JP2007159572A - Vitamin e-containing drinking composition - Google Patents
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Abstract
Description
本発明は、飲料を栄養強化するのに有用なビタミンＥ含有組成物に関する。 The present invention relates to vitamin E-containing compositions useful for fortifying beverages.
ビタミンＥは生体内における過酸化脂質の増加防止に有効な脂溶性ビタミンであり、ビタミンＥ欠乏症の予防および治療を目的として様々な食品、医薬品に添加され、使用されている（例えば、特許文献１参照）。しかし、ビタミンＥ、特に抽出ビタミンＥは出発原料由来の特異臭があり、飲料など特に風味が要求される食品に対しては、従来十分な量を添加することは難しかった。 Vitamin E is a fat-soluble vitamin effective in preventing the increase in lipid peroxides in vivo, and is added to various foods and pharmaceuticals for the purpose of preventing and treating vitamin E deficiency (for example, Patent Document 1). reference). However, vitamin E, particularly extracted vitamin E has a specific odor derived from the starting material, and it has been difficult to add a sufficient amount to foods such as beverages that particularly require a flavor.
この問題に関係するものとして、トコフェロールを５０質量％以上、中鎖脂肪酸トリグリセライドを０．２質量％以上含有することを特徴とする風味劣化が抑制されたトコフェロール製剤（特許文献２参照）が提案されている。 As a matter related to this problem, a tocopherol preparation (see Patent Document 2) with suppressed flavor deterioration, characterized by containing 50% by mass or more of tocopherol and 0.2% by mass or more of medium-chain fatty acid triglyceride has been proposed. ing.
しかし、上記の方法はトコフェロールが保存中に酸化し、風味が劣化するのを防ぐのが目的であり、抽出ビタミンＥの特異臭を抑制するためには十分な方法とは言えない。 However, the above method is intended to prevent the tocopherol from being oxidized during storage and the flavor from being deteriorated, and is not a sufficient method for suppressing the specific odor of extracted vitamin E.
本発明は、飲料を栄養強化するのに十分な量を添加可能な、抽出ビタミンＥ固有の特異臭が抑制されたビタミンＥ含有組成物を提供することを目的とする。 An object of the present invention is to provide a vitamin E-containing composition in which a specific odor inherent to extracted vitamin E can be added, which can be added in an amount sufficient to enhance nutrition of a beverage.
本発明者は、上記課題に対して鋭意、検討を行った結果、抽出ビタミンＥと植物ポリフェノールを同一水系で接触させることにより、抽出ビタミンＥに含まれる臭い成分が植物ポリフェノールに捕捉され、その結果抽出ビタミンＥ固有の特異臭が抑制されることを見出し、この知見に基づいて本発明をなすに至った。 As a result of earnestly examining the above problems, the inventor of the present invention captures the odor component contained in the extracted vitamin E by the plant polyphenol by contacting the extracted vitamin E and the plant polyphenol in the same aqueous system. It has been found that the specific odor inherent to the extracted vitamin E is suppressed, and the present invention has been made based on this finding.
すなわち、本発明は、
（１）抽出ビタミンＥと植物ポリフェノールを含有することを特徴とする飲料用のビタミンＥ含有組成物、
（２）更に、Ｌ−アスコルビン酸類を含有することを特徴とする前記（１）に記載のビタミンＥ含有組成物、
（３）植物ポリフェノールがカテキン類であることを特徴とする前記（１）または（２）に記載のビタミンＥ含有組成物、
からなっている。
That is, the present invention
(1) A vitamin E-containing composition for beverages, characterized by containing extracted vitamin E and plant polyphenols,
(2) The vitamin E-containing composition according to (1), further comprising L-ascorbic acids,
(3) The vitamin E-containing composition according to (1) or (2) above, wherein the plant polyphenol is a catechin,
It is made up of.
本発明の抽出ビタミンＥ含有組成物は、抽出ビタミンＥ固有の特異臭がない。
本発明の抽出ビタミンＥ含有組成物を使用することにより、飲料本来の風味を損うことなく栄養強化できる。
The extracted vitamin E-containing composition of the present invention has no specific odor inherent to extracted vitamin E.
By using the extracted vitamin E-containing composition of the present invention, nutrition can be enhanced without impairing the original flavor of the beverage.
本発明で用いられる抽出ビタミンＥとしては、植物油が精製される過程で副生する脱臭留出物（例えば脱臭スカム、脱臭スラッジまたはホットウエル油など）から回収されるビタミンＥであれば特に制限はなく、例えば、キャノーラ油、ごま油、米ぬか油、サフラワー油、大豆油、とうもろこし油、なたね油、パーム油、ひまわり油、綿実油、落花生油などの脱臭留出物から分離・精製して得られる、α−、β−、γ−、δ−トコフェロールおよびトコフェロールの同族体であるα−、β−、γ−、δ−トコトリエノールなどを含む混合物が挙げられる。該混合物は黄色〜茶褐色で粘性のある油性の液体で、固有の特異臭がある。 The extracted vitamin E used in the present invention is not particularly limited as long as it is recovered from deodorized distillate by-produced in the process of refining vegetable oil (for example, deodorized scum, deodorized sludge or hot well oil). Without separation and purification from deodorized distillates such as canola oil, sesame oil, rice bran oil, safflower oil, soybean oil, corn oil, rapeseed oil, palm oil, sunflower oil, cottonseed oil, peanut oil, etc. -, (Beta)-, (gamma)-, (delta) -tocopherol, and the mixture containing (alpha)-, (beta)-, (gamma)-, (delta) -tocotrienol etc. which are the homologues of tocopherol are mentioned. The mixture is a yellow-brown and viscous oily liquid with an inherent peculiar odor.
該混合物中の総トコフェロール含有量は約４０質量％以上であることが好ましく、約７０質量％以上であることが特に好ましい。更に、該混合物をカラムクロマトグラフィー、蒸留または超臨界抽出など公知の方法を用いて精製し、総トコフェロール中のｄ−α−トコフェロール含有量を約２５質量％以上としたもの、特に約５０質量％以上としたものが好ましく用いられる。 The total tocopherol content in the mixture is preferably about 40% by mass or more, particularly preferably about 70% by mass or more. Further, the mixture is purified using a known method such as column chromatography, distillation or supercritical extraction, so that the d-α-tocopherol content in the total tocopherol is about 25% by mass or more, particularly about 50% by mass. Those described above are preferably used.
