JP2018525492A - 中空ガラス微小球を含むポリオレフィン組成物 - Google Patents
中空ガラス微小球を含むポリオレフィン組成物 Download PDFInfo
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- JP2018525492A JP2018525492A JP2018506867A JP2018506867A JP2018525492A JP 2018525492 A JP2018525492 A JP 2018525492A JP 2018506867 A JP2018506867 A JP 2018506867A JP 2018506867 A JP2018506867 A JP 2018506867A JP 2018525492 A JP2018525492 A JP 2018525492A
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- AYNNSCRYTDRFCP-UHFFFAOYSA-N triazene Chemical compound NN=N AYNNSCRYTDRFCP-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/28—Glass
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
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- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
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- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
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- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
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- General Chemical & Material Sciences (AREA)
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- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Description
Ross Mixer(Charles Ross&Son Company,Hauppauge,N.Y.から入手可能)へ、3−アミノプロピルトリエトキシシラン(Evonik,Germanyから商品名「AMEO」で市販)の0.5重量%水溶液1500gを装入した。ガラスバブル(3M Company,St.Paul,MN,USAから商品名「iM16k」で入手可能)を、並みの混合速度で混合時間15分をかけてゆっくりと加えた。ガラスバブルの添加を、被覆濃度1.1重量%が達成されるような方法で行った。それに伴うペーストをアルミニウムのパン中へ注入し、強制空気オーブン中、80℃において一晩乾燥させた。乾燥したガラスバブルを180μmの篩を通してふるい、あらゆる凝集塊を除去した。
26重量%のガラスバブルGB1又はGB2を有するマスターバッチを、12の加熱ゾーン(40℃、195℃、210℃、210℃、210℃、210℃、210℃、210℃、210℃、210℃、210℃、210℃)が装備され300rpmで動作する共回転噛合26mm二軸押出機(L/D:55)中、調合した。ポリプロピレンポリマーペレットPPを、重量樹脂フィーダーを経てゾーン1へ供給し、次いで混錬ブロックと搬送要素とのセットを通した。ガラスバブルを、ゾーン4における重量供給系を備えたサイドフィーダーを用いて、溶融流れ中へ導入した。ガラスバブルのサイド供給の時点で、並びに残りの下流処理のために、高チャネル深さ運搬要素(OD/ID:1.75)、及び穏やかな分配の混合要素を用いた。押出物を水浴中で冷却し、続いてペレット化した。
最終組成物の調合と、試験片の射出成型とを、1つの工程において、Polymaterials AG,Kaufbeuren,Germanyにより開発されたハイスループットコンパウンディング(HTC)装置を用いて実施した。用いたHTC装置は、Engel,Schwertberg,Austriaからの改良型射出成型機であり、2つのプラスチック化ユニット/射出ユニット、及び調合のための集積化された内部混合機系を備える。この装置の詳細は、Kunststoffe international,9/2007,pp.145〜149で公開されている。
密度
成型した部分の密度を、DIN EN ISO 1183−3に従って、ガスピクノメータ(Micromeritics,Norcross,Georgia,USA製の「ACCUPYC II 1340 PYCNOMETER」)を用いて決定した。したがって、成型した試験片の代表部分の質量を決定し、続いて体積を、ガスピクノメータにより決定した。次いで密度を、式:密度=質量/体積に従って算出する。
射出成型した複合体の機械的特性を、表2に列記したISO標準試験法を用いて測定した。Zwick,Germany製の、10kNロードセル及び引張グリップを備えた引張試験装置Z010を、引張特性を決定するために用いた。Zwick HIT5.5P衝撃試験機及びその試験片のノッチャーを、成型した部品の室温でのシャルピーノッチ付き衝撃強度を測定するのに用いた。所与の試料からの少なくとも5つの異なる試験片を、引張及び衝撃試験で試験した。結果の算術平均を、以下の実施例において決定して報告した。結果には、高い再現性が観察され、試験結果における標準偏差は、典型的に3〜5%以下の範囲であることを観察した。
