JP2012516828A - 改善されたビーディング特性を有する表面を撥水性になるように被覆するための弗素不含組成物 - Google Patents
改善されたビーディング特性を有する表面を撥水性になるように被覆するための弗素不含組成物 Download PDFInfo
- Publication number
- JP2012516828A JP2012516828A JP2011548626A JP2011548626A JP2012516828A JP 2012516828 A JP2012516828 A JP 2012516828A JP 2011548626 A JP2011548626 A JP 2011548626A JP 2011548626 A JP2011548626 A JP 2011548626A JP 2012516828 A JP2012516828 A JP 2012516828A
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- Prior art keywords
- alkyl
- composition according
- hydrophobic
- composition
- series
- Prior art date
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- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 83
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 25
- 239000005871 repellent Substances 0.000 title description 4
- 238000000576 coating method Methods 0.000 title description 3
- 239000011248 coating agent Substances 0.000 title description 2
- 230000002940 repellent Effects 0.000 title description 2
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 62
- 239000000758 substrate Substances 0.000 claims abstract description 26
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 24
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 24
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 19
- 239000011707 mineral Substances 0.000 claims abstract description 19
- 230000000694 effects Effects 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 5
- -1 siloxanes Chemical class 0.000 claims description 31
- 125000000217 alkyl group Chemical group 0.000 claims description 30
- 239000003795 chemical substances by application Substances 0.000 claims description 25
- 239000003054 catalyst Substances 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 18
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 14
- 239000003995 emulsifying agent Substances 0.000 claims description 11
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 10
- 238000009833 condensation Methods 0.000 claims description 10
- 230000005494 condensation Effects 0.000 claims description 10
- 230000007062 hydrolysis Effects 0.000 claims description 10
- 238000006460 hydrolysis reaction Methods 0.000 claims description 10
- 239000003960 organic solvent Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 229910019142 PO4 Inorganic materials 0.000 claims description 7
- 235000021317 phosphate Nutrition 0.000 claims description 7
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 125000004122 cyclic group Chemical group 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000006384 oligomerization reaction Methods 0.000 claims description 4
- 239000010695 polyglycol Substances 0.000 claims description 4
- 229920000151 polyglycol Polymers 0.000 claims description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- 239000003085 diluting agent Substances 0.000 claims description 3
