JP2012102427A - Quick dry fabric and textile product - Google Patents

Quick dry fabric and textile product Download PDF

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JP2012102427A
JP2012102427A JP2010250908A JP2010250908A JP2012102427A JP 2012102427 A JP2012102427 A JP 2012102427A JP 2010250908 A JP2010250908 A JP 2010250908A JP 2010250908 A JP2010250908 A JP 2010250908A JP 2012102427 A JP2012102427 A JP 2012102427A
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fabric
quick
drying
organic fiber
washing
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JP5917800B2 (en
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Yoshikazu Tanaka
良和 田中
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Teijin Frontier Co Ltd
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Teijin Fibers Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a quick dry fabric extremely excellent in quick dry property regardless of the high basis weight of the fabric, and to provide a textile product using the quick dry fabric.SOLUTION: The fabric comprises an organic fiber yarn and has a basis weight of 150 g/mor more. The organic fiber yarn undergoes twisting which keeps the following twist coefficient of 5000 or more, and the fabric undergoes water-repellent processing: the twist coefficient=T×(D), in which T is a twist number (T/m) and D is a total fineness (dtex) of the organic fiber yarn.

Description

本発明は目付けが大きい布帛であるにもかかわわらず極めて速乾性に優れた速乾性布帛、および該速乾性布帛を用いてなる繊維製品に関する。   The present invention relates to a quick-drying fabric excellent in quick-drying despite being a fabric having a large basis weight, and a textile product using the quick-drying fabric.

従来、学生服や作業衣料などの用途で、保温性や布帛強度を高めるため目付けが大きい布帛が用いられている。そして、目付けの大きい布帛に、家庭洗濯等に代表される水を媒体とした洗濯を施した場合、洗濯、脱水後において布帛に含まれる水分が多いため、乾燥するまでに時間がかかるという問題があった。   2. Description of the Related Art Conventionally, fabrics having a large basis weight have been used in applications such as student clothes and work clothes in order to increase heat retention and fabric strength. Further, when a fabric having a large basis weight is subjected to washing using water as a medium such as home washing, there is a problem that it takes time to dry because there is a lot of moisture contained in the fabric after washing and dehydration. there were.

他方、布帛に速乾性を付与する方法としては、布帛を多層構造とする方法、布帛に撥水性を付与する方法、異型断面繊維で布帛を構成する方法、布帛に赤外線吸収剤を付与する方法などが提案されている(例えば、特許文献1、特許文献2、特許文献3、特許文献4参照)。
しかしながら、目付けの大きい布帛に従来の方法を適用したものでは、速乾性の点でまだ十分とはいえなかった。
On the other hand, as a method for imparting quick-drying property to a fabric, a method for forming a fabric with a multilayer structure, a method for imparting water repellency to a fabric, a method for forming a fabric with a modified cross-section fiber, a method for imparting an infrared absorber to a fabric, etc. Has been proposed (see, for example, Patent Document 1, Patent Document 2, Patent Document 3, and Patent Document 4).
However, what applied the conventional method to the fabric with a large fabric weight was not yet enough in terms of quick-drying.

特開2004−27409号公報JP 2004-27409 A 特開2010−180517号公報JP 2010-180517 A 特開2006−200054号公報JP 2006-200054 A 特開2009−299213号公報JP 2009-299213 A

本発明は上記の背景に鑑みなされたものであり、その目的は、目付けが大きい布帛であるにもかかわわらず極めて速乾性に優れた速乾性布帛、および該速乾性布帛を用いてなる繊維製品を提供することにある。   The present invention has been made in view of the above-described background, and an object of the present invention is to provide a quick-drying fabric excellent in quick-drying despite being a fabric having a large basis weight, and a fiber product using the quick-drying fabric. Is to provide.

本発明者は、撚糸を施した有機繊維糸条で布帛を構成し、該布帛に撥水加工を施すことにより極めて優れた速乾性が得られることを見出し、さらに鋭意検討を重ねることにより本発明を完成するに至った。   The present inventor has found that a very excellent quick-drying property can be obtained by constituting a fabric with twisted organic fiber yarns and subjecting the fabric to a water repellent treatment, and further studying the present invention. It came to complete.

かくして、本発明によれば「有機繊維糸条を含み、目付けが150g/m以上の布帛であって、前記有機繊維糸条に撚係数5000以上の撚糸が施されており、かつ布帛に撥水加工が施されていることを特徴とする速乾性布帛。」が提供される。
ただし、撚係数は下記式により算出する。
撚係数=T×(D)1/2
ここで、Tは撚数(T/m)であり、Dは有機繊維糸条の総繊度(dtex)である。
その際、下記式で定義する洗濯脱水抱水率が50%以下であることが好ましい。
洗濯脱水抱水率(%)=(W1−W0)/W0×100
ただし、W0は試料(タテ40cm、ヨコ40cm)を乾燥後、温度20℃、相対湿度65%の環境に24時間放置した後の重量(g)であり、W1は当該試料を洗濯脱水した後の重量(g)である。また、洗濯脱水は、試料(タテ40cm、ヨコ40cm)を、JIS−C−9606に規定する遠心式脱水装置付きの家庭用電気洗濯機を用い、JIS−L−0217の103法に記載の試験方法で行う。
Thus, according to the present invention, “a fabric including an organic fiber yarn and having a basis weight of 150 g / m 2 or more, wherein the organic fiber yarn is applied with a twist yarn of 5000 or more, and the fabric is repellent. A quick-drying fabric characterized by being subjected to water processing. "
However, the twist coefficient is calculated by the following formula.
Twist factor = T × (D) 1/2
Here, T is the number of twists (T / m), and D is the total fineness (dtex) of the organic fiber yarn.
In that case, it is preferable that the washing | cleaning dehydration water retention defined by a following formula is 50% or less.
Washing water dehydration rate (%) = (W1-W0) / W0 × 100
However, W0 is a weight (g) after drying a sample (40 cm in length, 40 cm in width) and leaving it in an environment at a temperature of 20 ° C. and a relative humidity of 65% for 24 hours, and W1 is after the sample is washed and dehydrated. Weight (g). In addition, laundry dehydration is a test described in the method 103 of JIS-L-0217 using a household electric washing machine with a centrifugal dehydrator specified in JIS-C-9606 for a sample (length 40 cm, width 40 cm). By the way.

