JP2018162224A - Water-in-oil type lip cosmetics - Google Patents
Water-in-oil type lip cosmetics Download PDFInfo
- Publication number
- JP2018162224A JP2018162224A JP2017060027A JP2017060027A JP2018162224A JP 2018162224 A JP2018162224 A JP 2018162224A JP 2017060027 A JP2017060027 A JP 2017060027A JP 2017060027 A JP2017060027 A JP 2017060027A JP 2018162224 A JP2018162224 A JP 2018162224A
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- Prior art keywords
- water
- component
- oil
- fatty acid
- silicone
- Prior art date
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- Granted
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- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- QPQANCNBWQXGTQ-UHFFFAOYSA-N trihydroxy(trimethylsilylperoxy)silane Chemical compound C[Si](C)(C)OO[Si](O)(O)O QPQANCNBWQXGTQ-UHFFFAOYSA-N 0.000 description 1
- 229940117985 trimethyl pentaphenyl trisiloxane Drugs 0.000 description 1
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は油中水型***化粧料に関し、特に唇へのフィット感、塗布膜の弾力と復元性によるツヤの持続、二次付着レス効果、経時安定性に優れた油中水型***化粧料に関するものである。 TECHNICAL FIELD The present invention relates to a water-in-oil lip cosmetic, and in particular, a water-in-oil lip cosmetic excellent in a feeling of fitting to the lips, a long lasting gloss due to elasticity and resilience of a coating film, an effect of preventing secondary adhesion, and stability over time. It is about.
近年、口紅等の***化粧料においては、使用時ののびのなめらかさやべたつきのなさ等の使用感、発色やツヤといった化粧膜の仕上がりに加え、化粧もちや***に塗布した口紅が衣服やカップに色移りしにくい二次付着レス効果も重要な品質として求められている。また、化粧もちの実感として唇へのフィット感や、塗布膜の弾力性も重視されてきた。これまでにも、良好な使用感や塗布膜のツヤに加え、二次付着レス効果を具現化する様々な検討がなされている。例えば、モノイソステアリン酸グリセリン、特定のメチルフェニルシリコーン、水又はグリセリン及びワックスとを組み合わせて二次付着レス性を有し、塗布後のつやが持続する唇用化粧料の技術（特許文献１）や、水、アルキルセルロース、Ｃ１０〜Ｃ２６モノアルコール、シリコーン油及び／又はフッ化油と界面活性剤及び／又は親水性ゲル化剤を含む水中油型エマルジョンが、べたつきのない使用感、化粧膜のツヤを有する技術（特許文献２）等があった。 In recent years, in lip cosmetics such as lipsticks, lipsticks applied to makeup and lips are applied to clothes and cups in addition to a feeling of use such as smoothness and non-stickiness when used, finishes of cosmetic films such as coloring and gloss. The secondary adhesion-less effect, which is difficult to transfer colors, is also required as an important quality. In addition, as a feeling of makeup, emphasis has been placed on the fit to the lips and the elasticity of the coating film. In the past, various studies have been made to realize a secondary adhesion-less effect in addition to a good feeling of use and gloss of the coating film. For example, lip cosmetic technology (Patent Document 1) having a secondary adhesion-less property in combination with glyceryl monoisostearate, specific methylphenyl silicone, water or glycerin and wax, and lasting gloss after application (Patent Document 1) , Water, alkylcellulose, C10-C26 monoalcohol, silicone oil and / or fluorinated oil, and an oil-in-water emulsion containing a surfactant and / or a hydrophilic gelling agent have a non-sticky feeling of use, gloss of a cosmetic film There is a technology (Patent Document 2) having
特許文献１で得られる唇用化粧料は、特定の界面活性剤とこれと相溶しない特定のメチルフェニルシリコーン油を用いることで、使用時に唇上で特定のメチルフェニルシリコーン油が表層に分離してツヤを付与し、かつ二次付着レス性を有するものであるが、塗布直後はメチルフェニルシリコーン由来の液ツヤがあるものの、得られた塗布膜は弾力や復元性に劣るため、満足のいくツヤの持続性が得られない場合があった。また、べたつきがなく、さらさらと伸び広がる特性を持つシリコーン油を多く用いているため、満足のいくフィット感が得られない場合があった。特許文献２の技術は、皮膜形成剤としてのエチルセルロースのべたつきを抑えるために、水中の分散液の形態で用いるものであるが、界面活性剤及び／又は親水性ゲル化剤を含む水中油型エマルジョンのため、唇を保護するエモリエント感や耐水性などの化粧持ちに劣り、二次付着レス効果も不十分であった。化粧持ちをさらに向上させるために、特許文献２の技術を外層が油系成分である油中水型化粧料に応用すると安定性が悪くなる傾向があった。 The lip cosmetic obtained in Patent Document 1 uses a specific surfactant and a specific methylphenyl silicone oil that is incompatible with this, so that the specific methylphenyl silicone oil separates into the surface layer on the lips during use. Although it is glossy and has secondary adhesion-less properties, although there is a liquid gloss derived from methylphenyl silicone immediately after coating, the obtained coating film is inferior in elasticity and resilience, so it is satisfactory In some cases, gloss persistence could not be obtained. In addition, since a lot of silicone oil that has no stickiness and spreads smoothly, a satisfactory fit may not be obtained. The technique of Patent Document 2 is used in the form of a dispersion in water in order to suppress the stickiness of ethyl cellulose as a film forming agent, but it is an oil-in-water emulsion containing a surfactant and / or a hydrophilic gelling agent. For this reason, it has inferior makeup with a sense of emollient and water resistance that protects the lips, and the secondary adhesion-less effect is also insufficient. In order to further improve the makeup life, when the technique of Patent Document 2 is applied to a water-in-oil cosmetic whose outer layer is an oil-based component, the stability tends to deteriorate.
そのため、二次付着レス効果を有し、高い化粧もち実感としての唇へのフィット感、塗布膜の弾力と復元性によるツヤの持続があり、かつ経時安定性に優れた***化粧料を提供することが課題であった。 Therefore, it provides a lip cosmetic that has a secondary adhesion-less effect, a lip fit as a feeling of high makeup, a long lasting luster due to the elasticity and restorability of the coating film, and excellent in stability over time. That was a challenge.
上記実情を鑑み、本発明者らは、エチルセルロースと特定の油剤が柔軟性と弾力性に富む油性ゲルを形成することに着目し、鋭意検討した結果、エチルセルロースに総炭素数１６〜２４の１価の液状アルコール、デキストリン脂肪酸エステル、特定の粘度を有するシリコーン油剤およびシリカを組み合わせた油中水型***化粧料において、エチルセルロースと炭素数１６〜２４の１価の液状アルコールが油中水型剤型において弾力と復元性に優れる化粧膜を形成し、その表層を高粘度液状油剤が覆うことにより、二次付着レス効果を発揮し、かつデキストリン脂肪酸エステル及びシリカによって経時安定性に優れる化粧料が得られることを見出し、本発明を完成させた。 In view of the above situation, the present inventors have focused on forming ethyl oil and a specific oil agent to form an oily gel rich in flexibility and elasticity. As a result of intensive studies, ethyl cellulose has a monovalent valence of 16 to 24 carbon atoms. In a water-in-oil lip cosmetic combining a liquid alcohol, a dextrin fatty acid ester, a silicone oil having a specific viscosity and silica, ethyl cellulose and a monovalent liquid alcohol having 16 to 24 carbon atoms are used in the water-in-oil dosage form. A cosmetic film with excellent elasticity and resilience is formed, and the surface layer is covered with a high-viscosity liquid oil agent, thereby exhibiting a secondary adhesion-less effect, and a dextrin fatty acid ester and silica can provide a cosmetic with excellent temporal stability. As a result, the present invention has been completed.
