JP2017178901A - Makeup cosmetic for lips - Google Patents
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- JP2017178901A JP2017178901A JP2016072573A JP2016072573A JP2017178901A JP 2017178901 A JP2017178901 A JP 2017178901A JP 2016072573 A JP2016072573 A JP 2016072573A JP 2016072573 A JP2016072573 A JP 2016072573A JP 2017178901 A JP2017178901 A JP 2017178901A
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 36
- 229930006000 Sucrose Natural products 0.000 claims abstract description 12
- 239000005720 sucrose Substances 0.000 claims abstract description 12
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 10
- 239000002734 clay mineral Substances 0.000 claims abstract description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 9
- 239000000194 fatty acid Substances 0.000 claims abstract description 9
- 229930195729 fatty acid Natural products 0.000 claims abstract description 9
- -1 sucrose fatty acid ester Chemical class 0.000 claims abstract description 9
- 229940102552 disteardimonium hectorite Drugs 0.000 claims abstract description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
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- 230000014759 maintenance of location Effects 0.000 abstract description 7
- 230000003020 moisturizing effect Effects 0.000 abstract description 6
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 abstract description 5
- 235000010290 biphenyl Nutrition 0.000 abstract description 5
- 239000004305 biphenyl Substances 0.000 abstract description 5
- 125000006267 biphenyl group Chemical group 0.000 abstract description 5
- 229940008099 dimethicone Drugs 0.000 abstract description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 abstract description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 abstract description 5
- 229940090934 diphenylsiloxy phenyl trimethicone Drugs 0.000 abstract description 5
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 abstract description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 abstract description 5
- HOQCVZHXKCEGTC-CPNOTHRPSA-N [(2R,3R,4S,5R,6R)-6-[(2S,3S,4S,5R)-3,4-dihydroxy-2,5-bis(16-methylheptadecanoyloxymethyl)oxolan-2-yl]oxy-3,5-dihydroxy-4-(16-methylheptadecanoyloxy)oxan-2-yl]methyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC[C@H]1O[C@@](COC(=O)CCCCCCCCCCCCCCC(C)C)(O[C@H]2O[C@H](COC(=O)CCCCCCCCCCCCCCC(C)C)[C@@H](O)[C@H](OC(=O)CCCCCCCCCCCCCCC(C)C)[C@H]2O)[C@@H](O)[C@@H]1O HOQCVZHXKCEGTC-CPNOTHRPSA-N 0.000 abstract description 4
- 239000002562 thickening agent Substances 0.000 abstract description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 238000010186 staining Methods 0.000 abstract 1
- 238000012546 transfer Methods 0.000 description 29
- 230000000694 effects Effects 0.000 description 24
- 238000011156 evaluation Methods 0.000 description 21
- 239000003921 oil Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 6
- 238000013329 compounding Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 230000002265 prevention Effects 0.000 description 5
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 2
- 241000519695 Ilex integra Species 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- LPGFSDGXTDNTCB-UHFFFAOYSA-N [3-(16-methylheptadecanoyloxy)-2,2-bis(16-methylheptadecanoyloxymethyl)propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCC(C)C)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C LPGFSDGXTDNTCB-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- 241000871495 Heeria argentea Species 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229940094522 laponite Drugs 0.000 description 1
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 210000003296 saliva Anatomy 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
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- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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Abstract
Description
本発明は***用メーキャップ化粧料に関し、さらに詳しくは、色持ちが良く良好な保湿感とツヤを備え、色移りしにくい***用メーキャップ化粧料に関する。 The present invention relates to a makeup cosmetic for lips, and more particularly to a makeup cosmetic for lips that has good color retention and has a good moisturizing feeling and gloss, and is difficult to transfer colors.
