JP2018168091A - Discoloration inhibitor of dyed hair, and composition for hair containing the same - Google Patents
Discoloration inhibitor of dyed hair, and composition for hair containing the same Download PDFInfo
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- JP2018168091A JP2018168091A JP2017066559A JP2017066559A JP2018168091A JP 2018168091 A JP2018168091 A JP 2018168091A JP 2017066559 A JP2017066559 A JP 2017066559A JP 2017066559 A JP2017066559 A JP 2017066559A JP 2018168091 A JP2018168091 A JP 2018168091A
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- hair
- extract
- discoloration
- dyed
- inhibitor
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- 238000002845 discoloration Methods 0.000 title claims abstract description 28
- 239000003112 inhibitor Substances 0.000 title claims abstract description 25
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 15
- 239000000460 chlorine Substances 0.000 claims abstract description 15
- 230000000694 effects Effects 0.000 claims abstract description 10
- 239000008399 tap water Substances 0.000 claims abstract description 6
- 235000020679 tap water Nutrition 0.000 claims abstract description 6
- 230000001133 acceleration Effects 0.000 claims abstract description 4
- 239000000284 extract Substances 0.000 claims description 73
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 20
- 244000144730 Amygdalus persica Species 0.000 claims description 15
- 238000004043 dyeing Methods 0.000 claims description 9
- 238000005562 fading Methods 0.000 claims description 9
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- 206010019030 Hair colour changes Diseases 0.000 claims description 5
- 210000003298 dental enamel Anatomy 0.000 claims description 5
- 241001647091 Saxifraga granulata Species 0.000 claims description 2
- 238000004040 coloring Methods 0.000 abstract description 6
- 238000005406 washing Methods 0.000 abstract description 4
- 230000002401 inhibitory effect Effects 0.000 abstract description 3
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- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 1
- UNWFFCPRJXMCNV-UHFFFAOYSA-N 3-[dodecanoyl(methyl)amino]propanoic acid Chemical compound CCCCCCCCCCCC(=O)N(C)CCC(O)=O UNWFFCPRJXMCNV-UHFFFAOYSA-N 0.000 description 1
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- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
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- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
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- CCDWGDHTPAJHOA-UHFFFAOYSA-N benzylsilicon Chemical compound [Si]CC1=CC=CC=C1 CCDWGDHTPAJHOA-UHFFFAOYSA-N 0.000 description 1
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- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
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- Cosmetics (AREA)
Abstract
Description
本発明は、染色毛の褪色、特に水道水中に含まれる遊離残留塩素による褪色加速に対して抑制効果に優れる褪色抑制剤及びこれを含有する頭髪用組成物に関する。 The present invention relates to a discoloration inhibitor having an excellent inhibitory effect on discoloration of dyed hair, in particular, fading acceleration due to free residual chlorine contained in tap water, and a hair composition containing the same.
近年、毛髪を綺麗に見せるために毛髪の色を様々な色に変化させるカラーリングが老若男女問わず行われており、白髪染めやオシャレ染めなど毛髪を染めることに対する消費者の関心は高まる傾向にあり、さらに毛髪に対する染色技術も日々改良が行われている。しかしながら、カラーリングした染色毛は、日光等の紫外線曝露や日常生活における繰返しの洗髪処理によって変色や色素消失、色素溶出等の褪色の問題により、カラーリング後の仕上がりのような色を維持することが難しい問題がある(特許文献1)。 In recent years, coloring to change hair color into various colors has been performed to make hair look beautiful, and there is a tendency for consumers to be interested in dyeing hair such as gray hair dyeing and fashion dyeing. In addition, hair dyeing techniques are being improved daily. However, the dyed hair that has been colored should maintain its color after the coloring due to discoloration problems such as discoloration, pigment disappearance, and pigment elution due to repeated exposure to ultraviolet rays such as sunlight and daily washing. There is a difficult problem (Patent Document 1).
カラーリング後の染色毛の色を維持するために、カルボキシベタイン型の両性界面活性剤と糖系非界面活性剤を用いた技術(特許文献2)やエーテルカルボン酸とその塩、アルキルグルコシド、ステロール誘導体を用いる技術(特許文献3)、アミドベタイン型両性界面活性剤とアニオン界面活性剤を用いる技術(特許文献4)が報告されている。しかしながら、これらは洗髪処理において染色毛の褪色を十分に抑制することができない点や染色毛からの色素溶出を抑制することが不十分であった。 In order to maintain the color of dyed hair after coloring, a technique using a carboxybetaine-type amphoteric surfactant and a sugar-based non-surfactant (Patent Document 2), ether carboxylic acid and its salt, alkyl glucoside, sterol A technique using a derivative (Patent Document 3) and a technique using an amide betaine amphoteric surfactant and an anionic surfactant (Patent Document 4) have been reported. However, these cannot sufficiently suppress the discoloration of the dyed hair in the hair washing treatment, and do not sufficiently suppress the dye elution from the dyed hair.
