JP2016530991A - 腐植質のフルボ試薬を使用して温室ガスを濾過し再利用するための方法 - Google Patents
腐植質のフルボ試薬を使用して温室ガスを濾過し再利用するための方法 Download PDFInfo
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- JP2016530991A JP2016530991A JP2016531857A JP2016531857A JP2016530991A JP 2016530991 A JP2016530991 A JP 2016530991A JP 2016531857 A JP2016531857 A JP 2016531857A JP 2016531857 A JP2016531857 A JP 2016531857A JP 2016530991 A JP2016530991 A JP 2016530991A
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Classifications
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Abstract
Description
本発明は、ガスを濾過することに、より詳細には、腐植質のフルボ濾過試薬(a humic and fulvic filter reagent)を使用して、ガス供給源から有害な汚染物質を濾過し再利用する方法に関する。
本発明の一側面において、ガスを濾過する方法は、以下:ガスを、腐植質のフルボ物質(humic and fulvic substance)を含む高度にアルカリ化された液体濾過試薬に通すこと、を含む。
本発明の別の側面において、濾過の方法は、以下:ガス流体を、腐植質のフルボ物質を含む高度にアルカリ化された液体濾過試薬に通し、使用済みの高度にアルカリ化された液体濾過試薬を形成すること;および、使用済みの高度にアルカリ化された液体濾過試薬を架橋して、固形化したフィルターを形成すること、を含む。
本発明の、これらのおよび他の特徴、側面ならびに利点は、以下の図面、説明および特許請求の範囲を参照してより良く理解されるようになるであろう。
以下の詳細な説明は、本発明の例示的な態様を実行するのに最良であると現在考えられている実施法についてである。説明は、限定する意味で取られるべきではないが、本発明の範囲が添付の特許請求の範囲によって最良に定義されているため、本発明の一般原理を解説する目的のみでなされている。
試験を、合成ガスならびに炭燃焼ガスを用いて行った。小規模試験の略図を図1に解説する。液体の腐植質のフルボ濾過試薬を、ガラスビーズで満たされたカラム反応器へ加えた。液体の腐植質のフルボ濾過試薬で満たされたカラム反応器を、周囲条件に保つ。組成(重量%):H2 4.5%、CO 10%、N2 25%、CO2 30.5%、CH4 30%を有する、ガスシリンダー中で予め混合された合成ガスを、カラム反応器の底から通過させた。ガスサンプルを、ガスクロマトグラフによるCO2、SOxおよびNOxの分析のために処置の前後でセプタムから取った。処置されたガス体積を、水置換方法によって測定する。
臭気のための試験において、アンモニア対照およびそれらの形成の緩和を、密閉されたチャンバー内の家禽敷料(poultry litter)上に、液体の腐植質のフルボ試薬を噴霧することによって試験した。アンモニアレベルは最初、敷料中のアンモニアを生成する化学物質が加水分解されたため、平均50ppmから100ppmまで上昇したが、24時間以内にアンモニアレベルが、規制限度を満たすのに必要な平均25ppmレベルまで減少した。処置された敷料の分析においてもまた、臭気化学物質を形成するのみならず、疾患をも増加させる、クロストリジウム菌、芽胞およびサルモネラ菌が除去されていた。
Claims (20)
- ガスを、腐植質のフルボ物質を含む高度にアルカリ化された液体濾過試薬に通すこと
を含む、ガスを濾過する方法。 - 高度にアルカリ化された液体濾過試薬が、アルカリ性溶液と組み合わせた腐植質のフルボ酸から形成される、請求項1に記載の方法。
- アルカリ性溶液が、水酸化カリウム、水酸化ナトリウム、水酸化アンモニウムまたはそれらの組み合わせを含む、請求項2に記載の方法。
- ガスが、ガス流体である、請求項1に記載の方法。
- 高度にアルカリ化された濾過試薬が、ガス流体から複数の夾雑物を除去する、請求項5に記載の方法。
- 複数の夾雑物が、二酸化炭素、硫黄酸化物、窒素酸化物、硫化水素、メルカプタン、アンモニア、放射性核種、有害金属、微粒子、揮発性の蒸気および有機物を含む、請求項6に記載の方法。
- 高度にアルカリ化された濾過試薬にガスを通すことによって、使用済みの高度にアルカリ化された濾過試薬を形成するステップをさらに含む、請求項1に記載の方法。
- 使用済みの高度にアルカリ化された濾過試薬を架橋して、固形化したフィルターを形成するステップをさらに含む、請求項6に記載の方法。
- 固形化したフィルターを使用して水性物質を濾過するステップをさらに含む、請求項7に記載の方法。
- 高度にアルカリ化された液体濾過試薬が、0.5Nより大きいかまたは等しい規定度を含む、請求項1に記載の方法。