本発明におけるポリフェノールとは、同一分子内に２個以上のフェノール性水酸基をもつ化合物の総称であり、代表的な化合物群としては、例えばフラボン類、フラボノール類、イソフラボン類、フラバン類、フラバノール（カテキン）類、フラバノン類、フラバノノール類、カルコン類、アントシアニジン類などに分類されるフラボノイド系の化合物およびそれらの関連化合物が挙げられる。 The polyphenol in the present invention is a general term for compounds having two or more phenolic hydroxyl groups in the same molecule, and typical compound groups include, for example, flavones, flavonols, isoflavones, flavans, flavanols (catechins). ), Flavanones, flavanonols, chalcones, anthocyanidins and the like, and flavonoid compounds and related compounds thereof.
本発明においては、植物ポリフェノールとして、上記化合物を含有する植物の抽出物または乾留物を用いることができるが、好ましくは抽出物を公知の方法を用いて精製し、植物ポリフェノールを所望の濃度に高めたものである。 In the present invention, a plant extract or dry-distilled product containing the above compound can be used as the plant polyphenol. Preferably, the extract is purified using a known method to increase the plant polyphenol to a desired concentration. It is a thing.
植物ポリフェノールを含有する植物としては、例えばカカオ（アオギリ科）、カンキツ類（ミカン科）、黄杞（クルミ科）、コーヒー（アカネ科）、ダイズ（マメ科）、茶（ツバキ科）、ブドウ（ブドウ科）、ブルーベリー（ツツジ科）、ホップ（クワ科）、ヤマモモ（ヤマモモ科）、リンゴ（バラ科）、ローズマリー（シソ科）などが挙げられる。 Plants containing plant polyphenols include, for example, cacao (Aegiriaceae), citrus (Rutaceae), jaundice (walnuts), coffee (Rubiaceae), soybeans (Leguminosae), tea (Camelliaceae), grapes (grapevines) Family), blueberry (Azalea), hop (Asteraceae), bayberry (Biraceae), apple (Rosaceae), rosemary (Lamiaceae), and the like.
本発明においては、とりわけ、茶、ブドウ、リンゴ、ヤマモモ由来の植物ポリフェノールが好ましく、茶由来の植物ポリフェノールが最も好ましい。生茶葉およびその加工品（例えば緑茶、ほうじ茶、ウーロン茶、プアール茶、紅茶など）に含まれる植物ポリフェノールの具体例としては、フラバノール（カテキン）類およびその関連化合物としてエピカテキン、エピカテキンガレート、エピガロカテキン、エピガロカテキンガレート、ガロカテキンガレート、カテキンガレート、テアフラビン、テアフラビンガレートＡ、テアフラビンガレートＢ、テアフラビンジガレートなどが挙げられる。これらは、粗製品であっても精製品であってもよく、またこれらを含有する製剤も使用できる。 In the present invention, plant polyphenols derived from tea, grapes, apples, and bayberry are particularly preferable, and plant polyphenols derived from tea are most preferable. Specific examples of plant polyphenols contained in fresh tea leaves and processed products thereof (for example, green tea, hoji tea, oolong tea, puer tea, black tea) include flavanols (catechins) and related compounds such as epicatechin, epicatechin gallate, epigallo Examples include catechin, epigallocatechin gallate, gallocatechin gallate, catechin gallate, theaflavin, theaflavin gallate A, theaflavin gallate B, and theaflavin digallate. These may be crude products or purified products, and preparations containing these can also be used.
本発明で用いられるＬ−アスコルビン酸類としては、Ｌ−アスコルビン酸、Ｌ−アスコルビン酸ナトリウムなどの他に、Ｌ−アスコルビン酸ステアリン酸エステル、Ｌ−アスコルビン酸パルミチン酸エステルなどのＬ−アスコルビン酸の誘導体、エリソルビン酸、エリソルビン酸ナトリウムなどのＬ−アスコルビン酸の異性体などが挙げられ、好ましくは、Ｌ−アスコルビン酸ステアリン酸エステル、Ｌ−アスコルビン酸パルミチン酸エステルなどのＬ−アスコルビン酸脂肪酸エステルである。 Examples of L-ascorbic acids used in the present invention include L-ascorbic acid, sodium L-ascorbate, and the like, as well as L-ascorbic acid derivatives such as L-ascorbic acid stearate and L-ascorbic acid palmitate. Isomers of L-ascorbic acid such as erythorbic acid and sodium erythorbate, and the like, preferably L-ascorbic acid fatty acid esters such as L-ascorbic acid stearic acid ester and L-ascorbic acid palmitic acid ester.
本発明のビタミンＥ含有組成物の形態としては、例えば水中油型乳化組成物、可溶化組成物、並びに前記水中油型乳化組成物または可溶化組成物を乾燥した粉末、顆粒、マイクロカプセルなどが挙げられ、好ましくは水中油型乳化組成物または可溶化組成物である。 Examples of the form of the vitamin E-containing composition of the present invention include an oil-in-water emulsion composition, a solubilized composition, and a powder, granule, microcapsule and the like obtained by drying the oil-in-water emulsion composition or the solubilized composition. Preferably, it is an oil-in-water emulsion composition or a solubilized composition.
上記水中油型乳化組成物の製造方法は特に限定されず、公知の方法を用いて行うことができる。以下に好ましい水中油型乳化組成物の製造方法を例示する。 The manufacturing method of the said oil-in-water emulsion composition is not specifically limited, It can carry out using a well-known method. Examples of the preferred method for producing an oil-in-water emulsion composition are as follows.
