JP2017019742A - エアゾール整髪剤 - Google Patents
エアゾール整髪剤 Download PDFInfo
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- JP2017019742A JP2017019742A JP2015138045A JP2015138045A JP2017019742A JP 2017019742 A JP2017019742 A JP 2017019742A JP 2015138045 A JP2015138045 A JP 2015138045A JP 2015138045 A JP2015138045 A JP 2015138045A JP 2017019742 A JP2017019742 A JP 2017019742A
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- meth
- acid ester
- mass
- sucrose
- aromatic monocarboxylic
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- 239000000443 aerosol Substances 0.000 title claims abstract description 30
- -1 sucrose aromatic monocarboxylic acid ester Chemical class 0.000 claims abstract description 42
- 229930006000 Sucrose Natural products 0.000 claims abstract description 32
- 239000005720 sucrose Substances 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 239000011347 resin Substances 0.000 claims abstract description 25
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000003380 propellant Substances 0.000 claims abstract description 11
- 125000004185 ester group Chemical group 0.000 claims abstract description 10
- 238000004140 cleaning Methods 0.000 abstract 1
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- 238000005160 1H NMR spectroscopy Methods 0.000 description 5
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- 238000006467 substitution reaction Methods 0.000 description 5
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 4
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- 125000000217 alkyl group Chemical group 0.000 description 3
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- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
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- 125000000129 anionic group Chemical group 0.000 description 2
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- 238000006243 chemical reaction Methods 0.000 description 2
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- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
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- 238000011049 filling Methods 0.000 description 2
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- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
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- KFYRJJBUHYILSO-YFKPBYRVSA-N (2s)-2-amino-3-dimethylarsanylsulfanyl-3-methylbutanoic acid Chemical compound C[As](C)SC(C)(C)[C@@H](N)C(O)=O KFYRJJBUHYILSO-YFKPBYRVSA-N 0.000 description 1
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- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- JQEBZBUGQPSANC-UHFFFAOYSA-N 3-methoxy-2-methylprop-2-enoic acid Chemical compound COC=C(C)C(O)=O JQEBZBUGQPSANC-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
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- 101001039157 Homo sapiens Leucine-rich repeat-containing protein 25 Proteins 0.000 description 1
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- 102100040695 Leucine-rich repeat-containing protein 25 Human genes 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
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- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
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- 235000021355 Stearic acid Nutrition 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
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- 150000001298 alcohols Chemical class 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- KWABLUYIOFEZOY-UHFFFAOYSA-N dioctyl butanedioate Chemical compound CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC KWABLUYIOFEZOY-UHFFFAOYSA-N 0.000 description 1
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- Cosmetics (AREA)
Abstract
【解決手段】皮膜形成樹脂(A)、ショ糖芳香族モノカルボン酸エステル(B)および噴射剤(C)を含有するエアゾ−ル整髪剤である。前記ショ糖芳香族モノカルボン酸エステル(B)は、前記皮膜形成樹脂(A)100質量部に対して5〜150質量部であることが好ましい。前記ショ糖芳香族モノカルボン酸エステル(B)は、平均エステル基数が2.5〜8.0であることが好ましい。
【選択図】なし
Description
(A−1) アクリル酸アルキル/ジアセトンアクリルアミドコポリマーAMP(商品名:プラスサイズ L−9540B、互応化学工業社製)
(A−2)(アクリレーツ/アクリル酸アルキル(C1−18)/アルキル(C1−8)アクリルアミド)コポリマーAMP(商品名:プラスサイズL−9909B、互応化学工業社製)
(合成例1)
[(B−1)ショ糖安息香酸エステル(平均エステル基数:6.1]
撹拌棒、温度計、冷却コンデンサ−、滴下漏斗、およびpHメ−タ−に接続したpH電極を備えた5つ口フラスコに、ショ糖30.0質量部と水70.0質量部を仕込み溶解した後、水浴で10℃以下に冷却しながら、塩化ベンゾイル77.6質量部とシクロヘキサノン100質量部との混合物を徐々に加え、均一に溶かした。20℃以下の温度を保ちながら、48%苛性ソ−ダ水溶液43.2質量部を、滴下漏斗よりpHが10〜11に保たれるような速度で加えた。滴下は1時間以内で終了した。その後、水浴を取り去り、20〜30℃の室温で、1時間撹拌を続け熟成して反応を完結させた。その後、若干量の炭酸ソ−ダを加え加熱して、微量に残っている塩化ベンゾイルを安息香酸ソ−ダに変換した。そして溶媒をロ−タリ−エバポレ−タ−により除去することにより、ショ糖安息香酸エステルを得た。平均置換度を1H−NMRによって求めたところ、6.1であった。
[(B−2)ショ糖安息香酸エステル(平均エステル基数:4.5)]
塩化ベンゾイルの使用量を55.5質量部とした以外は合成例1と同様の操作を行い、ショ糖安息香酸エステルを得た。平均置換度を1H−NMRによって求めたところ、4.5であった。
[(B−3)ショ糖安息香酸エステル(平均エステル基数:3.2)]
塩化ベンゾイルの使用量を39.4質量部とした以外は合成例1と同様の操作を行い、ショ糖安息香酸エステルを得た。平均置換度を1H−NMRによって求めたところ、3.2であった。
[(B−4)ショ糖トルイル酸エステル(平均エステル基数:6.3)]
塩化ベンゾイルに代えてトルイル酸クロライド85.4質量部とした以外は合成例1と同様の操作を行い、ショ糖安息香酸エステルを得た。平均置換度を1H−NMRによって求めたところ、6.3であった。
[(B−5)ショ糖トルイル酸エステル(平均エステル基数:5.0)]
塩化ベンゾイルに代えてトルイル酸クロライド144.4質量部とした以外は合成例1と同様の操作を行い、ショ糖安息香酸エステルを得た。平均置換度を1H−NMRによって求めたところ、3.0であった。
(C−1)ジメチルエーテル(DME)
(D−1)エタノール
(D−2)トリオクタン酸グリセリル
表1に記載の配合で、皮膜形成樹脂(A)、ショ糖芳香族モノカルボン酸エステル(B)およびその他の成分を混合し、エアゾール整髪剤原液を得た。このエアゾール整髪剤原液100質量部およびジメチルエーテル150質量部を耐圧容器(ガラス製)に充填することにより、エアゾール整髪剤を得た。得られたエアゾール整髪剤を用いて、カール保持力および洗浄性を下記の基準で評価した。結果を表1に示す。
長さ25cmの毛束2gを水で濡らし、タオルドライ後、直径2cmのロッドに巻きつけて自然乾燥させた。ロッドを外してカールをほぐした後、20cmの距離からヘアスプレーをスプレーして乾燥させた。これを、25℃、90%RH環境下に6時間つるした後、毛束の長さを測定し、試験前の毛束の長さに対する伸び率(%)を算出し、下記の基準で評価した。結果を表1に示す。なお、伸び率が低いほど、カール保持力が優れる(ヘアスタイルが維持できる)ことを示す。
A:0%以上25%未満
B:25%以上35%未満
C:35%以上45%未満
D:45%以上60%未満
E:60%以上
上記カール保持力で評価した毛束を、シャンプーで洗髪した後、ドライヤーを用いて乾燥した。乾燥後の毛束について、10人のパネラーによる官能試験を下記の基準で行い、その平均値を算出した。
3:ヘアスプレーが残っていない
2:ヘアスプレーがほとんど残っていない
1:ヘアスプレーが残っている
上記算出した平均値に基づいて、下記の基準で評価した。結果を表1に示す。
A:平均値が2.5点以上
B:平均値が2点以上2.5点未満
C:平均値が2点未満
Claims (3)
- 皮膜形成樹脂(A)、ショ糖芳香族モノカルボン酸エステル(B)および噴射剤(C)を含有するエアゾ−ル整髪剤。
- 前記ショ糖芳香族モノカルボン酸エステル(B)が、前記皮膜形成樹脂(A)100質量部に対して5〜150質量部である請求項1に記載のエアゾ−ル整髪剤
- 前記ショ糖芳香族モノカルボン酸エステル(B)が、平均エステル基数2.5〜8.0である請求項1または2に記載のエアゾ−ル整髪剤。
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KR20190097144A (ko) | 2017-08-28 | 2019-08-20 | 가부시키가이샤 만다무 | 에어로졸 스프레이 정발제 조성물 및 에어로졸 스프레이 정발제 |
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