- 150000004756 silanes Chemical class 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 229920005682 EO-PO block copolymer Polymers 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 239000003619 algicide Chemical class 0.000 claims description 2
- 125000001931 aliphatic group Chemical class 0.000 claims description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 claims description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
- 150000001414 amino alcohols Chemical class 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 239000003849 aromatic solvent Chemical class 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 239000000872 buffer Chemical class 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000003205 fragrance Substances 0.000 claims description 2
- 239000000417 fungicide Chemical class 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 125000000625 hexosyl group Chemical group 0.000 claims description 2
- 125000001165 hydrophobic group Chemical group 0.000 claims description 2
- 239000002917 insecticide Chemical class 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 230000003641 microbiacidal effect Effects 0.000 claims description 2
- 229940124561 microbicide Drugs 0.000 claims description 2
- 150000007522 mineralic acids Chemical class 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 235000005985 organic acids Nutrition 0.000 claims description 2
- 125000000962 organic group Chemical group 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 125000001805 pentosyl group Chemical group 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000003880 polar aprotic solvent Substances 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 150000003077 polyols Chemical class 0.000 claims description 2
- 239000003755 preservative agent Substances 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 125000004416 alkarylalkyl group Chemical group 0.000 claims 1
- 125000003282 alkyl amino group Chemical group 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 3
- 235000010755 mineral Nutrition 0.000 description 15
- 235000012239 silicon dioxide Nutrition 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 11
- 229910000077 silane Inorganic materials 0.000 description 11
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 11
- 239000000839 emulsion Substances 0.000 description 8
- 229910002012 Aerosil® Inorganic materials 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000004567 concrete Substances 0.000 description 6
- 239000010440 gypsum Substances 0.000 description 6
- 229910052602 gypsum Inorganic materials 0.000 description 6
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000004679 hydroxides Chemical class 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000011505 plaster Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- 125000005376 alkyl siloxane group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- 150000004812 organic fluorine compounds Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000011814 protection agent Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QDTDKYHPHANITQ-UHFFFAOYSA-N 7-methyloctan-1-ol Chemical compound CC(C)CCCCCCO QDTDKYHPHANITQ-UHFFFAOYSA-N 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- XQGSVNHIIVBMPX-UHFFFAOYSA-N Improsulfan tosylate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1.CS(=O)(=O)OCCC[NH2+]CCCOS(C)(=O)=O XQGSVNHIIVBMPX-UHFFFAOYSA-N 0.000 description 1
