JP2014008162A - Filter for removing toilet odor - Google Patents
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- JP2014008162A JP2014008162A JP2012146105A JP2012146105A JP2014008162A JP 2014008162 A JP2014008162 A JP 2014008162A JP 2012146105 A JP2012146105 A JP 2012146105A JP 2012146105 A JP2012146105 A JP 2012146105A JP 2014008162 A JP2014008162 A JP 2014008162A
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- filter
- toilet odor
- nonwoven fabric
- odor removal
- compound
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- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 42
- 229920005989 resin Polymers 0.000 claims abstract description 27
- 239000011347 resin Substances 0.000 claims abstract description 27
- 229910021331 inorganic silicon compound Inorganic materials 0.000 claims abstract description 24
- 239000011230 binding agent Substances 0.000 claims abstract description 21
- 239000004088 foaming agent Substances 0.000 claims abstract description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 11
- 239000005749 Copper compound Substances 0.000 claims description 27
- 150000001880 copper compounds Chemical class 0.000 claims description 27
- -1 phosphoric acid compound Chemical class 0.000 claims description 23
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 229920000178 Acrylic resin Polymers 0.000 claims description 5
- 239000004925 Acrylic resin Substances 0.000 claims description 5
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract description 24
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 abstract description 24
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract description 12
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract description 12
- 230000029142 excretion Effects 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 239000002781 deodorant agent Substances 0.000 abstract description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 235000019645 odor Nutrition 0.000 description 53
- 230000001877 deodorizing effect Effects 0.000 description 23
- 239000000835 fiber Substances 0.000 description 14
- 229910052782 aluminium Inorganic materials 0.000 description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 12
- 235000019832 sodium triphosphate Nutrition 0.000 description 12
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 12
- 239000007788 liquid Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 229920000728 polyester Polymers 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229910000365 copper sulfate Inorganic materials 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229920006026 co-polymeric resin Polymers 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- XYHKNCXZYYTLRG-UHFFFAOYSA-N 1h-imidazole-2-carbaldehyde Chemical compound O=CC1=NC=CN1 XYHKNCXZYYTLRG-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-M 3-Methylbutanoic acid Natural products CC(C)CC([O-])=O GWYFCOCPABKNJV-UHFFFAOYSA-M 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 208000035985 Body Odor Diseases 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- 206010021639 Incontinence Diseases 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 206010040904 Skin odour abnormal Diseases 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920005822 acrylic binder Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N beta-methyl-butyric acid Natural products CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 238000009530 blood pressure measurement Methods 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- RPOCFUQMSVZQLH-UHFFFAOYSA-N furan-2,5-dione;2-methylprop-1-ene Chemical compound CC(C)=C.O=C1OC(=O)C=C1 RPOCFUQMSVZQLH-UHFFFAOYSA-N 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000113 methacrylic resin Substances 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
本発明は、家庭用をはじめ公共施設等におけるトイレのいやな臭いを取り除くフィルター等として使用し、***臭、すなわち硫化水素、メチルメルカプタン、トリメチルアミン等の悪臭を効率的に吸着浄化するフィルターに関する。 The present invention relates to a filter that is used as a filter for removing unpleasant odors of toilets in homes and public facilities and the like and efficiently absorbs and purifies excretion odors, that is, malodors such as hydrogen sulfide, methyl mercaptan, and trimethylamine.
消臭フィルターは、様々な用途に利用されており、その消臭方法は大きく分類して活性炭やゼオライト等の吸着材を利用した吸着タイプと、オゾンや光触媒、金属フタロシアニン錯体等により悪臭物質を分解除去する触媒タイプ、あるいはこの吸着タイプと触媒タイプを併用した併用タイプに分けられる。このうち例えば、活性炭の優れた吸着作用を利用した技術がよく知られているが、これらは悪臭成分を吸着し、周辺の臭気濃度を短期的に低下させる働きには優れている。 Deodorizing filters are used in various applications. Deodorizing methods can be broadly classified into adsorption types that use adsorbents such as activated carbon and zeolite, and decomposition of malodorous substances using ozone, photocatalysts, metal phthalocyanine complexes, etc. It can be divided into a catalyst type to be removed or a combined type in which the adsorption type and the catalyst type are used in combination. Among these, for example, techniques using the excellent adsorption action of activated carbon are well known, but these are excellent in the function of adsorbing malodorous components and reducing the ambient odor concentration in the short term.
特許文献１は、病院や家庭での失禁を伴う病人の存在する環境において、消臭効果を発揮する消臭繊維を３０重量％以上含む布帛からなるシート状空気清浄機用フィルターを開示している。 Patent Document 1 discloses a sheet-like air purifier filter made of a fabric containing 30% by weight or more of deodorizing fibers exhibiting a deodorizing effect in an environment where there is a sick person with incontinence at a hospital or at home. .
特許文献２は、種々の臭気成分、特にアルデヒド系ガスや低級脂肪酸等に対して効果のある、ヒドロキシアミン化合物が坦持された固体より構成される消臭フィルターを開示している。 Patent Document 2 discloses a deodorizing filter composed of a solid carrying a hydroxyamine compound, which is effective against various odor components, particularly aldehyde gases and lower fatty acids.
なお、出願人は特許文献３を出願しており、特に体臭や汗臭、あるいはペット臭、すなわちイソ吉草酸、酪酸、酢酸等の有機酸臭に大きな消臭効果があって、しかも圧力損失が低く、耐久性能の優れた有機酸臭除去フィルターを発明している。 In addition, the applicant has applied for Patent Document 3, and particularly has a great deodorizing effect on body odor, sweat odor, or pet odor, that is, organic acid odor such as isovaleric acid, butyric acid, acetic acid, etc. and pressure loss. We have invented a low organic acid odor removal filter with excellent durability.
上記技術は、消臭繊維を含む布帛からなるフィルターや固体にヒドロキシアミン化合物を坦持させたフィルターであって、アンモニア、硫化水素、メチルメルカプタン、トリメチルアミン等の悪臭に効果のある中和反応型のフィルターであるが、圧力損失が低く、耐久性に優れるトイレ臭除去フィルターが求められていた。 The above technology is a filter made of a fabric containing deodorant fibers or a filter in which a hydroxyamine compound is supported on a solid, and is a neutralization reaction type that is effective against bad odors such as ammonia, hydrogen sulfide, methyl mercaptan, and trimethylamine. Although it is a filter, a toilet odor removal filter having low pressure loss and excellent durability has been demanded.