例えば、水に糖類（例えば、澱粉分解物、異性化液糖、オクテニルコハク酸エステル化澱粉など）或いは多価アルコール（例えば、グリセリン、Ｄ−ソルビトール、還元澱粉分解物など）、植物ポリフェノールおよび乳化剤（例えば、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステルなど）などを加えて約４０〜８０℃、好ましくは約６０〜８０℃に加熱して溶解し、水相とする。該水相を攪拌しながら、この中に約１００℃以下、好ましくは約６０〜１００℃に保温された抽出ビタミンＥを、または所望により抽出ビタミンＥとＬ−アスコルビン酸脂肪酸エステルを混合、溶解した油相をゆっくり加え、高速回転式分散・乳化機を用いて、回転数約４０００〜２００００ｒｐｍにて、攪拌時間約１０〜６０分間で乳化することにより、水中油型乳化組成物を製造することができる。 For example, saccharides (for example, starch degradation product, isomerized liquid sugar, octenyl succinate esterified starch, etc.) or polyhydric alcohol (for example, glycerin, D-sorbitol, reduced starch degradation product, etc.), plant polyphenols and emulsifiers (for example, , Polyglycerin fatty acid ester, sucrose fatty acid ester, etc.) are added and heated to about 40 to 80 ° C., preferably about 60 to 80 ° C. to dissolve and form an aqueous phase. While stirring the aqueous phase, the extracted vitamin E kept at a temperature of about 100 ° C. or less, preferably about 60 to 100 ° C., or the extracted vitamin E and L-ascorbic acid fatty acid ester were mixed and dissolved therein if desired. An oil-in-water emulsion composition can be produced by slowly adding an oil phase and emulsifying with a high-speed rotary dispersion / emulsifier at a rotation speed of about 4000 to 20000 rpm and a stirring time of about 10 to 60 minutes. it can.
上記水中油型乳化組成物を製造するための装置としては特に限定されず、例えば、攪拌機、加熱用のジャケットおよび邪魔板などを備えた通常の攪拌・混合槽を用いることができる。装備する攪拌機としては、ＴＫホモミクサー（プライミクス社製）またはクレアミックス（エムテクニック社製）などの高速回転式分散・乳化機が好ましく用いられる。 The apparatus for producing the oil-in-water emulsion composition is not particularly limited, and for example, a normal stirring / mixing tank equipped with a stirrer, a heating jacket, a baffle plate, and the like can be used. As a stirrer to be equipped, a high-speed rotary dispersing / emulsifying machine such as TK homomixer (manufactured by PRIMIX Co., Ltd.) or CLEARMIX (manufactured by MTechnic Co., Ltd.) is preferably used.
また、これらの装置で乳化した液を、高圧式均質化処理機を使用して、さらに均質化してもよい。ここで高圧式均質化処理機としては、例えばＡＰＶゴーリンホモジナイザー（ＡＰＶ社製）、マイクロフルイダイザー（マイクロフルイデックス社製）、アルティマイザー（スギノマシン社製）またはナノマイザー（大和製罐社製）などを好ましく使用することができる。上記均質化処理機に代えて、例えば超音波乳化機などの均質化処理機を用いてもよい。 Moreover, you may further homogenize the liquid emulsified with these apparatuses using a high-pressure-type homogenizer. Here, examples of the high-pressure homogenizer include an APV gorin homogenizer (manufactured by APV), a microfluidizer (manufactured by Microfluidics), an optimizer (manufactured by Sugino Machine), or a nanomizer (manufactured by Daiwa Steel). Can be preferably used. Instead of the homogenizer, a homogenizer such as an ultrasonic emulsifier may be used.
上記粉末状ビタミンＥ含有組成物の製造方法も特に限定されず、公知の方法を用いて行うことができる。以下に好ましい粉末状ビタミンＥ含有組成物の製造方法を例示する。 The method for producing the powdered vitamin E-containing composition is not particularly limited, and can be performed using a known method. A preferable method for producing a powdery vitamin E-containing composition is exemplified below.
例えば、水に糖類（例えば、澱粉分解物、異性化液糖、オクテニルコハク酸エステル化澱粉など）、増粘安定剤（例えば、アラビアガムなど）、植物ポリフェノールおよび乳化剤（例えば、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステルなど）などを加えて加熱して溶解し、水相とする。該水相を攪拌しながら、この中に加熱した抽出ビタミンＥを、または所望により抽出ビタミンＥとＬ−アスコルビン酸脂肪酸エステルを混合、溶解した油相をゆっくり加え、以下前記方法に準じて乳化し、水中油型乳化組成物を得る。 For example, sugar in water (for example, starch degradation product, isomerized liquid sugar, octenyl succinate starch, etc.), thickening stabilizer (for example, gum arabic), plant polyphenol and emulsifier (for example, glycerin fatty acid ester, polyglycerin) Fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, etc.) are added and dissolved by heating to obtain an aqueous phase. While stirring the aqueous phase, slowly add the extracted vitamin E heated therein or, if desired, the extracted vitamin E and L-ascorbic fatty acid ester mixed and dissolved, and then emulsified according to the above method. An oil-in-water emulsion composition is obtained.
次に水中油型乳化組成物を乾燥し粉末化する。乾燥方法としては、例えば、噴霧乾燥、ドラム乾燥、ベルト乾燥、真空乾燥あるいは真空凍結乾燥などが挙げられるが、好ましくは噴霧乾燥である。本発明で使用される噴霧乾燥装置に特に制限はなく、噴射式噴霧乾燥装置または回転円盤式噴霧乾燥装置など公知の装置を使用することができる。また、噴霧乾燥の操作条件に特に制限は無く、例えば、乳化組成物を加圧ノズル式噴霧乾燥装置に供給し、熱風入口温度約１５０〜２７０℃、排気温度約７０〜１３０℃の条件下で噴霧乾燥し、乾燥物をサイクロンで捕集することにより、粉末状ビタミンＥ組成物を得る。得られる粉末の平均粒子径は約２０〜２００μｍ、好ましくは約５０〜１００μｍである。また得られる粉末の乾燥減量は約１０質量％以下、好ましくは約７質量％以下、更に好ましくは約５質量％以下である。 Next, the oil-in-water emulsion composition is dried and powdered. Examples of the drying method include spray drying, drum drying, belt drying, vacuum drying, and vacuum freeze drying, and spray drying is preferable. There is no restriction | limiting in particular in the spray-drying apparatus used by this invention, Well-known apparatuses, such as a spray-type spray-drying apparatus or a rotary disk type spray-drying apparatus, can be used. There are no particular restrictions on the operating conditions for spray drying. For example, the emulsified composition is supplied to a pressure nozzle type spray drying apparatus, and the hot air inlet temperature is about 150 to 270 ° C. and the exhaust temperature is about 70 to 130 ° C. By spray-drying and collecting the dried product with a cyclone, a powdered vitamin E composition is obtained. The average particle diameter of the obtained powder is about 20 to 200 μm, preferably about 50 to 100 μm. The loss on drying of the obtained powder is about 10% by mass or less, preferably about 7% by mass or less, more preferably about 5% by mass or less.