口紅などの***用メーキャップ化粧料は、塗布面に好みの色調を付与し、油膜で覆うことで唇を華やかに見せながら保護する目的で利用される。従来、口紅を使用するに際し、カップなどに唇が触れると色落ちし、カップなどへの色移りが目立つことが問題視されてきた。そこで近年、口紅の色移りを改善するために様々な検討がなされてきた。
例えば、互いに相溶しない３種の液状油、色剤と親和性のある連続相油分、肌密着性油分、外層染み出し油分を配合することで、口紅を使用する際に外層染み出し油分のみがカップに触れるため色移りしない技術（特許文献１）、揮発性油分と撥水性ポリマーを組み合わせることで、色移りを防止しながらなめらかな塗り心地を保ちつつ、保水性を向上させる技術（特許文献２）、特定多価アルコール変性シリコーンとこれを相溶する特定のエステル油で水を添加混合した場合に相分離させることで、色移りを防止する技術（特許文献３）等があった。
しかしながら、特許文献１の技術では、塗布後に化粧膜が２層に分かれることにより色移り防止効果を出しているが、経時の色持ちが十分ではなかった。また、化粧直し時など口紅を再度塗布する際に上滑りし、色つきが悪くなる問題があった。特許文献２の技術では、揮発性油が蒸発した後に形成される皮膜により色移りしにくい効果が現れるが、乾燥感とつっぱり感が感じられ、塗布面のツヤが満足いくものではなかった。特許文献３の技術では、色移りしにくい効果が弱く、使用感がなめらか過ぎるために***の縦皺が目立つなどの仕上がりの点で満足いくものではなかった。
Makeup cosmetics for lips such as lipsticks are used for the purpose of protecting the lips while giving them a gorgeous color tone by covering them with an oil film. Conventionally, when using a lipstick, it has been regarded as a problem that the color of the lip is lost when the lip touches the cup and the color transfer to the cup is noticeable. In recent years, various studies have been made to improve the color transfer of lipstick.
For example, by blending three types of liquid oils that are incompatible with each other, a continuous phase oil component that is compatible with the colorant, a skin adhesion oil component, and an outer layer exuding oil component, only the outer layer exuding oil component is used when using lipstick. Technology that does not transfer color because it touches the cup (Patent Document 1), Technology that improves water retention while maintaining smooth coating comfort while preventing color transfer by combining volatile oil and water repellent polymer (Patent Document 2) ), A technology for preventing color transfer (Patent Document 3) and the like by phase separation when water is added and mixed with a specific polyhydric alcohol-modified silicone and a specific ester oil compatible with the specific polyhydric alcohol.
However, in the technique of Patent Document 1, although the decorative film is divided into two layers after application, an effect of preventing color migration is produced, but the color retention with time is not sufficient. In addition, there has been a problem that when the lipstick is reapplied, such as when re-applying, it slips up and the coloring becomes worse. In the technique of Patent Document 2, an effect that the color transfer is difficult to occur due to the film formed after the volatile oil is evaporated appears, but a dry feeling and a feeling of tension are felt, and the gloss of the coated surface is not satisfactory. The technique of Patent Document 3 is not satisfactory in terms of the finish such that the effect of difficult color transfer is weak and the feeling of use is too smooth, and the vertical lines of the lips are conspicuous.
ショ糖脂肪酸エステルは親水基のショ糖と、親油基の脂肪酸のエステルであり、一般的に乳化剤として用いられる。ワックス状、液状、ペースト状などさまざまな形状をしており、ＨＬＢは脂肪酸によって操作され用途によって選択される。***用メーキャップ化粧料に配合する素材としては公知の物質であり、良好な顔料分散性を有する。 Sucrose fatty acid esters are esters of hydrophilic sucrose and lipophilic fatty acids, and are generally used as emulsifiers. It has various shapes such as wax, liquid, and paste. HLB is manipulated by fatty acids and selected according to the application. It is a well-known substance as a raw material mix | blended with the makeup cosmetics for lips, and has favorable pigment dispersibility.
