JP2011042796A - 光輝スチールと一体となって改良された金属接着性と金属接着保持性とを示すゴム組成物及びゴム物品 - Google Patents
光輝スチールと一体となって改良された金属接着性と金属接着保持性とを示すゴム組成物及びゴム物品 Download PDFInfo
- Publication number
- JP2011042796A JP2011042796A JP2010215744A JP2010215744A JP2011042796A JP 2011042796 A JP2011042796 A JP 2011042796A JP 2010215744 A JP2010215744 A JP 2010215744A JP 2010215744 A JP2010215744 A JP 2010215744A JP 2011042796 A JP2011042796 A JP 2011042796A
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- parts
- weight
- rubber composition
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 102
- 239000005060 rubber Substances 0.000 title claims abstract description 99
- 239000000203 mixture Substances 0.000 title claims abstract description 70
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 43
- 239000010959 steel Substances 0.000 title claims abstract description 43
- 230000014759 maintenance of location Effects 0.000 title claims abstract description 10
- 239000002184 metal Substances 0.000 title claims description 30
- 229910052751 metal Inorganic materials 0.000 title claims description 30
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims abstract description 11
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical compound S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 claims abstract description 11
- -1 aminosilane compound Chemical class 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 238000004073 vulcanization Methods 0.000 claims description 12
- 239000004636 vulcanized rubber Substances 0.000 claims description 11
- 239000006229 carbon black Substances 0.000 description 14
- 235000019241 carbon black Nutrition 0.000 description 14
- 239000004594 Masterbatch (MB) Substances 0.000 description 12
- 230000002787 reinforcement Effects 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 229910000077 silane Inorganic materials 0.000 description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 150000001993 dienes Chemical class 0.000 description 8
- 229910052717 sulfur Inorganic materials 0.000 description 8
- 239000011593 sulfur Substances 0.000 description 8
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 229920001194 natural rubber Polymers 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 230000003014 reinforcing effect Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 229920003052 natural elastomer Polymers 0.000 description 5
- 229920002857 polybutadiene Polymers 0.000 description 5
- 230000001737 promoting effect Effects 0.000 description 5
- 150000004756 silanes Chemical class 0.000 description 5
- 244000043261 Hevea brasiliensis Species 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000002318 adhesion promoter Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 239000006231 channel black Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 230000003020 moisturizing effect Effects 0.000 description 3
- 150000005673 monoalkenes Chemical class 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229920003051 synthetic elastomer Polymers 0.000 description 3
- 239000005061 synthetic rubber Substances 0.000 description 3
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 2
- 239000006238 High Abrasion Furnace Substances 0.000 description 2
- 239000013032 Hydrocarbon resin Substances 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- 239000006242 Semi-Reinforcing Furnace Substances 0.000 description 2