尚、粉末状ビタミンＥ含有組成物中には、本発明の目的・効果を阻害しない範囲で、例えば賦形剤、流動性付与物質などを加えることができる。賦形剤としては、例えば、ブドウ糖、果糖などの単糖、ショ糖、乳糖、麦芽糖などの二糖、デキストリン、粉末水飴などのでん粉分解物、マルトトリオース、マルトテトラオース、マルトペンタオース、マルトヘキサオースなどのマルトオリゴ糖類、ソルビトール、マンニトール、マルチトール、粉末還元水飴、粉末還元パラチノースなどの糖アルコール類などが挙げられる。また流動性付与物質としては、例えば、リン酸三カルシウム、微粒二酸化ケイ素などが挙げられる。 In the powdered vitamin E-containing composition, for example, an excipient, a fluidity-imparting substance and the like can be added within a range that does not impair the object and effect of the present invention. Examples of excipients include monosaccharides such as glucose and fructose, disaccharides such as sucrose, lactose and maltose, starch decomposition products such as dextrin and starch syrup, maltotriose, maltotetraose, maltopentaose, malto Examples include malto-oligosaccharides such as hexaose, sugar alcohols such as sorbitol, mannitol, maltitol, powdered reduced starch syrup, and powdered reduced palatinose. Examples of the fluidity imparting substance include tricalcium phosphate and fine silicon dioxide.
本発明のビタミンＥ含有組成物の好ましい実施態様の一例は、該組成物１００質量％中に配合される抽出ビタミンＥ量が約１〜７０質量％、好ましくは約１０〜５０質量％、植物ポリフェノール量が約０．００１〜１質量％、好ましくは約０．００５〜０．５質量％である。抽出ビタミンＥ量に対する植物ポリフェノール量の比率は、約０．００００１５〜１が好ましく、約０．０００１〜０．０５であるのが特に好ましい。更に所望により配合されるＬ−アスコルビン酸類の量は、該組成物１００質量％中に約０．００１〜０．１質量％、好ましくは約０．００５〜０．０５質量％である。 An example of a preferred embodiment of the vitamin E-containing composition of the present invention is that the amount of extracted vitamin E blended in 100% by mass of the composition is about 1 to 70% by mass, preferably about 10 to 50% by mass, plant polyphenol The amount is about 0.001-1% by mass, preferably about 0.005-0.5% by mass. The ratio of the amount of plant polyphenols to the amount of extracted vitamin E is preferably about 0.000015 to 1, particularly preferably about 0.0001 to 0.05. Further, the amount of L-ascorbic acid compounded as desired is about 0.001 to 0.1% by mass, preferably about 0.005 to 0.05% by mass in 100% by mass of the composition.
また、本発明のビタミンＥ含有組成物組成物１００質量％中に含まれるｄ−α−トコフェロールの量は、約１〜７０質量％が好ましく、約１０〜５０質量％であるのが特に好ましい。 Moreover, about 1-70 mass% is preferable and, as for the quantity of d- (alpha) -tocopherol contained in 100 mass% of vitamin-E containing composition compositions of this invention, it is especially preferable that it is about 10-50 mass%.
本発明のビタミンＥ含有組成物が添加される飲料としては、例えば低酸性飲料および酸性飲料などが挙げられる。 Examples of beverages to which the vitamin E-containing composition of the present invention is added include low acid beverages and acidic beverages.
低酸性飲料としては、例えば加工乳、乳成分含有飲料、茶系飲料、麦茶など、その液性がｐＨ４．６以上の低酸性領域にある飲料が挙げられる。該加工乳としては、例えば低脂肪乳などが挙げられる。該乳成分含有飲料としては、例えばコーヒー乳飲料、ミルクコーヒー、カフェオレ、カフェラテ、ミルクティー、ミルクココア、いちご牛乳、抹茶ミルクなどが挙げられる。該茶系飲料としては、例えば緑茶飲料、紅茶飲料、ウーロン茶飲料、ブレンド茶系飲料などが挙げられる。 Examples of the low acid beverage include beverages having a liquidity in a low acid region having a pH of 4.6 or more, such as processed milk, milk component-containing beverages, tea-based beverages, and barley tea. Examples of the processed milk include low-fat milk. Examples of the milk component-containing beverage include coffee milk beverage, milk coffee, cafe au lait, latte, milk tea, milk cocoa, strawberry milk, matcha milk and the like. Examples of the tea-based beverage include green tea beverages, black tea beverages, oolong tea beverages, and blended tea beverages.
酸性飲料としては、例えば、炭酸飲料、果実飲料（例えば果汁飲料、果汁入り清涼飲料など）、乳酸菌飲料、フレーバーや機能性素材などを含んだ機能性飲料、スポーツ飲料、栄養補給飲料など、その液性がｐＨ２．０以上ｐＨ４．６未満の酸性領域にある飲料が挙げられる。 Examples of acidic beverages include carbonated beverages, fruit beverages (eg fruit juice beverages, soft drinks containing fruit juice), lactic acid bacteria beverages, functional beverages containing flavors and functional materials, sports beverages, nutritional supplement beverages, and the like. A beverage having an acidity in an acidic region having a pH of 2.0 or more and less than 4.6.