本発明は、かかる技術的背景に鑑みてなされたものであって、家庭用をはじめ公共施設等におけるトイレのいやな臭いである***臭、すなわち硫化水素、メチルメルカプタン、トリメチルアミン等の悪臭に大きな消臭効果があって、しかも圧力損失が低く、さらに耐久性に優れるトイレ臭除去フィルターを提供することを目的とする。 The present invention has been made in view of such a technical background, and is greatly effective for excretion odor, which is an unpleasant smell of toilets in homes and other public facilities, that is, bad odors such as hydrogen sulfide, methyl mercaptan, and trimethylamine. An object of the present invention is to provide a toilet odor removing filter that has an odor effect, has a low pressure loss, and is excellent in durability.
［１］発泡剤によって発泡したバインダー樹脂を介して不織布に銅化合物を坦持した無機ケイ素化合物と、リン酸系化合物とを固着させ、ＪＩＳ Ｂ９９０８規格で測定した圧力損失が、フィルターの通過風速が１．０ｍ／秒の条件下で、フィルターの厚さ１ｃｍ当たり３〜３０Ｐａであることに特徴のあるトイレ臭除去フィルター。 [1] An inorganic silicon compound carrying a copper compound on a non-woven fabric and a phosphoric acid compound are fixed to a nonwoven fabric through a binder resin foamed with a foaming agent, and the pressure loss measured according to JIS B9908 standard indicates that the passing wind speed of the filter is A toilet odor removing filter characterized by a pressure of 3 to 30 Pa per 1 cm thickness of the filter under the condition of 1.0 m / sec.
［２］前記バインダー樹脂がアクリル系樹脂である前項１に記載のトイレ臭除去フィルター。 [2] The toilet odor removal filter as described in 1 above, wherein the binder resin is an acrylic resin.
［３］前記発泡剤がアルキルスルホン酸のアルカリ金属塩である前項１または２に記載のトイレ臭除去フィルター。 [3] The toilet odor removal filter according to the above item 1 or 2, wherein the foaming agent is an alkali metal salt of an alkyl sulfonic acid.
［４］前記不織布に銅化合物を坦持した無機ケイ素化合物を３０〜１２０ｇ／ｍ２、リン酸系化合物を３０〜１２０ｇ／ｍ２固着させた前項１〜３のいずれか１項に記載のトイレ臭除去フィルター。 [4] The toilet according to any one of items 1 to 3, wherein an inorganic silicon compound carrying a copper compound is fixed to 30 to 120 g / m 2 and a phosphoric acid compound is fixed to 30 to 120 g / m 2 on the nonwoven fabric. Odor removal filter.
［５］トイレ臭除去フィルターの厚さが１〜１０ｍｍである前項１〜４のいずれか１項に記載のトイレ臭除去フィルター。 [5] The toilet odor removal filter according to any one of items 1 to 4, wherein the toilet odor removal filter has a thickness of 1 to 10 mm.
［１］の発明では、不織布の通気性を生かしながら、発泡剤によって発泡したバインダー樹脂を介して不織布に銅化合物を坦持した無機ケイ素化合物と、リン酸系化合物とを固着させることができる。前記不織布に銅化合物を坦持した無機ケイ素化合物が固着されているので、硫化水素、メチルメルカプタン等の***臭を無機ケイ素化合物に坦持している銅化合物との化学反応によって消臭することができる。かつ、前記不織布にリン酸系化合物が固着されているので、トリメチルアミン等の悪臭を吸着することによって消臭することができる。また、発泡剤によって発泡したバインダー樹脂を介して前記不織布に銅化合物を坦持した無機ケイ素化合物と、リン酸系化合物とを強力に固着させているので、消臭性能を持続することができる。さらに、ＪＩＳ Ｂ９９０８規格で測定した圧力損失が、フィルターの通過風速が１．０ｍ／秒の条件下で、フィルターの厚さ１ｃｍ当たり３〜３０Ｐａであるので例えば、家庭用をはじめ公共施設等におけるトイレのいやな臭いである***臭、すなわち硫化水素、メチルメルカプタン、トリメチルアミン等の悪臭を素早く消臭することができる。 In the invention of [1], the inorganic silicon compound carrying the copper compound on the nonwoven fabric and the phosphate compound can be fixed via the binder resin foamed by the foaming agent while taking advantage of the breathability of the nonwoven fabric. Since the inorganic silicon compound carrying the copper compound is fixed to the non-woven fabric, the excretion odor such as hydrogen sulfide and methyl mercaptan can be deodorized by a chemical reaction with the copper compound carrying the inorganic silicon compound. it can. And since the phosphoric acid type compound has adhered to the said nonwoven fabric, it can deodorize by adsorbing malodors, such as a trimethylamine. Moreover, since the inorganic silicon compound which supported the copper compound on the nonwoven fabric and the phosphoric acid compound are strongly fixed via the binder resin foamed by the foaming agent, the deodorizing performance can be maintained. Furthermore, since the pressure loss measured in accordance with JIS B9908 standard is 3 to 30 Pa per 1 cm thickness of the filter under the condition that the passing wind speed of the filter is 1.0 m / second, for example, toilets in homes and public facilities An unpleasant odor such as hydrogen sulfide, methyl mercaptan, trimethylamine and the like can be quickly eliminated.
［２］の発明では、前記バインダー樹脂がアクリル系樹脂であるので、強固に固着することができ、消臭効果の耐久性に優れたトイレ臭除去フィルターを提供できる。 In the invention of [2], since the binder resin is an acrylic resin, it is possible to provide a toilet odor removing filter that can be firmly fixed and has excellent deodorizing effect durability.
