JP2018002756A - 光学用粘着シート、粘着剤層付偏光フィルム、および液晶表示装置 - Google Patents
光学用粘着シート、粘着剤層付偏光フィルム、および液晶表示装置 Download PDFInfo
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- JP2018002756A JP2018002756A JP2016126415A JP2016126415A JP2018002756A JP 2018002756 A JP2018002756 A JP 2018002756A JP 2016126415 A JP2016126415 A JP 2016126415A JP 2016126415 A JP2016126415 A JP 2016126415A JP 2018002756 A JP2018002756 A JP 2018002756A
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- sensitive adhesive
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- adhesive layer
- adhesive sheet
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133528—Polarisers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/318—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
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- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Nonlinear Science (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mathematical Physics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
- Laminated Bodies (AREA)
- Polarising Elements (AREA)
- Liquid Crystal (AREA)
Abstract
Description
・カラム:TSKgel SuperAWM-H(上流側,東ソー株式会社製)とTSKgel SuperAW4000(東ソー株式会社製)とTSKgel SuperAW2500(下流側,東ソー株式会社製)とを直列に接続
・カラムサイズ:各カラムとも6.0mmφ×150mm
・カラム温度(測定温度):40℃
・溶離液:テトラヒドロフラン(THF)
・流量:0.4mL/分
・サンプル注入量:20μL
・サンプル濃度:約2.0g/L(テトラヒドロフラン溶液)
・標準試料:ポリスチレン
・検出器:示差屈折計(RI)
反応容器内で、メタクリル酸ジシクロペンタニル(DCPMA)60重量部と、メタクリル酸メチル(MMA)40重量部と、連鎖移動剤としてのα-チオグリセロール3.5重量部と、重合溶媒としてのトルエン100重量部とを含む混合物を、70℃で1時間、窒素雰囲気下で撹拌した。次に、重合開始剤としての2,2'-アゾビスイソブチロニトリル0.2重量部を反応容器内の混合物に加えて反応溶液を調製し、70℃で2時間、反応を行った。続いて、80℃で2時間、反応を行った。その後、反応容器内の反応溶液を、130℃の温度雰囲気下に置き、当該反応溶液からトルエン、連鎖移動剤、および未反応モノマーを乾燥除去した。これにより、固形状のアクリル系オリゴマーを得た。当該アクリル系オリゴマーの重量平均分子量(Mw)は、5.1×103であった。
