JP2007051167A - Transparent gel-like detergent composition - Google Patents
Transparent gel-like detergent composition Download PDFInfo
- Publication number
- JP2007051167A JP2007051167A JP2005235041A JP2005235041A JP2007051167A JP 2007051167 A JP2007051167 A JP 2007051167A JP 2005235041 A JP2005235041 A JP 2005235041A JP 2005235041 A JP2005235041 A JP 2005235041A JP 2007051167 A JP2007051167 A JP 2007051167A
- Authority
- JP
- Japan
- Prior art keywords
- mass
- manufactured
- fatty acid
- acid
- transparent gel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 239000003599 detergent Substances 0.000 title claims abstract description 19
- 229940096992 potassium oleate Drugs 0.000 claims abstract description 10
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 claims abstract description 10
- NGNZTXNWCGRXKL-UHFFFAOYSA-M potassium;16-methylheptadecanoate Chemical compound [K+].CC(C)CCCCCCCCCCCCCCC([O-])=O NGNZTXNWCGRXKL-UHFFFAOYSA-M 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 38
- 239000000194 fatty acid Substances 0.000 claims description 38
- 229930195729 fatty acid Natural products 0.000 claims description 38
- 150000004665 fatty acids Chemical class 0.000 claims description 29
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- 238000004140 cleaning Methods 0.000 claims description 15
- 239000002736 nonionic surfactant Substances 0.000 claims description 6
- -1 alkyl ether sulfates Chemical class 0.000 description 42
- 239000000284 extract Substances 0.000 description 22
- 229920001451 polypropylene glycol Polymers 0.000 description 20
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 18
- 238000005187 foaming Methods 0.000 description 16
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 16
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 12
- 239000006260 foam Substances 0.000 description 12
- 238000002156 mixing Methods 0.000 description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 10
- 239000000344 soap Substances 0.000 description 10
- 229910052708 sodium Inorganic materials 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 239000004094 surface-active agent Substances 0.000 description 9
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 8
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 8
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- 239000005642 Oleic acid Substances 0.000 description 8
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 8
- 239000002280 amphoteric surfactant Substances 0.000 description 8
- 229960003237 betaine Drugs 0.000 description 8
- 235000019864 coconut oil Nutrition 0.000 description 8
- 239000003240 coconut oil Substances 0.000 description 8
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 8
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 8
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 8
- 239000012459 cleaning agent Substances 0.000 description 7
- 235000011187 glycerol Nutrition 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- 238000006386 neutralization reaction Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 5
- 229940024606 amino acid Drugs 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 4
- 235000005979 Citrus limon Nutrition 0.000 description 4
- 244000131522 Citrus pyriformis Species 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 4
- 235000021360 Myristic acid Nutrition 0.000 description 4
- 235000019482 Palm oil Nutrition 0.000 description 4
- 244000288377 Saxifraga stolonifera Species 0.000 description 4
- 235000002953 Saxifraga stolonifera Nutrition 0.000 description 4
- 150000001413 amino acids Chemical class 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000002540 palm oil Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000004166 Lanolin Chemical class 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 3
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229940039717 lanolin Drugs 0.000 description 3
- 235000019388 lanolin Nutrition 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 3
- 235000010378 sodium ascorbate Nutrition 0.000 description 3
- 229960005055 sodium ascorbate Drugs 0.000 description 3
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 3
- UDZAXLGLNUMCRX-KHPPLWFESA-N (z)-n-(2-hydroxypropyl)octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCC(C)O UDZAXLGLNUMCRX-KHPPLWFESA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 2
- 241000282320 Panthera leo Species 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 244000044822 Simmondsia californica Species 0.000 description 2
- 235000004433 Simmondsia californica Nutrition 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 244000250129 Trigonella foenum graecum Species 0.000 description 2
- 235000001484 Trigonella foenum graecum Nutrition 0.000 description 2
- 229920006322 acrylamide copolymer Polymers 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- JIATYBYHEXWFRC-UHFFFAOYSA-L calcium;silver;(4-aminophenyl)sulfonyl-(5-methoxypyrimidin-2-yl)azanide;3-[(2,4-dihydroxy-3,3-dimethylbutanoyl)amino]propanoate Chemical compound [Ca+2].[Ag+].OCC(C)(C)C(O)C(=O)NCCC([O-])=O.OCC(C)(C)C(O)C(=O)NCCC([O-])=O.N1=CC(OC)=CN=C1[N-]S(=O)(=O)C1=CC=C(N)C=C1 JIATYBYHEXWFRC-UHFFFAOYSA-L 0.000 description 2
- 229940008396 carrot extract Drugs 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical class C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010642 eucalyptus oil Substances 0.000 description 2
- 229940044949 eucalyptus oil Drugs 0.000 description 2
- 230000001815 facial effect Effects 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- 210000004209 hair Anatomy 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical class CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 235000001019 trigonella foenum-graecum Nutrition 0.000 description 2
- OIFLLGNCLZLPAF-UHFFFAOYSA-M trimethyl-(5-methyl-4-oxohex-5-enyl)azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)CCC[N+](C)(C)C OIFLLGNCLZLPAF-UHFFFAOYSA-M 0.000 description 2
- 229960004418 trolamine Drugs 0.000 description 2
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- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- LPMBTLLQQJBUOO-KTKRTIGZSA-N (z)-n,n-bis(2-hydroxyethyl)octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(CCO)CCO LPMBTLLQQJBUOO-KTKRTIGZSA-N 0.000 description 1
- IFBDFMPSOCGRKA-UHFFFAOYSA-N 1-octadecoxyoctadecane;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC IFBDFMPSOCGRKA-UHFFFAOYSA-N 0.000 description 1
- IDYLOZGOBLTKMM-UHFFFAOYSA-N 14-(14-hydroxytetradecoxy)tetradecan-1-ol Chemical compound OCCCCCCCCCCCCCCOCCCCCCCCCCCCCCO IDYLOZGOBLTKMM-UHFFFAOYSA-N 0.000 description 1
- DORBKQIZZTWKOR-UHFFFAOYSA-N 2-(2-oxotridecylamino)ethanesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)CNCCS(O)(=O)=O DORBKQIZZTWKOR-UHFFFAOYSA-N 0.000 description 1
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
- AVBJHQDHVYGQLS-UHFFFAOYSA-N 2-(dodecanoylamino)pentanedioic acid Chemical compound CCCCCCCCCCCC(=O)NC(C(O)=O)CCC(O)=O AVBJHQDHVYGQLS-UHFFFAOYSA-N 0.000 description 1
- CMBPVDNWGJSARK-UHFFFAOYSA-N 2-[1-(2-hydroxyethyl)-2-undecylimidazol-1-ium-1-yl]acetate Chemical compound CCCCCCCCCCCC1=NC=C[N+]1(CCO)CC([O-])=O CMBPVDNWGJSARK-UHFFFAOYSA-N 0.000 description 1
- YPDCDBRKWQYBPV-UHFFFAOYSA-N 2-[2-(dodecanoylamino)ethyl-(2-hydroxyethyl)amino]acetic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)NCCN(CCO)CC(O)=O YPDCDBRKWQYBPV-UHFFFAOYSA-N 0.000 description 1
