JP2007261835A - 低融点金属鋳造装置用耐熱材料 - Google Patents
低融点金属鋳造装置用耐熱材料 Download PDFInfo
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- 239000003779 heat-resistant material Substances 0.000 title claims abstract description 38
- 238000005058 metal casting Methods 0.000 title claims abstract description 32
- 238000002844 melting Methods 0.000 title abstract description 11
- 230000008018 melting Effects 0.000 title abstract description 10
- 239000000378 calcium silicate Substances 0.000 claims abstract description 27
- 229910052918 calcium silicate Inorganic materials 0.000 claims abstract description 27
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims abstract description 27
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 23
- 239000011777 magnesium Substances 0.000 claims abstract description 23
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract description 21
- 229910052751 metal Inorganic materials 0.000 claims abstract description 12
- 239000002184 metal Substances 0.000 claims abstract description 12
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 4
- 239000011737 fluorine Substances 0.000 claims abstract description 4
- 238000005452 bending Methods 0.000 claims description 6
- 229910052882 wollastonite Inorganic materials 0.000 claims description 6
- 239000010456 wollastonite Substances 0.000 claims description 6
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 5
- 229910001634 calcium fluoride Inorganic materials 0.000 claims description 4
- 229910001610 cryolite Inorganic materials 0.000 claims description 4
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 claims description 4
- 229910004762 CaSiO Inorganic materials 0.000 claims description 3
- MKTRXTLKNXLULX-UHFFFAOYSA-P pentacalcium;dioxido(oxo)silane;hydron;tetrahydrate Chemical compound [H+].[H+].O.O.O.O.[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O MKTRXTLKNXLULX-UHFFFAOYSA-P 0.000 claims description 3
- UGGQKDBXXFIWJD-UHFFFAOYSA-N calcium;dihydroxy(oxo)silane;hydrate Chemical compound O.[Ca].O[Si](O)=O UGGQKDBXXFIWJD-UHFFFAOYSA-N 0.000 claims 1
- 229910045601 alloy Inorganic materials 0.000 abstract description 10
- 239000000956 alloy Substances 0.000 abstract description 10
- 230000003628 erosive effect Effects 0.000 abstract description 7
- 238000009413 insulation Methods 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 description 12
- 230000007797 corrosion Effects 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- 238000005266 casting Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 229910000861 Mg alloy Inorganic materials 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 238000010335 hydrothermal treatment Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000012300 argon atmosphere Substances 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 150000002681 magnesium compounds Chemical class 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 238000013001 point bending Methods 0.000 description 2
- 239000012783 reinforcing fiber Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminium flouride Chemical compound F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- 229910016036 BaF 2 Inorganic materials 0.000 description 1
- DPRGTTWPUSPFOS-UHFFFAOYSA-N FF.[Na] Chemical compound FF.[Na] DPRGTTWPUSPFOS-UHFFFAOYSA-N 0.000 description 1
- FBPPFTYHDJMKMK-UHFFFAOYSA-N N[H].FF Chemical compound N[H].FF FBPPFTYHDJMKMK-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- OYLGJCQECKOTOL-UHFFFAOYSA-L barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 description 1