本発明は、従来における問題を解決する染色毛の褪色抑制剤及びこれを含有する頭髪用組成物を提供することを課題とする。 It is an object of the present invention to provide a dyed hair fading inhibitor and a hair composition containing the same, which solve the conventional problems.
本発明者らは、染色毛の褪色抑制剤及びこれを含有する頭髪用組成物について鋭意研究した結果、日常的な洗髪処理に用いられる水道水中に含まれる遊離残留塩素による染色毛の褪色加速をモモ葉エキス、シナノキエキス、ジオウエキス、チンピエキス、パセリエキス、センキュウエキス、ユキノシタエキス、ガイヨウエキス、エンメイソウエキスから選択させる少なくとも1種を含有することで、顕著に褪色抑制効果を示すことを見出し、本発明を完成するに至った。 As a result of diligent research on dyeing hair discoloration inhibitors and hair-containing compositions containing the same, the present inventors have accelerated dyeing hair discoloration by free residual chlorine contained in tap water used for daily hair washing treatment. It has been found that by containing at least one selected from peach leaf extract, linden extract, gentian extract, chimpi extract, parsley extract, nematode extract, saxifrage extract, diatomaceous earth extract, and enamel extract, the present invention has a remarkable discoloration suppressing effect. It came to complete.
本発明の染色毛の褪色抑制剤及びこれを含有する頭髪用組成物は、染色毛に対して優れた褪色抑制効果及び水道水に含まれる遊離残留塩素を消去する作用を有し、カラーリング後の仕上がり色を維持することができる。 The dyed hair discoloration inhibitor of the present invention and the hair composition containing the same have an excellent discoloration inhibiting effect on the dyed hair and an action of eliminating free residual chlorine contained in tap water, and after coloring The finished color can be maintained.
本発明の褪色抑制剤は、遊離残留塩素の消去作用を有するモモ葉エキス、シナノキエキス、ジオウエキス、チンピエキス、パセリエキス、センキュウエキス、ユキノシタエキス、ガイヨウエキス、エンメイソウエキスから選択される少なくとも1種を含有し、さらに必要に応じてその他の成分を含有している。 The discoloration inhibitor of the present invention contains at least one selected from a peach leaf extract, a linden extract, a gentian extract, a chimpan extract, a parsley extract, a genus cucumber extract, a cypress extract, a diatom extract, and an enamel extract that have a scavenging action for free residual chlorine. In addition, it contains other components as required.
本発明に係る染色毛の褪色抑制剤は、モモ葉エキス(バラ科,学名:Prunus persica)、シナノキエキス(シナノキ科,学名:Tilia cordata)、ジオウエキス(ゴマノハグサ科,学名:Rehmannia glutinosa)、チンピエキス(ミカン科,学名:Citrus unshiu)、パセリエキス(セリ科,学名:Petroselinum sativum)、センキュウエキス(セリ科,学名:Cnidium officinale)、ユキノシタエキス(ユキノシタ科,学名:Saxifraga stolonifera)、ガイヨウエキス(キク科,学名:Artemisia princeps)、エンメイソウエキス(シソ科,学名:Rabdosia japonica)であり、これらはいずれも植物からの抽出物であり、その使用部位は、特に制限はなく、目的に応じ適宜選択することができ、例えば、葉、茎、花、果皮、根、根茎、地上部、全草等またはこれらの混合物が挙げられる。 The discoloration inhibitor for dyed hair according to the present invention includes peach leaf extract (Rosaceae, scientific name: Prunus persica), linden extract (Shinoki department, Scientific name: Tilia cordata), gentian extract (Lepidoptera, Scientific name: Rehmannia glutinosa), chimpi extract ( Citrus, Scientific name: Citrus unshiu), Parsley extract (Apiaceae, Scientific name: Petroselinum sativum), Senkyu extract (Apiaceae, Scientific name: Cinidium officinale), Yukinoshita extract (Yukinoshita, Scientific name) Scientific name: Artemisia princeps), Enmezo extract (Lamiaceae, Scientific name: Rabdosia japonica), These are all extracts from plants, and their use site is not particularly limited and can be appropriately selected according to the purpose. For example, leaves, stems, flowers, pericarp, roots, rhizomes, above-ground parts, The whole plant etc. or these mixtures are mentioned.
