JP2007533590A - 高シリカゼオライト:uzm−5hs - Google Patents
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- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/026—After-treatment
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- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
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- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
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- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/06—Catalytic processes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
- C07C5/2732—Catalytic processes
- C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
- C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
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- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
蒸気処理 → 焼成処理 → イオン交換;
焼成処理 → 蒸気処理 → イオン交換;
イオン交換 → 焼成処理 → 蒸気処理;
イオン交換 → 蒸気処理 → 焼成処理;
蒸気処理 → 焼成処理;
焼成処理 → 蒸気処理等;
アルミニウムトリsec−ブトキシド(95+%)58.75gを、TEAOH(35%)836.34g中に溶解させた。続いてコロイダルシリカ(LudoxTM AS−40、40%SiO2)294.73gを、脱イオン水10.18gと共に加えた。次にこの反応混合物を1時間強く撹拌し、複数のテフロン(登録商標)ボトルに移し、そして95℃の温度下で一晩熟成させた。結果的に生成されたアルミノシリケート混合物を分析すると、それが4.67%のSiを含んでいることが示された。
Claims (7)
- 少なくともAlO2及びSiO2四面体酸化物単位の三次元骨格構造を有し、及び成分のモル比が無水換算で以下の実験式で表されるミクロ多孔結晶質ゼオライトにおいて、
ここで、M1はアルカリ金属、アルカリ土類金属、希土類金属、アンモニウムイオン、水素イオン及びそれらの混合物から成る群より選択される少なくとも1つの交換性カチオンであり、aはM1対(Al+E)のモル比であって0.15〜5.0の範囲で変化し、Eはガリウム、鉄、ホウ素、クロム、インジウム及びそれらの混合物から成る群より選択される元素であり、xはEのモル分率であって0〜0.5の範囲で変化し、nはM1の加重平均原子価であって+1〜+3の値を有し、y’はSi対(Al+E)のモル比であって5より大きい値を有し、そしてz”はO対(Al+E)のモル比であって以下の式によって定義される値を有しており、
このゼオライトは、少なくとも2つのX線回折ピークを有していて、1つは3.84±0.07Åのdスペース、そしてもう1つは8.55±0.25Åのdスペースであるという点で特徴付けられる、
ことを特徴とするミクロ多孔結晶質ゼオライト。 - y’が5〜20,000の値を有していることを特徴とする請求項1又は2記載のゼオライト。
- 請求項1又は2又は3記載のミクロ多孔結晶質ゼオライトを調製する方法であって、該方法は、処理条件にて出発ゼオライトを処理し、これにより骨格アルミニウムの少なくとも一部を除去し、そして必要に応じて、シリコンを上記骨格内に挿入して改質ゼオライトを生成するステップを含んでおり、上記出発ゼオライトが無水換算で以下の実験式で表される組成を有しており、
ここで、M’はアンモニウムイオン、水素イオン、アルカリ金属、アルカリ土類金属、希土類金属及びそれらの混合物から成る群より選ばれる交換性カチオンであり、nはM’の加重平均原子価であって+1〜+3の範囲で変化し、m’はM’対(Al+E)のモル比であって0〜3.0の範囲で変化し、Rはプロトン化アミン、プロトン化ジアミン、プロトン化アルカノールアミン、第4級アンモニウムイオン、ジ第4級アンモニウムイオン、4級化アルカノールアンモニウムイオン及びそれらの混合物から成る群より選択される有機カチオンであり、pは上記有機カチオンの平均加重原子価であって+1〜+2の範囲で変化し、r’はR対(Al+E)のモル比であって0〜3.0の範囲で変化し、y’はSi対(Al+E)のモル比であって5〜12の範囲で変化し、そしてz’はO対(Al+E)のモル比であって以下の式によって示される値を有している、
ことを特徴とする方法。 - 上記処理ステップが、フルオロシリケート溶液又は懸濁液による処理、弱性、強性、又は複合酸による抽出、焼成プラスイオン交換、蒸気処理プラス酸抽出及びそれらの組み合わせから成る群より選択されることを特徴とする請求項4記載の方法。
- 炭化水素転化方法であって、該方法は、炭化水素流を炭化水素転化条件下で触媒合成物と接触させるステップを含んでおり、上記触媒合成物が請求項1又は2又は3記載のゼオライトを含んでいることを特徴とする炭化水素転化方法。
- 上記炭化水素転化方法が、芳香族化合物のアルキル化、キシレンの異性体化、ナフサ分解、開環、トランスアルキル化、イソパラフィンのアルキル化、エチルベンゼンの異性体化、及び酸素含有物のオレフィンへの転化より成る群から選択されることを特徴とする請求項6記載の方法。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2004/012831 WO2005113437A1 (en) | 2004-04-23 | 2004-04-23 | High silica zeolites uzm-5hs |
Publications (2)
Publication Number | Publication Date |
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JP2007533590A true JP2007533590A (ja) | 2007-11-22 |
JP4836939B2 JP4836939B2 (ja) | 2011-12-14 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2007509441A Expired - Fee Related JP4836939B2 (ja) | 2004-04-23 | 2004-04-23 | 高シリカゼオライト:uzm−5hs |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1756004B1 (ja) |
JP (1) | JP4836939B2 (ja) |
CN (1) | CN1972867B (ja) |
DE (1) | DE602004028766D1 (ja) |
WO (1) | WO2005113437A1 (ja) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013534896A (ja) * | 2010-06-21 | 2013-09-09 | ユーオーピー エルエルシー | Uzm−35ゼオライト組成物、調製方法及びプロセス |
JP2013536145A (ja) * | 2010-07-01 | 2013-09-19 | ユーオーピー エルエルシー | Uzm−45アルミノケイ酸塩ゼオライト、uzm−45の調製方法およびそれを用いたプロセス |
JP5570648B1 (ja) * | 2013-12-20 | 2014-08-13 | 株式会社池田工業 | 壁紙塗料 |