また、前記有機繊維糸条がポリエステル糸条であることが好ましい。また、前記有機繊維糸条に仮撚捲縮加工が施されていることが好ましい。また、布帛が、下記式で定義するカバーファクターCFが2000〜4500の織物であることが好ましい。
CF=(DWp/1.1)1/2×MWp+(DWf/1.1)1/2×MWf
ただし、DWpは経糸総繊度(dtex)、MWpは経糸織密度(本/2.54cm)、DWfは緯糸総繊度(dtex)、MWfは緯糸織密度(本/2.54cm)である。
また、本発明によれば、前記の速乾性布帛を用いてなる、学生服、学生ズボン、作業衣、および制服からなる群より選択されるいずれかの繊維製品が提供される。
The organic fiber yarn is preferably a polyester yarn. Moreover, it is preferable that false twist crimp processing is given to the said organic fiber yarn. The fabric is preferably a woven fabric having a cover factor CF defined by the following formula of 2000 to 4500.
CF = (DWp / 1.1) 1/2 * MWp + (DWf / 1.1) 1/2 * MWf
However, DWp is the total warp fineness (dtex), MWp is the warp weave density (main / 2.54 cm), DWf is the total weft fineness (dtex), and MWf is the weft weave density (main / 2.54 cm).
In addition, according to the present invention, there is provided any textile product selected from the group consisting of school uniforms, student pants, work clothes, and uniforms, using the quick-drying fabric.

本発明によれば、目付けが大きい布帛であるにもかかわわらず極めて速乾性に優れた速乾性布帛、および該速乾性布帛を用いてなる繊維製品が得られる。   ADVANTAGE OF THE INVENTION According to this invention, although it is a fabric with a large fabric weight, the quick-drying fabric excellent in quick-drying property, and the textiles using this quick-drying fabric are obtained.

実施例1で用いた織組織図である。1 is a woven structure diagram used in Example 1. FIG. 実施例2、比較例1、比較例2で用いた織組織図である。3 is a woven structure diagram used in Example 2, Comparative Example 1, and Comparative Example 2. FIG.

本発明の速乾性布帛は、有機繊維糸条を含み、目付けが150g/m以上(好ましくは150〜400g/m、特に好ましくは150〜300g/m)の布帛である。該目付けが150g/m未満の場合は、本発明の速乾性布帛を学生服の表地などとして用いた場合、保温性や布帛強度が不十分となるおそれがあり、好ましくない。 The quick-drying fabric of the present invention is a fabric containing organic fiber yarns and having a basis weight of 150 g / m 2 or more (preferably 150 to 400 g / m 2 , particularly preferably 150 to 300 g / m 2 ). When the basis weight is less than 150 g / m 2 , when the quick-drying fabric of the present invention is used as a surface for school clothes, the heat retention and fabric strength may be insufficient, such being undesirable.

次に、本発明の速乾性布帛は、撚係数5000以上(好ましくは8000〜40000、特に好ましくは20000〜30000)の撚糸が施された有機繊維糸条を含む。かかる撚係数で撚糸が施された有機繊維糸条が布帛に含まれない場合は、十分な速乾性が得られず好ましくない。ただし、撚係数は下記式により算出する。
撚係数=T×(D)1/2
ここで、Tは撚数(T/m)であり、Dは有機繊維糸条の総繊度(dtex)である。
Next, the quick-drying fabric of this invention contains the organic fiber yarn by which the twisted yarn of 5000 or more (preferably 8000-40000, especially preferably 20000-30000) was given. If the fabric does not contain an organic fiber yarn that has been twisted with such a twisting coefficient, it is not preferable because sufficient quick drying properties cannot be obtained. However, the twist coefficient is calculated by the following formula.
Twist factor = T × (D) 1/2
Here, T is the number of twists (T / m), and D is the total fineness (dtex) of the organic fiber yarn.

前記有機繊維の種類としては、ポリエステル繊維、アセテート繊維、ポリアミド繊維、アラミド繊維、炭素繊維、綿や羊毛などの天然繊維などいずれでもよい。なかでも、ポリエチレンテレフタレートやポリトリメチレンテレフタレート、ポリブチレンテレフタレート、ポリ乳酸、ステレオコンプレックスポリ乳酸、第3成分を共重合させたポリエステルなどからなるポリエステル繊維が、速乾性だけでなくリサイクル性にも優れ好ましい。なお、かかるポリエステルとしては、マテリアルリサイクルまたはケミカルリサイクルされたポリエステルであってもよい。さらには、特開2004−270097号公報や特開2004−211268号公報に記載されているような、特定のリン化合物およびチタン化合物を含む触媒を用いて得られたポリエステルでもよい。該ポリマー中には、本発明の目的を損なわない範囲内で必要に応じて、微細孔形成剤、カチオン染料可染剤、着色防止剤、熱安定剤、蛍光増白剤、艶消し剤、着色剤、吸湿剤、無機微粒子が1種または2種以上含まれていてもよい。   The organic fiber may be any of polyester fiber, acetate fiber, polyamide fiber, aramid fiber, carbon fiber, natural fiber such as cotton and wool. Among them, a polyester fiber made of polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polylactic acid, stereocomplex polylactic acid, polyester copolymerized with the third component, etc. is preferable because it is excellent not only in quick drying but also in recyclability. . The polyester may be material recycled or chemically recycled polyester. Furthermore, the polyester obtained using the catalyst containing the specific phosphorus compound and titanium compound which are described in Unexamined-Japanese-Patent No. 2004-270097 and 2004-21268 may be sufficient. In the polymer, a fine pore forming agent, a cationic dye dyeing agent, an anti-coloring agent, a heat stabilizer, a fluorescent whitening agent, a matting agent, a coloring agent may be added as necessary within the range not impairing the object of the present invention. 1 type, or 2 or more types of an agent, a hygroscopic agent, and inorganic fine particles may be contained.