［３］の発明では、前記発泡剤がアルキルスルホン酸のアルカリ金属塩であるので、バインダー樹脂を均一に発泡することができ、しかも安定した発泡状態とすることができるので、前記不織布に銅化合物を十分均一に固着することができ、しかも通気性の低下を抑制することができる。 In the invention of [3], since the foaming agent is an alkali metal salt of an alkyl sulfonic acid, the binder resin can be uniformly foamed and a stable foamed state can be obtained. Can be sufficiently uniformly fixed, and a decrease in air permeability can be suppressed.
［４］の発明では、前記不織布に銅化合物を坦持した無機ケイ素化合物を３０〜１２０ｇ／ｍ２固着しているので、硫化水素、メチルメルカプタンの悪臭を十分消臭でき、前記不織布にリン酸系化合物を３０〜１２０ｇ／ｍ２固着しているので、トリメチルアミン等の悪臭を十分消臭できる。 In the invention of [4], since the inorganic silicon compound carrying a copper compound is fixed to the nonwoven fabric in an amount of 30 to 120 g / m 2 , the bad odors of hydrogen sulfide and methyl mercaptan can be sufficiently eliminated, and phosphoric acid is added to the nonwoven fabric. Since 30 to 120 g / m 2 of the compound is fixed, it is possible to sufficiently deodorize malodors such as trimethylamine.
［５］の発明では、トイレ臭除去フィルターの厚さが１〜１０ｍｍであるので、消臭性能を確保しながらかさばらず省スペースであり、しかも圧力損失が抑制されたトイレ臭除去フィルターを提供できる。 In the invention of [5], since the thickness of the toilet odor removal filter is 1 to 10 mm, it is possible to provide a toilet odor removal filter that is compact and space-saving while suppressing the deodorizing performance and that suppresses pressure loss. .
本発明のトイレ臭除去フィルターは、家庭用をはじめ公共施設等におけるトイレのいやな臭いを取り除くフィルター等として使用し、***臭、すなわち硫化水素、メチルメルカプタン、トリメチルアミン等の悪臭に大きな消臭効果があって、しかも圧力損失が低く、さらに耐久性に優れるトイレ臭除去フィルターである。 The toilet odor removal filter of the present invention is used as a filter for removing unpleasant odors of toilets in homes and other public facilities, and has a great deodorizing effect on excretion odors, that is, malodor such as hydrogen sulfide, methyl mercaptan, trimethylamine In addition, the toilet odor removing filter has low pressure loss and excellent durability.
本発明の銅化合物としては、例えば銅（II）の硫酸塩、硝酸塩、ギ酸塩、シュウ酸塩などの銅化合物が挙げられるが、これら例示のものに特に限定されるものではない。これら銅化合物は、硫化水素、メチルメルカプタンの悪臭の分解に優れた効果を発揮する。 Examples of the copper compound of the present invention include copper compounds such as copper (II) sulfate, nitrate, formate, and oxalate, but are not particularly limited to these examples. These copper compounds exhibit an excellent effect in the decomposition of malodor of hydrogen sulfide and methyl mercaptan.
本発明の無機ケイ素化合物としては、例えば二酸化ケイ素、アルミノケイ酸、ゼオライトが挙げられる。そして、無機ケイ素化合物に銅化合物を坦持させるには、前記無機ケイ素化合物のアルカリ塩に銅化合物の分散液を混合すればよい。 Examples of the inorganic silicon compound of the present invention include silicon dioxide, aluminosilicate, and zeolite. And in order to make a copper compound carry on an inorganic silicon compound, what is necessary is just to mix the dispersion liquid of a copper compound with the alkali salt of the said inorganic silicon compound.
本発明のリン酸系化合物としては、例えばトリポリリン酸アルミニウム、ポリリン酸、リン酸、ピロリン酸が挙げられる。リン酸系化合物によって、トリメチルアミン等の悪臭を吸着することによって消臭することができる。 Examples of the phosphoric acid compound of the present invention include aluminum tripolyphosphate, polyphosphoric acid, phosphoric acid, and pyrophosphoric acid. The phosphoric acid compound can be deodorized by adsorbing malodor such as trimethylamine.
本発明のトイレ臭除去フィルターの不織布は、特に限定されることなくどのようなものも使用でき、例えばケミカルボンド不織布、サーマルボンド不織布、ニードルパンチ不織布、ウォーターニードル不織布、スパンボンド不織布などが用いられ、不織布の素材は、特に限定されるものではなく、ポリエステル繊維、ポリアミド繊維、ポリプロピレン繊維、アクリル繊維等の合成繊維、あるいは、麻、綿、羊毛等の天然繊維等の繊維から構成される。なお、不織布の素材は耐久性の点で合成繊維からなるのが好ましく、必要に応じて難燃性を付与された不織布を用いても良い。 The non-woven fabric of the toilet odor removal filter of the present invention can be used without any particular limitation, for example, a chemical bond nonwoven fabric, a thermal bond nonwoven fabric, a needle punch nonwoven fabric, a water needle nonwoven fabric, a spunbond nonwoven fabric, etc. The material of the nonwoven fabric is not particularly limited, and is composed of synthetic fibers such as polyester fibers, polyamide fibers, polypropylene fibers, and acrylic fibers, or fibers such as natural fibers such as hemp, cotton, and wool. In addition, it is preferable that the raw material of a nonwoven fabric consists of a synthetic fiber from a durable point, and you may use the nonwoven fabric provided with the flame retardance as needed.
前記不織布の厚さは、１〜１０ｍｍであるのが好ましい。１ｍｍ未満では、銅化合物を坦持した無機ケイ素化合物と、トリポリリン酸アルミニウムの固着量を確保するのが難しくなるので、十分な消臭性能が得られなくなる。１０ｍｍを超えると十分な空気の通過量を確保することが難しくなり、消臭性能の低下を招くおそれがあり、またコスト的にも好ましくない。 The nonwoven fabric preferably has a thickness of 1 to 10 mm. If the thickness is less than 1 mm, it is difficult to secure the fixed amount of the inorganic silicon compound carrying the copper compound and the aluminum tripolyphosphate, so that sufficient deodorizing performance cannot be obtained. If it exceeds 10 mm, it is difficult to ensure a sufficient amount of air passing, which may cause a reduction in deodorizing performance, and is not preferable in terms of cost.