JP2016505573A (ja) * | 2012-12-12 | 2016-02-25 | ユーオーピー エルエルシー | Uzm−39アルミノケイ酸塩ゼオライトを用いた芳香族トランスアルキル化反応 |
JP2016506298A (ja) * | 2012-12-18 | 2016-03-03 | ユーオーピー エルエルシー | Euo−nes−nonゼオライトのuzm−43を用いる炭化水素プロセス |
Families Citing this family (27)
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US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
US20050171393A1 (en) | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
WO2005021468A1 (en) | 2003-07-15 | 2005-03-10 | Grt, Inc. | Hydrocarbon synthesis |
US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
US20080275284A1 (en) | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
EP1993979A4 (en) | 2006-02-03 | 2011-07-06 | Grt Inc | CONTINUOUS PROCESS FOR CONVERTING NATURAL GAS TO LIQUID HYDROCARBONS |
UA95943C2 (ru) | 2006-02-03 | 2011-09-26 | ДжиАрТи, ИНК. | Отделение легких газов от галогенов |
EA017699B1 (ru) | 2007-05-24 | 2013-02-28 | Грт, Инк. | Зонный реактор с обратимым захватыванием и высвобождением галогеноводородов |
US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
SG192538A1 (en) | 2008-07-18 | 2013-08-30 | Grt Inc | Continuous process for converting natural gas to liquid hydrocarbons |
US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US7985886B1 (en) * | 2010-03-31 | 2011-07-26 | Uop Llc | Aromatic alkylation process using UZM-37 aluminosilicate zeolite |
US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
WO2013096069A2 (en) * | 2011-12-22 | 2013-06-27 | Uop Llc | Uzm-39 aluminosilicate zeolite |
US8609920B1 (en) * | 2012-12-12 | 2013-12-17 | Uop Llc | UZM-44 aluminosilicate zeolite |
CN112264086A (zh) | 2013-04-29 | 2021-01-26 | 沙特基础工业公司 | 石脑油转化成烯烃的催化方法 |
US9688587B2 (en) * | 2015-03-03 | 2017-06-27 | Uop Llc | Process for oxygenate to olefin conversion using 2-D pentasil zeolite |
EP3841063A4 (en) * | 2018-08-24 | 2022-06-01 | Rhodia Operations | ALUMINOTITANOSILICATE MICROPOROUS CRYSTALLINE ZEOLITE, METHOD FOR PREPARATION AND APPLICATIONS |
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2004
- 2004-04-23 JP JP2007509441A patent/JP4836939B2/ja not_active Expired - Fee Related
- 2004-04-23 CN CN2004800434240A patent/CN1972867B/zh not_active Expired - Fee Related
- 2004-04-23 DE DE602004028766T patent/DE602004028766D1/de not_active Expired - Lifetime
- 2004-04-23 EP EP04822021A patent/EP1756004B1/en not_active Expired - Fee Related
- 2004-04-23 WO PCT/US2004/012831 patent/WO2005113437A1/en active Application Filing
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WO2002036489A1 (en) * | 2000-11-03 | 2002-05-10 | Uop Llc | Uzm-5, uzm-5p and uzm-6; crystalline aluminosilicate zeolites and processes using the same |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013534896A (ja) * | 2010-06-21 | 2013-09-09 | ユーオーピー エルエルシー | Uzm−35ゼオライト組成物、調製方法及びプロセス |
JP2013536145A (ja) * | 2010-07-01 | 2013-09-19 | ユーオーピー エルエルシー | Uzm−45アルミノケイ酸塩ゼオライト、uzm−45の調製方法およびそれを用いたプロセス |
JP2013537510A (ja) * | 2010-07-01 | 2013-10-03 | ユーオーピー エルエルシー | Uzm−7アルミノケイ酸塩ゼオライト、uzm−7の調製方法及びそれを用いる方法 |
JP2016505573A (ja) * | 2012-12-12 | 2016-02-25 | ユーオーピー エルエルシー | Uzm−39アルミノケイ酸塩ゼオライトを用いた芳香族トランスアルキル化反応 |
JP2016506298A (ja) * | 2012-12-18 | 2016-03-03 | ユーオーピー エルエルシー | Euo−nes−nonゼオライトのuzm−43を用いる炭化水素プロセス |
JP5570648B1 (ja) * | 2013-12-20 | 2014-08-13 | 株式会社池田工業 | 壁紙塗料 |
Also Published As
Publication number | Publication date |
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WO2005113437A1 (en) | 2005-12-01 |
EP1756004A1 (en) | 2007-02-28 |
EP1756004B1 (en) | 2010-08-18 |
JP4836939B2 (ja) | 2011-12-14 |
CN1972867A (zh) | 2007-05-30 |
CN1972867B (zh) | 2010-11-03 |
DE602004028766D1 (de) | 2010-09-30 |
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