JP2018095636A - Pest control agent - Google Patents
Pest control agent Download PDFInfo
- Publication number
- JP2018095636A JP2018095636A JP2017169903A JP2017169903A JP2018095636A JP 2018095636 A JP2018095636 A JP 2018095636A JP 2017169903 A JP2017169903 A JP 2017169903A JP 2017169903 A JP2017169903 A JP 2017169903A JP 2018095636 A JP2018095636 A JP 2018095636A
- Authority
- JP
- Japan
- Prior art keywords
- test
- ants
- acid
- pelargonic acid
- pest control
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 241000607479 Yersinia pestis Species 0.000 title claims abstract description 106
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims abstract description 135
- 239000005643 Pelargonic acid Substances 0.000 claims abstract description 67
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 53
- 239000004480 active ingredient Substances 0.000 claims abstract description 31
- 150000003839 salts Chemical class 0.000 claims abstract description 20
- 230000009545 invasion Effects 0.000 claims description 46
- 239000005871 repellent Substances 0.000 claims description 45
- 230000002940 repellent Effects 0.000 claims description 45
- 230000005764 inhibitory process Effects 0.000 claims description 22
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 7
- 150000003863 ammonium salts Chemical class 0.000 claims description 6
- 159000000000 sodium salts Chemical class 0.000 claims description 6
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- 238000012360 testing method Methods 0.000 description 155
- 241000257303 Hymenoptera Species 0.000 description 69
- -1 2-ethylhexyl trimellitic acid Chemical compound 0.000 description 54
- 230000000694 effects Effects 0.000 description 51
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- 230000000052 comparative effect Effects 0.000 description 31
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Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Abstract
Description
本発明は、ペラルゴン酸およびその塩を有効成分とした新規な害虫防除剤に関する。
さらに、本発明は、害虫侵入阻害剤に関する。より詳しくは、本発明は、ペラルゴン酸またはその塩を有効成分とし、薬剤処理面内に害虫が侵入することを確実に阻害する害虫侵入阻害剤に関する。
The present invention relates to a novel pest control agent comprising pelargonic acid and a salt thereof as an active ingredient.
Furthermore, the present invention relates to a pest entry inhibitor. More specifically, the present invention relates to a pest invasion inhibitor that comprises pelargonic acid or a salt thereof as an active ingredient and that reliably inhibits the entry of pests into a drug-treated surface.
ペラルゴン酸は、天然にも存在する、茶、トウモロコシ、柑橘、ホップ等の食品に含まれる直鎖飽和脂肪酸のひとつとして知られており、不快な臭いをもつ無色油状液体である。しかし非特許文献1に示されたように、ペラルゴン酸は動物に対する毒性が低いことが知られており、安全性が高いことから各種用途において原料や有効成分としての利用が検討されている。 Pelargonic acid is known as one of the straight-chain saturated fatty acids contained in foods such as tea, corn, citrus, and hops that exist in nature, and is a colorless oily liquid with an unpleasant odor. However, as shown in Non-Patent Document 1, pelargonic acid is known to have low toxicity to animals, and since it is highly safe, its use as a raw material or active ingredient is being studied in various applications.
例えば、特許文献1には、ココア様香料組成物の原料としてペラルゴン酸を用いることが開示されている。また特許文献2には、除草剤の有効成分として用いることについて検討がなされている。さらに特許文献3では、ペラルゴン酸と植物精油とを併用することで種子の発芽抑制作用を高めることが検討されている。 For example, Patent Document 1 discloses using pelargonic acid as a raw material for a cocoa-like fragrance composition. Patent Document 2 discusses use as an active ingredient of a herbicide. Furthermore, in Patent Document 3, it has been studied to enhance seed germination inhibiting action by using pelargonic acid and plant essential oil in combination.
また、近年、屋外から家屋などの建造物内に侵入するアリ類により刺咬被害が増加し、アリ類も不快害虫の1つに挙げられている。その防除方法としては、殺虫活性成分を含有する液剤またはエアゾール剤を、アリ類に直接噴霧して駆除するタイプのものや、毒餌剤をアリ類に巣穴に持ち帰らせ、巣穴内のアリ類を駆除するタイプのものが主体である。
例えば、ピレスロイド系化合物を殺虫活性成分として含有させた液剤やエアゾール剤は、アリ類やアリ類の巣に直接噴霧することにより速効的な殺虫効果が得られることが知られている(例えば、特許文献4等)。また、フェニルピラゾール系化合物を殺虫活性成分として含有させた毒餌剤は、接触作用による速効的な殺虫性が示されず、アリ類が巣穴に毒餌剤を運搬して巣全体を崩壊させることが報告されている(特許文献5)。しかしながら、上記液剤やエアゾール剤は、接触作用により速効的な殺虫効果が得られるため、殺虫活性成分に接触しないアリ類は駆除することができない。また、上記毒餌剤は殺虫成分と共に含有される誘引成分によっては、運搬効果にバラツキが見られ十分な防除効果が得られないことがある。
一方、アリ類をはじめその他の害虫は、家屋内に侵入さえしなければ必ずしも駆除の必要がない場合も多いため、アリ類等の害虫の侵入を阻止したい家屋入り口や周辺等に、予め害虫忌避効果を発揮する薬剤を処理する方法が提案されているものの、その忌避効果は未だ十分ではなく、アリ類等の害虫の侵入を確実に阻害できる新たな薬剤の開発が望まれていた。
In recent years, ant bites invading buildings such as houses from the outside have increased bite damage, and ants are also listed as one of the unpleasant pests. As a control method, a solution or aerosol containing an insecticidal active ingredient is sprayed directly on the ants, or a poison bait is brought back to the burrow and the ants in the burrow are removed. The main thing is the type of extermination.
For example, it is known that a liquid agent or aerosol containing a pyrethroid compound as an insecticidal active ingredient can obtain a fast-acting insecticidal effect by spraying directly onto ants or ant nests (for example, patents) Reference 4). In addition, the poison bait containing a phenylpyrazole compound as an insecticidal active ingredient does not show fast-acting insecticidal effect due to contact action, and it is reported that ants carry the poison bait to the burrow and collapse the entire nest (Patent Document 5). However, since the liquid agent and the aerosol agent have a rapid insecticidal effect by contact action, ants that do not contact the insecticidal active ingredient cannot be controlled. In addition, depending on the attracting component contained together with the insecticidal component, the poison bait may have a variation in the transport effect and a sufficient control effect may not be obtained.
On the other hand, ants and other pests do not necessarily need to be exterminated unless they enter the house. Therefore, it is necessary to avoid pests at home entrances and the surrounding areas where you want to prevent the entry of pests such as ants. Although a method for treating a drug that exhibits an effect has been proposed, its repellent effect is not yet sufficient, and the development of a new drug that can reliably inhibit the invasion of pests such as ants has been desired.
ペラルゴン酸は、上述のとおり各種用途について検討がなされており、その一部については利用が進んでいる。近年、安全志向が高まる中、ユーザーの天然由来成分に対する期待は高まっており、ペラルゴン酸についても新たな用途の提供が望まれている。
そこで本発明は、安全性の高いペラルゴン酸に着目し、新たな用途として害虫防除剤を提供することを目的としている。
さらに、本発明は、屋外から家屋などの建造物内に侵入する害虫を確実に阻害する、害虫侵入阻害剤を提供することを目的としている。
As described above, pelargonic acid has been studied for various uses, and some of them are being used. In recent years, as safety-consciousness has increased, users' expectations for naturally-derived components have increased, and it has been desired to provide new uses for pelargonic acid.
Then, this invention pays attention to highly safe pelargonic acid, and it aims at providing a pest control agent as a new use.
Another object of the present invention is to provide a pest entry inhibitor that reliably inhibits pests that enter a building such as a house from the outside.
本発明者は、上記課題を解決するために鋭意研究を重ねた結果、ペラルゴン酸およびその塩が、各種の害虫に対して優れた殺虫効果、忌避効果を奏することを、さらには、薬剤処理面内に害虫が侵入することを確実に阻害する優れた侵入阻害効果を有することを見出し、上記課題を解決するに至ったものである。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that pelargonic acid and salts thereof have an excellent insecticidal effect and repellent effect against various pests, and further, a chemical treatment surface. It has been found that it has an excellent invasion inhibitory effect that surely inhibits the invading of pests therein and has solved the above problems.
本発明は、具体的には次の事項を要旨とする。
1.ペラルゴン酸およびその塩を有効成分として含有することを特徴とする害虫防除剤。
2.害虫防除が害虫忌避であることを特徴とする1.記載の害虫防除剤。
3.害虫忌避が侵入阻害であることを特徴とする2.記載の害虫防除剤。
4.ペラルゴン酸の塩が、ナトリウム塩、トリエタノールアミン塩、アンモニウム塩、カリウム塩のいずれか1種以上であることを特徴とする1.〜3.いずれかに記載の害虫防除剤。
The gist of the present invention is specifically as follows.
1. A pest control agent comprising pelargonic acid and a salt thereof as an active ingredient.
2. 1. The pest control is pest repellent. The pest control agent as described.
3. 1. Pest repellent is inhibition of invasion The pest control agent as described.
4). 1. The salt of pelargonic acid is at least one of a sodium salt, a triethanolamine salt, an ammonium salt, and a potassium salt. ~ 3. The pest control agent according to any one of the above.
(効果1)
本発明の害虫防除剤は、天然由来成分であるペラルゴン酸を有効成分とするため、環境や人畜に負荷も少なく安全性の高い新規な害虫防除剤を提供することができる。また、ペラルゴン酸の新たな用途を提供することができる。
(Effect 1)
Since the pest control agent of the present invention uses pelargonic acid, which is a naturally derived component, as an active ingredient, it is possible to provide a novel pest control agent that has little burden on the environment and human livestock and is highly safe. Moreover, the new use of pelargonic acid can be provided.
(効果2)
本発明の害虫侵入阻害剤は、そのまま若しくは水に希釈して、家屋等の建造物の入り口付近に直接散布することによって、薬剤処理面内にアリ類や等脚目類等の害虫が侵入することを確実に阻害することができるので、屋内等に居住する人やペット等の動物がアリ類等に刺咬される被害を防ぎ、害虫が屋内に侵入すること自体を抑制することができる。
また、本発明の害虫侵入阻害剤は、除草活性を有するペラルゴン酸またはその塩を有効成分としているため、散布した場所の除草効果も同時に得ることができる。すなわち、本発明の害虫侵入阻害剤は、家屋のまわりや駐車場に散布することにより、家屋内や車内への害虫の侵入を阻害すると共に、散布した場所の雑草の繁殖を抑制する効果が得られるという特徴を有するものである。
(Effect 2)
The pest invasion inhibitor of the present invention is directly or diluted with water and directly sprayed near the entrance of a building such as a house, so that pests such as ants and isopoda invade the chemical treatment surface. Since this can be surely inhibited, it is possible to prevent damage from being bitten by an ant or the like to an animal such as an indoor person or an animal such as a pet, and to prevent an insect from entering the room itself.
Moreover, since the pest invasion inhibitor of the present invention contains pelargonic acid having a herbicidal activity or a salt thereof as an active ingredient, the herbicidal effect at the sprayed place can be obtained at the same time. That is, the insect pest intrusion inhibitor of the present invention is effective to inhibit the invasion of pests into the house or inside the car and to suppress the weed propagation in the sprayed place by spraying around the house or in the parking lot. It has the characteristic that it is made.
以下、本発明の害虫防除剤について詳細に説明する。
本発明の害虫防除剤は、有効成分としてペラルゴン酸またはその塩を含有するものである。
本発明における害虫防除とは、害虫を死に至らしめる殺虫効果により防除することはもとより、害虫が忌避する効果により防除すること、さらには薬剤処理面内に害虫が侵入することを阻害することをも含むものである。
ここで、本発明における「忌避」、「侵入阻害」、「侵入回避」について、詳しく説明する。
本発明における忌避や忌避剤とは、薬剤処理面内に侵入した害虫が薬剤の臭い等を嫌がり、一度侵入した薬剤処理面内から出て遠ざかる行動や、その行動を促す薬剤を意味する。
一方、本発明における侵入阻害とは、薬剤処理面に対し害虫が触覚や歩脚を接触すらさせることなく薬剤処理面の前からUターンする行動、若しくは、触覚や歩脚を薬剤処理面に接触させたとしても薬剤処理面内に侵入することなくUターンする行動、すなわち、薬剤処理面内に害虫が全く侵入しない行動や、その行動を促す薬剤を意味する。さらに、本発明における侵入回避とは、薬剤処理面に対し害虫が触覚や歩脚を接触すらさせることなく薬剤処理面の前からUターンする行動を意味する。
Hereinafter, the pest control agent of the present invention will be described in detail.
The pest control agent of the present invention contains pelargonic acid or a salt thereof as an active ingredient.
The pest control in the present invention is not only controlled by the insecticidal effect that causes the pest to die, but also controlled by the effect that the pest repels, and also inhibits the entry of the pest into the chemical treatment surface. Is included.
Here, “avoidance”, “invasion inhibition”, and “invasion avoidance” in the present invention will be described in detail.
The repellent and the repellent in the present invention mean a behavior in which a pest that has entered the surface of the drug treatment dislikes the odor of the drug, moves away from the surface of the drug treatment once invaded, or a drug that promotes the action.