アクリル酸2-エチルヘキシル(2EHA)78重量部と、N-ビニル-2-ピロリドン(NVP)18重量部と、アクリル酸2-ヒドロキシエチル(HEA)4重量部とを含有するモノマー混合物に、第1の光重合開始剤(商品名「イルガキュア651」,BASF社製)0.035重量部および第2の光重合開始剤(商品名「イルガキュア184」,BASF社製)0.035重量部を加えた後、当該混合物に対し、粘度測定装置を使用して粘度を測定しつつ当該混合物の粘度が約20Pa・sになるまで紫外線照射装置を使用して紫外線を照射した。粘度測定において、装置のローター回転速度は10rpmとし、測定温度は30℃とした。これにより、混合物中のモノマー成分の一部が重合した部分重合物たるプレポリマー組成物(重合反応を経ていないモノマー成分を含有する)を得た。そして、このプレポリマー組成物100重量部と、上述のアクリル系オリゴマー11.8重量部と、アクリル酸2-ヒドロキシエチル(HEA)17.6重量部と、1,6-ヘキサンジオールジアクリレート(HDDA)0.294重量部と、シランカップリング剤(商品名「KBM-403」,信越化学工業株式会社製)0.353重量部とを混合し、アクリル系粘着剤組成物を得た。
〈第1粘着剤層の形成〉
ポリエチレンテレフタレート(PET)系剥離ライナー(厚さ125μm,日東電工株式会社製)上に、上記のアクリル系粘着剤組成物を塗布し、粘着剤組成物層を形成した。次に、この粘着剤組成物層上に更にPET系剥離ライナー(厚さ125μm,日東電工株式会社製)を積層し、当該粘着剤組成物層を被覆して酸素を遮断した。このようにして、[剥離ライナー/粘着剤組成物層/剥離ライナー]の積層構成を有する積層体(積層体L1’)を得た。次に、この積層体L1’に対し、その一方の剥離ライナーの側から、ブラックライト(株式会社東芝製)を使用して照度3mW/cm2の紫外線を300秒間照射した。これによって積層体L1’の粘着剤組成物層を硬化させて粘着剤層(第1粘着剤層)とし、[剥離ライナー/粘着剤層(第1粘着剤層)/剥離ライナー]の積層構成を有する積層体(積層体L1)を得た。積層体L1における第1粘着剤層の厚さは50μmである。
PET系剥離ライナー(厚さ125μm,日東電工株式会社製)上に、上記のアクリル系粘着剤組成物を塗布し、粘着剤組成物層を形成した。次に、この粘着剤組成物層上に更にPET系剥離ライナー(厚さ125μm,日東電工株式会社製)を積層し、当該粘着剤組成物層を被覆して酸素を遮断した。このようにして、[剥離ライナー/粘着剤組成物層/剥離ライナー]の積層構成を有する積層体(積層体L2’)を得た。次に、この積層体L2’に対し、その一方の剥離ライナーの側から、ブラックライト(株式会社東芝製)を使用して照度3mW/cm2の紫外線を300秒間照射した。これによって積層体L2’の粘着剤組成物層を硬化させて粘着剤層(第2粘着剤層)とし、[剥離ライナー/粘着剤層(第2粘着剤層)/剥離ライナー]の積層構成を有する積層体(積層体L2)を得た。積層体L2における第2粘着剤層の厚さは500μmである。
厚さ38μmのポリエチレンテレフタレートフィルム(商品名「ダイアホイルT100C38」,面内位相差1500,三菱樹脂株式会社製)の両面にコロナ処理を施したもの(フィルムF1)を用意し、上記の積層体L1(剥離ライナー/第1粘着剤層/剥離ライナー)から一方の剥離ライナーを剥離した後、この剥離によって露出した第1粘着剤層表面を介して、片側剥離ライナー付き第1粘着剤層をフィルムF1の一方の面に対して貼り合せた。これにより、[剥離ライナー/第1粘着剤層/フィルムF1]の積層構成を有する積層体を得た。次に、上記の積層体L2(剥離ライナー/第2粘着剤層/剥離ライナー)から一方の剥離ライナーを剥離した後、この剥離によって露出した第2粘着剤層表面を介して、片側剥離ライナー付き第2粘着剤層を前記フィルムF1の他方の面に対して貼り合せた。以上のようにして、[剥離ライナー/第1粘着剤層(厚さ50μm)/フィルムF1(厚さ38μm)/第2粘着剤層(厚さ500μm)/剥離ライナー]の積層構成を有する光学用粘着シートを作製した。剥離ライナーの厚さを除く実施例1の光学用粘着シートの厚さは、588μmである。また、実施例1の光学用粘着シートにおいて、基材の厚さ(TB)38μm(<100μm)に対し、第1粘着剤層の厚さ(TA1)は1.3倍であり、第2粘着剤層の厚さ(TA2)は13.2倍である。
