JP2020145392A - ダイシングテープ、及び接着フィルム付きダイシングテープ - Google Patents
ダイシングテープ、及び接着フィルム付きダイシングテープ Download PDFInfo
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- JP2020145392A JP2020145392A JP2019043186A JP2019043186A JP2020145392A JP 2020145392 A JP2020145392 A JP 2020145392A JP 2019043186 A JP2019043186 A JP 2019043186A JP 2019043186 A JP2019043186 A JP 2019043186A JP 2020145392 A JP2020145392 A JP 2020145392A
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- Prior art keywords
- dicing tape
- adhesive film
- pressure
- sensitive adhesive
- adhesive layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
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- IUURMAINMLIZMX-UHFFFAOYSA-N tris(2-nonylphenyl)phosphane Chemical compound CCCCCCCCCC1=CC=CC=C1P(C=1C(=CC=CC=1)CCCCCCCCC)C1=CC=CC=C1CCCCCCCCC IUURMAINMLIZMX-UHFFFAOYSA-N 0.000 description 1
- WXAZIUYTQHYBFW-UHFFFAOYSA-N tris(4-methylphenyl)phosphane Chemical compound C1=CC(C)=CC=C1P(C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 WXAZIUYTQHYBFW-UHFFFAOYSA-N 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
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Abstract
Description
1/計算Tg=W1/Tg(1)+W2/Tg(2)+・・・+Wn/Tn 〔1〕
ここで、W1、W2、・・・Wnは共重合体を構成するモノマー成分(1)、モノマー成分(2)、・・・モノマー成分(n)の全モノマー成分に対する各重量分率(重量%)を意味し、Tg(1)、Tg(2)、・・・Tg(n)は、モノマー成分(1)、モノマー成分(2)、・・・モノマー成分(n)のホモポリマーのガラス転移温度(単位は絶対温度:K)を表す。
なお、ホモポリマーのガラス転移温度は、各種文献、カタログなどから公知であり、例えば、J. Brandup, E. H. Immergut,E. A. Grulke: Polymer Handbook:JOHNWILEY & SONS, INCに記載されている。各種文献に数値が無いモノマーについては、一般的な熱分析、例えば示差熱分析や動的粘弾性測定法等により測定した値を採用することができる。
高TgモノマーのホモポリマーのTgとしては、ベースポリマーのTgを−43℃以下に調整しやいという観点から、好ましくは−10℃以上、より好ましくは0℃以上、より好ましくは20℃以上、より好ましくは40℃以上、より好ましくは60℃以上、より好ましくは80℃以上、さらに好ましくは100℃以上である。
また、低Tgモノマーとしては、アクリル酸2−エチルヘキシル(ホモポリマーのTg:−70℃)、アクリル酸2−ヒドロキシエチル(ホモポリマーのTg:−15℃)、アクリル酸ブチル(ホモポリマーのTg:−55℃)、アクリル酸4−ヒドロキシブチル(ホモポリマーのTg:−40℃)等が挙げられ、アクリル酸2−エチルヘキシル、アクリル酸2−ヒドロキシエチルが好ましい。
なお、本願発明における「ベースポリマーのTg」は、架橋剤と反応する前のベースポリマーのTgを意味するものとする。
なお、本願発明における「ベースポリマーのTg」は、第2の官能基と紫外線重合性炭素−炭素二重結合とを有する化合物等と反応して、紫外線重合性の炭素−炭素二重結合が導入される前のベースポリマーのTgを意味するものとする。
<レーザー光照射条件>
(A)レーザー光
レーザー光源 半導体レーザー励起Nd:YAGレーザー
波長 1064nm
レーザー光スポット断面積 3.14×10-8cm2
発振形態 Qスイッチパルス
繰り返し周波数 100kHz以下
パルス幅 1μs以下
出力 1mJ以下
レーザー光品質 TEM00
偏光特性 直線偏光
(B)集光用レンズ
倍率 100倍以下
NA 0.55
レーザー光波長に対する透過率 100%以下
(C)半導体基板が載置される載置台の移動速度 280mm/秒以下
〈ダイシングテープの作製〉
冷却管と、窒素導入管と、温度計と、撹拌装置とを備える反応容器内で、アクリル酸2-エチルヘキシル(2EHA;ホモポリマーのTg:−70℃)と、アクリル酸2-ヒドロキシエチル(HEA;ホモポリマーのTg:−15℃)と、アクリロイルモルフォリン(ACMO;ホモポリマーのTg:145℃)を表1に示される割合(モル部)で使用し、重合開始剤である過酸化ベンゾイルと、重合溶媒であるトルエンとを含む混合物(ベース55wt%)を、60℃で10時間、窒素雰囲気下で撹拌した(重合反応)。この混合物において、過酸化ベンゾイルの含有量はモノマー成分100質量部に対して0.3質量部であり、トルエンの含有量はモノマー成分100質量部に対して60質量部である。この重合反応により、アクリル系ポリマーP1を含有するポリマー溶液を得た。表1に、モノマー成分組成からFoxの式により算出されるアクリル系ポリマーP1のガラス転移温度(Tg)を示す。
