JP2018025798A5 - - Google Patents

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JP2018025798A5
JP2018025798A5 JP2017152316A JP2017152316A JP2018025798A5 JP 2018025798 A5 JP2018025798 A5 JP 2018025798A5 JP 2017152316 A JP2017152316 A JP 2017152316A JP 2017152316 A JP2017152316 A JP 2017152316A JP 2018025798 A5 JP2018025798 A5 JP 2018025798A5
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Prior art keywords
polarizing plate
polyvinyl alcohol
modified polyvinyl
water
based resin
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JP2017152316A
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Japanese (ja)
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JP6945380B2 (en
JP2018025798A (en
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Priority claimed from KR1020160100725A external-priority patent/KR101775594B1/en
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Claims (8)

偏光子の少なくとも一面に接着剤層を介在して接合された保護フィルムを含む偏光板において、
前記偏光板の水分率が2.8〜4.8%であり、
前記接着剤層は、アセトアセチル基変性ポリビニルアルコール系樹脂、グリオキサール架橋剤及び2種以上の多価金属イオンの水溶性塩を含む接着剤組成物よりなり、厚さが30〜200nmであることを特徴とする偏光板。
In a polarizing plate including a protective film bonded to at least one surface of a polarizer with an adhesive layer interposed,
The water content of the polarizing plate is 2.8 to 4.8%,
The adhesive layer is composed of an adhesive composition containing an acetoacetyl group-modified polyvinyl alcohol-based resin, a glyoxal crosslinking agent, and a water-soluble salt of two or more kinds of polyvalent metal ions, and has a thickness of 30 to 200 nm. Characteristic polarizing plate.
前記接着剤組成物は、アセトアセチル基変性ポリビニルアルコール系樹脂水溶液及びグリオキサール架橋剤を含むA液と、アセトアセチル基変性ポリビニルアルコール系樹脂水溶液及び2種以上の多価金属イオンの水溶性塩を含むB液と、を含むことを特徴とする請求項1に記載の偏光板。 The adhesive composition contains a solution A containing an acetoacetyl group-modified polyvinyl alcohol-based resin aqueous solution and a glyoxal crosslinking agent, an acetoacetyl group-modified polyvinyl alcohol-based resin aqueous solution, and a water-soluble salt of two or more polyvalent metal ions. The liquid crystal composition according to claim 1, further comprising a liquid B. 前記A液及びB液のそれぞれに含まれるアセトアセチル基変性ポリビニルアルコール系樹脂の固形分の含量は、アセトアセチル基変性ポリビニルアルコール系樹脂水溶液100重量%に対して、2.5〜4.5重量%であることを特徴とする請求項2に記載の偏光板。 The solid content of the acetoacetyl group-modified polyvinyl alcohol-based resin contained in each of the solutions A and B is 2.5 to 4.5% by weight based on 100% by weight of the acetoacetyl group-modified polyvinyl alcohol-based resin aqueous solution. %, The polarizing plate according to claim 2. 前記多価金属イオンの水溶性塩は、塩化亜鉛、硝酸亜鉛及び硝酸アルミニウムよりなる群から選択される2種以上であることを特徴とする請求項1に記載の偏光板。 The polarizing plate according to claim 1, wherein the water-soluble salt of the polyvalent metal ion is two or more selected from the group consisting of zinc chloride, zinc nitrate and aluminum nitrate. 前記A液に含まれるグリオキサール系架橋剤の含量は、前記A液に含まれるアセトアセチル基変性ポリビニルアルコール系樹脂の固形分総100重量部に対して、30〜70重量部で含まれることを特徴とする請求項2に記載の偏光板。The content of the glyoxal-based cross-linking agent contained in the solution A is 30 to 70 parts by weight based on 100 parts by weight of the total solid content of the acetoacetyl group-modified polyvinyl alcohol resin contained in the solution A. The polarizing plate according to claim 2. 前記多価金属イオンの水溶性塩は、塩化亜鉛、硝酸亜鉛及び硝酸アルミニウムよりなる群から選択される2種以上を含み、The water-soluble salt of a polyvalent metal ion includes two or more selected from the group consisting of zinc chloride, zinc nitrate and aluminum nitrate,
前記塩化亜鉛の含量は、前記B液に含まれるアセトアセチル基変性ポリビニルアルコール系樹脂の固形分総100重量部に対して、2〜10重量部で含まれることを特徴とする請求項2に記載の偏光板。The content of the zinc chloride is 2 to 10 parts by weight based on 100 parts by weight of the total solid content of the acetoacetyl group-modified polyvinyl alcohol-based resin contained in the solution B. Polarizing plate.
前記多価金属イオンの水溶性塩は、塩化亜鉛、硝酸亜鉛及び硝酸アルミニウムよりなる群から選択される2種以上を含み、The water-soluble salt of a polyvalent metal ion includes two or more selected from the group consisting of zinc chloride, zinc nitrate and aluminum nitrate,
前記硝酸亜鉛乃至硝酸アルミニウムの含量は、前記B液に含まれるアセトアセチル基変性ポリビニルアルコール系樹脂の固形分総100重量部に対して、30〜90重量部で含まれることを特徴とする請求項2に記載の偏光板。The content of the zinc nitrate to aluminum nitrate is 30 to 90 parts by weight based on 100 parts by weight of the total solid content of the acetoacetyl group-modified polyvinyl alcohol-based resin contained in the solution B. The polarizing plate according to 2.
偏光板の水分率が2.8〜4.8%であり、前記偏光板に含まれる接着剤層の厚さが30〜200nmである偏光板の製造方法において、In the method for producing a polarizing plate, wherein the water content of the polarizing plate is 2.8 to 4.8% and the thickness of the adhesive layer contained in the polarizing plate is 30 to 200 nm,
(a)偏光子の両面にアセトアセチル基変性ポリビニルアルコール系樹脂、グリオキサール架橋剤及び2種以上の多価金属イオンの水溶性塩を含む接着剤組成物が塗布され、接着剤層が生成される段階と、(A) An adhesive composition containing an acetoacetyl group-modified polyvinyl alcohol-based resin, a glyoxal crosslinking agent, and a water-soluble salt of two or more polyvalent metal ions is applied to both surfaces of the polarizer to form an adhesive layer. Stages,
(b)前記接着剤層上に少なくとも一つ以上の保護フィルムがニップロールにより接合され、偏光板が製作される段階と、(B) a step of joining at least one protective film on the adhesive layer with a nip roll to manufacture a polarizing plate,
(c)前記偏光板が少なくとも2個以上の乾燥路を通過し、乾燥される段階と、を含むことを特徴とする偏光板の製造方法。(C) a step of allowing the polarizing plate to pass through at least two or more drying paths and drying, and a method for manufacturing a polarizing plate.
JP2017152316A 2016-08-08 2017-08-07 Polarizing plate and its manufacturing method Active JP6945380B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020160100725A KR101775594B1 (en) 2016-08-08 2016-08-08 Polarizing plate and preparing method for the same
KR10-2016-0100725 2016-08-08