第1粘着剤層の厚さを50μmに代えて100μmとしたこと、および、光学用粘着シートの基材として、厚さ50μmのポリエチレンテレフタレートフィルム(商品名「ダイアホイルT100E50」,面内位相差2000,三菱樹脂株式会社製)の両面にコロナ処理を施したもの(フィルムF2)をフィルムF1の代わりに用いたこと以外は、実施例1と同様にして、実施例2の光学用粘着シートを作製した。剥離ライナーの厚さを除く実施例2の光学用粘着シートの厚さは、650μmである。また、実施例2の光学用粘着シートにおいて、基材の厚さ(TB)50μm(<100μm)に対し、第1粘着剤層の厚さ(TA1)は2倍であり、第2粘着剤層の厚さ(TA2)は10倍である。
第1粘着剤層の厚さを50μmに代えて250μmとしたこと、および、光学用粘着シートの基材としてフィルムF1に代えて上記フィルムF2を用いたこと以外は、実施例1と同様にして、実施例3の光学用粘着シートを作製した。剥離ライナーの厚さを除く実施例2の光学用粘着シートの厚さは、800μmである。また、実施例3の光学用粘着シートにおいて、基材の厚さ(TB)50μm(<100μm)に対し、第1粘着剤層の厚さ(TA1)は5倍であり、第2粘着剤層の厚さ(TA2)は10倍である。
第1粘着剤層の厚さを50μmに代えて500μmとしたこと、および、光学用粘着シートの基材としてフィルムF1に代えて上記フィルムF2を用いたこと以外は、実施例1と同様にして、実施例4の光学用粘着シートを作製した。剥離ライナーの厚さを除く実施例2の光学用粘着シートの厚さは、1050μmである。また、実施例4の光学用粘着シートにおいて、基材の厚さ(TB)50μm(<100μm)に対し、第1粘着剤層の厚さ(TA1)は10倍であり、第2粘着剤層の厚さ(TA2)は10倍である。
第1粘着剤層の厚さを50μmに代えて500μmとしたこと、および、光学用粘着シートの基材として、厚さ125μmのポリエチレンテレフタレートフィルム(商品名「ダイアホイルT104E125」,面内位相差5000,三菱樹脂株式会社製)の両面にコロナ処理を施したもの(フィルムF3)をフィルムF1の代わりに用いたこと以外は、実施例1と同様にして、実施例5の光学用粘着シートを作製した。剥離ライナーの厚さを除く実施例2の光学用粘着シートの厚さは、1125μmである。また、実施例5の光学用粘着シートにおいて、基材の厚さ(TB)125μm(≧100μm)に対し、第1粘着剤層の厚さ(TA1)は4倍であり、第2粘着剤層の厚さ(TA2)は4倍である。
第1粘着剤層の厚さを50μmに代えて100μmとしたこと、および、光学用粘着シートの基材として、厚さ80μmのポリエチレンテレフタレートフィルム(商品名「SRF」,面内位相差8400,東洋紡株式会社製)の両面にコロナ処理を施したもの(フィルムF4)をフィルムF1の代わりに用いたこと以外は、実施例1と同様にして、実施例6の光学用粘着シートを作製した。剥離ライナーの厚さを除く実施例2の光学用粘着シートの厚さは、680μmである。また、実施例6の光学用粘着シートにおいて、基材の厚さ(TB)80μm(<100μm)に対し、第1粘着剤層の厚さ(TA1)は1.25倍であり、第2粘着剤層の厚さ(TA2)は6.25倍である。
第1粘着剤層の厚さを50μmに代えて100μmとしたこと、および、光学用粘着シートの基材としてフィルムF1に代えてフィルムF3を用いたこと以外は、実施例1と同様にして、比較例1の光学用粘着シートを作製した。剥離ライナーの厚さを除く比較例1の光学用粘着シートの厚さは、725μmである。また、比較例1の光学用粘着シートにおいて、基材の厚さ(TB)125μm(≧100μm)に対し、第1粘着剤層の厚さ(TA1)は0.8倍(2.5倍未満)であり、第2粘着剤層の厚さ(TA2)は4倍である。
第1粘着剤層の厚さを50μmに代えて250μmとしたこと、および、光学用粘着シートの基材としてフィルムF1に代えてフィルムF3を用いたこと以外は、実施例1と同様にして、比較例2の光学用粘着シートを作製した。剥離ライナーの厚さを除く比較例2の光学用粘着シートの厚さは、875μmである。また、比較例2の光学用粘着シートにおいて、基材の厚さ(TB)125μm(≧100μm)に対し、第1粘着剤層の厚さ(TA1)は2倍(2.5倍未満)であり、第2粘着剤層の厚さ(TA2)は4倍である。
