JP2020033559A - コーティング剤 - Google Patents
コーティング剤 Download PDFInfo
- Publication number
- JP2020033559A JP2020033559A JP2019154018A JP2019154018A JP2020033559A JP 2020033559 A JP2020033559 A JP 2020033559A JP 2019154018 A JP2019154018 A JP 2019154018A JP 2019154018 A JP2019154018 A JP 2019154018A JP 2020033559 A JP2020033559 A JP 2020033559A
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- component
- resin
- pigment
- coating agent
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- 239000011248 coating agent Substances 0.000 title claims abstract description 73
- 229920005989 resin Polymers 0.000 claims abstract description 115
- 239000011347 resin Substances 0.000 claims abstract description 115
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000000049 pigment Substances 0.000 claims abstract description 41
- 238000010521 absorption reaction Methods 0.000 claims abstract description 37
- 239000002253 acid Substances 0.000 claims abstract description 34
- 239000007787 solid Substances 0.000 claims abstract description 31
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000006185 dispersion Substances 0.000 claims abstract description 18
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims abstract description 15
- 150000002902 organometallic compounds Chemical class 0.000 claims description 17
- 239000003125 aqueous solvent Substances 0.000 claims description 11
- 238000004040 coloring Methods 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 229910000765 intermetallic Inorganic materials 0.000 abstract 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 48
- 239000003921 oil Substances 0.000 description 39
- 235000019198 oils Nutrition 0.000 description 39
- 239000000178 monomer Substances 0.000 description 33
- 238000000576 coating method Methods 0.000 description 29
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 27
- 235000014113 dietary fatty acids Nutrition 0.000 description 26
- 239000000194 fatty acid Substances 0.000 description 26
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 26
- 229920002554 vinyl polymer Polymers 0.000 description 26
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- 235000021122 unsaturated fatty acids Nutrition 0.000 description 19
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 17
- 229910052500 inorganic mineral Inorganic materials 0.000 description 15
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- 238000001035 drying Methods 0.000 description 7
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- 229910010272 inorganic material Inorganic materials 0.000 description 7
- 150000003254 radicals Chemical class 0.000 description 7
- -1 2-ethylhexyl Chemical group 0.000 description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 6
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- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 6
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- 239000010941 cobalt Substances 0.000 description 6
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- 239000010936 titanium Substances 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 150000002894 organic compounds Chemical class 0.000 description 5