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- XGZGKDQVCBHSGI-UHFFFAOYSA-N butyl(triethoxy)silane Chemical compound CCCC[Si](OCC)(OCC)OCC XGZGKDQVCBHSGI-UHFFFAOYSA-N 0.000 description 1
- SXPLZNMUBFBFIA-UHFFFAOYSA-N butyl(trimethoxy)silane Chemical compound CCCC[Si](OC)(OC)OC SXPLZNMUBFBFIA-UHFFFAOYSA-N 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- RSKGMYDENCAJEN-UHFFFAOYSA-N hexadecyl(trimethoxy)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OC)(OC)OC RSKGMYDENCAJEN-UHFFFAOYSA-N 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 1
- 229960003493 octyltriethoxysilane Drugs 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- JWHOQZUREKYPBY-UHFFFAOYSA-N rubonic acid Natural products CC1(C)CCC2(CCC3(C)C(=CCC4C5(C)CCC(=O)C(C)(C)C5CC(=O)C34C)C2C1)C(=O)O JWHOQZUREKYPBY-UHFFFAOYSA-N 0.000 description 1
- 125000005624 silicic acid group Chemical class 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000007944 thiolates Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 description 1
- OYGYKEULCAINCL-UHFFFAOYSA-N triethoxy(hexadecyl)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC OYGYKEULCAINCL-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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Abstract
Description
更に、成分として、本発明による組成物は、
場合によっては少なくとも1つの加水分解触媒または縮合触媒、
場合によっては少なくとも1つの有機溶剤、
場合によっては水、
場合によっては少なくとも1つの乳化剤および/または
場合によっては他の助剤を含有することができる。
R1=CH3−、C2H5−、C3H7−、C4H9−、i−C4H9−、C6H13−、i−C6H13−、C8H16−、i−C8H16−および
R2=H、メチル−またはエチル−。
R1=CH3−、C2H5−、C3H7−、C4H9−、i−C4H9−、C6H13−、i−C6H13−、C8H16−、i−C8H16−および
R2=H、メチル−またはエチル−、
R3=CH3−、C2H5−、C3H7−、C4H9−、i−C4H9−、C6H13−、i−C6H13−、C8H16−、i−C8H16−、NH2−C3H6−、NH2−C2H4−NH−C3H6−、NH2−C2H4−NH−C2H4−NH−C3H6−、および
少なくとも1つの疎水性作用物質および
少なくとも1つの疎水性金属酸化物を混合装置中で一緒にし、
場合によっては少なくとも1つの加水分解触媒または縮合触媒、
場合によっては水、
場合によっては少なくとも1つの有機溶剤、
場合によっては少なくとも1つの乳化剤および
場合によっては少なくとも1つの他の助剤と連続的または非連続的に混合することにより、本発明による組成物を製造する方法である。
室温でアルキルトリアルコキシシラン(Evonik Degussa GmbH社のProtectosil(登録商標)BHN)を清潔な乾燥したガラス容器中に装入し、疎水性珪酸AEROSIL(登録商標)R 202 0.5質量%(Evonik Degussa GmbH社から入手可能)を添加した。生じた混合物をさらに5分間攪拌し、引続き直ちに使用することができた。
室温でエタノールを清潔な乾燥したガラス容器中に装入し、順次にアルキルトリアルコキシシラン20質量%(Evonik Degussa GmbH社のProtectosil(登録商標)BHN)、エチルポリシリケート20%(Evonik Degussa GmbH社のDynasylan A)、触媒1.5質量%(DuPont社のTyzor TnBT)ならびに疎水性珪酸AEROSIL(登録商標)R 202 0.5質量%(Evonik Degussa GmbH社から入手可能)を添加した。生じた混合物をさらに5分間攪拌し、引続き直ちに使用することができた。
室温でShellsol D 60(Shell Chemicals社から入手可能)を清潔な乾燥したガラス容器中に装入し、順次にアルキルシロキサン10質量%(Evonik Degussa GmbH社のProtectosil(登録商標)266)ならびに疎水性珪酸AEROSIL(登録商標)R 972 1質量%(Evonik Degussa GmbH社から入手可能)を添加した。生じた混合物をさらに5分間攪拌し、引続き直ちに使用することができた。
純粋なアルキルトリアルコキシシラン(Evonik Degussa GmbH社のProtectosil(登録商標)BHN)を使用した。
