JP2015117186A - Treatment agent for hair deformation - Google Patents
Treatment agent for hair deformation Download PDFInfo
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- JP2015117186A JP2015117186A JP2013259821A JP2013259821A JP2015117186A JP 2015117186 A JP2015117186 A JP 2015117186A JP 2013259821 A JP2013259821 A JP 2013259821A JP 2013259821 A JP2013259821 A JP 2013259821A JP 2015117186 A JP2015117186 A JP 2015117186A
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- agent
- hair
- treatment
- treatment agent
- hair deformation
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Abstract
Description
本発明は、縮毛矯正やウェーブ状に毛髪形状を変形させるための毛髪変形用処理剤に関するものである。 The present invention relates to a hair deformation treating agent for straightening hair or deforming a hair shape into a wave shape.
パーマネントウェーブ処理や縮毛矯正処理などの毛髪変形処理として、従来より、還元剤が配合された第１剤を用いて毛髪中のシスチン結合を還元し、毛髪を所望の形状とした後に、酸化剤が配合された第２剤を用いてその形状を固定させる処理が知られている。この処理での第１剤は、ｐＨがアルカリ性に設定されたものが多く使用されている（例えば、特許文献１参照）。 Conventionally, as a hair deformation treatment such as permanent wave treatment and curly hair straightening treatment, the first agent containing a reducing agent is used to reduce the cystine bond in the hair to make the hair into a desired shape, and then an oxidizing agent. The process which fixes the shape using the 2nd agent mix | blended with is known. As the first agent in this treatment, many agents whose pH is set to be alkaline are used (for example, see Patent Document 1).
上記のように第１剤のｐＨをアルカリ性に設定するのは、還元剤の還元力を高めるためであり、ｐＨが高いほどに還元力が高まる傾向がある。この傾向は同時に、毛髪変形処理の主目的である毛髪変形の程度を大きくできることを意味する。その一方で、毛髪の損傷の原因である過剰な還元を伴いやすい。また、毛髪変形処理前の毛髪の損傷が大きくなると還元剤の浸透性が高く、ブラッシングなどの物理的処理やヘアカラー処理などの化学的処理による毛髪への損傷蓄積が毛先に近づくほど大きいため、この損傷の蓄積差があると、処理後の毛髪形状の均一性が損なわれやすい。これを避けるために第１剤のｐＨを低くすれば、還元剤の還元力が弱まるから、毛髪形状の変形効率が低下する。 The reason why the pH of the first agent is set to be alkaline as described above is to increase the reducing power of the reducing agent, and the reducing power tends to increase as the pH increases. This tendency also means that the degree of hair deformation, which is the main purpose of the hair deformation treatment, can be increased. On the other hand, it tends to be accompanied by excessive reduction that causes hair damage. In addition, if the damage to the hair before the hair deformation treatment increases, the reducing agent has a high permeability, and the damage accumulation on the hair due to physical treatment such as brushing or chemical treatment such as hair color treatment increases as it approaches the tip of the hair. If there is an accumulation difference of this damage, the uniformity of the hair shape after the treatment tends to be impaired. If the pH of the first agent is lowered to avoid this, the reducing power of the reducing agent is weakened, so that the deformation efficiency of the hair shape is lowered.
本発明は、上記事情に鑑み、毛髪に塗布する毛髪変形用処理剤のｐＨを低く設定することに伴う毛髪変形効率の低下が改善された毛髪変形用処理剤の提供を目的とする。 In view of the circumstances described above, an object of the present invention is to provide a hair deformation treatment agent in which a decrease in hair deformation efficiency associated with setting the pH of a hair deformation treatment agent applied to hair to be low is improved.
本発明者等が鋭意検討を行った結果、還元剤が配合された第１剤及び酸化剤が配合された第２剤の使用の間に中間処理剤を用いることとし、中間処理剤のｐＨを第１剤のｐＨよりも高く設定すれば、第１剤のｐＨを低くする程に毛髪の変形効率が高まることを見出し、本発明を完成するに至った。 As a result of intensive studies by the present inventors, the intermediate treatment agent was used during the use of the first agent containing the reducing agent and the second agent containing the oxidizing agent, and the pH of the intermediate treatment agent was adjusted. It has been found that if the pH of the first agent is set higher than the pH of the first agent, the deformation efficiency of the hair increases as the pH of the first agent is lowered, and the present invention has been completed.
すなわち、本発明に係る毛髪変形用処理剤は、還元剤が配合されたｐＨが７．０未満の第１剤と、前記第１剤よりもｐＨが高く且つｐＨが１０．５以下の中間処理剤と、酸化剤が配合された第２剤と、を備えることを特徴とする。毛髪変形処理での第１剤のｐＨを１０．５よりも低くすると毛髪の変形効率が低下する傾向となるが、第１剤及び第２剤の使用の間に用いる中間処理剤のｐＨを第１剤よりも高く設定することで、第１剤のｐＨを低くするとその変形効率が改善傾向となる。また、本発明の毛髪変形用処理剤によれば、損傷した毛髪を変形させる場合、その変形の均一性が良好となる。 That is, the hair deformation treatment agent according to the present invention comprises a first agent having a pH of less than 7.0 in which a reducing agent is blended, and an intermediate treatment having a pH higher than that of the first agent and a pH of 10.5 or less. And a second agent in which an oxidizing agent is blended. When the pH of the first agent in the hair deformation treatment is lower than 10.5, the deformation efficiency of the hair tends to be lowered. However, the pH of the intermediate treatment agent used during the use of the first agent and the second agent is reduced. If the pH of the first agent is lowered by setting it higher than one agent, the deformation efficiency tends to improve. Moreover, according to the hair deformation treating agent of the present invention, when deforming damaged hair, the uniformity of the deformation becomes good.
本発明における前記第１剤のｐＨは、６．５未満が良い。このｐＨ範囲であると、毛髪の変形効率に優れる。 The pH of the first agent in the present invention is preferably less than 6.5. Within this pH range, the deformation efficiency of the hair is excellent.