前記不織布の見掛け密度は０．０１〜０．１ｇ／ｃｍ３であるのが好ましい。０．０１ｇ／ｃｍ３未満では、銅化合物を坦持した無機ケイ素化合物と、トリポリリン酸アルミニウムの固着量を確保するのが難しくなるので、十分な消臭性能が得られなくなる。０．１ｇ／ｃｍ３を超えると十分な空気の通過量を確保することが難しくなり、消臭性能の低下を招くおそれがあり、好ましくない。 The apparent density of the nonwoven fabric is preferably 0.01 to 0.1 g / cm 3 . If it is less than 0.01 g / cm 3 , it becomes difficult to secure the fixed amount of the inorganic silicon compound carrying the copper compound and the aluminum tripolyphosphate, so that sufficient deodorizing performance cannot be obtained. If it exceeds 0.1 g / cm 3 , it is difficult to ensure a sufficient amount of air passage, which may cause a decrease in deodorizing performance, which is not preferable.
前記不織布を構成する繊維の繊度は５〜５０ｄｔｅｘの範囲であるものを用いるのが好ましく、５ｄｔｅｘ未満では、通気性を確保し難く、消臭性能も低下することからも好ましくない。５０ｄｔｅｘを超えると、銅化合物の固着量を確保するのが難しくなるので、十分な消臭性能が得られなくなる。中でも、繊度は１０〜３０ｄｔｅｘの範囲とするのがより好ましい。 The fineness of the fibers constituting the nonwoven fabric is preferably in the range of 5 to 50 dtex, and if it is less than 5 dtex, it is difficult to ensure air permeability and the deodorizing performance is also deteriorated. If it exceeds 50 dtex, it will be difficult to ensure the amount of copper compound fixed, so that sufficient deodorizing performance cannot be obtained. Among these, the fineness is more preferably in the range of 10 to 30 dtex.
銅化合物を坦持した無機ケイ素化合物の不織布への固着量は３０〜１２０ｇ／ｍ２が好ましい。３０ｇ／ｍ２を下回ると消臭性能の低下を招き、１２０ｇ／ｍ２を越えると圧力損失の増加を招くおそれがあり、好ましくない。トリポリリン酸アルミニウムの不織布への固着量は３０〜１２０ｇ／ｍ２が好ましい。３０ｇ／ｍ２を下回ると消臭性能の低下を招くおそれがあり、１２０ｇ／ｍ２を越えても圧力損失を増加させるおそれがあり、好ましくない。 The adhesion amount of the inorganic silicon compound carrying the copper compound to the nonwoven fabric is preferably 30 to 120 g / m 2 . If it is less than 30 g / m 2 , the deodorizing performance is lowered, and if it exceeds 120 g / m 2 , there is a risk of increasing pressure loss, which is not preferable. The amount of aluminum tripolyphosphate fixed to the nonwoven fabric is preferably 30 to 120 g / m 2 . If it is less than 30 g / m 2 , the deodorizing performance may be lowered, and if it exceeds 120 g / m 2 , the pressure loss may be increased, which is not preferable.
本発明で用いるバインダ−樹脂として、どのような樹脂でも使用することができる。例えば、アクリル樹脂、ウレタン樹脂、メタアクリル樹脂、シリコン樹脂、グリオキザ−ル樹脂、酢酸ビニル樹脂、塩化ビニリデン樹脂、ブタジエン樹脂、メラミン樹脂、エポキシ樹脂、アクリル−シリコン共重合体樹脂、エチレン−酢酸ビニル共重合体樹脂、イソブチレン無水マレイン酸共重合体樹脂、エチレン−スチレン−アクリレート−メタアクリレ−ト共重合体樹脂などが挙げられる。また、これらの樹脂を２種類以上混合してバインダ−樹脂としてもよい。中でも、アクリル樹脂がヒドラジド化合物と相性がよく好ましい。 Any resin can be used as the binder resin used in the present invention. For example, acrylic resin, urethane resin, methacrylic resin, silicone resin, glyoxal resin, vinyl acetate resin, vinylidene chloride resin, butadiene resin, melamine resin, epoxy resin, acrylic-silicone copolymer resin, ethylene-vinyl acetate copolymer Examples thereof include a polymer resin, an isobutylene maleic anhydride copolymer resin, and an ethylene-styrene-acrylate-methacrylate copolymer resin. Two or more of these resins may be mixed to form a binder resin. Of these, acrylic resins are preferred because of their good compatibility with hydrazide compounds.
本発明の発泡剤として、どのような発泡剤でも使用することができる。例えば、アルキルスルホン酸のアルカリ金属塩、アルキルフェノールエチレンオキシド付加物、アルキルスルホコハク酸のアルカリ金属塩などを挙げることができる。中でも、アルキルスルホン酸のアルカリ金属塩が好ましい。アルキルスルホン酸のアルカリ金属塩として、例えば、ラウリル硫酸ナトリウムを挙げることができる。 Any foaming agent can be used as the foaming agent of the present invention. For example, an alkali metal salt of alkyl sulfonic acid, an alkylphenol ethylene oxide adduct, an alkali metal salt of alkyl sulfosuccinic acid and the like can be mentioned. Of these, alkali metal salts of alkylsulfonic acid are preferable. Examples of the alkali metal salt of alkylsulfonic acid include sodium lauryl sulfate.
発泡剤によるバインダー樹脂の発泡倍率は４〜８倍にするのが好ましい。すなわち、発泡剤をバインダー樹脂に加えたのち、例えばミキサーによって、機械的に泡立てて嵩を大きくした状態で不織布に塗布するのであるが、その際の発泡倍率は４〜８倍に設定する。そうすると、バインダー樹脂が発泡されているから、少ないバインダー樹脂でありながら不織布に銅化合物を坦持した無機ケイ素化合物と、トリポリリン酸アルミニウムとを十分均一に固着することができ、しかも通気性の低下を抑制することができる。中でも、バインダー樹脂の発泡倍率は５〜７倍にするのがより好ましい。 The expansion ratio of the binder resin with the foaming agent is preferably 4 to 8 times. That is, after adding a foaming agent to binder resin, it applies to a nonwoven fabric in the state which made it foamed mechanically, for example with a mixer, and increased the volume, but the foaming ratio in that case is set to 4-8 times. As a result, since the binder resin is foamed, the inorganic silicon compound carrying the copper compound on the nonwoven fabric and the aluminum tripolyphosphate can be sufficiently uniformly fixed with a small amount of the binder resin, and the air permeability is reduced. Can be suppressed. Among these, the expansion ratio of the binder resin is more preferably 5 to 7 times.
