JP2010501649A - 改善された接着性を有する組成物から形成される多層複合材 - Google Patents
改善された接着性を有する組成物から形成される多層複合材 Download PDFInfo
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- JP2010501649A JP2010501649A JP2009524725A JP2009524725A JP2010501649A JP 2010501649 A JP2010501649 A JP 2010501649A JP 2009524725 A JP2009524725 A JP 2009524725A JP 2009524725 A JP2009524725 A JP 2009524725A JP 2010501649 A JP2010501649 A JP 2010501649A
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- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- DCUFMVPCXCSVNP-UHFFFAOYSA-N methacrylic anhydride Chemical compound CC(=C)C(=O)OC(=O)C(C)=C DCUFMVPCXCSVNP-UHFFFAOYSA-N 0.000 description 1
- VPKDCDLSJZCGKE-UHFFFAOYSA-N methanediimine Chemical compound N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- JQKFLNWRTBPECK-UHFFFAOYSA-N methoxymethane;propane-1,2-diol Chemical compound COC.CC(O)CO JQKFLNWRTBPECK-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- VYKXQOYUCMREIS-UHFFFAOYSA-N methylhexahydrophthalic anhydride Chemical compound C1CCCC2C(=O)OC(=O)C21C VYKXQOYUCMREIS-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
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- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
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- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
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- MOWNZPNSYMGTMD-UHFFFAOYSA-N oxidoboron Chemical class O=[B] MOWNZPNSYMGTMD-UHFFFAOYSA-N 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 125000000466 oxiranyl group Chemical group 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- JVUYWILPYBCNNG-UHFFFAOYSA-N potassium;oxido(oxo)borane Chemical compound [K+].[O-]B=O JVUYWILPYBCNNG-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 210000003660 reticulum Anatomy 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- VLCLHFYFMCKBRP-UHFFFAOYSA-N tricalcium;diborate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-] VLCLHFYFMCKBRP-UHFFFAOYSA-N 0.000 description 1
- AJSTXXYNEIHPMD-UHFFFAOYSA-N triethyl borate Chemical compound CCOB(OCC)OCC AJSTXXYNEIHPMD-UHFFFAOYSA-N 0.000 description 1
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical class [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