本発明の第１剤に配合される還元剤は、例えば、チオグリコール酸、チオグリコール酸塩、システイン、システイン塩、アセチルシステイン、システアミン、システアミン塩、チオグリコール酸グリセリル、チオ乳酸、チオ乳酸塩、及びブチロラクトンチオールから選ばれた一種又は二種以上である。 Examples of the reducing agent blended in the first agent of the present invention include thioglycolic acid, thioglycolate, cysteine, cysteine salt, acetylcysteine, cysteamine, cysteamine salt, glyceryl thioglycolate, thiolactic acid, thiolactate, And one or more selected from butyrolactone thiol.
本発明における前記中間処理剤のｐＨは、７．５以上であると良い。第１剤のｐＨを低くすると毛髪の変形効率が高まる傾向とは逆に、中間処理剤では、ｐＨを高くすると変形効率が高まる傾向となる。 The pH of the intermediate treatment agent in the present invention is preferably 7.5 or more. When the pH of the first agent is lowered, contrary to the tendency that the deformation efficiency of the hair is increased, with the intermediate treatment agent, the deformation efficiency tends to be increased when the pH is increased.
本発明における前記中間処理剤のｐＨは、１０．０以下であると良い。このｐＨ範囲とすることで、毛髪の膨潤を抑え、毛髪内部からの成分流出の抑制を期待できる。 The pH of the intermediate treatment agent in the present invention is preferably 10.0 or less. By setting it as this pH range, swelling of hair can be suppressed and suppression of the component outflow from the inside of hair can be expected.
上記中間処理剤は、多価アルコールが配合されたものが好ましい。中間処理剤への多価アルコールの配合は、毛髪変形効率の向上に良い。 The intermediate treatment agent preferably contains a polyhydric alcohol. The blending of the polyhydric alcohol with the intermediate treatment agent is good for improving the hair deformation efficiency.
また、本発明は、還元剤が配合された第１剤と、前記第１剤よりもｐＨが高く且つ１０．５以下の中間処理剤と、酸化剤が配合された第２剤と、を備える毛髪変形用処理剤の第１剤であって、ｐＨが７．０未満であることを特徴とする毛髪変形用処理剤の第１剤である。 Further, the present invention includes a first agent containing a reducing agent, an intermediate treatment agent having a pH higher than that of the first agent and 10.5 or less, and a second agent containing an oxidizing agent. A first agent of a hair deformation treatment agent having a pH of less than 7.0.
また、本発明は、還元剤が配合されたｐＨが７．０未満の第１剤と、中間処理剤と、酸化剤が配合された第２剤と、を備える毛髪変形用処理剤の中間処理剤であって、ｐＨが前記第１剤よりも高く且つ１０．５以下であることを特徴とする毛髪変形用処理剤の中間処理剤である。 The present invention also provides an intermediate treatment for a hair deformation treatment agent comprising a first agent having a pH of less than 7.0 formulated with a reducing agent, an intermediate treatment agent, and a second agent incorporated with an oxidizing agent. An intermediate treatment agent for a hair deformation treatment agent, wherein the pH is higher than that of the first agent and 10.5 or less.
本発明に係る毛髪変形用処理剤によれば、酸化剤が配合された第２剤を使用するまでのｐＨを１０．５以下に設定することで、毛髪の過剰な還元を伴い易いｐＨが高い公知の第１剤を使用することはない。また、上記ｐＨ設定による毛髪変形効率の低下を、第１剤のｐＨを７．０未満とし且つ中間処理剤のｐＨを第１剤よりも高くすることで改善できる。 According to the treatment agent for deforming hair according to the present invention, by setting the pH until the use of the second agent containing the oxidizing agent to 10.5 or less, the pH is easily accompanied by excessive reduction of the hair. A known first agent is not used. Moreover, the fall of the hair deformation efficiency by the said pH setting can be improved by making pH of a 1st agent less than 7.0 and making pH of an intermediate treatment agent higher than a 1st agent.
本発明の実施形態に基づき、本発明を以下に説明する。
本実施形態の毛髪変形用処理剤は、還元剤が配合された第１剤、中間処理剤、及び酸化剤が配合された第２剤を備える。
Based on an embodiment of the present invention, the present invention will be described below.
The hair deformation treatment agent of this embodiment includes a first agent containing a reducing agent, an intermediate treatment agent, and a second agent containing an oxidizing agent.
（第１剤）
本実施形態の第１剤は、還元剤が水に配合されたｐＨが所定値のものである（本実施形態の第１剤として典型的なものは、水の配合量が８０質量％以上のものである。）。また、本実施形態の第１剤には、公知の第１剤用原料から適宜選定されたものが任意に配合される。
(First agent)
The first agent of the present embodiment has a predetermined pH value in which the reducing agent is blended in water (a typical example of the first agent of the present embodiment is that the blending amount of water is 80% by mass or more. Stuff.) Moreover, what was suitably selected from the well-known raw material for 1st agents is arbitrarily mix | blended with the 1st agent of this embodiment.
本実施形態の第１剤に配合する還元剤は、チオール基を有する公知の還元剤であり、例えば、チオグリコール酸、チオグリコール酸塩（チオグリコール酸アンモニウム、チオグリコール酸モノエタノールアミンなど）、システイン（Ｌ−システイン、ＤＬ−システインなど）、システイン塩（塩酸Ｌ−システイン、塩酸ＤＬ−システインなど）、アセチルシステイン（Ｎ−アセチル−Ｌ−システインなど）、システアミン、システアミン塩（システアミン塩酸塩）、チオグリコール酸グリセリル、チオ乳酸、チオ乳酸塩、ブチロラクトンチオールが挙げられる。還元剤の本実施形態の第１剤における配合量は、適宜設定すると良く、例えば２質量％以上１５質量％以下である。 The reducing agent blended in the first agent of the present embodiment is a known reducing agent having a thiol group, such as thioglycolic acid, thioglycolate (such as ammonium thioglycolate, monoethanolamine thioglycolate), Cysteine (L-cysteine, DL-cysteine, etc.), cysteine salt (hydrochloric acid L-cysteine, hydrochloric acid DL-cysteine, etc.), acetylcysteine (N-acetyl-L-cysteine, etc.), cysteamine, cysteamine salt (cysteamine hydrochloride), Examples include glyceryl thioglycolate, thiolactic acid, thiolactate, and butyrolactone thiol. The blending amount of the reducing agent in the first agent of this embodiment may be set as appropriate, and is, for example, 2% by mass or more and 15% by mass or less.