フェニル変性シリコーンは、シリコーンを主鎖としてフェニル基が側鎖状に単独または連続的に結合している。液状であり主に基材として用いられている。フェニル変性シリコーンはその他の油剤に比べて屈折率が高いため、発色を良好にすることから***用メーキャップ化粧料に使用されている。 The phenyl-modified silicone has silicone as a main chain, and phenyl groups are bonded in a side chain alone or continuously. It is liquid and is mainly used as a substrate. Phenyl-modified silicone has a higher refractive index than other oils, and is used in makeup cosmetics for lips because it improves color development.
粘土鉱物は増粘剤として用いられる。粘土鉱物由来で水と触れることで鉱物の層が解離し、電荷的な相互作用により全体を増粘させることができる。粘土鉱物は他の増粘剤と比べて耐熱性が優れる。しかし、***用メーキャップ化粧料に配合し、色移り防止効果を向上させる技術は知られていない。
Clay minerals are used as thickeners. The mineral layer dissociates when it comes from clay minerals and comes into contact with water, and the whole can be thickened by charge interaction. Clay minerals have superior heat resistance compared to other thickeners. However, a technique for improving the effect of preventing color transfer by blending in makeup cosmetics for lips is not known.
本発明は、***用メーキャップ化粧料に関し、特に色持ちが良く良好な保湿感とツヤを備え、色移りしにくい***用メーキャップ化粧料を提供することを課題とする。
The present invention relates to a makeup cosmetic for lips, and in particular, provides a makeup cosmetic for lips that has a good color retention and a good moisturizing feeling and gloss, and is difficult to transfer colors.
上記目的を達成するため、本発明者は、鋭意研究した結果、
成分（Ａ）：ショ糖脂肪酸エステル
成分（Ｂ）：フェニル変性シリコーン
成分（Ｃ）：粘土鉱物
を含有することによって、使用感を損なうことなく色移りしにくいことを見出し、本発明を完成するに至った。
In order to achieve the above object, the present inventor has intensively studied,
Component (A): Sucrose fatty acid ester component (B): Phenyl-modified silicone component (C): By containing clay mineral, it is found that color transfer is difficult without impairing the feeling of use, and the present invention is completed. It came.
本発明によれば、***用メーキャップ化粧料について色持ちが良く良好な保湿感とツヤを備え、色移りしにくい製剤を提供することができる。
ADVANTAGE OF THE INVENTION According to this invention, it can provide the formulation which has a good color retention and the favorable moisturizing feeling and gloss about the makeup cosmetics for lips, and does not transfer easily.
以下、本発明について更に詳しく説明する。 Hereinafter, the present invention will be described in more detail.
本発明の***用メーキャップ化粧料は、成分（Ａ）は成分（Ｃ）と親和性を有するのに対し、成分（Ｂ）が他の成分と親和性を有しないため単独で分離する。本発明の***用メーキャップ化粧料を***に塗布すると、分離した成分（Ｂ）は、***用メーキャップ化粧料の塗布面表面を覆うように染み出すと考えられる。成分（Ｂ）は透明であり、カップなどに***用メーキャップ化粧料を塗布した唇が触れると、透明な成分（Ｂ）のみがカップに付着する。このことから、カップへの色移りが防止される。 In the makeup cosmetic for lips of the present invention, the component (A) has an affinity for the component (C), whereas the component (B) does not have an affinity for other components, so that it is separated separately. When the makeup cosmetic for lips of the present invention is applied to the lips, it is considered that the separated component (B) oozes out so as to cover the application surface of the makeup cosmetic for lips. Ingredient (B) is transparent, and when a lip applied with makeup cosmetics for lips touches a cup or the like, only the transparent ingredient (B) adheres to the cup. This prevents color transfer to the cup.
本発明の***用メーキャップ化粧料は、ゲル構造中または固形ワックス中に液状油を保持した固形状でもよく、塗布直前に攪拌均一化して使用するような、流動性のある液状でもよい。どちらの場合でも、塗布後に透明な成分（Ｂ）が塗布面表面を覆うように染み出すことがわかっており、本発明の効果を得ることができる。
The makeup cosmetic for lips of the present invention may be in a solid form in which a liquid oil is held in a gel structure or in a solid wax, or may be in a fluid liquid form that is used with stirring and homogenization immediately before application. In either case, it is known that the transparent component (B) exudes so as to cover the surface of the coated surface after coating, and the effects of the present invention can be obtained.
本発明に用いられる成分（Ａ）ショ糖脂肪酸エステルは、高粘性の液状もしくはペースト状のものが好ましい。例えば、テトライソステアリン酸スクロースやヘキサイソステアリン酸スクロースなどから選択される。成分（Ａ）は市販品を使用しても良い。例えば、テトライソステアリン酸スクロースとしてＣＲＯＤＥＳＴＡ ４−ＩＳ、ヘキサイソステアリン酸スクロースとしてＣＲＯＤＥＳＴＡ ６−ＩＳ（クローダジャパン社製）などの名称で市販されているものが挙げられる。成分（Ａ）は、本発明の***用メーキャップ化粧料において一種を含有することもできるし、二種以上を組み合わせて含有することもできる。 The component (A) sucrose fatty acid ester used in the present invention is preferably a highly viscous liquid or paste. For example, sucrose tetraisostearate or sucrose hexaisostearate is selected. A commercial item may be used for a component (A). For example, what is marketed by names, such as CRODESTA 4-IS as tetraisostearic acid sucrose, and CRODESTA 6-IS (made by Croda Japan) as sucrose hexaisostearic acid, is mentioned. The component (A) can contain one kind in the makeup cosmetic for lips of the present invention, or can contain two or more kinds in combination.
本発明に用いられる成分（Ａ）の配合量は特に限定されないが、１０％〜４０％が好ましく、１３％〜２５％が更に好ましい。この範囲では肌への密着感や、色持ちなどの効果が顕著に発現でき、色移りしにくい効果が非常に良好である。 Although the compounding quantity of the component (A) used for this invention is not specifically limited, 10 to 40% is preferable and 13 to 25% is still more preferable. In this range, effects such as a feeling of close contact with the skin and color retention can be remarkably exhibited, and the effect of preventing color transfer is very good.
本発明に用いられる成分（Ｂ）フェニル変性シリコーンは、例えば、ジフェニルジメチコンやジフェニルシロキシフェニルトリメチコンなどから選択される。成分（Ｂ）の中には既に市販されているものがあり、本発明ではその様な市販品を利用することもできる。市販品としては、具体的にジフェニルジメチコンとしてＫＦ−５０−１００ｃｓ、ＫＦ−５０−３００ｃｓ、ＫＦ−５３、ＫＦ−５４。ジフェニルシロキシフェニルトリメチコンとしてＫＦ−５６Ａ（信越化学工業社製）などの名称で市販されているものなどが挙げられる。成分（Ｂ）は、本発明の***用メーキャップ化粧料において一種を含有することもできるし、二種以上を組み合わせて含有することもできる。 The component (B) phenyl-modified silicone used in the present invention is selected from, for example, diphenyl dimethicone and diphenylsiloxyphenyl trimethicone. Some components (B) are already commercially available, and such commercially available products can also be used in the present invention. As a commercial item, specifically KF-50-100cs, KF-50-300cs, KF-53, KF-54 as diphenyl dimethicone. Examples of the diphenylsiloxyphenyl trimethicone include those commercially available under names such as KF-56A (manufactured by Shin-Etsu Chemical Co., Ltd.). The component (B) can contain one kind in the makeup cosmetic for lips of the present invention, or can contain two or more kinds in combination.
本発明に用いられる成分（Ｂ）の配合量は特に限定されないが、２０％〜７５％が好ましく、３０％〜６５％が更に好ましい。この範囲ではツヤの発現、色持ち効果が十分に発揮され色移りしにくい効果が非常に良好である。 Although the compounding quantity of the component (B) used for this invention is not specifically limited, 20%-75% are preferable and 30%-65% are still more preferable. Within this range, the gloss and color retention effects are sufficiently exhibited and the effect of preventing color transfer is very good.
本発明に用いられる成分（Ｃ）粘土鉱物は、本発明では偶然にも成分（Ａ）および成分（Ｂ）との組み合わせ時に非常に色移りしにくい効果を増幅させる効果を示した。例えば、ケイ酸（Ｎａ／Ｍｇ）やジステアルジモニウムヘクトライトなどが挙げられる。粘土鉱物の種類としては極性を有するものが好ましい。***化粧料が唾液と触れることで粘土鉱物が電離すると、成分（Ｂ）以外の高極性成分と引き合う傾向があり、***用メーキャップ化粧料塗布後に成分（Ｂ）の分離を助けると考えられる。この様な成分（Ｃ）の中には既に市販されているものがあり、本発明ではその様な市販品を利用することもできる。市販品としては、ケイ酸（Ｎａ／Ｍｇ）としてラポナイトＸＬＧ（ＲＯＣＫＷＯＯＤ社製）などの名称で市販されているものが挙げられ、成分（Ａ）および成分（Ｂ）との組み合わせ時に良好な効果を示した。 In the present invention, the component (C) clay mineral used in the present invention has an effect of amplifying an effect that hardly causes color transfer when combined with the component (A) and the component (B). Examples thereof include silicic acid (Na / Mg) and disteardimonium hectorite. As the kind of clay mineral, those having polarity are preferable. When the clay mineral is ionized when the lip cosmetic comes into contact with saliva, it tends to attract high-polarity components other than the component (B), which is considered to help the separation of the component (B) after the makeup cosmetic for lips is applied. Some of such components (C) are already commercially available, and such commercially available products can also be used in the present invention. As a commercial item, what is marketed by names, such as Laponite XLG (made by ROCKWOOD), is mentioned as silicic acid (Na / Mg), and a good effect is obtained at the time of combination with component (A) and component (B). Indicated.
本発明に用いられる成分（Ｃ）の配合量は特に限定されないが、０．０５〜１％が好ましく、０．２％〜０．５％が更に好ましい。この範囲ではツヤの発現と色移りしにくい効果が非常に良好である。 Although the compounding quantity of the component (C) used for this invention is not specifically limited, 0.05 to 1% is preferable and 0.2% to 0.5% is still more preferable. In this range, the effect of gloss and color transfer is very good.
本発明の***用メーキャップ化粧料には、本発明の効果を損なわない範囲で、上記成分に加えて、化粧料において一般に用いられるその他の成分を配合してもよい。
In the makeup cosmetic for lips of the present invention, other components generally used in cosmetics may be blended in addition to the above-mentioned components within a range not impairing the effects of the present invention.
以下に実施例を挙げて、本発明を更に説明するが、これら実施例は本発明を何ら限定するものではない。配合量の数値はいずれも質量％である。なお、特記しない限りは化粧料全体で１００％となるように配合量を表示している。 The present invention will be further described with reference to the following examples. However, these examples do not limit the present invention. The numerical values of the amounts are all mass%. Unless otherwise specified, the blending amount is displayed so that the entire cosmetic is 100%.
効果の測定は以下の評価法によった。
[色移り防止効果評価方法]
表１、表２に示した各サンプルを容器に充填し０．１ｇを肌上に塗布する。塗布部に透明のプラスチック板を貼り、はがした後のプラスチック板への***用メーキャップ化粧料の色移りの程度を評価した。参考のため、プラスチック板面における色移り程度の評価基準を図１に示した。なお、色移り防止効果を示さなかったサンプルについては以降の試験を実施していない。
［色移り防止効果評価基準］
◎：大変良好（色移りなし）
○：良好（軽度の色移りあり）
△：やや悪い（色移りあり）
×：悪い（重度の色移りあり）
The effect was measured by the following evaluation method.
[Evaluation method for color transfer prevention effect]
Each sample shown in Table 1 and Table 2 is filled in a container, and 0.1 g is applied onto the skin. A transparent plastic plate was attached to the application part, and the degree of color transfer of the makeup cosmetic for lips onto the plastic plate after peeling was evaluated. For reference, an evaluation standard of the degree of color transfer on the plastic plate surface is shown in FIG. In addition, the subsequent test was not implemented about the sample which did not show the color transfer prevention effect.
[Evaluation criteria for color transfer prevention effect]
A: Very good (no color transfer)
○: Good (there is slight color transfer)
Δ: Slightly bad (there is color transfer)
×: Poor (there is severe color transfer)
[ツヤ評価方法]
表１、表２に示した各サンプルを容器に充填し、官能評価でもって評価した。化粧品評価専門パネル５名に使用してもらい、以下の基準に従って５段階評価し、化粧料毎に評点を付し、さらに全パネルの評点の平均点を以下の４段階の判断基準に従って判定した。
[ツヤ評価基準]
評価結果 ： 評点
非常に良好 ： ５点
良好 ： ４点
普通 ： ３点
やや不良 ： ２点
不良 ： １点
[判定基準]
評点の平均点 ： 判定
４．５以上 ： ◎
３．５以上〜４．５未満 ： ○
１．５以上〜３．５未満 ： △
〜１．５未満 ： ×
[Glossy evaluation method]
Each sample shown in Table 1 and Table 2 was filled in a container and evaluated by sensory evaluation. Five panelists specializing in cosmetics evaluation were used, evaluated according to the following criteria, graded according to the following criteria, scored for each cosmetic, and the average score of all the panels was judged according to the following criteria of the four grades.
[Glossy evaluation criteria]
Evaluation results: Score very good: 5 points good: 4 points Normal: 3 points Somewhat bad: 2 points bad: 1 point
[Criteria]
Average score: Judgment 4.5 or higher: ◎
3.5 or more and less than 4.5: ○
1.5 or more and less than 3.5: △
Less than ~ 1.5: ×
[保湿性評価方法]
表１、表２に示した各サンプルを容器に充填し、官能評価に供した。化粧品評価専門パネル５名に使用してもらい、以下の基準に従って５段階評価し、化粧料毎に評点を付し、さらに全パネルの評点の平均点を以下の４段階の判断基準に従って判定した。
[保湿性評価基準]
評価結果 ： 評点
非常に良好 ： ５点
良好 ： ４点
普通 ： ３点
やや不良 ： ２点
不良 ： １点
[判定基準]
評点の平均点 ： 判定
４．５以上 ： ◎
３．５以上〜４．５未満 ： ○
１．５以上〜３．５未満 ： △
〜１．５未満 ： ×
[Moisturizing evaluation method]
Each sample shown in Table 1 and Table 2 was filled in a container and subjected to sensory evaluation. Five panelists specializing in cosmetics evaluation were used, evaluated according to the following criteria, graded according to the following criteria, scored for each cosmetic, and the average score of all the panels was judged according to the following criteria of the four grades.
[Moisturizing evaluation criteria]
Evaluation results: Score very good: 5 points good: 4 points Normal: 3 points Somewhat bad: 2 points bad: 1 point
[Criteria]
Average score: Judgment 4.5 or higher: ◎
3.5 or more and less than 4.5: ○
1.5 or more and less than 3.5: △
Less than ~ 1.5: ×
[色もち評価方法]
各サンプルを容器に充填し、０．１ｇを***上に塗布して３時間後の官能評価でもって評価した。化粧品評価専門パネル５名に使用してもらい、以下の基準に従って５段階評価し、化粧料毎に評点を付し、さらに全パネルの評点の平均点を以下の４段階の判断基準に従って判定した。
[色もち評価基準]
評価結果 ： 評点
非常に良好 ： ５点
良好 ： ４点
普通 ： ３点
やや不良 ： ２点
不良 ： １点
[判定基準]
評点の平均点 ： 判定
４．５以上 ： ◎
３．５以上〜４．５未満 ： ○
１．５以上〜３．５未満 ： △
〜１．５未満 ： ×
[Color mochi evaluation method]
Each sample was filled in a container, 0.1 g was applied on the lips, and evaluated by sensory evaluation after 3 hours. Five panelists specialized in cosmetics evaluation used it, evaluated it in five levels according to the following criteria, assigned a score for each cosmetic, and determined the average score of all the panels according to the following four criteria.
[Color mochi evaluation criteria]
Evaluation results: Score very good: 5 points good: 4 points Normal: 3 points Somewhat bad: 2 points bad: 1 point
[Criteria]
Average score: Judgment 4.5 or higher: ◎
3.5 or more and less than 4.5: ○
1.5 or more and less than 3.5: △
Less than ~ 1.5: ×
以下に、評価結果の表を示す。
The table of evaluation results is shown below.
表１〜表２に示す組成で実施例１〜３および比較例１〜９の***用メーキャップ化粧料を常法にて調製した。 The makeup cosmetics for lips of Examples 1 to 3 and Comparative Examples 1 to 9 having the compositions shown in Tables 1 and 2 were prepared by a conventional method.
実施例より明らかなように、本発明の成分を用いた***用メーキャップ化粧料はいずれも優れた性能を示していた。 As is clear from the examples, all makeup cosmetics for lips using the components of the present invention exhibited excellent performance.
成分（Ａ）を含まない比較例１〜４、成分（Ｂ）を含まない比較例５〜６はそれぞれ色移り防止効果が非常に悪い。また、成分（Ｃ）を含まない比較例７〜９は色移り防止効果が弱くなる傾向が見てとれる。 In Comparative Examples 1 to 4 that do not contain the component (A) and Comparative Examples 5 to 6 that do not contain the component (B), the effect of preventing color migration is very poor. Moreover, the comparative examples 7-9 which do not contain a component (C) can see the tendency for a color transfer prevention effect to become weak.
成分（Ａ）と成分（Ｂ）は高温で均一な状態、低温で分離する関係である。これにより充填・成型時には均一状態を保ちつつ、塗布時にワックス構造を壊されることによって２成分が開放され分離すると考えられる。この分離をもって***上で透明層と色層に分かれるため色移り防止効果を発揮される。
更に成分（Ｃ）を加えることによって上記分離が促進されることがわかった。塗布後の成分（Ａ）と成分（Ｂ）の分離がより促進されることにより、色移り防止効果を向上させることが可能となったと考えられる。
Component (A) and component (B) are in a uniform state at a high temperature and are separated at a low temperature. Thereby, it is considered that the two components are released and separated by breaking the wax structure at the time of application while maintaining a uniform state at the time of filling and molding. With this separation, it is divided into a transparent layer and a color layer on the lips, thereby exhibiting an effect of preventing color migration.
Further, it was found that the separation was promoted by adding the component (C). It is considered that the effect of preventing color transfer can be improved by further promoting the separation of the component (A) and the component (B) after coating.