Publications (3)

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JP2018025798A JP2018025798A (en) 2018-02-15
JP2018025798A5 true JP2018025798A5 (en) 2020-07-02
JP6945380B2 JP6945380B2 (en) 2021-10-06

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JP (1) JP6945380B2 (en)
KR (1) KR101775594B1 (en)
CN (1) CN107703577B (en)
TW (1) TWI729183B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020137839A1 (en) * 2018-12-25 2020-07-02 日東電工株式会社 Polarizer and method for manufacturing same
JP7046901B2 (en) * 2018-12-25 2022-04-04 日東電工株式会社 Polarizer and its manufacturing method
JP2021043370A (en) * 2019-09-12 2021-03-18 住友化学株式会社 Polarizer

Family Cites Families (15)

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JP2002221619A (en) * 2001-01-25 2002-08-09 Gunze Ltd Polarizing plate
JP2005326531A (en) * 2004-05-13 2005-11-24 Nitto Denko Corp Polarizing plate equipped with protecting film, manufacturing method therefor, and image display device using polarizing plate
JP2008129258A (en) * 2006-11-20 2008-06-05 Nitto Denko Corp Method for producing polarizing plate, polarizing plate, optical film and image display device
JP2008180765A (en) * 2007-01-23 2008-08-07 Sumitomo Chemical Co Ltd Manufacturing method of polarizing film
JP5051696B2 (en) * 2007-04-06 2012-10-17 住友化学株式会社 Polarizer
JP4849563B2 (en) * 2007-08-07 2012-01-11 住友化学株式会社 Polarizing plate and manufacturing method thereof
JP5147014B2 (en) * 2008-10-08 2013-02-20 住友化学株式会社 High contrast polarizing plate and liquid crystal display device
JP4762320B2 (en) * 2009-02-20 2011-08-31 住友化学株式会社 Liquid crystal display
KR101211745B1 (en) * 2009-06-24 2012-12-12 주식회사 엘지화학 Retardation film, fabrication method thereof, and liquid crystal display comprising the same
JP2012047799A (en) * 2010-08-24 2012-03-08 Nitto Denko Corp Manufacturing method of polarizer
KR101459126B1 (en) * 2011-12-21 2014-11-07 제일모직주식회사 Polarizer plate and liquid crystal display comprising the same
KR101397705B1 (en) * 2011-12-30 2014-05-23 제일모직주식회사 Adhesive composition for polarizing plate
KR102282040B1 (en) * 2014-07-02 2021-07-28 수미토모 케미칼 컴퍼니 리미티드 Adhesive composition and polarizing plate comprising the same
WO2016002808A1 (en) * 2014-07-02 2016-01-07 住友化学株式会社 Adhesive composition and polarizing plate containing same
KR20160028316A (en) * 2014-09-03 2016-03-11 스미또모 가가꾸 가부시키가이샤 Adhesive composition and polarizing plate using the same

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