前記有機繊維の繊維形態は、長繊維(マルチフィラメント)、短繊維(紡績糸)いずれでもよいが、長繊維(マルチフィラメント)が好ましい。単繊維の断面形状も特に限定されず、丸、三角、扁平、中空など公知の断面形状でよい。また、通常の空気加工、仮撚捲縮加工が施されていてもさしつかえない。特に、有機繊維糸条に仮撚捲縮加工が施されていると布帛が嵩高となるため保温性が向上し好ましい。   The fiber form of the organic fiber may be either a long fiber (multifilament) or a short fiber (spun yarn), but a long fiber (multifilament) is preferable. The cross-sectional shape of the single fiber is not particularly limited, and may be a known cross-sectional shape such as a circle, a triangle, a flat shape, or a hollow shape. In addition, normal air processing and false twist crimping may be applied. In particular, it is preferable that the organic fiber yarn is subjected to false twist crimping because the fabric becomes bulky and thus the heat retention is improved.

前記有機繊維において、単糸繊維繊度、総繊度、フィラメント数は特に限定されないが、ソフトな風合いを得る上で、それぞれ単糸繊維繊度4.0dtex以下(好ましくは0.1〜4.0dtex)、総繊度30〜200dtex、フィラメント数30本以上(より好ましくは60本以上、さらに好ましくは60〜200本)の範囲内であることが好ましい。   In the organic fiber, the single fiber fineness, the total fineness, and the number of filaments are not particularly limited, but for obtaining a soft texture, the single fiber fineness is 4.0 dtex or less (preferably 0.1 to 4.0 dtex), It is preferable that the total fineness is 30 to 200 dtex and the number of filaments is 30 or more (more preferably 60 or more, and further preferably 60 to 200).

前記布帛の布帛組織は特に限定されず織物、編物、不織布などいずれでもよい。なかでも、引裂き強力の強さの点で織物または編物が好ましい。特に織物が好ましい。織物組織としては、平織、綾織、朱子織等の三原組織、変化組織、たて二重織、よこ二重織等の片二重組織、たてビロードなどが例示されるがこれらに限定されない。層数は単層でもよいし、2層以上の多層でもよい。特に、下記式により定義されるカバーファクターCFが2000〜4500の織物であると、前記のような大きな目付けが得られやすく好ましい。なお、以上のような布帛は常法により製造することが可能である。
CF=(DWp/1.1)1/2×MWp+(DWf/1.1)1/2×MWf
[DWpは経糸総繊度(dtex)、MWpは経糸織密度(本/2.54cm)、DWfは緯糸総繊度(dtex)、MWfは緯糸織密度(本/2.54cm)である。]
The fabric structure of the fabric is not particularly limited and may be a woven fabric, a knitted fabric, a nonwoven fabric, or the like. Of these, a woven fabric or a knitted fabric is preferable in terms of tear strength. A woven fabric is particularly preferable. Examples of the fabric structure include, but are not limited to, a three-layer structure such as plain weave, twill weave, and satin weave, a change structure, a single double structure such as a vertical double weave and a horizontal double weave, and a vertical velvet. The number of layers may be a single layer or a multilayer of two or more layers. In particular, a fabric having a cover factor CF defined by the following formula of 2000 to 4500 is preferable because large fabric weight as described above is easily obtained. In addition, the above fabrics can be manufactured by a conventional method.
CF = (DWp / 1.1) 1/2 × MWp + (DWf / 1.1) 1/2 × MWf
[DWp is the total warp fineness (dtex), MWp is the warp weave density (main / 2.54 cm), DWf is the total weft fineness (dtex), and MWf is the weft weave density (main / 2.54 cm). ]

本発明の速乾性布帛は、前記の布帛に撥水加工を施したものである。かかる布帛は、例えば、以下の製造方法により製造することができる。
まず、前記のような有機繊維糸条を用意し、該有機繊維糸条に撚係数5000以上の撚糸を施した後、該有機繊維糸条を用いて、目付けが150g/m以上の布帛を製編織する。その際、前記有機繊維糸条だけで布帛を構成することが最も好ましいが、布帛重量に対して50重量%以下であれば、他の有機繊維糸条(例えば、撚係数5000未満のポリエステル繊維糸条など)が含まれていてもよい。
The quick-drying fabric of the present invention is obtained by subjecting the fabric to a water repellent finish. Such a fabric can be manufactured, for example, by the following manufacturing method.
First, an organic fiber yarn as described above is prepared, and after twisting the organic fiber yarn with a twist coefficient of 5000 or more, a fabric having a basis weight of 150 g / m 2 or more is formed using the organic fiber yarn. Weaving and weaving. At that time, it is most preferable that the fabric is constituted only by the organic fiber yarn, but if it is 50% by weight or less based on the weight of the fabric, other organic fiber yarn (for example, polyester fiber yarn having a twist coefficient of less than 5000). Article etc.) may be included.

次いで、該布帛に撥水加工を施す。ここで、撥水加工の際に用いる撥水剤としてはフッ素系(例えば、旭硝子(株)製、アサヒガードLS−317)、シリコン系、パラフィン系、エチレン尿素系、脂肪酸系などの撥水剤を挙げることができるが、洗濯耐久性の点からフッ素系、シリコン系の撥水剤を使用するのが好ましい。   Next, the fabric is subjected to water repellent finish. Here, as the water repellent used in the water repellent processing, water-repellent such as fluorine-based (for example, Asahi Guard LS-317 manufactured by Asahi Glass Co., Ltd.), silicon-based, paraffin-based, ethylene urea-based, fatty acid-based, etc. In view of washing durability, it is preferable to use a fluorine-based or silicon-based water repellent.

