム油脂肪酸カリウム、パーム核油脂肪酸カリウム、ヤシ油脂肪酸トリエタノ―ルアミン、牛脂脂肪酸トリエタノ―ルアミン、ヒマシ油脂肪酸トリエタノ―ルアミン、オリーブ油脂肪酸トリエタノ―ルアミン、パーム油脂肪酸トリエタノ―ルアミン、パーム核油脂肪酸トリエタノ―ルアミン等が挙げられる。本発明の洗浄剤組成物には、これら高級脂肪酸塩を1種単独又は2種以上を組み合わせて用いることができる。 Specific examples of the component (A) fatty acid salt used in the cleaning agent composition of the present invention include sodium laurate, sodium myristate, sodium palmitate, sodium stearate, sodium isostearate, sodium oleate, and laurate. Potassium, potassium myristate, potassium palmitate, potassium stearate, potassium isostearate, potassium oleate, trietanolamine laurate, trietanolamine myristate, trietanolamine palmitate, trietanolamine stearate, trietanoisostearate Luamine, Trietanolamine oleate, Sodium palm oil fatty acid, Sodium beef fatty acid, Sodium castor oil fatty acid, Sodium olive oil fatty acid, Sodium palm oil fatty acid, Sodium palm kernel oil fatty acid, Potassium coconut oil fatty acid, Potassium beef fat , Olive Oil Fatty Acid Potassium, Palm Oil Fatty Acid Potassium, Palm Nuclear Oil Fatty Acid Potassium, Palm Oil Fatty Acid Trietanolamine, Beef Fat Fatty Acid Trietanolamine, Himashima Fatty Acid Trietanolamine, Olive Oil Fatty Acid Trietanolamine, Palm Oil Fatty Acid Trietanolamine, Palm Examples thereof include nuclear oil fatty acid triethanolamine. In the cleaning agent composition of the present invention, these higher fatty acid salts can be used alone or in combination of two or more.

本発明の洗浄剤組成物において、成分(A)高級脂肪酸塩の配合量は、好ましくは10〜50質量%である。より好ましくは15〜40質量%である。10質量%未満では、良好な泡量、泡質(クリーミィ性)が得られない。一方50質量%を超えると、水溶けが悪く、泡のたちが遅くなり良好な使用性を得られない。 In the cleaning agent composition of the present invention, the blending amount of the higher fatty acid salt of the component (A) is preferably 10 to 50% by mass. More preferably, it is 15 to 40% by mass. If it is less than 10% by mass, a good foam amount and foam quality (creaminess) cannot be obtained. On the other hand, if it exceeds 50% by mass, the water solubility is poor, the bubbles are slowed down, and good usability cannot be obtained.

本発明の洗浄剤組成物で用いられる成分(B)はN−アシルグリシン型又はN−アシルメチルアラニン型アミノ酸系界面活性剤である。かかるアシル基は炭素原子数8〜22の脂肪酸残基が好ましく、例えばラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、オレイン酸などの単一のアシル基や、ヤシ油脂肪酸、牛脂脂肪酸、ヒ
マシ油脂肪酸、オリーブ油脂肪酸、パーム油脂肪酸などから誘導されるアシル基、又はそれらの混合物が挙げられる。アミノ酸系界面活性剤の塩としては、例えばナトリウム塩、カリウム塩等のアルカリ金属塩、低級アルカノールアミン塩などが挙げられるが、好ましくは、ナトリウム塩、カリウム塩である。
The component (B) used in the cleaning composition of the present invention is an N-acylglycine type or N-acylmethylalanine type amino acid-based surfactant. Such an acyl group is preferably a fatty acid residue having 8 to 22 carbon atoms, for example, a single acyl group such as lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, or oleic acid, coconut oil fatty acid, or beef fatty acid. , Acyl groups derived from castor oil fatty acid, olive oil fatty acid, palm oil fatty acid and the like, or a mixture thereof. Examples of the salt of the amino acid-based surfactant include alkali metal salts such as sodium salt and potassium salt, lower alkanolamine salts and the like, and sodium salt and potassium salt are preferable.

本発明の洗浄剤組成物で用いられる成分(B)はN−アシルメチルアラニン型アミノ酸系界面活性剤が好ましい。 The component (B) used in the cleaning composition of the present invention is preferably an N-acylmethylalanine-type amino acid-based surfactant.