- 229910052726 zirconium Inorganic materials 0.000 description 5
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- 229910052718 tin Inorganic materials 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
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- 238000007796 conventional method Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000000944 linseed oil Substances 0.000 description 3
- 235000021388 linseed oil Nutrition 0.000 description 3
- 239000012046 mixed solvent Substances 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 239000010454 slate Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 229910052712 strontium Inorganic materials 0.000 description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
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- 238000003915 air pollution Methods 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 235000019241 carbon black Nutrition 0.000 description 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 2
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- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
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- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 2
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- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
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- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 2
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- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
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- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
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- OAJHWYJGCSAOTQ-UHFFFAOYSA-N [Zr].CCCCCCCCO.CCCCCCCCO.CCCCCCCCO.CCCCCCCCO Chemical compound [Zr].CCCCCCCCO.CCCCCCCCO.CCCCCCCCO.CCCCCCCCO OAJHWYJGCSAOTQ-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 230000009471 action Effects 0.000 description 1
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- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
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- 150000001408 amides Chemical class 0.000 description 1
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- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
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- 239000007864 aqueous solution Substances 0.000 description 1
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- ZCGHEBMEQXMRQL-UHFFFAOYSA-N benzyl 2-carbamoylpyrrolidine-1-carboxylate Chemical compound NC(=O)C1CCCN1C(=O)OCC1=CC=CC=C1 ZCGHEBMEQXMRQL-UHFFFAOYSA-N 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
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- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
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- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
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- SGLXWMAOOWXVAM-UHFFFAOYSA-L manganese(2+);octanoate Chemical compound [Mn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O SGLXWMAOOWXVAM-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