- 239000006236 Super Abrasion Furnace Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229920006270 hydrocarbon resin Polymers 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- SDJHPPZKZZWAKF-UHFFFAOYSA-N DMBD Natural products CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 1
- 239000006237 Intermediate SAF Substances 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 241000254043 Melolonthinae Species 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- DLLMWYLJLBBEBF-UHFFFAOYSA-N [SiH3]N.CCO[Si](OCC)(OCC)CCCN Chemical compound [SiH3]N.CCO[Si](OCC)(OCC)CCCN DLLMWYLJLBBEBF-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- OOXSLJBUMMHDKW-UHFFFAOYSA-N trichloro(3-chloropropyl)silane Chemical compound ClCCC[Si](Cl)(Cl)Cl OOXSLJBUMMHDKW-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Ropes Or Cables (AREA)
- Tyre Moulding (AREA)
- Tires In General (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
【解決手段】加硫前にゴム組成物中のゴム成分100重量部当りアミノシランとメルカプトシランとそれらの混合物からなる群から選択される化合物約0.1〜10重量部をゴム組成物に組込む工程を含むことにより、加硫可能なゴム組成物と光輝スチールと間の金属接着性と金属接着保持特性を改良する。
【選択図】なし
Description
Claims (9)
- 光輝スチールと一体になって改良された金属接着性と金属接着保持性とを示す加硫可能なゴム組成物であって、
前記ゴム組成物中のゴム成分100重量部あたりアミノシラン類とメルカプトシラン類とそれらの混合物とからなる群から選択される化合物約0.1〜約10重量部を、加硫前に前記ゴム組成物に組み込むことに改良点があることを特徴とする前記ゴム組成物。 - 前記アミノシラン化合物が3−アミノアルキルトリエトキシシランであり、該化合物がゴム100重量部に対して約0.5〜2重量部の量で存在することを特徴とする請求項1に記載のゴム組成物。
- 前記メルカプトシラン化合物が3−アミノメルカプトトリエトキシシランであり、該化合物がゴム100重量部に対して約0.5〜2重量部の量で存在することを特徴とする請求項1に記載のゴム組成物。
- 光輝スチールと一体になって改良された金属接着性と金属接着保持性とを示す加硫ゴム組成物を含む空気入りタイヤ用の構造部品であって、
前記ゴム組成物中のゴム成分100重量部あたりアミノシラン類とメルカプトシラン類とそれらの混合物とからなる群から選択される化合物約0.1〜約10重量部を、加硫前に前記ゴム組成物に組み込むことに改良点があることを特徴とする前記空気入りタイヤ用の構造部品。 - 前記アミノシラン化合物が3−アミノアルキルトリエトキシシランであり、該化合物がゴム100重量部に対して約0.5〜2重量部の量で存在することを特徴とする請求項4に記載の空気入りタイヤ用の構造部品。
- 前記メルカプトシラン化合物が3−アミノメルカプトトリエトキシシランであり、該化合物がゴム100重量部に対して約0.5〜2重量部の量で存在することを特徴とする請求項4に記載の空気入りタイヤ用の構造部品。
- 加硫可能なゴム組成物と光輝スチールとの間の金属接着性と金属接着保持特性とを改良する方法であって、
加硫前に、前記ゴム組成物中のゴム成分100重量部あたりアミノシラン類とメルカプトシラン類とそれらの混合物とからなる群から選択される化合物約0.1〜約10重量部を前記ゴム組成物に組み込む工程を含む、前記改良方法。 - 前記アミノシラン化合物が3−アミノアルキルトリエトキシシランであり、該化合物がゴム100重量部に対して約0.5〜2重量部の量で存在することを特徴とする請求項7に記載の方法。
- 前記メルカプトシラン化合物が3−アミノメルカプトトリエトキシシランであり、該化合物がゴム100重量部に対して約0.5〜2重量部の量で存在することを特徴とする請求項7に記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/323,458 US7201944B2 (en) | 2002-12-18 | 2002-12-18 | Rubber compositions and articles thereof having improved metal adhesion and metal adhesion retention with bright steel |
US10/323,458 | 2002-12-18 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004563579A Division JP2006510790A (ja) | 2002-12-18 | 2003-12-16 | 光輝スチールと一体となって改良された金属接着性と金属接着保持性とを示すゴム組成物及びゴム物品 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2011042796A true JP2011042796A (ja) | 2011-03-03 |
JP5351865B2 JP5351865B2 (ja) | 2013-11-27 |
Family
ID=32593217
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004563579A Pending JP2006510790A (ja) | 2002-12-18 | 2003-12-16 | 光輝スチールと一体となって改良された金属接着性と金属接着保持性とを示すゴム組成物及びゴム物品 |
JP2010215744A Expired - Fee Related JP5351865B2 (ja) | 2002-12-18 | 2010-09-27 | 光輝スチールと一体となって改良された金属接着性と金属接着保持性とを示すゴム組成物及びゴム物品 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004563579A Pending JP2006510790A (ja) | 2002-12-18 | 2003-12-16 | 光輝スチールと一体となって改良された金属接着性と金属接着保持性とを示すゴム組成物及びゴム物品 |
Country Status (9)
Country | Link |
---|---|
US (3) | US7201944B2 (ja) |