また、撥水加工としては通常のものでよいが、特許第3133227号公報や特公平4−5786号公報に記載された方法が好適である。すなわち、撥水剤として前記の撥水剤を使用し、必要に応じてメラミン樹脂、触媒を混合して撥水剤の濃度が2〜15重量%程度の加工剤とし、ピックアップ率50〜100%程度で、該加工剤を用いて布帛の表面を処理する方法である。加工剤で布帛の表面を処理する方法としては、パッド法、スプレー法などが例示され、なかでも、加工剤を布帛内部まで浸透させる上でパッド法が最も好ましい。なお、前記ピックアップ率とは、加工剤の布帛(加工剤付与前)重量に対する重量割合(%)である。   The water repellent finish may be a normal one, but the methods described in Japanese Patent No. 3133227 and Japanese Patent Publication No. 4-5786 are suitable. That is, the above-mentioned water repellent is used as a water repellent, and a melamine resin and a catalyst are mixed as necessary to obtain a processing agent having a water repellent concentration of about 2 to 15% by weight, and a pickup rate of 50 to 100%. This is a method of treating the surface of the fabric with the processing agent. Examples of the method of treating the surface of the fabric with the processing agent include a pad method and a spray method, and among them, the pad method is most preferable for allowing the processing agent to penetrate into the fabric. In addition, the said pick-up rate is a weight ratio (%) with respect to the fabric (before processing agent provision) weight of a processing agent.

また、本発明の目的が損なわれない範囲内であれば、撥水加工の前または後において、常法のアルカリ減量加工、染色仕上げ加工、起毛加工、紫外線遮蔽あるいは抗菌剤、消臭剤、防虫剤、蓄光剤、再帰反射剤、マイナスイオン発生剤等の機能を付与する各種加工を付加適用してもよい。   Further, as long as the object of the present invention is not impaired, before or after the water-repellent processing, conventional alkali weight loss processing, dyeing finishing processing, raising processing, ultraviolet shielding or antibacterial agent, deodorant, insect repellent Various processings that impart functions such as an agent, a phosphorescent agent, a retroreflective agent, and a negative ion generator may be additionally applied.

かくして得られた布帛は、目付けが150g/m以上と目付けが大きいにもかかわらず、極めて優れた速乾性を呈する。その理由は、布帛に含まれる有機繊維糸条に撚係数5000以上の撚糸が施されており、かつ布帛に撥水加工が施されているのでこれらの相乗作用によって、水分が布帛内部にはいりにくく、布帛内部にはいった場合においても、脱水時の水切れが良くなっているためでないか、と推定している。 The fabric thus obtained exhibits extremely excellent quick-drying properties although the basis weight is as large as 150 g / m 2 or more. The reason is that the organic fiber yarns contained in the fabric are twisted with a twist coefficient of 5000 or more, and the fabric is water-repellent, so that it is difficult for moisture to enter the fabric due to their synergistic action. Even in the case of entering the fabric, it is presumed that the drainage during dehydration is better.

ここで、速乾性としては、下記式で定義する洗濯脱水抱水率が50%以下(より好ましくは20%以下、特に好ましくは5〜20%)であることが好ましい。
洗濯脱水抱水率(%)=(W1−W0)/W0×100
ただし、W0は試料(タテ40cm、ヨコ40cm)を乾燥後、温度20℃、相対湿度65%の環境に24時間放置した後の重量(g)であり、W1は当該試料を洗濯脱水した後の重量(g)である。また、洗濯脱水は、試料(タテ40cm、ヨコ40cm)を、JIS−C−9606に規定する遠心式脱水装置付きの家庭用電気洗濯機を用い、JIS−L−0217の103法に記載の試験方法で行う。すなわち、洗液温度は40℃とし、標準使用量となる割合で合成洗剤を溶解し、浴比が1対30になるように試料を投入する。この状態で5分間処理した後に運転を止め、試料を脱水機で脱水し、洗濯液を30℃以下の新しい水に替えて2分間すすぎを行う。次に試料を脱水し、ふたたび2分間のすすぎを行い、脱水を3分間(通電時間)行った後の重量をW1とする。
Here, as quick-drying property, it is preferable that the laundry dehydration water retention rate defined by the following formula is 50% or less (more preferably 20% or less, particularly preferably 5 to 20%).
Washing water dehydration rate (%) = (W1-W0) / W0 × 100
However, W0 is a weight (g) after drying a sample (40 cm in length, 40 cm in width) and leaving it in an environment at a temperature of 20 ° C. and a relative humidity of 65% for 24 hours, and W1 is after the sample is washed and dehydrated. Weight (g). In addition, laundry dehydration is a test described in the method 103 of JIS-L-0217 using a household electric washing machine with a centrifugal dehydrator specified in JIS-C-9606 for a sample (length 40 cm, width 40 cm). By the way. That is, the washing temperature is set to 40 ° C., the synthetic detergent is dissolved at a rate corresponding to the standard usage amount, and the sample is introduced so that the bath ratio is 1:30. After processing for 5 minutes in this state, the operation is stopped, the sample is dehydrated with a dehydrator, and the washing liquid is replaced with fresh water of 30 ° C. or lower and rinsed for 2 minutes. Next, the sample is dehydrated, rinsed again for 2 minutes, and the weight after dehydration for 3 minutes (energization time) is defined as W1.

なお、本発明の評価に用いた、遠心式脱水装置付きの家庭用電気洗濯機を使用し、JIS−C−9606の8.12に記載の脱水性試験を行った結果、3分間(通電時間)脱水を行ったときの脱水度は、52(%)であった。その際、脱水度は、以下の式によって算出した。また、脱水性試験に用いる試験布は、JIS−C−9606 付随書1に記載の模擬洗濯物(以下、試験布と記載)を使用した。
脱水度(%)=乾燥試験布の重量(kg)/脱水後の試験布の重量(kg)×100
乾燥試験布の重量(kg)は、試験布を温度20℃、相対湿度65%の環境に24時間放置した後の重量(kg)であり、脱水後の試験布の重量(kg)とは、乾燥試験布を試験に先立ち1時間以上水に付けた後、遠心式脱水装置付きの家庭用電気洗濯機を用い、3分間(通電時間)脱水を行った後の重量(kg)で有る。
In addition, as a result of performing the dehydration test as described in 8.12 of JIS-C-9606 using the household electric washing machine with a centrifugal dehydrator used for the evaluation of the present invention, the result is 3 minutes (energization time ) Dehydration degree when dehydration was performed was 52 (%). At that time, the degree of dehydration was calculated by the following equation. Moreover, the simulated laundry (henceforth a test cloth) as described in the appendix 1 of JIS-C-9606 was used for the test cloth used for a dehydration test.
Dehydration degree (%) = weight of dry test cloth (kg) / weight of test cloth after dehydration (kg) × 100
The weight (kg) of the dried test cloth is the weight (kg) after leaving the test cloth in an environment of a temperature of 20 ° C. and a relative humidity of 65% for 24 hours. The weight (kg) of the test cloth after dehydration is It is the weight (kg) after dehydration for 3 minutes (energization time) using a household electric washing machine equipped with a centrifugal dehydrator after the dry test cloth is dipped in water for 1 hour or more prior to the test.

