JP2012518260A - アノード材料としてリチウム金属又はリチウム金属含有合金及びビス(オキサラト)ホウ酸リチウムと少なくとも1種の別のリチウム錯塩とを有する電解質を有するガルバニ電池 - Google Patents
アノード材料としてリチウム金属又はリチウム金属含有合金及びビス(オキサラト)ホウ酸リチウムと少なくとも1種の別のリチウム錯塩とを有する電解質を有するガルバニ電池 Download PDFInfo
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- lithium
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- galvanic cell
- lithium metal
- oxalato
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- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 51
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 239000003792 electrolyte Substances 0.000 title claims abstract description 16
- 239000010405 anode material Substances 0.000 title claims abstract description 9
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 8
- 239000000956 alloy Substances 0.000 title claims abstract description 8
- 150000003839 salts Chemical class 0.000 title claims abstract description 7
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 title claims abstract description 4
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 239000003115 supporting electrolyte Substances 0.000 claims abstract description 7
- 239000011877 solvent mixture Substances 0.000 claims abstract description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000010 aprotic solvent Substances 0.000 claims abstract description 3
- 229910052796 boron Inorganic materials 0.000 claims abstract description 3
- 125000004430 oxygen atom Chemical group O* 0.000 claims abstract description 3
- 125000004437 phosphorous atom Chemical group 0.000 claims abstract description 3
- 229910052698 phosphorus Chemical group 0.000 claims abstract description 3
- 125000004429 atom Chemical group 0.000 claims abstract 2
- 229910001386 lithium phosphate Inorganic materials 0.000 claims description 9
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical group CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 9
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 4
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 4
- 239000007983 Tris buffer Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 239000011245 gel electrolyte Substances 0.000 claims description 2
- 239000011244 liquid electrolyte Substances 0.000 claims description 2
- 239000003610 charcoal Substances 0.000 abstract 1
- 229910013188 LiBOB Inorganic materials 0.000 description 12
- 238000000354 decomposition reaction Methods 0.000 description 7
- 229940021013 electrolyte solution Drugs 0.000 description 7
- 239000008151 electrolyte solution Substances 0.000 description 6
- 229910013870 LiPF 6 Inorganic materials 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 238000009830 intercalation Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000733 Li alloy Inorganic materials 0.000 description 1
- 229910013063 LiBF 4 Inorganic materials 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000009530 blood pressure measurement Methods 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000005486 organic electrolyte Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/022—Boron compounds without C-boron linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/04—Esters of boric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65748—Esters of oxyacids of phosphorus the cyclic phosphorus atom belonging to more than one ring system
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
- H01M4/382—Lithium
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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Abstract
Description
Y1、Y2、Y3、Y4は、それぞれ互いに独立してOR(ここでR=炭素原子1〜5個を有するアルキル基)、H又は炭素原子1〜5個を有するアルキル基R1、R2であり、かつその際にm、n=0又は1である。
Claims (9)
- リチウム金属又はリチウム金属含有合金をアノード材料として有するガルバニ電池であって、
前記電池が、ビス(オキサラト)ホウ酸リチウム並びに式I及び/又はII
その際に支持電解質中の化合物(I)及び/又は(II)の割合が、0.01〜20mol%であり、かつ式(I、II)中のX、Y及びZが、2個の酸素原子と共にホウ素原子又はリン原子に結合された橋であり、前記橋は、
Y1、Y2、Y3、Y4はそれぞれ互いに独立してOR(ここでR=炭素原子1〜5個を有するアルキル基)、H又は炭素原子1〜5個を有するアルキル基R1、R2であり、かつm、n=0又は1である、
から選択されていることを特徴とする、リチウム金属又はリチウム金属含有合金をアノード材料として有するガルバニ電池。 - 式I及び/又はIIによる化合物の1種が0.2〜10質量%の量で含まれている、請求項1記載のガルバニ電池。
- 式I及び/又はIIによる化合物の1種が0.2〜5質量%の量で含まれている、請求項2記載のガルバニ電池。
- 電解質中にフッ素不含材料のみが含まれている、請求項1から3までのいずれか1項記載のガルバニ電池。
- リチウム錯塩としてトリス(オキサラト)リン酸リチウム又はマロナト−オキサラトホウ酸リチウムが含まれている、請求項1から4までのいずれか1項記載のガルバニ電池。
- 電解質が液体電解質又はゲル電解質として存在する、請求項1から4までのいずれか1項記載のガルバニ電池。
- 電解質中の溶剤がプロピレンカーボネートであるか又はエチレンカーボネート及びエチルメチルカーボネートの混合物である、請求項1から4までのいずれか1項記載のガルバニ電池。
- 好ましい濃度もしくは濃度比
- 電気駆動のため又は据置使用のための大型電池を製造するための、請求項1から8までのいずれか1項記載のガルバニ電池の使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009000977 | 2009-02-18 | ||