本実施形態の第１剤のｐＨは、７．０未満であり、６．５未満が良く、５．５未満が好ましく、５．０未満がより好ましく、４．５未満が更により好ましい。第１剤のｐＨを７．０未満にすることで、毛髪の変形効率が高まる。一方、第１剤のｐＨの下限は、特に限定されないが、例えば２．０である。 The pH of the first agent of the present embodiment is less than 7.0, preferably less than 6.5, preferably less than 5.5, more preferably less than 5.0, and even more preferably less than 4.5. By making the pH of the first agent less than 7.0, the deformation efficiency of the hair is increased. On the other hand, the lower limit of the pH of the first agent is not particularly limited, but is, for example, 2.0.
上記ｐＨ範囲に設定する場合、必要に応じて、グリコール酸、乳酸、グリセリン酸、グルコン酸、リンゴ酸、酒石酸、クエン酸、コハク酸、グルタミン酸、アスパラギン酸などの有機酸；有機酸塩；塩酸、硫酸、硝酸、リン酸などの無機酸；及び無機酸塩から選ばれた一種又は二種以上を本実施形態の第１剤に配合すると良い。 When set to the above pH range, an organic acid such as glycolic acid, lactic acid, glyceric acid, gluconic acid, malic acid, tartaric acid, citric acid, succinic acid, glutamic acid, aspartic acid; organic acid salt; hydrochloric acid, One or more selected from inorganic acids such as sulfuric acid, nitric acid and phosphoric acid; and inorganic acid salts may be added to the first agent of the present embodiment.
本実施形態の第１剤には、上記の通り、公知の第１剤用原料から適宜選択されたものが任意に配合される。この任意に配合される原料は、ノニオン界面活性剤、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、高分子化合物、シリコーン、炭化水素、ロウ、高級アルコール、多価アルコール、脂肪酸、油脂、エステル油、タンパク質、アミノ酸、キレート剤、抗炎症剤、防腐剤、香料などである。 What was suitably selected from the well-known raw material for 1st agents is arbitrarily mix | blended with the 1st agent of this embodiment as above-mentioned. These optional ingredients include nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, polymer compounds, silicones, hydrocarbons, waxes, higher alcohols, polyhydric alcohols, fatty acids, fats and oils , Ester oils, proteins, amino acids, chelating agents, anti-inflammatory agents, preservatives, perfumes and the like.
本実施形態の第１剤の使用時の剤型は、特に限定されず、例えば、液状、クリーム状、フォーム状（泡状）が挙げられる。 The dosage form at the time of use of the 1st agent of this embodiment is not specifically limited, For example, liquid form, cream form, and foam form (foam form) are mentioned.
（中間処理剤）
本実施形態の中間処理剤は、ｐＨ範囲が設定されたものである（本実施形態の中間処理剤として典型的なものは、水の配合量が８０質量％以上のものである。）。毛髪変形処理において、毛髪への第１剤の塗布と毛髪への第２剤の塗布との間に、中間処理剤を毛髪に塗布して使用する。
(Intermediate treatment agent)
The intermediate treatment agent of the present embodiment has a set pH range (typical as the intermediate treatment agent of the present embodiment has a water content of 80% by mass or more). In the hair deformation treatment, an intermediate treatment agent is applied to the hair between the application of the first agent to the hair and the application of the second agent to the hair.
この中間処理剤のｐＨは、毛髪の膨潤による過剰な還元の虞を避けるために、１０．５以下であり、１０．０以下が良く、９．５以下が好ましい。 The pH of the intermediate treatment agent is 10.5 or less, preferably 10.0 or less, and preferably 9.5 or less in order to avoid the possibility of excessive reduction due to hair swelling.
また、本実施形態の中間処理剤のｐＨは、本実施形態の第１剤のｐＨよりも高く設定され、ｐＨが７．０以上が良く、７．５以上が好ましく、８．０以上がより好ましく、８．５以上が更に好ましく、９．０以上が更により好ましい。ｐＨを７．０以上にすることで、毛髪の変形効率が高まる。 Further, the pH of the intermediate treatment agent of the present embodiment is set higher than the pH of the first agent of the present embodiment, the pH is preferably 7.0 or higher, preferably 7.5 or higher, more preferably 8.0 or higher. Preferably, 8.5 or more is further preferable, and 9.0 or more is even more preferable. By setting the pH to 7.0 or higher, the deformation efficiency of the hair is increased.
本実施形態の第２剤を上記ｐＨ範囲に設定する場合、必要に応じて、アンモニア、アミノアルコール（モノエタノールアミン、トリエタノールアミン、イソプロパノールアミン、２−アミノ−２−メチル−１−プロパノール、２−アミノ−２−メチル−１，３−プロパンジオールなど）、塩基性アミノ酸（アルギニンなど）、モルホリン、炭酸塩（炭酸アンモニウム、炭酸水素アンモニウム、炭酸ナトリウム、炭酸水素ナトリウムなど）、リン酸塩（リン酸一水素アンモニウム、リン酸一水素ナトリウムなど）、及び苛性アルカリ（水酸化カリウム、水酸化ナトリウム）などから選ばれたアルカリ剤の一種又は二種以上を配合すると良い。 When setting the second agent of this embodiment in the above pH range, ammonia, amino alcohol (monoethanolamine, triethanolamine, isopropanolamine, 2-amino-2-methyl-1-propanol, 2 -Amino-2-methyl-1,3-propanediol, etc.), basic amino acids (eg, arginine), morpholine, carbonates (eg, ammonium carbonate, ammonium bicarbonate, sodium carbonate, sodium bicarbonate), phosphates (phosphorus) One or more alkali agents selected from ammonium monohydrogen phosphate, sodium monohydrogen phosphate, and the like, and caustic alkalis (potassium hydroxide, sodium hydroxide) and the like may be blended.
本実施形態の中間処理剤には、公知の第１剤用原料及び第２剤用原料から適宜選択されたものが任意に配合される。この任意に配合される原料は、ノニオン界面活性剤、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、高分子化合物、シリコーン、炭化水素、ロウ、高級アルコール、多価アルコール、脂肪酸、油脂、エステル油、タンパク質、アミノ酸、キレート剤、抗炎症剤、防腐剤、香料などである。 In the intermediate treatment agent of the present embodiment, a material appropriately selected from known raw materials for the first agent and raw materials for the second agent is arbitrarily blended. These optional ingredients include nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, polymer compounds, silicones, hydrocarbons, waxes, higher alcohols, polyhydric alcohols, fatty acids, fats and oils , Ester oils, proteins, amino acids, chelating agents, anti-inflammatory agents, preservatives, perfumes and the like.