EP (1) | EP1572798B1 (ja) |
JP (2) | JP2006510790A (ja) |
AU (1) | AU2003293564A1 (ja) |
BR (1) | BR0317438B1 (ja) |
CA (1) | CA2510568C (ja) |
DE (1) | DE60331348D1 (ja) |
ES (1) | ES2340269T3 (ja) |
WO (1) | WO2004058871A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015178309A1 (ja) * | 2014-05-23 | 2015-11-26 | ダイキン工業株式会社 | フッ素ゴム組成物及びフッ素ゴム成形品 |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5236138B2 (ja) * | 2000-07-28 | 2013-07-17 | 住友ゴム工業株式会社 | タイヤトレッド用ゴム組成物およびそれを用いた空気入りタイヤ |
US7201944B2 (en) * | 2002-12-18 | 2007-04-10 | Bridgestone Firestone North American Tire, Llc | Rubber compositions and articles thereof having improved metal adhesion and metal adhesion retention with bright steel |
CN101180344B (zh) * | 2005-03-24 | 2012-01-11 | 株式会社普利司通 | 具有低挥发性有机化合物(voc)释放的配混二氧化硅补强橡胶 |
US8304480B2 (en) | 2005-12-27 | 2012-11-06 | Sumitomo Rubber Industries, Ltd. | Rubber composition for coating steel cord and tire using the same |
JP5220307B2 (ja) * | 2005-12-27 | 2013-06-26 | 住友ゴム工業株式会社 | スチールコード被覆用ゴム組成物およびそれを用いたタイヤ |
US7915368B2 (en) | 2007-05-23 | 2011-03-29 | Bridgestone Corporation | Method for making alkoxy-modified silsesquioxanes |
US8501895B2 (en) * | 2007-05-23 | 2013-08-06 | Bridgestone Corporation | Method for making alkoxy-modified silsesquioxanes and amino alkoxy-modified silsesquioxanes |
US7938158B2 (en) * | 2007-08-02 | 2011-05-10 | Bridgestone Americas Tire Operations, Llc | Puncture resistant pneumatic tire |
US8962746B2 (en) | 2007-12-27 | 2015-02-24 | Bridgestone Corporation | Methods of making blocked-mercapto alkoxy-modified silsesquioxane compounds |
US8513371B2 (en) * | 2007-12-31 | 2013-08-20 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxanes and method of preparation |
US8794282B2 (en) * | 2007-12-31 | 2014-08-05 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber |
US8641731B2 (en) * | 2008-01-02 | 2014-02-04 | East Carolina University | Emergency snake bite treatment devices, medical kits and related methods |
GB2473002A (en) * | 2009-08-25 | 2011-03-02 | Nippon Sheet Glass Co Ltd | Reinforcement structure for rubber articles and methods of preparation |
US20110086942A1 (en) * | 2009-10-09 | 2011-04-14 | Schlumberger Technology Corporation | Reinforced elastomers |
US8642691B2 (en) | 2009-12-28 | 2014-02-04 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber |
US20110245371A1 (en) * | 2010-03-31 | 2011-10-06 | Claude Schweitzer | Pneumatic tire with rubber component containing alkylalkoxysilane and silicone resin |
US9371434B2 (en) | 2010-07-02 | 2016-06-21 | Bridgestone Corporation | Elastomeric compounds having increased cold flow resistance and methods producing the same |
US8490707B2 (en) | 2011-01-11 | 2013-07-23 | Schlumberger Technology Corporation | Oilfield apparatus and method comprising swellable elastomers |
WO2014139053A1 (en) * | 2013-03-15 | 2014-09-18 | Yahoo! Inc. | Method and system for intent centric multi-facet content presentation |
CN105778166A (zh) * | 2014-12-18 | 2016-07-20 | 北京橡胶工业研究设计院 | 一种轮胎用钢丝粘合橡胶组合物及其制备方法 |
WO2016109625A1 (en) | 2014-12-31 | 2016-07-07 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for adhering steel alloy to rubber |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11505879A (ja) * | 1995-05-22 | 1999-05-25 | キャボット コーポレイション | ケイ素処理カーボンブラックを含有するエラストマーのコンパウンド |