第1粘着剤層の厚さを50μmに代えて100μmとしたこと、および、光学用粘着シートの基材として、厚さ25μmのポリエチレンテレフタレートフィルム(商品名「ダイアホイルT100-25」,面内位相差1000,三菱樹脂株式会社製)の両面にコロナ処理を施したもの(フィルムF5)をフィルムF1の代わりに用いたこと以外は、実施例1と同様にして、比較例3の光学用粘着シートを作製した。剥離ライナーの厚さを除く比較例3の光学用粘着シートの厚さは、625μmである。また、比較例3の光学用粘着シートにおいて、基材の厚さ(TB)25μmに対し、第1粘着剤層の厚さ(TA1)は4倍であり、第2粘着剤層の厚さ(TA2)は20倍である。
第1粘着剤層の厚さを50μmに代えて100μmとしたこと、および、光学用粘着シートの基材として、厚さ40μmの無延伸ポリプロピレンフィルム(商品名「サントックス-CP MK12」,面内位相差55,サン・トックス株式会社製)の両面にコロナ処理を施したもの(フィルムF6)をフィルムF1の代わりに用いたこと以外は、実施例1と同様にして、比較例4の光学用粘着シートを作製した。剥離ライナーの厚さを除く比較例4の光学用粘着シートの厚さは、640μmである。また、比較例4の光学用粘着シートにおいて、基材の厚さ(TB)40μmに対し、第1粘着剤層の厚さ(TA1)は2.5倍であり、第2粘着剤層の厚さ(TA2)は12.5倍である。
実施例および比較例の光学用粘着シートの基材として使用されている上述のフィルムF1〜F6のそれぞれについて、機械方向(MD)の90〜100℃における平均線膨張率と、幅方向(MD)の90〜100℃における平均線膨張率とを、それぞれ調べた。90〜100℃における平均線膨張率を求めるにあたり、具体的には、フィルムからサンプル片(3mm×20mm)を切り出し、当該サンプル片について、熱機械的分析装置(商品名「TMA/SS6000」,エスアイアイ・ナノテクノロジー社製)を使用して線膨張測定を行った。本測定においては、装置の具備する一対のチャックに挟持される測定試料の初期チャック間距離(測定に係る初期長さ)を10mmとし、測定雰囲気を空気雰囲気(流量200ml/分)とし、測定モードを引張モード(荷重19.6mN)とし、測定温度範囲を20℃から350℃までとし、昇温速度を例えば5℃/分とした。その結果を表1に掲げる。
実施例および比較例の各光学用粘着シートについて、次のようにして、偏光フィルムに対する接着信頼性を調べた。接着信頼性試験に供されるサンプル構造体の作製においては、まず、ガラス板(120mm×180mm)に対してハンドローラーを使用して偏光フィルム(商品名「SEG1425DU」,日東電工株式会社製)を貼り合わせた偏光フィルム付ガラスを用意した。次に、光学用粘着シートから第1粘着剤層側の剥離ライナーを剥離した後、ポリカーボネート層とポリメタクリル酸メチル層との二層構造を有する複合シート(商品名「ユーピロン・シート HMRS51T」,90mm×160mm,三菱ガス化学株式会社製)のポリカーボネート面に対し、当該光学用粘着シートをその第1粘着剤層側にて貼り合わせた。次に、このようにしてポリカーボネート面に貼り合わされた光学用粘着シートから第2粘着剤層側の剥離ライナーを剥離した後、当該複合シート付光学用粘着シートをその第2粘着剤層側にて前記の偏光フィルム付ガラスの偏光フィルム面に対して貼り合わせた。その際、光学用粘着シートの基材の機械方向(MD)と偏光フィルムの透過容易軸の方向とが45度をなす配向で、複合シート付光学用粘着シートと偏光フィルム付ガラスとを貼り合わせた。その後、真空プレスにより、複合シート付光学用粘着シートと偏光フィルム付ガラスとの間の圧着を行った。この真空プレスにおいては、圧力を0.3MPaとし、真空度を100Paとし、プレス時間を5秒間とした。以上のようにして、95℃接着信頼性試験に供されるサンプル構造体を光学用粘着シートごとに作製した。そして、サンプル構造体をオートクレーブに投入し、温度50℃および圧力0.5MPaの条件で、15分間のオートクレーブ処理を行った。オートクレーブ処理後のサンプル構造体について、95℃の環境下に24時間放置した後、目視による観察を行った。各サンプル構造体については、その厚さ方向に透過観察が可能であるところ、観察において、発泡がなく且つ剥がれもない場合を、95℃接着信頼性は良好(○)と評価し、発泡または剥がれがある場合を、95℃接着信頼性は不良(×)と評価した。その結果を表1に掲げる。
