JP2009540137A - カチオン性アミロペクチンデンプンを用いて紙を作製するための方法 - Google Patents
カチオン性アミロペクチンデンプンを用いて紙を作製するための方法 Download PDFInfo
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- JP2009540137A JP2009540137A JP2009514224A JP2009514224A JP2009540137A JP 2009540137 A JP2009540137 A JP 2009540137A JP 2009514224 A JP2009514224 A JP 2009514224A JP 2009514224 A JP2009514224 A JP 2009514224A JP 2009540137 A JP2009540137 A JP 2009540137A
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- Prior art keywords
- starch
- paper
- amylopectin
- cationic
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920002472 Starch Polymers 0.000 title claims abstract description 94
- 235000019698 starch Nutrition 0.000 title claims abstract description 93
- 239000008107 starch Substances 0.000 title claims abstract description 83
- 229920000945 Amylopectin Polymers 0.000 title claims abstract description 44
- 125000002091 cationic group Chemical group 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000011121 hardwood Substances 0.000 claims description 19
- 244000061456 Solanum tuberosum Species 0.000 claims description 18
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 16
- 229920003043 Cellulose fiber Polymers 0.000 claims description 7
- 229920002261 Corn starch Polymers 0.000 claims description 6
- 240000003183 Manihot esculenta Species 0.000 claims description 6
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 4
- 240000007472 Leucaena leucocephala Species 0.000 claims description 3
- 235000010643 Leucaena leucocephala Nutrition 0.000 claims description 3
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- 239000004857 Balsam Substances 0.000 claims description 2
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- 244000004281 Eucalyptus maculata Species 0.000 claims 1
- 239000007900 aqueous suspension Substances 0.000 claims 1
- 229920001131 Pulp (paper) Polymers 0.000 abstract description 3
- 229920001592 potato starch Polymers 0.000 description 20
- 235000013339 cereals Nutrition 0.000 description 15
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- 239000000976 ink Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 12
- 239000008187 granular material Substances 0.000 description 10
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- 108010039811 Starch synthase Proteins 0.000 description 8
- 239000000835 fiber Substances 0.000 description 8
- 238000004513 sizing Methods 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 108090000623 proteins and genes Proteins 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 238000007639 printing Methods 0.000 description 6
- 238000004381 surface treatment Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000000945 filler Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000008120 corn starch Substances 0.000 description 4
- 230000005764 inhibitory process Effects 0.000 description 4
- 238000006467 substitution reaction Methods 0.000 description 4
- 102100031260 Acyl-coenzyme A thioesterase THEM4 Human genes 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
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- 235000011684 Sorghum saccharatum Nutrition 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
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- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
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- 230000006872 improvement Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000208140 Acer Species 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 235000018185 Betula X alpestris Nutrition 0.000 description 1
- 235000018212 Betula X uliginosa Nutrition 0.000 description 1
- 241000219495 Betulaceae Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 240000004270 Colocasia esculenta var. antiquorum Species 0.000 description 1