室温で、乾燥した清潔なガラス容器中で疎水性珪酸AEROSIL(登録商標)R 202 0.5質量%(Evonik Degussa GmbH社から入手可能)をエタノール中に懸濁させた。
例2と同様に行なうが、しかし、疎水性珪酸AEROSIL(登録商標)R 202の添加なしに行なった。
室温でアルキルシロキサン(Evonik Degussa GmbH社のProtectosil(登録商標)WS 600)の水性乳濁液を清潔な乾燥したガラス容器中に装入し、疎水性珪酸AEROSIL(登録商標)R 202 1質量%(Evonik Degussa GmbH社から入手可能)を添加した。生じた混合物をさらに5分間攪拌し、引続き直ちに使用することができた。
次の第1表は、上記の実施例の結果を示す。そのために、直ちに使用できる溶液を寸法15×7.5×1cmのコンクリート板ならびに石灰質砂岩板上にそれぞれ記載された塗布量で前記板の浸漬によって施した。ビーディング特性の等級の測定のために、水滴を載置し、1分間の接触時間後に吸収されない限り、いわゆる濡れ角または接触角を測定した。(接触角の測定は、DIN EN 828により行なった。)付加的に液滴を10分間の接触時間後に拭き取り、後に残った面を評価した(斑点形成:0=液滴が弾き返された、1=濡れなし、2=接触面の半分が濡れた、3=接触面が完全に濡れた、4=接触面が暗色に着色され、液滴の若干が吸収された、5=接触面が暗色に着色され、液滴の50%が吸収された、6=接触面が暗色に着色され、液滴が完全に吸収された)。
本発明による組成物は、コンクリートおよび石灰質砂岩に対して、ならびに石膏に対して優れたビーディング特性および同時に存在する優れた疎水性の作用(水中での貯蔵の際の水吸収量または質量増加率の減少として表わされた)を示す。
Claims (17)
- 多孔質の鉱物質基体を疎水性にするため、および該基体の表面上にビーディング効果を形成するための弗素不含の組成物であって、この場合この組成物は、
少なくとも1つの疎水性作用物質および
少なくとも1つの疎水性金属酸化物を基礎とする、上記の弗素不含の組成物。 - 前記組成物が他の成分として
場合によっては少なくとも1つの加水分解触媒または縮合触媒、
場合によっては少なくとも1つの有機溶剤、
場合によっては水、
場合によっては少なくとも1つの乳化剤および/または
場合によっては他の助剤を含有することができる、請求項1記載の組成物。 - 疎水性作用物質が理想化された式II
- 前記組成物が理想化された式I、IIおよび/またはIIIの疎水性作用物質の混合物を基礎とする、請求項1から5までのいずれか1項に記載の組成物。
- 疎水性作用物質の含量が前記組成物に対して0.5〜99.99質量%である、請求項1から6までのいずれか1項に記載の組成物。
- 疎水性金属酸化物の含量が前記組成物に対して0.01〜10質量%である、請求項1から7までのいずれか1項に記載の組成物。
- 一連の脂肪族または芳香族溶剤、室温を上廻る沸点を有する脂肪族炭化水素ならびに芳香族炭化水素、極性の非プロトン性溶剤、アルコールまたはポリオール、ケトンからなる少なくとも1つの有機溶剤または希釈剤、または前記の有機溶剤または希釈剤の少なくとも2つからなる混合物の含量を有する、請求項1から8までのいずれか1項に記載の組成物。
- 元素の周期律表(PSE)の第3主族および第4主族の元素ならびにPSEの第II副族、第III副族、第IV副族、第V副族、第VI副族、第VII副族および第VIIIa副族、第VIIIb副族および第VIIIc副族の元素の一連の錯体化合物、殊にチタネートまたはジルコネート、PSEの第1主族および第2主族の元素の一連の塩、一連のアルコラート、一連のアミノアルコール、一連のカルボン酸または鉱酸からなる少なくとも1つの加水分解触媒または縮合触媒、または前記の加水分解触媒または縮合触媒の少なくとも2つからなる混合物の含量を有する、請求項1から9までのいずれか1項に記載の組成物。
- 使用された疎水性作用物質の量に対して0.05〜5質量%の触媒の含量を有する、請求項10記載の組成物。
- C8〜C18アルキルを有するアルキルスルフェート、疎水性基中にC8〜C18アルキルおよび1〜40個のエチレンオキシド(EO)単位またはプロピレンオキシド(PO)単位を有するアルキルエーテルスルフェートおよびアルカリールエーテルスルフェート、C8〜C18アルキルを有するアルキルスルホネート、C8〜C18アルキルを有するアルカリールスルホネート、スルホコハク酸と5〜15個の炭素原子を有する1価アルコールまたはアルキルフェノールとの半エステル、アルキル−、アリール−、アルカリール−またはアラルキル基中に8〜20個の炭素原子を有するカルボン酸のアルカリ金属塩およびアンモニウム塩、有機基中に8〜20個の炭素原子を有するアルキルホスフェートおよびアルカリールホスフェート、アルキル基またはアルカリール基中の8〜20個の炭素原子および1〜40個のEO単位を有するアルキルエーテルホスフェートまたはアルカリールエーテルホスフェート、8〜40個のEO単位およびアルキル基またはアリール基中のC8〜C20炭素原子を有するアルキルポリグリコールエーテルおよびアルカリールポリグリコールエーテル、8〜40個のEO単位またはPO単位を有するエチレンオキシド/プロピレンオキシド(EO/PO)ブロックコポリマー、C8〜C22アルキル基を有するアルキルアミンとエチレンオキシドまたはプロピレンオキシドとの付加生成物、直鎖状または分枝鎖状の飽和または不飽和C8〜C24アルキル基および1〜10個のヘキソース単位またはペントース単位を有するアルキルポリグリコシド、珪素官能性界面活性剤から選択された少なくとも1つの乳化剤または前記乳化剤の少なくとも2つからなる混合物の含量を有する、請求項1から11までのいずれか1項に記載の組成物。
- 前記組成物の全質量に対して0.01〜5質量%の乳化剤の含量を有する、請求項12記載の組成物。
- 一連の無機酸または有機酸、緩衝剤、殺真菌剤、殺虫剤、殺藻剤、殺微生物剤、臭気剤、耐蝕剤、防腐剤、レオロジー助剤から選択された、少なくとも1つの助剤の含量を有する、請求項1から13までのいずれか1項に記載の組成物。
- 請求項1から14までのいずれか1項に記載の弗素不含の組成物を製造する方法であって、
少なくとも1つの疎水性作用物質および
少なくとも1つの疎水性金属酸化物を混合装置中で一緒にし、
場合によっては少なくとも1つの加水分解触媒または縮合触媒、
場合によっては水、
場合によっては少なくとも1つの有機溶剤、
場合によっては少なくとも1つの乳化剤および
場合によっては少なくとも1つの他の助剤と連続的または非連続的に混合することにより、請求項1から14までのいずれか1項に記載の弗素不含の組成物を製造する方法。 - 請求項15の記載により得られた組成物。