すなわち、本発明は、次の成分（ａ）〜（ｆ）；
（ａ）エチルセルロース
（ｂ）総炭素数１６〜２４の１価の液状アルコール
（ｃ）デキストリン脂肪酸エステル
（ｄ）２５℃での粘度が１００〜１００万ｍＰａ・ｓである、ジメチルポリシロキサン、フェニル変性シリコーン、フッ素変性シリコーンから選ばれる１種または２種以上の油剤
（ｅ）水
（ｆ）シリカ
を含有する油中水型***化粧料に関するものである。
That is, the present invention provides the following components (a) to (f);
(A) ethyl cellulose (b) monovalent liquid alcohol having a total carbon number of 16 to 24 (c) dextrin fatty acid ester (d) dimethylpolysiloxane having a viscosity at 25 ° C. of 1 to 1,000,000 mPa · s, phenyl-modified The present invention relates to a water-in-oil lip cosmetic containing one or more kinds of oils selected from silicone and fluorine-modified silicone (e) water (f) silica.
前記成分（ａ）の含有量が、１〜１５質量％、前記成分（ｂ）の含有量が、３〜６０質量％である前記記載の油中水型***化粧料に関するものである。 The content of the component (a) is 1 to 15% by mass, and the content of the component (b) is 3 to 60% by mass.
前記成分（ａ）と（ｂ）を含有質量比が、（ａ）：（ｂ）＝１：２〜１：１０である前記記載の油中水型***化粧料に関するものである。 The present invention relates to the water-in-oil lip cosmetic described above, wherein the mass ratio of the components (a) and (b) is (a) :( b) = 1: 2 to 1:10.
本発明は、唇へのフィット感、塗布膜の弾力と復元性によるツヤの持続、二次付着レス効果、経時安定性に優れた油中水型***化粧料を提供するものである。 The present invention provides a water-in-oil lip cosmetic with excellent fit to the lips, long-lasting gloss due to the elasticity and resilience of the coating film, secondary adhesion-less effect, and stability over time.
以下、本発明を詳細に説明する。なお、本明細書において、「〜」はその前後の数値を含む範囲を意味するものとする。 Hereinafter, the present invention will be described in detail. In the present specification, “to” means a range including numerical values before and after.
本発明における成分（ａ）エチルセルロースは、β−グルコースが縮合重合したセルロースのグルコース単位のヒドロキシル基の一部又は全部をエチルエーテルに置換したものである。エチルセルロースは、重合度、エチルエーテル置換度等により、性状が異なるが、性状の異なる２種以上を組合せて用いてもよい。 The component (a) ethyl cellulose in the present invention is obtained by substituting part or all of the hydroxyl groups of glucose units of cellulose obtained by condensation polymerization of β-glucose with ethyl ether. Ethyl cellulose has different properties depending on the degree of polymerization, the degree of ethyl ether substitution, etc., but two or more types having different properties may be used in combination.
本発明における成分（ａ）のエチルエーテル置換度は、特に限定されないが、均一な膜が得られやすい等の観点から、グルコース単位のエチルエーテル置換度が２以上のものが好ましく、２〜３であるものが特に好ましい。 The degree of ethyl ether substitution of component (a) in the present invention is not particularly limited, but from the standpoint that a uniform film is easily obtained, the degree of substitution of ethyl ether in the glucose unit is preferably 2 or more, and 2 to 3 Some are particularly preferred.
本発明における成分（ａ）の量平均分子量は、特に限定されないが、成分（ｂ）への溶解性と塗布膜のフィット性とツヤの観点から、５０，０００〜３００，０００であることが好ましく、１００，０００〜２５０，０００であることがより好ましい。 The amount average molecular weight of the component (a) in the present invention is not particularly limited, but is preferably 50,000 to 300,000 from the viewpoint of solubility in the component (b), fit of the coating film and gloss. More preferably, it is 100,000-250,000.
成分（ａ）の市販品としては、エチルエーテルの平均置換度が２．４６〜２．５８のＡＱＵＡＬＯＮ ＥＣ−Ｎ１４、ＡＱＵＡＬＯＮ ＥＣ−Ｎ２２、ＡＱＵＡＬＯＮ ＥＣ−Ｎ５０、ＡＱＵＡＬＯＮ ＥＣ−Ｎ１００（以上、ＡＳＨＬＡＮＤ ＳＰＥＣＩＡＬＴＹ ＩＮＧＲＥＤＩＥＮＴＳ社製）等が挙げられる。 Commercially available components (a) include AQUALON EC-N14, AQUALON EC-N22, AQUALON EC-N50, AQUALON EC-N100 (above, ASHLAND SPECIALTY INGREDIENTS) having an average degree of substitution of ethyl ether of 2.46 to 2.58. Etc.).
本発明における成分（ａ）の含有量は、特に限定されないが、唇へのフィット感、塗布膜の弾力と復元性によるツヤの持続、二次付着レス効果がより優れる等の観点から、１〜１５質量％（以下、％と表す）が好ましく、更に好ましくは２〜１０％である。 The content of the component (a) in the present invention is not particularly limited, but from the viewpoints such as a feeling of fitting to the lips, gloss persistence due to the elasticity and resilience of the coating film, and the secondary adhesion-less effect is more excellent. 15 mass% (hereinafter referred to as%) is preferable, and more preferably 2 to 10%.
本発明における成分（ｂ）は総炭素数１６〜２４の１価のアルコールであり、化粧料に用いられるものであれば、特に限定されずに用いることができる。性状は特に限定されないが、２５℃で液状のものであることがより好ましい。総炭素数１６未満であると、***への刺激性がみられることがあり、好ましくない。総炭素数２５以上であると、成分（ａ）との相溶性が悪いため好ましくない。成分（ａ）を成分（ｂ）に溶解して調製された油性ゲルは、唇へのフィット感に優れ、ゲルの弾力と復元性に優れるため塗布膜の均一性が高まり、かつ均一な塗布膜が持続するためツヤの持続に優れる。具体的には、ヘキシルデカノール、イソステアリルアルコール、オレイルアルコール、オクチルドデカノール、デシルテトラデカノール等があげられ、１種又は２種以上を用いることができる。市販品としては、イソステアリルアルコールＥＸ、リソノール１６ＳＰ、リソノール１８ＳＰ、リソノール２０ＳＰ、リソノール２４ＳＰ（以上、高級アルコール工業社製）ＥＵＴＡＮＯＬ Ｇ−ＪＰ（ＢＡＳＦ社製）、ＮＯＦＡＢＬＥ ＡＯ−８５Ｓ（日油社製）、リカコール９０Ｂ（新日本理化社製）等が挙げられ、１種又は２種以上を用いることができる。本発明において成分（ｂ）は、成分（ａ）を均一に溶解することができる点等において、オクチルドデカノール、デシルテトラデカノールであることが特に好ましい。 The component (b) in the present invention is a monohydric alcohol having a total carbon number of 16 to 24 and can be used without particular limitation as long as it is used in cosmetics. The properties are not particularly limited, but are more preferably liquid at 25 ° C. When the total number of carbon atoms is less than 16, irritation to the lips may be observed, which is not preferable. A total carbon number of 25 or more is not preferable because of poor compatibility with the component (a). The oily gel prepared by dissolving the component (a) in the component (b) has a good fit to the lips and is excellent in elasticity and resilience of the gel. Because it lasts, it has excellent gloss. Specific examples include hexyl decanol, isostearyl alcohol, oleyl alcohol, octyldodecanol, decyltetradecanol and the like, and one or more can be used. Commercially available products include isostearyl alcohol EX, lithonol 16SP, lithonol 18SP, lithonol 20SP, lithonol 24SP (above, manufactured by Higher Alcohol Industry) EUTANOL G-JP (manufactured by BASF), NOFABLE AO-85S (manufactured by NOF Corporation) And Rica Coal 90B (manufactured by Shin Nippon Rika Co., Ltd.) and the like, and one or more can be used. In the present invention, the component (b) is particularly preferably octyldodecanol or decyltetradecanol in that the component (a) can be uniformly dissolved.