On the other hand, invasion inhibition in the present invention is an action in which a pest makes a U-turn from the front of the drug-treated surface without even touching the drug-treated surface with the tactile sensation or the pedestal, or touches the haptic or pedestrian to the drug-treated surface It means an action that makes a U-turn without entering the medicine processing surface even if the action is made, that is, an action in which no pests enter the medicine processing surface or a medicine that promotes the action. Furthermore, invasion avoidance in the present invention means an action in which a pest makes a U-turn from the front of the medicine processing surface without even touching the tactile sensation or the pedestal to the medicine processing surface.
ペラルゴン酸は、炭素数9個からなる飽和脂肪酸であり、安全かつ速効的な除草活性を有する化合物として公知であり、我が国においても、1996年に除草剤として農薬登録された化合物である。ペラルゴン酸の塩としては、ナトリウム塩、カリウム塩、カルシウム塩、マグネシウム塩、アンモニウム塩、エタノールアミン塩、トリエタノールアミン塩等が挙げられ、本発明の害虫防除剤の有効成分として、ペラルゴン酸またはその塩として、ナトリウム塩、トリエタノールアミン塩、アンモニウム塩、カリウム塩が好ましい。これらの塩は単体として害虫防除剤中に加えても良いが、ペラルゴン酸と対応する中和剤とを別々に加えて害虫防除剤の調製時に塩を形成させてもよい。例えば、ペラルゴン酸と、中和剤としてトリエタノールアミンまたは水酸化ナトリウムを別々に加えて、トリエタノールアミン塩またはナトリウム塩として使用することができる。中和剤として、水酸化ナトリウム、トリエタノールアミン、アンモニア、水酸化カリウム等が好適である。 Pelargonic acid is a saturated fatty acid having 9 carbon atoms, is known as a compound having safe and rapid herbicidal activity, and is a compound registered as an agrochemical as a herbicide in Japan in 1996. Examples of the salt of pelargonic acid include sodium salt, potassium salt, calcium salt, magnesium salt, ammonium salt, ethanolamine salt, triethanolamine salt and the like. As an active ingredient of the pest control agent of the present invention, pelargonic acid or its As the salt, sodium salt, triethanolamine salt, ammonium salt and potassium salt are preferable. These salts may be added as a simple substance to the pest control agent, but pelargonic acid and the corresponding neutralizing agent may be added separately to form a salt during preparation of the pest control agent. For example, pelargonic acid and triethanolamine or sodium hydroxide as a neutralizing agent can be added separately and used as a triethanolamine salt or sodium salt. As the neutralizing agent, sodium hydroxide, triethanolamine, ammonia, potassium hydroxide and the like are suitable.
本発明の害虫防除剤は、有効成分であるペラルゴン酸またはその塩を、害虫防除剤全体の0.01質量%以上、好ましくは0.05質量%以上、より好ましくは0.1質量%以上となるように用いるのがよい。また、ペラルゴン酸またはその塩をあまり多量に用いると臭いによる不快感が生じるおそれがあるので好ましくないため、10質量%以下含有することが好ましく、5質量%以下含有することがより好ましく、3質量%以下含有することがさらに好ましい。
本発明の害虫防除剤は、そのまま対象害虫に処理することができるが、所定の有効成分を含有した製剤を使用時に水で希釈して対象害虫に処理することもできる。この場合、水で希釈された製剤中での有効成分の含有量が0.01質量%以上、好ましくは0.05質量%以上となるように調製して使用することが好ましい。
The pest control agent of the present invention comprises pelargonic acid or a salt thereof as an active ingredient in an amount of 0.01% by mass or more, preferably 0.05% by mass or more, more preferably 0.1% by mass or more of the total pest control agent. It is good to use so that it becomes. Further, if too much pelargonic acid or a salt thereof is used, unpleasant feeling due to odor may occur, which is not preferable. Therefore, the content is preferably 10% by mass or less, more preferably 5% by mass or less, and more preferably 3% by mass. % Or less is more preferable.
The pest control agent of the present invention can be directly processed into the target pest, but a preparation containing a predetermined active ingredient can be diluted with water at the time of use to be processed into the target pest. In this case, it is preferable to prepare and use such that the content of the active ingredient in the preparation diluted with water is 0.01% by mass or more, preferably 0.05% by mass or more.
本発明の害虫防除剤は、公知の方法により調製、製造することができる。例えば、ペラルゴン酸を水に添加し、有機溶剤や界面活性剤を用いて混合撹拌し、溶解、乳化、分散、懸濁化、可溶化して液剤やジェル剤とすることができる。またマイクロカプセル化して使用することもできる。ペラルゴン酸は油状液体であることから、有機溶剤や界面活性剤を用いて調製、製造することが適切である。その中でも、スプレー剤やエアゾール剤等の噴霧用製剤や、液剤をジョウロヘッド付き容器に充填した散布剤等が、本発明の害虫防除性能を最大限に活用することができる製剤型として好適である。スプレー剤やエアゾール剤とするには、所定の噴霧パターン、噴霧粒子を供給する噴霧装置を備えたエアゾール缶、薬剤ボトルを用いることができる。
本発明の害虫防除剤は、本発明の効果を奏する限り、液剤に限らず、粉剤、顆粒剤、微細粒等の固形剤として用いることもできる。
調製、製造例の1つとして、ペラルゴン酸またはその塩を、必要に応じて界面活性剤を用いて、有機溶剤に溶かして溶液(A液)を調製し、このA液を適量の水に混合、撹拌することにより使用時に希釈する必要がない害虫防除剤とする方法を挙げることができる。水としては、水道水、イオン交換水、蒸留水、ろ過処理した水、滅菌処理した水、地下水などの天然水等の1種または2種以上を混合して用いることができる。
The pest control agent of the present invention can be prepared and produced by a known method. For example, pelargonic acid can be added to water, mixed and stirred using an organic solvent or surfactant, and dissolved, emulsified, dispersed, suspended, or solubilized to obtain a liquid or gel. It can also be used in microencapsulation. Since pelargonic acid is an oily liquid, it is appropriate to prepare and produce it using an organic solvent or a surfactant. Among them, spray formulations such as sprays and aerosols, sprays filled with liquid agents in containers with a water head, etc. are suitable as formulation types that can make maximum use of the pest control performance of the present invention. . In order to obtain a spray or aerosol, a predetermined spray pattern, an aerosol can equipped with a spray device for supplying spray particles, and a drug bottle can be used.
The pest control agent of the present invention can be used not only as a liquid agent but also as a solid agent such as a powder, granule, fine particle and the like as long as the effects of the present invention are exhibited.
As one of the preparation and production examples, pelargonic acid or its salt is dissolved in an organic solvent using a surfactant if necessary to prepare a solution (solution A), and this solution A is mixed with an appropriate amount of water. And a method of making a pest control agent that does not need to be diluted at the time of use by stirring. As water, tap water, ion-exchanged water, distilled water, filtered water, sterilized water, natural water such as ground water, etc. can be used alone or in combination.
使用できる有機溶剤としては、例えば、アジピン酸ジイソブチル、アジピン酸ジオレイル、アジピン酸ジイソデシル、フタル酸ジエチルヘキシル、フタル酸ジデシル、トリメリット酸2−エチルヘキシル、トリメリット酸トリデシル等の多塩基酸アルコールエステル;2−エチルヘキサン酸セチル、ヤシ脂肪酸セチル、ラウリン酸メチル、ミリスチン酸メチル、オレイン酸メチル、オレイン酸オクチル等の脂肪酸アルコールエステル;ソルビタンモノラウレート、ソルビタンモノオレエート等の多価アルコール脂肪酸エステル;メタノール、エタノール、イソプロパノール、ブタノール、ヘキサノール、シクロヘキサノール、フェノキシエタノール、ベンジルアルコール等のアルコール;オクチルアルコール、ラウリルアルコール、3−メトキシ−3−メチル−1−ブタノール等の高級アルコール;エチレングリコール、プロピレングリコール、ジエチレングリコール、ヘキシレングリコール、ポリエチレングリコール、ポリプロピレングリコール等の多価アルコール;メチルジグリコール、メチルトリグリコール、エチレングリコールモノベンジルエーテル、エチレングリコールジメチルエーテル、ジエチレングリコールモノエチルエーテル、プロピレングリコールモノメチルエーテル、ジエチレングリコールモノベンジルエーテル等のグリコールエーテル;キシレン、トルエン、フェニルキシリルエタン、ケロシン、軽油、ヘキサン、シクロヘキサン、1,2−ジメチル−4−エチル−ベンゼン、メチルナフタレン、1−フェニル−1−キシリルエタン、1−キシリル−1−(3−α−メチルベンジルフェニル)エタン等の芳香族または脂肪族炭化水素;ノルマルパラフィン、イソパラフィン、流動パラフィン等のパラフィン系炭化水素;酢酸エチル、酢酸ブチル、ミリスチン酸イソプロピル、乳酸エチル等のエステル類;アセトン、メチルエチルケトン、メチルイソブチルケトン、シクロヘキサノン等のケトン類;クロロベンゼン、ジクロロメタン、ジクロロエタン、トリクロロエタン等のハロゲン化炭化水素類;アセトニトリル、イソブチロニトリル等のニトリル類;ジメチルスルホキシド等のスルホキシド類;スルホラン、γ−ブチロラクトン、N−メチル−2−ピロリドン、N−エチル−2−ピロリドン、N−オクチル−2−ピロリドン、1,3−ジメチル−2−イミダゾリジノン等のヘテロ環系溶剤;N,N−ジメチルホルムアミド、N,N−ジメチルアセトアミド等の酸アミド類;炭酸プロピレン等の酸アルキリデン類;大豆油、ヤシ油、ナタネ油、キリ油、ヒマシ油、綿実油等の植物油;オレンジ油、ヒソップ油、レモン油等の植物精油の1種または2種以上が挙げられる。 Examples of organic solvents that can be used include polybasic acid alcohol esters such as diisobutyl adipate, dioleyl adipate, diisodecyl adipate, diethylhexyl phthalate, didecyl phthalate, 2-ethylhexyl trimellitic acid, and tridecyl trimellitic acid; 2 -Fatty acid alcohol esters such as cetyl ethylhexanoate, coconut fatty acid cetyl, methyl laurate, methyl myristate, methyl oleate, octyl oleate; polyhydric alcohol fatty acid esters such as sorbitan monolaurate, sorbitan monooleate; methanol, Alcohol such as ethanol, isopropanol, butanol, hexanol, cyclohexanol, phenoxyethanol, benzyl alcohol; octyl alcohol, lauryl alcohol, 3-metho Higher alcohols such as cis-3-methyl-1-butanol; polyhydric alcohols such as ethylene glycol, propylene glycol, diethylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol; methyl diglycol, methyl triglycol, ethylene glycol monobenzyl ether , Glycol ethers such as ethylene glycol dimethyl ether, diethylene glycol monoethyl ether, propylene glycol monomethyl ether, diethylene glycol monobenzyl ether; xylene, toluene, phenylxylylethane, kerosene, light oil, hexane, cyclohexane, 1,2-dimethyl-4-ethyl -Benzene, methylnaphthalene, 1-phenyl-1-xylylethane, 1-xylyl-1- ( Aromatic or aliphatic hydrocarbons such as -α-methylbenzylphenyl) ethane; paraffinic hydrocarbons such as normal paraffin, isoparaffin, liquid paraffin; esters such as ethyl acetate, butyl acetate, isopropyl myristate, and ethyl lactate; acetone , Ketones such as methyl ethyl ketone, methyl isobutyl ketone and cyclohexanone; halogenated hydrocarbons such as chlorobenzene, dichloromethane, dichloroethane and trichloroethane; nitriles such as acetonitrile and isobutyronitrile; sulfoxides such as dimethyl sulfoxide; sulfolane, γ- Heterocyclic solvents such as butyrolactone, N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N-octyl-2-pyrrolidone, 1,3-dimethyl-2-imidazolidinone; N, N Acid amides such as dimethylformamide and N, N-dimethylacetamide; acid alkylidenes such as propylene carbonate; vegetable oils such as soybean oil, coconut oil, rapeseed oil, kiri oil, castor oil, cottonseed oil; orange oil, hyssop oil, lemon 1 type or 2 types or more of plant essential oils, such as oil, are mentioned.
使用できる界面活性剤としては、非イオン界面活性剤、陰イオン界面活性剤、陽イオン界面活性剤および両性界面活性剤を用いることができる。具体的には、例えば、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルアリールエーテル、ポリオキシエチレンスチリルフェニルエーテル、ポリオキシエチレンアルキルエステル、ポリオキシエチレンソルビタンアルキレート、ポリオキシエチレンフェニルエーテルポリマー、ポリオキシエチレンアルキレンアリールフェニルエーテル、ポリオキシエチレンアルキレングリコール、およびポリオキシエチレンポリオキシプロピレンブロックポリマー、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンアルキルアミン、ポリオキシエチレン脂肪酸アミド、ポリオキシエチレン型シリコン系界面活性剤等の非イオン界面活性剤;ポリオキシエチレンアルキルエーテルフォスフェート、リグニンスルホン酸塩、アルキルアリールスルホン酸塩、ポリオキシエチレンアルキルアリールエーテルサルフェート、アルキルナフタレンスルホン酸塩、ジアルキルスルホコハク酸塩、ポリオキシエチレンスチリルフェニルエーテルサルフェート、アルキルベンゼンスルホン酸塩、アルキルスルホン酸塩、アルキル硫酸塩、アルキルマレイン酸共縮合物のナトリウム塩等の陰イオン界面活性剤;アルキルベタイン、アルキルアミドプロピルベタイン、2−アルキル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン等の両性界面活性剤;アルキルアミン塩、第四級アンモニウム塩等の陽イオン界面活性剤の1種または2種以上が挙げられる。 As the surfactant that can be used, nonionic surfactants, anionic surfactants, cationic surfactants and amphoteric surfactants can be used. Specifically, for example, polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene styryl phenyl ether, polyoxyethylene alkyl ester, polyoxyethylene sorbitan alkylate, polyoxyethylene phenyl ether polymer, polyoxyethylene Alkylene aryl phenyl ether, polyoxyethylene alkylene glycol, and polyoxyethylene polyoxypropylene block polymer, polyoxyethylene hydrogenated castor oil, polyoxyethylene alkylamine, polyoxyethylene fatty acid amide, polyoxyethylene type silicon surfactant, etc. Nonionic surfactants: polyoxyethylene alkyl ether phosphates, lignin sulfonates, alkyl amines Sulfonate, polyoxyethylene alkyl aryl ether sulfate, alkyl naphthalene sulfonate, dialkyl sulfosuccinate, polyoxyethylene styryl phenyl ether sulfate, alkyl benzene sulfonate, alkyl sulfonate, alkyl sulfate, alkyl maleic acid cocondensation Anionic surfactants such as sodium salts of products; amphoteric surfactants such as alkylbetaines, alkylamidopropylbetaines, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaines; alkylamine salts, fourth 1 type, or 2 or more types of cationic surfactants, such as a quaternary ammonium salt, are mentioned.