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- C—CHEMISTRY; METALLURGY
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Abstract
Description
本発明は、2つ以上のポリマー層からなり、そのポリマー層の少なくとも1つが熱硬化性組成物から形成される多層複合材に関する。複合材は、基材上に形成される第1ポリマー層および第1ポリマー層の少なくとも一部を覆って形成される第2ポリマー層を少なくとも含む。本発明は、また、多層複合材の形成に用いられ、多層複合材の層間接着性を改善する熱硬化性塗料組成物に関する。
彩色または着色したベースコートを基材に塗布した後、透明なコートまたはクリアコートを、ベースコートを覆って塗布することを含むカラープラスクリア塗料系は、例えば、自動車を含む多くの消費者製品の独特な仕上げ塗料としてますます人気が高まっている。カラープラスクリア塗料系は、主にクリアコートに起因する画像の光沢度および鮮明度等の顕著な外観特性を有する。このようなカラープラスクリア塗料系は、自動車、航空宇宙用途、セラミックタイルおよび木質フローリング等の床仕上げ材、パッケージ塗料等との使用に人気が高まっている。
本発明は、2つ以上のポリマー層からなり、そのポリマー層の少なくとも1つが熱硬化性組成物から形成される多層複合材に関する。その複合材は基材上に形成される第1ポリマー層、および第1ポリマー層の少なくとも一部を覆う第2ポリマー層を少なくとも含み、ホウ素含有化合物が存在しない場合、第1ポリマー層および第2ポリマー層は、弱い層間接着性を有する。改善は、第1ポリマー層および第2ポリマー層の片方または両方に第1ポリマー層および第2ポリマー層の層間接着性を改善するのに十分な量の接着促進剤を含有することを含む。接着促進剤は、
(i)ホウ酸またはその等価物
(ii)少なくとも一部分は、1,3−ポリオールから得られる2つ以上の末端水酸基を有するエステルから得られ、
ホウ酸またはその等価物の水酸基に対する当量比は、0.1:1より大きく、1,3−ポリオールの酸に対する当量比は、2:1より大きい。
操作例以外において、または特に記載がない限り、明細書および特許請求の範囲で用いられる原料、反応条件等の量を表すすべての数は、「約」という用語によってすべての場合、修飾されるものと理解されるべきである。したがって、逆に記載がない限り、以下の明細書および添付の特許請求の範囲に記載する数値パラメーターは、本発明によって得ることが求められる所望の特性によって変化してもよい近似値である。非常に最小に見ても、等価物の教義の適用を特許請求の範囲に限定する試みとしてではなく、各数値パラメーターは、記録した有効数字の数を考慮して、通常の丸め技術を適用することによって少なくとも構成されるべきである。
以下の実施例は、末端水酸基を有する各種水酸基官能性ポリエステルの調製法を示す。まず、ポリエステルをホウ酸と反応させて接着促進剤を形成する。
下記に記載の以下の原料からポリエステルを調製した。
下記に記載の以下の原料からホウ酸処理したポリエステル(B/OH当量比0.05:1)を調製した。
下記に記載の以下の原料からホウ酸処理したポリエステル(B/OH当量比0.1:1)を調製した。
下記に記載の以下の原料からホウ酸処理したポリエステル(B/OH当量比0.3:1)を調製した。
下記に記載の以下の原料からホウ酸処理したポリエステル(B/OH当量比0.6:1)を調製した。
下記に記載の以下の原料からホウ酸処理したポリエステル(B/OH当量比1:1)を調製した。
下記に記載の以下の原料からポリエステルを調製した。
下記に記載の以下の原料からポリエステルを調製した。
下記に記載の以下の原料からポリエステルを調製した。
下記に記載の以下の原料からポリエステルを調製した。
下記に記載の以下の原料からモノエステル含有材料を調製した。
下記に記載の以下の原料からポリエステルを調製した。
下記に記載の以下の原料からホウ酸処理したポリエステルを調製した。
下記に記載の以下の原料からポリエステルを調製した。
下記に記載の以下の原料からポリエステルを調製した。
実施例1〜4は、配合されたクリア塗料組成物からなる。実施例2、3および4は、さまざまな量の本発明の接着促進剤を含有していた。実施例1は、接着促進剤を含まない対照実験だった。初めに予備混合物を形成した後、以下の表1に示す接着促進剤を加えることによって塗料組成物を配合した。
2Union Carbide Corp.から入手可能なジエチレングリコルモノブチルエーテル
3酢酸2−(2−ブトキシエトキシ)エチルは、Union Carbide Corp.から市販されている。
4Ciba Specialty Chemicals Corp.から入手可能なUV吸収剤
5Ciba Additivesから市販されているヒンダードアミン光安定剤
6Chemcentralから市販されているドデシルベンゼンスルホン酸溶液