上記植物をエキスとして利用する場合は、抽出溶媒は特に限定されないが、上記植物を溶媒、例えば、水、低級アルコール、含水低級アルコール、プロピレングリコール、1,3−ブチレングリコール、ブタノール、含水プロピレングリコール、含水1,3−ブチレングリコール、含水ブタノール等の極性溶媒、またはクロロホルム、酢酸エチル、各種エーテル等あるいはこれらの混合有機溶媒で抽出して得たエキスをそのまま、あるいは濃縮して用いるか、不純物を除去したり、有機溶媒で溶出し濃縮したエキスや分配法等の手法を用いて抽出したエキスも使用できる。市販品としては、例えば、丸善製薬株式会社製のモモ抽出液、モモ抽出液BG、モモ抽出液LA、シナノキ抽出液、シナノキ抽出液BG−J、ジオウ抽出液J、ジオウ抽出液BG−J、チンピ抽出液−J、チンピ抽出液BG、チンピ抽出液LA、パセリ抽出液BG−J、センキュウ抽出液−JC、センキュウ抽出液BG、センキュウ抽出液LA、ユキノシタ抽出液、ユキノシタ抽出液BG、ガイヨウ抽出液、ガイヨウ抽出液BG、ガイヨウ抽出液LA、エンメイソウ抽出液−JC、エンメイソウ抽出液BG等が挙げられる。 When using the plant as an extract, the extraction solvent is not particularly limited, but the plant is a solvent such as water, lower alcohol, hydrous lower alcohol, propylene glycol, 1,3-butylene glycol, butanol, hydrous propylene glycol, Extracts obtained by extraction with polar solvents such as hydrous 1,3-butylene glycol, hydrous butanol, chloroform, ethyl acetate, various ethers, etc., or mixed organic solvents thereof, are used as they are or after concentration, or impurities are removed. Alternatively, an extract eluted with an organic solvent and concentrated, or an extract extracted using a technique such as a partitioning method can be used. As a commercial item, for example, peach extract manufactured by Maruzen Pharmaceutical Co., Ltd., peach extract BG, peach extract LA, linden extract, linden extract BG-J, gentian extract J, gentian extract BG-J, Chimpi Extract-J, Chimpi Extract BG, Chimpi Extract LA, Parsley Extract BG-J, Nematode Extract-JC, Nematode Extract BG, Nematode Extract LA, Yukinoshita Extract, Yukinoshita Extract BG, Gayoi Extract Liquid, diatomaceous earth extract BG, diatomaceous earth extract LA, enamel extract-JC, enamel extract BG and the like.
本発明の染色毛の褪色抑制剤を含有する頭髪用組成物には、褪色抑制効果のほか、染色向上、刺激緩和、ダメージ抑制、感触向上等の機能を持った成分と併用することができる。これらの成分を併用することは、本発明の染色毛の褪色抑制剤及びこれを含有する頭髪用組成物との相乗効果をもたらし、本発明品を損なうものではない。 The hair composition containing the dyed hair discoloration inhibitor of the present invention can be used in combination with components having functions such as dyeing improvement, stimulation mitigation, damage suppression, and touch improvement in addition to the effect of fading suppression. Use of these components in combination brings about a synergistic effect with the dyed hair fading inhibitor of the present invention and the hair composition containing the same, and does not impair the product of the present invention.
本発明の染色毛の褪色抑制剤を含有する頭髪用組成物への配合量は、好ましくは0.01〜20.0質量%であり、より好ましくは、0.1〜5.0質量%である。 The amount of the hair composition containing the discoloration inhibitor for dyed hair of the present invention is preferably 0.01 to 20.0% by mass, more preferably 0.1 to 5.0% by mass. is there.
本発明の染色毛の褪色抑制剤を含有する頭髪用組成物は、本発明の効果を損なわない範囲において、通常の頭髪用組成物に用いられる各種成分、例えば、油性成分、高級アルコール、脂肪酸、極性脂質、保湿成分、抗菌成分、pH調整剤、粘度調整剤、感触向上剤、紫外線吸収剤、粉体、ビタミン誘導体及びその塩、酸化防止剤、育毛剤、染料、香料などを配合することができる。 The composition for hair containing the discoloration inhibitor for dyed hair of the present invention has various components used in a normal hair composition, for example, oily components, higher alcohols, fatty acids, within the range not impairing the effects of the present invention. May contain polar lipids, moisturizing ingredients, antibacterial ingredients, pH adjusters, viscosity adjusters, feel improvers, UV absorbers, powders, vitamin derivatives and their salts, antioxidants, hair restorers, dyes, fragrances, etc. it can.