本発明の害虫防除剤を調製、製造するに際しては、水、有機溶剤および界面活性剤を適宜組み合わせて用いることができるが、本発明の効果を奏する限り、安定化剤、増粘剤、香料、色素、消泡剤、光安定化剤(紫外線吸収剤)、pH調整剤、凍結防止剤、防腐剤、噴射剤、酸化防止剤等その他の各種成分を用いることができる。
その他の各種成分としては、例えば、ブチルヒドロキシアニソール、ジブチルヒドロキシトルエン、没食子酸プロピル、トコフェロール、アスコルビン酸、ビタミン等の安定化剤;カルボキシビニルポリマー、ポリビニルアルコール、グアーガム、キサンタンガム、ポリビニルピロリドン、コロイド性含水珪酸アルミニウム、コロイド性含水珪酸マグネシウム等の増粘剤;イランイラン油、オレンジ油、カモミール油、カルダモン油、クミン油、グレープフルーツ油、クローブ油、月桃油、コパイバ油、コリアンダー油、紫蘇油、シダーウッド油、シトロネラ油、シナモン油、ジャスミン油、スギ油、スペアミント油、セージ油、ゼラニウム油、タイム油、ネロリ油、パイン油、薄荷油、ヒノキ油、ヒバ油、ペパーミント油、ベルガモット油、柚子油、ユーカリ油、ライム油、ラベンダー油、レモン油、レモングラス油、レモンバーム油、ローズマリー油、ロベージ油等の天然精油、アニスアルデヒド、アセトフェノン、アセチルオイゲノール、ベンジルアセテート、ベンジルアルコール、ベンジルサリシレート、ベンズアルデヒド、カルボン、セドロール、シンナミックアルコール、シンナミックアルデヒド、シスジャスモン、シトラール、シトロネラール、シトロネロール、クマリン、シンナミルアセテート、オイゲノール、α−ピネン、β−ピネン、リモネン、ミルセン、β−カリオフィレン、ゲラニオール、ゲラニルアセテート、ヘキシルシンナミックアルデヒド、インドール、リナロール、リナロールオキサイド、リナリルアセテート、メチルオイゲノール、メントール、ネロール、フェニルエチルアルコール、チモール等の香料;赤色2号、赤色3号、赤色102号、赤色106号、赤色227号、赤色504号、青色1号、青色2号、青色202号、黄色4号、黄色5号、黄色202号、緑色3号、緑色201号、緑色204号、橙色205号等の色素;シリコーン系化合物等の消泡剤;パラアミノ安息香酸、t−ブチルメトキシジベンゾイルメタン、サリチル酸フェニル等の光安定化剤(紫外線吸収剤);グルコン酸、グルコノデルタラクトン、L−酒石酸水素カリウム、炭酸ナトリウム、フマル酸、リンゴ酸、クエン酸、ピロリン酸二水素ナトリウム、L−酒石酸ナトリウム、リン酸三カリウム、リン酸、乳酸ナトリウム、アジピン酸およびナトリウムやカリウムの塩、アミン塩等のpH調整剤;エタノール、プロピレングリコール、エチレングリコール等の凍結防止剤;ソルビン酸カリウム、パラクロロメタキシレノール、パラオキシ安息香酸ブチル、パラオキシ安息香酸メチル、パラオキシ安息香酸エチル、パラオキシ安息香酸プロピル、安息香酸等の防腐剤;プロパン、プロピレン、n−ブタン、イソブタン等の液化石油ガス、ジメチルエーテル、CFC、HCFC、HFC等のクロロフルオロカーボン等の液化ガス、窒素、炭酸ガス、圧縮空気、亜酸化窒素等の圧縮ガス等の噴射剤;ブチルヒドロキシアニソール、ジブチルヒドロキシトルエン、トコフェロール、γ−オリザノール、エリソルビン酸、エリソルビン酸ナトリウム、没食子酸プロピル等の酸化防止剤の1種または2種以上が挙げられる。
In preparing and producing the pest control agent of the present invention, water, an organic solvent and a surfactant can be used in appropriate combination, but as long as the effects of the present invention are exhibited, a stabilizer, a thickener, a fragrance, Various other components such as a dye, an antifoaming agent, a light stabilizer (ultraviolet absorber), a pH adjuster, an antifreezing agent, an antiseptic, a propellant, and an antioxidant can be used.
Other various components include, for example, stabilizers such as butylhydroxyanisole, dibutylhydroxytoluene, propyl gallate, tocopherol, ascorbic acid, vitamins; carboxyvinyl polymer, polyvinyl alcohol, guar gum, xanthan gum, polyvinylpyrrolidone, colloidal water content Thickeners such as aluminum silicate, colloidal hydrous magnesium silicate; ylang ylang oil, orange oil, chamomile oil, cardamom oil, cumin oil, grapefruit oil, clove oil, moon peach oil, copaiba oil, coriander oil, shiso oil, cedarwood Oil, citronella oil, cinnamon oil, jasmine oil, cedar oil, spearmint oil, sage oil, geranium oil, thyme oil, neroli oil, pine oil, light oil, cypress oil, hiba oil, peppermint oil, bergamot oil Natural essential oils such as coconut oil, eucalyptus oil, lime oil, lavender oil, lemon oil, lemongrass oil, lemon balm oil, rosemary oil, lobe oil, anisaldehyde, acetophenone, acetyl eugenol, benzyl acetate, benzyl alcohol, benzyl salicylate, Benzaldehyde, Carvone, Cedrol, Cinamic alcohol, Cynamic aldehyde, Cis jasmon, Citral, Citronellal, Citronellol, Coumarin, Cinnamyl acetate, Eugenol, α-pinene, β-pinene, limonene, myrcene, β-caryophyllene, geraniol, geranyl Acetate, hexylcinnamic aldehyde, indole, linalool, linalool oxide, linalyl acetate, methyl eugenol, menthol, Perfume such as roll, phenylethyl alcohol, thymol; Red No. 2, Red No. 3, Red No. 102, Red No. 106, Red No. 227, Red No. 504, Blue No. 1, Blue No. 2, Blue No. 202, Yellow No. 4 Yellow No. 5, Yellow No. 202, Green No. 3, Green No. 201, Green No. 204, Orange No. 205, etc .; Antifoaming agents such as silicone compounds; Paraaminobenzoic acid, t-butylmethoxydibenzoylmethane, salicylic acid Light stabilizers (ultraviolet absorbers) such as phenyl; gluconic acid, glucono delta lactone, potassium L-tartrate, sodium carbonate, fumaric acid, malic acid, citric acid, sodium dihydrogen pyrophosphate, sodium L-tartrate, PH adjusters such as tripotassium phosphate, phosphoric acid, sodium lactate, adipic acid and sodium and potassium salts, amine salts; Antifreezing agents such as potassium, propylene glycol, and ethylene glycol; preservatives such as potassium sorbate, parachlorometaxylenol, butyl paraoxybenzoate, methyl paraoxybenzoate, ethyl paraoxybenzoate, propyl paraoxybenzoate, benzoic acid; propane Propellants such as liquefied petroleum gas such as propylene, n-butane and isobutane, liquefied gas such as dimethyl ether, chlorofluorocarbon such as CFC, HCFC and HFC, compressed gas such as nitrogen, carbon dioxide, compressed air and nitrous oxide; Examples thereof include one or more antioxidants such as butylhydroxyanisole, dibutylhydroxytoluene, tocopherol, γ-oryzanol, erythorbic acid, sodium erythorbate, and propyl gallate.
本発明の害虫侵入阻害効果を得る害虫侵入阻害剤は、アリ類等の害虫の巣穴やその周囲に処理した際に土壌への吸収を抑えて、アリ類等の害虫が触覚や歩脚を薬剤処理面に接触させることを抑制し、薬剤処理面内にアリ類等の害虫が侵入することを確実に阻害する効果を十分に発揮させるために、粘度のある液剤としてもよい。粘度を調整するに際しては、例えば、グリセリン、ザンフロー、キサンタンガム、ペクチン、アラビアガム、グアーガム、寒天、セルロースおよびその誘導体、デンプンおよびその誘導体、カルボキシアルカリ化物、ポリアクリル酸塩、ポリマレイン酸塩、ポリビニルアルコール、ポリビニルピロリドン、カルボキシビニルポリマー等の増粘剤の1種または2種以上を用いて調整すればよい。 The pest entry inhibitor that obtains the pest invasion inhibitory effect of the present invention suppresses absorption into the soil when treated in and around the nest holes of pests such as ants, so that pests such as ants have tactile sensations and pedestrians. In order to suppress the contact with the chemical treatment surface and to sufficiently exert the effect of reliably inhibiting the entry of pests such as ants into the chemical treatment surface, a liquid solution having a viscosity may be used. In adjusting the viscosity, for example, glycerin, xanthan, xanthan gum, pectin, gum arabic, guar gum, agar, cellulose and derivatives thereof, starch and derivatives thereof, carboxyalkaliates, polyacrylates, polymaleates, polyvinyl alcohol, What is necessary is just to adjust using 1 type, or 2 or more types of thickeners, such as polyvinylpyrrolidone and a carboxy vinyl polymer.
固形剤とするには、例えば、クレー、タルク、炭酸カルシウム、ベントナイト、ジークライト、セリサイト、酸性白土、珪石、ケイソウ土、ゼオライト、カオリン、ホワイトカーボン、塩化カルシウム、塩化カリウム、硫酸アンモニウム、植物粉末(例えば、小麦粉、大豆粉、おが屑、ヤシ殻等)、グルコース、フルクトース、マルトース、シュークロース、ラクトース等の単糖類、二糖類、多糖類等の1種または2種以上を用い調製、製造することができる。 Examples of the solid agent include clay, talc, calcium carbonate, bentonite, dikelite, sericite, acid clay, silica stone, diatomaceous earth, zeolite, kaolin, white carbon, calcium chloride, potassium chloride, ammonium sulfate, plant powder ( For example, wheat flour, soybean flour, sawdust, coconut shell, etc.), glucose, fructose, maltose, sucrose, lactose and other monosaccharides, disaccharides, polysaccharides etc. it can.
