JP2011090193A - 光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 - Google Patents
光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 Download PDFInfo
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- JP2011090193A JP2011090193A JP2009244427A JP2009244427A JP2011090193A JP 2011090193 A JP2011090193 A JP 2011090193A JP 2009244427 A JP2009244427 A JP 2009244427A JP 2009244427 A JP2009244427 A JP 2009244427A JP 2011090193 A JP2011090193 A JP 2011090193A
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- sensitive adhesive
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- adhesive layer
- optical film
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- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
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- 230000002441 reversible effect Effects 0.000 description 1
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- AYYIWCRQXLDMJG-UHFFFAOYSA-N tributoxy(pent-4-enyl)silane Chemical compound CCCCO[Si](CCCC=C)(OCCCC)OCCCC AYYIWCRQXLDMJG-UHFFFAOYSA-N 0.000 description 1
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- OCANZHUXNZTABW-UHFFFAOYSA-N triethoxy(pent-4-enyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCC=C OCANZHUXNZTABW-UHFFFAOYSA-N 0.000 description 1
- UMFJXASDGBJDEB-UHFFFAOYSA-N triethoxy(prop-2-enyl)silane Chemical compound CCO[Si](CC=C)(OCC)OCC UMFJXASDGBJDEB-UHFFFAOYSA-N 0.000 description 1
- WDUXKFKVDQRWJN-UHFFFAOYSA-N triethoxysilylmethyl prop-2-enoate Chemical compound CCO[Si](OCC)(OCC)COC(=O)C=C WDUXKFKVDQRWJN-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- LFRDHGNFBLIJIY-UHFFFAOYSA-N trimethoxy(prop-2-enyl)silane Chemical compound CO[Si](OC)(OC)CC=C LFRDHGNFBLIJIY-UHFFFAOYSA-N 0.000 description 1
- JPPHEZSCZWYTOP-UHFFFAOYSA-N trimethoxysilylmethyl prop-2-enoate Chemical compound CO[Si](OC)(OC)COC(=O)C=C JPPHEZSCZWYTOP-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/10—Adhesives in the form of films or foils without carriers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