- RZRILSWMGXWSJY-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;sulfuric acid Chemical compound OS(O)(=O)=O.OCCN(CCO)CCO RZRILSWMGXWSJY-UHFFFAOYSA-N 0.000 description 1
- ZCOLQXXFCPFSNU-UHFFFAOYSA-N 2-[methyl(tetradecanoyl)amino]ethanesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCCCC(=O)N(C)CCS(O)(=O)=O ZCOLQXXFCPFSNU-UHFFFAOYSA-N 0.000 description 1
- KTCCLEVCNRHWQL-UHFFFAOYSA-N 3-(2-oxotridecylamino)propanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)CNCCC(O)=O KTCCLEVCNRHWQL-UHFFFAOYSA-N 0.000 description 1
- SUOYMAAKYJKLCS-UHFFFAOYSA-N 3-(dodecanoylamino)propanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)NCCC(O)=O SUOYMAAKYJKLCS-UHFFFAOYSA-N 0.000 description 1
- NBDYSLCMCUDINP-UHFFFAOYSA-N 3-[dodecanoyl(methyl)amino]propanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)N(C)CCC(O)=O NBDYSLCMCUDINP-UHFFFAOYSA-N 0.000 description 1
- LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 description 1
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- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 235000012907 honey Nutrition 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 1
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- 239000010501 lemon oil Substances 0.000 description 1
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- 239000001627 myristica fragrans houtt. fruit oil Substances 0.000 description 1
- XGZOMURMPLSSKQ-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)N(CCO)CCO XGZOMURMPLSSKQ-UHFFFAOYSA-N 0.000 description 1
- SKDZEPBJPGSFHS-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)tetradecanamide Chemical compound CCCCCCCCCCCCCC(=O)N(CCO)CCO SKDZEPBJPGSFHS-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Chemical class CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- BOWVQLFMWHZBEF-KTKRTIGZSA-N oleoyl ethanolamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCO BOWVQLFMWHZBEF-KTKRTIGZSA-N 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
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- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 1
- 229940116985 potassium lauryl sulfate Drugs 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
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- 239000003531 protein hydrolysate Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 235000019719 rose oil Nutrition 0.000 description 1
- 239000010668 rosemary oil Substances 0.000 description 1
- 229940058206 rosemary oil Drugs 0.000 description 1
- 239000010670 sage oil Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 229940080237 sodium caseinate Drugs 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- KAEULCNPLNQDNI-UHFFFAOYSA-N sodium;dodecylazanide Chemical compound [Na+].CCCCCCCCCCCC[NH-] KAEULCNPLNQDNI-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
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- 235000019721 spearmint oil Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 229940099373 sudan iii Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000000213 tara gum Substances 0.000 description 1
- 235000010491 tara gum Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010678 thyme oil Substances 0.000 description 1
- 229940080117 triethanolamine sulfate Drugs 0.000 description 1
- VLJXNZIHIIROLJ-UHFFFAOYSA-N trimethyl-(5-methyl-4-oxohex-5-enyl)azanium Chemical class CC(=C)C(=O)CCC[N+](C)(C)C VLJXNZIHIIROLJ-UHFFFAOYSA-N 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
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- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
本発明は、透明ゲル状洗浄剤組成物に関し、詳しくは、泡立ち、洗浄性、すすぎ易さに優れ、使用後に肌に適度なしっとり感を付与し、高温や低温に保存してもそのゲル状態を長期間維持できる透明で安定性の良好な洗浄剤組成物に関する。 The present invention relates to a transparent gel-like cleaning composition, and in particular, it is excellent in foaming, detergency, ease of rinsing, imparts a moderate moist feeling to the skin after use, and maintains its gel state even when stored at high or low temperatures The present invention relates to a clear and stable cleaning composition that can maintain the viscosity for a long time.
従来、皮膚洗浄料としては外観的に分類すると、固形、液状、ペースト状（ゲル状）に分類され、それぞれにおいて不透明なものと透明なものが開発されている。中でも、透明ゲル状の洗浄剤組成物は独特の高級感があり、商品価値及び市場性も高いと考えられる。 Conventionally, skin cleansing materials are classified into solid, liquid, and paste (gel) in terms of appearance, and opaque and transparent ones have been developed. Among them, the transparent gel detergent composition has a unique high-class feeling, and is considered to have high commercial value and marketability.
透明ゲル状組成洗浄剤における公知の技術としては、アルキル硫酸塩やアルキルエーテル硫酸塩といった界面活性剤と高分子や膨潤性の粘土鉱物の組み合わせがあるが、洗浄時やすすぎ時にぬるぬるした特異な触感を有しており、消費者、特に日本人に好まれないという問題があった。また、アミノ酸系の界面活性剤を主成分とした透明ゲル状洗浄剤も知られている（特許文献１，２，３参照）が、この透明ゲル状洗浄剤の場合、比較的界面活性剤分が多量に必要であるうえ、アミノ酸系の界面活性剤は高価であるため汎用の洗浄剤としての使用には適さない。 Known techniques for transparent gel composition detergents include combinations of surfactants such as alkyl sulfates and alkyl ether sulfates with polymers and swellable clay minerals. There is a problem that it is not preferred by consumers, especially Japanese. In addition, a transparent gel-like cleaning agent containing an amino acid-based surfactant as a main component is also known (see Patent Documents 1, 2, and 3). In addition, amino acid-based surfactants are expensive and are not suitable for use as general-purpose cleaning agents.
また、安価で安全な原料である脂肪酸塩を用いた透明ゲル状洗浄剤も多く提案されてきている。脂肪酸塩を使用する透明ゲル状洗浄剤は、脂肪酸のクラフト点が高いため低温及び高温の安定性に劣る場合が多く、カウンターイオンに工夫を凝らしたり、脂肪酸塩の溶解度を上げる外相に多価アルコールや脂肪酸アルカノールアミド型非イオン性界面活性剤、ヒドロキシ多価アルコールエーテル化合物等を使用するなどの提案が為されている（特許文献４，５，６，７，８，９参照）。一方、脂肪酸塩を主成分とした洗浄剤組成物では、洗浄後の乾燥に伴って肌のツッパリ感やチクチクとしたスティンギング感があり、これらを低減する方法として、両性界面活性剤や半極性界面活性剤を配合する技術が開示されている（特許文献１０，１１参照）。これらの文献では、特定の構造を有する半極性界面活性剤を配合することによりこれらの問題を解決としているが、両性及び半極性界面活性剤の併用は少なからず石鹸特有のさっぱり感が損なわれる使用感を有するため、ヌメリ感の増加となり必ずしも満足できるものではなかった。 Many transparent gel detergents using fatty acid salts which are inexpensive and safe raw materials have been proposed. Transparent gel detergents that use fatty acid salts are often poor in stability at low and high temperatures due to the high crafting point of fatty acids. And proposals have been made such as using fatty acid alkanolamide type nonionic surfactants, hydroxy polyhydric alcohol ether compounds, and the like (see Patent Documents 4, 5, 6, 7, 8, 9). On the other hand, the detergent composition mainly composed of fatty acid salt has a feeling of skin tingling and tingling as it dries after washing. As a method for reducing these, amphoteric surfactants and semipolar A technique of blending a surfactant is disclosed (see Patent Documents 10 and 11). In these documents, these problems are solved by blending a semipolar surfactant having a specific structure, but the combined use of amphoteric and semipolar surfactants is not limited to use, and the refreshing feeling peculiar to soap is impaired. Since it has a feeling, the feeling of slime is increased and it is not always satisfactory.
上記事情において、本発明の目的とするところは、泡立ち、洗浄性、すすぎ易さに優れ、使用後に肌に適度なしっとり感を付与し、高温や低温に保存してもそのゲル状態を長期間維持できる透明な安定性に優れた透明ゲル状洗浄剤組成物を提供することにある。 In the above circumstances, the object of the present invention is excellent in foaming, detergency, and ease of rinsing, imparts a moderate moist feeling to the skin after use, and maintains its gel state for a long time even when stored at high or low temperatures. An object of the present invention is to provide a transparent gel-like cleaning composition that can be maintained and has excellent transparent stability.