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- 150000002739 metals Chemical class 0.000 description 1
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- 239000002480 mineral oil Substances 0.000 description 1
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- 239000004570 mortar (masonry) Substances 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
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- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 239000003973 paint Substances 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
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- 239000004014 plasticizer Substances 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- XPGAWFIWCWKDDL-UHFFFAOYSA-N propan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCC[O-].CCC[O-].CCC[O-].CCC[O-] XPGAWFIWCWKDDL-UHFFFAOYSA-N 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
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- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
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- 150000003839 salts Chemical class 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
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- 229920002050 silicone resin Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 description 1
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- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 1
- 239000008170 walnut oil Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
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- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
1.樹脂成分(A)、顔料(B)、有機金属化合物(C)、及び脂肪族炭化水素含有非水溶剤(D)を含むコーティング剤であって、
上記樹脂成分(A)として、非水分散型樹脂(A−1)、及び可溶型樹脂(A−2)を含み、
上記非水分散型樹脂(A−1)及び/または上記可溶型樹脂(A−2)が、酸化重合性基を有し、
上記非水分散型樹脂(A−1)及び/または上記可溶型樹脂(A−2)が、酸価を有し、
上記顔料(B)として、表面処理ルチル型酸化チタン(B−1)を含み、
上記樹脂成分(A)の固形分100gを基準としたときの上記顔料(B)の総吸油量が60g以下であることを特徴とするコーティング剤。
2.上記表面処理ルチル型酸化チタン(B−1)は、吸油量が30g/100g以下であることを特徴とする1.記載のコーティング剤。
2)エポキシ基含有ビニル単量体と、この単量体と共重合可能な他のビニル単量体とを共重合させた後、前記エポキシ基含有ビニル単量体に不飽和脂肪酸を付加させて得られた樹脂。
3)酸化重合性基を有するビニル単量体、及び/またはこの単量体と共重合可能な他のビニル単量体とをアルキド樹脂に共重合及び/またはグラフト重合させて得られた樹脂。
(B)成分の総吸油量=
[{(B1)の吸油量}×{(A)成分の固形分100gを基準としたときの(B1)のg数}/100]+
[{(B2)の吸油量}×{(A)成分の固形分100gを基準としたときの(B2)のg数}/100]+・・・
[{(Bm)の吸油量}×{(A)成分の固形分100gを基準としたときの(Bm)のg数}/100]
表1〜3に示す重量比率にて各成分を常法にて均一に混合し、各コーティング剤を製造した。なお、使用した成分は下記の通りである。
・樹脂2:酸化重合性基・酸基含有非水分散型樹脂(樹脂成分:エポキシ基含有アクリルスチレン樹脂の大豆油脂肪酸変性物,ミネラルスピリットを媒体とする非水分散型樹脂、不飽和脂肪酸構成比率:10重量%、重量平均分子量:130000、酸価:0.2mgKOH/g、固形分:50重量%)
・樹脂3:酸化重合性基含有非水分散型樹脂(樹脂成分:エポキシ基含有アクリルスチレン樹脂の大豆油脂肪酸変性物,ミネラルスピリットを媒体とする非水分散型樹脂、不飽和脂肪酸構成比率:10重量%、重量平均分子量:130000、酸価:0mgKOH/g、固形分:50重量%)
・樹脂4:酸基含有可溶型樹脂(樹脂成分:アクリルスチレン樹脂,ミネラルスピリットを媒体とする可溶型樹脂、重量平均分子量:11000、酸価:2mgKOH/g、アミン価:1mgKOH/g、水酸基価:30mgKOH/g、固形分:50重量%)
・樹脂5:酸化重合性基・酸基含有可溶型樹脂(樹脂成分:エポキシ基含有アクリルスチレン樹脂の大豆油脂肪酸変性物,ミネラルスピリットを媒体とする可溶型樹脂、不飽和脂肪酸構成比率:18重量%、重量平均分子量:11000、酸価:1mgKOH/g、水酸基価:40mgKOH/g、固形分:50重量%)
・樹脂6:酸化重合性基・酸基含有可溶型樹脂(樹脂成分:エポキシ基含有アクリルスチレン樹脂の大豆油脂肪酸変性物,ミネラルスピリットを媒体とする可溶型樹脂、不飽和脂肪酸構成比率:18重量%、重量平均分子量:80000、酸価:1mgKOH/g、水酸基価:40mgKOH/g、固形分:50重量%)
・樹脂7:酸化重合性基・酸基含有可溶型樹脂(樹脂成分:エポキシ基含有アクリルスチレン樹脂の大豆油脂肪酸変性物,ミネラルスピリットを媒体とする可溶型樹脂、不飽和脂肪酸構成比率:18重量%、重量平均分子量:120000、酸価:1mgKOH/g、水酸基価:40mgKOH/g、固形分:50重量%)