さらに必要に応じて公知の殺菌剤、防カビ剤、殺虫殺ダニ剤、除草剤等の薬剤として、例えば、ビテルタノール、ブロムコナゾール、シプロコナゾール、ジフェノコナゾール、ヘキサコナゾール、イマザリル、ミクロブタニル、シメコナゾール、テトラコナゾール、チアベンダゾール、ペンチオピラド、マンゼブ等の殺菌剤;塩化ベンゼトニウム、塩化ベンザルコニウム、塩酸クロルヘキシジン、グルコン酸クロルヘキシジン、ヒノキチオール、フェノキシエタノール、イソプロピルメチルフェノール等の防カビ剤;除虫菊エキス、天然ピレトリン、プラレトリン、イミプロトリン、フタルスリン、アレスリン、ビフェントリン、レスメトリン、フェノトリン、シフェノトリン、ペルメトリン、サイパーメスリン、エトフェンプロックス、シフルスリン、デルタメスリン、ビフェントリン、フェンバレレート、フェンプロパトリン、エムペントリン、シラフルオフェン、トランスフルトリン、メトフルトリン、プロフルトリン等のピレスロイド系化合物、カルバリル、プロポクスル、メソミル、チオジカルブ等のカーバメート系化合物、メトキサジアゾン等のオキサジアゾール系化合物、フィプロニル等のフェニルピラゾール系化合物、アミドフルメト等のスルホンアミド系化合物、ジノテフラン、イミダクロプリド等のネオニコチノイド系化合物、クロルフェナピル等のピロール系化合物等、フェニトロチオン、ダイアジノン、マラソン、ピリダフェンチオン、プロチオホス、ホキシム、クロルピリホス、ジクロルボス等の有機リン系化合物等の殺虫剤;アラクロール、アメトリン、アミノシクロピラクロール、アミノピラリド、アミプロホスメチル、アニロホス、アシュラム、アトラジン、アジムスルフロン、ベンカルバゾン、ベスロジン、ベンフレセート、ベンスルフロンメチル、ベンスリド、ベンタゾン、ベンチオカーブ、ベンゾビシクロン、ベンゾフェナップ、ビアラホス、ビシクロピロン、ビフェノックス、ビスピリバック、ブロマシル、ブロモブチド、ブタクロール、ブタミホス、ブテナクロール、カフェンストロール、カルフェントラゾンエチル、クロメトキシニル、クロリダゾン、クロルフタリム、クロロIPC、TCTP、シンメスリン、シノスルフロン、クロジナホップ、クロマゾン、クロメプロップ、クロピラリド、CNP、クミルロン、シアナジン、シクロスルファムロン、シハロホップブチル、ダイカンバ、ジクロベニル、ジフルフェニカン、ジメピペレート、ジメタメトリン、ジメテナミド、Pジメテナミド、ジチオピル、ジウロン、ダイムロン、エスプロカルブ、エトフメセート、エトベンザニド、エトキシスルフロン、フラザスルフロン、フェノキサプロップエチル、フェノキサスルフォン、フェントラザミド、フロラスラム、フルアジホップ、フルカルバゾンナトリウム塩、フルセトスルフロン、フルポキサム、グルホシネート、グリホサートアンモニウム塩、グリホサートイソプロピルアミン塩、グリホサートカリウム塩、グリホサートナトリウム塩、グリホサートトリメシウム塩、ハロスルフロンメチル、ヘキサジノン、イマザモックス、イマザピル、イマゼタピル、イマザキン、イマゾスルフロン、インダノファン、インダジフラム、ヨードスルフロンメチルナトリウム塩、アイオキシニル、イプフェンカルバゾン、イソプロチュロン、イソウロン、イソキサベン、イソキサフルトール、カルブチレート、レナシル、リニュロン、MCC、MCPA、MCPB、MCPP、メフェナセット、メソスルフロンメチル、メソトリオン、メタミホップ、メタミトロン、メタゾスルフロン、メチオゾリン、メチルダイムロン、メトラクロール、メトリブジン、メトスルフロンメチル、モリネート、モノスルフロン、モノスルフロンメチル、ナプロアニリド、ナプロパミド、ニコスルフロン、ノルフルラゾン、オルソベンカーブ、オルソスルファムロン、オキサジアルギル、オキサジアゾン、オキサジクロメホン、ペンディメタリン、ペノキススラム、ペントキサゾン、フェンメディファム、ピコリナフェン、ピノキサデン、プレチラクロール、プロジアミン、プロメトリン、プロパニル、プロピソクロール、プロポキシカルバゾンナトリウム塩、プロピリスルフロン、プロピザミド、ピラクロニル、ピラスルホトール、ピラゾリネート、ピラゾスルフロンエチル、ピラゾキシフェン、ピリブチカルブ、ピリフタリド、ピリミノバックメチル、ピリミスルファン、ピロキサスルホン、ピロキシスラム、キンクロラック、キノクラミン、キザロホップエチル、サフルフェナシル、セトキシジム、シデュロン、シマジン、シメトリン、スルフォスルフロン、テブティウロン、テフリルトリオン、テンボトリオン、テプラロキシジム、ターバシル、テトラピオン、テニルクロール、チアザフルロン、チエンカルバゾンメチル、チフェンスルフロンメチル、トプラメゾン、トリアファモン、トリフロキシスルフロン、トリフルラリン、2,4−PA、d−リモネン等の除草剤の1種または2種以上を用いることができる。 Further, if necessary, as known fungicides, fungicides, insecticides, acaricides, herbicides, etc., for example, vitertanol, bromconazole, cyproconazole, difenoconazole, hexaconazole, imazalyl, microbutanyl, cimeconazole, Bactericides such as tetraconazole, thiabendazole, penthiopyrad, manzeb; fungicides such as benzethonium chloride, benzalkonium chloride, chlorhexidine hydrochloride, chlorhexidine gluconate, hinokitiol, phenoxyethanol, isopropylmethylphenol; insecticide chrysanthemum extract, natural pyrethrin, praretrin, Imiprotolin, phthalthrin, allethrin, bifenthrin, resmethrin, phenothrin, ciphenothrin, permethrin, cypermethrin, etofenprox, ci Ruslin, deltamethrin, bifenthrin, fenvalerate, fenpropatoline, empentrin, silafluorophene, pyrethroid compounds such as transfluthrin, methfluthrin, profluthrin, carbamate compounds such as carbaryl, propoxl, mesomil, thiodicarb, and oxadiazoles such as methoxadiazone Compounds, phenylpyrazole compounds such as fipronil, sulfonamide compounds such as amidoflumet, neonicotinoid compounds such as dinotefuran and imidacloprid, pyrrole compounds such as chlorfenapyr, fenitrothion, diazinon, marathon, pyridafenthion, prothiophos, oxime, chlorpyrifos , Pesticides such as organophosphorus compounds such as dichlorvos; alachlor, ametri , Aminocyclopyrachlor, aminopyralide, amiprophosmethyl, anilophos, ashram, atrazine, azimusulfuron, bencarbazone, bethrosin, benfrecetate, bensulfuronmethyl, bensulide, bentazone, beniocarb, benzobicyclone, benzofenap, bialaphos, bicyclopyrone , Bifenox, bispyribac, bromacil, bromobutide, butachlor, butamifos, butenachlor, carfentrol, carfentrazone ethyl, clomethoxynil, chloridazon, chlorphthalim, chloro IPC, TCTP, simmesline, sinosulfurone, clodinahop, clomazone, clopiramil, P Cyanadine, cyclosulfamuron, cihalohop butyl , Dicamba, diclobenil, diflufenican, dimepiperate, dimetamethrin, dimethenamide, P-dimethenamide, dithiopyr, diuron, dimeron, eprocarb, etofumesate, etobenzanide, ethoxysulfuron, flazasulfuron, phenoxapropofol , Flucarbazone sodium salt, flucetosulfuron, flupoxam, glufosinate, glyphosate ammonium salt, glyphosate isopropylamine salt, glyphosate potassium salt, glyphosate sodium salt, glyphosate trimesium salt, halosulfuron methyl, hexazinone, imazamox, imazapyr, imazetapyr, imazaquin , Imazosulfuron, indanophan, Dandifram, iodosulfuron methyl sodium salt, ioxynil, ipfencarbazone, isoproturon, isouron, isoxaben, isoxaflutol, carbbutyrate, renacil, linuron, MCC, MCPA, MCPB, MCPP, mefenacet, mesosulfuron methyl, mesotrione , Metamihop, Metamitron, Metazosulfuron, Methiozoline, Methyl dimulone, Metolachlor, Metrivudine, Metosulfuron methyl, Molinate, Monosulfuron, Monosulfuron methyl, Naproanilide, Napropamide, Nicosulfuron, Norflurazon, Orthovencurve, Orthosulfamlone, Oxadiargyloxa , Oxadichrome mehon, pendimethalin, penox slam, pentoxazone Fenmedifam, picolinaphene, pinoxaden, pretilachlor, prodiamine, promethrin, propanyl, propisochlor, propoxycarbazone sodium salt, propyrisulfuron, propyzamide, pyraclonyl, pyrasulfol, pyrazolinate, pyrazosulfuron ethyl, pyrazoxifene, pyributicarb Pyriphthalide, Pyriminobacmethyl, Pyrisulfuran, Piroxasulfone, Pyroxislam, Quinclorac, Quinoclamine, Quizalofopethyl, Saflufenacyl, Cetoxidim, Ciduron, Simazine, Cimetrin, Sulfosulfurone, Tebutiuron, Tefriltrione, Tembrion, Tepra Roxydim, Turbacil, Tetrapion, Tenylchlor, Thiazaflulone, Thiencarbazone One or more herbicides such as methyl, thifensulfuron methyl, topramezone, triafamon, trifloxysulfuron, trifluralin, 2,4-PA, d-limonene can be used.
本発明の対象となる害虫を、以下に例示する。
アリ類(クロヤマアリ、トビイロシワアリ、アミメアリ、クロオオアリ、トビイロケアリ、オオハリアリ、ヒメアリ、クロクサアリ、イエヒメアリ、ルリアリ、オオズアリ、キイロヒメアリ、クロヒメアリ、コトビイロケアリ、ハヤシトビイロケアリ、キイロシリアゲアリ、トビイロシリアゲアリ、ハリブトシリアゲアリ、オオシワアリ、シワアリ、メクラハリアリ、トゲアリ、ムネアカオオアリ、サムライアリ、アカヤマアリ、アメイロアリ、ウメマツアリ、シワクシケアリ、エゾクシケアリ、オオズアカアリ、アズマオオズアカアリ、アシナガアリ、クロナガアリ、ムネボソアリ、フシアリ、アルゼンチンアリ、ヒアリ、アカカミアリ等)、
等脚目類(ホソワラジムシ、ワラジムシ等のワラジムシ類、オカダンゴムシ等のダンゴムシ類、フナムシ等のフナムシ類等)、
腹足類(コウラナメクジ、チャコウラナメクジ、ノナメクジ等のコウラナメクジ科、ナメクジ、ヤマナメクジ等のナメクジ科、ニワコウラナメクジ等のニワコウラナメクジ科、オカモノアラガイ等のオカモノアラガイ科、アフリカマイマイ等のアフリカマイマイ科、ウスカワマイマイ等のオナジマイマイ科、ニッポンマイマイ等のナンバンマイマイ科等のマイマイ、カタツムリ類)、
クモ類(カバキコマチグモ、セアカゴケグモ等)、
半翅目類(アオクサカメムシ、ホソヘリカメムシ、オオトゲシラホシカメムシ、トゲシラホシカメムシ、チャバネアオカメムシ、クサギカメムシ、ミナミアオカメムシ、アカスジカスミカメ、アカヒゲホソミドリカスミカメ等のカメムシ類、モモアカアブラムシ、リンゴアブラムシ、ワタアブラムシ、ニセダイコンアブラムシ等のアブラムシ類等)、
鱗翅目類(チャドクガ等のドクガ類、アメリカシロヒトリ等のヒトリガ類、マイマイガ等のマイマイガ類、ハスモンヨトウ、アワヨトウ、トリコプルシア属、ヘリオティス属、ヘリコベルパ属等のヤガ類、ニカメイガ、コブノメイガ、ワタノメイガ、ノシメマダラメイガ等のメイガ類、イガ、コイガ等のヒロズコガ類等の成虫または幼虫)、
双翅目類(ユスリカ類、タネバエ、タマネギバエ等のハナバエ類、マメハモグリバエ等のハモグリバエ類、ミバエ類、ショウジョウバエ類、クロバネキノコバエ類、ニセケバエ類、ハマベバエ類、ハヤトビバエ類、オオキモンノミバエ等のノミバエ類、オオチョウバエ等のチョウバエ類、ブユ類、アブ類、サシバエ類等)、
膜翅目類(ミナミキイロアザミウマ、ミカンキイロアザミウマ、ハナアザミウマ、アザミウマ類等)、
多足類(ゲジ、トビズムカデ等の唇脚綱類や、ヤケヤスデ、アカヤスデ等の倍脚綱類)、
ダニ目(タカラダニ類等)、
鞘翅目類(ゴミムシ等のコウチュウ目等)、
革翅目類(ハサミムシ類等)、
網翅目類(ゴキブリ目等)、
直翅目類(ケラ類、バッタ類、コオロギ類等)を例示することができる。
本発明の害虫防除剤は、これらの中でも、腹足類、等脚目類、アリ類、半翅目類に対して有効に使用することができる。
The pests that are the subject of the present invention are exemplified below.
Ants (black-backed ants, white-winged ants, sand ants, black-tailed ants, black-tailed ants, giant clams, black-tailed ants, black-headed ants, black-tailed ants, luriari, giant ants, yellow-tailed ants, black-tailed ants, black-tailed ants, red-eared ants Steller's whale, whale ant, clam harially, spider ant, muna cocoa ant, samurai ant, red ant ant, amilo ant, red pine ant, wrinkle squirrel, squirrel squirrel, giant red squirrel, azuma squirrel, red squirrel, black ant ant, red ant
Isopods (spotted beetle, slatted beetle, etc., beetle such as beetle, beetle such as beetle),
Gastropods (Coleamidae, Chachouranamakuji, Nonamekuji, etc.) Onimyidae such as Uskawa Maimai, Mymai such as Nambami Myidae such as Nippon Maimai, snails),
Spiders (Birdling spider, red spider spider, etc.),
Hemiptera (Aoksakamemushi, Hosohelikamushi, Otogeshirahoshimemushi, Togeshirahoshimemushi, Chabanaeokamushi, Kusagikamushi, Minamiokamemushi, Akajikamikamikame, Akajigemoshimikamikamome, etc. Aphids such as apple aphids, cotton aphids, fake aphids, etc.),
Lepidoptera (Spotted moths such as Chadokuga, Hitoriga such as white-spotted moth, Maimais such as mussels, Spodoptera litura, Ayayoto, Trichopulcia, Heliotis, Helicoberpa, etc., Nikamaiga, Konotomeiga, Watanomeiga, Noshimadarameiga Larvae such as Japanese moths, moths, common moths such as common moths),
Diptera (Chironomidae, Seed fly, Onion fly etc.), Flies flies such as Bean spider flies, Flies flies, Drosophila, Black fly flies, Nymphaea flies, Flies flies, Hayabobi flies, Flies , Butterflies such as giant butterflies, flyfish, fly, and fly flies),
Hymenoptera (Sciurus thrips, Citrus thrips, Hana thrips, Thrips, etc.),
Multi-legged species (lip-legged classes such as geji and tobism cadets, double-legged classes such as zelkova and red-spotted)
Tick eyes (Tacarid mites, etc.),
Coleoptera (Coleoptera, etc.),
Lepidoptera (Crustacea, etc.),
Reticulates (such as cockroaches),
Examples of the order of the order Diptera (Keras, Grasshoppers, Crickets, etc.).