本発明の洗浄剤組成物で用いられる成分(B)N−アシルメチルアラニン型アミノ酸系界面活性剤を具体的に例示すれば、ヤシ油脂肪酸メチルアラニンカリウム、ヤシ油脂肪酸メチルアラニンナトリウム、ヤシ油脂肪酸メチルアラニントリエタノールアミン、パーム核油脂肪酸メチルアラニンアンモニウム、ラウロイルメチルアラニンナトリウム、ラウロイルメチルアラニンカリウム、ラウロイルメチルアラニントリエタノールアミン、等が挙げられる。これらN−アシルメチルアラニン型アミノ酸系界面活性剤は市販品を使用することができ、具体的に例示すれば、アラノンACE、アラノンALE等のアラノンシリーズ(いずれも川研社製)や、ソフティルトAS、ソフティルトAT等のソフティルトシリーズ(いずれも日油社製)等が挙げられる。本発明の洗浄剤組成物には、これらN−アシルメチルアラニン型アミノ酸系界面活性剤を1種単独又は2種以上を組み合わせて用いることができる。 Specific examples of the component (B) N-acylmethylalanine-type amino acid-based surfactant used in the cleaning agent composition of the present invention include coconut oil fatty acid methylalanine potassium, coconut oil fatty acid methylalanine sodium, and coconut oil fatty acid. Examples thereof include methylalanine triethanolamine, palm kernel oil fatty acid methylalanine ammonium, lauroylmethylalanine sodium, lauroylmethylalanine potassium, lauroylmethylalanine triethanolamine, and the like. Commercially available products can be used for these N-acylmethylalanine-type amino acid-based surfactants. Specific examples include Alanon series (all manufactured by Kawaken Co., Ltd.) such as Alanon ACE and Alanon ALE, and Softilt AS. , Softilt series such as Softilt AT (both manufactured by NOF CORPORATION) and the like. In the cleaning agent composition of the present invention, these N-acylmethylalanine-type amino acid-based surfactants can be used alone or in combination of two or more.

本発明の洗浄剤組成物において、成分(B)N−アシルグリシン型又はN−アシルメチルアラニン型アミノ酸系界面活性剤の配合量は、好ましくは0.01〜1質量%、より好ましくは0.05〜1質量%である。0.01質量%未満では、泡の立ち始めが遅くなる。一方1質量%を超えると、泡立ちの初期において細かい泡を得られない。 In the cleaning agent composition of the present invention, the blending amount of the component (B) N-acylglycine type or N-acylmethylalanine type amino acid-based surfactant is preferably 0.01 to 1% by mass, more preferably 0. It is 05 to 1% by mass. If it is less than 0.01% by mass, the start of foaming will be delayed. On the other hand, if it exceeds 1% by mass, fine bubbles cannot be obtained at the initial stage of foaming.

本発明の洗浄剤組成物で用いられる成分(C)であるカチオン性ポリマーは、例えば塩化ジメチルジアリルアンモニウム・アルリルアミド共重合体、アクリルアミド・アクリル酸・塩化ジメチルジアリルアンモニウム共重合体液、塩化ジメチルジアリルアンモニウム・アクリル酸共重合体液、ポリ塩化ジメチルメチレンピペリジニウム液、カチオン化セルロース、カチオン化グァーガム、カチオン化フェヌグリークガム、カチオン化タラガム、カチオン化グルコマンナン、カチオン化ローカストビーンガム、アジピン酸ジメチルアミノヒドロキシプロピルジエチルトリアリアミン共重合体、ポリエチレンイミン、ポリエチレングリコール・エピクロルヒドリン・牛脂アルキルアミン・ジプロピレントリアミン縮合物などが挙げられる。これらのうち、塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体、カチオン化グァーガム、カチオン化グルコマンナンが好ましい。これらカチオン性ポリマーは、市販品を用いることが可能であり、例えば、マーコート550、マーコート295等のマーコートシリーズ(いずれもナルコ社製)、カチナールCG−100S、カチナールCLB−100等のカチナールシリーズ(いずれも東邦化学社製)が挙げられる。 The cationic polymer which is the component (C) used in the cleaning agent composition of the present invention is, for example, a dimethyldiallylammonium chloride / allylamide copolymer, an acrylamide / acrylic acid / dimethyldialylammonium chloride copolymer solution, a dimethyldialylammonium chloride. Acrylic acid copolymer solution, polydimethylmethylene piperidinium chloride solution, cationized cellulose, cationized guar gum, cationized phenuglique gum, cationized tara gum, cationized glucomannan, cationized locust bean gum, dimethylaminohydroxypropyl diethyl adipate Examples thereof include a triariamine copolymer, polyethyleneimine, polyethylene glycol, epichlorohydrin, beef alkylamine, and dipropylenetriamine condensate. Of these, dimethyldiallyl ammonium chloride / acrylamide copolymer, cationized guar gum, and cationized glucomannan are preferable. Commercially available products can be used as these cationic polymers. For example, Marurt series such as Marcoat 550 and Marcoat 295 (all manufactured by Narco), Katinal series such as Katinal CG-100S and Katinal CLB-100 (all of which are manufactured by Narco). Both are manufactured by Toho Chemical Industry Co., Ltd.).

本発明の洗浄剤組成物において、成分(C)カチオン性ポリマーの配合量は、好ましくは、0.03〜1質量%である。より好ましくは0.1〜0.5質量%である。0.03質量%未満では、満足する泡の持続性を得られず、1質量%を超えると泡立ちが遅くなり製品の使用性上好ましくない。 In the cleaning agent composition of the present invention, the blending amount of the component (C) cationic polymer is preferably 0.03 to 1% by mass. More preferably, it is 0.1 to 0.5% by mass. If it is less than 0.03% by mass, satisfactory foam persistence cannot be obtained, and if it exceeds 1% by mass, foaming becomes slow, which is not preferable in terms of product usability.