- 235000002723 Dioscorea alata Nutrition 0.000 description 1
- 235000007056 Dioscorea composita Nutrition 0.000 description 1
- 235000009723 Dioscorea convolvulacea Nutrition 0.000 description 1
- 235000005362 Dioscorea floribunda Nutrition 0.000 description 1
- 235000004868 Dioscorea macrostachya Nutrition 0.000 description 1
- 235000005361 Dioscorea nummularia Nutrition 0.000 description 1
- 235000005360 Dioscorea spiculiflora Nutrition 0.000 description 1
- 240000008395 Elaeocarpus angustifolius Species 0.000 description 1
- 102000005548 Hexokinase Human genes 0.000 description 1
- 108700040460 Hexokinases Proteins 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 235000006350 Ipomoea batatas var. batatas Nutrition 0.000 description 1
- 241000218652 Larix Species 0.000 description 1
- 235000005590 Larix decidua Nutrition 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000219000 Populus Species 0.000 description 1
- 244000062793 Sorghum vulgare Species 0.000 description 1
- 235000009430 Thespesia populnea Nutrition 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229920006320 anionic starch Polymers 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 235000004879 dioscorea Nutrition 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- RGCLLPNLLBQHPF-HJWRWDBZSA-N phosphamidon Chemical compound CCN(CC)C(=O)C(\Cl)=C(/C)OP(=O)(OC)OC RGCLLPNLLBQHPF-HJWRWDBZSA-N 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
- D21H17/29—Starch cationic
Landscapes
- Paper (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
Description
本実施例においては、4級アンモニウム置換基(置換度0.035)を含む以下の2種類のカチオン性デンプン産物を、紙の製造のためのウェットエンド添加物として使用した。
A.カチオン性ジャガイモデンプン(乾燥物質の重量で約20%のアミロースを含む、Amylofax PW)
B.カチオン性アミロペクチンジャガイモデンプン(本発明にしたがって、乾燥物質の重量で約2%のアミラーゼを含む、PR0602A)
本実施例においては、4級アンモニウム置換基(置換度0.035)を含む、実施例1において説明されたものと同じ2種類のカチオン性デンプン産物を使用した。
両方のパルプ品質(すなわち、実施例1および2両方)について、通常のカチオン性ジャガイモデンプンと比較してカチオン性アミロペクチンジャガイモデンプンを使用した際に、ベッセルピッキングの傾向において著しい改善が観察される。
本実施例においては、4級アンモニウム成分(置換度0.035)を含む、実施例1において説明されたものと同じ2種類のカチオン性デンプン産物を使用した。パルプは、38%の長繊維、28%の短繊維(ユーカリ)、および34%のCTMPの混合物から構成されていた。紙シートにおいて10%の最終的な灰含量を得るために、炭酸カルシウムを充填剤として添加した。添加したカチオン性デンプンの量は重量で1.0%(乾燥物質)であった。
Claims (9)
- カチオン性アミロペクチンデンプンがセルロース繊維の水性懸濁液に添加される、紙を作製するための方法であって、この懸濁液から従来の様式で紙を形成し、セルロース繊維の懸濁液が乾燥物質に基づいて少なくとも5重量%の広葉樹セルロース繊維を含む、方法。
- カチオン性アミロペクチンデンプンが、乾燥物質に基づいて少なくとも95重量%、好ましくは少なくとも98重量%のアミロペクチンを含む、請求項1記載の方法。
- カチオン性アミロペクチンデンプンが、モチトウモロコシ(waxy maize)デンプン、または根もしくは塊茎のアミロペクチンデンプンである、前記請求項のいずれか一項記載の方法。
- デンプンがジャガイモまたはタピオカデンプンである、請求項3記載の方法。
- セルロース繊維の懸濁液が、乾燥物質に基づいて少なくとも10重量%の広葉樹セルロース繊維を含む、前記請求項のいずれか一項記載の方法。
- 広葉樹セルロース繊維が、オーク、ニレ、ユーカリ、アスペン、ヒロハハコヤナギ(balsam cottonwood)、またはアカシアから取得される、前記請求項のいずれか一項記載の方法。
- 紙が枚葉紙である、前記請求項のいずれか一項記載の方法。
- 前記請求項のいずれか一項記載の方法によって取得可能な紙。
- ベッセルピッキング(vessel picking)を減少させるための、少なくとも5重量%の広葉樹パルプを含むパルプからの製紙のウェットエンドにおけるカチオン性アミロペクチンデンプンの使用。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06076199A EP1865105B1 (en) | 2006-06-09 | 2006-06-09 | Process for making paper using cationic amylopectin starch |
PCT/NL2007/050272 WO2007142528A1 (en) | 2006-06-09 | 2007-06-08 | Process for making paper using cationic amylopectin starch |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2009540137A true JP2009540137A (ja) | 2009-11-19 |
Family
ID=37891531
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009514224A Pending JP2009540137A (ja) | 2006-06-09 | 2007-06-08 | カチオン性アミロペクチンデンプンを用いて紙を作製するための方法 |
Country Status (17)
Country | Link |
---|---|
US (1) | US20100230063A1 (ja) |
EP (1) | EP1865105B1 (ja) |
JP (1) | JP2009540137A (ja) |
CN (1) | CN101466894B (ja) |
AT (1) | ATE443179T1 (ja) |
AU (1) | AU2007256038B2 (ja) |
BR (1) | BRPI0712653A2 (ja) |
CA (1) | CA2654156C (ja) |
DE (1) | DE602006009237D1 (ja) |
DK (1) | DK1865105T3 (ja) |
EA (1) | EA016520B1 (ja) |
ES (1) | ES2333741T3 (ja) |
MX (1) | MX2008015152A (ja) |
PL (1) | PL1865105T3 (ja) |
PT (1) | PT1865105E (ja) |