・樹脂8:酸化重合性基・酸基含有可溶型樹脂(樹脂成分:エポキシ基含有アクリルスチレン樹脂の大豆油脂肪酸変性物,ミネラルスピリットを媒体とする可溶型樹脂、不飽和脂肪酸構成比率:18重量%、重量平均分子量:120000、酸価:1mgKOH/g、水酸基価:16mgKOH/g、固形分:50重量%)
・樹脂9:酸化重合性基・酸基含有可溶型樹脂(樹脂成分:エポキシ基含有アクリルスチレン樹脂の大豆油脂肪酸変性物,ミネラルスピリットを媒体とする可溶型樹脂、不飽和脂肪酸構成比率:18重量%、重量平均分子量:120000、酸価:1mgKOH/g、水酸基価:8mgKOH/g、固形分:50重量%)
・樹脂10:酸化重合性基・酸基含有可溶型樹脂(樹脂成分:エポキシ基含有アクリルスチレン樹脂の大豆油脂肪酸変性物,ミネラルスピリットを媒体とする可溶型樹脂、不飽和脂肪酸構成比率:18重量%、重量平均分子量:120000、酸価:1mgKOH/g、水酸基価:2mgKOH/g、固形分:50重量%)
・酸化チタン1:表面処理ルチル型酸化チタン(吸油量:24g/100g、TiO2含有量:93%、表面処理化合物:シリカ、アルミナ、ジルコニア)
・酸化チタン2:表面処理ルチル型酸化チタン(吸油量:22g/100g、TiO2含有量:87%、表面処理化合物:シリカ、アルミナ、ジルコニア、有機化合物)
・酸化チタン3:表面処理ルチル型酸化チタン(吸油量:33g/100g、TiO2含有量:88%、表面処理化合物:シリカ、アルミナ)
・酸化チタン4:未処理ルチル型酸化チタン(吸油量:17g/100g、TiO2含有量:99%)
・酸化チタン5:アナターゼ型酸化チタン(吸油量:23g/100g、TiO2含有量:99%)
・着色顔料1:黒色顔料(カーボンブラック、吸油量:98g/100g)
・着色顔料2:黄色顔料(含水酸化第二鉄、吸油量:30g/100g)
・着色顔料3:赤色顔料(酸化第二鉄、吸油量:25g/100g)
・着色顔料4:青色顔料(銅フタロシアニンブルー、吸油量:35g/100g)
・体質顔料1:体質顔料(含水微粉珪酸、吸油量:250g/100g)
・有機金属化合物1:ナフテン酸コバルトのミネラルスピリット溶液
・有機金属化合物2:ナフテン酸ジルコニウムのミネラルスピリット溶液
・有機金属化合物3:ナフテン酸バリウムのミネラルスピリット溶液
・有機金属化合物4:アルミニウムモノアセチルアセトネートビス(エチルアセトアセテート)
・分散剤:ウレタン系分散剤
・増粘剤:アマイドワックス系増粘剤
・消泡剤:鉱物油系消泡剤
・溶剤:脂肪族炭化水素含有非水溶剤(ミネラルスピリットと芳香族炭化水素含有石油混合溶剤の混合物、脂肪族炭化水素含有比率:65重量%)
各コーティング剤について、以下の試験を実施した。
予めエポキシ樹脂下塗材を塗装したスレート板に、コーティング剤を塗付け量100g/m2でスプレー塗装した。日中は太陽光を受ける室内にて、所定時間(48時間、72時間)乾燥養生後、刷毛を用いて、同一のコーティング剤を塗付け量100g/m2で部分的に重ね塗りした。このときの塗膜の表面状態を観察し、リフティング現象が認められなかったものを「a」、ごく軽度のリフティング現象が認められたものを「b」、軽度のリフティング現象が認められたものを「c」、明らかにリフティング現象が認められたものを「d」とする4段階(a>b>c>d、実用レベルはa〜c)にて評価を行った。結果を表1〜3に示す。
予めエポキシ樹脂下塗材を塗装したスレート板に、コーティング剤を塗付け量100g/m2でスプレー塗装した。日中は太陽光を受ける室内にて、48時間乾燥養生後、刷毛を用いて、同一のコーティング剤を塗付け量100g/m2で部分的に重ね塗りした。この試験体を48時間放置後、スプレー塗装した領域と、刷毛塗りした領域との色差(△E)を色彩色差計にて測定した。評価基準は、△E0.5未満のものを「a」、△E0.5以上1.0未満のものを「b」、△E1.0以上1.5未満のものを「c」、△E1.5以上のものを「d」とした(実用レベルはa〜c)。結果を表1〜3に示す。なお、比較例2〜5については、上記重ね塗り適性1に劣る結果であったため、評価は行っていない。
実施例1〜21(特に実施例2〜9、14〜21)では、重ね塗り適性1及び2において良好な結果が得られた。また隠ぺい性も良好であった。
実施例5、及び14〜21のコーティング剤について、以下の試験を実施した。
ガラス板の片面に、すきま125μmのフィルムアプリケータを用いてコーティング剤を塗り、塗面を水平に置いて標準状態で48時間乾燥したときの鏡面光沢度(測定角度60度・20度)を測定した。評価は、
60度鏡面光沢度85以上かつ20度鏡面光沢度75以上を「a」、
60度鏡面光沢度85以上かつ20度鏡面光沢度75未満を「b」、
60度鏡面光沢度80以上85未満を「c」、
60度鏡面光沢度80未満を「d」、
として行った。結果を表4に示す。
予めエポキシ樹脂下塗材を塗装したスレート板に、コーティング剤を塗付け量100g/m2でスプレー塗装し、2時間後、同一のコーティング剤を再度塗付け量100g/m2でスプレー塗装し、標準状態(気温23℃、相対湿度50%環境下)にて3日間養生した。以上の方法で作製した試験体について、水浸漬18時間・−20℃3時間放置・50℃3時間放置を1サイクルとする温冷繰返し試験を合計10サイクル行った後、被膜外観を確認し、不具合(膨れ、剥れ、割れ等)の発生の状態を評価した。評価は、不具合発生が認められなかったものを「a」、明らかに不具合発生が認められたものを「d」とする4段階(a>b>c>d、実用レベルはa〜c)で行った。結果を表4に示す。
実施例15〜21では、仕上り性及び耐久性においても良好な結果が得られた。
Claims (2)
- 樹脂成分(A)、顔料(B)、有機金属化合物(C)、及び脂肪族炭化水素含有非水溶剤(D)を含むコーティング剤であって、
上記樹脂成分(A)として、非水分散型樹脂(A−1)、及び可溶型樹脂(A−2)を含み、
上記非水分散型樹脂(A−1)及び/または上記可溶型樹脂(A−2)が、酸化重合性基を有し、
上記非水分散型樹脂(A−1)及び/または上記可溶型樹脂(A−2)が、酸価を有し、
上記顔料(B)として、表面処理ルチル型酸化チタン(B−1)を含み、
上記樹脂成分(A)の固形分100gを基準としたときの上記顔料(B)の総吸油量が60g以下であることを特徴とするコーティング剤。 - 上記表面処理ルチル型酸化チタン(B−1)は、吸油量が30g/100g以下であることを特徴とする請求項1記載のコーティング剤。
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US4294735A (en) * | 1977-04-25 | 1981-10-13 | Imperial Chemical Industries Limited | Coating compositions |
US5331025A (en) * | 1992-11-04 | 1994-07-19 | Rohm And Haas Company | Coating compositions incorporating composite polymer particles |
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