本発明者は、本発明の目的を達成するために鋭意研究した結果、後述の洗浄剤の主成分としてオレイン酸カリウムとイソステアリン酸カリウムを用いることによって、皮脂を取りすぎず、皮膚に悪影響がなく、使用後に肌に適度なしっとり感を付与し、脂肪酸石鹸特有の泡立ち、洗浄性、すすぎ易さに優れかつ、オレイン酸及びイソステアリン酸のクラフト点が低いため低温でも安定な透明ゲル状洗浄剤組成物の開発に成功した。更に、オレイン酸カリウムとイソステアリン酸カリウムを特定の質量比で配合することにより、高温でも安定に、そのゲル状態を長期間維持できることを見出し、本発明を完成した。 As a result of earnest research to achieve the object of the present invention, the present inventor did not take too much sebum and had no adverse effect on the skin by using potassium oleate and potassium isostearate as the main components of the cleaning agent described later. A transparent gel detergent composition that gives a moderate moist feeling to the skin after use, is excellent in foaming, cleanability and ease of rinsing that are characteristic of fatty acid soap, and is stable even at low temperatures due to the low Kraft point of oleic acid and isostearic acid The product was successfully developed. Furthermore, the present inventors have found that by adding potassium oleate and potassium isostearate at a specific mass ratio, the gel state can be maintained stably for a long period of time even at a high temperature, and the present invention has been completed.
すなわち、本発明はオレイン酸カリウムとイソステアリン酸カリウムとを含み、その合計が５〜５０質量％、さらに水を含むことを特徴とする透明ゲル状洗浄剤組成物にある。また、本発明は、オレイン酸カリウム：イソステアリン酸カリウム＝３：１〜１：３（質量比）であることを特徴とする前記透明ゲル状洗浄剤組成物にある。さらに本発明は、更に、グリセリンを１〜４０質量％を含むことを特徴とする、前述の透明ゲル状洗浄剤組成物である。また、本発明は、更に、脂肪酸アルカノールアミド型非イオン性界面活性剤０．１〜１０質量％含むことを特徴とする前記いずれかの透明ゲル状洗浄剤組成物にある。 That is, this invention exists in the transparent gel-like cleaning composition characterized by including potassium oleate and potassium isostearate, the sum total is 5-50 mass%, and also contains water. Moreover, this invention exists in the said transparent gel-like cleaning composition characterized by being potassium oleate: potassium isostearate = 3: 1 to 1: 3 (mass ratio). Furthermore, this invention is the above-mentioned transparent gel-like cleaning composition characterized by including 1-40 mass% of glycerol further. Further, the present invention resides in any one of the above-described transparent gel detergent compositions, further comprising 0.1 to 10% by mass of a fatty acid alkanolamide type nonionic surfactant.
本発明によって、泡立ち、洗浄性、すすぎ易さに優れ、使用後に肌に適度なしっとり感を付与し、高温や低温に保存してもそのゲル状態を長期間維持できる安定性に優れた透明ゲル状洗浄剤組成物を提供することができる。 By this invention, it is excellent in foaming, detergency, ease of rinsing, imparts a moderate moist feeling to the skin after use, and has excellent stability that can maintain its gel state for a long time even when stored at high or low temperature A detergent composition can be provided.
以下、本発明の構成について詳述する。 Hereinafter, the configuration of the present invention will be described in detail.
本発明で用いられるオレイン酸またはイソステアリン酸のカリウム塩を調製するには、予め、オレイン酸またはイソステアリン酸をカリウムで中和した物を使用しても良いし、配合時にオレイン酸および／又はイソステアリン酸と水酸化カリウムとを別に添加して、配合系内で中和を行っても良い。また、脂肪酸１モルに対する中和当量は０．８〜１．５モル中和が望ましい。更に望ましくは、０．９〜１．２モル中和が望ましく、この中和当量が０．８を下回るとゲル組成物にはならず、１．５を超える中和を行うとゲルの形態が透明を保てない恐れがある。 In order to prepare the potassium salt of oleic acid or isostearic acid used in the present invention, a product obtained by neutralizing oleic acid or isostearic acid with potassium in advance may be used, or oleic acid and / or isostearic acid at the time of blending. And potassium hydroxide may be added separately, and neutralization may be performed in the blending system. Moreover, the neutralization equivalent with respect to 1 mol of fatty acids has desirable neutralization of 0.8-1.5 mol. More desirably, 0.9 to 1.2 molar neutralization is desirable, and when this neutralization equivalent is less than 0.8, the gel composition is not obtained, and when neutralization exceeding 1.5 is carried out, the gel form is reduced. There is a risk that it may not be transparent.
オレイン酸カリウムとイソステアリン酸カリウムは、本発明の最終洗浄剤組成物中に、合わせて５〜５０質量％配合することが必要であり、より好ましくは１０〜３０質量％である。５質量％未満になるような少ない配合量ではゲルの形態を取ることができず、５０質量％を超えると、製造中に高温で固化が起こり、部分的な結晶化が生じる等、透明性を
確保できないので好ましくない。
It is necessary that 5 to 50% by mass of potassium oleate and potassium isostearate are combined in the final detergent composition of the present invention, and more preferably 10 to 30% by mass. If the blending amount is less than 5% by mass, it cannot take the form of a gel. If it exceeds 50% by mass, solidification occurs at a high temperature during production, resulting in partial crystallization. It is not preferable because it cannot be secured.
また、オレイン酸カリウムとイソステアリン酸カリウムの質量比は、オレイン酸カリウム：イソステアリン酸カリウム＝３：１〜１：３であることが好ましい。この質量比で配合することにより、泡立ち、洗浄性、すすぎ易さといった官能特性が得られ、さらに高温及び、長期保存での安定性が良くなる。 The mass ratio of potassium oleate to potassium isostearate is preferably potassium oleate: potassium isostearate = 3: 1 to 1: 3. By blending at this mass ratio, sensory characteristics such as foaming, detergency and ease of rinsing are obtained, and stability at high temperatures and long-term storage is improved.
本発明で用いられるグリセリンは、本発明の最終組成物中に、１〜４０質量％配合することが好ましく、より好ましくは、５〜３０質量％である。グリセリンを配合することにより、脂肪酸塩の溶解度を上げることができ、さらに、しっとりした感触を付与することができるが、１質量％未満になるような少ない配合量では効果は得られず、４０質量％を超えると、最終組成物の泡立ちが悪くなる。 It is preferable that 1-40 mass% is mix | blended with the glycerin used by this invention in the final composition of this invention, More preferably, it is 5-30 mass%. By blending glycerin, the solubility of the fatty acid salt can be increased, and a moist feel can be imparted, but the effect is not obtained with a small blending amount of less than 1% by mass, and 40% by mass. When it exceeds%, the foaming of the final composition is worsened.
本発明で用いられる脂肪酸アルカノールアミド型非イオン性界面活性剤は、ラウリン酸モノエタノールアミド、ラウリン酸ジエタノールアミド、ヤシ油脂肪酸モノエタノールアミド、ヤシ油脂肪酸ジエタノールアミド、ミリスチン酸モノエタノールアミド、ミリスチン酸ジエタノールアミド、ステアリン酸モノエタノールアミド、ステアリン酸ジエタノールアミド、オレイン酸モノエタノールアミド、オレイン酸ジエタノールアミド、牛脂ジエタノールアミド、ポリオキシプロピレン（１）ラウリン酸イソプロパノールアミド、ポリオキシプロピレン（１．５）ラウリン酸イソプロパノールアミド、ポリオキシプロピレン（２）ラウリン酸イソプロパノールアミド、ポリオキシプロピレン（５）ラウリン酸イソプロパノールアミド、ポリオキシプロピレン（１．５）ミリスチン酸イソプロパノールアミド、ポリオキシプロピレン（３）ミリスチン酸イソプロパノールアミド、ポリオキシプロピレン（２）オレイン酸イソプロパノールアミド、ポリオキシプロピレン（５）オレイン酸イソプロパノールアミド、ポリオキシプロピレン（０．８）ヤシ油脂肪酸イソプロパノールアミド、ポリオキシプロピレン（１）ヤシ油脂肪酸イソプロパノールアミド、ポリオキシプロピレン（１．４）ヤシ油脂肪酸イソプロパノールアミド、ポリオキシプロピレン（１．８）ヤシ油脂肪酸イソプロパノールアミド、ポリオキシプロピレン（１）パーム脂肪酸イソプロパノールアミド、ポリオキシプロピレン（１）パーム脂肪酸イソプロパノールアミド、ポリオキシプロピレン（２）パーム脂肪酸イソプロパノールアミド、ポリオキシプロピレン（５）パーム脂肪酸イソプロパノールアミドなどが挙げられ、これらを配合することにより、安定性を更に向上させることができる。 Fatty acid alkanolamide type nonionic surfactants used in the present invention are lauric acid monoethanolamide, lauric acid diethanolamide, coconut oil fatty acid monoethanolamide, coconut oil fatty acid diethanolamide, myristic acid monoethanolamide, myristic acid diethanolamide. Stearic acid monoethanolamide, stearic acid diethanolamide, oleic acid monoethanolamide, oleic acid diethanolamide, beef tallow diethanolamide, polyoxypropylene (1) lauric acid isopropanolamide, polyoxypropylene (1.5) lauric acid isopropanol Amide, polyoxypropylene (2) lauric acid isopropanolamide, polyoxypropylene (5) lauric acid isopropanolamide, polyoxy Propylene (1.5) myristic acid isopropanolamide, polyoxypropylene (3) myristic acid isopropanolamide, polyoxypropylene (2) oleic acid isopropanolamide, polyoxypropylene (5) oleic acid isopropanolamide, polyoxypropylene (0. 8) Coconut oil fatty acid isopropanolamide, polyoxypropylene (1) Coconut oil fatty acid isopropanolamide, Polyoxypropylene (1.4) Coconut oil fatty acid isopropanolamide, Polyoxypropylene (1.8) Coconut oil fatty acid isopropanolamide, Polyoxy Propylene (1) Palm fatty acid isopropanolamide, Polyoxypropylene (1) Palm fatty acid isopropanolamide, Polyoxypropylene (2) Palm fatty acid isopropanol Ropanoruamido, polyoxypropylene (5) palm fatty acid isopropanol amide and the like, by compounding them, it is possible to further improve the stability.