例えば、油性成分としては、スクワラン、流動パラフィンなどの炭化水素油、オリーブ油、マカデミアナッツ油、ホホバ油などの植物油、トリエチルヘキサノイン、トリ(カプリル・カプリン酸)グリセリル、エチルヘキサン酸セチル、セバシン酸ジエチル、パルミチン酸エチルヘキシルなどのエステル油、ジメチルシリコーン、フェニルメチルシリコーン、シクロメチコンなどのシリコーン油などが挙げられる。高級アルコールとしては、ラウリルアルコール、セチルアルコール、ステアリルアルコール、オレイルアルコール、セトステアリルアルコールなどが挙げられる。脂肪酸としては、炭素数12以上の直鎖脂肪酸、分岐脂肪酸、不飽和脂肪酸、ヒドロキシ脂肪酸などが挙げられる。 For example, as oil components, hydrocarbon oils such as squalane, liquid paraffin, vegetable oils such as olive oil, macadamia nut oil, jojoba oil, triethylhexanoin, glyceryl tri (caprylic / capric acid), cetyl ethylhexanoate, diethyl sebacate, Examples include ester oils such as ethylhexyl palmitate, and silicone oils such as dimethyl silicone, phenylmethyl silicone, and cyclomethicone. Examples of the higher alcohol include lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, cetostearyl alcohol and the like. Examples of fatty acids include straight chain fatty acids having 12 or more carbon atoms, branched fatty acids, unsaturated fatty acids, and hydroxy fatty acids.
本発明に係る頭髪用組成物の使用用途は、特に限定されるものではないが、例えば、油系及び乳化系、水系を問わず、ヘアクリーム、ヘアミルク、ヘアリキッド、ヘアローション、ヘアコンディショナー、ヘアリンス、ヘアトリートメント、ヘアシャンプー、ヘアムース、ヘアミスト、ヘアカラー、ヘアマニキュアなどが挙げられる。 The use of the composition for hair according to the present invention is not particularly limited. For example, hair cream, hair milk, hair liquid, hair lotion, hair conditioner, hair rinse, regardless of oil system, emulsion system, or water system. , Hair treatment, hair shampoo, hair mousse, hair mist, hair color, hair manicure and so on.
本発明に係る染色毛とは、特に限定されるものではないが、例えば、酸性染料、塩基性染料、ニトロ染料、酸化染料などで染色した毛髪が挙げられる。 The dyed hair according to the present invention is not particularly limited, and examples thereof include hair dyed with an acid dye, a basic dye, a nitro dye, an oxidation dye, and the like.
以下に、実施例を挙げて本発明を具体的に説明するが、本発明の技術的範囲がこれらに限定されるものではない。 EXAMPLES The present invention will be specifically described below with reference to examples, but the technical scope of the present invention is not limited to these examples.
褪色抑制剤による遊離残留塩素の消去作用
1.試験概要
本発明品の褪色抑制剤の遊離残留塩素消去作用を評価した。
1. Elimination of free residual chlorine by fading inhibitor Test Outline The discoloration inhibitor of the present invention was evaluated for free residual chlorine scavenging action.
2.実験方法
試験管に、精製水で希釈した本発明の褪色抑制剤を10μLと水道水890μLを混合した。その後、100mg/mLに調製したラピッドDPD試薬(関東化学)を100μL添加し、よく混合した後、マイクロプレートリーダーで510nmの吸光度を測定し、消去率として算出した。
褪色抑制剤として丸善製薬株式会社製のモモ葉エキス(商品名:モモ抽出液BG)、シナノキエキス(商品名:シナノキ抽出液BG−J)、ジオウエキス(商品名:ジオウ抽出液BG−J)、チンピエキス(商品名:チンピ抽出液BG)、パセリエキス(商品名:パセリ抽出液BG−J)、センキュウエキス(商品名:センキュウ抽出液BG)、ユキノシタエキス(商品名:ユキノシタ抽出液BG)、ガイヨウエキス(商品名:ガイヨウ抽出液BG)、エンメイソウエキス(エンメイソウ抽出液BG)を使用した。
2. Experimental Method A test tube was mixed with 10 μL of the fading inhibitor of the present invention diluted with purified water and 890 μL of tap water. Thereafter, 100 μL of rapid DPD reagent (Kanto Chemical) prepared to 100 mg / mL was added and mixed well, and then the absorbance at 510 nm was measured with a microplate reader and calculated as the erasure rate.