発泡剤によって発泡したバインダー樹脂を介して不織布に銅化合物を坦持した無機ケイ素化合物と、トリポリリン酸アルミニウムとを固着させるには、例えば次のようにして固着させることができる。あらかじめ銅化合物を水に均一に分散させた銅化合物分散液を用意し、銅化合物分散液に無機ケイ素化合物を加え均一に分散させ反応させた後、吸引ろ過してから水洗・乾燥することで銅化合物を坦持した無機ケイ素化合物を得る。次に、銅化合物を坦持した無機ケイ素化合物と、トリポリリン酸アルミニウムとを水に加え均一に分散させた後、バインダー樹脂を加えた後に発泡剤を加え、例えばミキサーによって、機械的に泡立てて嵩を大きく発泡させた処理液を用意する。この処理液には、発泡させる前に分散剤などの各種添加剤を、各種特性向上のため配合してもよい。前記処理液を不織布に塗布する手段としては、特に限定されるものではないが、例えば浸漬法、コーティング法等が挙げられる。中でも、コーティング法が好ましい。 In order to fix the inorganic silicon compound supporting the copper compound on the nonwoven fabric and the aluminum tripolyphosphate through the binder resin foamed by the foaming agent, for example, the fixing can be performed as follows. Prepare a copper compound dispersion liquid in which the copper compound is uniformly dispersed in water beforehand, add the inorganic silicon compound to the copper compound dispersion liquid, uniformly disperse and react, then suction filter, wash with water and dry. An inorganic silicon compound carrying the compound is obtained. Next, an inorganic silicon compound carrying a copper compound and aluminum tripolyphosphate are added and uniformly dispersed in water, a binder resin is added, and then a foaming agent is added. Prepare a treatment liquid with a large foam. Various additives such as a dispersant may be added to the treatment liquid to improve various characteristics before foaming. The means for applying the treatment liquid to the nonwoven fabric is not particularly limited, and examples thereof include a dipping method and a coating method. Of these, the coating method is preferable.
上記のように、処理液を塗布した後に乾燥させるが、乾燥手段としては、加熱処理する方法が乾燥効率から好ましい。加熱処理温度は、１００〜１８０℃とするのが好ましい。この温度での加熱処理によって、固着性をより高め、悪臭除去性能の持続耐久性を一層向上させることができる。 As described above, the treatment liquid is applied and then dried. As a drying means, a heat treatment method is preferable from the viewpoint of drying efficiency. The heat treatment temperature is preferably 100 to 180 ° C. By heat treatment at this temperature, it is possible to further improve the sticking property and further improve the durability of the malodor removal performance.
本発明のトイレ臭除去フィルターの圧力損失は、フィルターの厚さ１ｃｍ当たり３〜３０Ｐａである。３Ｐａ未満では、不織布に対する銅化合物を坦持した無機ケイ素化合物と、トリポリリン酸アルミニウムの固着量を確保するのが難しくなるので、十分な消臭性能が得られなくなる。３０Ｐａを超えると十分な空気の通過量を確保することが難しくなり、消臭性能の低下を招くおそれがある。 The pressure loss of the toilet odor removal filter of the present invention is 3 to 30 Pa per 1 cm thickness of the filter. If it is less than 3 Pa, it becomes difficult to secure the fixed amount of the inorganic silicon compound carrying the copper compound to the nonwoven fabric and the aluminum tripolyphosphate, so that sufficient deodorizing performance cannot be obtained. If it exceeds 30 Pa, it will be difficult to ensure a sufficient amount of air passage, and the deodorizing performance may be reduced.
本発明のトイレ臭除去フィルターの厚さは、１〜１０ｍｍであるのが好ましい。１ｍｍ未満では、不織布に対する銅化合物を坦持した無機ケイ素化合物と、トリポリリン酸アルミニウムの固着量を確保するのが難しくなるので、十分な消臭性能が得られなくなる。１０ｍｍを超えると十分な空気の通過量を確保することが難しくなるおそれがあり、消臭性能の低下を招くおそれがあり、またコスト的にも好ましくない。 The thickness of the toilet odor removal filter of the present invention is preferably 1 to 10 mm. If the thickness is less than 1 mm, it is difficult to secure the fixed amount of the inorganic silicon compound carrying the copper compound to the nonwoven fabric and the aluminum tripolyphosphate, so that sufficient deodorizing performance cannot be obtained. If it exceeds 10 mm, it may be difficult to ensure a sufficient amount of air passage, which may cause a reduction in deodorizing performance, and is not preferable in terms of cost.
次に、実施例により本発明を具体的に説明する。なお、実施例における各種ガス除去性能（初期性能試験、繰り返し耐久性能試験）、圧力損失試験の測定は次のように行った。 Next, the present invention will be described specifically by way of examples. The various gas removal performance (initial performance test, repeated durability performance test) and pressure loss test in the examples were measured as follows.
（初期性能試験）
トイレ臭除去フィルターから切り出した試験片（４５０×２５０ｍｍ）を毎分８０００リットルの通気を行なうファンをセットした空気清浄機のフィルターホルダーに固定し、内容量１ｍ３のアクリルボックス内に入れた後、ボックス内において濃度が１０ｐｐｍとなるように硫化水素とメチルメルカプタンとトリメチルアミンを１：１：１の割合で混合したガスを注入し、３０分経過後にこの混合ガスの残存濃度を測定し、混合ガスの除去率（％）を算出し初期性能とした。除去率９０％以上であるものを「◎」、除去率が８０％以上９０％未満であるものを「○」、除去率が７０％以上８０％未満であるものを「△」、除去率が７０％未満であるものを「×」とし、「○」以上を合格とした。
(Initial performance test)
After the test pieces cut out from the toilet odor removal filter fan for performing the ventilation per minute 8000 l of (450 × 250 mm) was fixed to the filter holder of the set air purifier was placed in an acrylic box having an inner volume of 1 m 3, A gas in which hydrogen sulfide, methyl mercaptan, and trimethylamine were mixed at a ratio of 1: 1: 1 so as to have a concentration of 10 ppm in the box was injected, and after 30 minutes, the residual concentration of the mixed gas was measured. The removal rate (%) was calculated and used as the initial performance. “◎” if the removal rate is 90% or more, “◯” if the removal rate is 80% or more and less than 90%, “△” if the removal rate is 70% or more and less than 80%, What was less than 70% was set as “x”, and “○” or more was set as pass.