特に、洗濯20回後の、洗濯脱水抱水率が50%以下(より好ましくは5〜50%)であることが好ましい。ここで、洗濯は、JIS−C−9606に規定する遠心式脱水装置付きの家庭用電気洗濯機を用い、JIS−L−0217の103法に記載の試験方法に準じる洗濯、乾燥を20回繰返す。すなわち、洗液温度は40℃とし、標準使用量となる割合で合成洗剤を溶解し、浴比が1対30になるように試料を投入する。この状態で5分間処理した後に運転を止め、試料を脱水機で脱水し、洗濯液を30℃以下の新しい水に替えて2分間すすぎを行う。次に試料を脱水し、ふたたび2分間のすすぎを行い、脱水し、直射日光の影響を受けない状態で吊干し又は平干しをする。これを20回繰返した後、前記の洗濯脱水抱水率を測定する。   In particular, it is preferable that the water dehydration rate after washing 20 times is 50% or less (more preferably 5 to 50%). Here, washing uses a household electric washing machine with a centrifugal dewatering device specified in JIS-C-9606, and repeats washing and drying 20 times in accordance with the test method described in Method 103 of JIS-L-0217. . That is, the washing temperature is set to 40 ° C., the synthetic detergent is dissolved at a rate corresponding to the standard usage amount, and the sample is introduced so that the bath ratio is 1:30. After processing for 5 minutes in this state, the operation is stopped, the sample is dehydrated with a dehydrator, and the washing liquid is replaced with fresh water of 30 ° C. or lower and rinsed for 2 minutes. Next, the sample is dehydrated, rinsed again for 2 minutes, dehydrated, and hung or flat dried without being affected by direct sunlight. After repeating this 20 times, the washing dehydration water retention rate is measured.

次に、本発明によれば、前記の速乾性布帛を用いてなる、学生服、学生ズボン、作業衣、および制服からなる群より選択されるいずれかの繊維製品が提供される。かかる繊維製品は前記の速乾性布帛を用いているので、目付けが大きいにもかかわわらず極めて優れた速乾性を有する。   Next, according to the present invention, there is provided any textile product selected from the group consisting of school clothes, student trousers, work clothes, and uniforms, using the quick-drying fabric. Since such a fiber product uses the above-mentioned quick-drying fabric, it has extremely excellent quick-drying properties despite its large basis weight.

次に、本発明の実施例および比較例を詳述するが、本発明はこれらによって限定されるものではない。   Next, although the Example and comparative example of this invention are explained in full detail, this invention is not limited by these.

<目付>
JISL1096 6.4により測定した。
<Unit weight>
It was measured according to JISL1096 6.4.

<織物のカバーファクターCF>
下記式により、織物のカバーファクターCFを算出した。
CF=(DWp/1.1)1/2×MWp+(DWf/1.1)1/2×MWf
[DWpは経糸総繊度(dtex)、MWpは経糸織密度(本/2.54cm)、DWfは緯糸総繊度(dtex)、MWfは緯糸織密度(本/2.54cm)である。]
<Fabric cover factor CF>
The cover factor CF of the woven fabric was calculated from the following formula.
CF = (DWp / 1.1) 1/2 × MWp + (DWf / 1.1) 1/2 × MWf
[DWp is the total warp fineness (dtex), MWp is the warp weave density (main / 2.54 cm), DWf is the total weft fineness (dtex), and MWf is the weft weave density (main / 2.54 cm). ]

<撚係数>
下記式により撚係数を算出した。
撚係数=T×(D)1/2
ここで、Tは撚数(T/m)であり、Dは有機繊維糸条の総繊度(dtex)である。
<Twist factor>
The twist coefficient was calculated by the following formula.
Twist factor = T × (D) 1/2
Here, T is the number of twists (T / m), and D is the total fineness (dtex) of the organic fiber yarn.