多価アルコールを本実施形態の中間処理剤に配合すれば、毛髪の変形効率が高まる。多価アルコールとしては、例えば、エチレングリコール、プロピレングリコール、グリセリン、及び１，３−ブチレングリコールから選ばれた一種又は二種以上であると良い。本実施形態の中間処理剤における多価アルコールの配合量は、例えば５質量％以上１５質量％以下である。 If polyhydric alcohol is mix | blended with the intermediate processing agent of this embodiment, the deformation efficiency of hair will increase. As a polyhydric alcohol, it is good in it being 1 type, or 2 or more types chosen from ethylene glycol, propylene glycol, glycerol, and 1, 3- butylene glycol, for example. The blending amount of the polyhydric alcohol in the intermediate treatment agent of the present embodiment is, for example, 5% by mass or more and 15% by mass or less.
本実施形態の中間処理剤の使用時の剤型は、特に限定されず、例えば、液状、クリーム状、フォーム状（泡状）が挙げられる。 The dosage form at the time of use of the intermediate treatment agent of the present embodiment is not particularly limited, and examples thereof include liquid, cream, and foam (foam).
（第２剤）
本実施形態の第２剤は、酸化剤が水に配合されたｐＨが所定値のものである（本実施形態の第２剤として典型的なものは、水の配合量が８０質量％以上のものである。）。また、本実施形態の第２剤には、公知の第２剤用原料から適宜選定されたものが任意に配合される。
(Second agent)
The second agent of the present embodiment has a predetermined pH value in which an oxidizing agent is blended in water (a typical example of the second agent of the present embodiment is that the blending amount of water is 80% by mass or more. Stuff.) Moreover, what was suitably selected from the well-known raw material for 2nd agents is arbitrarily mix | blended with the 2nd agent of this embodiment.
本実施形態の第２剤に配合する酸化剤は、公知のパーマ用第２剤と同様、例えば、臭素酸塩（臭素酸ナトリウム、臭素酸カリウムなど）又は過酸化水素である。 The oxidizing agent blended in the second agent of the present embodiment is, for example, bromate (sodium bromate, potassium bromate, etc.) or hydrogen peroxide, like the known second agent for permanents.
臭素酸塩を配合する場合、本実施形態の第２剤のｐＨは、例えば５．０以上７．５以下である。過酸化水素を配合する場合の第２剤のｐＨは、例えば２．５以上３．５以下である。 When the bromate is blended, the pH of the second agent of the present embodiment is, for example, 5.0 or more and 7.5 or less. The pH of the second agent when hydrogen peroxide is blended is, for example, 2.5 or more and 3.5 or less.
本実施形態の第２剤には、上記の通り、公知の第２剤用原料から適宜選択されたものが任意に配合される。この任意に配合される原料は、例えば、ノニオン界面活性剤、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、高分子化合物、シリコーン、炭化水素、ロウ、高級アルコール、多価アルコール、脂肪酸、油脂、エステル油、タンパク質、アミノ酸、キレート剤、抗炎症剤、防腐剤、香料である。 As described above, the second agent of the present embodiment is arbitrarily blended with materials appropriately selected from known second agent raw materials. Examples of the raw material to be arbitrarily blended include nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, polymer compounds, silicones, hydrocarbons, waxes, higher alcohols, polyhydric alcohols, fatty acids. Oils, fats, ester oils, proteins, amino acids, chelating agents, anti-inflammatory agents, preservatives, and perfumes.
本実施形態の第２剤の使用時の剤型は、特に限定されず、例えば、液状、クリーム状、フォーム状（泡状）が挙げられる。 The dosage form at the time of use of the 2nd agent of this embodiment is not specifically limited, For example, liquid form, cream form, and foam form (foam form) are mentioned.
（使用方法）
本実施形態の毛髪変形用処理剤は、パーマネントウェーブ用剤と縮毛矯正用剤とを含む概念である。本実施形態の毛髪変形用処理剤に該当するパーマネントウェーブ用剤としては、常温で毛髪にウェーブを付与するコールド式パーマネントウェーブ用剤、加温下で毛髪にウェーブを付与する加温式パーマネントウェーブ用剤などである。本実施形態の毛髪変形用処理剤に該当する縮毛矯正用剤としては、常温で縮毛をストレートに伸ばして矯正するコールド式縮毛矯正用剤、加温下で縮毛をストレートに伸ばして矯正する加温式縮毛矯正用剤、高温整髪用アイロンを使用する加温式縮毛矯正用剤などである。
(how to use)
The hair deformation treating agent of the present embodiment is a concept including a permanent wave agent and a hair straightening agent. The permanent wave agent corresponding to the hair deformation treatment agent of the present embodiment includes a cold permanent wave agent that imparts waves to the hair at room temperature, and a warm permanent wave agent that imparts waves to the hair under heating. Agents. As a curly hair straightening agent corresponding to the hair deformation treatment agent of this embodiment, a cold hair straightening agent that straightens and straightens curly hair at room temperature, straightens curly hair under heating. These include a warming-type curly hair straightening agent that corrects, a warming-type curly hair straightening agent that uses a high-temperature hair-styling iron, and the like.
本実施形態の第１剤は、公知の第１剤と同様の方法で使用できるものである。当該第１剤を塗布した毛髪に熱を加えることが、毛髪の変形効率の向上に良い。第１剤による処理を行った後、中間処理剤を毛髪に塗布する前には、毛髪を水洗しても良い。 The 1st agent of this embodiment can be used by the method similar to a well-known 1st agent. Heating the hair coated with the first agent is good for improving the deformation efficiency of the hair. After the treatment with the first agent, the hair may be washed with water before applying the intermediate treatment agent to the hair.