- 多孔質の鉱物質基体を疎水化するため、および処理された基質表面上でビーディング効果を形成させるための請求項1から14までのいずれか1項または請求項16に記載の組成物または請求項15記載の方法により製造された組成物の使用であって、この場合1分間の時間に亘って、処理された基質表面上に残留する1つ以上水滴は、濡れた斑点を全く残さない、上記使用。
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DE102005004872A1 (de) | 2005-02-03 | 2006-08-10 | Degussa Ag | Wässrige Emulsionen von funktionellen Alkoxysilanen und deren kondensierten Oligomeren, deren Herstellung und Verwendung zur Oberflächenbehandlung |
DE102006006656A1 (de) | 2005-08-26 | 2007-03-01 | Degussa Ag | Silan enthaltendes Bindemittel für Verbundwerkstoffe |
ES2725499T3 (es) | 2007-04-20 | 2019-09-24 | Evonik Degussa Gmbh | Mezcla que contiene un compuesto de organosilicio y su uso |
DE102009017822A1 (de) | 2009-04-20 | 2010-10-21 | Evonik Degussa Gmbh | Wässrige Silansysteme basierend auf Tris(alkoxysilylalkyl)aminen und deren Verwendung |
DE102010030115A1 (de) | 2009-08-11 | 2011-02-17 | Evonik Degussa Gmbh | Glycidyloxyalkylalkoxysilan-basierte wässrige Silansysteme für den Blankkorrosionsschutz und Korrosionsschutz von Metallen |
WO2011121027A1 (de) | 2010-04-01 | 2011-10-06 | Evonik Degussa Gmbh | Härtbare mischung |
US8679247B2 (en) | 2010-04-01 | 2014-03-25 | Evonik Degussa Gmbh | Hydraulic setting mixture for materials having “easy-to-clean” properties |
DE102011007142A1 (de) | 2011-04-11 | 2012-10-11 | Evonik Degussa Gmbh | Lösung umfassend Propyl-funktionelle Alkali-Siliconate, Silikate sowie Verfahren zu deren Herstellung |
DE102011007137A1 (de) | 2011-04-11 | 2012-10-11 | Evonik Degussa Gmbh | Lösung umfassend organofunktionelle Alkali-Siliconate, Silicate sowie Verfahren zu deren Herstellung |
DE102011086362A1 (de) | 2011-11-15 | 2013-05-16 | Evonik Industries Ag | Zusammensetzung umfassend Block-Co-Kondensate von Propyl-funktionellen Alkali-Siliconaten und Silicaten sowie Verfahren zu deren Herstellung |
EP2956570A4 (en) * | 2013-02-15 | 2017-03-15 | Latitude 18, Inc. | Inorganic coating and composition |
DE102014206359A1 (de) | 2014-04-03 | 2015-10-08 | Evonik Degussa Gmbh | VOC-arme Dialkyl-funktionelle Alkoxysiloxane, Verfahren und deren Verwendung als hydrophobierende Imprägniermittel für mineralische Baustoffe |
EP3186079B1 (en) | 2014-08-27 | 2020-09-30 | W.L. Gore & Associates GmbH | Waterproof and water vapor permeable laminate |
CN104261877A (zh) * | 2014-09-27 | 2015-01-07 | 南雄鼎成化工有限公司 | 一种石材用超疏水防护剂的制备方法及其应用 |
WO2016077550A1 (en) * | 2014-11-12 | 2016-05-19 | University Of Houston System | Soil-resistant, stain-resistant fluorine-free coatings and methods of applying on materials |
WO2016077532A1 (en) | 2014-11-12 | 2016-05-19 | University Of Houston System | Soil-resistant, stain-resistant coatings and methods of applying on textile or other flexible materials |
SG11201703903PA (en) | 2014-11-12 | 2017-06-29 | Univ Houston System | Weather-resistant, fungal-resistant, and stain-resistant coatings and methods of applying on wood, masonry, or other porous materials |