JP2006510790A (ja) * | 2002-12-18 | 2006-03-30 | ブリヂストン/ファイヤストーン ノース アメリカン タイヤ エルエルシー | 光輝スチールと一体となって改良された金属接着性と金属接着保持性とを示すゴム組成物及びゴム物品 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US706628A (en) * | 1902-04-05 | 1902-08-12 | John W Wright | Box-lid holder and label-displayer. |
US4052524A (en) | 1975-08-15 | 1977-10-04 | Monsanto Company | Method for improving adhesive bonding in steel/rubber composites and article |
US4441946A (en) | 1981-05-04 | 1984-04-10 | The General Tire & Rubber Company | Heat and humidity resistant steel cord reinforced rubber composite |
US4474908A (en) * | 1982-05-27 | 1984-10-02 | Ppg Industries, Inc. | Rubber compositions |
CA1240434A (en) * | 1983-09-14 | 1988-08-09 | Steven E. Schonfeld | Rubber compositions and articles thereof having improved metal adhesion and metal adhesion retention |
US5126501A (en) | 1991-01-23 | 1992-06-30 | General Tire, Inc. | Elastomeric compositions and tire belt structure |
US5830930A (en) * | 1995-05-22 | 1998-11-03 | Cabot Corporation | Elastomeric compounds incorporating silicon-treated carbon blacks |
FR2743564A1 (fr) * | 1996-01-11 | 1997-07-18 | Michelin & Cie | Compositions de caoutchouc pour enveloppes de pneumatiques a base de silices contenant un additif de renforcement a base d'un polyorganosiloxane fonctionnalise et d'un compose organosilane . |
US5882799A (en) | 1996-12-16 | 1999-03-16 | Vernay Laboratories, Inc. | Polymeric coupling agents for the adhesion of macromolecular materials and metal substrates |
KR20010032104A (ko) * | 1997-12-15 | 2001-04-16 | 엑손 케미칼 패턴츠 인코포레이티드 | 투명하고 착색가능한 탄성중합체성 조성물 |
US6624220B1 (en) | 1997-12-15 | 2003-09-23 | Exxonmobil Chemical Patents Inc. | Transparent and colorable elastomeric compositions |
EP0953593A1 (en) | 1998-04-27 | 1999-11-03 | Cabot Corporation | Wire adhesion rubber products and methods of reducing cobalt adhesion promotors in such products |
US6172138B1 (en) | 1998-11-12 | 2001-01-09 | The Goodyear Tire & Rubber Company | Reinforced elastomer preparation, elastomer composite and tire having component thereof |
EP1333107B1 (en) | 1998-12-30 | 2011-04-20 | University Of Cincinnati | Silane coatings for metals |
US6416869B1 (en) * | 1999-07-19 | 2002-07-09 | University Of Cincinnati | Silane coatings for bonding rubber to metals |
AU4556200A (en) | 1999-04-14 | 2000-11-02 | University Of Cincinnati, The | Silane coatings for adhesion promotion |
BR0111626A (pt) | 2000-06-13 | 2003-05-06 | Exxonmobil Chem Patents Inc | Processo para a preparação de composições elastoméricas com carga de sìlica |
MXPA03000658A (es) | 2000-07-31 | 2003-09-10 | Michelin Rech Tech | Material compuesto (metal/caucho) para neumatico. |
US20030069332A1 (en) * | 2001-09-14 | 2003-04-10 | Giorgio Agostini | Prepared elastomer/reinforcing filler composite and tire having component thereof |
-
2002
- 2002-12-18 US US10/323,458 patent/US7201944B2/en not_active Expired - Lifetime
-
2003
- 2003-12-16 BR BR0317438A patent/BR0317438B1/pt not_active IP Right Cessation
- 2003-12-16 CA CA 2510568 patent/CA2510568C/en not_active Expired - Fee Related
- 2003-12-16 WO PCT/US2003/039956 patent/WO2004058871A1/en active Application Filing
- 2003-12-16 ES ES03790513T patent/ES2340269T3/es not_active Expired - Lifetime
- 2003-12-16 JP JP2004563579A patent/JP2006510790A/ja active Pending
- 2003-12-16 AU AU2003293564A patent/AU2003293564A1/en not_active Abandoned