実施例および比較例の各光学用粘着シートについて、ヘーズメーター HM-150型(株式会社村上色彩技術研究所製)を使用して、JIS K 7136に規定の方法に準拠してヘーズ(%)を測定した。本測定は、両剥離ライナーが剥離され且つスライドガラス(商品名「スライドグラス S1112」,厚さ1.0〜1.2mm,松波硝子工業株式会社製)に貼り付けられた状態にある光学用粘着シートについて行った。その結果を表1に掲げる。
本発明の構成を具備する実施例1〜6の光学用粘着シートにおいては、いずれも、良好な95℃接着信頼性が実現された。これに対し、比較例1〜4の光学用粘着シートにおいては、いずれも、良好な95℃接着信頼性が実現されなかった。比較例1の光学用粘着シートでは、基材の厚さTBが125μmであるのに対して第1粘着剤層の厚さTA1が100μmと小さすぎるため、上記接着信頼性試験において、基材に発生した熱応力を粘着剤層にて充分に緩和することができずに第1粘着剤層とその被着体たる複合シートのポリカーボネート面との界面に局所的剥離現象が生じたものと、考えられる。比較例2の光学用粘着シートでは、基材の厚さTBが125μmであるのに対して第1粘着剤層の厚さTA1が250μmと小さすぎるため、上記接着信頼性試験において、基材に発生した熱応力を粘着剤層にて充分に緩和することができずに第1粘着剤層とその被着体たる複合シートのポリカーボネート面との界面に局所的剥離現象が生じたものと、考えられる。比較例3の光学用粘着シートは、基材の厚さTBが25μmと小さすぎて基材の剛性が過小であるため、作製過程での基材と粘着剤層との貼合せ作業時や光学用粘着シートの対被着体貼合せ作業時において、貼合わせ界面に微小であってもシワが生じやすい。そのような比較例3の光学用粘着シートでは、当該シワの存在に起因して、基材と粘着剤層との界面や粘着剤層と被着体との界面にて特に高温条件下で気泡を生じやすく、従って、良好な95℃接着信頼性が得られなかったものと考えられる。比較例4の光学用粘着シートでは、基材の90〜100℃における平均線膨張率の絶対値が2×10-4℃-1を超えて過大であるため、上記接着信頼性試験において、温度変化に基づく基材の変形に各粘着剤層が追従しにくく、基材と第1粘着剤層との界面や基材と第2粘着剤層との界面に局所的剥離現象が生じたものと、考えられる。
Y 粘着剤層付偏光フィルム
Z 液晶表示装置
10 基材
11 粘着剤層(第1粘着剤層)
12 粘着剤層(第2粘着剤層)
21 偏光フィルム
30 液晶パネル
31,32 ガラス板
33 液晶層
34,35 偏光フィルム
41 透明カバー
Claims (10)
- 第1粘着剤層と、第2粘着剤層と、当該第1および第2粘着剤層の間の基材とを含む積層構造を有し、
前記基材は、厚さが25μmを超え、且つ、90〜100℃における平均線膨張率の絶対値が2×10-4℃-1以下であり、
前記基材の厚さTB、前記第1粘着剤層の厚さTA1、および前記第2粘着剤層の厚さTA2は、TBが100μm未満の場合にTB≦TA1≦TA2を充たし、TBが100μm以上の場合に2.5TB≦TA1≦TA2を充たす、光学用粘着シート。 - 前記第1粘着剤層の厚さは450μm以下である、請求項1に記載の光学用粘着シート。
- 前記第2粘着剤層の厚さは1000μm以下である、請求項1または2に記載の光学用粘着シート。
- 前記基材の厚さは150μm以下である、請求項1から3のいずれか一つに記載の光学用粘着シート。
- 前記第1粘着剤層および/または前記第2粘着剤層は、主剤としてアクリル系ポリマーを含有する、請求項1から4のいずれか一つに記載の光学用粘着シート。
- 前記第1粘着剤層および/または前記第2粘着剤層は、活性エネルギー線硬化型粘着剤組成物の硬化物である、請求項1から5のいずれか一つに記載の光学用粘着シート。
- ヘーズが5%以下である、請求項1から6のいずれか一つに記載の光学用粘着シート。
- 前記基材は、1500nm以上の面内位相差を有する、請求項1から7のいずれか一つに記載の光学用粘着シート。
- 請求項1から8のいずれか一つに記載の光学用粘着シートと偏光フィルムとの積層構造を有する、粘着剤層付偏光フィルム。
- 請求項1から8のいずれか一つに記載の光学用粘着シートを含む、液晶表示装置。
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