本発明の洗浄剤組成物で用いられる成分(D)であるノニオン性ポリマーは、例えばヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、ポリエチレングリコール、高重合ポリエチレングリコール、ポリビニルアルコール、ポリグルタミン酸、カルボキシビニルポリマー、アクリル酸・メタクリル酸アルキル共重合体、アクリル酸アルキル共重合体等が挙げられる。これらのうち、ヒドロキシエ
チルセルロース、ヒドロキシプロピルメチルセルロースが好ましい。これらノニオン性ポリマーは、市販品を用いることが可能であり、例えば、HECダイセルSE400、HECダイセルSE600等のHECダイセルシリーズ(いずれもダイセル化学工業社製)、メトローズ60SH10000、メトローズ60SH4000等のメトローズシリーズ(いずれも信越化学工業株式会社製)等が挙げられる。
The nonionic polymer which is the component (D) used in the cleaning agent composition of the present invention is, for example, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, polyethylene glycol, highly polymerized polyethylene glycol, polyvinyl alcohol, polyglutamic acid, carboxyvinyl polymer. , Acrylic acid / alkyl methacrylate copolymer, alkyl acrylate copolymer and the like. Of these, hydroxyethyl cellulose and hydroxypropyl methyl cellulose are preferable. Commercially available products can be used as these nonionic polymers. For example, HEC Daicel series such as HEC Daicel SE400 and HEC Daicel SE600 (all manufactured by Daicel Chemical Industries, Ltd.), Metrose series such as Metrose 60SH10000 and Metrose 60SH4000. (Both manufactured by Shin-Etsu Chemical Co., Ltd.) and the like.

本発明の洗浄剤組成物において、成分(D)ノニオン性ポリマーの配合量は、好ましくは、0.01〜1質量%である。より好ましくは0.1〜0.5質量%である。0.01質量%未満では、満足する泡の持続性を得られず、1質量%を超えると泡立ちが遅くなり製品の使用性上好ましくない。 In the cleaning agent composition of the present invention, the blending amount of the component (D) nonionic polymer is preferably 0.01 to 1% by mass. More preferably, it is 0.1 to 0.5% by mass. If it is less than 0.01% by mass, satisfactory foam persistence cannot be obtained, and if it exceeds 1% by mass, foaming becomes slow, which is not preferable in terms of product usability.

本発明の洗浄剤組成物で用いられる成分(E)である無機塩は、例えば塩化ナトリウム、塩化カリウム、リン酸一ナトリウム、リン酸二ナトリウム、炭酸ナトリウム、炭酸水素ナトリウム等が挙げられる。これらのうち塩化ナトリウム、塩化カリウムが好ましく、さらに好ましくは塩化カリウムである。本発明の洗浄剤組成物には、これら無機塩類を1種単独又は2種以上を組み合わせて用いることができる。 Examples of the inorganic salt which is the component (E) used in the cleaning agent composition of the present invention include sodium chloride, potassium chloride, monosodium phosphate, disodium phosphate, sodium carbonate, sodium hydrogencarbonate and the like. Of these, sodium chloride and potassium chloride are preferable, and potassium chloride is more preferable. In the cleaning agent composition of the present invention, these inorganic salts can be used alone or in combination of two or more.

本発明の洗浄剤組成物において、成分(E)無機塩類の配合量は、好ましくは、0.1〜2質量%である。0.1質量%未満では、満足する泡の持続性を得られず、2質量%を超えると泡立ちが遅くなり製品の使用性上好ましくない。 In the cleaning agent composition of the present invention, the blending amount of the component (E) inorganic salt is preferably 0.1 to 2% by mass. If it is less than 0.1% by mass, satisfactory foam persistence cannot be obtained, and if it exceeds 2% by mass, foaming becomes slow, which is not preferable in terms of product usability.

本発明の洗浄剤組成物は、上述した成分の他に、本発明の目的を損なわない範囲で他の成分、例えば、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、ノニオン界面活性剤、粉体(顔料、色素、樹脂等)、生理活性成分、酸化防止剤、金属イオン封鎖剤、防腐剤、紫外線吸収剤、香料、保湿剤、塩類、溶媒、パール化剤、中和剤、昆虫忌避剤、酵素等の成分を適宜配合することができる。 In addition to the above-mentioned components, the cleaning composition of the present invention contains other components, such as anionic surfactants, cationic surfactants, amphoteric surfactants, and nonionic surfactants, as long as the object of the present invention is not impaired. , Powders (pigments, pigments, resins, etc.), bioactive ingredients, antioxidants, sequestrants, preservatives, UV absorbers, fragrances, moisturizers, salts, solvents, pearlizing agents, neutralizers, insects Ingredients such as repellents and enzymes can be appropriately added.

上記アニオン界面活性剤としては、特に限定されるものではなく、例えばラウリル硫酸トリエタノールアミン、ラウリル硫酸アンモニウム、ラウリルエーテル硫酸ナトリウム、ポリオキシエチレンラウリルエーテル硫酸ナトリウム、ポリオキシエチレンヤシ油脂肪酸アミドエーテル硫酸カリウム、ラウリルリン酸ナトリウム、ポリオキシエチレンラウリルエーテル酢酸ナトリウム等が挙げられ、適宜一種又は二種以上選択して用いればよい。 The anionic surfactant is not particularly limited, and for example, triethanolamine lauryl sulfate, ammonium lauryl sulfate, sodium lauryl ether sulfate, sodium polyoxyethylene lauryl ether sulfate, polyoxyethylene coconut oil fatty acid amide ether potassium sulfate, and the like. Examples thereof include sodium lauryl phosphate and sodium polyoxyethylene lauryl ether acetate, and one or two or more thereof may be appropriately selected and used.