CN105463857B (zh) * | 2015-11-16 | 2018-01-19 | 上海华峰超纤材料股份有限公司 | 用于绒面超细纤维合成革的环保型防虹吸后整理方法 |
DE102016114000A1 (de) | 2016-07-29 | 2018-02-01 | Cosentino Research & Development, S.L. | Verfahren zum Infiltrieren einer Keramik-, Kunst- oder Natursteinoberfläche |
KR102105309B1 (ko) * | 2016-12-28 | 2020-04-28 | 한국세라믹기술원 | 비불소계 발수 코팅액의 제조방법 및 이를 이용한 발수 코팅막의 제조방법 |
WO2022161765A1 (en) | 2021-01-28 | 2022-08-04 | Evonik Operations Gmbh | Treatment composition for providing a water-repellent layer on a sur-face of a substrate |
CN114106694B (zh) * | 2021-11-25 | 2022-07-12 | 贵州理工学院 | 超疏水剂、超疏水剂制备方法及自修复超疏水结构 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0388879A (ja) * | 1989-08-08 | 1991-04-15 | Pcr Group Inc | アクリル酸とメタクリル酸アルキルの共重合体を含んで成る揆水性シランエマルジョン |
US6635735B1 (en) * | 1999-06-16 | 2003-10-21 | Nihon Yamamura Glass Co., Ltd. | Coating composition |
JP2004043289A (ja) * | 2002-04-26 | 2004-02-12 | Degussa Ag | 多孔性の鉱物質支持体の含浸法およびそのための噴霧装置の使用 |
JP2008291225A (ja) * | 2007-04-25 | 2008-12-04 | Sumitomo Seika Chem Co Ltd | 土木建築材料用吸水防止材 |
Family Cites Families (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3228660C2 (de) | 1982-07-31 | 1985-11-14 | Dynamit Nobel Ag, 5210 Troisdorf | Tiefenimprägnierung von Schwerbeton |
US4846886A (en) | 1988-05-05 | 1989-07-11 | Dow Corning Corporation | Water beading-water shedding repellent composition |
SU1738781A1 (ru) * | 1990-01-08 | 1992-06-07 | Белорусский Политехнический Институт | "Фасадна краска "Лавбор" |
US5674967A (en) | 1990-04-03 | 1997-10-07 | Ppg Industries, Inc. | Water repellent surface treatment with integrated primer |
DE19624032A1 (de) | 1996-06-17 | 1997-12-18 | Huels Chemische Werke Ag | Oligomerengemisch kondensierter Alkylalkoxysilane |
DE19634500A1 (de) | 1996-08-26 | 1998-03-05 | Wacker Chemie Gmbh | Zusammensetzungen für die wasser- und ölabweisende Behandlung saugfähiger Materialien |
DE19747794A1 (de) | 1997-10-30 | 1999-05-06 | Degussa | Verfahren zur Herstellung von in der Masse hydrophobiertem Beton |
DE10049153A1 (de) | 2000-09-27 | 2002-04-11 | Degussa | Farbe, Lack, Schadstoffe, Bioorganismen, Öl, Wasser, und/oder Schmutz abweisende Beschichtung |
DE10056344A1 (de) | 2000-11-14 | 2002-05-16 | Degussa | n-Propylethoxysiloxane, Verfahren zu deren Herstellung und deren Verwendung |
DE10056343A1 (de) | 2000-11-14 | 2002-05-16 | Degussa | Kontinuierliches Verfahren zur Herstellung von Organoalkoxysiloxanen |
US7078460B2 (en) * | 2001-01-15 | 2006-07-18 | Shin-Etsu Chemical Co., Ltd. | Room temperature curable organopolysiloxane composition for molding |
JP2002265785A (ja) * | 2001-03-06 | 2002-09-18 | Shin Etsu Chem Co Ltd | 型取り用室温硬化性オルガノポリシロキサン組成物 |
JP2002338943A (ja) | 2001-05-11 | 2002-11-27 | Inax Corp | 防汚層、その形成方法及び塗布液 |
DE10153803A1 (de) | 2001-11-05 | 2003-05-15 | Degussa | Korrosionsinhibitor für Stahlbeton |
EP1475426B1 (de) * | 2003-04-24 | 2006-10-11 | Goldschmidt GmbH | Verfahren zur Herstellung von ablösbaren schmutz- und wasserabweisenden flächigen Beschichtungen |