本実施形態の中間処理剤は、毛髪に塗布して使用されるものである。当該中間処理剤を塗布した毛髪に熱を加えることが、毛髪の変形効率の向上に良い。中間処理剤による処理を行った後、第２剤を毛髪に塗布する前には、毛髪を水洗しても良い。 The intermediate treatment agent of this embodiment is used by being applied to hair. Heating the hair coated with the intermediate treatment agent is good for improving the deformation efficiency of the hair. After the treatment with the intermediate treatment agent, the hair may be washed with water before applying the second agent to the hair.
本実施形態の第２剤は、公知の第２剤と同様の方法で使用できるものである。当該第２剤を塗布した毛髪に熱を加えることが、毛髪の変形効率の向上に良い。第２剤による処理を行った後、毛髪を水洗すると良い。 The 2nd agent of this embodiment can be used by the method similar to a well-known 2nd agent. Applying heat to the hair coated with the second agent is good for improving the deformation efficiency of the hair. After the treatment with the second agent, the hair may be washed with water.
以下、実施例に基づき本発明を詳述するが、この実施例の記載に基づいて本発明が限定的に解釈されるものではない。 EXAMPLES Hereinafter, although this invention is explained in full detail based on an Example, this invention is not interpreted limitedly based on description of this Example.
（実施例１、比較例１ａ〜１ｂ）
第１剤及び中間処理剤のｐＨが下記表１の通りである実施例１、比較例１ａ〜１ｂの毛髪変形用処理剤を製造し、毛髪変形処理を行った。詳細は、以下の通りである。
The hair deformation treatment agents of Example 1 and Comparative Examples 1a to 1b in which the pH of the first agent and the intermediate treatment agent are as shown in Table 1 below were produced, and the hair deformation treatment was performed. Details are as follows.
実施例１、比較例１ａ〜１ｂの第１剤
チオグリコール酸アンモニウム４質量％、リン酸二水素アンモニウム１質量％を配合し、リン酸を配合してｐＨを４．５に調整した水溶液を、実施例１、比較例１ａ〜１ｂの第１剤とした。
Example 1, the first agent of Comparative Examples 1a-1b 4% by mass of ammonium thioglycolate, 1% by mass of ammonium dihydrogen phosphate, an aqueous solution prepared by adding phosphoric acid and adjusting the pH to 4.5, It was set as the 1st agent of Example 1 and Comparative Examples 1a-1b.
実施例１、比較例１ａ〜１ｂの中間処理剤
ｐＨが２．０の比較例１ａの中間処理剤、ｐＨが３．０の比較例１ｂの中間処理剤、ｐＨが７程度の実施例１の中間処理剤を調製した。比較例１ａ〜１ｂでは、リン酸二水素アンモニウム１．０質量％を配合し、リン酸でｐＨ調整した水溶液を中間処理剤とした。実施例１では、水をそのまま中間処理剤とした。
Example 1 and intermediate treatment agent of Comparative Examples 1a to 1b The intermediate treatment agent of Comparative Example 1a having a pH of 2.0, the intermediate treatment agent of Comparative Example 1b having a pH of 3.0, and the pH of about 1 of Example 1. An intermediate treatment agent was prepared. In Comparative Examples 1a to 1b, an aqueous solution prepared by adding 1.0% by mass of ammonium dihydrogen phosphate and adjusting the pH with phosphoric acid was used as an intermediate treatment agent. In Example 1, water was used as an intermediate treatment agent as it was.
実施例１、比較例１ａ〜１ｂの第２剤
臭素酸ナトリウム８質量％、リン酸一水素ナトリウム１．０質量％を配合し、リン酸を配合してｐＨ６．５に調整した水溶液を、実施例１、比較例１ａ〜１ｂの第２剤とした。
Second agent of Example 1 and Comparative Examples 1a to 1b 8% by weight of sodium bromate and 1.0% by weight of sodium monohydrogen phosphate were mixed, and an aqueous solution adjusted to pH 6.5 by adding phosphoric acid was carried out. It was set as the 2nd agent of Example 1 and Comparative Examples 1a-1b.
実施例１、比較例１ａ〜１ｂの毛髪変形処理
毛髪変形処理での処理対象毛束を、以下の通りにして準備した。２０ｃｍの日本人毛髪の５０本又は２ｇの毛束に対して、脱色処理を行った。脱色処理では、アルカリ性水溶液（２５質量％アンモニア水９質量％、炭酸水素アンモニウム２質量％、及び水酸化カリウム０．５質量％の量で配合したもの）：過酸化水素濃度６％＝１：２の質量比で混合した脱色処理溶液に、毛束を６０分間浸漬してから水洗した。そして、シャンプーを用いて洗浄したものを、処理対象毛束として準備した。
Hair deformation treatment of Example 1 and Comparative Examples 1a to 1b A hair bundle to be treated in the hair deformation treatment was prepared as follows. Decolorization treatment was performed on 50 or 2 g hair bundles of 20 cm Japanese hair. In the decolorization treatment, an alkaline aqueous solution (25% by mass of ammonia water 9% by mass, ammonium hydrogen carbonate 2% by mass and potassium hydroxide 0.5% by mass): hydrogen peroxide concentration 6% = 1: 2 The hair bundle was immersed in a decolorization solution mixed at a mass ratio of 60 minutes and then washed with water. And what was washed using shampoo was prepared as a treatment target hair bundle.
毛髪変形処理を、以下の通りにして行った。直径１２ｍｍのロッドに水巻きした毛束に２ｍｌの第１剤を塗布してから、温度設定４３℃の恒温槽内に１５分間放置した毛束を水洗した。次に、毛束に２ｍｌの中間処理剤を塗布してから、温度設定４３℃の恒温槽内に１０分間放置した毛束を水洗した。その後、２ｍｌの第２剤を毛束に塗布してから５分間放置までの工程を２回繰り返し、毛束を水洗した。 The hair deformation treatment was performed as follows. After applying 2 ml of the first agent to a hair bundle wound around a rod having a diameter of 12 mm, the hair bundle left in a constant temperature bath at a temperature setting of 43 ° C. for 15 minutes was washed with water. Next, 2 ml of the intermediate treatment agent was applied to the hair bundle, and then the hair bundle left for 10 minutes in a constant temperature bath at a temperature setting of 43 ° C. was washed with water. Thereafter, the process from application of 2 ml of the second agent to the hair bundle and standing for 5 minutes was repeated twice, and the hair bundle was washed with water.