<洗濯脱水抱水率>
下記式により洗濯脱水抱水率を求めた。
洗濯脱水抱水率(%)=(W1−W0)/W0×100
ただし、W0は試料(タテ40cm、ヨコ40cm)を乾燥後、温度20℃、相対湿度65%の環境に24時間放置した後の重量(g)であり、W1は当該試料を洗濯脱水した後の重量(g)である。また、洗濯脱水は、試料(タテ40cm、ヨコ40cm)を、JIS−C−9606に規定する遠心式脱水装置付きの家庭用電気洗濯機を用い、JIS−L−0217の103法に記載の試験方法で行う。すなわち、洗液温度は40℃とし、標準使用量となる割合で合成洗剤を溶解し、浴比が1対30になるように試料を投入する。この状態で5分間処理した後に運転を止め、試料を脱水機で脱水し、洗濯液を30℃以下の新しい水に替えて2分間すすぎを行う。次に試料を脱水し、ふたたび2分間のすすぎを行い、脱水を3分間(通電時間)行った後の重量をW1とする。
また、洗濯20回後の洗濯脱水抱水率は、下記の洗濯を20回行った後、前記の洗濯脱水抱水率を求めた。すなわち、洗濯は、JIS−C−9606に規定する遠心式脱水装置付きの家庭用電気洗濯機を用い、JIS−L−0217の103法に記載の試験方法に準じる洗濯、乾燥を20回繰返した。すなわち、洗液温度は40℃とし、標準使用量となる割合で合成洗剤を溶解し、浴比が1対30になるように試料を投入した。この状態で5分間処理した後に運転を止め、試料を脱水機で脱水し、洗濯液を30℃以下の新しい水に替えて2分間すすぎを行った。次に試料を脱水し、ふたたび2分間のすすぎを行い、脱水し、直射日光の影響を受けない状態で吊干し又は平干しをする。これを20回繰返した後、前記の洗濯脱水抱水率を測定した。
<Washing and dehydration rate>
The dehydration rate of washing and dehydration was determined by the following formula.
Washing water dehydration rate (%) = (W1-W0) / W0 × 100
However, W0 is a weight (g) after drying a sample (40 cm in length, 40 cm in width) and leaving it in an environment at a temperature of 20 ° C. and a relative humidity of 65% for 24 hours, and W1 is after the sample is washed and dehydrated. Weight (g). In addition, laundry dehydration is a test described in the method 103 of JIS-L-0217 using a household electric washing machine with a centrifugal dehydrator specified in JIS-C-9606 for a sample (length 40 cm, width 40 cm). By the way. That is, the washing temperature is set to 40 ° C., the synthetic detergent is dissolved at a rate corresponding to the standard usage amount, and the sample is introduced so that the bath ratio is 1:30. After processing for 5 minutes in this state, the operation is stopped, the sample is dehydrated with a dehydrator, and the washing liquid is replaced with fresh water of 30 ° C. or lower and rinsed for 2 minutes. Next, the sample is dehydrated, rinsed again for 2 minutes, and the weight after dehydration for 3 minutes (energization time) is defined as W1.
Moreover, the washing | cleaning dehydration water retention after 20 times of washing | cleaning calculated | required the said washing | cleaning dehydration water retention after performing the following washing 20 times. That is, for washing, a household electric washing machine with a centrifugal dehydrator specified in JIS-C-9606 was used, and washing and drying were repeated 20 times in accordance with the test method described in Method 103 of JIS-L-0217. . That is, the washing temperature was set to 40 ° C., the synthetic detergent was dissolved at a rate corresponding to the standard usage amount, and the sample was introduced so that the bath ratio was 1:30. After treatment for 5 minutes in this state, the operation was stopped, the sample was dehydrated with a dehydrator, and the washing liquid was replaced with fresh water of 30 ° C. or less, and rinsed for 2 minutes. Next, the sample is dehydrated, rinsed again for 2 minutes, dehydrated, and hung or flattened without being affected by direct sunlight. After repeating this 20 times, the washing dehydration water retention rate was measured.

[実施例1]
ポリエチレンテレフタレート仮撚捲縮加工糸 167dtex/48filに、村田機械製のダブルツイスターDT−308を用いて仮撚方向と異方向に600T/m追撚(撚係数=7754)し、70℃で30分のスチームセットした撚糸糸条を経糸および緯糸に配して、通常のウォータージェットルーム織機を使用して、図1に記載の織組織を有する織物を織成した。その時の生機密度は、経密度107本/2.54cm、緯密度82本/2.54cmであった。次いで、U型ソフサーを用いて95℃で拡布精練し、液流染色機にて120℃リラックス処理した。次いで、テンターを用いて190℃で中間セットし、液流染色機にて130℃の分散染料による染色加工(黒色)を行い、撥水加工を施した後、テンターを用い170℃でファイナルセットした。その際、撥水加工は下記の加工剤を使用し、ピックアップ率80%で搾液し、130℃で3分間乾燥後170℃で45秒間熱処理を行った。
<加工剤組成>
・ふっ素系撥水剤 8.0wt%
(旭硝子(株)製、アサヒガードLS−317)
・メラミン樹脂 0.3wt%
(住友化学(株)製、スミテックスレジンM−3)
・触媒 0.3wt%
(住友化学(株)製、スミテックスアクセレレータACX)
・水 91.4wt%
得られた布帛は、経密度117本/2.54cm、緯密度100本/2.54cm、カバーファクターCF=2674で、目付=185g/m、洗濯脱水抱水率は、初期で12.3%、20回洗濯後で、45.7%であり、速乾性に優れるものであった。
次いで、該布帛を表地に用いて学生服を得た。該学生服は極めて速乾性に優れるものであった。
[Example 1]
Polyethylene terephthalate false twist crimped yarn 167 dtex / 48 fil is subjected to 600 T / m additional twist (twist factor = 7754) in a different direction from the false twist direction using a double twister DT-308 manufactured by Murata Machinery Co., Ltd., and 30 minutes at 70 ° C. The steam-set twisted yarns were arranged on warps and wefts, and a woven fabric having the woven structure shown in FIG. 1 was woven using a normal water jet loom. The green density at that time was a warp density of 107 / 2.54 cm and a weft density of 82 / 2.54 cm. Subsequently, the cloth was scoured and spread at 95 ° C. using a U-shaped softener, and relaxed at 120 ° C. using a liquid dyeing machine. Next, using a tenter, an intermediate set was performed at 190 ° C., dyed with a disperse dye at 130 ° C. (black) with a liquid dyeing machine, water-repellent treatment was performed, and then final set was performed at 170 ° C. using a tenter. . At that time, the following processing agent was used for the water-repellent processing, squeezed at a pickup rate of 80%, dried at 130 ° C. for 3 minutes, and then heat treated at 170 ° C. for 45 seconds.
<Processing agent composition>
・ Fluorine-based water repellent 8.0wt%
(Asahi Guard LS-317, manufactured by Asahi Glass Co., Ltd.)
・ Melamine resin 0.3wt%
(Sumitomo Chemical Co., Ltd., Sumtex Resin M-3)
・ Catalyst 0.3wt%
(Sumitomo Chemical Co., Ltd., Smithex Accelerator ACX)
・ Water 91.4wt%
The obtained fabric had a warp density of 117 / 2.54 cm, a weft density of 100 / 2.54 cm, a cover factor CF = 2675, a basis weight of 185 g / m 2 , and a washing dehydration water retention rate of 12.3 in the initial stage. %, After washing 20 times, it was 45.7% and was excellent in quick-drying.
Next, a school uniform was obtained using the fabric as an outer material. The school uniform was extremely quick-drying.