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Abstract
【解決手段】光学フィルム用粘着剤層であって、前記粘着剤層は、モノマーを界面活性剤およびラジカル重合開始剤の存在下に重合することにより得られたポリマーが水中に分散含有されている水分散液を含有する水分散型粘着剤を塗布した後、乾燥することにより形成されたものであり、前記界面活性剤の割合が、モノマー100重量部に対して0.3〜5重量部であり、かつ、前記粘着剤層は、23℃で1週間、水中に放置して、水不溶性成分と水溶性成分に分離した場合に、当該粘着剤層に対する前記水不溶性成分の割合が95〜99重量%であり、かつ、前記水溶性成分中に含まれる前記界面活性剤の割合が、前記水溶性成分に対して50重量%以下であることを特徴とする光学フィルム用粘着剤層。
【選択図】なし
Description
前記粘着剤層は、ベースポリマーが水中に分散含有されている水分散液を含有する水分散型粘着剤を塗布した後、乾燥することにより形成されたものであり、
前記水分散液は、モノマーを界面活性剤およびラジカル重合開始剤の存在下に水中で重合することにより得られたものであり、
前記界面活性剤の割合が、モノマー100重量部に対して0.3〜5重量部であり、
かつ、前記粘着剤層は、23℃で1週間、水中に放置して、水不溶性成分と水溶性成分に分離した場合に、
当該粘着剤層に対する前記水不溶性成分の割合が95〜99重量%であり、かつ、
前記水溶性成分中に含まれる前記界面活性剤の割合が、前記水溶性成分に対して50重量%以下であることを特徴とする光学フィルム用粘着剤、に関する。
(一般式(1)中、R1は、水素原子またはメチル基を示し、R2は炭素数1〜4のアルキレン基、mは2以上の整数を示し、M1およびM2は、それぞれ独立に、水素原子またはカチオンを示す。)で表されるリン酸基またはその塩を示す。)で表されるリン酸基含有モノマーが挙げられる。
(エマルション型アクリル系粘着剤の調製)
容器に、原料としてアクリル酸ブチル950部、アクリル酸50部、および3−メタクリロイルオキシプロピル−トリエトキシシラン(信越化学工業(株)製,KBM−503)0.3部を加えて混合し、モノマー混合物を得た。次いで、上記割合で調製したモノマー混合物600部に対して、界面活性剤として、非反応性界面活性剤(アニオン性)であるハイテノールNF−08(第一工業製薬(株)製)24部、イオン交換水382部を加え、ホモミキサー(特殊機化工業(株)製)を用い、5分間、6000(rpm/min)で攪拌し、モノマーエマルションを調製した。
上記エマルション型アクリル系粘着剤を、乾燥後の厚みが20μmとなるように、離型フィルム(三菱化学ポリエステル(株)製,ダイアホイルMRF−38,ポリエチレンテレフタレート基材)上にダイコーターにより塗布した後、120℃で5分間乾燥して、粘着剤層を形成した。当該粘着剤層を偏光板(日東電工(株)製,製品名SEG−DU)と貼り合せて、粘着型偏光板を作成した。
実施例1において、エマルション型アクリル系粘着剤の調製にあたり、界面活性剤として、ハイテノールNF−08の代わりに、反応性界面活性剤(アニオン性)であるアクアロンHS−10(第一工業製薬(株)製)24部を使用したこと以外は、実施例1と同様にしてエマルション型アクリル系粘着剤を調製した。また、当該粘着剤を用いて実施例1と同様にして粘着剤層の形成および粘着型偏光板の作成を行った。
実施例1において、エマルション型アクリル系粘着剤の調製にあたり、界面活性剤として、ハイテノールNF−08の代わりに、反応性界面活性剤(アニオン性)であるアクアロンHS−10(第一工業製薬(株)製)6部を使用したこと以外は、実施例1と同様にしてエマルション型アクリル系粘着剤を調製した。また、当該粘着剤を用いて実施例1と同様にして粘着剤層の形成および粘着型偏光板の作成を行った。
実施例1において、エマルション型アクリル系粘着剤の調製にあたり、界面活性剤として、ハイテノールNF−08の代わりに、反応性界面活性剤(ノニオン性)であるアクアロンRN−20(第一工業製薬(株)製)6部を使用したこと以外は、実施例1と同様にしてエマルション型アクリル系粘着剤を調製した。また、当該粘着剤を用いて実施例1と同様にして粘着剤層の形成および粘着型偏光板の作成を行った。