飲料に対する本発明のビタミンＥ含有組成物の添加量は、おおむね該組成物に含まれるｄ−α−トコフェロールの量によって決められる。即ち、本発明のビタミンＥ含有組成物は、例えば、飲料１００ｍＬ中のｄ−α−トコフェロールの含有量が約１〜２００ｍｇ、好ましくは約１〜１００ｍｇとなるように、飲料に配合されるのが好ましい。 The amount of the vitamin E-containing composition of the present invention added to the beverage is generally determined by the amount of d-α-tocopherol contained in the composition. That is, the vitamin E-containing composition of the present invention is blended in a beverage so that the content of d-α-tocopherol in 100 mL of beverage is about 1 to 200 mg, preferably about 1 to 100 mg. preferable.
以下、製造例および試験例をもって本発明を具体的に説明する。もちろん、本発明が以下に記載されたこれらの例に限定されるものでないことは言うまでもない。 Hereinafter, the present invention will be specifically described with production examples and test examples. Of course, it goes without saying that the present invention is not limited to these examples described below.
［製造例１］
１）２００ｍＬ容ビーカーに茶抽出物（商品名：ポリフェノン７０Ａ；三井農林社製）０．０１ｇを入れ、精製水２０ｇを加えて溶解し、水飴（商品名：ハローデックス；林原社製）１１０ｇを入れ６０℃に加温する。
２）Ｔ．Ｋホモミクサー（型式：ＭＡＲＫＩＩ；プライミクス社製）で低速で攪拌しながら、デカグリセリンモノステアレート（商品名：ＮＩＫＫＯＬ Ｄｅｃａｇｌｙｎ １−５０ＳＶ；日光ケミカルズ社製）１０ｇを加えて溶解し、水相とした。
３）抽出ビタミンＥ（商品名：理研Ｅオイル７０５；理研ビタミン社製，総トコフェロール含量約７０質量％以上，ｄ−α−トコフェロール含有量約３５質量％以上）６０ｇを約６０℃まで加熱し、油相とした。
４）ＴＫホモミクサーで低速で撹拌しながら、上記２）の水相に上記３）の油相を徐々に加え、その後７０００ｒｐｍで１５分間攪拌して乳化し、ビタミンＥ含有組成物（実施品１）を得た。
[Production Example 1]
1) 0.01 g of tea extract (trade name: Polyphenon 70A; manufactured by Mitsui Norin) is added to a 200 mL beaker, dissolved by adding 20 g of purified water, and 110 g of syrup (trade name: Hellodex; manufactured by Hayashibara) is added. Heat to 60 ° C.
2) T.M. While stirring at a low speed with a K homomixer (model: MARKII; manufactured by Primix), 10 g of decaglycerin monostearate (trade name: NIKKOL Decaglyn 1-50SV; manufactured by Nikko Chemicals) was added and dissolved to obtain an aqueous phase.
3) 60 g of extracted vitamin E (trade name: Riken E Oil 705; manufactured by Riken Vitamin Co., Ltd., total tocopherol content of about 70% by mass or more, d-α-tocopherol content of about 35% by mass or more) is heated to about 60 ° C., An oil phase was obtained.
4) While stirring at low speed with a TK homomixer, gradually add the oil phase of 3) above to the aqueous phase of 2) above, and then emulsify by stirring at 7000 rpm for 15 minutes to obtain a vitamin E-containing composition (Example 1) Got.
［製造例２］
製造例１の２）に記載されている茶抽出物（商品名：ポリフェノン７０Ａ；三井農林社製）０．０１ｇに替えて、茶抽出物（商品名：ポリフェノン７０Ａ；三井農林社製）０．１ｇを使用する以外は製造例１と同様に実施し、ビタミンＥ含有組成物（実施品２）を得た。
[Production Example 2]
Instead of 0.01 g of tea extract (trade name: Polyphenon 70A; manufactured by Mitsui Norinsha) described in 2) of Production Example 1, tea extract (trade name: Polyphenon 70A; manufactured by Mitsui Norin) 0. Except having used 1g, it implemented similarly to manufacture example 1 and obtained the vitamin E containing composition (implemented product 2).
［製造例３］
製造例１の２）に記載されている茶抽出物（商品名：ポリフェノン７０Ａ；三井農林社製）０．０１ｇに替えて、茶抽出物（商品名：ポリフェノン７０Ａ；三井農林社製）０．６ｇを使用する以外は製造例１と同様に実施し、ビタミンＥ含有組成物（実施品３）を得た。
[Production Example 3]
Instead of 0.01 g of tea extract (trade name: Polyphenon 70A; manufactured by Mitsui Norinsha) described in 2) of Production Example 1, tea extract (trade name: Polyphenon 70A; manufactured by Mitsui Norin) 0. Except having used 6g, it implemented similarly to manufacture example 1, and obtained the vitamin-E containing composition (Example product 3).
［製造例４］
１）２００ｍＬ容ビーカーに茶抽出物（商品名：ポリフェノン７０Ａ；三井農林社製）０．１ｇを入れ、精製水２０ｇを加えて溶解し、水飴（商品名：ハローデックス；林原社製）１１０ｇを入れ６０℃に加温する。
２）Ｔ．Ｋホモミクサー（型式：ＭＡＲＫＩＩ；プライミクス社製）で低速で攪拌しながら、デカグリセリンモノステアレート（商品名：ＮＩＫＫＯＬ Ｄｅｃａｇｌｙｎ １−５０ＳＶ；日光ケミカルズ社製）１０ｇを加えて溶解し、水相とした。
３）抽出ビタミンＥ（商品名：理研Ｅオイル７０５；理研ビタミン社製，総トコフェロール含量約７０質量％以上，ｄ−α−トコフェロール含有量約３５質量％以上）６０ｇとアスコルビン酸パルミチン酸エステル（ＤＳＭニュートリッシュンジャパン社製）０．１ｇを混合して約９５℃まで加熱し、油相とした。
４）ＴＫホモミクサーで低速で撹拌しながら、上記２）の水相に上記３）の油相を徐々に加え、その後７０００ｒｐｍで１５分間攪拌して乳化し、ビタミンＥ含有組成物（実施品４）を得た。
[Production Example 4]
1) Put 0.1 g of tea extract (trade name: Polyphenon 70A; manufactured by Mitsui Norin) in a 200 mL beaker, dissolve it by adding 20 g of purified water, and add 110 g of starch syrup (trade name: Hellodex; manufactured by Hayashibara). Heat to 60 ° C.