本発明における成分（ｂ）の含有量は、特に限定されないが、唇へのフィット感、塗布膜の弾力と復元性によるツヤの持続、経時安定性等がより優れる等の観点から、３〜６０％が好ましく、４〜５０％であるとより好ましい。 The content of the component (b) in the present invention is not particularly limited, but it is 3 to 60 from the viewpoints such as a feeling of fitting to the lips, gloss persistence due to elasticity and resilience of the coating film, and stability over time. % Is preferable, and 4 to 50% is more preferable.
本発明の油中水型***化粧料における、成分（ａ）と（ｂ）の含有質量比は、特に限定されないが、塗布膜の弾力と復元性によるツヤの持続、経時安定性により優れる等の観点から、（ａ）：（ｂ）＝１：２〜１：１０であることが好ましく、１：４〜１：１０であるとより好ましい。 The mass ratio of the components (a) and (b) in the water-in-oil lip cosmetic of the present invention is not particularly limited, but it is more excellent in continuity of gloss due to elasticity and resilience of the coating film, stability over time, etc. From the viewpoint, (a) :( b) = 1: 2 to 1:10 is preferable, and 1: 4 to 1:10 is more preferable.
本発明で用いられる成分（ｃ）のデキストリン脂肪酸エステルは、デキストリンと脂肪酸とのエステル化物である。化粧料に用いられるものであれば、特に限定されず、デキストリンの糖鎖は直鎖状、分岐鎖状、環状のいずれでもよく、脂肪酸も直鎖状、分岐鎖状のいずれでも良い。 The dextrin fatty acid ester of component (c) used in the present invention is an esterified product of dextrin and fatty acid. The sugar chain of dextrin may be linear, branched or cyclic, and the fatty acid may be either linear or branched, as long as it is used in cosmetics.
成分（ｃ）のデキストリン脂肪酸エステルに用いられるデキストリンのグルコース平均重合度は、特に限定されないが、油剤への溶解性に優れる等の観点から、３〜１５０であることが好ましく、１０〜１００であることがより好ましい。 The glucose average polymerization degree of dextrin used for the dextrin fatty acid ester of component (c) is not particularly limited, but is preferably 3 to 150, and preferably 10 to 100, from the viewpoint of excellent solubility in an oil agent. It is more preferable.
成分（ｃ）のデキストリン脂肪酸エステルに用いられる脂肪酸は、炭素数４〜２６の直鎖および／または分岐飽和脂肪酸の１種又は２種以上を必須とし、さらに炭素数２〜２２の直鎖飽和脂肪酸、炭素数６〜３０の直鎖又は分岐の不飽和脂肪酸、及び炭素数６〜３０の環状の飽和又は不飽和脂肪酸よりなる群から選ばれる１種又は２種以上（以下、これら炭素数４〜２６の分岐飽和脂肪酸以外の脂肪酸をまとめて表すときは「その他の脂肪酸」という）を含有してもよいものである。 The fatty acid used in the dextrin fatty acid ester of component (c) must be one or more of linear and / or branched saturated fatty acids having 4 to 26 carbon atoms, and further linear saturated fatty acids having 2 to 22 carbon atoms. 1 type, or 2 or more types selected from the group consisting of a C6-C30 linear or branched unsaturated fatty acid and a C6-C30 cyclic saturated or unsaturated fatty acid (hereinafter these C4-C When the fatty acids other than the 26 branched saturated fatty acids are collectively expressed, they may be referred to as “other fatty acids”).
成分（ｃ）のデキストリンへの脂肪酸の置換度は、特に限定されないが、着色や特異なにおいが生じにくいなどの観点から、グルコース単位当たり１．０〜３．０が好ましく、１．２〜２．８がさらに好ましい。 The degree of substitution of the fatty acid with the dextrin of component (c) is not particularly limited, but is preferably 1.0 to 3.0 per glucose unit from the viewpoint of being less likely to cause coloring or a specific odor, and 1.2 to 2 .8 is more preferred.
成分（ｃ）の市販品としては、レオパールＴＬ２、レオパールＴＴ２、レオーパールＷＸ、レオパールＫＬ２、レオパールＭＫＬ２（以上、千葉製粉社製）等が挙げられ、これらを１種又は２種以上用いることができる。 Examples of commercially available components (c) include Leo Pearl TL2, Leo Pearl TT2, Leo Pearl WX, Leo Pearl KL2, Leo Pearl MKL2 (manufactured by Chiba Flour Mills Co., Ltd.), and the like. One or more of these can be used.
本発明における成分（ｃ）の含有量は、特に限定されないが、唇へのフィット感、二次付着レス効果、経時安定性に優れる等の観点から、０．１〜５．０％が好ましく、０．５〜３．０％より好ましい。 The content of the component (c) in the present invention is not particularly limited, but is preferably 0.1 to 5.0% from the viewpoints of fit to the lips, secondary adhesion-less effect, excellent temporal stability, 0.5 to 3.0% is more preferable.
本発明における成分（ｄ）の２５℃での粘度が１００〜１００万ｍＰａ・ｓである、ジメチルポリシロキサン、フェニル変性シリコーン、フッ素変性シリコーンは、化粧料に用いられるものであれば、特に限定されずに用いることができ、１種または２種以上を用いても良い。ジメチルポリシロキサンは、ジメチルシロキンサンの重合物であり、粘度が１００ｍＰａ・ｓ以上のものである。フェニル変性シリコーンは、ポリシロキサンの一部にフェニル基を有するものである。具体的には、フェニルメチコン、フェニルジメチコン、フェニルトリメチコン、ジフェニルジメチコン、ジフェニルシロキシフェニルトリメチコン、トリメチルペンタフェニルトリシロキサン等が挙げられる。市販品としてはＫＦ−５０−１００ｃｓ／１０００ｃｓ、ＫＦ−５３、ＫＦ−５４、ＫＦ−５４ＨＶ、（以上、信越化学工業社製）、ＰＨ−１５５５ ＨＲＩ Ｃｏｓｍｅｔｉｃ Ｆｌｕｉｄ、ＦＺ−３１５６（以上東レ・ダウコ−ニング社製）、ＰＤＭ１００、ＰＤＭ１０００（以上、旭化成ワッカーシリコーン社製）等が挙げられ、これらの１種又は２種以上を用いることができる。フッ素変性シリコーンは、有機基として分子中に少なくとも一つ以上のフルオロアルキル基を有するオルガノポリシロキサンである。フルオロアルキル基として具体的には、トリフルオロプロピル基、ノナフルオロヘキシル基、ヘプタデシルフルオロデシル基等のフッ素置換アルキル基が挙げられ、特にトリフルオロプロピル基が好ましい。フルオロアルキル基含有オルガノポリシロキサンは、直鎖状、分岐状、環状のいずれであっても良い。具体的には、直鎖状のものとして、ＦＬ−１００、Ｘ−２２−８１９、Ｘ−２２−８２０、Ｘ−２２−８２１、Ｘ−２２−８２２（信越化学工業社製）、ＣＦＦ−３４００、ＣＦＦ−３４０１、ＣＦＦ−３４０２（ＮＵＳＩＬ社製）、ＦＳ−１２６５（東レ・ダウコーニング社製）等、環状のものとしては、ＫＦ−５００２（信越化学工業社製）等が挙げられ、これらの１種又は２種以上を用いることができる。 The dimethylpolysiloxane, phenyl-modified silicone, and fluorine-modified silicone having a viscosity at 25 ° C. of the component (d) in the present invention of 100 to 1,000,000 mPa · s are particularly limited as long as they are used in cosmetics. 1 type or 2 types or more may be used. Dimethyl polysiloxane is a polymer of dimethyl siloxane and has a viscosity of 100 mPa · s or more. The phenyl-modified silicone has a phenyl group as a part of polysiloxane. Specific examples include phenylmethicone, phenyldimethicone, phenyltrimethicone, diphenyldimethicone, diphenylsiloxyphenyltrimethicone, trimethylpentaphenyltrisiloxane and the like. Commercially available products include KF-50-100cs / 1000cs, KF-53, KF-54, KF-54HV (above, manufactured by Shin-Etsu Chemical Co., Ltd.), PH-1555 HRI Cosmetic Fluid, FZ-3156 (above Toray Dowco- Ning Co., Ltd.), PDM100, PDM1000 (above, manufactured by Asahi Kasei Wacker Silicone Co., Ltd.) and the like, and one or more of these can be used. The fluorine-modified silicone is an organopolysiloxane having at least one fluoroalkyl group in the molecule as an organic group. Specific examples of the fluoroalkyl group include fluorine-substituted alkyl groups such as a trifluoropropyl group, a nonafluorohexyl group, and a heptadecylfluorodecyl group, with a trifluoropropyl group being particularly preferred. The fluoroalkyl group-containing organopolysiloxane may be linear, branched or cyclic. Specifically, as a linear thing, FL-100, X-22-819, X-22-820, X-22-821, X-22-822 (made by Shin-Etsu Chemical Co., Ltd.), CFF-3400 , CFF-3401, CFF-3402 (manufactured by NUSIL), FS-1265 (manufactured by Toray Dow Corning), and the like, KF-5002 (manufactured by Shin-Etsu Chemical Co., Ltd.) and the like can be mentioned. 1 type (s) or 2 or more types can be used.