Among these, the pest control agent of the present invention can be effectively used for gastropods, isopods, ants, and hemiptera.
本発明の害虫侵入阻害剤は、アリ類等の害虫が触覚や歩脚を薬剤処理面に接触させることを抑制し、薬剤処理面内に害虫が侵入することを確実に阻害するために、薬剤処理面1平方メートル当たり、ペラルゴン酸またはその塩を、好ましくは0.01〜30g、より好ましくは0.05〜25gとなる量で散布する。施用頻度は、アリ類等の害虫の発生を確認したら、1〜2週間に1回程度の頻度で施用するのがよい。施用手段は特に制限されない。
本発明の害虫侵入阻害剤は、害虫が侵入して欲しくない家屋などの建造物の入り口付近、例えば台所、勝手口、玄関、廊下、リビング、窓辺、ベランダ、ウッドデッキ、ポート、アスファルト等の家屋などの建造物周辺や駐車場等に噴霧または散布処理することにより、アリ類等の害虫が触覚や歩脚を薬剤処理面に接触させることを抑制し、薬剤処理面内にアリ類等の害虫が侵入することを確実に阻害する効果を発揮し、家屋などの建造物内や車内へのアリ類等の害虫の侵入を確実に阻害する点において極めて実用的である。
The pest invasion inhibitor of the present invention suppresses the contact of pests such as ants with the tactile sensation and the pedestal in contact with the drug-treated surface, and reliably inhibits the entry of pests into the drug-treated surface. Pelargonic acid or a salt thereof is preferably sprayed in an amount of 0.01 to 30 g, more preferably 0.05 to 25 g per square meter of the treated surface. As for the frequency of application, once the occurrence of pests such as ants is confirmed, it is preferable to apply it once every 1-2 weeks. The application means is not particularly limited.
The pest entry inhibitor of the present invention is near the entrance of a building such as a house where a pest does not want to invade, such as a house such as a kitchen, a doorway, an entrance, a hallway, a living room, a window, a veranda, a wood deck, a port, and asphalt. By spraying or spraying around buildings, parking lots, etc., pests such as ants are prevented from touching the tactile sense and pedestrians with the drug treatment surface, and pests such as ants are present in the drug treatment surface. It is extremely practical in that it exerts an effect of reliably inhibiting the invasion and reliably inhibits the entry of pests such as ants into a building such as a house or a vehicle.
以下に実施例によって本発明をさらに詳しく説明するが、本発明はこれらに限定されるものではない。 EXAMPLES The present invention will be described in more detail with reference to examples below, but the present invention is not limited to these examples.
<試験検体の調製1>
表1記載の組成からなる試験検体を調製し、実施例1〜6および比較例1とした。
試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
実施例1〜6は、ペラルゴン酸と25%アンモニア水とが中和してペラルゴン酸のアンモニウム塩を形成し、有効成分として作用する。
<Test sample preparation 1>
Test specimens having the compositions shown in Table 1 were prepared and used as Examples 1 to 6 and Comparative Example 1.
In preparing the test specimen, each component was mixed and stirred with a magnetic stirrer so that the composition became uniform.
In Examples 1 to 6, pelargonic acid and 25% aqueous ammonia are neutralized to form an ammonium salt of pelargonic acid, which acts as an active ingredient.
<殺虫試験1>
表2記載の各種害虫を対象として殺虫試験1を実施した。試験の概要は図1に示した。
≪アリ類・等脚目類・ナメクジ殺虫試験≫
内径100mm、高さ45mmのプラスチック製カップ(商品名:KP−200(鴻池プラスチック社製))の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記カップ内に供試虫5頭を放ち、10cmの距離から各試験検体2mLを噴霧器で処理した。処理後、供試虫を清潔なプラスチック製カップに移し、12時間後に致死数を計数し、下記式にて致死率(%)を算出した。試験は、25℃、明るい条件下にて行い、3回の平均値を致死率(%)として表2に記載した。
≪カメムシ殺虫試験≫
上記「アリ類・等脚目類・ナメクジ殺虫試験」と同様に、チャバネアオカメムシ、クサギカメムシ、ミナミアオカメムシ、ホソヘリカメムシは供試虫を3〜5頭とし、24時間後の致死数を計数し、下記式にて致死率(%)を算出した。試験は、25℃、明るい条件下にて1回行った。
≪ニッポンマイマイ殺虫試験≫
上記「アリ類・等脚目類・ナメクジ殺虫試験」と同様に、ニッポンマイマイは供試虫を1頭とし、12時間後の致死を確認し、下記式にて致死率(%)を算出した。試験は、25℃、明るい条件下にて1回行った。
≪トビズムカデ殺虫試験≫
内径130mm、高さ100mmのプラスチック製カップ(商品名:KP−860MB(鴻池プラスチック社製))の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記カップ内に供試虫1頭を放ち、10cmの距離から各試験検体6mLを噴霧器で処理した。処理後、供試虫を清潔なプラスチック製カップに移し、24時間後に致死を確認し、下記式にて致死率(%)を算出した。試験は、25℃、明るい条件下にて1回行った。
[式]:致死率(%)=致死した供試虫数/全供試虫数×100
<Insecticide test 1>
Insecticidal test 1 was conducted on various pests described in Table 2. The outline of the test is shown in FIG.
≪Antys, Isopods, Slug Insect Test≫
Calcium carbonate was applied to the upper part of the inner wall surface of a plastic cup (trade name: KP-200 (manufactured by Konoike Plastics)) having an inner diameter of 100 mm and a height of 45 mm so that no insects escape. Five test insects were released into the cup, and 2 mL of each test sample was treated with a sprayer from a distance of 10 cm. After the treatment, the test insects were transferred to a clean plastic cup, the number of lethals was counted after 12 hours, and the lethality (%) was calculated by the following formula. The test was performed at 25 ° C. under bright conditions, and the average of three times was shown in Table 2 as the mortality rate (%).
≪Snail insecticide test≫
In the same manner as the above-mentioned “Anteles, Isopods, and Slug Insect Testing”, 3 to 5 test insects were used for each of the Chabanae stink bugs, Kusagi stink bugs, Minamia stink bugs, and Hosoheli stink bugs. Counting was performed, and lethality (%) was calculated by the following formula. The test was performed once at 25 ° C. under bright conditions.
≪Nippon Maimai insecticide test≫
In the same manner as the above-mentioned “ant, isopod, slug insecticide test”, Nippon Maimai confirmed the lethality 12 hours later and calculated the lethality (%) by the following formula. . The test was performed once at 25 ° C. under bright conditions.
≪Tobism cadet insecticide test≫
Calcium carbonate was applied to the upper part of the inner wall surface of a plastic cup (trade name: KP-860MB (manufactured by Tsugaike Plastic Co., Ltd.)) having an inner diameter of 130 mm and a height of 100 mm so that no insects escape. One test insect was released into the cup, and 6 mL of each test specimen was treated with a sprayer from a distance of 10 cm. After the treatment, the test insects were transferred to a clean plastic cup. After 24 hours, lethality was confirmed, and the lethality (%) was calculated by the following formula. The test was performed once at 25 ° C. under bright conditions.
[Formula]: lethality rate (%) = number of dead test insects / total number of test insects × 100
表2に示したとおり、本発明のペラルゴン酸のアンモニウム塩を有効成分とした実施例1の害虫防除剤は、各種害虫に対して優れた殺虫効果を奏することが明らかとなった。 As shown in Table 2, it was revealed that the pest control agent of Example 1 comprising the ammonium salt of pelargonic acid of the present invention as an active ingredient has an excellent insecticidal effect against various pests.
実施例1と同様にして、表1に記載した実施例2〜6について各種害虫に対する殺虫効果を確認した結果、以下のとおり優れた殺虫効果を奏することが確認された。
クロヤマアリ、クサギカメムシ、ミナミアオカメムシ、ホソヘリカメムシに対して実施例2を処理した結果、致死率は93.3%、100%、100%および100%であった。
ニッポンマイマイ、ホソヘリカメムシに対して、実施例3を処理した結果、いずれも致死率は100%であった。
ダンゴムシ、ワラジムシに対して実施例3〜4を処理した結果、いずれも致死率は100%であった。
ダンゴムシ、ワラジムシおよびナメクジに対して実施例5を処理した結果、致死率は、80%、86.7%および100%であった。
ダンゴムシ、ナメクジに対して実施例6を処理した結果、致死率は、73.3%、93%であった。
As in Example 1, as a result of confirming the insecticidal effect against various pests in Examples 2 to 6 described in Table 1, it was confirmed that the following excellent insecticidal effect was exhibited.
As a result of the treatment of Example 2 against the black ant, the black bug, the southern blue bug, and the white bug, the mortality rate was 93.3%, 100%, 100% and 100%.
As a result of processing Example 3 on Nippon Maimai and Hosohelikamushi, the mortality was 100% in both cases.
As a result of processing Example 3-4 with respect to a common rubber leaf and a common beetle, the mortality rate was 100% in all.
As a result of the treatment of Example 5 against common rubber beetles, rotifers and slugs, the mortality rates were 80%, 86.7% and 100%.
As a result of processing Example 6 on the rubber tree and slug, the mortality was 73.3% and 93%.
<試験検体の調製2>
表3記載の組成からなる試験検体を調製し、実施例7〜9とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Test sample preparation 2>
Test specimens having the compositions described in Table 3 were prepared and designated as Examples 7-9. In preparing the test specimen, each component was mixed and stirred with a magnetic stirrer so that the composition became uniform.
<忌避試験1>
表4記載の各種害虫を対象として忌避試験1を実施した。試験の概要は図2に示した。
縦25cm、横30cm、高さ10cmのプラスチック製容器の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記容器内には、供試虫の餌場として、水を含浸した脱脂綿または固形餌を2ヵ所設置した。次に直径5.5cm、ナメクジ対象のみ直径7cmのろ紙に実施例7〜9と対照(アセトン100%)を各2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。
次に、容器内に供試虫を放ち、30分後の定着数を計数し、下記式にて忌避率(%)を算出した。試験は、25℃、明るい条件下にて行い、2回の平均値を忌避率(%)として表4に記載した。
試験では、クロヤマアリおよびアミメアリは各50頭、ダンゴムシおよびワラジムシは各40頭、ナメクジは20頭を用いた。
忌避率(%)={1−(試験検体定着数)/(試験検体定着数+対照定着数)}×100
以後、式中の「試験検体」とは、実施例または比較例の検体を意味する。
<Repellent test 1>
The repellent test 1 was conducted on various pests described in Table 4. The outline of the test is shown in FIG.
Calcium carbonate was applied to the upper part of the inner wall surface of a plastic container having a length of 25 cm, a width of 30 cm, and a height of 10 cm so that pests would not escape. Two absorbent cottons or solid baits impregnated with water were installed in the container as feed for test insects. Next, 2 mL each of Examples 7 to 9 and a control (100% acetone) were impregnated into a filter paper having a diameter of 5.5 cm and a slug target only to a diameter of 7 cm, and the filter paper was placed so as to surround the feeding area.
Next, the test insects were released into the container, the number of colonies after 30 minutes was counted, and the repelling rate (%) was calculated by the following formula. The test was performed under 25 degreeC and bright conditions, and the average value of 2 times was described in Table 4 as the repelling rate (%).
In the test, 50 black ants and red ants were used each, 40 stag beetles and rotifers were used each, and 20 slugs were used.
Repelling rate (%) = {1− (number of fixed test specimen) / (number of fixed test specimen + number of fixed control)} × 100
Hereinafter, the “test sample” in the formula means the sample of the example or the comparative example.
表4に示したとおり、本発明のペラルゴン酸を有効成分とした害虫防除剤は、各種害虫に対して優れた忌避効果を奏することが明らかとなった。 As shown in Table 4, it was revealed that the pest control agent containing the pelargonic acid of the present invention as an active ingredient has an excellent repellent effect against various pests.
<試験検体の調製3>
表5記載の組成からなる試験検体を調製し、実施例10、比較例2とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Test sample preparation 3>
Test specimens having the compositions described in Table 5 were prepared and used as Example 10 and Comparative Example 2. In preparing the test specimen, each component was mixed and stirred with a magnetic stirrer so that the composition became uniform.
<腹足類防除試験1>
チャコウラナメクジを対象として腹足類防除試験1を実施した。試験の概要は図1に示した。
内径100mm、高さ45mmのプラスチック製カップ(商品名:KP−200(鴻池プラスチック社製))の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記カップ内に供試虫1頭を放ち、10cmの距離から実施例10、比較例2の各試験検体3mLを噴霧器で処理した。処理後、供試虫を観察し完全停止するまでの時間(FT:秒)を測定した。また、チャコウラナメクジの粘液脱ぎ捨て行動の有無、逃亡行動の有無、15分後および24時間後の致死について確認し、その結果を表6に記載した。
表6中の「無」は粘液脱ぎ捨て行動や逃亡行動が無かったことを、「有」は粘液脱ぎ捨て行動や逃亡行動があったことを、「〇」は致死していたことを、「×」は生存していたことを意味する。
<Gastropod control test 1>
A gastropod control test 1 was conducted on a Japanese black-tailed slug. The outline of the test is shown in FIG.