2) T.M. While stirring at a low speed with a K homomixer (model: MARKII; manufactured by Primix), 10 g of decaglycerin monostearate (trade name: NIKKOL Decaglyn 1-50SV; manufactured by Nikko Chemicals) was added and dissolved to obtain an aqueous phase.
3) 60 g of extracted vitamin E (trade name: Riken E Oil 705; manufactured by Riken Vitamin Co., Ltd., total tocopherol content of about 70% by mass or more, d-α-tocopherol content of about 35% by mass or more) and ascorbyl palmitate (DSM) 0.1 g of Neutrish Japan) was mixed and heated to about 95 ° C. to obtain an oil phase.
4) While stirring at low speed with a TK homomixer, gradually add the oil phase of 3) above to the aqueous phase of 2) above, and then emulsify by stirring at 7000 rpm for 15 minutes to give a vitamin E-containing composition (Example 4) Got.
［製造例５］
製造例１の２）に記載されている茶抽出物（商品名：ポリフェノン７０Ａ；三井農林社製）０．０１ｇを使用しない以外は製造例１と同様に実施し、ビタミンＥ含有組成物（対照品１）を得た。
[Production Example 5]
A vitamin E-containing composition (control) was carried out in the same manner as in Production Example 1 except that 0.01 g of the tea extract described in Production Example 1 2) (trade name: Polyphenone 70A; manufactured by Mitsui Norin Co., Ltd.) was not used. 1) was obtained.
［試験例１］
製造例１〜４で得たビタミンＥ含有組成物（実施品１〜４）と製造例５で得たビタミンＥ含有組成物（対照品１）の風味を官能試験で評価した。試験は２点比較法で行い、その結果について２点比較法（両側検定）検定表で検定した。結果を表１に示した。
[Test Example 1]
The tastes of the vitamin E-containing compositions (Examples 1 to 4) obtained in Production Examples 1 to 4 and the vitamin E-containing composition (Control Product 1) obtained in Production Example 5 were evaluated by sensory tests. The test was conducted by a two-point comparison method, and the results were tested by a two-point comparison method (two-sided test) test table. The results are shown in Table 1.
〈官能試験の方法〉
２０℃の精製水にビタミンＥ含有組成物（実施品１）とビタミンＥ含有組成物（対照品１）をそれぞれ分散させて１質量％水溶液を作り、試験液とした。官能試験は１５名のパネルで行い、実施品１と対照品１の対の試験液から、風味についてより好ましい方を選択させた。ビタミンＥ含有組成物（実施品２〜４）についても実施品１と同様に試験した。
<Method of sensory test>
A vitamin E-containing composition (practical product 1) and a vitamin E-containing composition (control product 1) were each dispersed in purified water at 20 ° C. to prepare a 1% by mass aqueous solution, which was used as a test solution. The sensory test was conducted with a panel of 15 people, and the more preferred flavor was selected from the paired test solutions of Example 1 and Control 1. Vitamin E-containing compositions (Examples 2 to 4) were also tested in the same manner as Example 1.
［製造例６］
１）２００ｍＬ容ビーカーに茶抽出物（商品名：テアビゴ；ＤＳＭニュートリッシュンジャパン社製）０．０１を入れ、精製水２０ｇを加えて溶解し、水飴（商品名：ハローデックス；林原社製）１１０ｇを入れ６０℃に加温する。
２）Ｔ．Ｋホモミクサー（型式：ＭＡＲＫＩＩ；プライミクス社製）で低速で攪拌しながら、デカグリセリンモノステアレート（商品名：ＮＩＫＫＯＬ Ｄｅｃａｇｌｙｎ １−５０ＳＶ；日光ケミカルズ社製）１０ｇを加えて溶解し、水相とした。
３）抽出ビタミンＥ（商品名：理研Ｅオイル７０５；理研ビタミン社製）６０ｇを約６０℃まで加熱し、油相とした。
４）ＴＫホモミクサーで低速で撹拌しながら、上記２）の水相に上記３）の油相を徐々に加え、その後７０００ｒｐｍで１５分間攪拌して乳化し、ビタミンＥ含有組成物（実施品５）を得た。
[Production Example 6]
1) Put a tea extract (trade name: Theavigo; DSM Nutrish Japan Japan) 0.01 in a 200 mL beaker, dissolve with adding 20 g of purified water, and water syrup (trade name: Hellodex; Hayashibara) Add 110 g and warm to 60 ° C.
2) T.M. While stirring at a low speed with a K homomixer (model: MARKII; manufactured by Primix), 10 g of decaglycerin monostearate (trade name: NIKKOL Decaglyn 1-50SV; manufactured by Nikko Chemicals) was added and dissolved to obtain an aqueous phase.
3) 60 g of extracted vitamin E (trade name: Riken E Oil 705; manufactured by Riken Vitamin Co., Ltd.) was heated to about 60 ° C. to obtain an oil phase.
4) While stirring at a low speed with a TK homomixer, gradually add the oil phase of 3) above to the aqueous phase of 2) above, and then emulsify by stirring at 7000 rpm for 15 minutes to give a vitamin E-containing composition (Example 5) Got.
［製造例７］
製造例６の２）に記載されている茶抽出物（商品名：テアビゴ；ＤＳＭニュートリッシュンジャパン社製）０．０１ｇに替えて、茶抽出物（商品名：テアビゴ；ＤＭＳニュートリッシュンジャパン社製）０．０８ｇを使用する以外は製造例６と同様に実施し、ビタミンＥ含有組成物（実施品６）を得た。
[Production Example 7]
The tea extract (trade name: Theavigo; DMS Nutrish Japan) was replaced with 0.01 g of the tea extract described in Production Example 6-2) (trade name: Theavigo; manufactured by DSM Nutrish Japan). (Product made) Except using 0.08g, it implemented similarly to manufacture example 6 and obtained the vitamin-E containing composition (Example product 6).