上記両性界面活性剤としては、特に限定されるものではないが、例えばラウリン酸アミドプロピルベタイン、ヤシ油脂肪酸アミドプロピルベタイン、ラウリルジメチルアミノ酢酸ベタイン、2−アルキル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、ラウリルアミノジ酢酸ナトリウム、β−アミノプロピオン酸ナトリウム、N−ラウロイル−N'−カルボキシメチル−N'−ヒドロキシエチルエチレンジアミンナトリウム等が挙げられ、適宜一種又は二種以上選択して用いればよい。 The amphoteric surfactant is not particularly limited, but is, for example, lauric acid amide propyl betaine, coconut oil fatty acid amide propyl betaine, lauryldimethylaminoacetic acid betaine, 2-alkyl-N-carboxymethyl-N-hydroxyethyl. Examples thereof include imidazolinium betaine, sodium laurylaminodiacetate, sodium β-aminopropionate, N-lauroyl-N'-carboxymethyl-N'-hydroxyethylethylenediamine sodium, etc., and one or more of them are appropriately selected and used. Just do it.

上記ノニオン界面活性剤としては、特に限定されるものではないが、例えばポリオキシエチレンセチルエーテル、モノステアリン酸ソルビタン、トリイソステアリン酸ポリオキシエチレンソルビタン、デシルグルコシド、ラウリルグルコシド、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンモノイソステアレート、ポリオキシエチレンジオレイン酸グリセリル、ヤシ油脂肪酸ジエタノールアミド、ヤシ油脂肪酸モノエタノールアミド、ヤシ油脂肪酸N−メチルエタノールアミド、ポリオキシエチレンポリオキシプロピレングリコール、モノラウリン酸ポリエチレングリコール等が挙げられ、適宜一種又は二種以上選択して用いればよい。 The nonionic surfactant is not particularly limited, and is, for example, polyoxyethylene cetyl ether, sorbitan monostearate, polyoxyethylene sorbitan triisostearate, decyl glucoside, lauryl glucoside, polyoxyethylene hydrogenated castor oil, and the like. Polyoxyethylene monoisostearate, glyceryl polyoxyethylene dioleate, coconut oil fatty acid diethanolamide, coconut oil fatty acid monoethanolamide, coconut oil fatty acid N-methylethanolamide, polyoxyethylene polyoxypropylene glycol, polyethylene glycol monolaurate Etc., and one or more of them may be selected and used as appropriate.

また、上記粉体としては、例えば赤色201号、黄色4号、青色1号、黒色401号等の
色素、黄色4号Alレーキ、黄色203号Baレーキ等のレーキ色素、ナイロンパウダー、シルクパウダー、シリコーンパウダー、セルロースパウダー、シリコーンエラストマー球状粉体、ポリエチレン末等の高分子、黄酸化鉄、赤色酸化鉄、酸化クロム、カーボンブラック、群青、紺青等の有色顔料、酸化亜鉛、酸化チタン等の白色顔料、タルク、マイカ、セリサイト、カオリン等の体質顔料、雲母チタン等のパール顔料、硫酸バリウム、炭酸カルシウム、炭酸マグネシウム、珪酸マグネシウム等の金属塩、シリカ、アルミナ等の無機粉体、ベントナイト、スメクタイト、窒化ホウ素等が挙げられる。これらの粉体の形状(球状、棒状、針状、板状、不定形状、燐片状、紡錘状など)に特に制限はない。
Examples of the powder include pigments such as red No. 201, yellow No. 4, blue No. 1, black No. 401, rake pigments such as yellow No. 4 Al lake and yellow No. 203 Ba lake, nylon powder, and silk powder. Silicone powder, cellulose powder, silicone elastomer spherical powder, polymers such as polyethylene powder, colored pigments such as yellow iron oxide, red iron oxide, chromium oxide, carbon black, ultramarine blue, dark blue, and white pigments such as zinc oxide and titanium oxide. , Tarku, mica, sericite, kaolin and other extender pigments, mica titanium and other pearl pigments, barium sulfate, calcium carbonate, magnesium carbonate, magnesium silicate and other metal salts, silica, alumina and other inorganic powders, bentonite, smectite, Examples thereof include boron nitride. The shape of these powders (spherical, rod-shaped, needle-shaped, plate-shaped, indefinite-shaped, flaky, spindle-shaped, etc.) is not particularly limited.