Calcium carbonate was applied to the upper part of the inner wall surface of a plastic cup (trade name: KP-200 (manufactured by Konoike Plastics)) having an inner diameter of 100 mm and a height of 45 mm so that no insects escape. One test insect was released into the cup, and 3 mL of each test sample of Example 10 and Comparative Example 2 was treated with a sprayer from a distance of 10 cm. After the treatment, the test insects were observed and the time until complete stop (FT: seconds) was measured. In addition, the presence or absence of mucus removal behavior, escape behavior, lethality after 15 minutes and 24 hours was confirmed for Chakoura slugs, and the results are shown in Table 6.
“No” in Table 6 indicates that there was no mucus removal or escape behavior, “Yes” indicates that there was mucus removal behavior or escape behavior, and “〇” indicates that it was fatal, “×” Means alive.
一般的に、ナメクジ等の腹足類は、ピレスロイド系殺虫剤を体表に処理しても、体表の粘液を脱ぎ捨てることにより殺虫効果が得られにくいことが知られている。
表6の実施例10の結果より明らかなように、ペラルゴン酸は処理してから行動を完全停止するまでの時間(FT)が191秒(約3分程度)であり、粘液の脱ぎ捨て行動や逃亡行動が見られず、15分以内に致死することが確認された。
一方、比較例2のピレスロイド系殺虫剤の1つであるピレトリンを処理した場合は、公知技術のとおり、体表の粘液脱ぎ捨て行動や逃亡行動が見られ、24時間後も致死しなかった。
表6に示したとおり、本発明のペラルゴン酸を有効成分とした害虫防除剤は、公知のピレスロイド系殺虫剤では得られない、確実に致死活性が得られる、ナメクジ等の腹足類に対する優れた防除効果を発揮することが明らかとなった。
In general, it is known that gastropods such as slugs are difficult to obtain the insecticidal effect by removing the mucus on the body surface even if the body surface is treated with a pyrethroid insecticide.
As is clear from the results of Example 10 in Table 6, the time (FT) from the treatment of pelargonic acid to the complete stop of the action (FT) is 191 seconds (about 3 minutes), and the mucus is removed and escaped. No action was seen, and it was confirmed that it would be fatal within 15 minutes.
On the other hand, when pyrethrin, which is one of the pyrethroid insecticides of Comparative Example 2, was treated, as was known in the art, mucus removal and escape behavior on the body surface were observed, and even after 24 hours, no death occurred.
As shown in Table 6, the pest control agent comprising the pelargonic acid of the present invention as an active ingredient is an excellent control effect on gastropods such as slugs, which is not obtained with known pyrethroid insecticides, and can surely obtain lethal activity. It was revealed that
<試験検体の調製4>
表7記載の組成からなる試験検体を調製し、実施例11、比較例3、4とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Test sample preparation 4>
Test specimens having the compositions described in Table 7 were prepared and used as Example 11 and Comparative Examples 3 and 4. In preparing the test specimen, each component was mixed and stirred with a magnetic stirrer so that the composition became uniform.
<腹足類防除試験2>
チャコウラナメクジを対象として腹足類防除試験2を実施した。試験の概要は図1に示した。
上記「腹足類防除試験1」と同様に試験を行った。処理後、供試虫を観察し完全停止するまでの時間(FT:秒)を測定した。また、チャコウラナメクジの粘液脱ぎ捨て行動の有無、逃亡行動の有無、15分後および24時間後の致死について確認し、その結果を表8に記載した。
表8中の「無」は粘液脱ぎ捨て行動や逃亡行動が無かったことを、「有」は粘液脱ぎ捨て行動や逃亡行動があったことを、「有*」は粘液脱ぎ捨て行動はあるが完全に脱ぎ捨てられずにいたことを、「〇」は致死していたことを、「×」は生存していたことを意味する。
<Gastropod control test 2>
A gastropod control test 2 was conducted on the Japanese black slug. The outline of the test is shown in FIG.
The test was conducted in the same manner as in the above “Gastropod control test 1”. After the treatment, the test insects were observed and the time until complete stop (FT: seconds) was measured. In addition, the presence or absence of mucus removal behavior, the presence or absence of escape behavior, and lethality after 15 minutes and 24 hours were confirmed, and the results are shown in Table 8.
“No” in Table 8 indicates that there was no mucus removal or escape behavior, “Yes” indicates that there was mucus removal behavior or escape behavior, and “Yes *” indicates that there was mucus removal behavior but was completely removed. “○” means being dead, “×” means being alive.
上述したとおり、ピレスロイド系殺虫剤をナメクジ等の腹足類の体表に処理しても、体表の粘液を脱ぎ捨てることにより殺虫効果が得られにくいが、天然系成分の中には、例えば、L−カルボンのように体表の粘液脱ぎ捨て行動を阻害し致死させるものが存在する一方で、リモネンのように体表の粘液脱ぎ捨て行動を阻害できない成分があることも知られている。
表8の実施例11の結果より明らかなように、ペラルゴン酸は処理してから行動を完全停止するまでの時間(FT)が240秒(約4分程度)であり、粘液の脱ぎ捨て行動や逃亡行動が見られず、15分以内に致死した。
一方、体表の粘液脱ぎ捨て行動を阻害し致死させることが公知のL−カルボンを処理した場合には、ペラルゴン酸処理と同様に逃亡行動は見られず、15分以内に致死したが、体表の粘液脱ぎ捨て行動が見られ、行動を完全停止するまでの時間(FT)が425秒(7分以上)であった。また、リモネンを処理した場合には、体表の粘液脱ぎ捨て行動や逃亡行動が見られ、24時間後も致死に至らなかった。
表8に示したとおり、本発明のペラルゴン酸を有効成分とした害虫防除剤は、L−カルボン等の公知の腹足類駆除剤よりも優れた防除効果が得られることが明らかとなった。
As described above, even if the pyrethroid insecticide is treated on the body surface of gastropods such as slugs, it is difficult to obtain an insecticidal effect by removing the mucus on the body surface, but some of the natural components include, for example, L- It is also known that there is a component that cannot inhibit the mucus removal action on the body surface, such as limonene, while there is a substance that inhibits and kills the mucus removal action on the body surface, such as carvone.
As is apparent from the results of Example 11 in Table 8, the time (FT) from the treatment to the complete stop of the action (FT) after treatment with pelargonic acid is 240 seconds (about 4 minutes). No action was seen and he died within 15 minutes.
On the other hand, when L-carvone known to inhibit and kill lethal mucus on the body surface was treated, escape behavior was not seen as in the case of pelargonic acid treatment, but it was fatal within 15 minutes. The mucus was removed, and the time (FT) until the behavior was completely stopped was 425 seconds (7 minutes or more). In addition, when limonene was treated, mucus removal and escape behavior were observed on the body surface, and it was not lethal after 24 hours.
As shown in Table 8, it was clarified that the pest control agent containing the pelargonic acid of the present invention as an active ingredient can obtain a control effect superior to known gastropod control agents such as L-carvone.
<試験検体の調製5>
表9記載の組成からなる試験検体を調製し、実施例12、比較例5とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Test sample preparation 5>
Test specimens having the compositions described in Table 9 were prepared and used as Example 12 and Comparative Example 5. In preparing the test specimen, each component was mixed and stirred with a magnetic stirrer so that the composition became uniform.
<アリ類忌避試験1>
表10記載のアリ類を対象としてアリ類忌避試験1を実施した。試験の概要は図2に示した。
縦25cm、横30cm、高さ10cmのプラスチック製容器の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記容器内には、供試虫の餌場として、水を含浸した脱脂綿を2ヵ所設置した。次に直径5.5cmのろ紙に実施例12または比較例5と対照(アセトン100%)を各2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。
次に、容器内に供試虫(50頭)を放ち、30分後の餌場への定着数を計数し、下記式にて忌避率(%)を算出した。
また、試験検体を含浸させたろ紙に対する侵入回避効果(試験検体を含浸させたろ紙に対しアリ類が触覚や歩脚を接触すらさせることなくろ紙の前からUターンする行動を促す効果)の有無についても、確認した。試験は、25℃、明るい条件下にて行い、忌避率(%)として表10に記載した。
忌避率(%)={1−(試験検体定着数)/(試験検体定着数+対照定着数)}×100
表10中の「有」は侵入回避効果が認められたことを、「無」は侵入回避効果が認められなかったことを意味する。
<Antial repellent test 1>
An ant repellent test 1 was performed on the ants described in Table 10. The outline of the test is shown in FIG.
Calcium carbonate was applied to the upper part of the inner wall surface of a plastic container having a length of 25 cm, a width of 30 cm, and a height of 10 cm so that pests would not escape. Two absorbent cottons impregnated with water were installed in the container as feeding sites for the test insects. Next, a filter paper having a diameter of 5.5 cm was impregnated with 2 mL each of Example 12 or Comparative Example 5 and the control (100% acetone), and the filter paper was placed so as to surround the feeding area.
Next, test insects (50) were released into the container, the number of colonies in the feeding area 30 minutes later was counted, and the repelling rate (%) was calculated by the following formula.
In addition, there is an invasion avoidance effect on the filter paper impregnated with the test specimen (an effect of urging the U-turn from the front of the filter paper without causing the ants to touch the tactile sense or the pedestal to the filter paper impregnated with the test specimen) Also confirmed. The test was performed at 25 ° C. under bright conditions, and the repelling rate (%) is shown in Table 10.
Repelling rate (%) = {1− (number of fixed test specimen) / (number of fixed test specimen + number of fixed control)} × 100
“Yes” in Table 10 means that the intrusion avoidance effect is recognized, and “No” means that the intrusion avoidance effect is not recognized.
表10の実施例12の結果より明らかなように、ペラルゴン酸はクロヤマアリ、アミメアリのアリ類の種類に関わらず忌避率が100%であり、優れた忌避効果を奏することが確認された。これに対し、ピレスロイド系殺虫剤のフェンプロパトリンは忌避率が50%未満であり、しかもクロヤマアリとアミメアリのようにアリ類の種類により忌避効果に差があった。
さらに、ペラルゴン酸を含浸させたろ紙に対する侵入回避効果をも有することが確認された一方、フェンプロパトリンを含浸させたろ紙に対する、侵入回避効果は認められなかった。
表10に示したとおり、本発明のペラルゴン酸を有効成分とした害虫防除剤は、ピレスロイド系殺虫剤よりも優れたアリ類忌避効果および薬剤処理面内に対する侵入回避効果を発揮することが明らかとなった。
As is clear from the results of Example 12 in Table 10, pelargonic acid has a repellent rate of 100% regardless of the species of black ants and ants, and it was confirmed that the repellent effect was excellent. On the other hand, the repellent rate of the pyrethroid insecticide fenpropatoline was less than 50%, and the repellent effect was different depending on the kind of ants such as black ants and red ants.
Furthermore, while it was confirmed that the filter paper impregnated with pelargonic acid also had an invasion avoidance effect, no invasion avoidance effect was observed for the filter paper impregnated with fenpropatoline.
As shown in Table 10, it is clear that the pest control agent containing the pelargonic acid of the present invention as an active ingredient exhibits an ant repellent effect and an invasion avoidance effect on the surface of the drug treatment superior to the pyrethroid insecticide. became.
上記「アリ類忌避試験1」において確認された、アリ類侵入回避効果について、詳しく調査するため以下の「アリ類侵入阻害確認試験」と「アリ類侵入阻害詳細確認試験」を行った。
<試験検体の調製6>
下記表11記載の組成からなる試験検体を調製し、実施例13、比較例6〜11とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
The following “ant invasion inhibition confirmation test” and “ant invasion inhibition detailed confirmation test” were conducted in order to investigate in detail the ant invasion avoidance effect confirmed in the “ant repellent test 1”.
<Test sample preparation 6>
Test specimens having the compositions described in Table 11 below were prepared and used as Example 13 and Comparative Examples 6-11. In preparing the test specimen, each component was mixed and stirred with a magnetic stirrer so that the composition became uniform.
<アリ類侵入阻害確認試験>
試験の概要は図3に示す。
縦15cm、横20cm、高さ10cmのプラスチック製容器の内壁面上部にアリ類が逃亡しないよう炭酸カルシウムを施した。前記容器内には、アリ類の餌場として、水を含浸した脱脂綿を1ヵ所設置した。次に直径5.5cmのろ紙に試験検体をそれぞれ2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。
次に、容器内にアリ類(クロヤマアリ、10頭)を放ち、ろ紙上に侵入したアリ類の数を(a)侵入回数として、10分間カウントした。試験は、25℃、明るい条件下にて行った。
この(a)侵入回数は、触覚や歩脚を当該ろ紙に接触させ、さらに前進してろ紙内に侵入した回数を意味する。
上記試験検体の組成とそれぞれの(a)侵入回数を表11に示した。
<Anty invasion inhibition confirmation test>
The outline of the test is shown in FIG.
Calcium carbonate was applied to the upper part of the inner wall surface of a plastic container 15 cm long, 20 cm wide and 10 cm high so that ants would not escape. One absorbent cotton impregnated with water was installed in the container as a feeding ground for ants. Next, 2 mL of each test specimen was impregnated into a filter paper having a diameter of 5.5 cm, and the filter paper was placed so as to surround the feeding area.
Next, ants (black ants, 10) were released in the container, and the number of ants that entered the filter paper was counted as (a) the number of intrusions for 10 minutes. The test was performed at 25 ° C. under bright conditions.
This (a) number of intrusions means the number of times the tactile sensation or the pedestal is brought into contact with the filter paper and further advanced to enter the filter paper.
Table 11 shows the composition of the test specimen and the number of intrusions for each (a).