また、脂肪酸アルカノールアミド型非イオン性界面活性剤としては、ポリオキシプロピレンモノイソプロパノールアミド型非イオン性活性剤を配合することが好ましく、より好ましくは、ポリオキシプロピレンヤシ油脂肪酸モノイソプロパノールアミド（商品名：アミゼット１ＰＣ〔川研ファインケミカル社製〕）であることが安定性上望ましい。また、その配合量は、０．１〜１０質量％であり、更に望ましくは０．１〜３質量％である。０．１質量％未満になるような少ない量では充分な効果が得られず、１０質量％を超えると製造中の剤の流動性が損なわれるため、好ましくない。 Further, as the fatty acid alkanolamide type nonionic surfactant, it is preferable to blend a polyoxypropylene monoisopropanolamide type nonionic surfactant, more preferably polyoxypropylene coconut oil fatty acid monoisopropanolamide (trade name). : Amidette 1PC (manufactured by Kawaken Fine Chemical Co., Ltd.)) is desirable in terms of stability. Moreover, the compounding quantity is 0.1-10 mass%, More desirably, it is 0.1-3 mass%. If the amount is less than 0.1% by mass, a sufficient effect cannot be obtained, and if it exceeds 10% by mass, the fluidity of the agent during production is impaired.
本発明の透明ゲル状洗浄剤組成物には所望により、洗浄剤に一般に配合される成分、例えば、各種界面活性剤、水溶性高分子；植物油、高級アルコール、スクワラン、ラノリン、ラノリン誘導体、ポリエチレングリコールの脂肪酸エステル類等の油性成分、エチレングリコール、プロピレングリコール、１，３−ブタンジオール、ポリエチレングリコール等の保湿剤；ポリビニルアルコール、ポリビニルピロリドン、シリコーン等の被膜剤；シリコーン誘導体、蛋白誘導体、アミノ酸及びその塩類、ビタミン類、低級アルコール、糖類、酸化防止剤、殺菌剤、キレート剤、紫外線吸収剤、ｐＨ調整剤、動植物由来の天然エキス、生薬抽出物、色素、顔料及び香料等を適宜配合することができる。 The transparent gel detergent composition of the present invention optionally contains components generally incorporated into the detergent, such as various surfactants, water-soluble polymers; vegetable oils, higher alcohols, squalane, lanolin, lanolin derivatives, polyethylene glycols. Oily components such as fatty acid esters, humectants such as ethylene glycol, propylene glycol, 1,3-butanediol, and polyethylene glycol; coating agents such as polyvinyl alcohol, polyvinyl pyrrolidone, and silicone; silicone derivatives, protein derivatives, amino acids and their Salts, vitamins, lower alcohols, saccharides, antioxidants, bactericides, chelating agents, UV absorbers, pH adjusters, natural extracts derived from animals and plants, herbal extracts, pigments, pigments, and fragrances may be appropriately blended. it can.
その他の界面活性剤は、ノニオン性、アニオン性、カチオン性、両性、半極性のいずれでもよく、特にアニオン性界面活性剤、両性界面活性剤などが洗浄性、起泡性の面から好ましい。 Other surfactants may be any of nonionic, anionic, cationic, amphoteric, and semipolar, and anionic surfactants, amphoteric surfactants and the like are particularly preferable from the viewpoints of detergency and foaming properties.
好ましい界面活性剤の具体例としては、アニオン性界面活性剤として、高級アルキル硫酸エステル塩として、例えばラウリル硫酸ナトリウム、ラウリル硫酸カリウム、ラウリル硫酸トリエタノールアミン、アルキルエーテル硫酸エステル塩として、例えば、ＰＯＥラウリル硫酸トリエタノールアミン、ＰＯＥラウリル硫酸ナトリウム、Ｎ−アシルアミノ酸塩として、例えば、ラウロイルサルコシンナトリウム、ラウロイル−β−アラニンナトリウム、ラウロイル−Ｎ−メチル−β−アラニンナトリウム、Ｎ−ラウロイルグルタミン酸モノナトリウム、Ｎ−ステアロイルグルタミン酸ジナトリウム、Ｎ−ミリストイル−Ｌ−グルタミン酸モノナトリウム、Ｎ−パルミトイルアスパラギン酸ジエタノールアミン、ヤシ脂肪酸シルクペプチド、高級脂肪酸アミドスルホン酸塩として、例えばＮ−ミリストイル−Ｎ−メチルタウリンナトリウム、ヤシ脂肪酸メチルタウリンナトリウム、ラウロイルメチルタウリンナトリウム、リン酸エステル塩として、例えばＰＯＥオレイルエーテルリン酸ナトリウム、ＰＯＥステアリルエーテルリン酸、ＰＯＥラウリルアミドエーテルリン酸ナトリウム、スルホコハク酸塩として、例えばジ−２−エチルヘキシルスルホコハク酸ナトリウム、モノラウロイルモノエタノールアミドポリオキシエチレンスルホコハク酸ナトリウム、ラウリルポリプロピレングリコールスルホコハク酸ナトリウム、アルキルベンゼンスルホン酸塩として、例えばリニアドデシルベンゼンスルホン酸ナトリウム、リニアドデシルベンゼンスルホン酸トリエタノールアミン、リニアドデシルベンゼンスルホン酸、高級脂肪酸エステル硫酸エステル塩として、例えば硬化ヤシ油脂肪酸グリセリン硫酸ナトリウム、α−オレフィンスルホン酸塩、高級脂肪酸エステルスルホン酸塩、二級アルコール硫酸エステル塩、高級脂肪酸アルキロールアミド硫酸エステル塩として、例えばラウロイルモノエタノールアミドコハク酸ナトリウム、カゼインナトリウム等が挙げられる。また、８〜２２個の炭素原子を有する高級脂肪酸を、ナトリウム、カリウム等のアルカリ金属、及び／または、トリエタノールアミン等のアルカノールアミン、及び／またはアルギニン、リジン等の塩基性アミノ酸から選ばれる少なくとも一種以上で中和した水溶性脂肪酸塩等も挙げられ、これらは泡立ちや使用感の改善を目的に配合することができ、通常、最終組成物中に０．１〜５０質量％配合することが好ましい。 Specific examples of preferred surfactants include anionic surfactants, higher alkyl sulfate salts such as sodium lauryl sulfate, potassium lauryl sulfate, triethanolamine lauryl sulfate, alkyl ether sulfate salts such as POE lauryl. Examples of triethanolamine sulfate, sodium POE lauryl sulfate, and N-acyl amino acid salts include, for example, sodium lauroyl sarcosine, sodium lauroyl-β-alanine, sodium lauroyl-N-methyl-β-alanine, monosodium N-lauroyl glutamate, N- Stearoyl glutamate disodium, N-myristoyl-L-glutamate monosodium, N-palmitoyl aspartate diethanolamine, palm fatty acid silk peptide, higher fat Examples of fatty acid amide sulfonates include, for example, sodium N-myristoyl-N-methyltaurine, sodium coconut fatty acid methyltaurine, sodium lauroylmethyltaurine, and phosphoric acid ester salts such as sodium POE oleyl ether, POE stearyl ether phosphate, POE sodium lauryl amide ether phosphate, sulfosuccinate, for example, sodium di-2-ethylhexyl sulfosuccinate, sodium monolauroyl monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, alkyl benzene sulfonate, for example linear Sodium dodecylbenzenesulfonate, triethanolamine, linear dodecylbenzenesulfonate, lineardo Silbenzene sulfonic acid, higher fatty acid ester sulfate, for example, hydrogenated coconut oil fatty acid sodium glycerin sulfate, α-olefin sulfonate, higher fatty acid ester sulfonate, secondary alcohol sulfate, higher fatty acid alkylol amide sulfate Examples of the salt include sodium lauroyl monoethanolamide succinate, sodium caseinate and the like. Further, the higher fatty acid having 8 to 22 carbon atoms is at least selected from alkali metals such as sodium and potassium, and / or alkanolamines such as triethanolamine, and / or basic amino acids such as arginine and lysine. Examples thereof include water-soluble fatty acid salts neutralized with one or more kinds, and these can be blended for the purpose of improving foaming and feeling of use, and usually 0.1 to 50% by mass is blended in the final composition. preferable.