7Cytec Industriesから市販されているメラミンホルムアルデヒド樹脂
8BASF AGから入手可能なトリス(アルキルカルバモイル)トリアジン
9PPGからのSCAアクリル樹脂溶液
10PPGからのアクリル樹脂溶液
11Nuplex Resinsから市販されているメラミンホルムアルデヒド樹脂
12Byk Chemieからのポリアクリル共重合体溶液
13Byk Chemieからのポリエーテル修飾ポリジメチルシロキサン溶液
14周囲温度で#4FORD流出カップを用いて秒で測定した粘度
15所望のスプレー粘度に達するように加えられた十分な溶媒
2Dow Chemical Co.から入手可能な酢酸プロピレングリコールメチルエーテル
3Ciba Additivesから入手可能なベンゾトリアゾール誘導体
4Ciba Additivesから入手可能な2−(2’−ヒドロキシ−3’,5’−ジ−tert−アミルフェニル)ベンゾトリアゾールUV光安定剤
5エチレングリコールジメタクリレート、スチレン、ブチルアクリレートおよびメチルメタクリレートを含む架橋ポリマー分散液。分散液は、酢酸オキソ−ヘキシル(Exxon Chemicalsから入手可能)中、31重量%存在する。数平均粒径は1000オングストロームである。
6AEROSIL R812 Sシリカ(Degussaから入手可能)と、ヒドロキシプロピルアクリレート、スチレン、ブチルメタクリレート、ブチルメタクリレートアクリル酸を含む、固形分で325の水酸基EWを有する7000のMwのポリマー成分を含有する分散液。ポリマーは、重量比60/40のプロピレングリコールモノアセテート/SOLVESSO 100(Exxonから入手可能)のメチルエーテル中、固形分67.5重量%である。
7Solutia Inc.から市販されているメラミンホルムアルデヒド樹脂
8カルバメート官能性ポリエステル樹脂溶液(米国特許第6,592,999号に記載の組成物)
9Ciba Additivesから市販されているヒンダードアミン光安定剤
10Chemcentralから入手可能なドデシルベンゼンスルホン酸溶液
11DuPontから入手可能な、固形分62.5%のキシレン中で製造される約6700のMwと約2600のMnを有する流れ調整剤
12King Industriesから入手可能な添加剤
13周囲温度で#4 FORD流出カップを用いて秒で測定した粘度。
実施例19〜24は、エステル−ボレート接着促進剤中のボレート含有量の増加の効果を示す。すべての実施例に対して、以下の表5に記載の予備混合物Bに接着促進剤を加えて塗料組成物を配合した。各場合、約160重量部(固形分88.4)の予備混合物に接着促進剤を加えた。
2画像の鮮明度(DOI)測定値をHunter Associates Dorigon IITM DOI計を用いて測定した。
3重ね塗り接着試験説明(クロスハッチ接着性)−表3脚注2の下に位置する米国特許第6,592,999号の試験説明を参照すること。
4クイックナイフ試験は、以下のように行われた。フロントガラス接着性を試験するために、フロントガラス接着剤のビーズを最終焼成(285°Fで30分)後1〜4時間以内にクリアコート表面に塗布する。Dow AutomotiveのBetasealウレタン水分硬化フロントガラス接着剤15625を用いた。約5mm×5mm×250mmの接着剤ビーズを硬化カラープラスクリア基材上に置く。接着剤を室温(〜75°F)、20〜50%の相対湿度で72時間硬化する。72時間後、硬化接着ビーズをカミソリの刃で切断する。接着剤の縁部を180°の角度で引き戻しながら12mmおきに60°の角度で接着ビーズを介して切断する。各系に対して最低10回切断した。所望の結果は、90〜100%の凝集破壊(CF)として記載する。切断して引っ張った結果として、接着ビーズの結着性が失われると、凝集破壊(CF)が起こる。接着損失が接着ビーズとクリアコート表面の間で起こると、凝集破壊率は、0%になる。
Claims (31)
- (a)反応性官能基を有する薄膜形成ポリマー、
(b)(a)の官能基と反応する官能基を有する硬化剤、
(c)(i)ホウ酸またはその等価物、および
(ii)少なくとも一部分は、1,3−ポリオールから得られる2つ以上の末端水酸基を有するエステルから得られる接着促進剤
を含む熱硬化性組成物であって、
ホウ酸またはその等価物の水酸基に対する当量比が、0.1:1より大きく、1,3−ポリオールの酸に対する当量比が、2:1より大きい、熱硬化性組成物。 - 薄膜形成ポリマーの官能基が、水酸基、第1級アミノ、第2級アミノ、カルボン酸、エポキシ、カルバメート、アミド、尿素、およびそれらの相溶性混合物から選択される、請求項1に記載の組成物。
- 官能基が、水酸基、カルバメートおよびそれらの相溶性混合物から選択される、請求項2に記載の組成物。
- 硬化剤の官能基が、ブロックイソシアネートを含むイソシアネート、メチロ−ルエーテルを含むメチロール、エポキシ、カルボン酸、無水物およびそれらの相溶性混合物から選択される、請求項2に記載の組成物。