Peach leaf extract (trade name: peach extract BG), linden extract (trade name: linden extract BG-J), ziou extract (trade name: ziou extract BG-J), manufactured by Maruzen Pharmaceutical Co., Ltd. Chimpi extract (trade name: Chimpi extract BG), Parsley extract (trade name: Parsley extract BG-J), Senkyu extract (trade name: Senkyu extract BG), Yukinoshita extract (Product name: Yukinoshita extract BG), Gayoi extract (Trade name: gaitou extract BG) and enmiso extract (enmiso extract BG) were used.
3.結果
結果を表1に示した。いずれの本発明品の褪色抑制剤においても0.1%添加することで、50%以上の遊離残留塩素消去活性を示した。
3. Results The results are shown in Table 1. Addition of 0.1% of any discoloration inhibitor of the product of the present invention showed a free residual chlorine scavenging activity of 50% or more.
染色毛の遊離残留塩素による褪色に対するモモ葉エキスの褪色抑制作用
1.試験概要
遊離残留塩素による染色毛の褪色に対するモモ葉エキスの褪色抑制作用を評価した。
1. Anti-fading effect of peach leaf extract against fading caused by free residual chlorine in dyed hair Test Outline The effect of peach leaf extract on the discoloration of dyed hair by free residual chlorine was evaluated.
2.実験方法
ブリーチした毛束に対し、市販の酸化染毛料(赤色)を用いて、添付のインストラクションに従って染毛を施した。染色毛は、未処理コントロールとして精製水に、また遊離残留塩素として次亜塩素酸を10%添加した精製水中に浸漬した。これらを基本条件とし、各条件1%モモ葉エキス(商品名:モモ抽出液BG,丸善製薬株式会社)の添加有無の条件を準備した。染色毛は、各溶液に浸漬し2時間振とう後、シャンプー、ドライヤーでの乾燥を行い、これを3サイクル繰り返した後、染色毛を乾燥させた後、染色毛の色調を色差計(CR−13、コニカミノルタHD)を用いて測定した。赤色の指標であるa*を色味の指標として評価した。
2. Experimental Method Hair bleaching was performed on the bleached hair bundle using a commercially available oxidation hair dye (red) according to the attached instructions. The dyed hair was immersed in purified water as an untreated control and in purified water to which 10% hypochlorous acid was added as free residual chlorine. With these as basic conditions, conditions for the presence or absence of addition of 1% peach leaf extract (trade name: peach extract BG, Maruzen Pharmaceutical Co., Ltd.) were prepared for each condition. The dyed hair is immersed in each solution and shaken for 2 hours, then dried with a shampoo and a dryer. After repeating this for three cycles, the dyed hair is dried, and then the color of the dyed hair is measured by a color difference meter (CR- 13, Konica Minolta HD). The red index a * was evaluated as a color index.
3.結果
精製水中ではモモ葉エキスの有無による色味の差は認められなかった。一方、次亜塩素酸含有溶液では、精製水と比べ有意な色味の減少が認められたことから、遊離残留塩素による褪色の加速が確認された。これに対し、1%のモモ葉エキスを添加することで、色味の変化は認められなかった。以上のことより、モモ葉エキスは遊離残留塩素の繰返し曝露による染色毛の褪色に対して、顕著な褪色抑制効果を有することが明らかとなった。
3. Results No difference in color was observed between purified water and peach leaf extract. On the other hand, in the hypochlorous acid-containing solution, a significant decrease in color was observed compared to purified water, confirming acceleration of discoloration due to free residual chlorine. On the other hand, the color change was not recognized by adding 1% peach leaf extract. From the above, it has been clarified that the peach leaf extract has a remarkable discoloration suppressing effect on the discoloration of the dyed hair caused by repeated exposure to free residual chlorine.
以下に、本発明の染色毛の褪色抑制剤を配合した頭髪用組成物の応用例を示す。配合量は質量%である。実施例3〜8は、いずれも実施例2の評価法により染色毛の褪色抑制効果が認められた。 Below, the application example of the composition for hair which mix | blended the discoloration inhibitor of the dyed hair of this invention is shown. A compounding quantity is the mass%. In each of Examples 3 to 8, the effect of suppressing discoloration of the dyed hair was recognized by the evaluation method of Example 2.