本発明における成分（ｄ）の２５℃での粘度は、特に限定されないが、塗布膜の弾力と復元性によるツヤの持続、二次付着レス効果、経時安定性に優れる等の観点から、１００〜１００万ｍＰａ・ｓであることが好ましく、５００〜１０万ｍＰａ・ｓであることがより好ましい。なお、本発明における粘度は、ＡＳＴＭ Ｄ ４４５−４６Ｔによるウッペローデ粘度計にて２５℃で測定して求めた。 The viscosity at 25 ° C. of the component (d) in the present invention is not particularly limited, but it is 100 to 100% from the viewpoint of excellent glossiness due to elasticity and resilience of the coating film, secondary adhesion-less effect, excellent stability over time, and the like. It is preferably 1 million mPa · s, and more preferably 500 to 100,000 mPa · s. In addition, the viscosity in this invention was calculated | required by measuring at 25 degreeC with the Upperode viscometer by ASTMD445-46T.
本発明における成分（ｄ）の含有量は、特に限定されないが、二次付着レス効果、経時安定性等により優れる等の観点から、５〜５０％が好ましく、更に好ましくは１０〜３０％である。 The content of the component (d) in the present invention is not particularly limited, but is preferably 5 to 50%, more preferably 10 to 30%, from the viewpoint of excellent secondary adhesion-less effect, temporal stability, and the like. .
本発明における成分（ｅ）の水は、特に限定されないが、常水、精製水、温泉水、深層水、ラベンダー水、ローズ水、オレンジフラワー水等が挙げられ、１種又は２種以上を用いることができる。 Although the water of the component (e) in this invention is not specifically limited, Normal water, purified water, hot spring water, deep water, lavender water, rose water, orange flower water etc. are mentioned, 1 type (s) or 2 or more types are used. be able to.
本発明における成分（ｅ）の水の含有量としては、特に限定されないが、唇へのフィット感、二次付着レス効果、経時安定性により優れる等の観点から、３〜４０％が好ましく、更に好ましくは５〜２０％である。 The water content of the component (e) in the present invention is not particularly limited, but is preferably 3 to 40% from the viewpoints of fit to the lips, secondary adhesion-less effect, superior stability over time, and the like. Preferably it is 5 to 20%.
本発明における成分（ｆ）のシリカは、化粧料に用いられるものであれば、粒子形状（球状、針状、板状、不定形等）、粒子径（煙霧状、微粒子、顔料級等）、粒子構造（多孔質、無孔質等）等を問わず、何れのものも使用することができる。具体的には、例えば四塩化ケイ素を水素と酸素炎中で加水分解して得られるものが挙げられる。粒子経に関しては、特に限定されないが使用感や経時安定性の観点から、シリカの一次粒子径は５０ｎｍ以下が好ましく、２０ｎｍ以下が特に好ましい。一次粒子径は、電子顕微鏡写真により測定した３０００〜５０００個の粒子の平均の値で求めることができる。また、成分（ｆ）は疎水化処理したものであってもよい。疎水化処理としてはジメチルジクロロシラン処理、トリメチルシリルクロライドやヘキサメチルジシラザンによるトリメチルシロキシ処理、オクチルシラン化処理、ジメチルシリコーンオイル処理、パーフルオロオクチルトリエトキシシラン処理、メチルハイドロジェンポリシロキサンを用いたコーティング焼付け処理、金属石鹸によるコーティング等、また、これらの疎水化処理を２種またはそれ以上組み合わせた処理等が挙げられる。 If the silica of the component (f) in the present invention is used in cosmetics, the particle shape (spherical, needle-like, plate-like, amorphous, etc.), particle size (smoke, fine particles, pigment grade, etc.), Regardless of the particle structure (porous, nonporous, etc.) etc., any one can be used. Specific examples include those obtained by hydrolyzing silicon tetrachloride in hydrogen and an oxygen flame. The particle diameter is not particularly limited, but from the viewpoint of usability and stability over time, the primary particle diameter of silica is preferably 50 nm or less, and particularly preferably 20 nm or less. A primary particle diameter can be calculated | required by the average value of 3000-5000 particle | grains measured with the electron micrograph. Component (f) may be hydrophobized. Hydrophobic treatment includes dimethyldichlorosilane treatment, trimethylsiloxy treatment with trimethylsilyl chloride and hexamethyldisilazane, octylsilanization treatment, dimethylsilicone oil treatment, perfluorooctyltriethoxysilane treatment, coating baking using methylhydrogenpolysiloxane Examples thereof include a treatment, a coating with a metal soap, and a treatment in which two or more of these hydrophobic treatments are combined.
成分（ｆ）の市販品としては、ＡＥＲＯＳＩＬ５０、ＡＥＲＯＳＩＬ１３０、ＡＥＲＯＳＩＬ２００、ＡＥＲＯＳＩＬ２００Ｖ、ＡＥＲＯＳＩＬ２００ＣＦ、ＡＥＲＯＳＩＬ２００ＦＡＤ、ＡＥＲＯＳＩＬ３００、ＡＥＲＯＳＩＬ３００ＣＦ、ＡＥＲＯＳＩＬ３８０、ＡＥＲＯＳＩＬ３８０Ｓ（以上、日本アエロジル社製）等、疎水化処理したものとしては、ＡＥＲＯＳＩＬ Ｒ９７２、ＡＥＲＯＳＩＬ Ｒ９７２Ｖ、ＡＥＲＯＳＩＬ Ｒ９７２ＣＦ、ＡＥＲＯＳＩＬ Ｒ９７４、ＡＥＲＯＳＩＬ Ｒ９７６Ｓ、ＡＥＲＯＳＩＬ ＲＸ２００、ＡＥＲＯＳＩＬ ＲＸ３００、ＡＥＲＯＳＩＬ ＲＹ２００、ＡＥＲＯＳＩＬ Ｒ２０２、ＡＥＲＯＳＩＬ Ｒ８０５、ＡＥＲＯＳＩＬ Ｒ８１２、ＡＥＲＯＳＩＬ ＲＡ２００Ｈ（以上、日本アエロジル社製）、ＣＡＢ−Ｏ−ＳＩＬ ＴＳ５３０（キャボット社製）等が挙げられる。 As a commercially available component (f), AEROSIL50, AEROSIL130, AEROSIL200, AEROSIL200V, AEROSIL200CF, AEROSIL200FAD, AEROSIL300, AEROSIL300CF, AEROSIL380S (above, manufactured by Nippon Aerosil Co., Ltd.), etc. AEROSIL R972V, AEROSIL R972CF, AEROSIL R974, AEROSIL R976S, AEROSIL RX200, AEROSIL RX300, AEROSIL RY200, AEROSIL R202, AEROSIL R805, AEROSIL R812, AEROSIL RA200H (manufactured by Nippon Aero C) B-O-SIL TS530 (manufactured by Cabot Corporation), and the like.