- 硬化剤が、ブロックイソシアネートを含むイソシアネートおよびアミノプラストから選択される、請求項3に記載の組成物。
- (a)が、ホウ酸、ホウ酸エステル、金属ホウ酸塩およびそれらの混合物から選択される、請求項1に記載の組成物。
- (i)が、エステル基中に1〜6個の炭素原子を有するホウ酸エステルである、請求項6に記載の組成物。
- ホウ酸エステルが、ホウ酸トリメチル、ホウ酸トリイソプロピルおよびホウ酸トリフェニルから選択される、請求項7に記載の組成物。
- (c)が、硬化性組成物中に存在する樹脂固形分の全重量を基準として、0.001〜5重量%のホウ素含有量を与えるのに十分な量で組成物中に存在する、請求項1に記載の組成物。
- (i)および(ii)が、反応生成物として硬化性組成物中に存在する、請求項1に記載の組成物。
- エステルが、ポリエステルである、請求項1に記載の組成物。
- ポリエステルが、ポリカルボン酸またはその等価物を1,3−ポリオールと反応させることから形成される、請求項11に記載の組成物。
- 1,3−ポリオールが、トリメチロールプロパンおよびペンタエリスリトールから選択される、請求項1に記載の組成物。
- 2つ以上のポリマー層からなり、そのポリマー層の少なくとも1つが熱硬化性組成物から形成される多層複合材において、複合材が、基材上に形成される第1ポリマー層、および第1ポリマー層の少なくとも一部を覆って形成される第2ポリマー層を含み、改善が、ポリマー層の片方または両方に第1および第2ポリマー層の間の層間接着性を改善するのに十分な量の接着促進剤を含有することを含み、接着促進剤が、
(i)ホウ酸またはその等価物
(ii)少なくとも一部分は、1,3−ポリオールから得られる2つ以上の末端水酸基を有するエステル
から得られ、ホウ酸またはその等価物の水酸基に対する当量比が、0.1:1より大きく、1,3−ポリオールの酸に対する当量比が、2:1より大きい、複合材。 - 第1ポリマー層と第2ポリマー層の片方または両方が、
(a)反応性官能基を有する薄膜形成ポリマー、
(b)(a)の官能基と反応する官能基を有する硬化剤、
を含む熱硬化性組成物から形成される硬化層を含む、請求項14に記載の複合材。 - 薄膜形成ポリマー(a)が、アクリルポリマー、ポリエステルポリマー、ポリウレタンポリマーおよびそれらの混合物から選択される少なくとも1つのポリマーを含む、請求項15に記載の複合材。
- 薄膜形成ポリマー(a)が、水酸基、カルボン酸、第1級アミン、第2級アミン、アミド、カルバメート、尿素、エポキシおよびそれらの相溶性混合物から選択される官能基を含む、請求項15に記載の複合材。
- 薄膜形成ポリマーが、水酸基、カルバメート基およびそれらの混合物から選択される官能基を含む、請求項17に記載の複合材。
- 硬化剤(b)が、アミノプラスト樹脂、ポリイソシアネート、ブロックイソシアネート、ポリカルボン酸、ポリエポキシドおよびそれらの相溶性混合物を含む、請求項15に記載の複合材。
- 硬化剤(b)が、少なくとも1つのアミノプラスト樹脂、およびトリカルバモイルトリアジン化合物を含む少なくとも1つのブロックイソシアネート化合物を含む、請求項19に記載の複合材。
- (i)が、ホウ酸、ホウ酸エステル、金属ホウ酸塩およびそれらの混合物から選択される、請求項14に記載の複合材。
- (i)が、エステル基中に1〜6個の炭素原子を有するホウ酸エステルである、請求項14に記載の複合材。
- (i)および(ii)が、反応生成物として存在する、請求項14に記載の複合材。
- (i)および(ii)が、複合材中の樹脂固形分の重量を基準として、0.001〜5重量%のホウ素含有量を提供するのに十分な量で存在する、請求項14に記載の複合材。
- 金属基材またはエラストマー基材上に堆積した顔料含有ポリマー層を含む複合材であって、実質的に顔料非含有のクリアポリマー層が顔料含有ポリマー層上に堆積し、接着剤層がクリアポリマー層上に堆積し、クリアポリマー層が第1ポリマー層であって、接着剤層が第2ポリマー層である、請求項14に記載の複合材。
- 接着促進剤が、クリアポリマー層中に存在する、請求項25に記載の複合材。
- 顔料含有ポリマー層上に堆積した実質的に顔料非含有の第1クリアポリマー層と、第1クリアポリマー層上に堆積した実質的に顔料非含有の第2クリアポリマー層を含む、請求項14に記載の複合材。
- 接着促進剤が、第1クリアポリマー層中に存在する、請求項27に記載の複合材。
- エステルが、ポリエステルである、請求項14に記載の複合材。
- ポリエステルが、ポリカルボン酸またはその等価物を1,3−ポリオールと反応させることから形成される、請求項29に記載の複合材。
- 1,3−ポリオールが、トリメチロールプロパンおよびペンタエリスリトールから選択される、請求項14に記載の複合材。
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US11/465,624 US8029894B2 (en) | 2006-08-18 | 2006-08-18 | Multi-layer composites formed from compositions having improved adhesion |