シャンプー
(A)1,3−ブチレングリコール 4.0(質量%)
70%ソルビトール水溶液 2.0
グアーヒドロキシプロピルトリモニウムクロリド 1.0
クエン酸 0.6
キレート剤 適量
防腐剤 適量
(B)水 残量
モモ葉エキス(1,3−ブチレングリコール、水) 5.0
(C)ココイルメチルタウリンNa水溶液(30%)
(NIKKOL CMT−30) 20.0
ラウロイルメチルアラニンNa水溶液(30%)
(NIKKOL アラニネートLN−30) 15.0
コカミドプロピルベタイン
(NIKKOL AM−3130N) 15.0
(カプリリル/カプリル)グルコシド 10.0
ラウリン酸プロピレングリコール 2.0
PEG−40水添ヒマシ油
(NIKKOL HCO−40) 3.0
ジステアリン酸エチレングリコール
(NIKKOL エステパール 15V) 2.0
合計 100.0
調製方法:A相を室温で均一に混合し、これにB相を加え均一とした後、80℃に加温しながら十分に膨潤させる。膨潤後、C成分を1成分ずつ添加し、全て添加後に再度加温し均一混合する。35℃まで冷却する。
Shampoo (A) 1,3-butylene glycol 4.0 (mass%)
70% sorbitol aqueous solution 2.0
Guar hydroxypropyltrimonium chloride 1.0
Citric acid 0.6
Chelating agent Suitable amount Preservative Suitable amount (B) Water remaining Peach leaf extract (1,3-butylene glycol, water) 5.0
(C) Cocoyl methyl taurine Na aqueous solution (30%)
(NIKKOL CMT-30) 20.0
Lauroylmethylalanine Na aqueous solution (30%)
(NIKKOL Alaninate LN-30) 15.0
Cocamidopropyl betaine (NIKKOL AM-3130N) 15.0
(Caprylyl / Capryl) Glucoside 10.0
Propylene glycol laurate 2.0
PEG-40 hydrogenated castor oil (NIKKOL HCO-40) 3.0
Ethylene glycol distearate (NIKKOL Estepearl 15V) 2.0
Total 100.0
Preparation method: Phase A is uniformly mixed at room temperature, and phase B is added thereto to make it uniform. After swelling, C component is added one by one, and after all addition, the mixture is heated again and mixed uniformly. Cool to 35 ° C.
インバストリートメント
(A)ステアラミドプロピルジメチルアミン
(NIKKOL アミドアミン MPS) 3.25(質量%)
ステアリン酸グリセリル
(NIKKOL MGS−BV2) 0.50
ステアリルアルコール
(NIKKOL 脱臭ステアリルアルコール) 7.0
ラウリン酸メチルへプチル
(NIKKOL GS−MHL) 3.0
スクワラン
(NIKKOL シュガースクワラン) 3.0
イソステアリン酸フィトステアリル 3.0
ダイマージリノール酸/ステアリン酸/ヒドロキシステアリン酸)
ポリグリセリル−10 (NIKKOL GS−WHO) 4.0
(B)プロピレングリコール 5.0
グルタミン酸 1.05
ポリクオタニウム−47 2.4
防腐剤 適量
水 残量
(C)モモ葉エキス(エタノール、水) 5.0
香料 適量
合計 100.0
調製方法:A相およびB相をそれぞれ80℃に加温し均一溶解する。B相にA相を添加し、乳化する。撹拌しながら40℃まで冷却し、さらにC相を添加し均一撹拌し、35℃に冷却する。
Invas Treatment (A) Stearamidpropyldimethylamine (NIKKOL Amidoamine MPS) 3.25 (mass%)
Glyceryl stearate (NIKKOL MGS-BV2) 0.50
Stearyl alcohol (NIKKOL deodorized stearyl alcohol) 7.0
Methyl heptyl laurate (NIKKOL GS-MHL) 3.0
Squalane (NIKKOL Sugar Squalane) 3.0
Phytostearyl isostearate 3.0
Dimer linoleic acid / stearic acid / hydroxystearic acid)
Polyglyceryl-10 (NIKKOL GS-WHO) 4.0
(B) Propylene glycol 5.0
Glutamic acid 1.05
Polyquaternium-47 2.4
Preservative Suitable amount Water Remaining amount (C) Peach leaf extract (ethanol, water) 5.0
Perfume appropriate amount Total 100.0
Preparation method: Phase A and phase B are each heated to 80 ° C. and uniformly dissolved. Add Phase A to Phase B and emulsify. Cool to 40 ° C. with stirring, add phase C, stir uniformly and cool to 35 ° C.