（繰り返し耐久性能試験）
上記性能試験を５回繰り返し行ったあと、そのまま空気清浄機を動かし３０分間経過してこの混合ガスの残存濃度を測定し、混合ガスの除去率（％）を算出し耐久性能とした。除去率６０％以上であるものを「◎」、除去率が５０％以上６０％未満であるものを「○」、除去率が４０％以上５０％未満であるものを「△」、除去率が４０％未満であるものを「×」とし、「○」以上を合格とした。
(Repeated durability test)
After the above performance test was repeated five times, the air cleaner was moved as it was, and after 30 minutes, the residual concentration of the mixed gas was measured, and the removal rate (%) of the mixed gas was calculated to be the durability performance. “◎” if the removal rate is 60% or more, “◯” if the removal rate is 50% or more and less than 60%, “△” if the removal rate is 40% or more and less than 50%, What was less than 40% was set to “x”, and “○” or more was set to pass.
（圧力損失試験）
ＪＩＳ Ｂ９９０８形式３に準拠し測定した。すなわち、トイレ臭除去フィルターを風洞のユニット固定部に保持し、送風機を作動させフィルター面風速が１．０ｍ／秒になるように調整した。次に静圧測定孔に接続されたマノメーターによって、フィルターの上流側と下流側の静圧を測定しフィルターの厚み１ｃｍ当たりの圧力損失を算出した。評価基準は、圧力損失３０Ｐａ以下が合格で「○」、３０Ｐａ超３５Ｐａ以下を「△」、３５Ｐａ超を「×」とした。
(Pressure loss test)
Measured according to JIS B9908 format 3. That is, the toilet odor removal filter was held in the unit fixing portion of the wind tunnel, and the air blower was operated to adjust the filter surface wind speed to 1.0 m / second. Next, the pressure loss per 1 cm thickness of the filter was calculated by measuring the static pressure upstream and downstream of the filter with a manometer connected to the static pressure measurement hole. The evaluation criteria were “◯” when the pressure loss was 30 Pa or less, “Δ” when more than 30 Pa and 35 Pa or less, and “X” when more than 35 Pa.
次に、本発明の実施例について説明するが、本発明はこれらの実施例のものに特に限定されるものではない。なお、不織布、銅化合物を坦持した無機ケイ素化合物、リン酸系化合物及びバインダー樹脂の種類、不織布への固着量、発泡倍率、フィルターの厚さを表１に、各種ガス除去性能（初期、繰り返し耐久）及び圧力損失試験の結果を表２に示す。 Next, examples of the present invention will be described, but the present invention is not particularly limited to these examples. In addition, Table 1 shows the types of nonwoven fabrics, inorganic silicon compounds carrying copper compounds, phosphoric acid compounds and binder resins, the amount of adhesion to the nonwoven fabrics, the expansion ratio, and the filter thickness. Table 2 shows the results of durability and pressure loss tests.
＜実施例１＞
硫酸銅５水和物２０質量部を水１００質量部に加えた後、攪拌機により攪拌を行い、均一に分散させた硫酸銅分散液を用意した。続いて、該硫酸銅分散液にケイ酸ナトリウム５０質量部を加えた後、攪拌機により攪拌を行い、均一に分散させ２時間反応させた後、吸引ろ過してから水洗し、１２０℃×３０分乾燥することで硫酸銅を担持した二酸化ケイ素を得た。次に、該硫酸銅を担持した二酸化ケイ素４０質量部と、トリポリリン酸アルミニウム４０質量部とを水２００質量部に加えた後、攪拌機により攪拌を行い、均一に分散させた後、アクリル系バインダー樹脂（固形分６０％）２５質量部を加えよく攪拌したのちに発泡剤としてラウリル硫酸ナトリウム１０質量部を加え、ミキサーによって機械的に泡立て嵩を大きくし６倍発泡させた処理液を得た。この処理液をケミカルボンド不織布（ポリエステル繊維、目付５０ｇ／ｍ２、厚み５ｍｍ）にドクターナイフを用いてコーティングし、１００℃×２０分乾燥して、厚さ５ｍｍのトイレ臭除去フィルターを得た。
<Example 1>
After adding 20 parts by mass of copper sulfate pentahydrate to 100 parts by mass of water, the mixture was stirred with a stirrer to prepare a uniformly dispersed copper sulfate dispersion. Subsequently, 50 parts by mass of sodium silicate was added to the copper sulfate dispersion, and the mixture was stirred with a stirrer, uniformly dispersed, reacted for 2 hours, filtered with suction, washed with water, and 120 ° C. × 30 minutes. By drying, silicon dioxide carrying copper sulfate was obtained. Next, after adding 40 parts by mass of silicon dioxide carrying the copper sulfate and 40 parts by mass of aluminum tripolyphosphate to 200 parts by mass of water, the mixture is stirred and uniformly dispersed with an acrylic binder resin. (Solid content 60%) After adding 25 parts by mass and stirring well, 10 parts by mass of sodium lauryl sulfate was added as a foaming agent, and a foaming bulk was mechanically increased by a mixer to obtain a treatment liquid which was foamed 6 times. This treatment liquid was coated on a chemically bonded nonwoven fabric (polyester fiber, basis weight 50 g / m 2 , thickness 5 mm) using a doctor knife and dried at 100 ° C. for 20 minutes to obtain a toilet odor removal filter having a thickness of 5 mm.