- 2003-12-16 EP EP20030790513 patent/EP1572798B1/en not_active Expired - Fee Related
- 2003-12-16 DE DE60331348T patent/DE60331348D1/de not_active Expired - Lifetime
-
2005
- 2005-01-05 US US11/029,854 patent/US20050119383A1/en not_active Abandoned
-
2006
- 2006-06-14 US US11/453,366 patent/US7393564B2/en not_active Expired - Lifetime
-
2010
- 2010-09-27 JP JP2010215744A patent/JP5351865B2/ja not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11505879A (ja) * | 1995-05-22 | 1999-05-25 | キャボット コーポレイション | ケイ素処理カーボンブラックを含有するエラストマーのコンパウンド |
JP2006510790A (ja) * | 2002-12-18 | 2006-03-30 | ブリヂストン/ファイヤストーン ノース アメリカン タイヤ エルエルシー | 光輝スチールと一体となって改良された金属接着性と金属接着保持性とを示すゴム組成物及びゴム物品 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015178309A1 (ja) * | 2014-05-23 | 2015-11-26 | ダイキン工業株式会社 | フッ素ゴム組成物及びフッ素ゴム成形品 |
JP2016000806A (ja) * | 2014-05-23 | 2016-01-07 | ダイキン工業株式会社 | フッ素ゴム組成物及びフッ素ゴム成形品 |
Also Published As
Publication number | Publication date |
---|---|
JP5351865B2 (ja) | 2013-11-27 |
CA2510568C (en) | 2012-03-06 |
EP1572798B1 (en) | 2010-02-17 |
JP2006510790A (ja) | 2006-03-30 |
US20040122180A1 (en) | 2004-06-24 |
US7393564B2 (en) | 2008-07-01 |
CA2510568A1 (en) | 2004-07-15 |
US7201944B2 (en) | 2007-04-10 |
DE60331348D1 (de) | 2010-04-01 |
US20050119383A1 (en) | 2005-06-02 |
ES2340269T3 (es) | 2010-06-01 |
EP1572798A1 (en) | 2005-09-14 |
US20070010606A1 (en) | 2007-01-11 |
BR0317438A (pt) | 2005-11-16 |
AU2003293564A1 (en) | 2004-07-22 |
WO2004058871A1 (en) | 2004-07-15 |
BR0317438B1 (pt) | 2013-10-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5351865B2 (ja) | 光輝スチールと一体となって改良された金属接着性と金属接着保持性とを示すゴム組成物及びゴム物品 | |
JP4109324B2 (ja) | 空気入りタイヤのための高弾性率低ヒステリシスゴムコンパウンド | |
JP5265114B2 (ja) | ゴム組成物及びそれを用いた空気入りタイヤ | |
JP2008169296A (ja) | ゴム組成物及びそれを用いた空気入りタイヤ | |
JP2008038059A (ja) | ゴム組成物、その複合体、およびそれを用いた空気入りタイヤ | |
JP5265115B2 (ja) | ゴム組成物及びそれを用いた空気入りタイヤ | |
WO2019111546A1 (ja) | ゴム組成物及び空気入りタイヤ | |
CA1180479A (en) | Cured rubber skim stocks having improved metal adhesion and metal adhesion retention by use of organo-metal complexes and halogenated polymer | |
CN111171401A (zh) | 包含双重二氧化硅部分的鞋类和橡胶鞋底 | |
NO158188B (no) | Fremgangsmaate for aa forbedre adhesjonen av en vulkanisert hydrokarbon-gummi-blanding til staaltraad-deler. | |
JP6248004B2 (ja) | 更生タイヤ用クッションゴム及び更生タイヤ | |
JPH06306205A (ja) | ゴム組成物 | |
JP4230859B2 (ja) | スチールコーティング用ゴム組成物 | |
JP5265118B2 (ja) | ゴム組成物及びそれを用いた空気入りタイヤ | |
EP3240816B1 (en) | Halogenated wax grafted to low molecular weight polymer and rubber composition | |
JP6701672B2 (ja) | タイヤ用ゴム組成物 | |
EP3966044A1 (en) | Electrically conductive tread chimney compound | |
EP0133936B1 (en) | Rubber compositions and articles thereof having improved metal adhesion retention | |
JP6701671B2 (ja) | タイヤ用ゴム組成物 | |
JPS63258940A (ja) | タイヤのベルト層補強用スチールコードの被覆ゴム組成物 | |
JP4405238B2 (ja) | 空気入りタイヤ | |
JP2021004293A (ja) | タイヤ用ゴム組成物 | |
JP2005220259A (ja) | ゴム組成物 | |
JPH04277536A (ja) | スチールコード被覆用ゴム組成物 | |
JP2009203324A (ja) | タイヤテキスタイルコード被覆用ゴム組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20120824 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120828 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20121116 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130813 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130823 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |