JP2017109930A - 液状皮膚化粧料組成物 - Google Patents
液状皮膚化粧料組成物 Download PDFInfo
- Publication number
- JP2017109930A JP2017109930A JP2015243168A JP2015243168A JP2017109930A JP 2017109930 A JP2017109930 A JP 2017109930A JP 2015243168 A JP2015243168 A JP 2015243168A JP 2015243168 A JP2015243168 A JP 2015243168A JP 2017109930 A JP2017109930 A JP 2017109930A
- Authority
- JP
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- Prior art keywords
- meth
- cosmetic composition
- component
- liquid skin
- skin cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 229960003921 octisalate Drugs 0.000 description 1
- WCJLCOAEJIHPCW-UHFFFAOYSA-N octyl 2-hydroxybenzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1O WCJLCOAEJIHPCW-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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Abstract
Description
従って、本発明の課題は、含有している粉体の再分散性に優れ、さらさら感、清涼感も良好な液状皮膚化粧料を提供することにある。
(A)圧縮強度が0.7〜10kgf/mm2である架橋(メタ)アクリル酸エステル系樹脂粉体、
(B)親水性シリカ、
(C)有機酸又はその塩及び
(D)エタノール
を含有する液状皮膚化粧料組成物を提供するものである。
樹脂粒子の圧縮強度は、樹脂粒子を構成する単量体と架橋剤の種類と配合量を制御することにより、適宜調節することができる。
なお、本明細書において、「(メタ)アクリル」とは、アクリル及びメタクリルの両方を含む概念である。
本発明の架橋(メタ)アクリル酸エステル系樹脂粉体の好ましい製造法としては、例えば特開2006−225311号公報のものが挙げられる。
これらの親水性シリカの平均粒子径は、再分散性、使用感、肌上でのさらさら感を得る観点から、1〜30μmが好ましく、1〜20μmがより好ましい。本発明において、平均粒子径は、レーザー回折型粒径分布測定装置で測定される体積平均粒子径である。
また、親水性シリカの比表面積は、再分散性、使用感、肌上でのさらさら感を得る観点から、50〜2000m2/gが好ましく、100〜1500m2/gがより好ましく、100〜900m2/gがさらに好ましく、400〜900m2/gがさらにより好ましい。ここで、比表面積は、BET法により測定できる。
また、同様の観点から、本発明の液状皮膚化粧料組成物中、成分(B)親水性シリカに対する疎水性シリカの含有割合(疎水性シリカ/親水性シリカ)は、0〜0.4が好ましく、0〜0.1がより好ましく、0〜0.01がさらに好ましく、実質0であることがさらにより好ましい。
(E)水溶性高分子としては、カルボキシビニルポリマー、アクリル酸/メタクリル酸アルキル共重合体、メチルセルロース、エチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース等が挙げられる。このうち、アクリル酸/メタクリル酸アルキル共重合体が好ましい。アクリル酸/メタクリル酸アルキル共重合体の市販品としては、例えば、Noveon Inc.社製のPEMULEN TR−1、PEMULEN TR−2、Carbopol ETD2020等を挙げることができる。
(F)水の液状皮膚化粧料中の含有量は、再分散性、さらさら感、さっぱり感を得る観点から20〜90質量%が好ましく、30〜80質量%がより好ましく、30〜75質量%がさらに好ましい。
紫外線散乱剤は、粉体状であり、前述の(B)以外の他の粉体である。
紫外線吸収剤の中で、粉体状のものは、前述の(B)以外の他の粉体である。
表1記載の化粧料を製造し、再分散性、さらさら感及び冷涼感を評価した。その結果を表1に示す。
成分(F)に成分(C)を混合・撹拌し溶解する。溶解を確認後、成分(A)、成分(B)、成分(E)を混合撹拌し、溶解・分散を確認する。得られた混合液を水相1とする。その後成分(D)にその他の成分を混合させて上述の水相1に混合撹拌し、液状組成物を得る。
50mL容量のガラス瓶に、水10g、ヘキサン10g、及び粉体1gを添加し、蓋を閉め、手で軽くガラス瓶を振り水、ヘキサン及び粉体を混合する。その後、該ガラス瓶を超音波洗浄機(38kHz)で2分間超音波処理をし、その後5分間静置し、外観を目視にて観察する。水とヘキサンの界面を基準に、粉体が下側(水)に存在する場合を親水性、上側(ヘキサン)に存在する場合を疎水性と判断する。
(再分散性の評価)
無色透明なガラス瓶(100mL)にサンプルを(90mL)調製し、密閉して−5℃で一ヶ月保存した。その後、粉体の再分散性を評価するために、保存した瓶を、一秒で逆さにして一秒で元に戻す操作を繰り返し、瓶底に沈降している粉体の分散状態を目視で観察した。一秒で逆さにして一秒で元に戻す操作を1回の再分散工程とし、粉体再分散されまでこの再分散工程を繰り返し、この工程の回数を下記基準にしたがって評価した。回数の少ないほど、再分散性に優れることを意味する。
◎:5回以内
○:6回以上10回以内
△:11回以上15回以内
×:16回以上
3名の専門パネルによる官能評価を行い、以下の評価点基準に基づき評価する。
ついで、各人がつけた評価点を合計し、以下の評価基準に基づき評価すする。
評価点基準
非常にサラサラと感じる場合を5点、非常に違和感を感じる場合を1点とし5点評価した。
評価基準
◎:14点以上
○:12点以上14点未満
△:9点以上12点未満
×:9点未満
3名の専門パネルによる官能評価を行い、以下の評価点基準に基づき評価する。
ついで、各人がつけた評価点を合計し、以下の評価基準に基づき評価すする
評価点基準
非常に冷涼感がある場合を5点、冷涼感がない場合を1点として5点評価した。
評価基準
◎:14点以上
○:12点以上14点未満
△:9点以上12点未満
×:9点未満
6名のボランティアによる官能評価を行い、以下の評価点基準に基づき評価する。
ついで、各人がつけた評価点を合計し、以下の評価基準に基づき評価すする。
塗布のしやすさは、手に取った感じと、肌への転写性、のびの良さは肌へなじませた時の感じで評価した。
評価点基準
3点:良い
2点:どちらとも言えない
1点:悪い
評価基準
◎:15点以上
○:12点以上14点未満
△:10点以上12点未満
×:10点未満
*2:サンスフェア H−52(親水性シリカ、AGCエスアイテック社製、平均粒径5μm、比表面積700m2/g)
*3:サンスフェア H−121(親水性シリカ、AGCエスアイテック社製、平均粒径12μm、比表面積800m2/g)
*4:VM−2270 Aerogel fine Partticle(疎水性シリカ、Dow Corning社製、平均粒径10μm、比表面積700m2/g)
*5:ペムレン TR−1(Lubrizol Advanced Material
*6:ニッコール PEN−4630(日本サーファクタント工業社製)
*7:エマルゲン 108(花王社製)
*8:シリコーン KF−96L−2CS(−G)(信越化学工業社製)
*9:シリコーン KF−96A−10CS(−G)(信越化学工業社製)
*10:シリコーン SS−2804(東レ・ダウコーニング社製)
s,Inc製)
なお、塗布しやすさ、のびの良さに関しては、実施例1、2、3、4、5、10及び11の化粧料が良好であり、実施例10及び11が特に良好であった。
Claims (7)
- 次の成分(A)、(B)、(C)及び(D):
(A)圧縮強度が0.7〜10kgf/mm2である架橋(メタ)アクリル酸エステル系樹脂粉体、
(B)親水性シリカ、
(C)有機酸又はその塩及び
(D)エタノール
を含有する液状皮膚化粧料組成物。 - 成分(C)が、クエン酸又はその塩を含む請求項1記載の液状皮膚化粧料組成物。
- 成分(B)に対する成分(A)の質量比(A/B)が、100〜1である請求項1又は2記載の液状皮膚化粧料組成物。
- 成分(C)に対する成分(A)と成分(B)との合計の含有質量比[(A+B)/C]が、200〜1である請求項1〜3のいずれか1項記載の液状皮膚化粧料組成物。
- さらに成分(E)水溶性高分子を含有する請求項1〜4のいずれか1項記載の液状皮膚化粧料組成物。
- さらに成分(F)水を含有する請求項1〜5のいずれか1項記載の液状皮膚化粧料組成物。
- デオドラント液状皮膚化粧料組成物である請求項1〜6のいずれか1項記載の液状皮膚化粧料組成物。
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JP2020200249A (ja) * | 2019-06-06 | 2020-12-17 | 花王株式会社 | 大気有害物質付着抑制剤 |
WO2022215728A1 (ja) * | 2021-04-08 | 2022-10-13 | 花王株式会社 | シート状化粧料 |
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