上記生理活性成分としては、皮膚に塗布した場合に皮膚に何らかの生理活性を与える物質が挙げられる。例えば、抗炎症剤、老化防止剤、紫外線防御剤、ひきしめ剤、抗酸化剤、保湿剤、血行促進剤、抗菌剤、殺菌剤、乾燥剤、冷感剤、温感剤、ビタミン類、アミノ酸、創傷治癒促進剤、刺激緩和剤、鎮痛剤、細胞賦活剤、酵素成分等が挙げられる。上記生理活性成分は、天然系の植物抽出成分、海藻抽出成分、生薬成分や、化合物等が挙げられるが、これらの中でも、特に天然系の植物抽出成分、海藻抽出成分、生薬成分が安全性の点で好ましい。 Examples of the bioactive component include substances that give some bioactivity to the skin when applied to the skin. For example, anti-inflammatory agents, anti-aging agents, UV protection agents, tightening agents, antioxidants, moisturizers, blood circulation promoters, antibacterial agents, bactericides, desiccants, cooling agents, warming agents, vitamins, amino acids, Wound healing promoters, irritation relievers, analgesics, cell activators, enzyme components and the like can be mentioned. Examples of the bioactive component include natural plant extract components, seaweed extract components, crude drug components, compounds, etc. Among these, natural plant extract components, seaweed extract components, and crude drug components are particularly safe. It is preferable in that.

上記天然系の植物抽出成分、海藻抽出成分、生薬成分の例としては、例えばアシタバエキス、アマチャエキス、アルテアエキス、アロエエキス、アンズエキス、イチョウエキス、ウイキョウエキス、ウーロン茶エキス、エイジツエキス、オウゴンエキス、オウバクエキス、オトギリソウエキス、オランダカラシエキス、オレンジエキス、海水乾燥物、海藻エキス、加水分解コムギ末、加水分解シルク、カモミラエキス、カロットエキス、カワラヨモギエキス、甘草エキス、カキョクエキス、キウイエキス、キューカンバーエキス、クチナシエキス、クマザサエキス、クララエキス、クルミエキス、グレープフルーツエキス、クロレラエキス、クワエキス、紅茶エキス、酵母エキス、コラーゲン、サルビアエキス、サボンソウエキス、サンザシエキス、ジオウエキス、シコンエキス、シソエキス、シナノキエキス、シャクヤクエキス、シラカバエキス、スギナエキス、セイヨウキズタエキス、セイヨウサンザシエキス、セイヨウニワトコエキス、セイヨウノコギリソウエキス、セイヨウハッカエキス、セージエキス、センキュウエキス、センブリエキス、ダイズエキス、タイソウエキス、タイムエキス、茶エキス、チョウジエキス、チンピエキス、トウキエキス、トウニンエキス、ドクダミエキス、トマトエキス、納豆エキス、ニンジンエキス、ニンニクエキス、ノバラエキス、蜂蜜、ハマメリスエキス、ヒキオコシエキス、ビサボロール、ビワエキス、ブクリョウエキス、プロポリス、ヘチマエキス、ペパーミントエキス、ボダイジュエキス、ホップエキス、マドンナリリー花エキス、マロニエエキス、ムクロジエキス、メリッサエキス、モモエキス、ユキノシタエキス、ユズエキス、ヨモギエキス、ラベンダーエキス、レモンエキス、レンゲソウエキス、ローズマリーエキス、ローヤルゼリーエキス等を挙げることができる。 Examples of the above-mentioned natural plant extract component, seaweed extract component, and crude drug component include, for example, Ashitaba extract, Amacha extract, Artea extract, Aloe extract, Anzu extract, Ginkgo extract, Wikyo extract, Woolong tea extract, Agetsu extract, Ogon extract, Oubaku extract, Otogirisou extract, Dutch mustard extract, orange extract, dried seawater, seaweed extract, hydrolyzed wheat powder, hydrolyzed silk, chamomile extract, carrot extract, kawarayomogi extract, licorice extract, kakyoku extract, kiwi extract, cucumber extract, Kuchinashi extract, Kumazasa extract, Clara extract, Walnut extract, Grapefruit extract, Chlorella extract, Kwa extract, Tea extract, Yeast extract, Collagen, Salvia extract, Sabonsou extract, Sanzashi extract, Jio extract, Shikon extract, Shiso extract, Shinanoki extract, Shakuyaku extract, White birch extract, sugina extract, sardine extract, sardine extract, sardine extract, sardine extract, sage extract, sage extract, senkyu extract, senburi extract, soybean extract, taiso extract, thyme extract, tea extract, chowji extract, chimpi extract , Touki extract, Tounin extract, Dokudami extract, Tomato extract, Natto extract, Carrot extract, Garlic extract, Novara extract, Honey, Hamamelis extract, Hikiokoshi extract, Bisaborol, Biwa extract, Bukuryo extract, Propolis, Hechima extract, Peppermint extract, Bodaiju extract, Hop Examples thereof include extracts, madonna lily flower extracts, marronnier extracts, mukuroji extracts, melissa extracts, peach extracts, yukinoshita extracts, yuzu extracts, yomogi extracts, lavender extracts, lemon extracts, astragalus extracts, rosemary extracts, royal jelly extracts and the like.