アウトバストリートメント
(A)ミリスチルアルコール 2.6(質量%)
オレイルグリセリル
(NIKKOL セラキルアルコール) 0.5
ベヘニルアルコール
(NIKKOL ベヘニルアルコール 65) 0.25
ステアリン酸ソルビタン
(NIKKOL SS−10V) 0.25
ステアルトリモニウムクロリドエタノール水溶液
(NIKKOL CA−2450) 1.4
シクロペンタシロキサン 11.0
(B)グリセリン 2.0
防腐剤 適量
水 残量
(C)モモ葉エキス(1,3−ブチレングリコール、水) 3.0
香料 適量
合計 100.0
調製方法:A相およびB相をそれぞれ80℃に加温し均一溶解する。A相にB相を添加し、乳化する。撹拌しながら35℃まで冷却し、さらにC相を加え撹拌する。
Out bath treatment (A) Myristyl alcohol 2.6 (mass%)
Oleyl glyceryl (NIKKOL cerakil alcohol) 0.5
Behenyl alcohol (NIKKOL behenyl alcohol 65) 0.25
Sorbitan stearate (NIKKOL SS-10V) 0.25
Stealtrimonium chloride ethanol aqueous solution (NIKKOL CA-2450) 1.4
Cyclopentasiloxane 11.0
(B) Glycerin 2.0
Preservative Suitable amount Water Remaining amount (C) Peach leaf extract (1,3-butylene glycol, water) 3.0
Perfume appropriate amount Total 100.0
Preparation method: Phase A and phase B are each heated to 80 ° C. and uniformly dissolved. Add Phase B to Phase A and emulsify. Cool to 35 ° C. with stirring, add phase C and stir.
アウトバストリートメント
(A)ミリスチルアルコール 2.6(質量%)
オレイルグリセリル
(NIKKOL セラキルアルコール) 0.5
ベヘニルアルコール
(NIKKOL ベヘニルアルコール 65) 0.25
ステアリン酸ソルビタン
(NIKKOL SS−10V) 0.25
ステアルトリモニウムクロリドエタノール水溶液
(NIKKOL CA−2450) 1.4
シクロペンタシロキサン 11.0
(B)グリセリン 2.0
防腐剤 適量
水 残量
(C)シナノキエキス(1,3−ブチレングリコール、水) 0.1
香料 適量
合計 100.0
調製方法:A相およびB相をそれぞれ80℃に加温し均一溶解する。A相にB相を添加し、乳化する。撹拌しながら35℃まで冷却し、さらにC相を加え撹拌する。
Out bath treatment (A) Myristyl alcohol 2.6 (mass%)
Oleyl glyceryl (NIKKOL cerakil alcohol) 0.5
Behenyl alcohol (NIKKOL behenyl alcohol 65) 0.25
Sorbitan stearate (NIKKOL SS-10V) 0.25
Stealtrimonium chloride ethanol aqueous solution (NIKKOL CA-2450) 1.4
Cyclopentasiloxane 11.0
(B) Glycerin 2.0
Preservative appropriate amount Water remaining amount (C) linden extract (1,3-butylene glycol, water) 0.1
Perfume appropriate amount Total 100.0
Preparation method: Phase A and phase B are each heated to 80 ° C. and uniformly dissolved. Add Phase B to Phase A and emulsify. Cool to 35 ° C. with stirring, add phase C and stir.
アウトバストリートメント
(A)ミリスチルアルコール 2.6(質量%)
オレイルグリセリル
(NIKKOL セラキルアルコール) 0.5
ベヘニルアルコール
(NIKKOL ベヘニルアルコール 65) 0.25
ステアリン酸ソルビタン
(NIKKOL SS−10V) 0.25
ステアルトリモニウムクロリドエタノール水溶液
(NIKKOL CA−2450) 1.4
シクロペンタシロキサン 11.0
(B)グリセリン 2.0
防腐剤 適量
水 残量
(C)チンピエキス(1,3−ブチレングリコール、水) 0.5
香料 適量
合計 100.0
調製方法:A相およびB相をそれぞれ80℃に加温し均一溶解する。A相にB相を添加し、乳化する。撹拌しながら35℃まで冷却し、さらにC相を加え撹拌する。
Out bath treatment (A) Myristyl alcohol 2.6 (mass%)
Oleyl glyceryl (NIKKOL cerakil alcohol) 0.5
Behenyl alcohol (NIKKOL behenyl alcohol 65) 0.25
Sorbitan stearate (NIKKOL SS-10V) 0.25
Stealtrimonium chloride ethanol aqueous solution (NIKKOL CA-2450) 1.4
Cyclopentasiloxane 11.0
(B) Glycerin 2.0
Preservative Suitable amount Water Remaining amount (C) Chinpi extract (1,3-butylene glycol, water) 0.5
Perfume appropriate amount Total 100.0
Preparation method: Phase A and phase B are each heated to 80 ° C. and uniformly dissolved. Add Phase B to Phase A and emulsify. Cool to 35 ° C. with stirring, add phase C and stir.