セット率の算出
毛髪変形処理を行った毛束について、Wortmannの報告（Wortmann F. -J., Kure N., J. Soc. Cosmet. Chem., 41, 123(1990)）による曲げセットにおけるセット率（精製水に浮かべた際の毛束直径÷ロッド径×100）を算出した。
Calculation of the set rate The set in a bending set according to Wortmann's report (Wortmann F. -J., Kure N., J. Soc. Cosmet. Chem., 41, 123 (1990)) The rate (hair bundle diameter when floated on purified water ÷ rod diameter × 100) was calculated.
図１は、上記の算出したセット率の結果を表すグラフである。図１において、中間処理剤のｐＨが高くなるに伴い、セット率も高くなったことを確認できる。なお、図１のグラフにおける縦軸は、毛髪変形処理を行った後の毛束の上端を固定した状態での、上端と下端との直線長さを意味する。 FIG. 1 is a graph showing the result of the calculated set rate. In FIG. 1, it can be confirmed that as the pH of the intermediate treatment agent increases, the set rate also increases. In addition, the vertical axis | shaft in the graph of FIG. 1 means the linear length of an upper end and a lower end in the state which fixed the upper end of the hair | bristle bundle after performing a hair deformation process.
（実施例２ａ〜２ｂ）
実施例２ａ〜２ｂの毛髪変形用処理剤を製造し、毛髪変形処理を行った。詳細は、以下の通りである。
(Examples 2a to 2b)
The hair deformation treatment agents of Examples 2a to 2b were produced and subjected to hair deformation treatment. Details are as follows.
実施例２ａ〜２ｂの第１剤
実施例１と同様、チオグリコール酸アンモニウム４質量％、リン酸二水素アンモニウム１質量％を配合し、リン酸を配合してｐＨを４．５に調整した水溶液を、実施例２ａ〜２ｂの第１剤とした。
First agent of Examples 2a to 2b As in Example 1, 4% by mass of ammonium thioglycolate and 1% by mass of ammonium dihydrogen phosphate were mixed, and phosphoric acid was added to adjust the pH to 4.5. Was used as the first agent of Examples 2a to 2b.
実施例２ａ〜２ｂの中間処理剤
実施例１と同様、水をそのまま実施例２ａの中間処理剤とした。実施例２ｂでは、グリセリン１０質量％水溶液を中間処理剤とした（当該処理剤では、リン酸などを使用したｐＨ調整を行わなかった。）。
Intermediate treatment agent of Examples 2a to 2b As in Example 1, water was used as it was as an intermediate treatment agent of Example 2a. In Example 2b, a 10% by mass aqueous solution of glycerin was used as an intermediate treatment agent (in the treatment agent, pH adjustment using phosphoric acid or the like was not performed).
実施例２ａ〜２ｂの第２剤
実施例１と同様、臭素酸ナトリウム８質量％を配合したｐＨ６．５の水溶液を、実施例２ａ〜２ｂの第２剤とした。
Second Agent of Examples 2a to 2b As in Example 1, an aqueous solution with a pH of 6.5 containing 8% by mass of sodium bromate was used as the second agent of Examples 2a to 2b.
毛髪変形処理
実施例１と同様に準備した毛束を処理対象とし、実施例１と同様にして毛髪変形処理、セット率の算出を行った。
Hair deformation treatment The hair bundle prepared in the same manner as in Example 1 was treated, and hair deformation treatment and the set rate were calculated in the same manner as in Example 1.
図２は、上記算出したセット率の結果を表すグラフである。図２のおいて、多価アルコールであるグリセリンを配合すること、セット率が高まったことを確認できる。 FIG. 2 is a graph showing the result of the set rate calculated above. In FIG. 2, it can be confirmed that glycerin, which is a polyhydric alcohol, is blended and the set rate is increased.
（実施例３ａ〜３ｃ）
第１剤及び中間処理剤のｐＨが下記表２の通りである実施例３ａ〜３ｃの毛髪変形用処理剤を製造し、毛髪変形処理を行った。詳細は、以下の通りである。
The hair deformation treatment agents of Examples 3a to 3c in which the pH of the first agent and the intermediate treatment agent are as shown in Table 2 below were produced, and the hair deformation treatment was performed. Details are as follows.
実施例３ａ〜３ｃの第１剤
ｐＨが２．０の実施例３ａの第１剤、ｐＨが４．０の実施例３ｂの第１剤、ｐＨが６．０の実施例３ｃの第１剤を調製した。これらの第１剤は、チオグリコール酸アンモニウム４質量％、リン酸二水素アンモニウム２質量％を配合し、リン酸を配合してｐＨを調整した水溶液である。
First Agent of Examples 3a-3c First Agent of Example 3a with pH 2.0, First Agent of Example 3b with pH 4.0, First Agent of Example 3c with pH 6.0 Was prepared. These 1st agents are the aqueous solution which mix | blended 4 mass% of ammonium thioglycolate and 2 mass% of ammonium dihydrogen phosphate, mix | blended phosphoric acid, and adjusted pH.
実施例３ａ〜３ｃ中間処理剤
リン酸一水素アンモニウム２．０質量％を配合し、アンモニア水でｐＨを９．５に調整した水溶液を、実施例３ａ〜３ｃの中間処理剤とした。
Examples 3a to 3c Intermediate Treatment Agent An aqueous solution containing 2.0% by mass of ammonium monohydrogen phosphate and adjusted to pH 9.5 with aqueous ammonia was used as the intermediate treatment agent of Examples 3a to 3c.
実施例３ａ〜３ｃの第２剤
臭素酸ナトリウム８質量％、リン酸一水素ナトリウム１．０質量％を配合し、リン酸を配合してｐＨ６．５に調整した水溶液を、実施例３ａ〜３ｃの第２剤とした。
Second Agent of Examples 3a to 3c An aqueous solution prepared by blending 8% by mass of sodium bromate and 1.0% by mass of sodium monohydrogen phosphate and adjusting the pH to 6.5 by blending phosphoric acid was used in Examples 3a to 3c. The second agent.