また、上記天然系の植物抽出成分、海藻抽出成分、生薬成分以外の成分としては、例えばデオキシリボ核酸、コラーゲン、エラスチン、キチン、キトサン、加水分解卵殻膜などの生体高分子、アミノ酸、乳酸ナトリウム、尿素、ピロリドンカルボン酸ナトリウム、ベタイン、ホエイなどの保湿成分、スフィンゴ脂質、セラミド、コレステロール、コレステロール誘導体、リン脂質などの油性成分、ε−アミノカプロン酸、グリチルリチン酸、β−グリチルレチン酸、塩化リゾチーム、グアイアズレン、ヒドロコルチゾン等の抗炎症剤、ビタミン類(A、B2、B6、C、D、E)、パントテン酸カルシウム、ビオチン、ニコチン酸アミド、ビタミンCエステル等のビタミン類、アラントイン、ジイソプロピルアミンジクロロアセテート、4−アミノメチルシクロヘキサンカルボン酸等の活性成分、トコフェロール、カロチノイド、フラボノイド、タンニン、リグナン、サポニン等の抗酸化剤、α−ヒドロキシ酸、β−ヒドロキシ酸などの細胞賦活剤、γ−オリザノール、ビタミンE誘導体などの血行促進剤、イソプロピルメチルフェノール、トリクロサン、ヒノキチオ
ール、塩化ベンザルコニウム等の殺菌剤、l−メントール、ハッカ油等の冷感剤、レチノール、レチノール誘導体等の創傷治癒剤等が挙げられる。
In addition, examples of components other than the above-mentioned natural plant extract components, seaweed extract components, and crude drug components include biopolymers such as deoxyribonucleic acid, collagen, elastin, chitin, chitosan, and hydrolyzed eggshell membrane, amino acids, sodium lactate, and urea. , Moisturizing ingredients such as sodium pyrrolidone carboxylate, betaine, whey, oily ingredients such as sphingolipid, ceramide, cholesterol, cholesterol derivative, phospholipid, ε-aminocaproic acid, glycyrrhizinic acid, β-glycyrrhetinic acid, lysozyme chloride, guaiazulene, hydrocortisone Anti-inflammatory agents such as, vitamins (A, B2, B6, C, D, E), vitamins such as calcium pantothenate, biotin, nicotinic acid amide, vitamin C ester, allantin, diisopropylamine dichloroacetate, 4-amino Active ingredients such as methylcyclohexanecarboxylic acid, antioxidants such as tocopherols, carotinoids, flavonoids, tannins, lignans, saponins, cell activators such as α-hydroxy acids and β-hydroxy acids, γ-orizanol, vitamin E derivatives, etc. Examples thereof include blood circulation promoters, bactericides such as isopropylmethylphenol, triclosan, hinokithiol and benzalkonium chloride, cold sensitizers such as l-menthol and peppermint oil, and wound healing agents such as retinol and retinol derivatives.

本発明の洗浄剤組成物は、洗顔、クレンジング、ボディシャンプー、ハンドソープ、シェービング料、マッサージ料等の皮膚用洗浄剤として好適に使用できる。またそれぞれ、粘性液体、クリーム状等の形態として用いることができ、特に洗顔フォーム、液状ボディシャンプーとして好適に用いられる。 The cleansing composition of the present invention can be suitably used as a cleansing agent for the skin such as face wash, cleansing, body shampoo, hand soap, shaving agent, and massage agent. In addition, they can be used in the form of viscous liquid, cream, etc., respectively, and are particularly preferably used as facial cleansing foam and liquid body shampoo.

次に本発明の洗浄剤組成物について、実施例をもって詳細に説明するが、本発明はこれにより限定されるものではない。まず、各実施例で採用した試験法、評価法を説明する。 Next, the cleaning agent composition of the present invention will be described in detail with reference to Examples, but the present invention is not limited thereto. First, the test method and evaluation method adopted in each example will be described.

実施例1〜10及び比較例1〜5
表1に示す組成の洗浄剤組成物を常法により調製した。泡立ち、泡量、泡質(クリーミィ性)、泡の持続性評価の結果は表1及び表2に併せて示した。なお、以下の全ての実施例及び比較例における配合量は質量%である。
Examples 1-10 and Comparative Examples 1-5
The cleaning agent composition having the composition shown in Table 1 was prepared by a conventional method. The results of foaming, foam volume, foam quality (creaminess), and foam sustainability evaluation are also shown in Tables 1 and 2. In addition, the compounding amount in all the following Examples and Comparative Examples is mass%.

(1)泡立ち評価
10名の専門パネルにより、実施例及び比較例の洗浄剤組成物を使用し、泡立ちについて官能評価により評価を行った。尚、評価基準は以下の通りである。
[評価基準]
◎:極めて良好 泡立ちが早いと答えた被験者の数が8人以上
○:良好 泡立ちが早いと答えた被験者の数が6人以上、8人未満
△:やや悪い 泡立ちが早いと答えた被験者の数が4人以上、6人未満
×:悪い 泡立ちが早いと答えた被験者の数が4人未満
(1) Foaming evaluation Using the cleaning agent compositions of Examples and Comparative Examples by a panel of 10 people, foaming was evaluated by sensory evaluation. The evaluation criteria are as follows.
[Evaluation criteria]
⊚: Very good Number of subjects who answered that foaming was fast 8 or more ○: Good Number of subjects who answered that foaming was fast, less than 8 △: Number of subjects who answered that foaming was rather bad 4 or more, less than 6 ×: Bad The number of subjects who answered that foaming was fast was less than 4