DE10320779A1 (de) | 2003-05-09 | 2004-11-18 | Degussa Ag | Korrosionsschutz auf Metallen |
DE10320765A1 (de) | 2003-05-09 | 2004-11-25 | Degussa Ag | Mittel zur Beschichtung von Metallen zum Schutz vor Korrosion |
DE102004002499A1 (de) | 2004-01-17 | 2005-08-11 | Degussa Ag | Verfahren zur Verhinderung von Anfeuerungseffekten bei Imprägnierungen von Substraten |
DE102004010756A1 (de) | 2004-03-05 | 2005-09-22 | Degussa Ag | Silanisierte Kieselsäuren |
DE102004037043A1 (de) | 2004-07-29 | 2006-03-23 | Degussa Ag | Blockkondensate organofunktioneller Siloxane, deren Herstellung, Verwendung sowie deren Eigenschaften |
DE102004037045A1 (de) | 2004-07-29 | 2006-04-27 | Degussa Ag | Wässrige Silan-Nanokomposite |
DE102004053384A1 (de) | 2004-11-02 | 2006-05-04 | Degussa Ag | Flüssiges, viskoses Mittel auf Basis eines organofunktionellen Silansystems zur Herstellung witterungsstabiler Schutzbeschichtungen zur Verhinderung von Verschmutzungen von Oberflächen |
DE102004055585A1 (de) | 2004-11-18 | 2006-05-24 | Degussa Ag | Hydrophobe Kieselsäure |
DE102005004871A1 (de) * | 2005-02-03 | 2006-08-10 | Degussa Ag | Hochviskose wässrige Emulsionen von funktionellen Alkoxysilanen, deren kondensierten Oligomeren, Organopolysiloxanen, deren Herstellung und Verwendung zur Oerflächenbehandlung von anorganischen Materialien |
DE102005004872A1 (de) | 2005-02-03 | 2006-08-10 | Degussa Ag | Wässrige Emulsionen von funktionellen Alkoxysilanen und deren kondensierten Oligomeren, deren Herstellung und Verwendung zur Oberflächenbehandlung |
JP2006335969A (ja) | 2005-06-03 | 2006-12-14 | Sumitomo Seika Chem Co Ltd | 吸水防止材 |
DE102006006656A1 (de) | 2005-08-26 | 2007-03-01 | Degussa Ag | Silan enthaltendes Bindemittel für Verbundwerkstoffe |
DE102006006654A1 (de) | 2005-08-26 | 2007-03-01 | Degussa Ag | Spezielle Aminoalkylsilanverbindungen als Bindemittel für Verbundwerkstoffe |
DE102006006655A1 (de) | 2005-08-26 | 2007-03-01 | Degussa Ag | Cellulose- bzw. lignocellulosehaltige Verbundwerkstoffe auf der Basis eines auf Silan basierenden Komposits als Bindemittel |
JP4986444B2 (ja) | 2005-12-12 | 2012-07-25 | 株式会社トクヤマ | 疎水性無機粉体及びその製造方法 |
DE102006003956A1 (de) | 2006-01-26 | 2007-08-02 | Degussa Gmbh | Korrossionsschutzschicht auf Metalloberflächen |
DE102006003957A1 (de) | 2006-01-26 | 2007-08-02 | Degussa Gmbh | Wasserverdünnbare Sol-Gel-Zusammensetzung |
DE102006013090A1 (de) | 2006-03-20 | 2007-09-27 | Georg-August-Universität Göttingen | Kompositwerkstoff aus Holz und thermoplastischem Kunststoff |
JP2008031275A (ja) | 2006-07-28 | 2008-02-14 | Bridgestone Corp | 吸水防止材 |
US7943234B2 (en) | 2007-02-27 | 2011-05-17 | Innovative Surface Technology, Inc. | Nanotextured super or ultra hydrophobic coatings |
ES2725499T3 (es) | 2007-04-20 | 2019-09-24 | Evonik Degussa Gmbh | Mezcla que contiene un compuesto de organosilicio y su uso |
DE102007040802A1 (de) | 2007-08-28 | 2009-03-05 | Evonik Degussa Gmbh | VOC-arme aminoalkyl-funktionelle Siliciumverbindungen enthaltende Zusammensetzung für Streichfarben zur Behandlung von Papier oder Folie |