＜実施例２＞
次に、実施例１において、ケミカルボンド不織布（ポリエステル繊維、目付２０ｇ／ｍ２、厚み２ｍｍ）を用いた以外は実施例１と同様にして、厚さ２ｍｍのトイレ臭除去フィルターを得た。
<Example 2>
Next, a toilet odor removal filter having a thickness of 2 mm was obtained in the same manner as in Example 1 except that a chemical bond nonwoven fabric (polyester fiber, basis weight 20 g / m 2 , thickness 2 mm) was used.
＜実施例３＞
次に、実施例１において、ケミカルボンド不織布（ポリエステル繊維、目付８０ｇ／ｍ２、厚み８ｍｍ）を用いた以外は実施例１と同様にして、厚さ８ｍｍのトイレ臭除去フィルターを得た。
<Example 3>
Next, a toilet odor removal filter having a thickness of 8 mm was obtained in the same manner as in Example 1 except that a chemical bond nonwoven fabric (polyester fiber, basis weight 80 g / m 2 , thickness 8 mm) was used.
＜実施例４＞
次に、実施例１において、スパンボンド不織布（ポリエステル繊維、目付５０ｇ／ｍ２、厚み５ｍｍ）を用いた以外は実施例１と同様にして、厚さ５ｍｍのトイレ臭除去フィルターを得た。
<Example 4>
Next, a toilet odor removal filter having a thickness of 5 mm was obtained in the same manner as in Example 1 except that a spunbonded nonwoven fabric (polyester fiber, basis weight 50 g / m 2 , thickness 5 mm) was used.
＜実施例５＞
次に、実施例１において、硫酸銅５水和物に代えて酢酸銅（ＩＩ）１水和物を用いた以外は実施例１と同様にして、厚さ５ｍｍのトイレ臭除去フィルターを得た。
<Example 5>
Next, a toilet odor removal filter having a thickness of 5 mm was obtained in the same manner as in Example 1 except that copper acetate (II) monohydrate was used instead of copper sulfate pentahydrate. .
＜実施例６＞
次に、実施例１において、ウレタン系バインダー樹脂（固形分５０％）を用いた以外は実施例１と同様にして、厚さ５ｍｍのトイレ臭除去フィルターを得た。
<Example 6>
Next, a toilet odor removal filter having a thickness of 5 mm was obtained in the same manner as in Example 1 except that the urethane-based binder resin (solid content 50%) was used.
＜実施例７＞
次に、実施例１において、発泡倍率を４倍にし、ドクターナイフを用いてコーティングの付着量を調整した以外は実施例１と同様にして、厚さ５ｍｍのトイレ臭除去フィルターを得た。
<Example 7>
Next, a toilet odor removal filter having a thickness of 5 mm was obtained in the same manner as in Example 1 except that the expansion ratio was set to 4 in Example 1 and the amount of coating adhered was adjusted using a doctor knife.
＜実施例８＞
次に、実施例１において、発泡倍率を８倍にし、ドクターナイフを用いてコーティングの付着量を調整した以外は実施例１と同様にして、厚さ５ｍｍのトイレ臭除去フィルターを得た。
<Example 8>
Next, a toilet odor removal filter having a thickness of 5 mm was obtained in the same manner as in Example 1, except that the expansion ratio was 8 times and the amount of coating adhered was adjusted using a doctor knife.
＜実施例９＞
次に、実施例１において、トリポリリン酸アルミニウムに代えてリン酸４０質量部を用いた以外は実施例１と同様にして、厚さ５ｍｍのトイレ臭除去フィルターを得た。
<Example 9>
Next, a toilet odor removal filter having a thickness of 5 mm was obtained in the same manner as in Example 1, except that 40 parts by mass of phosphoric acid was used instead of aluminum tripolyphosphate.
＜実施例１０＞
次に、実施例１において、ケミカルボンド不織布（ポリエステル繊維、目付１２０ｇ／ｍ２、厚み１２ｍｍ）を用いた以外は実施例１と同様にして、厚さ１２ｍｍのトイレ臭除去フィルターを得た。
<Example 10>
Next, a toilet odor removal filter having a thickness of 12 mm was obtained in the same manner as in Example 1 except that a chemical bond nonwoven fabric (polyester fiber, basis weight 120 g / m 2 , thickness 12 mm) was used.
＜実施例１１＞
次に、実施例１において、ケミカルボンド不織布（ポリエステル繊維、目付６００ｇ／ｍ２、厚み６０ｍｍ）を用いた以外は実施例１と同様にして、厚さ６０ｍｍのトイレ臭除去フィルターを得た。
<Example 11>
Next, a toilet odor removal filter having a thickness of 60 mm was obtained in the same manner as in Example 1 except that a chemical bond nonwoven fabric (polyester fiber, basis weight 600 g / m 2 , thickness 60 mm) was used.
＜比較例１＞
次に、実施例１において、硫酸銅５水和物を用いなかった以外は実施例１と同様にして、厚さ５ｍｍのトイレ臭除去フィルターを得た。
<Comparative Example 1>
Next, a toilet odor removal filter having a thickness of 5 mm was obtained in the same manner as in Example 1 except that copper sulfate pentahydrate was not used.
＜比較例２＞
次に、実施例１において、発泡剤を用いず、すなわちバインダー樹脂を発泡させなかった以外は実施例１と同様にして、厚さ５ｍｍのトイレ臭除去フィルターを得た。
<Comparative example 2>
Next, a toilet odor removal filter having a thickness of 5 mm was obtained in the same manner as in Example 1, except that the foaming agent was not used, that is, the binder resin was not foamed.
＜比較例３＞
次に、実施例１において、硫酸銅を担持した二酸化ケイ素の代わりに硫酸銅５水和物を用いた以外は実施例１と同様にして、厚さ５ｍｍのトイレ臭除去フィルターを得た。
<Comparative Example 3>
Next, a toilet odor removal filter having a thickness of 5 mm was obtained in the same manner as in Example 1, except that copper sulfate pentahydrate was used instead of silicon dioxide supporting copper sulfate.
＜比較例４＞
次に、実施例１において、トリポリリン酸アルミニウムを用いなかった以外は実施例１と同様にして、厚さ５ｍｍのトイレ臭除去フィルターを得た。
<Comparative Example 4>
Next, a toilet odor removal filter having a thickness of 5 mm was obtained in the same manner as in Example 1 except that aluminum tripolyphosphate was not used.