- 高度にアルカリ化された液体濾過試薬が、多機能性固体、遷移金属、遷移金属錯体またはそれらの組み合わせを含む触媒を含む、請求項1に記載の方法。
- ガス流体を、腐植質のフルボ物質を含む高度にアルカリ化された液体濾過試薬に通し、使用済みの高度にアルカリ化された液体濾過試薬を形成すること;および、
使用済みの高度にアルカリ化された液体濾過試薬を架橋して、固形化したフィルターを形成すること
を含む、濾過の方法。 - 高度にアルカリ化された液体濾過試薬が、アルカリ性溶液と組み合わせて、腐植質のフルボ酸から形成される、請求項12に記載の方法。
- アルカリ性溶液が、水酸化カリウム、水酸化ナトリウム、水酸化アンモニウムまたはそれらの組み合わせを含む、請求項13に記載の方法。
- 高度にアルカリ化された濾過試薬が、ガス流体から複数の夾雑物を除去する、請求項12に記載の方法。
- 複数の夾雑物が、二酸化炭素、硫黄酸化物、窒素酸化物、硫化水素、メルカプタン、アンモニア、放射性核種、有害金属、微粒子、揮発性の蒸気および有機物を含む、請求項15に記載の方法。
- 固形化したフィルターを使用して水性物質を濾過するステップをさらに含む、請求項12に記載の方法。
- 高度にアルカリ化された液体濾過試薬が、0.5Nより大きいかまたは等しい規定度を含む、請求項12に記載の方法。
- ガスで満たされたチャンバーを、高度にアルカリ化された液体の腐植質のフルボ濾過試薬をチャンバー内で噴霧することによって、処置すること
を含む、臭気化学物質および微生物を除去する方法であって、
ガスが、アンモニアを含む臭気化学物質を含み、ガスが、複数の微生物および芽胞をさらに含み、
処置が、アンモニアレベルを低下させ、および、複数の微生物および芽胞の少なくとも一部を死滅させる、前記方法。 - チャンバーが、家禽敷料であり、および、微生物が、敷料のクロストリジウム菌およびサルモネラ菌を含む、請求項19に記載の方法。
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US11549064B2 (en) | 2019-09-20 | 2023-01-10 | Gaps Technology, Llc | Chemical compositions and treatment systems and treatment methods using same for remediating H2S and other contaminants in fluids, including liquids,gasses and mixtures thereof |
US10913911B1 (en) * | 2019-09-20 | 2021-02-09 | Gaps Technology Llc | Chemical compositions and treatment systems and treatment methods using same for remediating H2S and other contaminants in gasses |
US11919827B2 (en) | 2020-04-30 | 2024-03-05 | Nuorganics LLC | System and method for producing an organic fertilizer from waste gases or liquids |
CN111545036A (zh) * | 2020-05-21 | 2020-08-18 | 北京天益源生物科技有限公司 | 一种垃圾处理专用混合型除臭剂 |
CN111632487A (zh) * | 2020-06-29 | 2020-09-08 | 北京斯隆生物技术有限责任公司 | 一种降低畜禽圈舍气味的制剂及其制备方法 |
AU2022269010B2 (en) | 2021-05-07 | 2024-05-23 | Gaps Technology, Llc | Hydrocarbon liquid based chemical compositions and treatment methods using same for remediating h2s and other contaminants in fluids and mixtures of contaminated fluids |
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RU2016107075A (ru) | 2017-08-31 |
RU2016107075A3 (ja) | 2018-05-03 |
US9011577B2 (en) | 2015-04-21 |
CN105517689A (zh) | 2016-04-20 |
WO2015017534A1 (en) | 2015-02-05 |
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CA2948405A1 (en) | 2015-02-05 |
CN105517689B (zh) | 2020-09-08 |
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