- 229910001632 barium fluoride Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- QCCDYNYSHILRDG-UHFFFAOYSA-K cerium(3+);trifluoride Chemical compound [F-].[F-].[F-].[Ce+3] QCCDYNYSHILRDG-UHFFFAOYSA-K 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910001506 inorganic fluoride Inorganic materials 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- FVRNDBHWWSPNOM-UHFFFAOYSA-L strontium fluoride Chemical compound [F-].[F-].[Sr+2] FVRNDBHWWSPNOM-UHFFFAOYSA-L 0.000 description 1
- 229910001637 strontium fluoride Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 229940105963 yttrium fluoride Drugs 0.000 description 1
- RBORBHYCVONNJH-UHFFFAOYSA-K yttrium(iii) fluoride Chemical compound F[Y](F)F RBORBHYCVONNJH-UHFFFAOYSA-K 0.000 description 1
- -1 zonotlite Substances 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/22—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in calcium oxide, e.g. wollastonite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/18—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type
- C04B28/186—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type containing formed Ca-silicates before the final hardening step
- C04B28/188—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type containing formed Ca-silicates before the final hardening step the Ca-silicates being present in the starting mixture
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/553—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on fluorides
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0087—Uses not provided for elsewhere in C04B2111/00 for metallurgical applications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
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- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Organic Chemistry (AREA)
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- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
- Glass Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Mold Materials And Core Materials (AREA)
- Ceramic Products (AREA)
Abstract
【解決手段】けい酸カルシウムと、フッ化物とを含有することを特徴とする低融点金属鋳造装置用耐熱材料。
【選択図】なし
Description
(1)けい酸カルシウムと、フッ化物とを含有することを特徴とする低融点金属鋳造装置用耐熱材料。
(2)フッ化物を、フッ素分として0.05〜30質量%の割合で含有することを特徴とする上記(1)記載の低融点金属鋳造装置用耐熱材料。
(3)けい酸カルシウムはワラストナイト(CaSiO3)、トバモライト(5CaO・6SiO2・5H2O)及びゾノトライト(6CaO・6SiO2・H2O)から選ばれる少なくとも1種であることを特徴とする上記(1)または(2)記載の低融点金属鋳造装置用耐熱材料。
(4)フッ化物はフッ化カルシウム(CaF2)、フッ化マグネシム(MgF2)及びクリオライト(Na3AlF6)から選ばれる少なくとも1種であることを特徴とする上記(1)〜(3)の何れか1項に記載の低融点金属鋳造装置用耐熱材料。
(5)密度が200〜2500kg/m3で、曲げ強度が1〜20MPaであることを特徴とする上記(1)〜(4)の何れか1項に記載の低融点金属鋳造装置用耐熱材料。
(6)マグネシウムまたはマグネシウムを含む合金の溶湯と接触する部位に使用されることを特徴とする上記(1)〜(5)の何れか1項に記載の低融点金属鋳造装置用耐熱材料。
尚、本発明においてマグネシウムを含む合金とは、アルミニウムや亜鉛、スズ、鉛等のマグネシウム以外の低融点金属とマグネシウムとの合金全般を意味し、マグネシウムの含有率は問わないが、現実的には合金全量の0.1質量%〜99.9質量%の範囲でマグネシウムを含むものである。
表1〜3に示す配合にてけい酸カルシウム原料、フッ化物及びその他の材料を混合攪拌して水性スラリーを調製した。尚、配合物の詳細は以下のとおりである。
試験体から切り出した長さ300mm、幅75mm、厚さ25mmの試験片を、株式会社島津製作所製オートグラフ「AG−50kNG」を用いて、支点間距離200mm、荷重速度10mm/minで3点曲げ強度を測定した。
試験体から切り出した長さ20mm、幅5mm、厚さ5mmの試験片を、理学電機工業株式会社製熱機械分析装置「TMA8310」を用いて、空気中で5℃/minの速度で室温から800℃まで昇温し熱膨張係数を測定した。
試験体から一辺が約70mmの正方形で、厚さが25mmの試験片を切り出し、図1に模式的に示すように、セッター上に配置された試験片のほぼ中心部にマグネシウム合金(AZ31)からなる直径8mmで高さ10mmの円柱を置き、円柱の上面に0.2MPaの荷重を加えた状態で、アルゴン雰囲気中で室温から2時間かけて800℃まで昇温してマグネシウム合金を溶融させ、その後、マグネシウム合金融液の液面上に同荷重を負荷した状態で、アルゴン雰囲気中、800℃にて1時間保持し、マグネシウム合金融液と試験片との接触状態を保った。1時間後、開圧してマグネシウム合金融液を試験片の表面から回収し、室温まで冷却した後、試験片の断面を観察してマグネシウム合金融液との接触により浸食された部分の面積を測定した。そして、実用上特に問題なしを「○」、多少問題があるが実用上問題なしを「△」、実用上問題ありを「×」とし、表中に記した。
Claims (6)
- けい酸カルシウムと、フッ化物とを含有することを特徴とする低融点金属鋳造装置用耐熱材料。
- フッ化物を、フッ素分として0.05〜30質量%の割合で含有することを特徴とする請求項1記載の低融点金属鋳造装置用耐熱材料。
- けい酸カルシウムはワラストナイト(CaSiO3)、トバモライト(5CaO・6SiO2・5H2O)及びゾノトライト(6CaO・6SiO2・H2O)から選ばれる少なくとも1種であることを特徴とする請求項1または2記載の低融点金属鋳造装置用耐熱材料。