アクリル樹脂(商品名「テイサンレジンSG−280」,ナガセケムテック株式会社製)15質量部と、エポキシ樹脂(商品名「EPPN 501HY」,日本化薬株式会社製)29質量部と、フェノール樹脂(商品名「HF−1M」,明和化成株式会社製)16質量部と、無機フィラー(商品名「SE−2050MCV」,球状シリカ,株式会社アドマテックス製)40質量部とを、メチルエチルケトンに溶解して濃度40〜50重量%の接着剤組成物溶液を調製した。
この接着剤組成物溶液を、剥離ライナとしてシリコーン離型処理した厚さが50μmのポリエチレンテレフタレートフィルムからなるPETセパレータ上に塗布した後、130℃で2分間乾燥させることにより、厚さ60μmの接着フィルムを作製した。作製した60μmの接着フィルム同士を貼り合せることで、120μmの接着フィルムを作製した(ラミネート条件:80℃、0.15MPa、10mm/s)。
PETセパレータを伴う上述の接着フィルムを直径330mmの円盤形に打ち抜き加工した。次に、当該接着フィルムからPETセパレータを剥離し且つ上述のダイシングテープからPETセパレータを剥離した後、当該ダイシングテープにおいて露出した粘着剤層と、接着フィルムにおいてPETセパレータの剥離によって露出した面とを、ロールラミネーターを使用して貼り合わせた。この貼り合わせにおいて、貼合わせ速度を10mm/分とし、温度条件を25℃とし、圧力条件を0.15MPaとした。その後、接着フィルムの貼り合せ部分のみに紫外線を照射した(300mJ/cm2)。以上のようにして、ダイシングテープと接着フィルムとを含む積層構造を有する実施例1〜5、比較例1〜3の接着フィルム付きダイシングテープを作製した。
実施例1〜5および比較例1〜3の各ダイシングテープについて、以下のようにして破断伸度、破断強度を測定した。当該ダイシングテープからダイシングテープ試験片(幅10mm×長さ100mm)を切り出した。実施例1〜5および比較例1〜3のダイシングテープごとに、必要数のダイシングテープ試験片を用意した。そして、引張試験機(商品名「オートグラフAGS-50NX」,株式会社島津製作所製)を使用して、ダイシングテープ試験片について引張試験を行い、所定の引張速度で伸張されるダイシングテープ試験片の破断伸度、破断強度を測定した。引張試験において、初期チャック間距離は50mmであり、温度条件は−15℃であり、引張速度は300mm/分である。測定結果を表1に示す。
実施例1〜5および比較例1〜3の各接着フィルムについて、以下のようにして破断伸度、破断強度を測定した。まず、接着フィルム試験片(幅10mm×長さ40mm)を切り出した。実施例1〜5および比較例1〜3の接着フィルムごとに、必要数の接着フィルム試験片を用意した。そして、引張試験機(商品名「オートグラフAGS-50NX」,株式会社島津製作所製)を使用して、接着フィルム試験片について引張試験を行い、所定の引張速度で伸張される接着フィルム試験片の破断伸度、破断強度を測定した。引張試験において、初期チャック間距離は10mmであり、温度条件は25℃であり、引張速度は300mm/分である。測定結果を表1に示す。
チップサイズ10×10mmで割断予定ライン(ブレードハーフカット;幅20μm,深さ100μm)の施された12インチウエハを40μmの厚みになるまでバックグラインドし、実施例1〜5、比較例1〜3で作成した接着フィルム付きダイシングテープとの貼り合せを行った(ウエハ貼り合せ温度:70℃、速度10mm/s)。
その後、ダイセパレート装置(商品名「ダイセパレータDDS2300」,株式会社ディスコ製)を用いて半導体ウエハ及び接着フィルムの割断、更にダイシングシートの熱収縮を行うことにより、ダイシングテープの裂け、割断性を評価した。
まず、クールエキスパンダーユニットで、エキスパンド温度−15℃、エキスパンド速度300mm/秒、エキスパンド量14mmの条件で半導体ウエハを割断した。
その後、ダイシングテープ裂けを評価した。テープ裂けが発生しなかったものを〇、発生したものをXとした。
また、半導体ウエハの割断率が80%以上のものを〇、90%以上のものを◎、80%未満のものを×とした。評価結果を表1に示す。
10 ダイシングテープ
11 基材
12 粘着剤層
20,21 接着フィルム
W,30A,30B 半導体ウエハ
30C 半導体ウエハ分割体
30a 改質領域
30b 分割溝
31 半導体チップ
Claims (8)
- 基材と粘着剤層とを含む積層構造を有するダイシングテープであって、
前記粘着剤層は、ガラス転移温度が−43℃以下であるベースポリマーを含有する、ダイシングテープ。 - 前記ベースポリマーは、アクリル系ポリマーである、請求項1に記載のダイシングテープ。
- 前記粘着剤層の厚みは、5μm以上40μm以下である、請求項1又は2に記載のダイシングテープ。
- −15℃での破断伸度が300%以上である、請求項1〜3のいずれか1項に記載のダイシングテープ。
- −15℃での破断強度が15N/10mm以上である、請求項1〜4のいずれか1項に記載のダイシングテープ。
- 請求項1〜5のいずれか1項に記載のダイシングテープと、
前記ダイシングテープにおける前記粘着剤層に剥離可能に密着している接着フィルムとを有する、接着フィルム付きダイシングテープ。 - 前記接着フィルムの25℃での破断強度は5N/10mm以下であり、25℃での破断伸度は100%以下である、請求項6に記載の接着フィルム付きダイシングテープ。
- 半導体ウエハの割断工程に用いられる、請求項6又は7に記載の接着フィルム付きダイシングテープ。
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KR1020200027003A KR20200107833A (ko) | 2019-03-08 | 2020-03-04 | 다이싱 테이프 및 접착 필름을 구비한 다이싱 테이프 |
TW109107241A TW202045660A (zh) | 2019-03-08 | 2020-03-05 | 切晶帶、及附接著膜之切晶帶 |
CN202010149735.6A CN111662646A (zh) | 2019-03-08 | 2020-03-06 | 切割带和带有粘接薄膜的切割带 |
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