[実施例2]
ポリエチレンテレフタレート複合仮撚捲縮加工糸 190dtex/63filに、村田機械製のダブルツイスターDT−308を用いて仮撚方向と異方向に1800T/m追撚(撚係数=24811)し、75℃で45分のスチームセットした撚糸糸条を経糸に配し、一方、ポリエチレンテレフタレート仮撚捲縮加工糸110dtex/48fil双糸に、村田機械製のダブルツイスターDT−308を用いて仮撚方向と異方向に600T/m追撚(撚係数=8899)し、70℃で30分のスチームセットした撚糸糸条を緯糸に配して、通常のウォータージェットルーム織機を使用して、図2に記載の織組織を有する織物を織成した。その時の生機密度は、経密度137本/2.54cm、緯密度78本/2.54cmであった。それ以外は、実施例1と同様に実施した。得られた布帛は、経密度162本/2.54cm、緯密度88本/2.54cm、カバーファクターCF=3374で、目付=260g/m、洗濯脱水抱水率は、初期で10.4%、20回洗濯後で、31.7%であり、速乾性に優れるものであった。
次いで、該布帛を表地に用いて学生服を得た。該学生服は極めて速乾性に優れるものであった。
[Example 2]
Polyethylene terephthalate composite false twist crimped yarn 190dtex / 63fil is subjected to 1800T / m additional twist (twist factor = 24811) in a different direction from the false twist direction using a double twister DT-308 made by Murata Machinery Co., Ltd. and 45 at 75 ° C. The twisted yarn with the steam set for the minute is placed on the warp yarn, while the double twister DT-308 made by Murata Machinery is used for the polyethylene terephthalate false twisted crimped yarn 110 dtex / 48 fil double yarn in a different direction from the false twist direction. A twisted yarn of 600 T / m (twisting coefficient = 8899) and steam set for 30 minutes at 70 ° C. is arranged on the weft, and using a normal water jet loom, the woven structure shown in FIG. A woven fabric having The green density at that time was warp density 137 / 2.54 cm, and weft density 78 / 2.54 cm. Other than that was carried out in the same manner as in Example 1. The obtained fabric had a warp density of 162 / 2.54 cm, a weft density of 88 / 2.54 cm, a cover factor CF of 3374, a basis weight of 260 g / m 2 , and a washing dehydration water retention rate of 10.4 in the initial stage. %, After washing 20 times, it was 31.7% and was excellent in quick-drying.
Next, a school uniform was obtained using the fabric as an outer material. The school uniform was extremely quick-drying.

[実施例3]
ポリエチレンテレフタレート複合仮撚捲縮加工糸 190dtex/63filに、村田機械製のダブルツイスターDT−308を用いて仮撚方向と異方向に1200T/m追撚(撚係数=16541)し、75℃で45分のスチームセットした撚糸糸条を経糸に配し、一方、ポリエチレンテレフタレート仮撚捲縮加工糸110dtex/48fil双糸に、村田機械製のダブルツイスターDT−308を用いて仮撚方向と異方向に150T/m追撚(撚係数=2225)した撚糸糸条を緯糸に配して、通常のウォータージェットルーム織機を使用して、図2に記載の織組織を有する織物を織成した。その時の生機密度は、経密度136本/2.54cm、緯密度78本/2.54cmであった。次いで、U型ソフサーを用いて95℃で拡布精練し、液流染色機にて120℃リラックス処理した。次いで、テンターを用いて190℃で中間セットし、液流染色機にて130℃の分散染料による染色を行い、撥水加工を施した後、テンターを用い170℃でファイナルセットした。その際、撥水加工は下記の加工剤を使用し、ピックアップ率80%で搾液し、130℃で3分間乾燥後170℃で45秒間熱処理を行った。
<加工剤組成>
・ふっ素系撥水剤 2.0wt%
(旭硝子(株)製、アサヒガード AG710)
・水 98.0wt%
得られた布帛は、経密度161本/2.54cm、緯密度94本/2.54cm、カバーファクターCF=3445で、目付=273g/m、洗濯脱水抱水率は、初期で55.1%、20回洗濯後で、82.9%であり、速乾性にやや優れるものであった。
次いで、該布帛を表地に用いて学生服を得た。該学生服は、実施例2で得られたものより劣るものの速乾性にやや優れるものであった。
[Example 3]
Polyethylene terephthalate composite false twist crimped yarn 190 dtex / 63 fil is subjected to 1200 T / m additional twist (twist factor = 16541) in the opposite direction to the false twist direction using a double twister DT-308 manufactured by Murata Machinery Co., Ltd. and 45 at 75 ° C. The twisted yarn with the steam set for the minute is placed on the warp yarn, while the double twister DT-308 made by Murata Machinery is used for the polyethylene terephthalate false twisted crimped yarn 110 dtex / 48 fil double yarn in a different direction from the false twist direction. A woven fabric having the woven structure shown in FIG. 2 was woven using a normal water jet loom by placing twisted yarns with 150 T / m additional twist (twisting coefficient = 2225) on the weft. The green density at that time was warp density 136 / 2.54 cm, and weft density 78 / 2.54 cm. Subsequently, the cloth was scoured and spread at 95 ° C. using a U-shaped softener, and relaxed at 120 ° C. using a liquid dyeing machine. Subsequently, using a tenter, intermediate setting was performed at 190 ° C., dyeing with a disperse dye at 130 ° C. was performed with a liquid dyeing machine, and after water-repellent finishing, final setting was performed at 170 ° C. using a tenter. At that time, the following processing agent was used for the water-repellent processing, squeezed at a pickup rate of 80%, dried at 130 ° C. for 3 minutes, and then heat-treated at 170 ° C. for 45 seconds.
<Processing agent composition>
・ Fluorine-based water repellent 2.0wt%
(Asahi Guard AG710, manufactured by Asahi Glass Co., Ltd.)
・ Water 98.0wt%
The obtained fabric had a warp density of 161 pieces / 2.54 cm, a weft density of 94 pieces / 2.54 cm, a cover factor of CF = 3445, a basis weight of 273 g / m 2 , and a washing dehydration water retention rate of 55.1 in the initial stage. %, After washing 20 times, it was 82.9%, which was somewhat excellent in quick-drying.
Next, a school uniform was obtained using the fabric as an outer material. Although the school uniform was inferior to that obtained in Example 2, it was somewhat superior in quick-drying.