両性界面活性剤としては、例えば２−ウンデシル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリウムベタイン、Ｎ−ラウロイル−Ｎ’−カルボキシメチル−Ｎ’−ヒドロキシエチルエチレンジアミンナトリウム、Ｎ−ヤシ脂肪酸アシル−Ｎ’−カルボキシエチル−Ｎ’−ヒドロキシエチルエチレンジアミンナトリウム等のアミドアミン系両性界面活性剤、例えばヤシ脂肪酸アミドプロピルベタイン、ミリスチン酸アミドプロピルベタイン等のアミド酢酸ベタイン型両性界面活性剤、例えばラウリン酸アミドプロピルヒドロキシスルホベタイン等のアミドスルホベタイン型両性界面活性剤、アルキル酢酸ベタイン型両性界面活性剤、アルキルスルホベタイン型両性界面活性剤等が挙げられる。泡立ちや使用感の改善などを目的として一種または二種以上を適宜配合することができ、通常、最終組成物中に０．１〜５０質量％配合することが好ましい。 Examples of the amphoteric surfactant include 2-undecyl-N-carboxymethyl-N-hydroxyethylimidazolium betaine, N-lauroyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine sodium, N-coconut fatty acid acyl-N Amidoamine-based amphoteric surfactants such as' -carboxyethyl-N'-hydroxyethylethylenediamine sodium, for example, amidoacetic acid betaine-type amphoteric surfactants such as coconut fatty acid amidopropyl betaine, myristate amidopropyl betaine, such as amidopropyl hydroxy laurate Amidosulfobetaine-type amphoteric surfactants such as sulfobetaine, alkyl acetate betaine-type amphoteric surfactants, alkylsulfobetaine-type amphoteric surfactants, and the like. One or two or more kinds can be appropriately blended for the purpose of improving foaming and feeling of use, and usually 0.1 to 50% by mass is preferably blended in the final composition.
本発明で用いられる水溶性高分子は、特に限定されないが、カチオン価多糖類、例えばカチオン化セルロース（商品名：ポリマーＪＲ−４００［ＵＣＣ社製］、レオガードＧ［ライオン社製］、カチナールＨＣ−２００、カチナールＬＣ−２００［東邦化学工業社製］など）、カチオン化グアーガム（商品名：ジャガーＣ−１７及びＣ−１３−Ｓ［三晶社製］など）、カチオン化フェヌグリークガム（商品名：カチナールＣＦ−１００、カチナールＣＦ−２００［東邦化学工業社製］など）、カチオン化ローカストビーンガム（商品名：カチナールＣＬＢ−１００［東邦化学工業社製］など）、カチオン化タラガム（商品名：カチナールＣＴＲ−１００［東邦化学工業社製］など）。ジメチルジアリルアンモニ
ウム誘導ポリマー、例えば塩化ジメチルジアリルアンモニウム重合体（商品名：ＭＥＲＱＵＡＴ １００（ナルコ社製）など）、塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体（商品名：ＭＥＲＱＵＡＴ ５５０、２２００（ナルコ社製）など）、アクリル酸・塩化ジメチルジアリルアンモニウム共重合体（商品名：ＭＥＲＱＵＡＴ ２８０、２９５（ナルコ社製）など）、アクリルアミド・アクリル酸・塩化ジメチルジアリルアンモニウム共重合体（商品名：ＭＥＲＱＵＡＴ ＰＬＵＳ ３３３０、３３３１（ナルコ社製）など）。メタクリルプロピルトリメチルアンモニウム誘導ポリマー、例えばアクリル酸・塩化メタクリルプロピルトリメチルアンモニウム・メチルアクリレート共重合体（商品名：ＭＥＲＱＵＡＴ ２００１［ナルコ社製］など）が好ましく、一種または二種以上を組み合わせて用いることができる。
The water-soluble polymer used in the present invention is not particularly limited, but is a cation polysaccharide, such as cationized cellulose (trade name: Polymer JR-400 (manufactured by UCC), Leogard G (manufactured by Lion), Kachinal HC- 200, Katchinal LC-200 [manufactured by Toho Chemical Industry Co., Ltd.], etc.), cationized guar gum (trade names: Jaguar C-17 and C-13-S [manufactured by Sansho Co., Ltd.], etc.), cationized fenugreek gum (trade name: Catinal CF-100, Catinal CF-200 [manufactured by Toho Chemical Industry Co., Ltd.], cationized locust bean gum (trade name: Katchinal CLB-100 [manufactured by Toho Chemical Industry Co., Ltd.], etc.), cationized tara gum (trade name: Katinaral) CTR-100 [manufactured by Toho Chemical Industry Co., Ltd.]). Dimethyl diallylammonium derivative polymer, for example, dimethyl diallylammonium chloride polymer (trade name: MERQUAT 100 (manufactured by Nalco)), dimethyl diallylammonium chloride / acrylamide copolymer (trade name: MERQUAT 550, 2200 (manufactured by Narco), etc.) ), Acrylic acid / dimethyldiallylammonium chloride copolymer (trade name: MERQUAT 280, 295 (manufactured by Nalco)), acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer (trade name: MERQUAT PLUS 3330, 3331) Nalco)). A methacrylpropyltrimethylammonium derivative polymer, for example, acrylic acid / methacrylpropyltrimethylammonium chloride / methyl acrylate copolymer (trade name: MERQUAT 2001 [manufactured by Nalco Co., Ltd.], etc.) is preferable, and one or a combination of two or more can be used. .
本発明で用いられる植物油は、特に限定されないが、ローズ油、ローズマリー油、オレンジ油、ライム油、レモン油、ユズ油、グレープフルーツ油、マンダリン油、ベルガモット油、スペアミント油、ラベンダー油、ユーカリ油、セージ油、タイム油、バジル油、ナツメグ油など、最終組成物の原料臭を抑えるために芳香を有するものが特に好ましく、一種または二種以上を組み合わせて用いることができる。 The vegetable oil used in the present invention is not particularly limited, but rose oil, rosemary oil, orange oil, lime oil, lemon oil, yuzu oil, grapefruit oil, mandarin oil, bergamot oil, spearmint oil, lavender oil, eucalyptus oil, In order to suppress the raw material odor of the final composition, such as sage oil, thyme oil, basil oil, and nutmeg oil is particularly preferable, and one or a combination of two or more can be used.