DE102009000977.9 | 2009-02-18 | ||
PCT/EP2010/000992 WO2010094467A1 (de) | 2009-02-18 | 2010-02-17 | Galvanische zelle mit einer lithiummetall oder eine lithiummetallhaltigen legierung als anodenmaterial und einem elektrolyten mit lithium bis(oxalato)borat sowie mindestens einem weiteren lithiumkomplexsalz |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2012518260A true JP2012518260A (ja) | 2012-08-09 |
JP2012518260A5 JP2012518260A5 (ja) | 2013-03-28 |
JP5791522B2 JP5791522B2 (ja) | 2015-10-07 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2011550468A Active JP5791522B2 (ja) | 2009-02-18 | 2010-02-17 | アノード材料としてリチウム金属又はリチウム金属含有合金及びビス(オキサラト)ホウ酸リチウムと少なくとも1種の別のリチウム錯塩とを有する電解質を有するガルバニ電池 |
Country Status (6)
Country | Link |
---|---|
US (1) | US9509014B2 (ja) |
EP (1) | EP2399318B1 (ja) |
JP (1) | JP5791522B2 (ja) |
CN (2) | CN107046148A (ja) |
DE (1) | DE102010008331A1 (ja) |
WO (1) | WO2010094467A1 (ja) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102012220793A1 (de) | 2011-11-14 | 2013-05-16 | Chemetall Gmbh | Verfahren zur Herstellung von Metalldifluorochelatoboraten und Verwendung als Batterieelektrolyte oder Additive in galvanischen Zellen |
CN104185522B (zh) * | 2012-01-13 | 2018-02-06 | 罗克伍德锂有限责任公司 | 稳定化的用形成合金的元素涂覆的锂金属成型体及其制备方法 |
JP6064724B2 (ja) * | 2012-05-30 | 2017-01-25 | セントラル硝子株式会社 | シュウ酸を配位子とする金属錯体精製物及び該金属錯体の非水溶媒精製溶液の製造方法 |
US10903522B2 (en) * | 2016-09-21 | 2021-01-26 | Basf Se | Phosphonate based lithium complexes |
DE102021122745A1 (de) | 2021-09-02 | 2023-03-02 | Pinta Abdichtung Gmbh | Verfahren zum Aktivieren eines zur verzögerten Rückstellung getränkten Dichtbands sowie Mittel zur Verwendung hierzu |
Citations (8)
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JP2003505464A (ja) * | 1999-07-22 | 2003-02-12 | ヒェメタル ゲゼルシャフト ミット ベシュレンクテル ハフツング | トリス(オキサラト)ホスフェート、その製造法および該化合物の使用 |
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US7255965B2 (en) * | 2005-04-25 | 2007-08-14 | Ferro Corporation | Non-aqueous electrolytic solution |
US7727669B2 (en) * | 2005-05-26 | 2010-06-01 | Novolyte Technologies Inc. | Triazine compounds for removing acids and water from nonaqueous electrolytes for electrochemical cells |
US8273484B2 (en) * | 2005-05-26 | 2012-09-25 | Novolyte Technologies, Inc. | Nitrogen silylated compounds as additives in non-aqueous solutions for electrochemical cells |
DE102008040153A1 (de) | 2007-07-04 | 2009-01-08 | Chemetall Gmbh | Verfahren zur Herstellung säurearmer Lithiumboratsalze und Mischungen aus säurearmen Lithiumboratsalzen und Lithiumhydrid |
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2010
- 2010-02-17 DE DE102010008331A patent/DE102010008331A1/de not_active Withdrawn
- 2010-02-17 JP JP2011550468A patent/JP5791522B2/ja active Active
- 2010-02-17 CN CN201710099760.6A patent/CN107046148A/zh active Pending
- 2010-02-17 WO PCT/EP2010/000992 patent/WO2010094467A1/de active Application Filing
- 2010-02-17 EP EP10705802.6A patent/EP2399318B1/de active Active
- 2010-02-17 US US13/201,640 patent/US9509014B2/en active Active
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Patent Citations (8)
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JP2003505464A (ja) * | 1999-07-22 | 2003-02-12 | ヒェメタル ゲゼルシャフト ミット ベシュレンクテル ハフツング | トリス(オキサラト)ホスフェート、その製造法および該化合物の使用 |
JP2003536229A (ja) * | 2000-06-16 | 2003-12-02 | アリゾナ ボード オブ リージェンツ, ア ボディ コーポレイト アクティング オン ビハーフ オブ アリゾナ ステート ユニバーシティ | リチウムバッテリのための電解塩 |
JP2005500432A (ja) * | 2001-08-17 | 2005-01-06 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 高分子電解質及びそのガルヴァーニ電池における使用 |
JP2005026203A (ja) * | 2003-06-11 | 2005-01-27 | Sony Corp | 電池 |
JP2007528109A (ja) * | 2004-03-08 | 2007-10-04 | ヒェメタル ゲゼルシャフト ミット ベシュレンクテル ハフツング | ガルヴァーニ電池用の導電性塩、その製造及び使用 |
JP2008539548A (ja) * | 2005-04-25 | 2008-11-13 | フエロ コーポレーション | 混合塩を含む非水電解液 |
JP2007165125A (ja) * | 2005-12-14 | 2007-06-28 | Central Glass Co Ltd | 非水電解液電池用電解液及び非水電解液電池 |
JP2008004503A (ja) * | 2006-06-26 | 2008-01-10 | Sony Corp | 非水電解質組成物及び非水電解質二次電池 |
Also Published As
Publication number | Publication date |
---|---|
EP2399318A1 (de) | 2011-12-28 |
DE102010008331A1 (de) | 2010-08-19 |
US9509014B2 (en) | 2016-11-29 |
CN107046148A (zh) | 2017-08-15 |
JP5791522B2 (ja) | 2015-10-07 |
EP2399318B1 (de) | 2015-07-29 |
WO2010094467A1 (de) | 2010-08-26 |
CN102484293A (zh) | 2012-05-30 |
US20120082900A1 (en) | 2012-04-05 |
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