実施例３ａ〜３ｃの毛髪変形処理
毛髪変形処理での処理対象毛束を、以下の通りにして準備した。ヘアカラー処理などの化学的処理の履歴がない２０ｃｍの日本人毛髪の５０本の毛束に対して、脱色処理を行った。脱色処理では、アンモニア水でｐＨを１０．４とした３質量％過酸化水素水に、毛束を３０分間浸漬してから水洗した。この脱色処理した毛束を、処理対象毛束として準備した。
Hair deformation treatment of Examples 3a to 3c A hair bundle to be treated in the hair deformation treatment was prepared as follows. Decolorization treatment was performed on 50 hair bundles of 20 cm Japanese hair having no history of chemical treatment such as hair color treatment. In the decolorization treatment, the hair bundle was immersed in 3% by mass hydrogen peroxide water adjusted to pH 10.4 with ammonia water for 30 minutes and then washed with water. This decolorized hair bundle was prepared as a treatment target hair bundle.
毛髪変形処理を、以下の通りにして行った。直径１２ｍｍのロッドに巻き付けた毛束を、４００ｍｌの第１剤に室温で１０分間浸漬してから、４００ｍｌの水に室温で１０分間浸漬した。次に、毛束を、４００ｍｌの中間処理剤に室温で１０分間浸漬してから、４００ｍｌの水に室温で１分間浸漬した。その後、毛束を、４００ｍｌの第２剤に室温で１５分間浸漬してから、４００ｍｌの水に浸漬した。この浸漬後の毛束をロッドから取り外し、水切りした毛束の上端を固定してから、自然乾燥させた。 The hair deformation treatment was performed as follows. A hair bundle wound around a rod having a diameter of 12 mm was immersed in 400 ml of the first agent at room temperature for 10 minutes, and then immersed in 400 ml of water at room temperature for 10 minutes. Next, the hair bundle was immersed in 400 ml of the intermediate treatment agent at room temperature for 10 minutes, and then immersed in 400 ml of water at room temperature for 1 minute. Thereafter, the hair bundle was immersed in 400 ml of the second agent at room temperature for 15 minutes and then immersed in 400 ml of water. The hair bundle after the immersion was removed from the rod, the upper end of the hair bundle which had been drained was fixed, and then naturally dried.
図３ａは、毛髪変形処理後の自然乾燥前の濡れた毛束を撮影した写真であり、図３ｂは、自然乾燥後の毛束を撮影した写真である。図３ａ及び図３ｂにおいて、第１剤のｐＨが低くなる程にウェーブ形状が明確になっており、第１剤のｐＨを低くすると毛髪変形効率が高かったと確認できる。 FIG. 3a is a photograph of a wet hair bundle before natural drying after the hair deformation treatment, and FIG. 3b is a photograph of a hair bundle after natural drying. In FIGS. 3a and 3b, the wave shape becomes clearer as the pH of the first agent becomes lower, and it can be confirmed that the hair deformation efficiency is higher when the pH of the first agent is lowered.
（実施例４ａ〜４ｂ）
第１剤及び中間処理剤のｐＨが下記表３の通りである実施例４ａ〜４ｂの毛髪変形用処理剤を製造し、毛髪変形処理を行った。詳細は、以下の通りである。
The hair deformation treatment agents of Examples 4a to 4b in which the pH of the first agent and the intermediate treatment agent are as shown in Table 3 below were produced, and the hair deformation treatment was performed. Details are as follows.
実施例４ａ〜４ｂの第１剤
チオグリコール酸アンモニウム４質量％、リン酸二水素アンモニウム２質量％を配合し、リン酸でｐＨを４．５に調整した水溶液を、実施例４ａ〜４ｂの第１剤とした。
The first agent of Examples 4a to 4b An aqueous solution in which 4% by mass of ammonium thioglycolate and 2% by mass of ammonium dihydrogen phosphate were blended and the pH was adjusted to 4.5 with phosphoric acid One agent was used.
実施例４ａ〜４ｂの中間処理剤
ｐＨが９．０の実施例４ａの第１剤、ｐＨが１０．０の実施例４ｂの中間処理剤を調製した。これらの中間処理剤は、リン酸一水素アンモニウム２．０質量％を配合し、リン酸又はアンモニア水を配合してｐＨを調整した水溶液である。
Intermediate treatment agents of Examples 4a to 4b A first agent of Example 4a having a pH of 9.0 and an intermediate treatment agent of Example 4b having a pH of 10.0 were prepared. These intermediate treatment agents are aqueous solutions in which 2.0% by mass of ammonium monohydrogen phosphate is blended and the pH is adjusted by blending phosphoric acid or aqueous ammonia.
実施例４ａ〜４ｂの第２剤
実施例３ａと同様、臭素酸ナトリウム８質量％を配合したｐＨ６．５の水溶液を、実施例４ａ〜４ｂの第２剤とした。
Second Agent of Examples 4a to 4b As in Example 3a, an aqueous solution with a pH of 6.5 containing 8% by mass of sodium bromate was used as the second agent of Examples 4a to 4b.
実施例４ａ〜４ｂの毛髪変形処理
実施例３ａと同様にして、脱色処理した毛束の毛髪変形処理を行った。
Hair deformation treatment of Examples 4a to 4b In the same manner as in Example 3a, the hair deformation treatment of the decolorized hair bundle was performed.
図４は、毛髪変形処理後の濡れた毛束を撮影した写真であり、中間処理剤のｐＨが高くなる程にウェーブ形状が明確になっており、中間処理剤のｐＨを高くすると毛髪変形効率が高かったと確認できる。この結果は、図３ａ及び図３ｂでの確認した第１剤のｐＨと毛髪変形効率との関係とは逆の傾向である。 FIG. 4 is a photograph of a wet hair bundle after the hair deformation treatment, where the wave shape becomes clearer as the pH of the intermediate treatment increases, and the hair deformation efficiency increases as the pH of the intermediate treatment increases. Can be confirmed. This result has a tendency opposite to the relationship between the pH of the first agent and the hair deformation efficiency confirmed in FIGS. 3a and 3b.
（実施例５、参考例）
第１剤及び中間処理剤のｐＨが下記表４の通りである実施例５及び参考例の毛髪変形用処理剤（参考例は、中間処理剤を有さない）を製造し、毛髪変形処理を行った。詳細は、以下の通りである。
The hair deformation treatment agent of Example 5 and Reference Example (reference example does not have an intermediate treatment agent) in which the pH of the first agent and the intermediate treatment agent is as shown in Table 4 below, and the hair deformation treatment is performed. went. Details are as follows.