DE102008007261A1 (de) | 2007-08-28 | 2009-03-05 | Evonik Degussa Gmbh | Wässrige Silansysteme basierend auf Bis(trialkoxysilyalkyl)aminen |
US20090064894A1 (en) * | 2007-09-05 | 2009-03-12 | Ashland Licensing And Intellectual Property Llc | Water based hydrophobic self-cleaning coating compositions |
DE102007045186A1 (de) | 2007-09-21 | 2009-04-09 | Continental Teves Ag & Co. Ohg | Rückstandsfreies, schichtbildendes, wässriges Versiegelungssystem für metallische Oberflächen auf Silan-Basis |
DE102008040783A1 (de) | 2008-07-28 | 2010-02-04 | Evonik Degussa Gmbh | Zusammensetzung für Bautenschutzanwendungen basierend auf Alkylalkoxysiloxanen mit verbesserten Abperleigenschaften |
DE102009017822A1 (de) | 2009-04-20 | 2010-10-21 | Evonik Degussa Gmbh | Wässrige Silansysteme basierend auf Tris(alkoxysilylalkyl)aminen und deren Verwendung |
DE102010030115A1 (de) | 2009-08-11 | 2011-02-17 | Evonik Degussa Gmbh | Glycidyloxyalkylalkoxysilan-basierte wässrige Silansysteme für den Blankkorrosionsschutz und Korrosionsschutz von Metallen |
-
2009
- 2009-02-04 DE DE102009000614A patent/DE102009000614A1/de not_active Withdrawn
-
2010
- 2010-01-11 CN CN2010800057921A patent/CN102300833A/zh active Pending
- 2010-01-11 EP EP10700237.0A patent/EP2393762B1/de active Active
- 2010-01-11 DK DK10700237.0T patent/DK2393762T3/da active
- 2010-01-11 RU RU2011136524/03A patent/RU2558864C2/ru not_active IP Right Cessation
- 2010-01-11 ES ES10700237T patent/ES2904268T3/es active Active
- 2010-01-11 WO PCT/EP2010/050207 patent/WO2010089166A1/de active Application Filing
- 2010-01-11 US US13/147,712 patent/US8741038B2/en active Active
- 2010-01-11 PL PL10700237T patent/PL2393762T3/pl unknown
- 2010-01-11 KR KR1020117018129A patent/KR101493560B1/ko active IP Right Grant
- 2010-01-11 JP JP2011548626A patent/JP5787771B2/ja active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0388879A (ja) * | 1989-08-08 | 1991-04-15 | Pcr Group Inc | アクリル酸とメタクリル酸アルキルの共重合体を含んで成る揆水性シランエマルジョン |
US6635735B1 (en) * | 1999-06-16 | 2003-10-21 | Nihon Yamamura Glass Co., Ltd. | Coating composition |
JP2004043289A (ja) * | 2002-04-26 | 2004-02-12 | Degussa Ag | 多孔性の鉱物質支持体の含浸法およびそのための噴霧装置の使用 |
JP2008291225A (ja) * | 2007-04-25 | 2008-12-04 | Sumitomo Seika Chem Co Ltd | 土木建築材料用吸水防止材 |
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KR101493560B1 (ko) | 2015-02-16 |
KR20110117672A (ko) | 2011-10-27 |
JP5787771B2 (ja) | 2015-09-30 |
US20110308423A1 (en) | 2011-12-22 |
RU2558864C2 (ru) | 2015-08-10 |
ES2904268T3 (es) | 2022-04-04 |
DK2393762T3 (da) | 2022-03-07 |
PL2393762T3 (pl) | 2022-03-21 |
RU2011136524A (ru) | 2013-03-10 |
EP2393762A1 (de) | 2011-12-14 |
US8741038B2 (en) | 2014-06-03 |
WO2010089166A1 (de) | 2010-08-12 |
DE102009000614A1 (de) | 2010-08-05 |
EP2393762B1 (de) | 2021-12-08 |
CN102300833A (zh) | 2011-12-28 |
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