また、本発明の洗浄剤組成物は、頭髪や身体各部の皮膚洗浄剤のいずれにも適用でき、ヘアシャンプー、ボディシャンプー、ハンドソープ、洗顔剤等の身体用洗浄剤として好適に使用できる。 Moreover, the cleaning composition of the present invention can be applied to any of the hair cleaning agents and the skin cleaning agents for various parts of the body, and can be suitably used as a body cleaning agent such as a hair shampoo, body shampoo, hand soap, and facial cleanser.
以下、本発明を実施例により具体的に説明するが、本発明はこれに限定されるものではない。実施例に先立ち、実施例で用いた評価法を説明する。 Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited thereto. Prior to the examples, the evaluation methods used in the examples will be described.
ａ）洗浄性試験法
５ｃｍ×５ｃｍのウールモスリン布にラノリン７％及びスダンＩＩＩ ０．００５％のクロロホルム溶液０．４ｍＬを均一に塗布し、乾燥させ、この汚染布を３％の洗浄剤溶液４０ｍＬが入った約１００ｍＬのガラス製シリンダー中に入れ、４０℃の恒温槽中で１５分間振盪し、汚染布を流水中でよく濯ぎ、乾燥させ、反射率を調べ、次式により洗浄率を求めた。
a) Detergency Test Method 0.4 mL of a 7% lanolin and 0.005% Sudan III chloroform solution was uniformly applied to a 5 cm × 5 cm wool muslin fabric, dried, and 40 mL of 3% detergent solution was applied to the contaminated fabric. Was placed in a glass cylinder of about 100 mL, shaken in a constant temperature bath at 40 ° C. for 15 minutes, the contaminated cloth was rinsed thoroughly in running water, dried, the reflectivity was examined, and the washing rate was obtained by the following formula. .
また、評価の基準を次のように設定した。
◎・・・洗浄性優秀 洗浄率８５％以上
○・・・洗浄性良好 洗浄率７０％以上８５％未満
△・・・洗浄性普通 洗浄率５５％以上７０％未満
×・・・洗浄性不良 洗浄率５５％未満
The evaluation criteria were set as follows.
◎ ・ ・ ・ Excellent detergency Cleaning rate 85% or more ○ ・ ・ ・ Good detergency Cleaning rate 70% or more and less than 85% △ ・ ・ ・ Normal detergency Detergency 55% or more and less than 70% Less than 55%
ｂ）使用感・仕上がり感試験法
パネル（３０人）が左右の腕に、一方にコントロールとして下記組成の身体用洗浄料を、他方に試料を用いてそれぞれ洗浄し、泡立ち、泡量及び泡質と、洗い流し時のヌルツキ、すすぎ易さ、タオルドライ後の、しっとり感、滑らか感等の仕上がり感を官能評価した。
b) Feeling of use / finish feeling test Panel (30 people) washes the left and right arms, one body with the following body cleansing agent as a control, and the other with a sample. Then, sensory evaluation was performed for the finish feeling such as the smoothness and smoothness after the towel was dried.
コントロール （質量％）
・ラウリン酸 １０．０
・ミリスチン酸 ５．０
・水酸化カリウム ４．０
・ポリオキシエチレン（３）ラウリルエーテル硫酸ナトリウム ７．０
・精製水 残 余
Control (mass%)
・ Lauric acid 10.0
・ Myristic acid 5.0
・ Potassium hydroxide 4.0
-Polyoxyethylene (3) sodium lauryl ether sulfate 7.0
・ Purified water residue
また、評価の基準を次のように設定した。
◎・・・コントロールより良いと答えた人数が１９名以上
○・・・コントロールより良いと答えた人数が１６〜１８名
△・・・コントロールより良いと答えた人数が８〜１５名
×・・・コントロールより良いと答えた人数が７名以下
The evaluation criteria were set as follows.
◎ ・ ・ ・ 19 or more respondents said that it is better than control ○ ・ ・ ・ 16 to 18 respondents said that it was better than control △ ・ ・ ・ 8 to 15 respondents said that it was better than control × ・ ・・ The number of people who answered that it is better than control is less than 7
ｃ）安定性試験
製造したサンプルをポスターカラー瓶に詰めて、密閉し、−５℃及び４５℃の恒温器に静置して、１ヵ月後にゲルの状態を目視観察して以下の基準で評価した。
◎・・・製造直後と変化なし
○・・・わずかに白濁しているが、室温に戻すと透明状態に戻る、又は、外観にわずかに着色を生じる。
△・・・白濁しているが、室温に戻すと透明ゲル状態に戻る、又は、わずかに離水が生じる。
×・・・白濁あるいは結晶化、又は分離、変臭を生じる、又は外観の着色が著しくなり、室温に戻しても状態が変化しない
c) Stability test The manufactured sample was packed in a poster color bottle, sealed, and left in a thermostatic chamber at -5 ° C and 45 ° C, and after 1 month, the gel state was visually observed and evaluated according to the following criteria. did.
◎ ・ ・ ・ No change immediately after production ○ ・ ・ ・ Slightly cloudy, but returns to room temperature or returns to a transparent state or slightly colored appearance.
Δ: Although cloudy, it returns to a transparent gel state when returned to room temperature, or water separation occurs slightly.
×: White turbidity or crystallization, separation, odor generation, or appearance coloration becomes significant, and the state does not change even after returning to room temperature
・実施例１〜５及び比較例１〜７
表１に記載の配合組成よりなる透明ゲル状洗浄剤を常法により調製し、泡立ち、泡量及び泡質と、洗い流し時のヌルツキ、すすぎ易さ、タオルドライ後の、しっとり感、滑らか感を評価し、その結果を表１に示した。
-Examples 1-5 and Comparative Examples 1-7
A transparent gel-like cleaning agent having the composition shown in Table 1 is prepared by a conventional method. Foaming, foam amount and foam quality, nulliness at rinsing, ease of rinsing, moist feeling after towel drying, smooth feeling The results are shown in Table 1.
表１より明らかなように、本発明の成分を用いた実施例１〜５の透明ゲル状洗浄剤は、泡立ち、泡量はコントロールに比べて、やや劣る〜同程度であったものの、洗浄性、泡質、洗い流し感、仕上がり感、安定性は優れた性能を示していた。 As is clear from Table 1, the transparent gel-like detergents of Examples 1 to 5 using the components of the present invention were foamed and the amount of foam was slightly inferior to that of the control, although it was about the same. The foam quality, feeling of washing, feeling of finish, and stability showed excellent performance.
一方、比較例１〜７では、洗浄性、泡立ち、泡量、泡質、洗い流し感、仕上がり感、安定性のいずれかの特性が劣っており、さらに比較例６、７ではゲル状にならず、本発明の目的を達成できなかった。 On the other hand, Comparative Examples 1 to 7 are inferior in any of the properties of detergency, foaming, foam amount, foam quality, feeling of washing, feeling of finishing, and finishing, and Comparative Examples 6 and 7 are not gelled. The object of the present invention could not be achieved.