本発明における成分（ｆ）の含有量は、特に限定されないが、唇へのフィット感と経時安定性により優れる等の観点から、０．５〜１０％であることが好ましく、更に好ましくは１〜５％である。 The content of the component (f) in the present invention is not particularly limited, but is preferably 0.5 to 10%, more preferably 1 to 10% from the viewpoint of superior fit to the lips and stability over time. 5%.
本発明の油中水型***化粧料は、本発明の効果を妨げない範囲であれば、上記成分（ａ）〜（ｆ）の他に、通常化粧料に含有される成分として、油性成分、アルコール類、水溶性高分子、保湿剤等の水性成分、粉体、界面活性剤、美容成分、紫外線吸収剤、酸化防止剤、防腐剤、香料等を含有することができる。 As long as the water-in-oil lip cosmetic of the present invention is within a range that does not impede the effects of the present invention, in addition to the above components (a) to (f), an oily component, It may contain aqueous components such as alcohols, water-soluble polymers, humectants, powders, surfactants, cosmetic ingredients, ultraviolet absorbers, antioxidants, preservatives, fragrances and the like.
油性成分としては、通常化粧料に用いられるものであれば特に限定されず、動物油、植物油、合成油等の起源、固形油、半固形油、液体油、揮発性油等の性状を問わず、炭化水素類、油脂類、ロウ類、硬化油類、エステル油類、脂肪酸類、高級アルコール類、成分（ｄ）以外のシリコーン油類、フッ素系油類、ラノリン誘導体類、油性ゲル化剤類等が挙げられる。具体的には、ワセリン、ポリエチレンワックス、エチレン・プロピレンコポリマー、パラフィンワックス、フィッシャートロプシュワックス、オゾケライトワックス等の非液状の炭化水素類、モクロウ、オリーブ油、ヒマシ油、ミンク油、マカデミアンナッツ油等の油脂類、ミツロウ、ゲイロウ、カルナウバワックス、キャンデリラワックス等のロウ類、ロジン酸ペンタエリトリットエステル、コレステロール脂肪酸エステル、フィトステロール脂肪酸エステル等の非液状のエステル類、ステアリン酸、ラウリン酸、ミリスチン酸、ベヘニン酸、イソステアリン酸、オレイン酸等の脂肪酸類、トリメチルシロキシケイ酸、アルキル変性ポリシロキサン、ポリオキシアルキレン変性オルガノポリシロキサン、架橋型ポリエーテル変性メチルポリシロキサン、フッ素変性ポリシロキサン等のシリコーン類、パーフルオロデカン、パーフルオロオクタン、パーフルオロポリエーテル等のフッ素系油剤類、ラノリン、酢酸ラノリン、ラノリン脂肪酸イソプロピル、ラノリンアルコール類のラノリン誘導体、ショ糖脂肪酸エステル、イソステアリン酸アルミニウム、ステアリン酸カルシウム、１２−ヒドロキシステアリン酸等の油性ゲル化剤類等が挙げられ、これらを１種または２種以上用いることができる。 The oil component is not particularly limited as long as it is usually used in cosmetics, regardless of the nature of animal oil, vegetable oil, synthetic oil, etc., solid oil, semi-solid oil, liquid oil, volatile oil, etc. Hydrocarbons, fats and oils, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils other than component (d), fluorinated oils, lanolin derivatives, oily gelling agents, etc. Is mentioned. Specifically, petroleum jelly, polyethylene wax, ethylene / propylene copolymer, paraffin wax, Fischer-Tropsch wax, ozokerite wax and other non-liquid hydrocarbons, owl, olive oil, castor oil, mink oil, macadamian nut oil, etc. Oils, beeswax, gaywax, carnauba wax, candelilla wax and other waxes, rosin acid pentaerythritol ester, cholesterol fatty acid ester, phytosterol fatty acid ester and other non-liquid esters, stearic acid, lauric acid, myristic acid , Fatty acids such as behenic acid, isostearic acid, oleic acid, trimethylsiloxysilicic acid, alkyl-modified polysiloxane, polyoxyalkylene-modified organopolysiloxane, cross-linked polyether-modified methylpoly Loxane, silicones such as fluorine-modified polysiloxane, fluorine oils such as perfluorodecane, perfluorooctane, perfluoropolyether, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives of lanolin alcohols, sucrose fatty acid ester , Oily gelling agents such as aluminum isostearate, calcium stearate, 12-hydroxystearic acid and the like, and one or more of them can be used.
水性成分としては、水に可溶な通常化粧料に用いられるものであれば特に限定されず、エチルアルコール等のアルコール類、プロピレングリコール、１，３−ブチレングリコール、ジプロピレングリコール、ポリエチレングリコール等のグリコール類、グリセリン、ジグリセリン、ポリグリセリン等のグリセロール類、デキストリン、グルコース、ソルビトール、キシリトール、トレハロース、オリゴ糖、セルロース等の糖類が挙げられる。水溶性高分子としては、グアーガム、コンドロイチン硫酸ナトリウム、ヒアルロン酸ナトリウム、アラビアガム、アルギン酸ナトリウム、カラギーナン等の天然系のもの、メチルセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース等の半合成系のもの、カルボキシビニルポリマー、アルキル付加カルボキシビニルポリマー、ポリビニルアルコール、ポリビニルピロリドン、ポリアクリル酸ナトリウム等の合成系のもの、他にタンパク質、ムコ多糖類、コラーゲン、エラスチン、ケラチン等が挙げられ、これらを１種または２種以上用いることができる。 The aqueous component is not particularly limited as long as it is used for normal cosmetics soluble in water, and alcohols such as ethyl alcohol, propylene glycol, 1,3-butylene glycol, dipropylene glycol, polyethylene glycol, etc. Glycerols such as glycols, glycerin, diglycerin and polyglycerin, and saccharides such as dextrin, glucose, sorbitol, xylitol, trehalose, oligosaccharides and cellulose. Examples of water-soluble polymers include guar gum, sodium chondroitin sulfate, sodium hyaluronate, gum arabic, sodium alginate, carrageenan, and other semi-synthetic materials such as methyl cellulose, hydroxyethyl cellulose, carboxymethyl cellulose, carboxyvinyl polymer, Synthetic compounds such as alkyl-added carboxyvinyl polymer, polyvinyl alcohol, polyvinyl pyrrolidone, sodium polyacrylate, and other proteins, mucopolysaccharides, collagen, elastin, keratin, etc. are used, and one or more of these are used. be able to.