実施例1において、エマルション型アクリル系粘着剤の調製にあたり、界面活性剤として、ハイテノールNF−08の代わりに、反応性界面活性剤(アニオン性)であるアクアロンHS−10(第一工業製薬(株)製)6部を使用したこと、モノマー混合物に、3−メタクリロイルオキシプロピル−トリエトキシシラン(信越化学工業(株)製,KBM−503)を加えなかったこと以外は、実施例1と同様にしてエマルション型アクリル系粘着剤を調製した。また、当該粘着剤を用いて実施例1と同様にして粘着剤層の形成および粘着型偏光板の作成を行った。
実施例1において、エマルション型アクリル系粘着剤の調製にあたり、界面活性剤として、ハイテノールNF−08の代わりに、非反応性界面活性剤(ノニオン性)であるエマルゲンA−60(花王(株)製)24部を使用した以外は、実施例1と同様にしてエマルション型アクリル系粘着剤を調製した。また、当該粘着剤を用いて実施例1と同様にして粘着剤層の形成および粘着型偏光板の作成を行った。
実施例1において、エマルション型アクリル系粘着剤の調製にあたり、モノマー混合物に、3−メタクリロイルオキシプロピル−トリエトキシシラン(信越化学工業(株)製,KBM−503)を加えなかったこと、得られたエマルション型アクリル系粘着剤100部(固形分)に更に、架橋剤としてカルボジライトE−03A(日清紡ケミカル(株)製)1部を配合したこと以外は、実施例1と同様にしてエマルション型アクリル系粘着剤を調製した。また、当該粘着剤を用いて実施例1と同様にして粘着剤層の形成および粘着型偏光板の作成を行った。
実施例3で得られた、エマルション型アクリル系粘着剤100部(固形分)に更に、架橋剤としてカルボジライトE−03A(日清紡ケミカル(株)製)1部を配合したこと以外は、実施例3と同様にしてエマルション型アクリル系粘着剤を調製した。また、当該粘着剤を用いて実施例1と同様にして粘着剤層の形成および粘着型偏光板の作成を行った。
実施例1において、エマルション型アクリル系粘着剤の調製にあたり、界面活性剤として、ハイテノールNF−08の代わりに、反応性界面活性剤(アニオン性)であるアクアロンHS−10(第一工業製薬(株)製)0.1部を使用したこと以外は、実施例1と同様にしてエマルション型アクリル系粘着剤を調製した。また、当該粘着剤を用いて実施例1と同様にして粘着剤層の形成および粘着型偏光板の作成を行った。
実施例1において、エマルション型アクリル系粘着剤の調製にあたり、非反応界面活性剤(アニオン性)であるハイテノールNF−08の使用量を36部に変えたこと以外は、実施例1と同様にしてエマルション型アクリル系粘着剤を調製した。また、当該粘着剤を用いて実施例1と同様にして粘着剤層の形成および粘着型偏光板の作成を行った。
実施例1において、エマルション型アクリル系粘着剤の調製にあたり、モノマー混合物に、3−メタクリロイルオキシプロピル−トリエトキシシラン(信越化学工業(株)製,KBM−503)を加えなかったこと、界面活性剤として、ハイテノールNF−08の代わりに、反応性界面活性剤(アニオン性)であるアクアロンHS−10(第一工業製薬(株)製)60部を使用した、得られたエマルション型アクリル系粘着剤100部(固形分)に更に、エポキシ系シランカップリング剤としてKBE−403(信越化学工業(株)製)10部を配合したこと以外は、実施例1と同様にしてエマルション型アクリル系粘着剤を調製した。また、当該粘着剤を用いて実施例1と同様にして粘着剤層の形成および粘着型偏光板の作成を行った。
実施例1において、エマルション型アクリル系粘着剤の調製にあたり、モノマー混合物中の3−メタクリロイルオキシプロピル−トリエトキシシラン(信越化学工業(株)製,KBM−503)の配合量を0.05部にしたこと、界面活性剤である、ハイテノールNF−08の配合量を36部にしたこと、得られたエマルション型アクリル系粘着剤100部(固形分)に更に、エポキシ系シランカップリング剤としてKBE−403(信越化学工業(株)製)20部を配合したこと以外は、実施例1と同様にしてエマルション型アクリル系粘着剤を調製した。また、当該粘着剤を用いて実施例1と同様にして粘着剤層の形成および粘着型偏光板の作成を行った。
容器に、アクリル酸2−エチルヘキシル50.5部、アクリル酸ブチル40.5部、アクリル酸エチル5部、メタクリル酸メチル3部、アクリル酸1部、接着付与樹脂としてロジン系樹脂である「スーパーエステルA-125」(荒川化学工業(株)製)10部、テルペン系樹脂である「YSレジンPX1250」(ヤスハラケミカル(株)製)5部を混合し、モノマーに接着付与樹脂を溶解し、両者の混合物を得た。この混合物に、水溶性の非反応性界面活性剤であるポリオキシエチレンアルキルエーテルサルフェート(アルキル基の炭素数12,オキシエチレン基の付加数18)1部とイオン交換水50を加え、ホモミキサーを用いて撹拌し、モノマーエマルションを調製した。次いで、冷却管、窒素導入管、温度計および撹拌機を備えた反応容器に、イオン交換水49部と上記ポリオキシエチレンアルキルエーテルサルフェート0.1部を仕込み、窒素雰囲気下で撹拌して内温78℃まで昇温させて、5%過硫酸アンモイウム水溶液を2.1部加えた。5分後に、上記モノマーエマルションと5%過硫酸アンモニウム水溶液6.3部をそれぞれ別の滴下槽から4時間かけて滴下して、重合を行った。滴下終了後、3時間で80℃に保ち、その後、40℃以下に冷却してから10%アンモニア水で中和し、pHを8に調整した、エマルション型アクリル系粘着剤を得た。このエマルション型アクリル系粘着剤の不揮発分は50.1%であった。
各例で調製したエマルション型アクリル系粘着剤を、離型フィルムを貼り合せたガラス容器内に乾燥膜厚が0.5mmになるように流し込み、室温(23℃)で1週間して、粘着剤層を作製した。当該粘着剤層を4cm2の大きさで切り出して、これをサンプルとして、その重量(初期重量)を秤量した。そのサンプルを、純水を満たした100ml瓶に入れて、室温(23℃)で1週間放置した。放置後に、サンプルを前記瓶から取り出し、130℃で2時間乾燥し、その重さ(乾燥後重量)を測定し、下記式から、粘着剤層の水不溶成分の割合を算出した。
水不溶成分(%)=(乾燥後重量/初期重量)×100
上記粘着剤層の水不溶成分において、サンプルを取り出した瓶中には、粘着剤層から分離された水溶性成分を含有する水溶液が残存している。当該水溶液を分析し、当該水溶性成分中の界面活性剤量を定量した。水不溶成分測定で算出された水溶性成分量(水不溶成分以外の量)と、前記定量した界面活性剤量から、下記式によって、水溶性成分中の界面活性剤の割合を算出した。
界面活性剤の割合(%)=(定量した界面活性剤量/水溶性成分量)×100
HPLCの測定条件:カラム・オーブンの温度は50℃に設定し、移動相の流量は0.3mL/分とした。移動相は、A液:20mM酢酸アンモニウム水溶液、B液:アセトニトリルを使用した。サンプル注入量は10μLとした。
カラムは、内径4.6mm、長さ150mm、粒径5μmのゲル濾過クロマトグラフィー用カラム(Shodex(株)製,MSpak GF−310 4D)を用いた。
MSの測定条件:測定は、エレクトロスプレイイオン化、SIMモードを採用した。脱溶媒ガスとコーンガスには窒素を用い、その流量はそれぞれ150L/時と45L/時とした。脱溶媒温度とイオン源温度は、それぞれ330℃及び130℃とした。
各実施例および各比較例の粘着型偏光板を、15インチサイズの大きさに切断し、これを、厚さ0.7mmの無アルカリガラス板(コーニング#1737,コーニング(株)製)に貼着し、50℃、0.5MPaのオートクレーブ中に15分間放置した。その後、80℃の雰囲気下で、500時間の処理を行なった。処理された粘着型偏光板における粘着剤層の気泡の発生度合いを下記の基準により、光学顕微鏡にて、その個数と大きさを確認し、下記基準で評価した。(但し、処理前からある気泡は除いて評価した。)
5:最大長さ200μm以上の気泡が1cm2中になし。
4:最大長さ200μm以上の気泡が1cm2中に5個以下。
3:最大長さ200μm以上の気泡が1cm2中に6個〜10個。
2:最大長さ200μm以上の気泡が1cm2中に11個〜100個。
1:最大長さ200μm以上の気泡が1cm2中に101個以上。
各実施例および各比較例の粘着型偏光板を、15インチサイズの大きさに切断し、これを、厚さ0.7mmの無アルカリガラス板(コーニング#1737,コーニング(株)製)に貼着し、50℃、0.5MPaのオートクレーブ中に15分間放置した。その後、60℃/90%R.H.の環境下で、500時間の処理を行なった。
60℃/90%R.H.の環境下から、室温条件(23℃,55%R.H.)に取り出してから24時間以内に、処理された粘着型偏光板と無アルカリガラスの間の剥がれの度合いを目視で確認し、下記基準で評価した。
5:剥がれの発生なし。
4:粘着型偏光板の端部から0.5mm以内の箇所に剥がれが発生。
3:粘着型偏光板の端部から1.0mm以内の箇所に剥がれが発生。
2:粘着型偏光板の端部から3.0mm以内の箇所に剥がれが発生。
1:粘着型偏光板の端部から3.0mm以上の箇所に剥がれが発生。
Claims (10)
- 光学フィルム用粘着剤層であって、
前記粘着剤層は、ベースポリマーが水中に分散含有されている水分散液を含有する水分散型粘着剤を塗布した後、乾燥することにより形成されたものであり、
前記水分散液は、モノマーを界面活性剤およびラジカル重合開始剤の存在下に水中で重合することにより得られたものであり、
前記界面活性剤の割合が、モノマー100重量部に対して0.3〜5重量部であり、
かつ、前記粘着剤層は、23℃で1週間、水中に放置して、水不溶性成分と水溶性成分に分離した場合に、
当該粘着剤層に対する前記水不溶性成分の割合が95〜99重量%であり、かつ、
前記水溶性成分中に含まれる前記界面活性剤の割合が、前記水溶性成分に対して50重量%以下であることを特徴とする光学フィルム用粘着剤層。 - 前記粘着剤層が、架橋構造を有していることを特微とする請求項1記載の光学フィルム用粘着剤層。
- 界面活性剤が、ラジカル重合性官能基を有する反応性界面活性剤であることを特徴とする請求項2記載の光学フィルム用粘着剤層。
- モノマーが、多官能性モノマーを含有することを特徴とする請求項2または3記載の光学フィルム用粘着剤層。
- 水分散型粘着剤が、架橋剤を含有することを特徴とする請求項2〜4のいずれかに記載の光学フィルム用粘着剤層。
- 前記界面活性剤の割合が、モノマー100重量部に対して0.3〜2重量部であることを特徴とする請求項1〜5のいずれかに記載の光学フィルム用粘着剤層。
- 前記水分散型粘着剤における水分散液が、乳化重合により得られたポリマーエマルションであることを特徴とする請求項1〜6記載のいずれかに記載の光学フィルム用粘着剤層。
- 前記水分散型粘着剤におけるベースポリマーが、前記モノマーとして少なくとも(メタ)アクリル酸エステルを用いた、(メタ)アクリル系ポリマーであることを特徴とする請求項1〜7のいずれかに記載の光学フィルム用粘着剤層。
- 光学フィルムの少なくとも片側に、請求項1〜8のいずれかに記載の光学フィルム用粘着剤層が積層されていることを特徴とする粘着型光学フィルム。
- 請求項9記載の粘着型光学フィルムを少なくとも1枚用いていることを特徴とする画像表示装置。
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CN201080046593.5A CN102575133B (zh) | 2009-10-23 | 2010-09-01 | 光学薄膜用粘合剂层、粘合型光学薄膜以及图像显示装置 |
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JP2013238640A (ja) * | 2012-05-11 | 2013-11-28 | Nitto Denko Corp | 偏光子の製造方法、偏光子、偏光板、光学フィルムおよび画像表示装置 |
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JP6185303B2 (ja) * | 2012-06-27 | 2017-08-23 | ジャパンコーティングレジン株式会社 | エマルジョン型粘着剤組成物、エマルジョン型粘着剤およびエマルジョン型剥離性粘着剤、ならびにそれを用いた粘着シート |
JP2014224963A (ja) * | 2012-09-13 | 2014-12-04 | 日東電工株式会社 | 光学部材、偏光板のセットおよび液晶表示装置 |
JP6344812B2 (ja) * | 2012-12-28 | 2018-06-20 | 日東電工株式会社 | 透明導電層用水分散型粘着剤組成物、透明導電層用粘着剤層、粘着剤層付き光学フィルム、及び、液晶表示装置 |
US10047288B2 (en) * | 2016-06-27 | 2018-08-14 | Unique Materials Co., Ltd. | Optical composite material composition and optical composite material comprising the same |
EP3831907A4 (en) * | 2018-07-31 | 2022-06-01 | Nitto Denko Corporation | OPTICAL PRESSURE SENSITIVE ADHESIVE COMPOSITION AND ITS USE |
CN112251172A (zh) * | 2020-09-30 | 2021-01-22 | 江苏斯迪克新材料科技股份有限公司 | 光学粘合剂层,其制备方法,光学胶以及柔性显示装置 |
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