表２から明らかなように、本発明のトイレ臭除去フィルターは、硫化水素、メチルメルカプタン、トリメチルアミン等の悪臭に優れた消臭効果を発揮するとともに、圧力損失が低く、耐久性に優れたフィルターである。 As is clear from Table 2, the toilet odor removal filter of the present invention is a filter with excellent deodorizing effects such as hydrogen sulfide, methyl mercaptan, trimethylamine, etc., low pressure loss, and excellent durability. is there.
本発明の技術は、家庭用をはじめ公共施設等におけるトイレのいやな臭いを取り除くフィルター等として使用し、***臭、すなわち硫化水素、メチルメルカプタン、トリメチルアミン等を効率的に吸着浄化するフィルターとして広く利用される。 The technology of the present invention is used as a filter for removing unpleasant odors of toilets in homes and other public facilities, and widely used as a filter for efficiently adsorbing and purifying excretion odors, that is, hydrogen sulfide, methyl mercaptan, trimethylamine, etc. Is done.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2016158013A1 (en) * | 2015-03-31 | 2016-10-06 | 住江織物株式会社 | Deodorant composition, deodorant fabric, and fiber product |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58150413A (en) * | 1982-02-26 | 1983-09-07 | Kanai Hiroyuki | Deodorising and adsorbing filter sheet |
| JPS62299266A (en) * | 1986-06-20 | 1987-12-26 | セ−レン株式会社 | Washable deodorizing body and its production |
| JPS6440055A (en) * | 1987-08-06 | 1989-02-10 | Nippon Zeon Co | Deodorizing composition and deodorizing composite material |
| JPH07185324A (en) * | 1993-12-28 | 1995-07-25 | Zeon Kasei Co Ltd | Deodorant and composite material having deodorizing property |
| JPH1060778A (en) * | 1996-06-11 | 1998-03-03 | Toray Ind Inc | Deodorant textile material and its production |
| JPH11172112A (en) * | 1997-10-08 | 1999-06-29 | Ain Kosan Kk | Photocatalytic ligneous synthetic material composition and its production, photocatalytic ligneous synthetic foam and its production, photocatalytic ligneous synthetic molded product using the same material composition and molded product using the same foam |
| JP2001262095A (en) * | 2000-03-24 | 2001-09-26 | Takara Yojo Shizai Kk | Functional adhesive tape |
| JP2002028484A (en) * | 2000-07-14 | 2002-01-29 | Mitsubishi Paper Mills Ltd | Deodorizing filter |
| US20020141898A1 (en) * | 2000-05-23 | 2002-10-03 | Giovanni Carlucci | Layered absorbent structure for neutralizing odour and absorbing liquid in inanimate places and a method of containment of odour and liquid in inanimate places using the same |
| JP2004089982A (en) * | 2002-03-29 | 2004-03-25 | Mitsubishi Paper Mills Ltd | Air cleaning filter |
| JP2006316401A (en) * | 2006-06-16 | 2006-11-24 | Toagosei Co Ltd | Deodorizing paper piece and method for deodorizing excreta odor therewith |
| JP2013510797A (en) * | 2009-11-16 | 2013-03-28 | ビーピービー・リミテッド | Plaster materials containing drugs that can trap formaldehyde |
-
2012
- 2012-06-28 JP JP2012146105A patent/JP5694244B2/en active Active
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58150413A (en) * | 1982-02-26 | 1983-09-07 | Kanai Hiroyuki | Deodorising and adsorbing filter sheet |
| JPS62299266A (en) * | 1986-06-20 | 1987-12-26 | セ−レン株式会社 | Washable deodorizing body and its production |
| JPS6440055A (en) * | 1987-08-06 | 1989-02-10 | Nippon Zeon Co | Deodorizing composition and deodorizing composite material |
| JPH07185324A (en) * | 1993-12-28 | 1995-07-25 | Zeon Kasei Co Ltd | Deodorant and composite material having deodorizing property |
| JPH1060778A (en) * | 1996-06-11 | 1998-03-03 | Toray Ind Inc | Deodorant textile material and its production |
| JPH11172112A (en) * | 1997-10-08 | 1999-06-29 | Ain Kosan Kk | Photocatalytic ligneous synthetic material composition and its production, photocatalytic ligneous synthetic foam and its production, photocatalytic ligneous synthetic molded product using the same material composition and molded product using the same foam |
| JP2001262095A (en) * | 2000-03-24 | 2001-09-26 | Takara Yojo Shizai Kk | Functional adhesive tape |
| US20020141898A1 (en) * | 2000-05-23 | 2002-10-03 | Giovanni Carlucci | Layered absorbent structure for neutralizing odour and absorbing liquid in inanimate places and a method of containment of odour and liquid in inanimate places using the same |
| JP2002028484A (en) * | 2000-07-14 | 2002-01-29 | Mitsubishi Paper Mills Ltd | Deodorizing filter |
| JP2004089982A (en) * | 2002-03-29 | 2004-03-25 | Mitsubishi Paper Mills Ltd | Air cleaning filter |
| JP2006316401A (en) * | 2006-06-16 | 2006-11-24 | Toagosei Co Ltd | Deodorizing paper piece and method for deodorizing excreta odor therewith |
| JP2013510797A (en) * | 2009-11-16 | 2013-03-28 | ビーピービー・リミテッド | Plaster materials containing drugs that can trap formaldehyde |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016158013A1 (en) * | 2015-03-31 | 2016-10-06 | 住江織物株式会社 | Deodorant composition, deodorant fabric, and fiber product |
| CN107427597A (en) * | 2015-03-31 | 2017-12-01 | 住江织物株式会社 | Smelly eliminating composition, smelly eliminating cloth and silk and fibre |
| JPWO2016158013A1 (en) * | 2015-03-31 | 2018-01-25 | 住江織物株式会社 | Deodorant composition, deodorant fabric, and textile product |
| US10517978B2 (en) | 2015-03-31 | 2019-12-31 | Suminoe Textile Co., Ltd. | Deodorant composition, deodorant fabric, and fiber product |
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