- フッ化物はフッ化カルシウム(CaF2)、フッ化マグネシム(MgF2)及びクリオライト(Na3AlF6)から選ばれる少なくとも1種であることを特徴とする請求項1〜3の何れか1項に記載の低融点金属鋳造装置用耐熱材料。
- 密度が200〜2500kg/m3で、曲げ強度が1〜20MPaであることを特徴とする請求項1〜4の何れか1項に記載の低融点金属鋳造装置用耐熱材料。
- マグネシウムまたはマグネシウムを含む合金の溶湯と接触する部位に使用されることを特徴とする請求項1〜5の何れか1項に記載の低融点金属鋳造装置用耐熱材料。
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006086401A JP5420815B2 (ja) | 2006-03-27 | 2006-03-27 | 低融点金属鋳造装置用耐熱材料 |
KR1020070029647A KR101235534B1 (ko) | 2006-03-27 | 2007-03-27 | 저융점 금속 주조기용 내열재료 |
ES07006331T ES2358131T3 (es) | 2006-03-27 | 2007-03-27 | Material termorresistente para máquina de colada de metal de bajo punto de fusión. |
AT07006331T ATE495839T1 (de) | 2006-03-27 | 2007-03-27 | HITZEBESTÄNDIGES MATERIAL FÜR EINE MASCHINE ZUM GIEßEN VON METALLEN MIT NIEDRIGEM SCHMELZPUNKT |
DE602007012005T DE602007012005D1 (de) | 2006-03-27 | 2007-03-27 | Hitzebeständiges Material für eine Maschine zum Gießen von Metallen mit niedrigem Schmelzpunkt |
EP07006331A EP1839773B1 (en) | 2006-03-27 | 2007-03-27 | Heat-resistant material for low-melting metal casting machine |
CN2007100895223A CN101054303B (zh) | 2006-03-27 | 2007-03-27 | 用于低熔点金属铸造设备的耐热材料 |
US11/727,646 US7700061B2 (en) | 2006-03-27 | 2007-03-27 | Heat-resistant material for low-melting metal casting machine |
Applications Claiming Priority (1)
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JP2019196300A (ja) * | 2018-05-07 | 2019-11-14 | 日本インシュレーション株式会社 | 断熱材及びその製造方法、並びに組成物 |
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JP2007269605A (ja) * | 2006-03-31 | 2007-10-18 | Nichias Corp | 溶融シリカ質耐火物及びその製造方法 |
FR2933397B1 (fr) * | 2008-07-02 | 2011-07-22 | Air Liquide | Procede de fabrication d'une structure de garnissage avec maitrise des parametres de la synthese hydrothermale |
JP5639243B2 (ja) * | 2013-09-05 | 2014-12-10 | ニチアス株式会社 | 低融点金属鋳造装置用耐熱材料 |
EP3397796A4 (en) * | 2015-12-29 | 2019-08-07 | Rutgers, the State University of New Jersey | PROCESSES FOR SYNTHESIS OF LOW ENERGY INORGANIC MATERIAL |
CN106746673B (zh) * | 2016-11-24 | 2019-09-13 | 福州大学 | 一种Co-Ni共掺的耐蚀玻璃及其制备和使用方法 |
CN106746672B (zh) * | 2016-11-24 | 2019-09-13 | 福州大学 | 一种Fe-Ni共掺的耐蚀玻璃及其制备和使用方法 |
CN106746623B (zh) * | 2016-11-24 | 2019-09-13 | 福州大学 | 一种Fe-Co共掺的耐蚀玻璃及其制备和使用方法 |
CN115259170B (zh) * | 2022-07-15 | 2023-04-25 | 南京工业大学 | 一种多孔硬硅钙石的制备方法 |
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JPS59199564A (ja) * | 1983-07-04 | 1984-11-12 | ニチアス株式会社 | ケイ酸カルシウム系耐熱材料の製造法 |
JPH03183665A (ja) * | 1989-12-12 | 1991-08-09 | Kurosaki Refract Co Ltd | 低融点金属用耐火組成物 |
JPH0557402A (ja) * | 1991-09-05 | 1993-03-09 | Nichias Corp | 低融点金属水平連続鋳造装置用断熱材 |
JPH05319901A (ja) * | 1992-05-18 | 1993-12-03 | Nippon Steel Corp | 耐火物 |
JP2002274959A (ja) * | 2001-03-14 | 2002-09-25 | Nippon Crucible Co Ltd | アルミニウムおよびアルミニウム合金用耐火物 |
US20050127549A1 (en) * | 2003-12-11 | 2005-06-16 | Bischoff Todd F. | Method for suppressing reaction of molten metals with refractory materials |
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JP2019196300A (ja) * | 2018-05-07 | 2019-11-14 | 日本インシュレーション株式会社 | 断熱材及びその製造方法、並びに組成物 |
JP7034981B2 (ja) | 2018-05-07 | 2022-03-14 | 日本インシュレーション株式会社 | 断熱材及びその製造方法、並びに組成物 |
Also Published As
Publication number | Publication date |
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KR20070096964A (ko) | 2007-10-02 |
DE602007012005D1 (de) | 2011-03-03 |
EP1839773B1 (en) | 2011-01-19 |
CN101054303A (zh) | 2007-10-17 |
EP1839773A1 (en) | 2007-10-03 |
KR101235534B1 (ko) | 2013-02-21 |
ATE495839T1 (de) | 2011-02-15 |
US7700061B2 (en) | 2010-04-20 |
US20070221013A1 (en) | 2007-09-27 |
ES2358131T3 (es) | 2011-05-05 |
CN101054303B (zh) | 2012-09-05 |
JP5420815B2 (ja) | 2014-02-19 |
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