ヘアミスト
1,3−ブチレングリコール 4.0(質量%)
70%ソルビトール水溶液 2.0
モモ葉エキス(エタノール、水) 1.0
pH調整剤 適量
キレート剤 適量
防腐剤 適量
水 残量
合計 100.0
調製方法:各成分を均一混合する。
Hair mist 1,3-butylene glycol 4.0 (mass%)
70% sorbitol aqueous solution 2.0
Peach leaf extract (ethanol, water) 1.0
pH adjuster appropriate amount Chelating agent appropriate amount Preservative appropriate amount Water remaining amount Total 100.0
Preparation method: Each component is uniformly mixed.
本発明品を用いることで染色毛の褪色を抑制し、染色毛の色を維持することが可能となる。 By using the product of the present invention, it is possible to suppress discoloration of the dyed hair and maintain the color of the dyed hair.
Claims (3)
Priority Applications (2)
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JP2017066559A JP6927487B2 (en) | 2017-03-30 | 2017-03-30 | Anti-fading agent for dyed hair and hair composition containing it |
JP2021087387A JP2021120416A (en) | 2017-03-30 | 2021-05-25 | Discoloration inhibitor of dyed hair, and composition for hair containing the same |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020049815A1 (en) | 2018-09-07 | 2020-03-12 | 富山住友電工株式会社 | Metal porous body, fuel cell, and production method for metal porous body |
JP7372669B2 (en) | 2019-12-11 | 2023-11-01 | 日本メナード化粧品株式会社 | oil-in-water hair cosmetics |
Citations (7)
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JP2000070956A (en) * | 1998-08-28 | 2000-03-07 | Goshu Yakuhin Kk | Removing agent containing extract of galenical with hot water for free residual chlorine in water and bathing agent containing the same |
JP2001186995A (en) * | 1999-10-21 | 2001-07-10 | Kao Corp | Shower implement |
JP2002346575A (en) * | 2001-05-28 | 2002-12-03 | Maruzen Pharmaceut Co Ltd | Residual chlorine removing agent |
JP2004250356A (en) * | 2003-02-19 | 2004-09-09 | Kanebo Ltd | Active oxygen scavenger composition for oxidation-treated hair |
JP2006289208A (en) * | 2005-04-07 | 2006-10-26 | Jipangu Project Kk | Method for removing residual chlorine and removing material therefor |
JP2007008867A (en) * | 2005-06-30 | 2007-01-18 | Lion Corp | Hair cosmetic |
JP2008024689A (en) * | 2006-07-25 | 2008-02-07 | Nippon Apricot Kk | Bathing agent |
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- 2017-03-30 JP JP2017066559A patent/JP6927487B2/en active Active
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- 2021-05-25 JP JP2021087387A patent/JP2021120416A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2000070956A (en) * | 1998-08-28 | 2000-03-07 | Goshu Yakuhin Kk | Removing agent containing extract of galenical with hot water for free residual chlorine in water and bathing agent containing the same |
JP2001186995A (en) * | 1999-10-21 | 2001-07-10 | Kao Corp | Shower implement |
JP2002346575A (en) * | 2001-05-28 | 2002-12-03 | Maruzen Pharmaceut Co Ltd | Residual chlorine removing agent |
JP2004250356A (en) * | 2003-02-19 | 2004-09-09 | Kanebo Ltd | Active oxygen scavenger composition for oxidation-treated hair |
JP2006289208A (en) * | 2005-04-07 | 2006-10-26 | Jipangu Project Kk | Method for removing residual chlorine and removing material therefor |
JP2007008867A (en) * | 2005-06-30 | 2007-01-18 | Lion Corp | Hair cosmetic |
JP2008024689A (en) * | 2006-07-25 | 2008-02-07 | Nippon Apricot Kk | Bathing agent |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2020049815A1 (en) | 2018-09-07 | 2020-03-12 | 富山住友電工株式会社 | Metal porous body, fuel cell, and production method for metal porous body |
JP7372669B2 (en) | 2019-12-11 | 2023-11-01 | 日本メナード化粧品株式会社 | oil-in-water hair cosmetics |
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JP2021120416A (en) | 2021-08-19 |
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