［製造例８］
製造例６の２）に記載されている茶抽出物（商品名：テアビゴ；ＤＳＭニュートリッシュンジャパン社製）０．０１ｇに替えて、茶抽出物（商品名：テアビゴ；ＤＭＳニュートリッシュンジャパン社製）０．６ｇを使用する以外は製造例６と同様に実施し、ビタミンＥ含有組成物（実施品７）を得た。
[Production Example 8]
The tea extract (trade name: Theavigo; DMS Nutrish Japan) was replaced with 0.01 g of the tea extract described in Production Example 6-2) (trade name: Theavigo; manufactured by DSM Nutrish Japan). (Product made) Except using 0.6g, it implemented similarly to manufacture example 6 and obtained the vitamin-E containing composition (Example product 7).
［製造例９］
製造例６の２）に記載されている茶抽出物（商品名：テアビゴ；ＤＳＭニュートリッシュンジャパン社製）０．０１ｇを使用しない以外は製造例６と同様に実施し、ビタミンＥ含有組成物（対照品２）を得た。
[Production Example 9]
A vitamin E-containing composition was carried out in the same manner as in Production Example 6 except that 0.01 g of the tea extract described in Production Example 6-2) (trade name: Theavigo; DSM Nutrish Japan) was not used. (Control product 2) was obtained.
［試験例２］
製造例６〜８で得たビタミンＥ含有組成物（実施品５〜７）と製造例９で得たビタミンＥ含有組成物（対照品２）の風味を官能試験で評価した。試験は２点比較法で行い、その結果について２点比較法（両側検定）検定表で検定した。結果を表２に示した。
[Test Example 2]
The flavors of the vitamin E-containing compositions (Examples 5 to 7) obtained in Production Examples 6 to 8 and the vitamin E-containing composition (Control Product 2) obtained in Production Example 9 were evaluated by a sensory test. The test was conducted by a two-point comparison method, and the results were tested by a two-point comparison method (two-sided test) test table. The results are shown in Table 2.
〈官能試験の方法〉
２０℃の精製水にビタミンＥ含有組成物（実施品５）とビタミンＥ含有組成物（対照品２）をそれぞれ分散させて１質量％水溶液を作り、試験液とした。官能試験は１５名のパネルで行い、実施品５と対照品２の対の試験液から、風味についてより好ましい方を選択させた。ビタミンＥ含有組成物（実施品６、７）についても実施品５と同様に試験した。
<Method of sensory test>
A vitamin E-containing composition (Example 5) and a vitamin E-containing composition (Control 2) were each dispersed in purified water at 20 ° C. to prepare a 1% by mass aqueous solution, which was used as a test solution. The sensory test was carried out by a panel of 15 people, and the more preferred flavor was selected from the paired test solutions of Example Product 5 and Control Product 2. The vitamin E-containing compositions (Examples 6 and 7) were also tested in the same manner as Example 5.
［製造例１０］
１）５Ｌ容ステンレス製ビーカーに茶抽出物（商品名：ポリフェノン７０Ａ；三井農林社製）０．５ｇを入れ、精製水１８５０ｍＬを加えて溶解し、澱粉分解物（商品名：パインデックス＃２；松谷化学工業社製）４９６ｇを入れ８０℃に加温する。
２）ＴＫホモミクサー（型式：ＭＡＲＫ２．５；プライミクス社製）で低速で攪拌しながら、アラビアガム（商品名：クイックガム＃８０２９；クレオ・インターナショナル社製）２００ｇを加えて溶解し、更にグリセリンモノパルミテート（商品名：エマルジーＰ−１００；理研ビタミン社製）１ｇ、ソルビタンモノステアレート（商品名：ポエムＳ−６０Ｖ；理研ビタミン社製）３ｇを加えて溶解し、水相とした。
３）抽出ビタミンＥ（製品名：理研Ｅオイル８０５；理研ビタミン社製，総トコフェロール含量約８０質量％以上，ｄ−α−トコフェロール含有量約４０質量％以上）３００ｇを約８０℃まで加熱し、油相とした。
４）ＴＫホモミクサーで７０００ｒｐｍで撹拌しながら、上記２）の水相に上記３）の油相を徐々に加え、その後１００００ｒｐｍで１５分間攪拌・乳化し、得られた乳化液を更にＡＰＶゴーリンホモジナイザー（型式：ＬＡＢ１０００；ＡＰＶ社製）にて３４．３ＭＰａで１回処理し、均質化液を得た。
５）上記４）の均質化液を、加圧ノズル式噴霧乾燥装置（型式：Ｌ−８ｉ；大川原化工機社）にて、熱風入口温度１７０℃、排気温度８０℃の条件下で噴霧乾燥し、乾燥物をサイクロンで捕集することにより粉末状ビタミンＥ製剤（実施品８）を約８８０ｇ得た。得られた粉末の乾燥減量は約４．３質量％であった。
[Production Example 10]
1) Put 0.5 g of tea extract (trade name: Polyphenon 70A; manufactured by Mitsui Norin Co., Ltd.) into a 5 L stainless steel beaker, add 1850 mL of purified water to dissolve, and dissolve starch (product name: Paindex # 2; 496 g (made by Matsutani Chemical Co., Ltd.) is added and heated to 80 ° C.
2) While stirring at low speed with a TK homomixer (model: MARK2.5; manufactured by Primix), 200 g of gum arabic (trade name: Quick Gum # 8029; manufactured by Creo International) was added and dissolved, and glycerin monopalmi 1 g of Tate (trade name: Emargy P-100; manufactured by Riken Vitamin Co., Ltd.) and 3 g of sorbitan monostearate (trade name: Poem S-60V; manufactured by Riken Vitamin Co., Ltd.) were added and dissolved to obtain an aqueous phase.
3) 300 g of extracted vitamin E (product name: Riken E Oil 805; manufactured by Riken Vitamin Co., Ltd., total tocopherol content of about 80% by mass or more, d-α-tocopherol content of about 40% by mass or more) is heated to about 80 ° C. An oil phase was obtained.