＜処方例＞
常法にて、各処方の組成物を作製した。いずれの処方においても、問題なく本発明の効果を示した。
＜口紅＞
成分名 配合量（%）
１．テトライソステアリン酸スクロース： １８
２．テトラ（ヒドロキシステアリンサン／イソステアリン酸）ジペンタエリスリチル：５
３．ジフェニルジメチコン： ４０
４．ジフェニルシロキシフェニルトリメチコン： ５
５．テトライソステアリン酸ペンタエリスリチル： １２
６．水添ポリデセン： ７．１５
７．ポリエチレン： ５
８．合成ワックス： ２
９．ケイ酸（Ｎａ／Ｍｇ）： ０．２５
１０．赤色２０２号： １．５
１１．酸化チタン： １．８
１２．マイカ： ２．３
合計： １００
＜口紅＞
成分名 配合量（%）
１．テトライソステアリン酸スクロース： １３
２．テトラ（ヒドロキシステアリンサン／イソステアリン酸）ジペンタエリスリチル：６
３．ジフェニルジメチコン： ４４
４．ジフェニルシロキシフェニルトリメチコン： ５
５．テトライソステアリン酸ペンタエリスリチル： １２
６．水添ポリデセン： ７．４
７．ポリエチレン： ６
８．合成ワックス： １
９．ケイ酸（Ｎａ／Ｍｇ）： ０．５
１０．赤色２０２号： １．５
１１．黄色４号： ０．８
１２．酸化チタン： ２．８
合計： １００
<Prescription example>
The composition of each prescription was produced by the conventional method. In any formulation, the effect of the present invention was shown without any problem.
<Lipstick>
Ingredient name Compounding amount (%)
1. Sucrose tetraisostearate: 18
2. Tetra (hydroxystearic acid / isostearic acid) dipentaerythrityl: 5
3. Diphenyl dimethicone: 40
4). Diphenylsiloxyphenyl trimethicone: 5
5). Pentaerythrityl tetraisostearate: 12
6). Hydrogenated polydecene: 7.15
7). Polyethylene: 5
8). Synthetic wax: 2
9. Silicic acid (Na / Mg): 0.25
10. Red No. 202: 1.5
11. Titanium oxide: 1.8
12 Mica: 2.3
Total: 100
<Lipstick>
Ingredient name Compounding amount (%)
1. Sucrose tetraisostearate: 13
2. Tetra (hydroxystearic acid / isostearic acid) dipentaerythrityl: 6
3. Diphenyl dimethicone: 44
4). Diphenylsiloxyphenyl trimethicone: 5
5). Pentaerythrityl tetraisostearate: 12
6). Hydrogenated polydecene: 7.4
7). Polyethylene: 6
8). Synthetic wax: 1
9. Silicic acid (Na / Mg): 0.5
10. Red No. 202: 1.5
11. Yellow No. 4: 0.8
12 Titanium oxide: 2.8
Total: 100
Claims (3)
成分（Ｂ）：フェニル変性シリコーン
成分（Ｃ）：粘土鉱物
を含有する***用メーキャップ化粧料。 Component (A): Sucrose fatty acid ester component (B): Phenyl-modified silicone component (C): Makeup cosmetic for lips containing clay mineral.
成分（Ｂ）：フェニル変性シリコーン
成分（Ｃ）：合成ヘクトライト
を含有する***用メーキャップ化粧料。 Component (A): Sucrose fatty acid ester component (B): Phenyl-modified silicone component (C): Makeup cosmetic for lips containing synthetic hectorite.
成分（Ｂ）：フェニル変性シリコーン
成分（Ｃ）：ケイ酸（Ｎａ／Ｍｇ）、ジステアルジモニウムヘクトライトから選ばれる１種または２種
を含有する***用メーキャップ化粧料。
Component (A): Sucrose fatty acid ester component (B): Phenyl-modified silicone component (C): Makeup for lips containing one or two selected from silicic acid (Na / Mg) and disteardimonium hectorite Cosmetics.
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|---|---|---|---|
| JP2016072573A JP6470698B2 (en) | 2016-03-31 | 2016-03-31 | Makeup cosmetics for lips |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016072573A JP6470698B2 (en) | 2016-03-31 | 2016-03-31 | Makeup cosmetics for lips |
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| Publication Number | Publication Date |
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| JP2017178901A true JP2017178901A (en) | 2017-10-05 |
| JP6470698B2 JP6470698B2 (en) | 2019-02-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
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| JPS49134846A (en) * | 1973-05-08 | 1974-12-25 | ||
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|---|---|
| JP6470698B2 (en) | 2019-02-13 |
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