(2)泡量評価
10名の専門パネルにより、実施例及び比較例の洗浄剤組成物を使用し、泡量について官能評価により評価を行った。尚、評価基準は以下の通りである。
[評価基準]
◎:極めて良好 泡量が多いと答えた被験者の数が8人以上
○:良好 泡量が多いと答えた被験者の数が6人以上、8人未満
△:やや悪い 泡量が多いと答えた被験者の数が4人以上、6人未満
×:悪い 泡量が多いと答えた被験者の数が4人未満
(2) Evaluation of foam amount Using the cleaning agent compositions of Examples and Comparative Examples by a panel of 10 people, the foam amount was evaluated by sensory evaluation. The evaluation criteria are as follows.
[Evaluation criteria]
⊚: Very good The number of subjects who answered that the amount of foam was large was 8 or more ○: Good The number of subjects who answered that the amount of foam was large was 6 or more and less than 8 △: Somewhat bad The number of subjects who answered that the amount of foam was large Number of subjects is 4 or more and less than 6 ×: The number of subjects who answered that the amount of bubbles is large is less than 4

(3)泡立ち初期の泡質(クリーミィ性)評価
10名の専門パネルにより、実施例及び比較例の洗浄剤組成物を使用し、泡立ち初期の泡質(クリーミィ性)について官能評価により評価を行った。尚、評価基準は以下の通りである。
[泡立ち初期の泡質(クリーミィ性)]
◎:極めて良好 泡質(クリーミィ性)が良いと答えた被験者の数が8人以上
○:良好 泡質(クリーミィ性)が良いと答えた被験者の数が6人以上、8人未満△:やや悪い 泡質(クリーミィ性)が良いと答えた被験者の数が4人以上、6人未満×:悪い 泡質(クリーミィ性)が良いと答えた被験者の数が4人未満
(3) Evaluation of foam quality (creaminess) at the initial stage of foaming The foam quality (creaminess) at the initial stage of foaming is evaluated by sensory evaluation using the cleaning agent compositions of Examples and Comparative Examples by a panel of 10 people. It was. The evaluation criteria are as follows.
[Foam quality at the initial stage of foaming (creaminess)]
⊚: Very good The number of subjects who answered that the foam quality (creaminess) was good was 8 or more ○: The number of subjects who answered that the foam quality (creaminess) was good was 6 or more and less than 8 △: Slightly The number of subjects who answered that the foam quality (creaminess) was good was 4 or more and less than 6 ×: The number of subjects who answered that the foam quality (creaminess) was good was less than 4

(4)泡の持続性評価
10名の専門パネルにより、実施例及び比較例の洗浄剤組成物を使用し、泡の持続性について官能評価により評価を行った。尚、評価基準は以下の通りである。
[評価基準]
◎:極めて良好 持続性が良いと答えた被験者の数が8人以上
○:良好 持続性が良いと答えた被験者の数が6人以上、8人未満
△:やや悪い 持続性が良いと答えた被験者の数が4人以上、6人未満
×:悪い 持続性が良いと答えた被験者の数が4人未満
(4) Evaluation of foam persistence Using the cleaning agent compositions of Examples and Comparative Examples by a panel of 10 experts, the foam persistence was evaluated by sensory evaluation. The evaluation criteria are as follows.
[Evaluation criteria]
⊚: Very good Number of subjects who answered that the sustainability was good 8 or more ○: Good Number of subjects who answered that the sustainability was good 6 or more, less than 8 △: Somewhat bad The number of subjects who answered that the sustainability was good Number of subjects is 4 or more and less than 6 ×: Poor The number of subjects who answered that the sustainability is good is less than 4

Figure 0006795305
Figure 0006795305

表1より明らかなように、本発明の成分を用いた実施例1〜10の洗浄剤組成物は比較例1〜5の組成物に比べていずれも優れた性能を見出した。 As is clear from Table 1, the cleaning agent compositions of Examples 1 to 10 using the components of the present invention were found to have excellent performance as compared with the compositions of Comparative Examples 1 to 5.

以下、本発明の洗浄剤組成物のその他の処方例を実施例11、12として挙げる。なお、これらの実施例の洗浄剤組成物についても、上記の泡立ち、泡量、泡質(クリーミィ性)、泡の持続性の各項目を評価した。 Hereinafter, other formulation examples of the cleaning agent composition of the present invention will be given as Examples 11 and 12. The cleaning agent compositions of these examples were also evaluated for each of the above items of foaming, foaming amount, foam quality (creaminess), and foam persistence.