4) While stirring at 7000 rpm with a TK homomixer, gradually add the oil phase of 3) above to the aqueous phase of 2) above, then stir and emulsify at 10000 rpm for 15 minutes. The resulting emulsion is further added to an APV gorin homogenizer ( (Model: LAB1000; manufactured by APV) was processed once at 34.3 MPa to obtain a homogenized liquid.
5) The homogenized liquid of the above 4) is spray-dried under the conditions of a hot air inlet temperature of 170 ° C. and an exhaust temperature of 80 ° C. in a pressure nozzle type spray drying device (model: L-8i; Okawara Chemical Co., Ltd.). The dried product was collected with a cyclone to obtain about 880 g of powdered vitamin E preparation (Example 8). The loss on drying of the obtained powder was about 4.3% by mass.
［製造例１１］
製造例１０の２）に記載されている茶抽出物（商品名：ポリフェノン７０Ａ；三井農林社製）０．５ｇに替えて、茶抽出物（商品名：テアビゴ；ＤＳＭニュートリッシュンジャパン社製）０．５ｇを使用する以外は製造例１０と同様に実施し、粉末状ビタミンＥ含有組成物（実施品９）を得た。
[Production Example 11]
Instead of 0.5 g of the tea extract described in Production Example 10 2) (trade name: Polyphenon 70A; manufactured by Mitsui Norin), tea extract (trade name: Theavigo; manufactured by DSM Nutrish Japan) Except having used 0.5g, it implemented similarly to manufacture example 10, and obtained the powdery vitamin E containing composition (Example product 9).
［製造例１２］
製造例１０の２）に記載されている茶抽出物（商品名：ポリフェノン７０Ａ；三井農林社製）０．５ｇを使用しない以外は製造例１０と同様に実施し、粉末状ビタミンＥ含有組成物（対照品３）を得た。
[Production Example 12]
A powdered vitamin E-containing composition was carried out in the same manner as in Production Example 10 except that 0.5 g of the tea extract (trade name: Polyphenone 70A; manufactured by Mitsui Norin Co., Ltd.) described in 2) of Production Example 10 was not used. (Control 3) was obtained.
［試験例３］
製造例１０〜１１で得たビタミンＥ含有組成物（実施品８、９）と製造例１２で得たビタミンＥ含有組成物（対照品３）の風味を官能試験で評価した。試験は２点比較法で行い、その結果について２点比較法（両側検定）検定表で検定した。結果を表３に示した。
[Test Example 3]
The flavors of the vitamin E-containing compositions obtained in Production Examples 10 to 11 (Examples 8 and 9) and the vitamin E-containing composition obtained in Production Example 12 (Control 3) were evaluated by sensory tests. The test was conducted by a two-point comparison method, and the results were tested by a two-point comparison method (two-sided test) test table. The results are shown in Table 3.
〈官能試験の方法〉
２０℃の精製水にビタミンＥ含有組成物（実施品８）とビタミンＥ含有組成物（対照品３）をそれぞれ分散させて１質量％水溶液を作り、試験液とした。官能試験は１５名のパネルで行い、実施品８と対照品３の対の試験液から、風味についてより好ましい方を選択させた。ビタミンＥ含有組成物（実施品９）についても実施品８と同様に試験した。
<Method of sensory test>
A vitamin E-containing composition (Example 8) and a vitamin E-containing composition (Control 3) were each dispersed in purified water at 20 ° C. to prepare a 1% by mass aqueous solution, which was used as a test solution. The sensory test was carried out by a panel of 15 people, and the more preferred flavor was selected from the paired test solutions of Example Product 8 and Control Product 3. The vitamin E-containing composition (Example 9) was also tested in the same manner as Example 8.
［試験例４］
製造例６〜８で得たビタミンＥ含有組成物（実施品５〜７）と製造例９で得たビタミンＥ含有組成物（対照品２）を加工乳に添加し、その風味を官能試験で評価した。試験は２点比較法で行い、その結果について２点比較法（両側検定）検定表で検定した。結果を表４に示した。
[Test Example 4]
Vitamin E-containing compositions obtained in Production Examples 6 to 8 (Examples 5 to 7) and Vitamin E-containing compositions obtained in Production Example 9 (Control 2) were added to processed milk, and the flavor was determined by a sensory test. evaluated. The test was conducted by a two-point comparison method, and the results were tested by a two-point comparison method (two-sided test) test table. The results are shown in Table 4.
〈官能試験の方法〉
低脂肪乳（榛名酪農業協同組合連合会製）２００ｍＬを軽く攪拌しながら４０℃に温めた中にビタミンＥ含有組成物（実施品５）とビタミンＥ含有組成物（対照品２）をそれぞれ０．１２ｇ加えて均一に分散させ、試験液とした。官能試験は１５名のパネルで行い、実施品５と対照品２の対の試験液から、風味についてより好ましい方を選択させた。ビタミンＥ含有組成物（実施品６、７）についても実施品５と同様に試験した。
<Method of sensory test>
Vitamin E-containing composition (practical product 5) and vitamin E-containing composition (control product 2) are each 0 in 200 ml of low-fat milk (manufactured by Haruna Dairy Agricultural Cooperative Association) while warming to 40 ° C while stirring gently. .12 g was added and dispersed uniformly to prepare a test solution. The sensory test was carried out by a panel of 15 people, and the more preferred flavor was selected from the paired test solutions of Example Product 5 and Control Product 2. The vitamin E-containing compositions (Examples 6 and 7) were also tested in the same manner as Example 5.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105707856A (en) * | 2016-02-02 | 2016-06-29 | 福建省农业科学院农业工程技术研究所 | Prunus salicina fruit extract microcapsules capable of restraining xanthine oxidase and preparation method of prunus salicina fruit extract microcapsules |
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| CN105707856B (en) * | 2016-02-02 | 2018-06-22 | 福建省农业科学院农业工程技术研究所 | With Lee's berry extract microcapsules for inhibiting xanthine oxidase and preparation method thereof |
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