実施例６（ボディソープ）
（質量％）
・オレイン酸 ９．０
・イソステアリン酸 ９．０
・グリセリン １０．０
・ＰＯＥ（３）ラウリルエーテル硫酸ナトリウム ５．０
・ラウリン酸アミドプロピルベタイン １．５
・ヤシ油脂肪酸ジエタノールアマイド １．０
・塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体液
（約９％）（商品名：ＭＥＲＱＵＡＴ ５５０；ナルコ社製） ０．５
・カチオン化フェヌグリークガム
（商品名：カチナールＣＦ−１００；東邦化学工業社製） ０．１
・ＰＯＥセトステアリルヒドロキシミリスチレンエーテル
（商品名：エルファコスＧＴ２８２Ｓ；ライオンアクゾ社製） ０．２
・加水分解コムギ液
（商品名：ＧＬＵＡＤＩＮ Ｗ−２０；コグニス社製） ０．５
・レモン果実抽出物（商品名：レモン抽出液ＢＧ［丸善製薬社製］） ０．１
・サボンソウ抽出物
（商品名：サボンソウ抽出液ＢＧ［丸善製薬社製」） ０．０５
・トウキンセンカ抽出物
（商品名：トウキンセンカ抽出液ＢＧ［丸善製薬社製］） ０．１
・ブドウ抽出物 ０．１
・ＥＤＴＡ ０．４
・水酸化カリウム 適 量
・アスコルビン酸ナトリウム ０．２
・ユーカリ油 ０．８
・水 バランス
Example 6 (Body soap)
(mass%)
・ Oleic acid 9.0
・ Isostearic acid 9.0
・ Glycerin 10.0
-POE (3) sodium lauryl ether sulfate 5.0
・ Lamidate amidopropyl betaine 1.5
・ Palm oil fatty acid diethanolamide 1.0
・ Dimethyldiallylammonium chloride-acrylamide copolymer solution
(About 9%) (Brand name: MERQUAT 550; manufactured by Nalco) 0.5
・ Cationized fenugreek gum
(Product name: Kachinar CF-100; manufactured by Toho Chemical Industry Co., Ltd.) 0.1
・ POE cetostearyl hydroxymyristyl ether
(Product name: Elfacos GT282S; manufactured by Lion Akzo) 0.2
・ Hydrolyzed wheat liquid
(Product name: GLUADIN W-20; manufactured by Cognis) 0.5
Lemon fruit extract (trade name: Lemon extract BG [manufactured by Maruzen Pharmaceutical Co., Ltd.]) 0.1
・ Soap extract
(Brand name: Savonso extract BG [Maruzen Pharmaceutical Co., Ltd.]) 0.05
・ Toukanka extract
(Brand name: Milky milk extract BG [Maruzen Pharmaceutical Co., Ltd.]) 0.1
・ Grape extract 0.1
・ EDTA 0.4
・ Potassium hydroxide appropriate amount ・ Sodium ascorbate 0.2
・ Eucalyptus oil 0.8
・ Water balance
上記成分を均一に混合して調製した上記組成のボディソープ（ｐＨ９．０）は、洗浄性、泡立ち、泡量、泡質、洗い流し感、仕上がり感のいずれにおいても、良好な結果を得た。 The body soap (pH 9.0) having the above composition prepared by uniformly mixing the above components gave good results in all of the cleaning properties, foaming, foam amount, foam quality, washing-off feeling, and finishing feeling.
実施例７（ボディソープ）
（質量％）
・オレイン酸 １８．０
・イソステアリン酸 ６．０
・グリセリン ２０．０
・ポリオキシエチレンラウリルエーテル酢酸ナトリウム ５．０
・ラウロイルメチル−β−アラニンナトリウム １．０
・Ｎ−ラウロイル−Ｎ−カルボキシメチル−Ｎ−
ヒドロキシエチルイミダゾリニウムベタイン液
（商品名：ソフタゾリンＣＬ［川研ファインケミカル社製］） １．０
・ラウリルジメチルアミノ酢酸ベタイン １．０
・ポリオキシプロピレンヤシ油脂肪酸モノイソプロパノールアミド １．０
・ＥＤＴＡ ０．４
・アスコルビン酸ナトリウム ０．２
・ダイズ蛋白加水分解物
（商品名：プロモイスＷＳ；成和化成社製） ０．１
・アクリル酸・塩化メタクリルプロピルトリメチルアンモニウム・
メチルアクリレート共重合体液（約２１％）
（商品名：ＭＥＲＱＵＡＴ ２００１；ナルコ社製） ０．５
・カチオン化ハチミツ誘導体
（商品名：ハニーコート５０［ＡＲＣＨ社製］） ０．１
・ウイキョウ抽出物（商品名：ＮＡＢ Ｆｅｎｎｅｌ
Ｓｅｅｄ Ｅｘｔｒａｃｔ［ＡＲＣＨ社製］） ０．１
・ガリカバラ抽出物（商品名：Ｐｈｙｔｏｆｌｅｕｒ
Ｆｒｅｎｃｈ Ｒｏｓｅ［ＣＲＯＤＡＲＯＭ社製］） ０．１
・トウキンセンカ抽出物（商品名：オーガニック
トウキンセンカ抽出液ＢＧ−５０［香栄興業社製］） ０．１
・ホホバ抽出物（商品名：ホホバリーフエキス［香栄興業社製］） ０．１
・ユキノシタ抽出物
（商品名：ユキノシタ抽出液ＢＧ［丸善製薬社製］） ０．１
・カギイバラノリ抽出物
（商品名：ＢＩＯＳＴＲＵＣＴＵＲＥＲ［ＳＥＣＭＡ社製］） ０．１
・水酸化カリウム 適 量
・香料 適 量
・水 バランス
Example 7 (body soap)
(mass%)
・ Oleic acid 18.0
-Isostearic acid 6.0
・ Glycerin 20.0
・ Polyoxyethylene lauryl ether sodium acetate 5.0
・ Lauroylmethyl-β-alanine sodium 1.0
N-lauroyl-N-carboxymethyl-N-
Hydroxyethyl imidazolinium betaine solution
(Product name: Softazolin CL [manufactured by Kawaken Fine Chemicals Co., Ltd.]) 1.0
・ Lauryldimethylaminoacetic acid betaine 1.0
・ Polyoxypropylene palm oil fatty acid monoisopropanolamide 1.0
・ EDTA 0.4
・ Sodium ascorbate 0.2
・ Soybean protein hydrolyzate
(Product name: Promois WS; Seiwa Kasei Co., Ltd.) 0.1
Acrylic acid, methacrylpropyltrimethylammonium chloride,
Methyl acrylate copolymer liquid (about 21%)
(Product name: MERQUAT 2001; manufactured by Nalco) 0.5
・ Cationized honey derivatives
(Product name: Honeycoat 50 [manufactured by ARCH)] 0.1
-Fennel extract (trade name: NAB Fennel
Seed Extract [manufactured by ARCH]] 0.1
・ Galika rose extract (trade name: Phytofullur
French Rose [manufactured by CRODAROM] 0.1
・ Toukanka extract (trade name: Organic
Tokinkinka extract BG-50 [manufactured by Koei Kogyo Co., Ltd.]) 0.1
Jojoba extract (trade name: jojoba leaf extract [manufactured by Koei Kogyo Co., Ltd.]) 0.1
・ Yukinoshita extract
(Product name: Yukinoshita Extract BG [Maruzen Pharmaceutical Co., Ltd.]) 0.1
・ Kagii Baranori Extract
(Product name: BIOSTRUCTURER [manufactured by SECMA]) 0.1
・ Potassium hydroxide appropriate amount / fragrance appropriate amount / water balance
上記成分を均一に混合して調製した上記組成のボディソープ（ｐＨ９．５）は、洗浄性、泡立ち、泡量、泡質、洗い流し感、仕上がり感のいずれにおいても、良好な結果を得た。 A body soap (pH 9.5) having the above composition prepared by uniformly mixing the above components gave good results in all of the cleaning properties, foaming, foam amount, foam quality, washing-off feeling, and finishing feeling.