実施例５及び参考例の第１剤
ｐＨが４．５の実施例５の第１剤、ｐＨが９．０の参考例の第１剤を調製した。これらの第１剤は、チオグリコール酸アンモニウム４質量％、リン酸二水素アンモニウム２質量％を配合し、リン酸を配合してｐＨを調整した水溶液である。
First Agent of Example 5 and Reference Example A first agent of Example 5 having a pH of 4.5 and a first agent of Reference Example having a pH of 9.0 were prepared. These 1st agents are the aqueous solution which mix | blended 4 mass% of ammonium thioglycolate and 2 mass% of ammonium dihydrogen phosphate, mix | blended phosphoric acid, and adjusted pH.
実施例５の中間処理剤
リン酸一水素アンモニウム２．０質量％を配合し、アンモニア水でｐＨを９．５に調整した水溶液を、実施例５の中間処理剤とした。
Intermediate treatment agent of Example 5 An aqueous solution in which 2.0% by mass of ammonium monohydrogen phosphate was blended and the pH was adjusted to 9.5 with aqueous ammonia was used as the intermediate treatment agent of Example 5.
実施例５及び参考例の第２剤
実施例３ａと同様、臭素酸ナトリウム８質量％を配合したｐＨ６．５の水溶液を、実施例５及び参考例の第２剤とした。
Second Agent of Example 5 and Reference Example As in Example 3a, an aqueous solution with a pH of 6.5 containing 8% by mass of sodium bromate was used as the second agent of Example 5 and Reference Example.
実施例５の毛髪変形処理
毛髪変形処理において、３種類の毛束を処理対象とした以外は、実施例３ａと同様にして毛束の毛髪変形処理を行った。ここで使用した毛束は、上記脱色処理を行わなかった毛束、上記実施例３ａでの脱色処理を１回行った毛束、同脱色処理を３回行った毛束である。
Hair deformation treatment of Example 5 In the hair deformation treatment, the hair deformation treatment of the hair bundle was performed in the same manner as in Example 3a, except that three types of hair bundles were treated. The hair bundle used here is a hair bundle that has not been subjected to the decoloring process, a hair bundle that has been subjected to the decoloring process in Example 3a once, and a hair bundle that has been subjected to the same decoloring process three times.
参考例の毛髪変形処理
処理対象とした毛束は、実施例５の毛髪変形処理と同様、脱色処理を行わなかった毛束、脱色処理を１回行った毛束、脱色処理を３回行った毛束とした。そして、参考例の毛髪変形処理を、実施例５の毛髪変形処理における中間処理剤の使用から第２剤の使用前までの工程を省略した方法により行った。
Hair deformation treatment of the reference example The hair bundle to be treated was the same as the hair deformation treatment of Example 5, the hair bundle that was not subjected to the decolorization treatment, the hair bundle that was subjected to the decolorization treatment once, and the hair removal treatment that was performed three times. A hair bundle was used. And the hair deformation process of the reference example was performed by the method which abbreviate | omitted the process from the use of the intermediate treatment agent in the hair deformation process of Example 5 to the use before the 2nd agent.
図５は、毛髪変形処理後の濡れた毛束を撮影した写真である。この図において、実施例５よりも参考例の方が、毛束の脱色回数による毛髪変形効率に差が生じている。このことから、実施例５の毛髪変形処理によれば、毛束の損傷の大小があったとしても、変形の均一性が高いことを確認できる。 FIG. 5 is a photograph of a wet hair bundle after the hair deformation treatment. In this figure, the reference example is different from Example 5 in the hair deformation efficiency depending on the number of decolorizations of the hair bundle. From this, according to the hair deformation process of Example 5, it can be confirmed that the uniformity of deformation is high even if the hair bundle is damaged.
Claims (8)
ｐＨが７．０未満であることを特徴とする毛髪変形用処理剤の第１剤。 A hair deformation treatment agent comprising: a first agent formulated with a reducing agent; an intermediate treatment agent having a pH higher than that of the first agent and 10.5 or less; and a second agent incorporated with an oxidizing agent. The first agent,
A first agent of a hair deformation treatment agent, wherein the pH is less than 7.0.
ｐＨが前記第１剤よりも高く且つ１０．５以下であることを特徴とする毛髪変形用処理剤の中間処理剤。 An intermediate treatment agent for a hair deformation treatment agent comprising a first agent having a pH of less than 7.0 formulated with a reducing agent, an intermediate treatment agent, and a second agent incorporated with an oxidizing agent,
An intermediate treatment agent for a hair deformation treatment agent, wherein the pH is higher than that of the first agent and 10.5 or less.
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| JP2017114838A (en) * | 2015-12-25 | 2017-06-29 | タカラベルモント株式会社 | Intermediate treatment agent for hair deformation treatment |
| JP2017218416A (en) * | 2016-06-08 | 2017-12-14 | 株式会社ミルボン | First agent for hair deformation, hair deforming agent and hair deforming method |
| JP2017218415A (en) * | 2016-06-08 | 2017-12-14 | 株式会社ミルボン | First agent for hair deformation, hair deforming agent and hair deforming method |
| JP2018030783A (en) * | 2016-08-22 | 2018-03-01 | 株式会社ミルボン | Second agent for hair deformation, hair deforming agent and method for hair deformation |
| JP2018030782A (en) * | 2016-08-22 | 2018-03-01 | 株式会社ミルボン | Second agent for hair deformation, hair deforming agent and method for hair deformation |
| JP2019137649A (en) * | 2018-02-14 | 2019-08-22 | 株式会社 リトル・サイエンティスト | Hair treatment method |
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| JP2017114838A (en) * | 2015-12-25 | 2017-06-29 | タカラベルモント株式会社 | Intermediate treatment agent for hair deformation treatment |
| JP2017218416A (en) * | 2016-06-08 | 2017-12-14 | 株式会社ミルボン | First agent for hair deformation, hair deforming agent and hair deforming method |
| JP2017218415A (en) * | 2016-06-08 | 2017-12-14 | 株式会社ミルボン | First agent for hair deformation, hair deforming agent and hair deforming method |
| JP2018030782A (en) * | 2016-08-22 | 2018-03-01 | 株式会社ミルボン | Second agent for hair deformation, hair deforming agent and method for hair deformation |
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