粉体としては、通常化粧料に用いられるものであれば特に限定されず、例えば、酸化チタン、黒色酸化チタン、コンジョウ、群青、ベンガラ、黄酸化鉄、黒酸化鉄、酸化亜鉛、酸化アルミニウム、無水ケイ酸、酸化マグネシウム、酸化ジルコニウム、炭酸マグネシウム、炭酸カルシウム、酸化クロム、水酸化クロム、カーボンブラック、ケイ酸アルミニウム、ケイ酸マグネシウム、ケイ酸アルミニウムマグネシウム、雲母、合成金雲母、セリサイト、タルク、カオリン、炭化珪素、硫酸バリウム、窒化ホウ素、オキシ塩化ビスマス等の無機粉体類や、ナイロン、ポリメチルメタクリレート、ポリアクリル酸アルキル、オルガノポリシロキサンエラストマー、ポリメチルセスキオキサン、架橋型シリコーン・網状シリコーンブロック共重合体、ポリスチレン、アクリロニトリル−メタクリル酸共重合体、塩化ビニリデン−メタクリル酸共重合体、ポリエチレン、ウレタン、ウール、シルク、結晶セルロース、Ｎ−アシルリジン等の有機粉体類や、有機タール系顔料、有機色素等のレーキ顔料等の色素粉体類や、微粒子酸化チタン被覆雲母チタン、微粒子酸化亜鉛被覆雲母チタン、硫酸バリウム被覆雲母チタン、酸化チタン含有無水ケイ酸、酸化亜鉛含有無水ケイ酸、酸化チタン被覆ガラス末、酸化チタン被覆合成金雲母、雲母チタン、酸化鉄被覆雲母チタン、紺青被覆雲母チタン、カルミン被覆雲母チタン等の複合粉体類や、ポリエチレンテレフタレート・アルミニウム・エポキシ積層末、ポリエチレンテレフタレート・ポリメチルメタクリレート積層末などの積層フィルム末類等が挙げられる。また、これらの粉体をフッ素系化合物、シリコーン系化合物、金属石鹸、レシチン、水素添加レシチン、コラーゲン、アミノ酸、炭化水素、高級脂肪酸、高級アルコール、エステル、ワックス、ロウ、界面活性剤等の１種または２種以上を用いて表面処理を施してあってもよい。 The powder is not particularly limited as long as it is usually used in cosmetics. For example, titanium oxide, black titanium oxide, conch, ultramarine, bengara, yellow iron oxide, black iron oxide, zinc oxide, aluminum oxide, anhydrous Silicic acid, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, chromium oxide, chromium hydroxide, carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic phlogopite, sericite, talc, kaolin , Inorganic powders such as silicon carbide, barium sulfate, boron nitride, bismuth oxychloride, nylon, polymethyl methacrylate, polyalkyl acrylate, organopolysiloxane elastomer, polymethyl sesquioxane, cross-linked silicone / reticulated silicone block Copolymer, Organic powders such as styrene, acrylonitrile-methacrylic acid copolymer, vinylidene chloride-methacrylic acid copolymer, polyethylene, urethane, wool, silk, crystalline cellulose, N-acyl lysine, organic tar pigments, organic dyes, etc. Dye powders such as lake pigments, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated mica titanium, barium sulfate coated mica titanium, titanium oxide-containing silicic acid, zinc oxide-containing silicic acid, titanium oxide-coated glass powder, Composite powders such as titanium oxide coated synthetic phlogopite, mica titanium, iron oxide coated mica titanium, bitumen coated mica titanium, carmine coated mica titanium, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polymethyl methacrylate laminated powder Laminated film powders such as It is below. In addition, these powders can be used as a fluorine compound, silicone compound, metal soap, lecithin, hydrogenated lecithin, collagen, amino acid, hydrocarbon, higher fatty acid, higher alcohol, ester, wax, wax, surfactant, etc. Or you may surface-treat using 2 or more types.
活性剤としては、通常化粧料に用いられるものであれば特に限定されず、非イオン性界面活性剤、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤等が挙げられる。例えば、グリセリン脂肪酸エステルおよびそのアルキレングリコール付加物、ポリグリセリン脂肪酸エステルおよびそのアルキレングリコール付加物、ショ糖脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、レシチン等を挙げることができ、これらを１種または２種以上用いることができる。 The active agent is not particularly limited as long as it is usually used in cosmetics, and examples thereof include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants. Examples include glycerin fatty acid esters and alkylene glycol adducts thereof, polyglycerin fatty acid esters and alkylene glycol adducts thereof, sucrose fatty acid esters, polyoxyethylene hydrogenated castor oil, lecithin, and the like. The above can be used.
酸化防止剤としては、例えば、α−トコフェロール、アスコルビン酸、ジブチルヒドロキシトルエン等、美容成分としては例えばビタミン類、消炎剤、生薬等、防腐剤としては、例えばパラオキシ安息香酸エステル、フェノキシエタノール、ペンタンジオール等、紫外線吸収剤としては、例えばベンゾフェノン系、ＰＡＢＡ系、ケイ皮酸系、サリチル酸系、４−ｔｅｒｔ−ブチル−４’−メトキシベンゾイルメタン、トリアジン系、オキシベンゾン等を挙げることができ、これらを１種または２種以上用いることができる。 As antioxidants, for example, α-tocopherol, ascorbic acid, dibutylhydroxytoluene and the like, cosmetic ingredients such as vitamins, anti-inflammatory agents, herbal medicines, etc., as antiseptics, for example, paraoxybenzoic acid ester, phenoxyethanol, pentanediol, etc. Examples of ultraviolet absorbers include benzophenone, PABA, cinnamic acid, salicylic acid, 4-tert-butyl-4′-methoxybenzoylmethane, triazine, oxybenzone, and the like. Or 2 or more types can be used.
本発明の油中水型***化粧料は、液状、ペースト状、固形状等のいずれの形状にも限定されないが、２５℃でペースト状から液状であることが好ましい。また、口紅、リップグロス、リップクリーム、リップエッセンス等に用いることができ、ツヤの持続、二次付着レス効果に優れることから口紅、リップグロス等のメークアップ化粧料に好適に用いることができる。
The water-in-oil lip cosmetic of the present invention is not limited to any shape such as liquid, paste or solid, but it is preferably from paste to liquid at 25 ° C. Further, it can be used for lipsticks, lip glosses, lip balms, lip essences and the like, and it can be suitably used for make-up cosmetics such as lipsticks and lip glosses because of its excellent gloss and secondary adhesion-less effect.
以下、実施例によって本発明をさらに詳細に説明するが、これらの実施例により本発明の技術範囲が限定されるものではない。 EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, the technical scope of this invention is not limited by these Examples.
実施例１〜６及び比較例１〜５：口紅（液状）
表１に示す組成の口紅を下記の製造方法により調製し、各試料を、（イ）唇へのフィット感、（ロ）ツヤの持続、（ハ）二次付着レス効果、（ニ）経時安定性について下記評価方法にて評価し、その結果も併せて表１に示した。
Examples 1-6 and Comparative Examples 1-5: Lipstick (liquid)
Lipsticks having the composition shown in Table 1 were prepared by the following production method, and each sample was prepared by (i) fitting to the lips, (b) lasting gloss, (c) secondary adhesion-less effect, (d) stable over time. The properties were evaluated by the following evaluation methods, and the results are also shown in Table 1.
（製造方法）
Ａ．成分（１）〜（９）を１２０℃にて加熱溶解後、成分（１３）〜（１６）を加えて均一に混合する。
Ｂ．Ａに成分（１０）〜（１２）を加えて均一に混合、分散する。
Ｃ．成分（１７）〜（１８）を均一に混合する。
Ｄ．ＢにＣを撹拌しながら加え乳化する。脱泡後、塗布体（フロッキーチップ）付容器に流し込み充填する。
(Production method)
A. Components (1) to (9) are heated and dissolved at 120 ° C., and then components (13) to (16) are added and mixed uniformly.
B. Add components (10) to (12) to A and mix and disperse uniformly.
C. Ingredients (17) to (18) are mixed uniformly.
D. Add C to B with stirring and emulsify. After defoaming, it is poured into a container with an application body (floky chip) and filled.
（評価方法）
（イ）唇へのフィット感、（ロ）ツヤの持続
専門パネル１０名が各試料を使用し、（イ）は唇へのフィット感を実感できるかどうか、（ロ）は使用後３時間後の化粧膜の状態についてツヤが持続しているかどうかについて、下記絶対評価基準にて評価し評点をつけ、各試料のパネル全員の評点合計から、その平均値を算出し、下記判定基準により判定した。
＜評価基準＞
（評点）：（評価）
６点 ：非常に良好
５点 ：良好
４点 ：やや良好
３点 ：普通
２点 ：やや不良
１点 ：不良
＜判定基準＞
（判定）：（評点の平均点）
◎ ：５．０点を超える
○ ：３．５点を超え、５．０点以下
△ ：２．０点を超え、３．５点以下
× ：２．０点以下
（ハ）二次付着レス効果
各試料を、唇に塗布し、陶器のカップ（白色）で水を飲み、カップについた跡を目視にて評価し、下記判定基準により判定した。
＜判定基準＞
（評価） ：（判定）
カップに全く色が付かない： ◎
カップに僅かに色が付く ： ○
カップに明らか色が付く ： ×
（ニ）経時安定性
各試料を透明の樹脂容器に充填し、５０℃の恒温槽に１ヶ月保管した後、調製直後の状態を基準として、分離や排液の状態について以下の３段階判定基準に従って判定した。
＜判定基準＞
（評価） ：（判定）
変化なし ：◎
軽微な変化があるが使用に問題なし ：○
やや変化があり使用に多少支障がある：△
かなり変化があり使用に支障がある ：×
(Evaluation method)
(A) Fit to lips, (B) 10 glossy sustaining panels use each sample, (A) whether or not you can feel the fit to the lips, (B) after 3 hours after use Whether or not the gloss of the cosmetic film is maintained is evaluated according to the following absolute evaluation criteria and given a score, and the average value is calculated from the total score of all the panels of each sample, and determined according to the following criteria .