ポリアミド(PA6)を添加したポリプロピレン系配合物
任意の更なる添加剤、例えば耐衝撃性改良剤、相溶化剤又は充填剤なしに、極性半晶質熱可塑性添加剤PST1を添加すると、PP及びGB1に基づく化合物の引張強度及びシャルピーノッチ付き衝撃強度は低下する(表3において、比較例1(CEX1)と比較例2(CEX2)とを比較されたい)。相溶化剤C1を更に添加すると、引張強度は実質的に上がり、かつ驚くことにまたシャルピーノッチ付き衝撃強度も上がり、一方で、弾性率は一定に保たれる(表3において、比較例1(CEX1)及び比較例2(CEX2)を、実施例1(EX1)と比較されたい)。
エチレンビニルコポリマーを添加したポリプロピレン系配合物
耐衝撃性改良剤と相溶化剤との組み合わせC2を、GB1と一緒に使用する組成物において、極性半晶質熱可塑性添加剤PST2を更に添加すると、シャルピーノッチ付き衝撃強度は実質的に上がり、一方で、引張強度及び引張弾性率は一定に保たれる(表4において、比較例10(CEX10)を、実施例5(EX5)と比較されたい)。
ポリエチレンテレフタレートを添加したポリプロピレン系配合物
相溶化剤と耐衝撃性改良剤との組み合わせC2を有する配合物において、シャルピーノッチ付き衝撃強度は実質的に上がり、一方で、引張弾性率及び引張強度は、耐衝撃性改良剤IM1及び極性半晶質熱可塑性添加剤PST3を加えることにより、ほとんど一定に保たれる(表5において、比較例13(CEX13)を、実施例8(EX8)と比較されたい)。
実施形態1.ポリオレフィン、中空ガラス微小球、極性半晶質熱可塑性添加剤、及び耐衝撃性改良剤又は相溶化剤のうちの少なくとも1種を含む組成物。
Claims (18)
- ポリオレフィン、中空ガラス微小球、極性半晶質熱可塑性添加剤、及び耐衝撃性改良剤又は相溶化剤のうちの少なくとも1種を含む組成物。
- 組成物の総重量に基づいて、前記中空ガラス微小球が、0.2重量%〜49重量%の範囲で存在し、前記極性半晶質熱可塑性添加剤が、0.5重量%〜49.3重量%の範囲で存在し、前記耐衝撃性改良剤が、0重量%〜49.3重量%の範囲で存在し、前記相溶化剤が、0重量%〜20重量%の範囲で存在する、請求項1に記載の組成物。
- ポリオレフィンと組み合わせるためのマスターバッチ組成物であって、前記マスターバッチが、中空ガラス微小球及び極性半晶質熱可塑性添加剤を含む、マスターバッチ組成物。
- ポリオレフィンを更に含む、請求項3に記載のマスターバッチ組成物。
- 耐衝撃性改良剤又は相溶化剤のうちの少なくとも1種を更に含む、請求項3又は4に記載のマスターバッチ組成物。
- 前記中空ガラス微小球が、20重量%〜60重量%の範囲で存在し、前記極性半晶質熱可塑性添加剤が、1重量%〜80重量%の範囲で存在する、請求項3〜5のいずれか一項に記載のマスターバッチ組成物。
- 前記ポリオレフィンが、ポリプロピレン又はポリエチレンのうちの少なくとも1種を含む、請求項1、2及び4〜6のいずれか一項に記載の組成物。
- 前記極性半晶質熱可塑性添加剤が、ポリアミド、ビニルポリマー、ポリエステル、ポリケトン、ポリエーテルケトン、ポリエーテルエーテルケトン、ポリアリーレンスルフィド、又はこれらの組み合わせである、請求項1〜7のいずれか一項に記載の組成物。
- 前記相溶化剤が、無水マレイン酸変性ポリマーである、請求項1、2及び5〜8のいずれか一項に記載の組成物。
- 前記耐衝撃性改良剤が、極性官能基を含まない、請求項1、2及び5〜9のいずれか一項に記載の組成物。
- 前記耐衝撃性改良剤が、極性官能基を有する、請求項1、2及び5〜9のいずれか一項に記載の組成物。
- 前記極性官能基が、無水マレイン酸(MAH)、無水イタコン酸(IAH)、又は無水シトラコン酸(CAH)、アクリル酸、マレイン酸、イタコン酸、シトラコン酸、又は別のカルボン酸である、請求項11に記載の組成物。
- 前記中空ガラス微小球が、シランカップリング剤で表面処理されている、請求項1〜12のいずれか一項に記載の組成物。
- 発泡パーライトを更に含む、請求項1〜13のいずれか一項に記載の組成物。
- 前記中空ガラス微小球の10体積%が崩壊する静水圧が、少なくとも100MPaである、請求項1〜14のいずれか一項に記載の組成物。
- 固体である請求項1〜15のいずれか一項に記載の組成物を含む、物品。
- 物品を作製する方法であって、請求項1〜15のいずれか一項に記載の組成物を溶融加工して前記物品を作製することを含む、方法。
- 安全帽、自動車の内装及び外装コンポーネント、包装用材料及び運送用材料、航空宇宙用物品、海洋、鉄道及び他の輸送機関用途、家庭用品、玩具、並びにレジャー及びスポーツ用物品を作製するための、請求項1〜15のいずれか一項に記載の組成物の使用。
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PCT/US2016/046539 WO2017027700A1 (en) | 2015-08-13 | 2016-08-11 | Polyolefin composition comprising hollow glass microspheres |
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EP3130636A1 (en) | 2017-02-15 |
KR101957116B1 (ko) | 2019-03-11 |
WO2017027700A1 (en) | 2017-02-16 |
US20190002678A1 (en) | 2019-01-03 |
CN107922691A (zh) | 2018-04-17 |
BR112018002933A2 (pt) | 2019-03-19 |
JP6530556B2 (ja) | 2019-06-12 |
US10696831B2 (en) | 2020-06-30 |
KR20180031783A (ko) | 2018-03-28 |
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