表11の実施例13の結果より明らかなように、ペラルゴン酸を含浸させたろ紙上にアリ類は侵入することが全くなく、優れた侵入阻害効果を発揮することが確認された。これに対し、ペラルゴン酸と同じ飽和脂肪酸である酪酸(比較例6)を含浸させたろ紙上にアリ類が10分間に49回、カプリル酸(比較例7)を含浸させたろ紙上に25回、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸(比較例8〜11)は、それぞれを含浸させたろ紙上に13〜15回侵入しており、ペラルゴン酸とは異なり侵入阻害効果を示さないことも明らかとなった。
ペラルゴン酸は、酪酸、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸と炭素数のみが相違する飽和脂肪酸であるが、薬剤処理面内にアリ類が一度も侵入しない、すなわち、薬剤処理面内への侵入阻害効果を発揮する点において、他の脂肪酸と大きく相違することが確認された。
ペラルゴン酸が有する優れた薬剤処理面内への侵入阻害効果は、本発明者が多くの実験を行い初めて確認した格別顕著な効果である。
As is clear from the results of Example 13 in Table 11, it was confirmed that ants did not penetrate at all on the filter paper impregnated with pelargonic acid and exhibited an excellent penetration inhibiting effect. In contrast, ants were 49 times in 10 minutes on filter paper impregnated with butyric acid (Comparative Example 6), the same saturated fatty acid as pelargonic acid, and 25 times on filter paper impregnated with caprylic acid (Comparative Example 7). , Capric acid, lauric acid, myristic acid, palmitic acid (Comparative Examples 8 to 11) have invaded 13 to 15 times on the filter paper impregnated with each of them, and unlike pelargonic acid, does not show an invasion inhibitory effect It became clear.
Pelargonic acid is a saturated fatty acid that differs from butyric acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid only in carbon number, but ants do not enter the drug-treated surface at all, that is, drug treatment It was confirmed that the fatty acid is greatly different from other fatty acids in that it exerts an in-plane penetration inhibiting effect.
The excellent inhibitory effect of pelargonic acid on the surface treated with a drug is a particularly remarkable effect that the present inventor has confirmed for the first time through many experiments.
<試験検体の調製7>
下記表12記載の組成からなる試験検体を調製し、実施例14、比較例12〜15とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test sample 7>
Test specimens having the compositions described in Table 12 below were prepared and used as Example 14 and Comparative Examples 12-15. In preparing the test specimen, each component was mixed and stirred with a magnetic stirrer so that the composition became uniform.
<アリ類侵入阻害詳細確認試験>
試験の概要は図3に示す。
縦15cm、横20cm、高さ10cmのプラスチック製容器の内壁面上部にアリ類が逃亡しないよう炭酸カルシウムを施した。前記容器内には、アリ類の餌場として、水を含浸した脱脂綿を1ヵ所設置した。次に直径5.5cmのろ紙に試験検体をそれぞれ2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。
次に、容器内にアリ類(クロヤマアリ、10頭)を放ち、ろ紙に接近したアリ類の行動を観察した。ろ紙に触覚や歩脚を接触させることなくUターンしたアリ類の数を(b)侵入回避回数、ろ紙に触覚や歩脚を接触させたが、ろ紙に侵入することなくUターンしたアリ類の数を(c)接触後回避回数として、10分間カウントした。また、(b)侵入回避回数と(c)接触後回避回数の和を(d)侵入阻害回数とした。さらに、(d)侵入阻害回数における(b)侵入回避回数の割合を「侵入回避率(%)」とした。
試験は、25℃、明るい条件下にて行った。
上記試験検体の組成とそれぞれの(b)侵入回避回数、(c)接触後回避回数、(d)侵入阻害回数、侵入回避率(%)を表12に示した。
<Detailed confirmation test for ant invasion inhibition>
The outline of the test is shown in FIG.
Calcium carbonate was applied to the upper part of the inner wall surface of a plastic container 15 cm long, 20 cm wide and 10 cm high so that ants would not escape. One absorbent cotton impregnated with water was installed in the container as a feeding ground for ants. Next, 2 mL of each test specimen was impregnated into a filter paper having a diameter of 5.5 cm, and the filter paper was placed so as to surround the feeding area.
Next, the ants (10 black ants) were released into the container, and the behavior of the ants approaching the filter paper was observed. The number of ants that have made a U-turn without touching the filter paper with a tactile sensation or a pedestal (b) The number of intrusion avoidances. The number was counted for 10 minutes as (c) number of avoidance after contact. Further, the sum of (b) invasion avoidance count and (c) after-contact avoidance count was defined as (d) intrusion inhibition count. Further, the ratio of (d) invasion avoidance frequency to (d) invasion inhibition frequency was defined as “invasion avoidance rate (%)”.
The test was performed at 25 ° C. under bright conditions.
Table 12 shows the composition of the test specimen and (b) the number of times of invasion avoidance, (c) the number of times of avoidance after contact, (d) the number of times of intrusion inhibition, and the invasion avoidance rate (%).
表12の実施例14の結果より明らかなように、ペラルゴン酸を含浸させたろ紙の前からUターンする(d)侵入阻害回数は、炭素数のみが相違する飽和脂肪酸である酪酸、カプリル酸、カプリン酸、ラウリン酸(比較例12〜15)に比べて約1.5〜4倍程度高く、ペラルゴン酸は極めて優れた薬剤処理面内への侵入阻害効果を有することが明らかとなった。中でも、ペラルゴン酸は、薬剤処理面にアリ類が触覚や歩脚を接触すらさせずに薬剤処理面の前からUターンする(b)侵入回避回数が、触覚や歩脚を接触さてからUターンする(c)接触後回避回数に比べて概略5倍程度高いことも確認された。このことは、(d)侵入阻害回数における(b)侵入回避回数の割合を意味する「侵入回避率(%)」が、ペラルゴン酸(実施例14)は、酪酸、カプリル酸、カプリン酸、ラウリン酸(比較例12〜15)に比べて極めて高いことからも、明白である。
すなわち、ペラルゴン酸は、アリ類が触覚や歩脚を薬剤処理面に接触させることを抑制し、薬剤処理面内にアリ類が侵入することを確実に阻害する優れた効果を発揮することが明らかとなった。
As is clear from the results of Example 14 in Table 12, the U-turn is made from the front of the filter paper impregnated with pelargonic acid. (D) The number of times of invasion inhibition is butyric acid, caprylic acid, which is a saturated fatty acid having only a difference in carbon number, About 1.5 to 4 times higher than capric acid and lauric acid (Comparative Examples 12 to 15), it was revealed that pelargonic acid has an extremely excellent invasion inhibitory effect on the drug-treated surface. Among them, pelargonic acid makes a U-turn from the front of the drug-treated surface without causing ants to touch the tactile sense or the pedestrian leg on the drug-treated surface. (C) It was also confirmed that it was about 5 times higher than the number of avoidance after contact. This means that (d) “invasion avoidance rate (%)” means the ratio of invasion avoidance frequency to (b) invasion inhibition frequency, and pelargonic acid (Example 14) is butyric acid, caprylic acid, capric acid, laurin. It is also clear from the fact that it is very high compared to the acid (Comparative Examples 12 to 15).
That is, it is clear that pelargonic acid exerts an excellent effect of inhibiting ants from touching the tactile sensation and pedestrians with the drug-treated surface and reliably inhibiting ants from entering the drug-treated surface. It became.
<試験検体の調製8>
表13記載の組成からなる試験検体を調製し、実施例15、比較例16とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test specimen 8>
Test specimens having the compositions described in Table 13 were prepared and used as Example 15 and Comparative Example 16. In preparing the test specimen, each component was mixed and stirred with a magnetic stirrer so that the composition became uniform.
<アリ類忌避試験2>
表14記載のアリ類を対象としてアリ類忌避試験2を実施した。試験の概要は図2に示した。
縦25cm、横30cm、高さ10cmのプラスチック製容器の内壁面上部に害虫が逃亡しないよう逃亡処理を施した。前記容器内には、供試虫の餌場として、水を含浸した脱脂綿を2ヵ所設置した。次に直径5.5cmのろ紙に実施例15または比較例16と対照(アセトン100%)を各2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。容器内に供試虫を放ち、30分後の定着数を計数し、下記式にて忌避率(%)を算出した。これを「初期」の忌避率とする。
次いで、直径5.5cmのろ紙に実施例15または比較例16と対照(アセトン100%)を各2mLずつ含浸させ、1週間ドラフト内で風乾させた。上記と同様の試験を1週間風乾させたろ紙を用いて再度行い、12時間後の定着数を係数し、下記式にて忌避率(%)を算出した。これを「1週間後」の忌避率とした。試験は、25℃、明るい条件下にて行い、2回の平均値を忌避率(%)を表14に記載した。
忌避率(%)={1−(試験検体定着数)/(試験検体定着数+対照定着数)}×100
<Antial repellent test 2>
An ant repellent test 2 was performed on the ants described in Table 14. The outline of the test is shown in FIG.
An escape process was applied to the upper part of the inner wall surface of a plastic container having a length of 25 cm, a width of 30 cm, and a height of 10 cm so that no insects escape. Two absorbent cottons impregnated with water were installed in the container as feeding sites for the test insects. Next, filter paper having a diameter of 5.5 cm was impregnated with 2 mL each of Example 15 or Comparative Example 16 and the control (100% acetone), and the filter paper was placed so as to surround the feeding area. The test insects were released into the container, the number of colonies after 30 minutes was counted, and the repelling rate (%) was calculated by the following formula. This is the “initial” avoidance rate.
Next, 2 mL each of Example 15 or Comparative Example 16 and a control (100% acetone) was impregnated into a filter paper having a diameter of 5.5 cm, and air-dried in a fume hood for 1 week. The same test as described above was performed again using filter paper that had been air-dried for 1 week, the number of fixings after 12 hours was used as a coefficient, and the repelling rate (%) was calculated by the following formula. This was regarded as the repelling rate after “one week”. The test was performed under a bright condition at 25 ° C., and the average value of two times was shown in Table 14 as the repelling rate (%).
Repelling rate (%) = {1− (number of fixed test specimen) / (number of fixed test specimen + number of fixed control)} × 100
表14の実施例15の結果より明らかなように、ペラルゴン酸はクロヤマアリ、アミメアリに対して、初期、1週間後ともに忌避率が100%であることが確認された。これに対し、アリ類に対する天然成分由来の忌避成分として知られているサリチル酸ベンジル(比較例16)は、初期の忌避率はクロヤマアリ、アミメアリともに100%であるものの、1週間後の忌避率は、クロヤマアリに対しては46.2%、アミメアリに対しては84.8%と、忌避率が低下することが明らかとなった。この忌避率の低下は、サリチル酸ベンジルが揮散性の高い薬剤であることから、1週間風乾させたろ紙には、忌避活性に十分なサリチル酸ベンジルが残存していないことに起因するものと考えられる。
これらの結果より、本発明のペラルゴン酸を有効成分とした害虫防除剤は、長期間安定したアリ類忌避効果を発揮することが明らかとなった。
As is clear from the results of Example 15 in Table 14, it was confirmed that pelargonic acid had a repellent rate of 100% in the early and one week periods relative to the black ants and the red ants. On the other hand, benzyl salicylate (Comparative Example 16), which is known as a repellent component derived from natural ingredients for ants, has an initial repellent rate of 100% for both black and white ants, but the repellent rate after 1 week is It was clarified that the repelling rate was reduced to 46.2% for the black ants and 84.8% for the red ants. This decrease in repellent rate is considered to be due to the fact that benzyl salicylate sufficient for repellent activity does not remain on the filter paper air-dried for 1 week since benzyl salicylate is a highly volatile chemical.
From these results, it was clarified that the pest control agent comprising pelargonic acid of the present invention as an active ingredient exhibits a long-term stable ant repellent effect.
<試験検体の調製9>
表15記載の組成からなる試験検体を調製し、実施例16、比較例17とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test specimen 9>
Test specimens having the compositions described in Table 15 were prepared and used as Example 16 and Comparative Example 17. In preparing the test specimen, each component was mixed and stirred with a magnetic stirrer so that the composition became uniform.
<等脚目類防除試験1>
表16記載の等脚目類を対象として等脚目類防除試験1を実施した。試験の概要は図2に示した。
縦25cm、横30cm、高さ10cmのプラスチック製容器の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記容器内には、供試虫の餌場として、水を含浸した脱脂綿を2ヵ所設置した。次に直径5.5cmのろ紙に実施例16または比較例17と対照(アセトン100%)を各2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。
次に、容器内に供試虫(20頭)を放ち、30分後の餌場への定着数を計数し、下記式にて忌避率(%)を算出した。また、試験検体を含浸させたろ紙に対する侵入回避効果(試験検体を含浸させたろ紙に対し等脚目類が触覚や歩脚を接触すらさせることなくろ紙の前からUターンする行動を促す効果)の有無についても確認した。試験は、25℃、明るい条件下にて行い、忌避率(%)として表16に記載した。
忌避率(%)={1−(試験検体定着数)/(試験検体定着数+対照定着数)}×100
表16中の「有」は侵入回避効果が認められたことを、「無」は侵入回避効果が認められなかったことを意味する。
<Isopod control test 1>
The isopod control test 1 was carried out on the isopods listed in Table 16. The outline of the test is shown in FIG.
Calcium carbonate was applied to the upper part of the inner wall surface of a plastic container having a length of 25 cm, a width of 30 cm, and a height of 10 cm so that pests would not escape. Two absorbent cottons impregnated with water were installed in the container as feeding sites for the test insects. Next, filter paper having a diameter of 5.5 cm was impregnated with 2 mL each of Example 16 or Comparative Example 17 and control (acetone 100%), and the filter paper was placed so as to surround the feeding area.