実施例11 洗顔フォーム
(1)ラウリン酸カリウム 2.0
(2)ミリスチン酸カリウム 16.0
(3)パルミチン酸カリウム 6.0
(4)ステアリン酸カリウム 6.0
(5)ココイルグリシンK 2.0
(6)ラウロイルメチルアラニンNa 8.0
(7)塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体 0.5
(8)シア脂 0.5
(9)バラエキス 0.5
(10)サピンヅストリホリアツス果実エキス 0.5
(11)モモ葉エキス 0.5
(12)アロエベラ葉エキス 0.5
(13)N−アセチルグルコサミン 0.5
(14)カニナバラ果実エキス 0.5
(15)エデト酸二ナトリウム 0.5
(16)フェノキシエタノール 0.5
(17)DPG 0.5
(18)グリセリン 30.0
(19)香料 0.2
(20)精製水 残余
Example 11 Facial cleansing foam (1) Potassium laurate 2.0
(2) Potassium myristate 16.0
(3) Potassium palmitate 6.0
(4) Potassium stearate 6.0
(5) Cocoyl glycine K 2.0
(6) Lauroylmethylalanine Na 8.0
(7) Dimethyldialylammonium chloride / acrylamide copolymer 0.5
(8) Shea butter 0.5
(9) Rose extract 0.5
(10) Sapindus trifoliatus fruit extract 0.5
(11) Peach leaf extract 0.5
(12) Aloe vera leaf extract 0.5
(13) N-Acetylglucosamine 0.5
(14) Canina rose fruit extract 0.5
(15) Disodium edetate 0.5
(16) Phenoxyethanol 0.5
(17) DPG 0.5
(18) Glycerin 30.0
(19) Fragrance 0.2
(20) Purified water residue

常法により上記組成の洗浄剤組成物を調製し、初期の泡立ち、泡量、泡質(クリーミィ性)、泡の持続性を評価したところ、いずれの特性も優れており良好な結果を得た。 A cleaning composition having the above composition was prepared by a conventional method, and the initial foaming, foam amount, foam quality (creaminess), and foam persistence were evaluated. As a result, all the characteristics were excellent and good results were obtained. ..

実施例12 ボディソープ
(1)ラウリン酸カリウム 6.0
(2)ミリスチン酸カリウム 12.0
(3)パルミチン酸カリウム 3.0
(4)ステアリン酸カリウム 1.0
(5)ココイルグリシンK 2.0
(6)ラウロイルメチルアラニンNa 8.0
(7)塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体 0.5
(8)シア脂 0.5
(9)バラエキス 0.5
(10)サピンヅストリホリアツス果実エキス 0.5
(11)モモ葉エキス 0.5
(12)アロエベラ葉エキス 0.5
(13)N−アセチルグルコサミン 0.5
(14)カニナバラ果実エキス 0.5
(15)エデト酸二ナトリウム 0.5
(16)フェノキシエタノール 0.5
(17)DPG 0.5
(18)グリセリン 30.0
(19)香料 0.2
(20)精製水 残余
Example 12 Body Soap (1) Potassium Laurate 6.0
(2) Potassium myristate 12.0
(3) Potassium palmitate 3.0
(4) Potassium stearate 1.0
(5) Cocoyl glycine K 2.0
(6) Lauroylmethylalanine Na 8.0
(7) Dimethyldialylammonium chloride / acrylamide copolymer 0.5
(8) Shea butter 0.5
(9) Rose extract 0.5
(10) Sapindus trifoliatus fruit extract 0.5
(11) Peach leaf extract 0.5
(12) Aloe vera leaf extract 0.5
(13) N-Acetylglucosamine 0.5
(14) Canina rose fruit extract 0.5
(15) Disodium edetate 0.5
(16) Phenoxyethanol 0.5
(17) DPG 0.5
(18) Glycerin 30.0
(19) Fragrance 0.2
(20) Purified water residue

常法により上記組成の洗浄剤組成物を調製し、初期の泡立ち、泡量、泡質(クリーミィ性)、泡の持続性を評価したところ、いずれの特性も優れており良好な結果を得た。 A cleaning composition having the above composition was prepared by a conventional method, and the initial foaming, foam amount, foam quality (creaminess), and foam persistence were evaluated. As a result, all the characteristics were excellent and good results were obtained. ..

Claims (1)

下記成分(A)、成分(B)、成分(C)、成分(D)および成分(E)を含有し、洗浄剤組成物総量に対して前記成分(A)の含有量は15質量〜50質量%、前記成分(B)の含有量は0.05質量%〜1.0質量%であり、前記成分(A)の総量に対してラウリン酸および/またはその塩の含有量は45質量%以上であり、パルミチン酸および/またはその塩の含有量は15質量%〜25質量%であることを特徴とする洗浄剤組成物。
(A)脂肪酸塩
(B)N−アシルメチルアラニン型アミノ酸系界面活性剤
(C)カチオン性ポリマー
(D)ノニオン性ポリマー
(E)塩化ナトリウムまたは塩化カリウムである無機塩
It contains the following component (A), component (B), component (C), component (D) and component (E), and the content of the component (A) is 15% by mass to 50 with respect to the total amount of the cleaning agent composition. By mass, the content of the component (B) is 0.05% by mass to 1.0% by mass, and the content of lauric acid and / or a salt thereof is 45% by mass with respect to the total amount of the component (A). The cleaning agent composition as described above, wherein the content of palmitic acid and / or a salt thereof is 15% by mass to 25% by mass.
(A) Fatty acid salt (B ) N -acylmethylalanine type amino acid-based surfactant (C) Cationic polymer (D) Nonionic polymer (E) Inorganic salt which is sodium chloride or potassium chloride
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