[比較例1]
実施例3において、撥水加工を付与せず処理を行い、それ以外は、実施例3と同様に実施した。
得られた布帛は、経密度161本/2.54cm、緯密度94本/2.54cm、カバーファクターCF=3445で、目付=271g/m、洗濯脱水抱水率は、初期で97.3%、20回洗濯後で、98.4%であり、速乾性に劣るものであった。
次いで、該布帛を表地に用いて学生服を得た。該学生服は、実施例3で得られたものより速乾性に劣るものであった。
[Comparative Example 1]
In Example 3, the treatment was performed without imparting the water repellent treatment, and the other processes were performed in the same manner as in Example 3.
The obtained fabric had a warp density of 161 pieces / 2.54 cm, a weft density of 94 pieces / 2.54 cm, a cover factor CF of 3445, a basis weight of 271 g / m 2 , and a washing dehydration water retention of 97.3 at the initial stage. %, After washing 20 times, it was 98.4%, which was inferior in quick-drying.
Next, a school uniform was obtained using the fabric as an outer material. The school uniform was inferior in quick-drying than that obtained in Example 3.

本発明によれば、目付けが大きい布帛であるにもかかわわらず極めて速乾性に優れた速乾性布帛、および該速乾性布帛を用いてなる繊維製品が提供され、その工業的価値は極めて大である。   ADVANTAGE OF THE INVENTION According to this invention, although it is a fabric with a large fabric weight, the quick-drying fabric excellent in quick-drying property, and the textiles using this quick-drying fabric are provided, The industrial value is very large. is there.

Claims (6)

有機繊維糸条を含み、目付けが150g/m以上の布帛であって、前記有機繊維糸条に撚係数5000以上の撚糸が施されており、かつ布帛に撥水加工が施されていることを特徴とする速乾性布帛。
ただし、撚係数は下記式により算出する。
撚係数=T×(D)1/2
ここで、Tは撚数(T/m)であり、Dは有機繊維糸条の総繊度(dtex)である。
It is a fabric including organic fiber yarns and having a basis weight of 150 g / m 2 or more, the organic fiber yarns having a twist coefficient of 5000 or more, and the fabric being subjected to water repellent processing. Quick-drying fabric characterized by
However, the twist coefficient is calculated by the following formula.
Twist factor = T × (D) 1/2
Here, T is the number of twists (T / m), and D is the total fineness (dtex) of the organic fiber yarn.
下記式で定義する洗濯脱水抱水率が50%以下である、請求項1に記載の速乾性布帛。
洗濯脱水抱水率(%)=(W1−W0)/W0×100
ただし、W0は試料(タテ40cm、ヨコ40cm)を乾燥後、温度20℃、相対湿度65%の環境に24時間放置した後の重量(g)であり、W1は当該試料を洗濯脱水した後の重量(g)である。また、洗濯脱水は、試料(タテ40cm、ヨコ40cm)を、JIS−C−9606に規定する遠心式脱水装置付きの家庭用電気洗濯機を用い、JIS−L−0217の103法に記載の試験方法で行う。
The quick-drying fabric according to claim 1, wherein the dehydrating water retention rate for washing defined by the following formula is 50% or less.
Washing water dehydration rate (%) = (W1-W0) / W0 × 100
However, W0 is a weight (g) after drying a sample (40 cm in length, 40 cm in width) and leaving it in an environment at a temperature of 20 ° C. and a relative humidity of 65% for 24 hours, and W1 is after the sample is washed and dehydrated. Weight (g). In addition, laundry dehydration is a test described in the method 103 of JIS-L-0217 using a household electric washing machine with a centrifugal dehydrator specified in JIS-C-9606 for a sample (length 40 cm, width 40 cm). By the way.
前記有機繊維糸条がポリエステル糸条である、請求項1または請求項2に記載の速乾性布帛。   The quick-drying fabric according to claim 1 or 2, wherein the organic fiber yarn is a polyester yarn. 前記有機繊維糸条に仮撚捲縮加工が施されている、請求項1〜3のいずれかに記載の速乾性布帛。   The quick-drying cloth according to any one of claims 1 to 3, wherein the organic fiber yarn is subjected to false twist crimping. 布帛が、下記式で定義するカバーファクターCFが2000〜4500の織物である、請求項1〜4のいずれかに記載の速乾性布帛。
CF=(DWp/1.1)1/2×MWp+(DWf/1.1)1/2×MWf
ただし、DWpは経糸総繊度(dtex)、MWpは経糸織密度(本/2.54cm)、DWfは緯糸総繊度(dtex)、MWfは緯糸織密度(本/2.54cm)である。
The quick-drying fabric according to any one of claims 1 to 4, wherein the fabric is a woven fabric having a cover factor CF defined by the following formula of 2000 to 4500.
CF = (DWp / 1.1) 1/2 * MWp + (DWf / 1.1) 1/2 * MWf
However, DWp is the total warp fineness (dtex), MWp is the warp weave density (main / 2.54 cm), DWf is the total weft fineness (dtex), and MWf is the weft weave density (main / 2.54 cm).
請求項1〜5のいずれかに記載の速乾性布帛を用いてなる、学生服、学生ズボン、作業衣、および制服からなる群より選択されるいずれかの繊維製品。   Any one textile product selected from the group which consists of a school uniform, student pants, work clothes, and a uniform which uses the quick-drying cloth in any one of Claims 1-5.
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