SI (1) | SI1865105T1 (ja) |
WO (1) | WO2007142528A1 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009243013A (ja) * | 2008-03-31 | 2009-10-22 | Nippon Paper Industries Co Ltd | 澱粉を塗布した印刷用紙 |
EP2199462A1 (en) * | 2008-12-18 | 2010-06-23 | Coöperatie Avebe U.A. | A process for making paper |
CN103343478B (zh) * | 2013-07-03 | 2016-03-30 | 金华盛纸业(苏州工业园区)有限公司 | 一种湿部淀粉及其应用 |
PT3221512T (pt) * | 2014-11-19 | 2020-01-07 | Omya Int Ag | Método de produção de uma carga |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0241496A (ja) * | 1988-06-22 | 1990-02-09 | W R Grace & Co | サイジング組成物、それの製造方法および使用方法 |
EP0703314B1 (en) * | 1994-09-13 | 1999-05-19 | Coöperatieve Verkoop- en Productievereniging van Aardappelmeel en Derivaten 'AVEBE' B.A. | Method for manufacturing paper, and paper manufactured thereby |
JP2001518988A (ja) * | 1997-04-04 | 2001-10-16 | ビーエーエスエフ アクチェンゲゼルシャフト | 高い乾燥強度を有する紙、厚紙及びボール紙の製造法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2935436A (en) * | 1957-05-09 | 1960-05-03 | Nat Starch Chem Corp | Method of making paper containing a starch ether and product produced thereby |
US5635028A (en) | 1995-04-19 | 1997-06-03 | The Procter & Gamble Company | Process for making soft creped tissue paper and product therefrom |
DE19540998A1 (de) | 1995-11-03 | 1997-05-07 | Basf Ag | Wäßrige Alkyldiketen-Dispersionen und ihre Verwendung als Leimungsmittel für Papier |
-
2006
- 2006-06-09 EP EP06076199A patent/EP1865105B1/en active Active
- 2006-06-09 DK DK06076199.6T patent/DK1865105T3/da active
- 2006-06-09 AT AT06076199T patent/ATE443179T1/de active
- 2006-06-09 PL PL06076199T patent/PL1865105T3/pl unknown
- 2006-06-09 SI SI200630499T patent/SI1865105T1/sl unknown
- 2006-06-09 ES ES06076199T patent/ES2333741T3/es active Active
- 2006-06-09 PT PT06076199T patent/PT1865105E/pt unknown
- 2006-06-09 DE DE602006009237T patent/DE602006009237D1/de active Active
-
2007
- 2007-06-08 AU AU2007256038A patent/AU2007256038B2/en not_active Ceased
- 2007-06-08 EA EA200900677A patent/EA016520B1/ru not_active IP Right Cessation
- 2007-06-08 JP JP2009514224A patent/JP2009540137A/ja active Pending
- 2007-06-08 WO PCT/NL2007/050272 patent/WO2007142528A1/en active Application Filing
- 2007-06-08 MX MX2008015152A patent/MX2008015152A/es active IP Right Grant
- 2007-06-08 BR BRPI0712653-0A patent/BRPI0712653A2/pt not_active IP Right Cessation
- 2007-06-08 CN CN2007800214422A patent/CN101466894B/zh not_active Expired - Fee Related
- 2007-06-08 CA CA2654156A patent/CA2654156C/en not_active Expired - Fee Related
- 2007-06-08 US US12/303,574 patent/US20100230063A1/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0241496A (ja) * | 1988-06-22 | 1990-02-09 | W R Grace & Co | サイジング組成物、それの製造方法および使用方法 |
EP0703314B1 (en) * | 1994-09-13 | 1999-05-19 | Coöperatieve Verkoop- en Productievereniging van Aardappelmeel en Derivaten 'AVEBE' B.A. | Method for manufacturing paper, and paper manufactured thereby |
JP2001518988A (ja) * | 1997-04-04 | 2001-10-16 | ビーエーエスエフ アクチェンゲゼルシャフト | 高い乾燥強度を有する紙、厚紙及びボール紙の製造法 |
Also Published As
Publication number | Publication date |
---|---|
EP1865105A1 (en) | 2007-12-12 |
ATE443179T1 (de) | 2009-10-15 |
SI1865105T1 (sl) | 2010-01-29 |
DE602006009237D1 (de) | 2009-10-29 |
EP1865105B1 (en) | 2009-09-16 |
PL1865105T3 (pl) | 2010-02-26 |
EA200900677A1 (ru) | 2009-10-30 |
ES2333741T3 (es) | 2010-02-26 |
BRPI0712653A2 (pt) | 2012-11-20 |
AU2007256038B2 (en) | 2010-06-24 |
US20100230063A1 (en) | 2010-09-16 |
CN101466894B (zh) | 2012-10-17 |
CA2654156A1 (en) | 2007-12-13 |
WO2007142528A1 (en) | 2007-12-13 |
MX2008015152A (es) | 2008-12-15 |
AU2007256038A1 (en) | 2007-12-13 |
EA016520B1 (ru) | 2012-05-30 |
PT1865105E (pt) | 2009-12-23 |
CN101466894A (zh) | 2009-06-24 |
CA2654156C (en) | 2012-10-16 |
DK1865105T3 (da) | 2010-01-18 |
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