Next, the test insects (20 heads) were released into the container, the number of colonies in the feeding area after 30 minutes was counted, and the repelling rate (%) was calculated by the following formula. Invasion avoidance effect on filter paper impregnated with test specimen (Effect of prompting U-turn action from front of filter paper without contact of isopods with tactile sensation or pedestrians on filter paper impregnated with test specimen) The presence or absence of was also confirmed. The test was performed at 25 ° C. under bright conditions, and the repelling rate (%) is shown in Table 16.
Repelling rate (%) = {1− (number of fixed test specimen) / (number of fixed test specimen + number of fixed control)} × 100
“Yes” in Table 16 means that the intrusion avoidance effect is recognized, and “No” means that the intrusion avoidance effect is not recognized.
表16の実施例16の結果より明らかなように、ペラルゴン酸はダンゴムシ、ワラジムシに対して、市販のダンゴムシ忌避剤の有効成分としても使用され、ピレスロイド系殺虫剤として公知のピレトリン(比較例17)に比べ、高い忌避活性を示すことが明らかとなった。さらに、ペラルゴン酸を含浸させたろ紙に対する侵入回避効果をも有することが確認された。
表16に示したとおり、本発明のペラルゴン酸を有効成分とした害虫防除剤は、ピレスロイド系殺虫剤よりも優れた等脚目類防除効果を発揮することが明らかとなった。
As is clear from the results of Example 16 in Table 16, pelargonic acid is also used as an active ingredient of a commercially available reed repellent against dansipes and slats, and is known as a pyrethroid insecticide (Comparative Example 17). Compared to the above, it was revealed that it exhibits high repellent activity. Furthermore, it was confirmed that the filter paper impregnated with pelargonic acid also has an invasion avoidance effect.
As shown in Table 16, it became clear that the pest control agent containing the pelargonic acid of the present invention as an active ingredient exhibits an isopoda control effect superior to the pyrethroid insecticide.
<試験検体の調製10>
表17記載の組成からなる試験検体を調製し、実施例17、比較例18、19とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Test specimen preparation 10>
Test specimens having the compositions described in Table 17 were prepared and used as Example 17 and Comparative Examples 18 and 19. In preparing the test specimen, each component was mixed and stirred with a magnetic stirrer so that the composition became uniform.
<等脚目類防除試験2>
表18記載の等脚目類を対象として等脚目類防除試験2を実施した。試験の概要は図3に示した。
縦15cm、横20cm、高さ10cmのプラスチック製容器の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記容器内には、供試虫の餌場として、水を含浸した脱脂綿を1ヵ所設置した。次に直径5.5cmのろ紙に実施例17、比較例18または比較例19と対照(アセトン100%)を各2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。
次に、容器内に供試虫(10頭)を放ち、ろ紙への侵入回数と侵入阻害回数(試験検体を含浸させたろ紙に対し等脚目類が触覚や歩脚を接触すらさせることなくろ紙の前からUターンする回数と、触覚や歩脚を当該ろ紙に接触させたとしても当該ろ紙に侵入することなくUターンする回数の和)を、15分間計数し、下記式にて侵入阻害率(%)を算出した。試験は、25℃、明るい条件下にて行い、侵入阻害率(%)を表18に記載した。
侵入阻害率(%)={(侵入阻害回数)/(侵入回数+侵入阻害回数)}×100
<Isopod control test 2>
The isopod control test 2 was carried out on the isopods listed in Table 18. The outline of the test is shown in FIG.
Calcium carbonate was applied to the upper part of the inner wall surface of a plastic container having a length of 15 cm, a width of 20 cm, and a height of 10 cm so that pests would not escape. One absorbent cotton impregnated with water was installed in the container as a feeding place for the test insects. Next, 2 mL each of Example 17, Comparative Example 18 or Comparative Example 19 and control (100% acetone) was impregnated into a filter paper having a diameter of 5.5 cm, and the filter paper was placed so as to surround the feeding area.
Next, test insects (10 heads) are released into the container, and the number of times of intrusion into the filter paper and the number of times of intrusion inhibition (without isopods touching the tactile sense or the pedestal with the filter paper impregnated with the test sample) Count the number of times of U-turn from the front of the filter paper and the sum of the number of times of U-turn without entering the filter paper even if a tactile sensation or pedestal is in contact with the filter paper) The rate (%) was calculated. The test was performed under a bright condition at 25 ° C., and the penetration inhibition rate (%) is shown in Table 18.
Invasion inhibition rate (%) = {(intrusion inhibition frequency) / (intrusion frequency + intrusion inhibition frequency)} × 100
表18の実施例17の結果より明らかなように、ペラルゴン酸はダンゴムシ、ワラジムシに対して、ピレスロイド系殺虫剤の中でも揮散性が高いことが公知のエンペントリン(比較例18)やプロフルトリン(比較例19)に比べ、侵入阻害回数が多い一方で侵入回数が極めて低いことが明らかとなった。
また、エンペントリン(比較例18)やプロフルトリン(比較例19)の試験系においては、試験終了後に致死個体が確認されたが、ペラルゴン酸の試験系では、致死個体は確認されなかった。ペラルゴン酸を直接等脚目類に処理しないこの試験系においては、忌避効果および侵入阻害効果のみが発揮されることも確認された。
表18に示したとおり、本発明のペラルゴン酸を有効成分とした害虫防除剤は、ピレスロイド系殺虫剤よりも優れた等脚目類防除効果を発揮することが明らかとなった。
As is apparent from the results of Example 17 in Table 18, pelargonic acid is known to have high volatility among pyrethroid insecticides against dangamushi and warabidushi, such as empentrin (Comparative Example 18) and profluthrin (Comparative Example 19). ), The number of intrusion inhibition was large, but the number of intrusion was very low.
Further, in the test system of Empentrin (Comparative Example 18) and Profluthrin (Comparative Example 19), lethal individuals were confirmed after the test was completed, but in the pelargonic acid test system, no lethal individuals were confirmed. It was also confirmed that in this test system in which pelargonic acid was not directly processed into isopods, only repellent and invasion inhibiting effects were exhibited.
As shown in Table 18, it was revealed that the pest control agent containing the pelargonic acid of the present invention as an active ingredient exhibits an isopoda control effect superior to the pyrethroid insecticide.
<試験検体の調製11>
下記表19記載の組成からなる試験検体を調製し、実施例18、比較例20とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test specimen 11>
Test specimens having the compositions described in Table 19 below were prepared and used as Example 18 and Comparative Example 20. In preparing the test specimen, each component was mixed and stirred with a magnetic stirrer so that the composition became uniform.
<ムカデ忌避確認試験>
試験の概要は図3に示した。
縦25cm、横30cm、高さ30cmのプラスチック製容器の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。直径10cmのろ紙に実施例18と比較例20(アセトン100%)を各4mLずつ含浸させ、前記容器内に設置し、ろ紙上に市販の毒餌(アース製薬(株)ムカデコロリ(毒餌剤)容器タイプ)を載置した。
次に、容器内に1日絶食させたトビズムカデ1頭を放ち、24時間後の致死を確認した。試験は、25℃、明るい条件下にて行い、忌避評価結果を表20に記載した。
この確認試験ではろ紙上に侵入してはじめて餌(毒餌)を摂食できるため、忌避評価結果は、トビズムカデが致死した場合には忌避効果はなく「×」と、トビズムカデが致死していない場合は忌避効果があるとして「〇」と表記した。
<Centipede repellent confirmation test>
The outline of the test is shown in FIG.
Calcium carbonate was applied to the upper part of the inner wall surface of a plastic container having a length of 25 cm, a width of 30 cm, and a height of 30 cm so that pests would not escape. A filter paper having a diameter of 10 cm is impregnated with 4 mL each of Example 18 and Comparative Example 20 (acetone 100%), placed in the container, and commercially available bait (earth pharmaceutical Co., Ltd. centipede (poison bait) container type) on the filter paper. ) Was placed.
Next, one Tobism cadet fasted for 1 day was released in the container, and lethality was confirmed after 24 hours. The test was performed at 25 ° C. under bright conditions, and the repellent evaluation results are shown in Table 20.
In this confirmation test, the bait (poisonous bait) can be fed only after entering the filter paper. Therefore, the repellent evaluation result shows that there is no repellent effect when the Tobism cadet is lethal, and the Tobism cadet is not lethal. “O” is indicated as having a repellent effect.
表19に示したとおり、ペラルゴン酸は、ムカデに対しても優れた忌避効果を奏することが明らかとなった。 As shown in Table 19, it became clear that pelargonic acid has an excellent repellent effect against centipedes.
<試験検体の調製12>
下記表20記載の組成からなる試験検体を調製し、実施例19とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test sample 12>
A test specimen having the composition shown in Table 20 below was prepared and designated as Example 19. In preparing the test specimen, each component was mixed and stirred with a magnetic stirrer so that the composition became uniform.
<カメムシ忌避確認試験>
試験の概要は図4に示した。
内径130mm、高さ100mmのプラスチック製カップ(商品名:KP−860MB(鴻池プラスチック社製))の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記カップ内に、供試虫の餌場として水を含浸した脱脂綿を2ヵ所設置し、片方の餌場に実施例19の試験検体を2mL含浸させた。
次に、前記カップ内に表21記載の供試虫(5頭)を放ち、24時間後の餌場への定着数を計数し、下記式にて忌避率(%)を算出した。
忌避率(%)={1−(試験検体定着数)/(試験検体定着数+対照定着数)}×100
試験は25℃、明るい条件下にて行い、忌避率(%)を表21に記載した。
<Stinkbug repellent confirmation test>
The outline of the test is shown in FIG.
Calcium carbonate was applied to the upper part of the inner wall surface of a plastic cup (trade name: KP-860MB (manufactured by Tsugaike Plastic Co., Ltd.)) having an inner diameter of 130 mm and a height of 100 mm so that no insects escape. Two absorbent cotton impregnated with water were placed in the cup as a feed for test insects, and 2 mL of the test sample of Example 19 was impregnated in one feed.
Next, the test insects (five) listed in Table 21 were released into the cup, the number of colonies in the feeding area after 24 hours was counted, and the repelling rate (%) was calculated by the following formula.
Repelling rate (%) = {1− (number of fixed test specimen) / (number of fixed test specimen + number of fixed control)} × 100
The test was performed at 25 ° C. under bright conditions, and the repelling rate (%) is shown in Table 21.
表21に示したとおり、ペラルゴン酸は、カメムシに対しても種類を問わず良好な忌避活性を奏することが明らかとなった。 As shown in Table 21, it was revealed that pelargonic acid has a good repellent activity against stink bugs regardless of the type.
本発明のペラルゴン酸を有効成分とした害虫防除剤は、ピレスロイド系殺虫剤等の公知の薬剤に比べ、優れた害虫防除効果、特に害虫忌避効果や、侵入阻害効果若しくは侵入回避効果を奏するものである。詳しくは、本発明の害虫防除剤は、腹足類、等脚目類、アリ類、半翅目類、多足類に対して優れた致死活性を有するものであり、さらには、腹足類、等脚目類、アリ類、多足類に対して優れた忌避効果や侵入阻害効果を発揮するものである。
本発明の侵入阻害効果は、ペラルゴン酸またはその塩を有効成分とする薬剤処理面に対し、害虫が触覚や歩脚を接触することなく薬剤処理面の前からUターン行動をとる、若しくは接触させたとしても薬剤処理面の前からUターン行動をとることに起因する、優れた効果である。
本発明の害虫防除剤は、除草活性を有するペラルゴン酸またはその塩を有効成分としているため、散布した場所の除草効果も同時に得ることができる。これにより、本発明の害虫防除剤を家屋等の建造物の入り口付近や駐車場などに処理することにより、薬剤に接触した害虫は致死し、薬剤処理面内に対しては害虫が侵入することを確実に阻害するので、家屋内や車内等に害虫を侵入させることがなく、さらに処理した場所の雑草の繁殖を抑制する効果が得られるという特徴を有するものである。
本発明の害虫防除剤が奏するこれらの効果は、本発明者により新たに見出された知見であり、格別顕著な効果である。
The pest control agent comprising the pelargonic acid of the present invention as an active ingredient has an excellent pest control effect, particularly a pest repellent effect, an invasion inhibition effect or an invasion avoidance effect, compared to known drugs such as pyrethroid insecticides. is there. Specifically, the pest control agent of the present invention has excellent lethal activity against gastropods, isopods, ants, hemiptera, polypods, and further, gastropods, isopoda It exhibits an excellent repellent effect and invasion inhibitory effect against species, ants and multipods.
The invasion-inhibiting effect of the present invention is that a pest is made to take or make a U-turn action from the front of the drug-treated surface without touching the tactile sense or the pedestal with respect to the drug-treated surface containing pelargonic acid or a salt thereof as an active ingredient Even if it is, it is the outstanding effect resulting from taking a U-turn action from the front of a chemical treatment side.
Since the pest control agent of the present invention contains pelargonic acid having a herbicidal activity or a salt thereof as an active ingredient, the herbicidal effect at the sprayed place can be obtained at the same time. As a result, by treating the pest control agent of the present invention in the vicinity of the entrance of a building such as a house or a parking lot, the pests that come into contact with the drug are lethal and the pests enter the surface of the drug treatment. Therefore, it is possible to obtain an effect of suppressing the propagation of weeds in a treated place without causing a pest to enter the house or in the vehicle.
These effects exhibited by the pest control agent of the present invention are findings newly found by the present inventor and are particularly remarkable effects.
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JP7193668B2 (en) | 2022-12-20 |
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