実施例８（ハンドソープ）
（質量％）
・オレイン酸 ７．０
・イソステアリン酸 ６．０
・ＰＯＥ（２）ラウリルエーテル硫酸ナトリウム ８．０
・パーム核油脂肪酸アミドプロピルベタイン ２．５
・カチオン化セルロース
（商品名：カチナールＬＣ−２００；東邦化学工業社製） ０．３
・レモンエキス
（商品名：レモン抽出液ＢＧ；丸善製薬社製） ０．２
・ニンジンエキス
（商品名：ニンジン抽出液ＢＧ；丸善製薬社製） ０．２
・加水分解シルク液
（商品名：プロモイスシルク−１０００；成和化成社製） １．０
・グリセリン ５．０
・１，３−ブチレングリコール ５．０
・ＥＤＴＡ ０．３
・亜硫酸ナトリウム ０．２
・水酸化カリウム 適 量
・香料 適 量
・水 バランス
Example 8 (hand soap)
(mass%)
・ Oleic acid 7.0
-Isostearic acid 6.0
-POE (2) sodium lauryl ether sulfate 8.0
Palm oil fatty acid amidopropyl betaine 2.5
・ Cationized cellulose
(Product name: Kachinar LC-200; manufactured by Toho Chemical Industry Co., Ltd.) 0.3
・ Lemon extract
(Product name: Lemon extract BG; manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.2
・ Carrot extract
(Product name: carrot extract BG; manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.2
・ Hydrolysis silk solution
(Product name: Promois Silk-1000; manufactured by Seiwa Kasei Co., Ltd.) 1.0
・ Glycerin 5.0
1,3-butylene glycol 5.0
・ EDTA 0.3
・ Sodium sulfite 0.2
・ Potassium hydroxide appropriate amount / fragrance appropriate amount / water balance
上記成分を均一に混合して調製した上記組成のハンドソープ（ｐＨ８．５）は、洗浄性、泡立ち、泡質、洗い流し感、仕上がり感のいずれにおいても、良好な結果を得た。 A hand soap (pH 8.5) having the above composition prepared by uniformly mixing the above components gave good results in all of the cleaning properties, foaming, foam quality, washing-off feeling and finishing feeling.
実施例９（洗顔料）
（質量％）
・オレイン酸 １０．０
・イソステアリン酸 １０．０
・ＰＯＥ（３）ヤシ油アルキルエーテル硫酸ナトリウム ８．０
・ラウリン酸アミドプロピルベタイン ２．５
・アクリルアミド・アクリル酸・
塩化ジメチルジアリルアンモニウム共重合体液（約１０％）
（商品名：ＭＥＲＱＵＡＴ ＰＬＵＳ ３３３０；ナルコ社製） １．０
・カチオン化グアーガム
（商品名：ジャガーＣ−１３−Ｓ；三晶社製） ０．２
・Ｎ−ラウロイル−Ｌ−グルタミン酸ジ
（フィトステリル・２−オクチルドデシル）
（商品名：エルデュウＰＳ−２０３；味の素社製） ２．５
・ユキノシタエキス
（商品名：ユキノシタ抽出液ＢＧ；丸善製薬社製） １．０
・海藻抽出物（商品名：カイソウ抽出液；丸善製薬社製） ０．５
・グリセリン ２．０
・１，３−ブチレングリコール １０．０
・ＥＤＴＡ ０．４
・アスコルビン酸ナトリウム ０．２
・水酸化カリウム 適 量
・ラベンダー油 ０．８
・水 バランス
Example 9 (face wash)
(mass%)
・ Oleic acid 10.0
・ Isostearic acid 10.0
-POE (3) palm oil sodium alkyl ether sulfate 8.0
・ Lamidate amidopropyl betaine 2.5
・ Acrylamide ・ Acrylic acid ・
Dimethyl diallylammonium chloride copolymer liquid (about 10%)
(Product name: MERQUAT PLUS 3330; manufactured by Nalco) 1.0
・ Cationized guar gum
(Product name: Jaguar C-13-S; manufactured by Sankisha) 0.2
N-lauroyl-L-glutamic acid di
(Phytosteryl, 2-octyldodecyl)
(Product name: L-Du PS-203; manufactured by Ajinomoto Co., Inc.) 2.5
・ Yukinoshita Extract
(Product name: Yukinoshita Extract BG; manufactured by Maruzen Pharmaceutical Co., Ltd.) 1.0
・ Seaweed extract (trade name: diatom extract; manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.5
・ Glycerin 2.0
・ 1,3-Butylene glycol 10.0
・ EDTA 0.4
・ Sodium ascorbate 0.2
・ Positive amount of potassium hydroxide ・ Lavender oil 0.8
・ Water balance
上記成分を均一に混合して調製した上記組成の洗顔料（ｐＨ９．０）は、洗浄性、泡立ち、泡質、洗い流し感、仕上がり感のいずれにおいても、良好な結果を得た。 The facial cleanser (pH 9.0) having the above composition prepared by uniformly mixing the above components gave good results in all of the detergency, foaming, foam quality, feeling of washing and finishing.
上記各処方において用いた香料は下記のものである。
本発明によって、泡立ち、洗浄性、すすぎ易さに優れ、使用後に肌に適度なしっとり感を付与し、高温や低温に保存してもそのゲル状態を長期間維持できる安定性に優れた透明ゲル状洗浄剤組成物を提供することができる。 By this invention, it is excellent in foaming, detergency, ease of rinsing, imparts a moderate moist feeling to the skin after use, and has excellent stability that can maintain its gel state for a long time even when stored at high or low temperature A detergent composition can be provided.
Claims (4)
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010209322A (en) * | 2009-02-13 | 2010-09-24 | Kao Corp | Cleaner |
| JP2012201789A (en) * | 2011-03-25 | 2012-10-22 | P & P F:Kk | Transparent soap |
| JP2013544246A (en) * | 2010-11-22 | 2013-12-12 | ▲蘇▼州元素集▲化▼学工▲業▼有限公司 | Dense cleaning composition |
| JP2015172187A (en) * | 2014-02-19 | 2015-10-01 | 株式会社コーセー | detergent composition |
| JP2017193507A (en) * | 2016-04-20 | 2017-10-26 | 日油株式会社 | Oil gel composition |
| CN109897745A (en) * | 2017-12-07 | 2019-06-18 | 株式会社Lg生活健康 | Composition of skin cleanser and preparation method thereof |
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| JPH0457896A (en) * | 1990-06-27 | 1992-02-25 | Yuho Chem Kk | Fluidized soap composition |
| JP2002161028A (en) * | 2000-11-28 | 2002-06-04 | Kose Corp | Composition for cleaning agent |
| JP2003055699A (en) * | 2001-08-20 | 2003-02-26 | Lion Corp | Liquid detergent composition |
| JP2005154360A (en) * | 2003-11-27 | 2005-06-16 | Lion Corp | Skin cleansing agent composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0457896A (en) * | 1990-06-27 | 1992-02-25 | Yuho Chem Kk | Fluidized soap composition |
| JP2002161028A (en) * | 2000-11-28 | 2002-06-04 | Kose Corp | Composition for cleaning agent |
| JP2003055699A (en) * | 2001-08-20 | 2003-02-26 | Lion Corp | Liquid detergent composition |
| JP2005154360A (en) * | 2003-11-27 | 2005-06-16 | Lion Corp | Skin cleansing agent composition |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010209322A (en) * | 2009-02-13 | 2010-09-24 | Kao Corp | Cleaner |
| JP2013544246A (en) * | 2010-11-22 | 2013-12-12 | ▲蘇▼州元素集▲化▼学工▲業▼有限公司 | Dense cleaning composition |
| US9326928B2 (en) | 2010-11-22 | 2016-05-03 | Suzhou Eleco Chemical Industry CO., Ltd. | Thick cleaning composition |
| JP2012201789A (en) * | 2011-03-25 | 2012-10-22 | P & P F:Kk | Transparent soap |
| JP2015172187A (en) * | 2014-02-19 | 2015-10-01 | 株式会社コーセー | detergent composition |
| JP2017193507A (en) * | 2016-04-20 | 2017-10-26 | 日油株式会社 | Oil gel composition |
| CN109897745A (en) * | 2017-12-07 | 2019-06-18 | 株式会社Lg生活健康 | Composition of skin cleanser and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| JP4667163B2 (en) | 2011-04-06 |
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