PCT/US2007/074803 WO2008021712A2 (en) | 2006-08-18 | 2007-07-31 | Multi-layer composites formed from compositions having improved adhesion |
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DE102009018249A1 (de) | 2009-04-21 | 2010-11-11 | Basf Coatings Ag | Mehrschicht-Beschichtung, deren Herstellung und Verwendung zur Verklebung von Glasscheiben |
DE102009018217A1 (de) | 2009-04-21 | 2010-11-11 | Basf Coatings Ag | Wasserfreie High-Solid-Basislacke, ihre Herstellung und ihre Verwendung zur Herstellung von Mehrschichtlackierungen, sowie Mehrschichtlackierungen enthaltend eine Basislackierung aus einem wasserfreien High-Solid-Basislack |
US20120301647A1 (en) * | 2011-05-23 | 2012-11-29 | Ppg Industries Ohio, Inc. | Phosphatized polyesters and coating compositions containing the same |
RU2495160C1 (ru) * | 2012-05-30 | 2013-10-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Российский химико-технологический университет им. Д.И. Менделеева" (РХТУ им. Д.И. Менделеева) | Водоразбавляемая полимерная композиция для покрытий |
US8846156B2 (en) * | 2013-02-28 | 2014-09-30 | Ppg Industries Ohio, Inc. | Methods and compositions for coating substrates |
RU2527524C1 (ru) * | 2013-04-25 | 2014-09-10 | Вячеслав Ефимович Цветков | Способ изготовления нетоксичных древесно-стружечных плит |
EP3010984B1 (de) | 2013-06-21 | 2017-03-29 | BASF Coatings GmbH | Pigmentiertes beschichtungsmittel sowie verfahren zur herstellung einer mehrschichtbeschichtung unter einsatz des pigmentierten beschichtungsmittels zum erhalt einer scheibenverklebungshaftung |
CN108264784A (zh) * | 2017-12-25 | 2018-07-10 | 衢州南高峰化工股份有限公司 | 一种用于制冷***的有机硅改性环氧防腐涂料及防腐涂层 |
CN115851065B (zh) * | 2022-11-25 | 2023-08-15 | 湖北双键精细化工有限公司 | 一种与uv罩光面漆相配套的单组份底漆用改性丙烯酸乳液及其制备方法 |
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WO2003011986A1 (en) * | 2001-07-31 | 2003-02-13 | Ppg Industries Ohio, Inc. | Multi-layer composites formed from compositions having improved adhesion, coating compositions, and methods related thereto |
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US8029894B2 (en) | 2011-10-04 |
WO2008021712A3 (en) | 2008-05-29 |
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