<Evaluation criteria>
(Score): (Evaluation)
6 points: Very good 5 points: Good 4 points: Somewhat good 3 points: Normal 2 points: Somewhat bad 1 point: Defect <Criteria>
(Judgment): (Average score)
◎: Over 5.0 points ○: Over 3.5 points, 5.0 points or less △: Over 2.0 points, 3.5 points or less ×: 2.0 points or less (c) No secondary adhesion Effect Each sample was applied to the lips, water was drunk with a ceramic cup (white), the marks on the cup were visually evaluated, and judged according to the following criteria.
<Criteria>
(Evaluation): (Judgment)
No color on the cup: ◎
The cup is slightly colored: ○
The cup has a clear color: ×
(D) Stability over time After each sample is filled in a transparent resin container and stored in a thermostatic bath at 50 ° C. for one month, the following three-stage criteria for separation and drainage are used based on the state immediately after preparation. Judged according to.
<Criteria>
(Evaluation): (Judgment)
No change: ◎
There is a slight change but there is no problem in use: ○
There is a slight change and there is some difficulty in use: △
There is considerable change and there is a hindrance to use: ×
表１の結果から明らかな如く、実施例１〜６の口紅は、唇へのフィット感、ツヤの持続、二次付着レス効果、経時安定性の全てにおいて良好なものであった。一方、成分（ａ）を含有しない比較例１は、フィット感に優れる化粧膜が形成されず、唇への付着性が不足するためにツヤの持続も十分でなく、二次付着レス効果も認められなかった。成分（ｃ）を含有しない比較例２と成分（ｆ）を含まない比較例５は、成分（ｅ）を含む水系成分を乳化することが出来ず、また成分（ｄ）の分離が起こり製剤として成り立たないものであった。成分（ｄ）の代わりに２５℃での粘度が１００ｍＰａ・ｓ未満であるシリコーン油を用いた比較例３は、塗布後に成分（ａ）を含む塗布膜と分離する成分がないために二次付着レス効果が認められなかった。成分（ｅ）を含まない比較例４は、成分（ａ）と（ｂ）を含む層と成分（ｄ）を含む層の分離が起こり、ツヤの持続、二次付着レス効果が認められず、経時安定性も悪いものであった。 As is apparent from the results in Table 1, the lipsticks of Examples 1 to 6 were good in all of the fit to the lips, the persistence of gloss, the secondary adhesion-less effect, and the stability over time. On the other hand, Comparative Example 1 containing no component (a) does not form a decorative film with an excellent fit, lacks adhesion to the lips, so that the gloss does not last sufficiently, and a secondary adhesion-less effect is also recognized. I couldn't. Comparative Example 2 that does not contain component (c) and Comparative Example 5 that does not contain component (f) cannot emulsify an aqueous component containing component (e), and separation of component (d) occurs as a preparation. It was not possible. In Comparative Example 3 using a silicone oil having a viscosity at 25 ° C. of less than 100 mPa · s instead of component (d), there is no component that separates from the coating film containing component (a) after coating. The less effect was not recognized. In Comparative Example 4 which does not contain the component (e), separation of the layer containing the components (a) and (b) and the layer containing the component (d) occurs, no gloss persistence, secondary adhesion-less effect, The stability over time was also poor.
実施例７：リップグロス（液状）
成分名 （％）
１．エチルセルロース ※１１ ６
２．オクチルドデカノール ※２ ５
３．デシルテトラデカノール ※３ ３０
４．トリイソステアリン酸ジグリセリル 残量
５．トリオクタン酸グリセリル ５
６．ジフェニルジメチコン（４００ｍＰａ・ｓ） １０
７．トリメチルシロキフェニルジメチコン（１０００ｍＰａ・ｓ）※７ １０
８．ジフェニルシロキシフェニルトリメチコン ※８ ５
９．ダイマージリノレイル水添ロジン縮合物 ※１２ ３
１０．（パルミチン酸／２−エチルヘキサン酸）デキストリン ※４ ３
１１．ラウリルＰＥＧ−９ポリジメチルシロキシエチルジメチコン １．５
１２．ホホバ油 ５
１３．シリコーン処理１０％赤色２０２号 ０．１
１４．シリコーン処理１０％黄色４号 ０．２
１５．酸化チタン ０．０５
１６．シリル化シリカ ※１０ ２．０
１７．酸化防止剤（ＢＨＴ） ０．０１
１８．防腐剤（フェノキシエタノール） ０．３
１９．ガラス末 ※１３ １
２０．（ＰＥＴ／ポリメタクリル酸メチル）ラミネート ※１４ １
２１．精製水 ５
２２．エタノール ０．５
２３．ヒアルロン酸 適量
※１１ ＡＱＵＡＬＯＮ ＥＣ−Ｎ５０（ＡＳＨＬＡＮＤ社製）（エチルエーテルの平均置換度：２．４６〜２．５８、量平均分子量：１６００００）
※１２ ＬＵＳＰＬＡＮ ＤＤ−ＤＨＲ（日本精化社製）
※１３ マイクログラスメタシャインＭＴ１０８０ＲＹ（日本板硝子社製）
※１４ オーロラフレークレッド ０．０５（角八魚鱗箔社製）
（製造方法）
Ａ．成分（１）〜（１２）を１１０℃〜１２０℃にて加熱溶解後、成分（１３）〜（２０）を加えて均一に混合分散する。
Ｂ．成分（２１）〜（２３）を均一に混合溶解する。
Ｃ．ＡにＢを加えて乳化した後、脱泡し、チューブ容器に流し込み充填する。
Example 7: Lip gloss (liquid)
Ingredient name (%)
1. Ethylcellulose * 11 6
2. Octild decanol * 2 5
3. Decyltetradecanol * 3 30
4). 4. Diglyceryl triisostearate remaining amount Glyceryl trioctanoate 5
6). Diphenyl dimethicone (400 mPa · s) 10
7). Trimethylsiloxyphenyl dimethicone (1000 mPa · s) * 7 10
8). Diphenylsiloxyphenyl trimethicone * 8 5
9. Dimer linoleyl hydrogenated rosin condensate * 12 3
10. (Palmitic acid / 2-ethylhexanoic acid) dextrin * 4 3
11. Lauryl PEG-9 polydimethylsiloxyethyl dimethicone 1.5
12 Jojoba oil 5
13. Silicone treatment 10% red 202 No. 0.1
14 Silicone treatment 10% yellow No.4 0.2
15. Titanium oxide 0.05
16. Silylated silica * 10 2.0
17. Antioxidant (BHT) 0.01
18. Preservative (phenoxyethanol) 0.3
19. Glass powder * 13 1
20. (PET / Polymethyl methacrylate) Laminate * 14 1
21. Purified water 5
22. Ethanol 0.5
23. Hyaluronic acid appropriate amount * 11 AQUALON EC-N50 (manufactured by ASHLAND) (average degree of ethyl ether substitution: 2.46 to 2.58, weight average molecular weight: 160000)
* 12 LUSPLAN DD-DHR (Nippon Seika Co., Ltd.)
* 13 Microglass Metashine MT1080RY (Nippon Sheet Glass Co., Ltd.)
* 14 Aurora Flakes Red 0.05 (manufactured by Kakuhachi Fish Scale)
(Production method)
A. Components (1) to (12) are heated and dissolved at 110 ° C. to 120 ° C., and then components (13) to (20) are added and uniformly mixed and dispersed.
B. Ingredients (21) to (23) are uniformly mixed and dissolved.
C. After emulsifying by adding B to A, defoaming, pouring into a tube container and filling.
得られたリップグロスは、唇へのフィット感、ツヤの持続、二次付着レス効果、経時安定性に優れたものであった。 The obtained lip gloss was excellent in feeling of fitting to the lips, lasting gloss, secondary adhesion-less effect, and stability over time.
実施例８：口紅（固形）
成分名
１．エチルセルロース ※１５ ３
２．オクチルドデカノール ※２ ２０
３．ヒドロキシステアリン酸オクチル 残量
４．トリオクタン酸グリセリル １０
５．水添ポリイソブテン １
６．（エチレン／プロピレン）コポリマー ８
７．合成ワックス ７
８．ジメチルポリシロキサン（１００ｍＰａ・ｓ） ５
９．ジメチルポリシロキサン（１０００ｍＰａ・ｓ） ５
１０．ジフェニルシロキシフェニルトリメチコン ※８ ５
１１．パルミチン酸デキストリン ※５ ０．０２
１２．イソステアリン酸デキストリン ※１６ １．０
１３．天然ビタミンＥ ０．１
１４．オリーブスクワラン １
１５．シリコーン処理１０％赤色２０２号 １．０
１６．レシチン処理１％酸化チタン ０．５
１７．パーフルオロオクチルトリエトキシシラン処理３％雲母チタン １．０
１８．炭酸カルシウム ０．１
１９．シリカ ※１７ ０．５
２０．精製水 １０
２１．１，３−ブチレングリコール ２
２２．キシリトール ０．１
２３．ステビア ０．０５
２４．香料 適量
※１５ ＡＱＵＡＬＯＮ ＥＣ−Ｎ１００（ＡＳＨＬＡＮＤ社製）（エチルエーテルの平均置換度：２．４６〜２．５８、量平均分子量：２１５０００）
※１６ ユニフィルマＨＶＹ（千葉製粉社製）
※１７ ＡＥＲＯＳＩＬ３８０Ｓ（日本アエロジル社製）
（製造方法）
Ａ．成分（１）〜（１４）を１１０℃〜１２０℃にて加熱溶解後、成分（１５）〜（１９）を加えて均一に混合分散する。
Ｂ．成分（２０）〜（２３）を均一に混合溶解する。
Ｃ．Ａを加熱溶解しＢを加えて乳化した後、脱泡し、成分（２４）を加えて均一に混合し、金型に流し込み充填成形する。
Example 8: Lipstick (solid)
Ingredient name
1. Ethylcellulose * 15 3
2. Octild decanol * 2 20
3. 3. Octyl hydroxystearate remaining amount Glyceryl trioctanoate 10
5. Hydrogenated polyisobutene 1
6). (Ethylene / Propylene) Copolymer 8
7). Synthetic wax 7
8). Dimethylpolysiloxane (100 mPa · s) 5
9. Dimethylpolysiloxane (1000 mPa · s) 5
10. Diphenylsiloxyphenyl trimethicone * 8 5
11. Dextrin palmitate * 5 0.02
12 Dextrin isostearate * 16 1.0
13. Natural vitamin E 0.1
14 Olive squalane 1
15. Silicone treatment 10% red 202 No. 1.0
16. Lecithin treated 1% titanium oxide 0.5
17. Perfluorooctyltriethoxysilane-treated 3% mica titanium 1.0
18. Calcium carbonate 0.1
19. Silica * 17 0.5
20. Purified water 10
21.1,3-butylene glycol 2
22. Xylitol 0.1
23. Stevia 0.05
24. Perfume appropriate amount * 15 AQUALON EC-N100 (manufactured by ASHLAND) (average degree of substitution of ethyl ether: 2.46 to 2.58, amount average molecular weight: 215000)
* 16 Unifilma HVY (Chiba Flour Mills)
* 17 AEROSIL380S (Nippon Aerosil Co., Ltd.)
(Production method)
A. Components (1) to (14) are heated and dissolved at 110 ° C. to 120 ° C., and then components (15) to (19) are added and uniformly mixed and dispersed.
B. Components (20) to (23) are mixed and dissolved uniformly.
C. After A is heated and dissolved and B is added to emulsify, it is degassed, and component (24) is added and mixed uniformly, poured into a mold and filled.
得られた口紅は、唇へのフィット感、ツヤの持続、二次付着レス効果、経時安定性に優れたものであった。 The obtained lipstick was excellent in the fit to the lips, the persistence of gloss, the secondary adhesion-less effect, and the stability over time.
Claims (3)
（ａ）エチルセルロース
（ｂ）総炭素数１６〜２４の１価の液状アルコール
（ｃ）デキストリン脂肪酸エステル
（ｄ）２５℃での粘度が１００〜１００万ｍＰａ・ｓである、ジメチルポリシロキサン、フェニル変性シリコーン、フッ素変性シリコーンから選ばれる１種または２種以上の油剤
（ｅ）水
（ｆ）シリカ
を含有する油中水型***化粧料。 The following components (a) to (f);
(A) ethyl cellulose (b) monovalent liquid alcohol having a total carbon number of 16 to 24 (c) dextrin fatty acid ester (d) dimethylpolysiloxane having a viscosity at 25 ° C. of 1 to 1,000,000 mPa · s, phenyl-modified A water-in-oil lip cosmetic containing one or more oils selected from silicone and fluorine-modified silicone (e) water (f) silica.
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| JP2017060027A JP6904744B2 (en) | 2017-03-24 | 2017-03-24 | Water-in-oil lip cosmetics |
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|---|---|---|---|
| JP2017060027A JP6904744B2 (en) | 2017-03-24 | 2017-03-24 | Water-in-oil lip cosmetics |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018199638A (en) * | 2017-05-26 | 2018-12-20 | 花王株式会社 | Oily cosmetic |
| WO2023228895A1 (en) * | 2022-05-26 | 2023-11-30 | 日油株式会社 | Oil for cosmetic and cosmetic containing same |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59122415A (en) * | 1982-12-28 | 1984-07-14 | Kobayashi Kooc:Kk | Make-up cosmetic |
| JPH10306012A (en) * | 1997-02-27 | 1998-11-17 | L'oreal Sa | Composition for topical use containing dissolved ethyl cellulose and free from monohydric alcohol |
| WO2010113956A1 (en) * | 2009-03-31 | 2010-10-07 | 株式会社 資生堂 | Lip cosmetic |
| JP2013537214A (en) * | 2010-09-20 | 2013-09-30 | ロレアル | Aqueous cosmetic composition comprising alkylcellulose |
| JP2016166146A (en) * | 2015-03-10 | 2016-09-15 | 株式会社コーセー | Gel lip cosmetics |
| JP2016190810A (en) * | 2015-03-31 | 2016-11-10 | 株式会社コーセー | Oily lip cosmetic |
-
2017
- 2017-03-24 JP JP2017060027A patent/JP6904744B2/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59122415A (en) * | 1982-12-28 | 1984-07-14 | Kobayashi Kooc:Kk | Make-up cosmetic |
| JPH10306012A (en) * | 1997-02-27 | 1998-11-17 | L'oreal Sa | Composition for topical use containing dissolved ethyl cellulose and free from monohydric alcohol |
| WO2010113956A1 (en) * | 2009-03-31 | 2010-10-07 | 株式会社 資生堂 | Lip cosmetic |
| JP2013537214A (en) * | 2010-09-20 | 2013-09-30 | ロレアル | Aqueous cosmetic composition comprising alkylcellulose |
| JP2016166146A (en) * | 2015-03-10 | 2016-09-15 | 株式会社コーセー | Gel lip cosmetics |
| JP2016190810A (en) * | 2015-03-31 | 2016-11-10 | 株式会社コーセー | Oily lip cosmetic |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018199638A (en) * | 2017-05-26 | 2018-12-20 | 花王株式会社 | Oily cosmetic |
| WO2023228895A1 (en) * | 2022-05-26 | 2023-11-30 | 日油株式会社 | Oil for cosmetic and cosmetic containing same |
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| Publication number | Publication date |
|---|---|
| JP6904744B2 (en) | 2021-07-21 |
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